1224202 玖、發明說明： 【發明所屬之技術領域】 本發明係有關於一種複合功能光學膜，且特別有關於一種 具有硬化層及防污層的複合功能光學膜，藉由硬化層及抗反射 層間的分子作用力來達成永久防污的效果。 【先前技術】 ^近年來隨著高科技產業的發展，對光資訊、光通訊元件品 質的要求越來越高，其中光學膜更是光學元件器材中的關鍵技 術。尤其應用在平面顯示器上，其品質更是有一定的要求，如 高透光率、低反射率等光學性質；及重量輕、厚度薄等特性， 以符合顯示器的輕、薄特性趨勢；並能夠同時具有高硬度、高 耐磨度、高防污效果等物理性質，以提供平面顯示器之良好保 護。 ’、 一般常用的光學膜結構如第丨圖所示，此光學膜包含一基 材110、一硬化層（hard coat layer ) 12〇與一抗反射層 (ant卜reflection layer) 130。該硬化層120可使此光學膜硬度 增加，以保護顯示器内部結構；該抗反射層13〇可降低反射率， 提面穿透率。但此光學膜一般放置於顯示器外層易遭污染。 另一種如第2圖所示之光學膜，是在硬化層22〇與防污層 240間加上一抗反射層（anti-reflecti〇n layer) 23〇,使反射率 降低。雖然此光學膜雖可提供更好的光學品質，但卻會使光學 =的整體膜厚增加，且因其中的硬化層22〇是以濕式精密塗佈 製造、抗反射層230是以無機鍍膜方式製造、防污層24〇又以 濕式精密塗佈製造，故製程非常複雜，以致成本相當高。 另外，一般的防污層是利用浸潰法（dipping)方式塗佈， 也就疋將需要鍍上防污層的基板垂直置入防污層浸泡液中，再 5 1224202 垂直取出，此時兩面均會含有塗料；但若產品只需單面塗佈 時，此方式將不適用，如觸碰式面板（touch panel)用的透明 導電膜，因其外層常與外界接觸故需防污層，但内層的銦錫氧 化物（Indium Tin Oxide，簡稱ITO )導電玻璃層則不需被塗佈， 此時就需要一種單層塗佈方式來塗佈此防污層。 為了更符合市場需求，一種具低反射率、製程簡單且單層 塗佈的光學膜為一項重要的研發課題。 【發明内容】 有鑑於此，本發明的目的就是提供一種複合功能光學膜之 φ 結構及其製造方法，此複合功能光學膜不但符合顯示器規格之 要求，且具有製造方法簡單等特色。 為達上述目的，本發明提供一種複合功能光學膜之結構， 如第3圖所示，包含一基材310 ; —硬化層320位於上述基材 310上，且此硬化層包含奈米尺寸之二氧化矽顆粒321 ;及一 防污層330位於上述硬化層320上，且此防污層330包含一化 合物，該化合物之兩端分別具有氟之官能基332與具有矽烷之 官能基331，且該化合物的矽烷官能基端331朝向該防污層330 及該硬化層320界面、該化合物的氟之官能基端332朝向該防 鲁 污層330上表面。 如上所述之複合功能光學膜的結構，其中基材可為任何光 學元件，如顯示器或鏡片等；且其通常為透明基材，如三醋酸 鹽（triacetate，簡稱TAC )或聚對酞酸乙二酯（即為達克綸， polyethylene terephthalate，簡稱 PET)等。 另外，如上所述之複合功能光學膜的結構，其中硬化層的 厚度約為3〜7um ;且硬化層的存在可增加基材表面之平坦性、 提高尺寸安定性、降低入射光之散射；且硬化層中包含奈米尺 6 1224202 寸之二氧化石夕之顆粒，此二氧切顆粒大小約為iq〜術…更 好為1G〜2〇nm，且藉由控制此二氧切顆粒大小及固含 硬化層呈現透明特性來降低濁度，並 能光學臈整體之耐磨度。 發明之複合功 再者，如上所述之複合功能光學膜的結構，其中防污層的 厚度約為5〜5〇nm;此防污層中包含—化合物，該化合物^ 烷的官能基端會與硬化層中的二氧化矽顆粒產生分子作用 力’使防污層中化合物分子之氟的官能基端朝向防污層上表 面’而氟不但可以降低光線進入的障礙，使此光學膜的穿透率 增加、折射率下降，還可使此防污層的接觸角增加，達到永久 防污的效果。另外，由於本發明是藉由硬化層中的二 粒來使防污層中的化合物中具有氟官能基端朝向防污層上表 面而達永久防污效果，故防污層中的化合物以單層形式 此防污層中最有防污效率，否則防污層的上表面就不一定為氟 之官能基端，而使本發明之效果降低。 此結構之複合功能光學膜的透光率高於9〇%、霧度不大於 0.8%、接觸角高於1〇〇度。 、 為達上述目的，本發明提供一種複合功能光學膜之製造方 法，包括提供一基材；塗佈一包含奈米尺寸之二氧化矽顆粒之 硬化層塗液於上述基材上；將上述硬化層塗液經一第一處理後 形成一硬化層；塗佈一防污層塗液於上述硬化層上，且此防污 層包含一化合物，該化合物之兩端分別具有氟之官能基與具有 矽烷之官能基，且該化合物的矽烷官能基端朝向該防污層及該 硬化層界面、該化合物的氟之官能基端朝向該防污層上表面； 以及將上述防污層塗液經一第二處理後形成一防污層。 如上所述之複合功能光學膜的製造方法，其中基材可為任 何光學元件，如顯示器或鏡片等；且其通常為透明基材，如三 1224202 醋酸鹽（triacetate，簡稱TAC)或聚對酞酸乙二酯（即為達克綸，， polyethylene terephthalate，簡稱 PET)等。 另外，如上所述之複合功能光學膜的製造方法，其中硬化 層的塗佈方式為成捲式塗佈法（roll-to-roll coating )、線棒塗 佈法（wire bar coating )、旋轉塗佈法（spin coating)與喷霧 塗佈法（spray coating )等。且硬化層中所包含的二氧化石夕顆 粒大小約為10〜50nm，更好為10〜20nm。硬化層塗液則包括 起始劑（initiator)、單體（monomer)、含二氧化石夕之寡聚合體 (oligomer)與溶劑等進行高分子聚合反應所需材料；其中各 化合物在此硬化層塗液所佔的比例如下：起始劑為3〜20%、單 麵| 體為5〜70%、含二氧化矽之寡聚合體為5〜70%、溶劑為5〜70%。 此硬化層塗液之黏度約為lcps〜1000cps、固含量約為40%〜 60%。針對此硬化層的第一處理，依序為熱處理（thermal curing ) 與紫外光處理（UV curing );其中熱處理用以烘乾塗液的溶劑， 其作用溫度為60〜150°C ;接著以紫外光處理來開啟聚合反 應，以形成高分子層來使此硬化層硬化，其中紫外光處理之作 用條件為在空氣中，以高壓汞燈照射約300mJ/cm2。經這些處 理後，此硬化層的厚度約為3〜7um。 再者，如上所述之複合功能光學膜的結構，其中防污層的 · 塗佈方式為成捲式塗佈法（roll-to-roll coating )、線棒塗佈法 (wire bar coating)、旋轉塗佈法（spin coating )與喷霧塗佈 法（spray coating )等。其中防污層塗液包括一化合物與共溶 劑（co-solvent);其中需控制此化合物在防污層塗液中的濃度， 使塗佈後的化合物以單層形式存在於此防污層中，如此可使本 發明的防污效果達最佳化；而共溶劑為HFE-7100。此防污層塗 液之固含量約為0.1%〜1%。而防污層的第二處理為熱處理， 此熱處理用以烘乾塗液溶劑，且其作用溫度為60〜150T：。經 8 1224202 這些處理後，此防污層的厚度約為5〜50nm。 ， 由此製造方法所製造的複合功能光學膜，其透光率約為透 光率高於90%、霧度不大於0.8%、接觸角高於100度。 【實施方式】 為使本發明之上述和其他目的、特徵和優點能更明顯易 懂，下文特舉出較佳實施例，並配合所附圖式，作詳細說明如 下： 【實施例1】 硬化層塗液成分百分比與物理特性：起始劑為3〜20%、單 φ 體為5〜70%、含二氧化矽之寡聚合體為5〜70%、溶劑為5〜70%。 