TWI224014B - Device and method for producing sterilized water - Google Patents

Device and method for producing sterilized water Download PDF

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Publication number
TWI224014B
TWI224014B TW091133830A TW91133830A TWI224014B TW I224014 B TWI224014 B TW I224014B TW 091133830 A TW091133830 A TW 091133830A TW 91133830 A TW91133830 A TW 91133830A TW I224014 B TWI224014 B TW I224014B
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Taiwan
Prior art keywords
water
aqueous solution
mentioned
nozzle
mixing unit
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TW091133830A
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Chinese (zh)
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TW200304836A (en
Inventor
Yoshinori Ota
Kenichi Kato
Takeshi Asami
Tatsuo Okazaki
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Sony Corp
Vta Co Ltd
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Publication of TW200304836A publication Critical patent/TW200304836A/en
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Publication of TWI224014B publication Critical patent/TWI224014B/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
    • B01F23/23105Arrangement or manipulation of the gas bubbling devices
    • B01F23/2312Diffusers
    • B01F23/23121Diffusers having injection means, e.g. nozzles with circumferential outlet
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/76Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Nozzles (AREA)

Abstract

To provide a device for producing sterilized water which is constituted in a compact size as a whole although a diluting and mixing unit with an enough volume is installed, which does not require a check valve and which produces no chlorine gas. In the device to produce hypochlorous acid-sterilized water by adding an aqueous solution of sodium hypochlorite and an acidic aqueous solution such as hydrochloric acid to the raw water of city water, well water or the like, the inside of a diluting and mixing tank 50 also as a buffer tank is provided with a nozzle 21 for addition of the aqueous solution of sodium hypochlorite, a nozzle 26 for addition of the acidic aqueous solution and mixing and stirring tanks 31, 32 so as to add the raw water and the aqueous solutions from the topside in the vertical direction.

Description

1224014 玫、發明說明: 【發明所屬之技術領域】 本發明係關於製造次氯酸鈉殺菌水之裝置及其方法 於殺菌水製造裝置及殺g水製造方法,特別是關於含次氯 :夂納之殺菌水製造裝置及其製造方法,係於自來水和井水 專原X中添加混合次氣酸鈉水溶液和鹽酸、硫酸、醋酸等 之酸性水溶液來製造之。 、 【先前技術】 已知可於原水中添加次氯酸鈉(NaC1〇)和鹽酸(HC1)等, 並經混合能於水中生成產生殺菌力強之次氯酸鈉(Hci^ 殺菌水。但次氯酸鈉和鹽酸直接反應的話會可能產生有宝 的氯氣(Ch)。在此,如特開平11-1 88083號公報和新型第 3058642號公報所記載的,為確保適當之pH值,一邊調整 次氣酸鈉和鹽酸等之添加量一邊想其添加混合之方法和裝 置。 ’ 在此,由圖1 4來說明先前裝置概略。又在此為使用作為 酸性水溶液之鹽酸水溶液。然後,於圖1 4所示之裝置,首 先連接逆流防止閥1 2 1於原水供應管路1 20,在其下游側分 歧2條管路123、124後,於這些管路123、124各連接各逆流 防止閥1 25、1 26。然後,連接於有次氣酸鈉水溶液添加喷 嘴132及鹽酸水溶液添加喷嘴137之管路127、128,由這些 添加喷嘴1 3 2、1 3 7適量添加各次氯酸鈉水溶液和鹽酸水溶 液於管路127及管路128。接著,於其下游有稀釋攪拌槽129 及1 3 0,並充分混合所添加之次氯酸鈉水溶液及鹽酸水溶液 和所供應之原水。之後,管路145、146合流並通過合流管 1224014 路147引入混合攪拌槽148,並充分混合已稀釋之各水溶 液。此時’為充分進行混合液之攪拌混合,因應必要,可 没法加大混合擾拌槽148本體,更於混合攪拌槽148之下游 來連接緩衝儲槽。 在如圖14所示之殺菌水製造裝置,一般為從鉛直方向下 部來供應原水’如藉由關閉連接於混合攪拌槽148下游之前 端停止閥(無圖示)來停止原水之供應的話,利用從檢測原 水流s之感應裝置(無圖示)等之信號來停止幫浦丨34、 139 ’因此也停止次氣酸鈉水溶液及鹽酸水溶液之添加。因 檢測出原水供應之停止後才停止添加,因此在時間上與原 水停止相比下稍有延遲。故變成對於無流水之原水來進行 上述各水溶液之添加。因此,高濃度次氣酸鈉及鹽酸水溶 液,便滞留在添加次氣酸鈉水溶液及鹽酸水溶液之添加喷 嘴132、137之附近。如此,所滯留的次氣酸鈉水溶液及鹽 酸水溶液因其比重比原水重,因此隨時間而引起沉澱擴 散,並向原水供應口附近移動,故有次氣酸鈉與鹽酸反應 而產成氣氣之顧慮,因此有必要在各添加喷嘴132、137之 正下方來設置逆流防止閥125、126等之閉鎖機構。 在此,像這樣之殺菌水製造裝置設置於寒冷地帶之情況 下,為防止因凍結而使管路破損,有必要在逆流防止閥 125、126之上游與下游來個別設置排水機構,因此不只裝 置複雜且價格變高,也有因操作複雜而導致麻煩。 又在如圖14所示之殺菌水製造裝置,上述添加噴嘴丨^、 137為只有在加比所設定壓力高之壓力下才設置開放閥,特 1224014 別是次氣酸鈉水溶液之氣化氣體易停滯於添加喷嘴丨32内 部,滯留於添加喷嘴132内之氣化氣體在保持該滯留狀態 下,氣泡會變大。於是,在有氣泡之狀況下將其排出於管 路1 27内的話,次氯酸鈉水溶液之供應會一時地減少,因有 降低所製造殺菌水之殘留氣濃度和pH之問題。 又在如圖1 5所# ’如在比次氯酸鈉水溶液及鹽酸水溶液 之添加喷嘴丨32、i37更錯直方向上部,來設置授拌次氣酸 鈉水溶液及鹽酸水溶液之混合攪拌槽148的話,因混合所製 造之次氣酸鈉本身會沉澱擴 於次氣酸鈉水溶液添加喷嘴 氯氣之可能性,所以於添加 也變成有必要設置逆流防止 散’且經低PH值之鹽酸水溶液 1 3 2之附近沉澱,同樣也有產生 噴嘴132與混合攪拌槽148之間 閱1 5 0,因此更使問題變複雜。 又由如圖14及圖15所示之管路所構成之裝置,其空間浪 費多,且裝置全體大型化,為在混合攪拌槽148充分進行攪 拌,也有必要增大混合攪拌槽148本體容積並於混合攪拌槽 148下部設置緩衝槽之情況,因此有導致褒置更大塑化之問 題0 鐘於像這樣之問題點’本發明之目的為提供―殺菌水製 造裝置及製造方法’其係無需設置像逆流防止閥之閉鎖機 構,能小型化全體裝置並可於混合料槽内進行充分授摔。 【發明内容】 本案之主要發明 動於給水管路之自 液和鹽酸、硫酸、 係關於一種殺菌水製 來水或井水等原水中 醋酸等之酸性水溶液 造裝置,其係在流 添加次氯酸納水溶 ’來製造一定pH值 1224014 及/或殘留氯濃度之殺菌水,其中該殺 稀釋混合單元,其連接供應上述原水 述次氯酸鈉水溶液之添加噴嘴、添力 加噴嘴及排出已製造之殺菌水之排出 元係由以板狀體封住上下之筒體所構 管路、上述次氣酸鈉水溶液之添加噴 之添加噴嘴與上側之板狀體結合,由 所供應之原水係由稀釋混合單元内側 被分歧2個以上之通路,且至少位於一 氯酸鈉水溶液之添加噴嘴,而於殘餘 酸性水溶液添加喷嘴;在構成稀釋混 流動已添加次氣酸鈉水溶液之鹼性水 添加上述酸性水溶液之酸性水之第二 合單元排出混合上述鹼性水和上述酸 管體;上述次氣酸鈉水溶液之添加喷 體,上述酸性水溶液之添加喷嘴連接 於上述第一管體及上述第二管體設置 上述稀釋混合單元内部排放在上述稀 體附近之上述鹼性水及上述酸性水者 設置通水口或溝,其係在該第三管體 合早元上側板狀體附近所製造之殺菌 在此’於上述稀釋混合單元上側之 置輔助板,藉於該辅助板所形成延向 成上述分歧通路,經上述上側板狀體 _水製造裝 之供水管路 上述酸性水 管路;該稀 成,上述原 嘴和上述酸 i述原水之 戶斤構成之分 方通路内配 通路内至少 合單元之筒 之第一管體 管體,和從 性水之殺菌 嘴連接於上 於上述第二 通水口或溝 釋混合單元 ,並於上述 内引進在上 水者。 板狀體内側 橫方向之溝 之原水供應 置含有一 、添加上 溶液之添 釋混合單 水之供水 性水溶液 供水管路 歧通路來 置上述次 一個結合 體,設置 、流動已 該稀釋混 水之第三 述第一管 管體,且 ’其係於 丁側板狀 第三管體 述稀釋混 重疊地配 或穴來構 口,於上 -10- 1224014 述分歧通路供應原水為佳。又’於構成上述稀釋混合單元 之筒體内上下複數段地來配列擋板為佳。又,經流動驗性 水之隙間在上述第一管體外側設置第四管體,經流動酸性 水之隙間在上述第二管體外側設置第五管體·,經流動殺菌 水之隙間在上述第三管體外側設置第六管體,於上述第四 管體及上述第五管體來設置於上側板狀體附近之通水口或‘ 通水溝,並在上述第六管體來設置於下側板狀體附近之通★ 水口或通水溝為佳。 又,在各別連接對應上述次氯酸鈉水溶液添加喷嘴及/ _ 或上述酸性水溶液添加喷嘴之水溶液供應管路同時,也各 別連接別的管路,該別的管路位於上述次氣酸鈉水溶液添 加喷嘴及/或酸性水溶液添加喷嘴裝置於稀釋混合單元時 所對應之水溶液供應管路更鉛直方向上方為佳。又有於途 中連接幫浦之水溶液供應管路,該幫浦從各對應水溶液儲 槽輸运-人氯酸納水溶液或酸性水溶液於各添加喷嘴,且依 上述水/谷液供應管路與儲槽之連接部、上述幫浦、上述添 喷=之順序於錯直方向下方來設置上游側部份為佳。· 1有途中連接幫浦之水溶液供應管路,該幫浦從各對 $ ^ /合液儲槽輸送次氯酸鈉水溶液或酸性水溶液於各添加 、 及於途中連接開閉閥並連接於對應上述添加喷嘴之* 水溶液错轉R π> 曰間之回&管路,藉打開上述回流管路之上述開 閉閥,以上沭暂、占收〜 疋駕浦將所送出之水溶液回流至儲槽為佳。又, 酉蔓 * _ /容液儲槽及/或酸性水溶液儲槽有各兩個以上 之管路連拉立 °丨 該管路連接部具備藉彈性機構彈性地可施 -11- 1224014 壓之閥體,如在上述管路連接部連接管 閥體之同時,如從上述管路i車姑a " 打開上述 <钱邵卸下營跋 體經上述彈性機構封鎖,一方之总 的清,上述閥 溶液供應管路之同時,其他方技連接一連接於上述水 流管路為佳。 連接邛連接於上述回 關於製造方法之主要發明係關於一種殺菌水 其係在流動於給水管路之自來水或 、、置 酸鈉水溶液和鹽酸、硫酸、醋 ,、7中添加次氯 ^ ττ 文4之酸性水溶液,來摔 一疋ΡΗ值及/或殘留氯漢度之殺菌水,其中該殺菌水 置含有-稀釋混合單元,其連接 :囷水氣造裝 路、添加上述次氯酸鈉水溶液之添加噴嘴 :“ 水溶液之添加喷嘴及排出已製菌 ^ 、’〔馱性 :Γ合單元係…狀體封L之二之 酸:::二管路、上述次氯酸納水溶液之添加噴嘴和上述 …浴液之添加喷嘴與上側之板狀體結合,由水 :::管路所供應之原水係由稀釋混合單元内側所構成之 =通路來分歧2個以上之通路,且至少位於—方通路内配 逑次氯酸納纟溶液之添加喷冑,而㈣餘通路内至少 :結^性水溶液之添加噴嘴;在構成稀釋混合單元之 ^二设置流動已添加次氯酸鈉水溶液之鹼性水之第一管 f =流動已添加上述酸性水溶液之酸性水之第二管體,和 =該稀釋混合單元排出混合上述鹼性水和上述酸性水之殺 囷水之第二管體;上述次氣酸鈉水溶液之添加噴嘴連接於 上述第一管體,上述酸性水溶液之添加喷嘴連接於上述第 -12 · 1224014 二管體,且於上 溝,其於上述稀 下側板狀體附近 三管體設置通水 釋混合單元上侧 在此,有於途 各對應水溶液儲 添加喷嘴,且依 述幫浦、上述添 側部份為佳。 本案發明之最 合單元係作為於 嘴,和稀釋混合 體。又,原水供 方,即使於添加 液和酸性水溶液 構造無需逆流防 再者,藉由上 淡之水溶液接觸 量之氯氣,因氯I 又,加上考量安 第1管體及第2管 第4管體及第5管: 單元之筒體上部/ 述第一管體及上述第二管體設置通水口或 釋混合單元内部排放在上述稀釋混合單元 之上述驗性水及上述酸性水,並於上述第 口或溝’其在該第三管體内引進在上述稀 板狀體附近所製造之殺菌水。 中連接幫浦之水溶液供應管路,該幫浦從 槽輸送次氯酸鈉水溶液或酸性水溶液於各 上述水溶液供應管路與儲槽之連接部、上 加喷嘴之順序於鉛直方向下方來設置上游 佳樣態,係設置稀釋混合單元,該稀釋混 所製造殺菌水之緩衝槽本體内設置添加喷 槽及混合攪拌槽之構造,藉此,小型化全 應係位於比添加噴嘴前端部更鉛直方向上 噴嘴前端附近所停滯高濃度次氯酸鈉水溶 沉澱擴散,並不會擴及原水供應路,故此 止閥。 述水溶液於混合攪拌槽内擴散,因與十分 ,該構造幾乎不產成氯氣,如即使產生微 L再一次溶入殺菌水中,故無此問題產生。 全性時,於流動添加各水溶液之稀釋液之 體外側設置第4及第5管體,藉配置對這些 體之混合授拌槽之出σ於構成該稀釋混合 則,而使比重重、高濃度之次氯酸鈉水溶 -13- 1224014 液和馬濃度之酸性水溶液不流入混合攪拌槽,而可確實 止各水溶液反應而產生氯氣。 又’為了除去次氯酸鈉氣化氣體之影響,以各水溶液 槽出口、幫浦、添加噴嘴之順序來設置下游側使其位於 直方向上方之同時,添加喷嘴之添加方向係為鉛直方向 於其相反方向使連接逃脫氣化氣體之管路,該管路 電開閉閥來連接各水溶液儲槽,除去於儲槽交換時進入 路之空氣和長時間停止後於供應管路内所產生之氣化氣 時來打開開閉閥,藉幫浦運轉使這些氣體與水溶液回到 槽’而能總除去供應管路内及添加喷嘴内之氣體。 又,各水溶液之濃度雖不高,但仍然為避免其直接接 人體皮膚,和避免因錯誤之潑灑而混合兩種水溶液進而 ^氣氣,各水溶液儲槽於儲槽下面有兩個管路連接部, 官路連接部有以彈簧和彈性體所附加之閥體,通常這些 路連接部閥體為關閉的,連接儲槽於裝置時,藉由安裝 管路侧接頭之突起部等來使上述彈簧和彈性體變形而施 閥體,初使管路連接部開啟,形成儲槽和水溶液供應管 及管路内之氣體返回儲槽之返回管路之兩個管路同時盥 槽接續之構造。藉此,如從裝置外拆除儲槽,管路連接 會再次關閉,因無儲槽内之水溶液向儲槽外撥 【實施方式】 應 以下藉由圖示之一實施型態來說明本發明。圖丨係以區 表示本實施型態之殺菌水製造裝置全體之構成圖。首先 為從上水道供應供應水而設置原水供應管路丨〇,並於該 防 儲 鉛 下 經 管 體 儲 觸 產 該 管 於 壓 路 儲 部 段 原 •14- 1224014 水供應管路l 〇連接減壓閥丨丨。藉由減壓閥丨丨減壓之供應水 係通過電磁閥1 2,並通過流量計1 3、1 4,此外於通過定流 量閥1 6後,經逆流防止閥丨7供應到稀釋混合單元5〇。 於稀釋混合單元50内,原水供應管路1〇分歧成兩條分歧 路60。於各分歧路60配置次氯酸鈉水溶液添加噴嘴2丨及鹽 酸水溶液添加噴嘴26,通過這些添加噴嘴21、26並添加各 水溶液後’在稀釋混合槽31、32混合各水溶液和原水,並 通水於混合攪拌槽3 3内。經混合所製造之殺菌水係藉由排 出官路44排出於稀釋混合單元5〇之外。又,於排出管路^ 連接pH計34,於檢查所製造之殺菌水之pH值後排水於裝置 外0 可於排出管路44來連接水龍頭等之前端停止閥,或連接 其他管路’於其他管路末端來設置水龍頭等之前端停止闕 來使用。X,於稀釋混合單元5〇為排出内部液體,因雇必 要而連接排水管路35,並於該排水管路35前端設置手動 閉閥3 6。 在像這樣之裝置中’於儲槽22來健藏次氯酸納水溶液, 通過管路38來連接幫浦23。然後,藉控制部㈣動幫浦^, 通過管路39將相稱之原水流量送入於添加喷嘴21。又,儲 槽22經電動開關之開閉閥24藉由管路4〇連接添加噴嘴η, 以打開開閉闕24之狀態,藉由幫浦23運轉,依管㈣、幫 浦23、官路39、添加噴嘴21、管路4〇、開閉閥24之順序來 通水溶液’使能進行再次回到儲槽22之循 能將停滞於管路38、39和添加喷嘴21内之氣體送入儲槽 -15- 1224014 22,並能除去水溶液供應管路系之氣體。 同樣地關於鹽酸水溶液之供應,該鹽酸水溶液儲存於儲 槽27。然後,藉由管路41、42及幫浦28於鹽酸水溶液添加 喷嘴26來供應鹽酸水溶液。又’自動關閉之開閉閥29和管 路43連接於鹽酸水溶液添加喷嘴26和儲槽27之間,藉此來 構成回流管路。 接下來藉由圖2〜圖5來說明稀釋混合單元5〇之構成。稀釋 混合單元50係藉由圓筒狀之筒體5〇來構成其外殼,並於其 内部來配置管體3 1、32、33,於其上下具備有上側板狀體 5 1和下側板狀體52。此外,於上述上側板狀體5丨之下側重 豐地來設置辅助板53。於上側板狀體5丨設置原水供應口 % 和兩個添加喷嘴插入穴57、58。接著,原水分歧用輔助板 53係設置分歧從上侧板狀體51之原水供應口 %所供應之原 水之溝60和添加喷嘴插通口 6卜62,且於該辅助板”下面 特別是如圖3所示,來設置為保持管體31、32、33之位置而 挖成之凹部63、64、65。又,於下側板狀體52來設置為有 效混合各稀釋水溶液之導水用之溝67、為保持管體3ι、Μ 之位置之凹部68、69及通過排出管路44來排出所製造之殺 菌水之排出管插通孔70。 接著,邊參照圖4及圖5來詳細說明稀釋混合單元5〇。圖* 係表示所示於圖2之稀釋混合單元之縱向剖面圖,也圖示無 表示於圖2之添加喷嘴21、26。管體31、32、33係藉由下側 之板狀體52和輔助板53以上下被夾住之狀態來保持住,並 以外側筒體50包圍這些管體31、32、33’該外侧筒體“也 -16- 丄224014 藉由下板5 2和辅助板5 3從上下被夾住。又為防止向外部液 體之漏出,加裝一適當密封材質。 又於上側板狀體5 1和輔助板5 3之間也設置防漏液之密封 材質。此外,次氯酸鈉水溶液添加喷嘴2丨和鹽酸水溶液添 加嘴嘴26貫通上側板狀體51之添加喷嘴插入口 57、58及輔 助板53之添加喷嘴插入口 61、62,並插入管體31、32内。 各添加喷嘴2 1、26也設置防漏液之密封材質。在與排出所 製造之殺菌水之排出管路44連接之管體33之上部,來設置 殺菌水流入該管體33之通水口 79,然而於該管體33之下端 =置防漏液之密封材質。在此,也可於輔助板53之下面來 設置通水用之溝來替代於管體33來設置通水口 79。 接著,說明關於於圖4所示之添加喷嘴21、26。添加喷嘴 21係於内部有通路且其前端侧有於側開之噴射口 π。然後 於内部通路之前端部,藉由彈簧76施加於氣門座來$晉 圓錐狀之閥體75。㈤此在該添加噴嘴21之内部無大:彈笪1224014 Rose, description of the invention: [Technical field to which the invention belongs] The present invention relates to a device and method for producing sodium hypochlorite sterilizing water, a method for producing sterilizing water, and a method for producing g-killing water, and more particularly to a germicidal water containing hypochlorous: 夂 na The manufacturing device and manufacturing method are manufactured by adding a mixed aqueous solution of sodium hypophosgene and an acidic aqueous solution such as hydrochloric acid, sulfuric acid, and acetic acid to tap water and well water original X. [Previous technology] It is known that sodium hypochlorite (NaC10), hydrochloric acid (HC1), etc. can be added to raw water, and mixed with water can produce sodium hypochlorite (Hci ^ sterilizing water with strong bactericidal effect. But if sodium hypochlorite and hydrochloric acid react directly Chlorine gas (Ch) may be generated. Here, as described in Japanese Patent Application Laid-Open No. 11-1 88083 and New Japanese Patent No. 3058642, in order to ensure proper pH, adjust sodium hypochlorite and hydrochloric acid. The method and apparatus for adding and mixing are to be considered. 'Here, the outline of the previous apparatus will be described with reference to FIG. 14. Here again, an aqueous hydrochloric acid solution is used as an acidic aqueous solution. Then, in the apparatus shown in FIG. 14, first, After connecting the backflow prevention valve 1 2 1 to the raw water supply line 120, two downstream lines 123 and 124 are branched, and the backflow prevention valves 1 25 and 1 26 are connected to these lines 123 and 124. Then, The pipes 127 and 128 connected to the sodium hypochlorite aqueous solution adding nozzle 132 and the hydrochloric acid aqueous solution adding nozzle 137 are added from these adding nozzles 1 3 2, 1 3 7 in an appropriate amount to each of the sodium hypochlorite aqueous solution and hydrochloric acid aqueous solution. 127 and pipeline 128. Next, there are dilution stirring tanks 129 and 130 at the downstream thereof, and the added sodium hypochlorite aqueous solution and hydrochloric acid aqueous solution and the supplied raw water are thoroughly mixed. After that, the pipelines 145 and 146 merge and pass through the merge pipe The 1224014 channel 147 is introduced into the mixing and stirring tank 148, and the diluted aqueous solutions are fully mixed. At this time, 'to fully stir the mixing solution, if necessary, the body of the mixing and stirring tank 148 cannot be enlarged, and it is more important than the mixing and stirring tank. The buffer storage tank is connected to the downstream of 148. In the sterilizing water production device shown in FIG. 14, the raw water is generally supplied from the lower part in the vertical direction. For example, by closing the front stop valve connected to the downstream of the mixing and stirring tank 148 (not shown) ) To stop the supply of raw water, use the signal from the sensing device (not shown) that detects the raw water flow s to stop the pump. 34, 139 'Therefore, the addition of sodium hypogas solution and hydrochloric acid aqueous solution is also stopped. The addition of raw water is stopped only after the supply is stopped, so there is a slight delay in time compared with the stop of raw water. Therefore, the above is performed for raw water without flowing water. Addition of various aqueous solutions. Therefore, high-concentration sodium hypochlorite and hydrochloric acid aqueous solutions are retained near the addition nozzles 132 and 137 of the sodium hypochlorite aqueous solution and the hydrochloric acid aqueous solution. In this way, the retained sodium hypochlorous acid aqueous solution and hydrochloric acid are retained. Because the specific gravity of the aqueous solution is heavier than that of the raw water, it causes precipitation to diffuse with time and moves to the vicinity of the raw water supply port. Therefore, there is a concern that sodium hypochlorite reacts with