此硬化層塗液之黏度約為lcps〜lOOOcps、固含量約為40%〜 60%。 防污層塗液成分與物理特性：化合物為L18256;共溶劑為 HFE-7100。塗液之固含量約為0.1%。 將硬化層塗液利用成捲式塗佈法（roll-to-roll coating)塗 佈在聚對駄酸乙二酯（即為達克論，polyethylene terephthalate， 簡稱PET)基材上，其塗佈速度為0.5m/min;再利用60°C/850rpm 的熱處理將硬化層塗液的溶劑烘乾；接者利用在〇.5m/min的速 · 度下以H-lamp紫外光處理啟發聚合反應，使硬化層塗液硬化， 形成硬化層。 再將防污層塗液利用成捲式塗佈法（roll-to-roll coating ) 塗佈在上述硬化層上，其塗佈速度為0.5m/min ;再利用溫度為 120°C、出風速率為850rpm的熱處理將共溶劑乾，即形成防污 層。 將完成後的複合光學膜進行物理性質測試及光學測試，其 乾膜厚度為3〜7/zm、透光率為90.8%、濁度為0·8%。另外， 9 1224202 j 接觸角及防污性的測試結果列於 . 字筆在此複合光學膜上做4 "，、中防巧性是以油性簽 擦拭乾淨做為參考6己錢，再利用擦拭方式，觀察是否 【實施例2】 硬化層塗液成分百分比盥物 體為5〜7·含二氧切之寬、2特性·起始劑為3〜、單 茈#彳爲泠 來1:7體為5〜7〇G/。、溶劑為5〜70〇/〇。 化層塗液之黏度…cps〜雜cps、固含量約請〜 將硬化層塗液利用成捲式塗佈法（續如_ coating )塗 ，在聚紐酸乙二自旨（即為達克綸，㈣州吵咖㈣編批， 間稱PET)基材上，其塗佈速度為每分鐘5()公分；再利用6〇 C/85〇rpm的熱處理將硬化層塗液的溶劑烘乾；接者利用在 〇.5m/min的速度下以H_iamp的紫外光處理啟發聚合反應，使 硬化層塗液硬化，形成硬化層。 再將防污層塗液利用線棒塗佈法（wire bar c〇ating)塗佈 在上述硬化層上，其塗佈速度為31cm/min，其濕膜厚度為Η·4 //m,再利用/JDL度為120C、出風速率為850rpm的熱處理將共 溶劑乾，即形成防污層。 將完成後的複合光學膜進行物理性質測試及光學測試，其 乾膜厚度為3〜7// m、透光率為90.8%、濁度為〇·8%。另外， 接觸角及防污性的測試結果列於表1，其中防污性是以油性簽 字筆在此複合光學膜上做記號後，再利用擦拭方式，觀察是否 擦拭乾淨做為參考。 【比較實施例1】 直接取聚對酞酸乙二酯（即為達克綸，p〇1yethylene 10 1224202 terephthalate，簡稱 pE 、 於表其中防污性是以其接㈣及防污性，結果列 利用擦拭方式，觀窣θ否枫只子筆在此基材上做記號後，再 硯察疋否擦拭乾淨做為參考。 【比較實施例2】 硬化^塗液成分百分比與物理特性：起始劑為3〜观、單 : 、各一氧化矽之养聚合體為5〜70%、溶劑為5〜70〇/〇。 在硬化層塗液之黏度約為lcps〜1〇〇〇cps、固含 〇%〜 60〇/〇 〇1224202 发明 Description of the invention: [Technical field to which the invention belongs] The present invention relates to a composite functional optical film, and more particularly to a composite functional optical film having a hardened layer and an antifouling layer. Molecular force to achieve the effect of permanent antifouling. [Previous technology] ^ In recent years, with the development of high-tech industries, the requirements for the quality of optical information and optical communication components have become higher and higher. Among them, optical films are the key technology in optical component equipment. Especially applied to flat display, its quality has certain requirements, such as high light transmittance, low reflectivity and other optical properties; and light weight, thin thickness and other characteristics to meet the light and thin characteristics of the display trend; and At the same time, it has physical properties such as high hardness, high abrasion resistance, and high antifouling effect to provide good protection for flat displays. ′. The structure of a commonly used optical film is shown in FIG. 丨. The optical film includes a substrate 110, a hard coat layer 12 and an anti-reflection layer 130. The hardened layer 120 can increase the hardness of the optical film to protect the internal structure of the display. The anti-reflection layer 130 can reduce the reflectivity and increase the transmittance of the surface. However, this optical film is generally placed on the outer layer of a display and is easily contaminated. Another type of optical film as shown in FIG. 2 is to add an anti-reflective layer 23o between the hardened layer 22o and the antifouling layer 240 to reduce the reflectance. Although this optical film can provide better optical quality, it will increase the overall thickness of the optical film, and because the hardened layer 22 is manufactured by wet precision