hydrochloric acid to produce gas, so it is necessary to add nozzles 132, A blocking mechanism for backflow prevention valves 125, 126, etc. is provided directly below 137. Here, when such a sterilizing water production device is installed in a cold zone, in order to prevent the pipeline from being damaged due to freezing, it is necessary to prevent backflow. Drainage mechanisms are separately provided upstream and downstream of the valves 125 and 126. Therefore, not only the equipment is complicated and the price becomes high, but also the operation is complicated, which causes trouble. In the sterilizing water manufacturing device shown in FIG. 14, the above-mentioned adding nozzles ^ and 137 are provided with an open valve only when the pressure is higher than the set pressure, especially 1224014, which is a gasification gas of sodium hypogas solution. It is easy to stagnate inside the addition nozzle 32, and the gasification gas trapped inside the addition nozzle 132 keeps the stagnated state, and the bubbles will become large. Therefore, if it is discharged into the pipe 1 27 with air bubbles, the supply of the sodium hypochlorite aqueous solution may be temporarily reduced due to the problem of reducing the residual gas concentration and pH of the sterilizing water produced. As shown in Fig. 15 # "If the nozzles 32, i37 are more straight than the addition nozzles of the sodium hypochlorite aqueous solution and the hydrochloric acid aqueous solution, the mixing and stirring tank 148 for mixing the sodium hypochlorite aqueous solution and the hydrochloric acid aqueous solution is set, because The sodium hypooxygen produced by the mixing itself will precipitate and expand in the possibility of adding chlorine gas to the sodium hypoxia aqueous solution. Therefore, it is necessary to set a countercurrent to prevent the addition of the sodium hypochlorite aqueous solution, and near the hydrochloric acid aqueous solution with a low pH value of 1 2 Similarly, precipitation also occurs between the nozzle 132 and the mixing and stirring tank 148, which makes the problem more complicated. The device composed of pipelines as shown in Figs. 14 and 15 has a lot of space wasted and the entire device becomes large. In order to fully stir the mixing tank 148, it is necessary to increase the volume of the mixing tank 148 and In the case where a buffer tank is provided at the lower part of the mixing and stirring tank 148, there is a problem that a larger plasticization is caused. The purpose of the present invention is to provide a `` sterilizing water manufacturing apparatus and manufacturing method '', which does not require A lock mechanism like a backflow prevention valve is provided, which can miniaturize the entire device and fully drop in the mixing tank. [Summary of the invention] The main invention of this case is the self-liquid of the water supply pipeline and hydrochloric acid and sulfuric acid, which are related to an acidic aqueous solution making device such as acetic acid in raw water such as tap water or well water, which is added with hypochlorous Sodium acid is soluble in water to produce sterilizing water with a certain pH value of 1224014 and / or residual chlorine concentration. The killing and diluting mixing unit is connected to the above-mentioned sodium hypochlorite aqueous solution addition nozzle, Timriga nozzle, and discharges the manufactured sterilizing water. The discharge element is composed of a pipe formed by sealing the upper and lower cylinders with a plate-shaped body, the addition nozzle of the above-mentioned sodium hypogas solution, and the plate-shaped body on the upper side. The supplied raw water system is diluted by the mixing unit. The inside is divided into two or more channels, and is located at least in the nozzle of the sodium monochloride aqueous solution, and the nozzle of the residual acidic aqueous solution; the alkaline water that has been added to the diluted aqueous solution of the sodium hypochlorite aqueous solution is added to the acidic aqueous solution. The second combination unit of acidic water discharges and mixes the above-mentioned alkaline water and the above-mentioned acid tube body; The addition nozzle of the acidic aqueous solution is connected to the first pipe body and the second pipe body. The alkaline water and the acidic water discharged near the dilute body inside the dilution and mixing unit are provided with water passages or grooves. The sterilization manufactured near the upper plate of the third tube body and the early element is placed here. An auxiliary plate is placed on the upper side of the above-mentioned dilution and mixing unit. The auxiliary plate is formed to extend into the branch path through the upper plate. The water supply pipeline of the body_water manufacturing equipment is the above-mentioned acidic water pipeline; the dilute, the above-mentioned original mouth and the above-mentioned acid-based raw water are composed of a square channel in the channel, and at least the first tube body tube in the channel The body is connected with the sterilizing nozzle of the tap water to the second water inlet or the ditch release mixing unit, and is introduced into the water within the above. The raw water supply of the ditch in the horizontal direction on the inside of the plate-shaped body contains a water-supply aqueous solution and a water supply pipeline branch channel which is added with a solution and added and released single water to set the next combined body, and set and flow the diluted mixed water. The third one is the first tube body, and it is formed on the D-side plate-shaped third tube body, which is mixed with dilute mixtures or holes to form the mouth. It is better to supply raw water in the branch channel described above on -10- 1224014. It is also preferable to arrange the baffles in a plurality of stages in the cylinder constituting the dilution mixing unit. In addition, a fourth pipe body is provided outside the first pipe body through the gap of flowing test water, a fifth pipe body is provided outside the second pipe body through the gap of flowing acidic water, and a gap between the flow sterilizing water is provided in the above. A sixth pipe body is provided on the outside of the third pipe body, and a water opening or a water channel is arranged near the upper plate body on the fourth pipe body and the fifth pipe body, and is disposed on the sixth pipe body. Passage near the plate-like body on the lower side. In addition, at the same time, the respective aqueous