coating, the anti-reflection layer 230 is an inorganic coating. The antifouling layer 24 is manufactured by a method and wet precision coating, so the manufacturing process is very complicated and the cost is quite high. In addition, the general antifouling layer is applied by the dipping method, that is, the substrate to be coated with the antifouling layer is vertically placed in the antifouling layer soaking solution, and then 5 1224202 is taken out vertically. Both will contain coatings; but if the product only needs to be coated on one side, this method will not be applicable. For example, the transparent conductive film for touch panels requires an antifouling layer because the outer layer is often in contact with the outside world. However, the inner layer of indium tin oxide (ITO) conductive glass layer does not need to be coated, and a single-layer coating method is needed to coat the antifouling layer. In order to better meet market demands, an optical film with a low reflectivity, a simple process, and a single-layer coating is an important research topic. [Summary of the Invention] In view of this, the object of the present invention is to provide a φ structure of a composite functional optical film and a manufacturing method thereof. The composite functional optical film not only meets the requirements of display specifications, but also has the characteristics of simple manufacturing method and the like. In order to achieve the above object, the present invention provides a structure of a composite functional optical film, as shown in FIG. 3, including a substrate 310; a hardened layer 320 is located on the above substrate 310, and the hardened layer includes a nanometer size two Silicon oxide particles 321; and an antifouling layer 330 is located on the hardened layer 320, and the antifouling layer 330 includes a compound having a functional group 332 of fluorine and a functional group 331 of silane at both ends of the compound, and the The silane functional end 331 of the compound faces the interface between the antifouling layer 330 and the hardened layer 320, and the functional end 332 of the fluorine of the compound faces the upper surface of the antifouling layer 330. The structure of the composite functional optical film as described above, wherein the substrate can be any optical element, such as a display or lens; and it is usually a transparent substrate, such as triacetate (TAC) or polyethylene terephthalate Diesters (that is, Dacron, polyethylene terephthalate, PET for short). In addition, the structure of the composite functional optical film described above, wherein the thickness of the hardened layer is about 3 to 7um; and the presence of the hardened layer can increase the flatness of the surface of the substrate, improve dimensional stability, and reduce the scattering of incident light; and The hardened layer contains particles of nanometer 6 1224202 inches of dioxide dioxide. The size of the dioxygen cut particles is about iq ~ surgery ... more preferably 1G ~ 20nm, and by controlling the size of the dioxide particles and The solid-containing hardened layer exhibits transparent properties to reduce turbidity, and it is able to wear-resistant the entire