solution supply pipes corresponding to the sodium hypochlorite aqueous solution addition nozzle and / or the acidic aqueous solution addition nozzle are also connected to each other separately. The other pipelines are located at the sodium hypochlorite aqueous solution addition. The nozzle and / or the acidic aqueous solution adding nozzle device in the dilution and mixing unit is preferably provided in a vertical direction above the aqueous solution supply pipeline. There is also an aqueous solution supply pipeline connected to the pump on the way, the pump transports-sodium chloride solution or acidic aqueous solution from each corresponding aqueous solution storage tank to each addition nozzle, and according to the above water / valley fluid supply pipeline and storage It is better to arrange the upstream part of the connection part of the groove, the above pump, and the above-mentioned spraying nozzle in the order of the downward direction. · 1 Aqueous solution supply line connected to pumps on the way, this pump sends sodium hypochlorite or acid solution from each pair of liquid storage tanks to each addition, and connects the on-off valve on the way to the corresponding nozzle. * Aqueous solution is reversed R π > between the return & pipeline, by opening the on-off valve of the above-mentioned return pipeline, the above is temporarily, occupied ~ It is better to drive the returned aqueous solution back to the storage tank. In addition, 酉 vine * _ / liquid storage tank and / or acidic aqueous solution storage tank has two or more pipelines to stand up to each other ° This pipeline connection part is elastically capable of applying -11-1224014 pressure by using an elastic mechanism If the valve body is connected with the valve body at the pipeline connecting portion, if the car is opened from the pipeline i " Qian Shao and the camp body is removed and blocked by the elastic mechanism, the total clearance of one side At the same time as the valve solution supply pipeline, other technical connections are preferably connected to the water flow pipeline. Connection 邛 Connection to the above The main invention of the manufacturing method is related to a sterilizing water which is added to the tap water or water flowing in the water supply pipe, sodium water solution and hydrochloric acid, sulfuric acid, vinegar, and the addition of hypochlorite ^ ττ 文The acidic aqueous solution of 4 is used to drop a sterilizing water with a pH value and / or residual chlorine content. The sterilizing water contains a -diluting mixing unit, which is connected with: water and gas to build a road, and the addition nozzle for adding the above sodium hypochlorite aqueous solution: "Addition nozzle of aqueous solution and discharge of sterilized ^ ," [驮: Γ combination unit system ... like body seal L of the second acid :: two lines, the above nozzle of sodium hypochlorite aqueous solution and the above ... bath The liquid addition nozzle is combined with the upper plate-shaped body, and the raw water supplied by the water ::: pipeline is divided into two or more channels by the = channel formed by the inside of the dilution mixing unit, and is located at least in the square channel. The addition of sodium hypochlorite solution is sprayed, and in the remaining passages, at least: the addition nozzle of the aqueous solution; the alkali that has been added to the sodium hypochlorite aqueous solution is set to flow in the second part of the dilution mixing unit. The first pipe of water f = the second pipe of the acidic water to which the above-mentioned acidic aqueous solution has flowed, and the second pipe of the diluted mixing unit discharging the alkaline water and the killing water of the acidic water; The addition nozzle of the sodium gas aqueous solution is connected to the first pipe body, and the addition nozzle of the acidic aqueous solution is connected to the -12 · 1224014 second pipe body, and in the upper ditch, it is arranged in the three pipe bodies near the thin lower plate body. The upper side of the water release mixing unit is here, and there are nozzles for the corresponding aqueous solution storage in the way, and according to the pump, the above-mentioned adding side part is better. The most suitable unit of the invention is used as the mouth and dilution mixture. In addition, the raw water supplier does not need to prevent the backflow even in the structure of the addition liquid and the acidic aqueous solution. The amount of chlorine gas in contact with the light aqueous solution is due to the chlorine I. In addition, the first tube body and the second tube are considered. Pipe body and the fifth pipe: the upper part of the cylinder of the unit / the first pipe body and the second pipe body are provided with water vents or the inside of the mixing unit is discharged into the above-mentioned diagnostic water and the above-mentioned acidic water in the diluted mixing unit, and The sterilizing water produced near the thin plate-like body is introduced into the third port or the groove. The pump is connected to an aqueous solution supply pipe of the pump, and the pump conveys an aqueous sodium hypochlorite solution or an acidic aqueous solution from the tank. A good upstream mode is set at the connection part of each of the above-mentioned aqueous solution supply pipelines and the storage tank, and the nozzle is added in the vertical direction. A dilution mixing unit is provided. The buffer tank of the sterilizing water produced by the dilution mixing is added in the body. The structure of the spray tank and the mixing and stirring tank, so that the miniaturization should be located near the front end of the nozzle in a more vertical direction than the front end of the added nozzle. Since the aqueous solution diffuses in the mixing and stirring tank, the structure almost does not produce chlorine gas, and even if the micro-L is generated and dissolved in the sterilizing water again, this problem does not occur. In the case of completeness, 4th and 5th tube bodies are set outside the body to which the diluent of each aqueous solution is added. By arranging the σ of the mixing and mixing tank for these bodies to constitute the dilution and mixing, the specific gravity and high The concentration of sodium hypochlorite in water is 13-1224014, and the acidic aqueous solution of horse concentration does not flow into the mixing and stirring tank, but the reaction of each aqueous solution can be stopped to generate chlorine gas. In order to remove the influence of the sodium