optical fiber. In addition, the composite function of the invention, the structure of the composite functional optical film as described above, wherein the thickness of the antifouling layer is about 5 to 50 nm; the antifouling layer contains a compound, and the functional end of the compound Generate molecular force with the silicon dioxide particles in the hardened layer 'make the functional end of the fluorine of the compound molecules in the antifouling layer face the upper surface of the antifouling layer', and the fluorine can not only reduce the barrier to light entry, but also make the optical film wear through. Increasing transmittance and decreasing refractive index can also increase the contact angle of this antifouling layer to achieve the effect of permanent antifouling. In addition, since the present invention uses two particles in the hardened layer to make the compound in the antifouling layer have a fluorine functional end toward the upper surface of the antifouling layer to achieve a permanent antifouling effect, the compound in the antifouling layer is a single Layer type This antifouling layer has the most antifouling efficiency. Otherwise, the upper surface of the antifouling layer may not be the functional end of fluorine, and the effect of the present invention will be reduced. The composite functional optical film of this structure has a light transmittance of more than 90%, a haze of not more than 0.8%, and a contact angle of more than 100 degrees. In order to achieve the above object, the present invention provides a method for manufacturing a composite functional optical film, which includes providing a substrate; coating a coating solution of a hardened layer containing nanometer-sized silicon dioxide particles on the substrate; The layer coating liquid is subjected to a first treatment to form a hardened layer; an antifouling layer coating liquid is coated on the above hardened layer, and the antifouling layer contains a compound having functional groups of fluorine at both ends of the compound and having A functional group of silane, and the silane functional end of the compound faces the interface of the antifouling layer and the hardened layer, and the functional end of fluorine of the compound faces the upper surface of the antifouling layer; and An antifouling layer is formed after the second treatment. The method for manufacturing a composite functional optical film as described above, wherein the substrate can be any optical element, such as a display or a lens; and it is usually a transparent substrate, such as tri 1224202 triacetate (TAC) or poly-terephthalate Ethylene glycol (that is, Dacron, polyethylene terephthalate, PET for short) and the like. In the manufacturing method of the composite functional optical film as described above, the coating method of the hardened layer is a roll-to-roll coating method, a wire bar coating method, or a spin coating method. Spin coating, spray coating and the like. Moreover, the particle size of the dioxide contained in the hardened layer is about 10 to 50 nm, more preferably 10 to 20 nm. The coating solution of the hardened layer includes an initiator, a monomer, a oligomer containing a dioxide and an oligomer, and a solvent, etc., which are required for the polymer polymerization reaction. Among them, each compound is in the hardened layer. The proportion of the coating solution is as follows: the starting agent is 3 to 20%, the single-sided body is 5 to 70%, the oligomer containing silicon dioxide is 5 to 70%, and the solvent is 5 to 70%. The viscosity of this hardened coating liquid is about lcps ~ 1000cps, and the solid content is about 40% ~ 60%. The first treatment for this hardened layer is thermal curing and UV curing in this order; the thermal treatment is used to dry the solvent of the coating liquid, and its working temperature is 60 ~ 150 ° C; Light treatment is used to start the polymerization reaction to form a polymer layer to harden the hardened layer. The condition of the ultraviolet light treatment is to irradiate about 300mJ / cm2 with a high-pressure mercury lamp in the air. After these treatments, the thickness of this hardened layer is about 3 ~ 7um. In addition, as for the structure of the composite functional optical film as described above, the coating method of the antifouling layer is a roll-to-roll coating method, a wire bar coating method, Spin coating method, spray coating method, and the like. The antifouling layer coating liquid includes a compound and a co-solvent; the concentration of the compound in the antifouling layer coating liquid needs to be controlled so that the coated compound exists as a single layer in the antifouling layer. In this way, the antifouling effect of the present invention can be optimized; and the co-solvent is HFE-7100. The solid content of this antifouling layer coating liquid is about 0.1% to 1%. The second treatment of the antifouling layer is a heat treatment. This heat treatment is used to dry the coating liquid solvent, and its action temperature is 60 ~ 150T :. After these treatments of 8 1224202, the thickness of this antifouling layer is about 5 ~ 50nm. The composite functional optical film manufactured by this manufacturing method has a light transmittance of about 90% or higher, a haze of not more than 0.8%, and a contact angle of more than 100 degrees. [Embodiment] In order to make the above and other objects, features, and advantages of the present invention more comprehensible, the following describes the preferred embodiments in detail with the accompanying drawings as follows: [Example 1] Hardening Percentage and physical characteristics of layer coating liquid: 3 ~ 20% of the starting agent, 5 ~ 70% of the single φ body, 5 ~ 70% of the oligomer containing silicon dioxide, and 5 ~ 70% of the solvent. The viscosity of this hardened layer coating liquid is about lcps ~ 1000cps, and the solid content is about 40% ~ 60%. Antifouling layer coating liquid composition and physical properties: the compound is L18256; the co-solvent is HFE-7100. The solid content of the coating liquid is about 0.1%. The hardened layer coating liquid is applied on a polyethylene terephthalate (PET) substrate by a roll-to-roll coating method, and the coating is applied. The speed is 0.5m / min; then the heat treatment of the hardened layer coating liquid is dried by heat treatment at 60 ° C / 850rpm; and then the H-lamp ultraviolet light