hypochlorite gasification gas, the downstream side of the aqueous solution tank outlet, the pump, and the addition nozzle are set so that they are above the straight direction, and the addition direction of the addition nozzle is the vertical direction in the opposite direction. Make the pipeline that escapes the gasification gas, the pipeline electrically opens and closes the valve to connect each aqueous solution storage tank, remove the air entering the road during the storage tank exchange and the gasification gas generated in the supply pipeline after a long stop To open the on-off valve, the gas and the aqueous solution can be returned to the tank by the pump operation, so that the gas in the supply pipe and the addition nozzle can always be removed. In addition, although the concentration of each aqueous solution is not high, in order to avoid direct contact with the human skin, and to avoid mixing two aqueous solutions and thus gas due to erroneous splashing, each aqueous solution tank has two pipes connected below the storage tank. There is a valve body attached to the official road connecting part by a spring and an elastic body. Generally, the valve body of these road connecting parts is closed. When connecting the storage tank to the device, the above is made by installing the protruding part of the pipe side joint, etc. The spring and the elastic body are deformed to apply the valve body, and the pipeline connection portion is initially opened to form a structure in which the two pipelines of the storage tank, the aqueous solution supply pipe, and the return pipeline of the gas return pipeline to the storage tank are connected at the same time. Therefore, if the storage tank is removed from the outside of the device, the pipeline connection will be closed again, because there is no aqueous solution in the storage tank to be dialed out of the storage tank. [Embodiment] The present invention should be described below by using one of the illustrations. Figure 丨 is a block diagram showing the entire structure of the sterilizing water manufacturing apparatus according to the embodiment. Firstly, a raw water supply pipeline is provided for supplying water from the upper water channel, and the pipe is stored under the lead storage to trigger the production of the pipe in the pressure storage section. • 14-1224014 The water supply pipeline is connected to a pressure reducing valve.丨 丨. The pressure-reduced supply water passes through the solenoid valve 12 and the flowmeters 1 3 and 1 4 and passes through the constant flow valve 16 and is supplied to the dilution mixing unit through the backflow prevention valve 丨 7 50%. In the dilution mixing unit 50, the raw water supply line 10 is branched into two branching paths 60. The sodium hypochlorite aqueous solution addition nozzle 2 and the hydrochloric acid aqueous solution addition nozzle 26 are arranged in each branch path 60. After adding these aqueous solutions 21, 26 through the addition nozzles 21 and 26, the respective aqueous solutions and raw water are mixed in the dilution mixing tanks 31 and 32, and water is passed through the mixture. Inside the stirring tank 3 3. The sterilized water produced by the mixing is discharged out of the dilution mixing unit 50 through the discharge official path 44. In addition, connect the pH meter 34 to the discharge line ^, and drain it outside the device after checking the pH value of the sterilized water manufactured. 0 You can connect the front stop valve such as a faucet to the discharge line 44 or connect other lines Stop the other end of the pipe to set the faucet, etc. before using. X, in the dilution and mixing unit 50, for draining the internal liquid, a drain pipe 35 is connected as necessary, and a manual closing valve 36 is provided at the front end of the drain pipe 35. In such a device, the sodium hypochlorite aqueous solution is stored in the storage tank 22, and the pump 23 is connected through a pipe 38. Then, the control unit activates the pump ^, and sends a corresponding raw water flow rate to the adding nozzle 21 through the pipe 39. In addition, the storage tank 22 is connected to the additional nozzle η through the opening and closing valve 24 of the electric switch through the pipeline 40 to open and close the opening 阙 24, and operates by the pump 23, according to the pipe ㈣, pump 23, official road 39, Add the nozzle 21, the pipeline 40, and the opening and closing valve 24 in order to pass the aqueous solution. 'Enable the circulation to return to the storage tank 22 again. The gas stagnated in the pipelines 38 and 39 and the addition nozzle 21 can be sent to the storage tank- 15-1224014 22, and can remove the gas from the aqueous solution supply pipeline. Regarding the supply of an aqueous hydrochloric acid solution, the aqueous hydrochloric acid solution is stored in a storage tank 27 in the same manner. Then, the hydrochloric acid aqueous solution is supplied through the pipes 41, 42 and pump 28 to the hydrochloric acid aqueous solution adding nozzle 26. The auto-closing on-off valve 29 and the pipe 43 are connected between the hydrochloric acid aqueous solution addition nozzle 26 and the storage tank 27, thereby forming a return line. Next, the structure of the dilution mixing unit 50 will be described with reference to FIGS. 2 to 5. The dilution and mixing unit 50 is constituted by a cylindrical body 50, and a tube body 3 1, 32, 33 is arranged inside the body. An upper plate body 51 and a lower plate body are provided above and below the body.体 52。 Body 52. In addition, an auxiliary plate 53 is provided on the upper side of the upper-side plate-like body 5 and the lower side is provided abundantly. A raw water supply port% and two adding nozzles are inserted into the upper plate-shaped body 5 丨 and the insertion holes 57 and 58 are provided. Next, the raw water branching auxiliary plate 53 is provided with a raw water ditch 60 and an additional nozzle insertion port 62 and 62 which are branched from the raw water supply port% of the upper plate-shaped body 51, and is located below the auxiliary plate. As shown in Fig. 3, recesses 63, 64, and 65 dug to maintain the positions of the pipe bodies 31, 32, and 33 are provided. In addition, a groove for water conduction for effectively mixing the diluted aqueous solutions is provided in the lower plate-like body 52. 