treatment is used to inspire the polymerization reaction at a speed of 0.5m / min. , The hardening layer coating liquid is hardened to form a hardened layer. The antifouling layer coating liquid is further coated on the hardened layer by a roll-to-roll coating method, the coating speed is 0.5 m / min; the reuse temperature is 120 ° C, and the wind speed A heat treatment at 850 rpm dries the co-solvent to form an antifouling layer. The completed composite optical film was subjected to physical property test and optical test. The dry film thickness was 3 to 7 / zm, the light transmittance was 90.8%, and the turbidity was 0.8%. In addition, the test results of 9 1224202 j contact angle and antifouling are listed in the following. The pen is made on this composite optical film 4 ", the middle anti-smartness is wiped clean with an oily signature as a reference. Wipe method and observe if [Example 2] Percentage of the coating composition of the hardened layer is 5 ~ 7. The width containing dioxane, 2 characteristics. The starting agent is 3 ~, single 茈 # 彳 为 凌 来 1: 7 The volume is 5 to 70 g /. The solvent is 5 ~ 70 //. The viscosity of the coating solution ... cps ~ Miscps, the solid content is about ~ Please apply the coating of the hardened layer using a roll coating method (continued as _ coating), and apply it on polyethylene acid (that is, DAK) The coating speed is 5 () cm per minute on the base material of Luzhou, Luzhou Noisy Coffee, and the coating speed is 5 (cm) per minute; and then the solvent of the hardened layer coating liquid is dried by heat treatment at 60C / 85rpm. ; The receiver uses the UV light treatment of H_iamp at a speed of 0.5 m / min to inspire the polymerization reaction, so that the hardened layer coating liquid is hardened to form a hardened layer. The antifouling layer coating liquid was further coated on the hardened layer by a wire bar coating method, the coating speed was 31 cm / min, and the wet film thickness was Η · 4 // m, and The anti-fouling layer is formed by drying the co-solvent with a heat treatment with a degree of / JDL of 120C and an air velocity of 850 rpm. The completed composite optical film was subjected to physical property test and optical test. The dry film thickness was 3 to 7 // m, the light transmittance was 90.8%, and the turbidity was 0.8%. In addition, the contact angle and antifouling test results are listed in Table 1. Among them, the antifouling property is marked on the composite optical film with an oil-based marker pen, and then wiped to see if it is clean. [Comparative Example 1] Polyethylene terephthalate (that is, Dacron, p〇1yethylene 10 1224202 terephthalate, abbreviated as pE) is shown in the table. The antifouling property is the resistance and antifouling property. By using the wiping method, after observing whether θNo maple pen is marked on this substrate, check whether it is wiped clean as a reference. [Comparative Example 2] Hardening ^ Coating liquid composition percentage and physical characteristics: Initial The agent is 3 ~ view, single:, the nutrient polymer of each silicon oxide is 5 ~ 70%, and the solvent is 5 ~ 70〇 / 〇. The viscosity of the coating solution in the hardened layer is about lcps ~ 1000cps, solid Contains 0% ~ 60〇 / 〇〇
將硬化層塗液利用成捲式塗佈法（rQL⑹1⑽㈣）塗 ，在聚㈣ m (㈣達克綸，⑽yethylene terephthaiate， 簡稱PET)基材上，其塗佈速度為〇.5m/min;再利用_ /85_m 的熱處理將硬化層塗液的溶劑烘乾；接者利用在〇 5m/min的速 度下以H-lamp的紫外光處理啟發聚合反應，使硬化層塗液硬 化’形成硬化層。 將完成後的光學膜進行接觸角及防污性的測試，結果列於 表1 ’其中防污性是以油性簽字筆在此光學膜上做記號後，再 利用擦拭方式，觀察是否擦拭乾淨做為參考。 表1 _ 實施例1 實施例2 比較實施 例1 比較實施 例2 結構 防污層/硬 化層/基材 防污層/硬 化層/基材 硬化層/基 材 基材 簽字筆測 言式 可擦拭 可擦拭 不可擦拭 不可擦拭 接觸角 103.05 104.3 70.88 31.85 11 學膜均可= ，實施例1與實施例2的本發明之複合光 實施例7 I 但無防污層的比較實施例1與單純基材的比較 之 句無法擦拭，證明本發明之複合光學膜的確罝有良好 角m;此外，接觸角測試結果發現防污層確實能使接觸 門S入，違防污效果。 雖，本發明已揭露較佳實施例如上1其並非用以限定本 任何熟習此技藝者，在不脫離本發明之精神和範圍内， 些許之更動與㈣，因此本發明之保護範圍當視後附之 申請專利範圍所界定者為準。 參The coating solution of the hardened layer is applied by a roll coating method (rQL⑹1 ，), and the coating speed is 0.5 m / min on a poly㈣m (㈣ ethylene terephthaiate, referred to as PET) substrate; reuse The heat treatment of _ / 85_m heats the solvent of the coating of the hardened layer; the receiver then uses H-lamp ultraviolet light treatment at a speed of 0.05 m / min to inspire the polymerization reaction, so that the hardened coating is hardened to form a hardened layer. The completed optical film was tested for contact angle and antifouling. The results are shown in Table 1. 'The antifouling is marked on the optical film with an oil-based signature pen, and then wiped to see if it is clean. For reference. Table 1 _ Example 1 Example 2 Comparative Example 1 Comparative Example 2 Structural antifouling layer / hardened layer / base material antifouling layer / hardened layer / base material hardened layer / base material signature pen tester wipeable Can be wiped, not wiped, and not wiped. The contact angle is 103.05 104.3 70.88 31.85 11 The film can be both, Example 1 and Example 2 of the composite light of the present invention Example 7 I but without antifouling layer Comparative Example 1 and simple substrate The comparison sentence cannot be wiped, which proves that the composite optical film of the present invention does have a good angle m; in addition, the contact angle test results found that the antifouling layer can indeed make the contact door S enter, which violates the antifouling effect. Although the present invention has been disclosed as a preferred embodiment, it is not intended to limit any person skilled in the art. Without departing from the spirit and scope of the present invention, some changes and modifications are made. The attached application patent shall prevail. Participate
12 以4202 【圖式簡單說明】 ' 第1圖為一剖面圖，用以說明習知光學膜的結構。 第2圖為一剖面圖，用以說明另一習知光學膜的龄 第3圖為一剖面圖，用以說明本發明 、° 。 構 月设合功能光學膜的 【符號說明】 110、210、310〜基材 120、220、320〜硬化層 240、330〜防污層 130、230〜抗反射層 321〜二氧化矽顆粒 _ 3 31〜化合物的矽烷官能基端 332〜化合物的氟官能基端12 Take 4202 [Brief description of the drawings] 'Figure 1 is a sectional view for explaining the structure of a conventional optical film. Fig. 2 is a cross-sectional view illustrating the age of another conventional optical film. Fig. 3 is a cross-sectional view illustrating the invention. [Symbol description] 110, 210, 310 ~ substrate 120, 220, 320 ~ hardened layer 240, 330 ~ antifouling layer 130, 230 ~ anti-reflection layer 321 ~ silicon dioxide particles _ 3 31 ~ Silane functional end of compound332 ~ Fluorofunctional end of compound
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