67. Recesses 68 and 69 for maintaining the positions of the tube body 3m and M and a discharge tube insertion hole 70 for discharging the sterilized water produced through the discharge pipe 44. Next, the dilution will be described in detail with reference to FIGS. 4 and 5. Mixing unit 50. The figure * is a longitudinal cross-sectional view of the dilution mixing unit shown in FIG. 2, and the addition nozzles 21 and 26 not shown in FIG. 2 are also shown. The tubes 31, 32, and 33 are shown on the lower side. The plate-shaped body 52 and the auxiliary plate 53 are held in a sandwiched state, and these tube bodies 31, 32, 33 are surrounded by an outer cylinder 50. The outer cylinder "also -16--224014 The plate 5 2 and the auxiliary plate 5 3 are sandwiched from above and below. To prevent leakage of liquid to the outside, a suitable sealing material is added. A leak-proof sealing material is also provided between the upper plate-like body 51 and the auxiliary plate 53. In addition, the sodium hypochlorite aqueous solution addition nozzle 2 and the hydrochloric acid aqueous solution addition nozzle 26 penetrate the addition nozzle insertion openings 57 and 58 of the upper plate-shaped body 51 and the addition nozzle insertion openings 61 and 62 of the auxiliary plate 53 and are inserted into the tube bodies 31 and 32. . Each additional nozzle 21, 26 is also provided with a leak-proof sealing material. The upper part of the pipe body 33 connected to the discharge pipe 44 for discharging the sterilizing water is provided with a water inlet 79 for the sterilizing water to flow into the pipe body 33. However, the lower end of the pipe body 33 is provided with a leak-proof seal Material. Here, instead of the pipe body 33, a water-passing port 79 may be provided below the auxiliary plate 53. Next, the addition nozzles 21 and 26 shown in FIG. 4 are demonstrated. The addition nozzle 21 has an injection port π with a passage in the inside and a side opening on the front end side. Then at the front end of the internal passage, a spring valve 76 is applied to the valve seat to conical valve body 75. ㈤There is not much inside the adding nozzle 21: impeachment

之力產生之限制了,為一從内部通路通過喷射 H 會噴出液體之構造。 並不 藉由如圖1所示之幫浦23,從儲槽2 溶液係通過管路38、39,而道^叮命出之久氣酸制水 、、吕路38、39,而導入添加喷嘴21内之 時,如圖1所示之自動閥24關閉時,因該喷嘴2ι内壓。此 升,使添加喷嘴21之閥體75對抗彈簧冗而使复開 之上 酸鈉水溶液係通過分歧通路6〇並添加到所供應之y次氯 邊與原水混合而向下方流動於管體3 1内。 ,、7中, 又於長時間停止殺菌水製造期間,在該添加喷 、用z 1之内 -17- 1224014 部所產生之氣化氣體會沿著管路40排出於上方,並不停滯 於構成次氯I納水溶液供應管路之該喷嘴2 1内部。即使有 停滯於管路40之氣化氣體,打開開閉閥24於循環運轉幫浦 23時,使其通過管路40並變成回到儲槽22之循環流,因此 氣化氣體流向儲槽22,於最終送入健槽22,故不影響次氯 酸鈉水溶液之添加量。又另一方之鹽酸水溶液添加噴嘴26 也有著相同之構造。 接著,由圖6來說明關於含有 ^ “ ,王取加 I % 21、26之供應管路及從添加喷嘴21、26回到健槽22、27之 回流管路之管路系統。又在此以添加喷嘴2丨部份為例子來 說明。於儲存次氣酸鈉水溶液之儲槽22之下部有一對連接 供應管路38及回流管路40之連接部,於供雁总物,〇 + 1 π仏應官路3 8連接幫 浦23,藉由運轉幫浦23從儲槽22吸上水溶液,並通過與路 38導入管路39。管路39係連接添加噴嘴21, 貝角错由幫浦23所 吸上之水溶液供應給添加喷嘴2 1。 此時,於鉛直方向上方依儲槽22之下部捸妞a 丨免硬部、幫浦23、 添加喷嘴2 1之順序朝向下游側來配置,並由 ^ 邱下到上來配置 官路38及39,途中於上方不形成凸狀山形。# 错此,使在營 路3 8、管路3 9及幫浦2 3所產生微小氣化氣濟 札瑕所凝聚之氣體 不易滯留。又即使有小凝聚之氣泡,氣泡备 u㈢错由因幫浦23 向水溶液添加喷嘴2 1供應運轉而被送至添加 1 % 2 1,並將 之送至設置於添加噴嘴2 1之鉛直方向朝上々 &路4 0。藉 此’添加於原水之水溶液量與幫浦2 3所送之息 了所製造殺菌水殘留氯氣濃度及pH值。 疋 -18 - 1224014 ^而,在儲槽22交換後和長時間停止運轉之情況下,進 入官路39之氣體和滯留氣化氣體不只會到達管路“内,也 有可能會到達添加喷嘴21之内部通路。因此,在交換儲槽 22和長時間停止運轉之後,自動打開開閉閥並運轉幫浦 23。藉此,水溶液由儲槽22通過管路38、幫浦23、管路39、 添加喷嘴21、管路40、開閉閥24,再流回儲槽22。因此,、 =健槽22通過幫浦23朝向添加喷嘴21之管路内氣體被總施 壓流動,並流向管路40或儲槽22内。藉此運轉,於水溶液 之供應管路氣化氣體不再滯留,&無對於水溶液之添加量 有不好之影響。 接著藉由圖7及圖8以儲槽22為例來詳細說明儲槽22、 27與^應管路38、41之連接部。於儲槽22之下部設置筒狀 連接邛82,藉由彈簧84施加於氣門座以於該連接部内設 置開關該連接部82之閥體83。上述彈簧84以被夾於藉由^ 住工具所支承之板與閥體8 3之間之狀態被壓縮著。此外, ^體83含有防漏液之密閉部材。對此,連接於管路w前端 部=接碩87具有突部88,於該突部88内亦設置防漏液之密 閉部材並於内部形成通路8 9。 接者,連接部82與接頭87之連接係藉於該裝置裝設儲槽 並藉由施壓儲槽22丁部之連接部82於接頭87之突部88 來T行藉由突部8 8相對地推開連接部8 2之閥體8 3,如圖8 八接。卩82之閥體83對抗彈簧84而向上方移動,為從氣 門座85離間,而使成為儲槽22與管路38連接之狀態。 對此,從裝置卸下儲槽22之情況下,如圖7所示向上方抬 -19- 起儲槽22的話,接頭87之突 菁Μ闕體83押住氣門座85,藉此;^體83分離,藉由彈 部。因此,儲槽22内之水溶液並储槽22下部之連接 況。i> u /並“、、漏出至儲槽22外部之情 况在本只轭狀態之殺菌水製造梦 下部有付各兩個之連接部82,2置中,於各儲槽22、27 ψ, m ^ . 而來連接對應各連接部82之 仏應e路38、41或回流管路40、43。 :著’藉由圖9來說明像這樣之殺菌水製造裝置控制部之 m使用之商用電源即10()v之電源係藉電源電路變 換至±5V、5V、24V之電壓’來供應各幫浦和cpu。cpu96 係通過接口 95㈣對應從檢測原水流量之兩個流量計Η、 14流量之信號。此時’如在兩個流量計13、i4出現規定以 上之差值時,判斷一對流量計13、14之至少一方有不適等 問題,在發出警報之同日夺’會一時封閉電磁閥12來切斷原 X之供應 '並中止叙Ij水之製造。從兩個流量計i 3、Μ發 出之4號差在無特別問題之情況下,從這些信號來計算原 水流量,基於流量與預先設定殘留氣濃度之情報,而計算 次氣酸鈉水溶液供應用幫浦2 3之迴轉數來運轉之。又同樣 地基於預先設定之pH值和次氯酸鈉水溶液之供應量,計算 鹽酸水溶液供應用幫浦2 8之迴轉數來運轉之。 又,於除去各水溶液供應管路系統之氣體時,經接口 95 押連接於CPU 96開閉閥94之對應釦,或藉由計時器依從 CPU 96來之指令來開放開閉閥24、29之同時,於一定時間 來運轉幫浦23或28,從各儲槽22、27經噴嘴21、26及這些 開閉閥24、29來產生再次回流至儲槽22、27之循環流,進 1224014 而進,管路38、39、4卜42内之氣體流回至儲槽22之運轉。 —又藉由開關控制板94來進行殘留氯氣濃度ipH值之設 定及運轉/停止之開關。又仲計34係連接於放大器叼之同 時放大器97係經A — 0轉換器98及比較器99連接於Cpu 96。因幫浦23、28之異常和管路阻塞等,pH值和已設定之 PH值也有相異的時候,故CPU 96會檢測出異常而發出警 鈴,因應必要封閉電磁閥12來中止殺菌水之製造。 1著藉由關於如以上構造之殺菌水製造裝置來說明殺菌 水製造過程之運轉。通過如圖丨所示之減壓閥u、電磁閥 2 0机里汁1 3、1 4、定流量閥1 6之原水,其係通過稀釋混 二單元5 0之上側板狀體5丨之原水供應口 5 6而流入該稀釋混 合單70 50之内部,其係藉由接合於上側板狀體5 1之下側所 配置辅助板53之溝60所分歧的。之後,通過添加次氣酸鈉 水/合液之添加喷嘴2丨及添加酸性水溶液之添加喷嘴2 6之内 部和周邊,從上方向下方通水至該稀釋混合單元5 〇内部之 管體31及32内。 對此’從儲槽2 2、2 7藉由幫浦2 3、2 8來吸取次氯酸納水 溶液及鹽酸水溶液,來供應至添加喷嘴21、26。此時,幫 浦23係基於藉由流量計13、14所測定之流量和所設定之殘 留氯氣濃度及pH值,適宜地來供應次氯酸鈉水溶液及鹽酸 水〉谷液。藉此’使所供應之原水與次氯酸鈉水溶液及鹽酸 水溶液混合,鹼性水由上方至下方流入管體3丨内,而酸性 水則由上方至下方流入管體32内。 在各官體3 1、3 2與下側板狀體5 2之接合部,導入流入稀 -21 - 1224014 釋混合單元5 0内之管體3丨、3 2之鹼性水和酸性水至該下側 板狀體52之上面所設之溝67,使之衝突邊互相混合而排出 於該稀釋混合單元之筒體50内。此時,從管體31及32向筒 體50内之驗性水和酸性水之排出,係不只在下側板狀體52 之上面所設之溝67排出,也可於管體3丨、32之下側設置通 水口從其排出。 於構成稀釋混合單元5〇之筒體50内排出之鹼性水和酸性 水係’邊於容量大之筒體5 〇内混合而邊向上方流動,從在 官體33之上部側辅助板53之附近來設置通水口 79來流入該 管體33内,邊從上方至下方來流動至該管體33内並邊混合 之’藉由排出管路44向該裝置外部排出。 藉由像這樣之殺菌水製造裝置之殺菌水製造,在適宜地 添加次氣酸鈉水溶液和鹽酸等之酸性水溶液來製造殺菌力 強之次氣酸鈉水溶液裝置中,藉由該簡單之構造能防止因 次氣酸納與鹽酸或次氯酸與鹽酸之接觸而產生氯氣,並能 兩全安全性和經濟性。 又儘管有由兼用緩衝槽之大筒體所構成之稀釋混合單元 5〇,也能使裝置小型化。且,由次氣酸鈉水溶液所產生之 氣化氣體,難滯留於同水溶液供應管路3 9和添加噴嘴2丨之 内部’即使萬一滯留也易排出該氣化氣體,藉此,並無對 水溶液之添加量有壞影響。因此,安定了所製造之殺菌水 之殘留氯濃度和pH值。又藉由於儲槽22、27之底部所設置 之連接部8 2,即使於交換次氯酸鈉水溶液之儲槽和酸性水 溶液之儲槽時,因人為失誤而潑灑出水溶液也無混合2液之 -22- 1224014 虞,使用上非常安全。 。該變形例係在構The force generated is limited by a structure in which a liquid is ejected by spraying H from an internal path. Instead of pump 23 as shown in Figure 1, the solution from storage tank 2 is passed through pipes 38 and 39, and the long-lasting acid gas produced by Ding Ming, Lu Road 38 and 39 is introduced and added. When the nozzle 21 is inside, when the automatic valve 24 shown in FIG. 1 is closed, the internal pressure of the nozzle is 2m. With this liter, the valve body 75 of the nozzle 21 is added against the slackness of the spring, and the reopened sodium aqueous solution passes through the branch path 60 and is added to the supplied y-th order chlorine edge and mixed with the raw water to flow downwardly through the pipe body 3. 1 within. In 7 and 7, during the long period of stopping the sterilization water production, the gasification gas generated in the -17- 1224014 portion of the addition spray and the use of z 1 will be discharged upward along the pipeline 40, and will not stagnate. The inside of the nozzle 21 constituting the hypochlorous sodium aqueous solution supply line. Even if there is gasification gas stagnated in the pipeline 40, when the on-off valve 24 is opened and the circulation pump 23 is opened, it passes through the pipeline 40 and becomes a circulating flow back to the storage tank 22. Therefore, the gasification gas flows to the storage tank 22, It is sent to the well 22 at the end, so it does not affect the amount of sodium hypochlorite aqueous solution added. The other hydrochloric acid aqueous solution addition nozzle 26 has the same structure. Next, the piping system containing the supply lines containing ^ ", Wang Toka plus I% 21, 26 and the return lines from the addition nozzles 21, 26 back to the wells 22, 27 will be described with reference to Fig. 6. Here again Take the part of adding nozzle 2 丨 as an example. There is a pair of connection parts connecting the supply line 38 and the return line 40 under the storage tank 22 storing the sodium hypogas solution, and the total supply for the wild goose, 0 + 1 π 仏 Yingguan Road 38 is connected to pump 23, and the pump 23 is operated to draw the aqueous solution from storage tank 22, and is introduced into pipe 39 through channel 38. Pipe 39 is connected to add nozzle 21, and the angle is wrong. The aqueous solution sucked by the pump 23 is supplied to the adding nozzle 21. At this time, in the vertical direction, the lower part of the storage tank 22 is placed on the bottom of the storage tank 22 丨 free hard part, pump 23, and the adding nozzle 21 are arranged toward the downstream side. , And arrange the official roads 38 and 39 from ^ Qiu down to the top, and do not form a convex mountain shape on the way. # Wrong this, so that the small gasification gas generated in Yinglu 3 8, pipeline 39 and pump 23 The condensed gas is not easy to stay. Even if there are small condensed air bubbles, the air bubbles are added by the pump 23 to the aqueous solution. Nozzle 2 1 is supplied to the adding 1% 2 1 during the supply operation, and it is sent to the installation nozzle 2 1 in a vertical direction facing upwards & road 40. By this, the amount of the aqueous solution added to the raw water and the pump 2 The information sent by 3 is the residual chlorine concentration and pH value of the sterilizing water produced. 疋 -18-1224014 ^ And, after the storage tank 22 is exchanged and the operation is stopped for a long time, the gas entering the official road 39 and the remaining gasification. The gas may not only reach the inside of the pipe “, but may also reach the internal passage of the addition nozzle 21. Therefore, after the storage tank 22 is replaced and the operation is stopped for a long time, the on-off valve is automatically opened and the pump 23 is operated. Thereby, the aqueous solution flows back from the storage tank 22 to the storage tank 22 through the pipeline 38, the pump 23, the pipeline 39, the addition nozzle 21, the pipeline 40, and the on-off valve 24. Therefore, the gas from the healthy tank 22 through the pump 23 toward the adding nozzle 21 is always pressurized and flows into the pipeline 40 or the storage tank 22. By this operation, the gasification gas in the supply line of the aqueous solution is no longer retained, and there is no adverse effect on the amount of the aqueous solution added. 7 and FIG. 8 are used to describe the storage tank 22 as an example to describe the connection between the storage tanks 22 and 27 and the application pipelines 38 and 41 in detail. A cylindrical connection cymbal 82 is provided at the lower portion of the storage tank 22, and a spring 84 is applied to the valve seat to provide a valve body 83 for opening and closing the connection portion 82 in the connection portion. The spring 84 is compressed in a state of being sandwiched between a plate supported by the holding tool and the valve body 83. In addition, the body 83 contains a liquid-tight sealing member. To this end, the front end of the pipe w = the connection 87 has a protrusion 88, and a leak-proof sealing member is also provided in the protrusion 88, and a passage 89 is formed inside. Then, the connection between the connecting portion 82 and the joint 87 is achieved by installing a storage tank in the device and pressing the connecting portion 82 of the storage tank 22 to the protrusion 88 of the joint 87 to make the T through the protrusion 8 8 The valve body 8 3 of the connecting portion 82 is relatively opened, as shown in FIG. 8. The valve body 83 of 卩 82 moves upward against the spring 84, and is separated from the valve seat 85, so that the storage tank 22 and the pipeline 38 are connected. In this regard, in the case of removing the storage tank 22 from the device, as shown in FIG. 7, if the storage tank 22 is lifted upwards -19-, the protrusion 87 of the joint 87 holds the valve seat 85, and thereby ^ The body 83 is separated by a spring portion. Therefore, the aqueous solution in the storage tank 22 is connected to the lower part of the storage tank 22. i > u / ", leaking to the outside of the storage tank 22 In the yoke state of the sterilizing water production dream, there are two connection parts 82, 2 in the middle, and each storage tank 22, 27 ψ, m ^. To connect the corresponding channels 38 and 41 or the return lines 40 and 43 corresponding to the respective connecting portions 82: "The commercial use of m in the control unit of such a sterilizing water manufacturing device like this will be described with reference to Fig. 9" The power source is 10 () v power supply, which is converted to ± 5V, 5V, 24V voltage by the power supply circuit to supply each pump and cpu. Cpu96 is connected to two flowmeters for detecting raw water flow through interface 95, and 14 flow At this time, 'If it is judged that at least one of the pair of flow meters 13 and 14 is uncomfortable when the difference between the two flow meters 13 and i4 exceeds the prescribed value, the solenoid valve will be closed on the same day when the alarm is issued. 12 to cut off the supply of the original X 'and suspend the production of Ij water. The difference of No. 4 from the two flow meters i 3 and M is calculated from these signals without special problems. Based on the flow and Set the information of the residual gas concentration in advance and calculate the supply The number of revolutions of 2 to 3 is operated. Similarly, based on the preset pH value and the supply amount of sodium hypochlorite aqueous solution, the number of revolutions of pump 28 for hydrochloric acid aqueous solution operation is calculated. Also, each of the aqueous solution supply lines is removed. When gas is in the system, it is connected to the corresponding buckle of the on / off valve 94 of the CPU 96 via the interface 95, or to open and close the on / off valves 24 and 29 by the timer according to the instructions from the CPU 96. 28. From each of the storage tanks 22 and 27 through the nozzles 21 and 26 and these on-off valves 24 and 29 to generate a circulating flow that returns to the storage tanks 22 and 27 again, and enter 1224014, and enter the pipelines 38, 39, 4 and 42. The gas flows back to the operation of the storage tank 22. -The switch control panel 94 is used to set the residual chlorine concentration ipH value and the switch of operation / stop. The 34 is connected to the amplifier and the 97 is connected to the amplifier. A — 0 converter 98 and comparator 99 are connected to CPU 96. Due to the abnormality of pumps 23 and 28 and blocked pipelines, when the pH value and the set PH value are also different, the CPU 96 will detect the abnormality When an alarm is issued, the solenoid valve 12 is closed as necessary. Discontinued the production of sterilizing water. 1 Explain the operation of the sterilizing water manufacturing process by using the sterilizing water manufacturing device configured as above. Through the pressure reducing valve u and the solenoid valve 20 shown in Figure 丨, the machine juice 1 3, 14. The raw water of the constant flow valve 16 flows through the raw water supply port 56 of the plate 5 5 on the upper side of the second mixing unit 50 and flows into the inside of the diluted mixing unit 70 50. The upper plate-shaped body 51 is divided by the groove 60 of the auxiliary plate 53 disposed on the lower side. After that, the internal nozzles of the addition nozzle 2 and the addition of the acidic aqueous solution are added through the addition nozzle 2 of the sodium hypothionite / water solution. At the periphery, water is passed from the top to the bottom and into the tubes 31 and 32 inside the dilution mixing unit 50. In response to this, the sodium hypochlorite aqueous solution and the hydrochloric acid aqueous solution are sucked from the storage tanks 2 2, 2 7 through the pumps 2 3, 2 8 and supplied to the addition nozzles 21, 26. At this time, the pump 23 is suitable to supply a sodium hypochlorite aqueous solution and hydrochloric acid water> valley based on the flow rate measured by the flow meters 13, 14 and the set residual chlorine gas concentration and pH value. In this way, the supplied raw water is mixed with an aqueous solution of sodium hypochlorite and an aqueous solution of hydrochloric acid, and alkaline water flows into the pipe body 3 from top to bottom, and acidic water flows into the pipe body 32 from top to bottom. At the joints between the official bodies 3 1, 3 2 and the lower plate-like body 5 2, the alkaline water and acidic water flowing into the tubes 3 3 and 3 2 in the dilute -21-1224014 release mixing unit 50 0 are introduced to the The grooves 67 provided on the upper surface of the lower plate-shaped body 52 are mixed with each other and discharged into the cylinder 50 of the dilution mixing unit. At this time, the drainage of the experimental water and the acidic water from the tubes 31 and 32 into the cylinder 50 is not only discharged through the groove 67 provided on the upper side of the lower plate-shaped body 52, but also in the tubes 3, 32. The lower side is provided with a water outlet to discharge therefrom. The alkaline water and acidic water system discharged in the cylinder 50 constituting the dilution mixing unit 50 flows upward while mixing in the large-capacity cylinder 50, and flows from the side auxiliary plate 53 above the official body 33. A water inlet 79 is provided in the vicinity to flow into the pipe body 33, while flowing into the pipe body 33 from above to below and mixed while being discharged to the outside of the device through the discharge pipe 44. The sterilizing water produced by such a sterilizing water producing device is suitably added to an acidic aqueous solution such as sodium hypoxia aqueous solution and hydrochloric acid to produce a sodium oxygenate aqueous solution device having strong sterilizing power. With this simple structure, It can prevent the chlorine gas from being generated by the contact between sodium hypochlorite and hydrochloric acid or hypochlorous acid and hydrochloric acid, and can have both safety and economy. In addition, despite the presence of a dilution mixing unit 50 composed of a large cylinder that also serves as a buffer tank, the device can be miniaturized. In addition, the gasification gas generated by the sodium hypogas solution is difficult to stay inside the same aqueous solution supply pipe 39 and the addition nozzle 2 ′, and the gasification gas is easily discharged even if it stays, so there is no Has a bad effect on the amount of aqueous solution added. Therefore, the residual chlorine concentration and pH of the sterilizing water produced are stabilized. And because of the connection part 8 2 provided at the bottom of the storage tanks 22 and 27, even when the storage tank of the sodium hypochlorite aqueous solution and the storage tank of the acidic aqueous solution are exchanged, the aqueous solution is not mixed due to human error. 1224014, very safe to use. . This modification is in the structure

接著,藉由圖10及圖11來說明變形例 成稀釋混合單元之筒體50内,並於管體 間部份上下地配置3枚擋板1〇3。在 接著藉由圖1 2及圖1 3來說明變形例。該變形例係有防止 因於原水供應停止時,次氯酸鈉水溶液與鹽酸水溶液之擴 散沉澱而混合之特徵。即,其係於管體3丨、32之外側設置 管體109、11〇内部之同時,將下側板狀體52之溝67做成滯 留於管體109、110之大小,或無設溝67,取而代之於管體 31、32下部附近設置穴112,通過管體31、32之鹼性水及酸 性水係由下方向上方通過管體1〇9、11〇内,並導入於這些 管體109、11〇之上部所設置穴114、115或於輔助板53下面 所設置之溝,排出於稀釋混合單元50内而混合之構造。 該情況下,藉由於停止原水後少許延遲,來停止次氣酸 鈉水溶液和鹽酸水溶液之添加,即使滯留於添加噴嘴2 1、 26附近之濃度高水溶液沉澱擴散,其會滯留於管體109、11〇 之下部附近,並不相互接觸,可更完全來抑制氯氣之產生。 此外’如圖12所示,為了更充分於混合攪拌槽來混合殺菌 -23- 1224014 水,在管體33之外側設置管體lu於同心圓狀,藉由於該管 體111下部附近設置通水口 i丨6,並藉由混合攪拌槽50内之 殺菌水從上述通水口 116進入管體U1而混合,且混合水由 下方向上方流入外侧官體i丨丨内,通過穴79並藉由流入内侧 管體3 3,來更促進混合。 【發明效果】 本案之主要發明係一種殺菌水製造裝置,其係在流動於 給水e路之自來水或井水等原水中添加次氯酸鈉水溶液和 鹽酸、硫酸、醋酸等之酸性水溶液,來製造一定pH值及/ 或殘留氯濃度之殺菌水’其中該殺菌水製造裝置含有一稀 釋混合單元,其係連接供應原水之供水管路、添加上述次 氯酸納水溶液之添加喷冑、添加上㉛酸性^容液之添加喷 嘴及排出已製^殺菌水之排出管路者;該稀釋混合單元 係由以板狀體封住上下之筒體所所構成,上述原水之供水 管路、上述次氣酸納水溶液之添加喷嘴和上述酸性水溶液 之添加喷嘴與上側之板狀體結合,由μ、広, ° 口 田上述原水之供水管路 所供應之原水係由稀釋混合單元内側所娃> 、 w W構成之分歧通路來 被分歧2個以上之通路,且至少位於一 乃通路内配置上述次 氯酸鈉水溶液之添加喷嘴,而於殘餘通路内至小 ^ 酸性水溶液之添加喷嘴;在構成上述稀盤、日 师榨此合早元之筒體 内,設置流動已添加次氯酸鈉水溶液之 晚性水之第一瞢 體、流動已添加上述酸性水溶液之酸性k '^弟二管體,夺 從該稀釋混合單元排出混合上述驗性水知μ° 上建酸性水$ & 菌水之第三管體;上述次氯酸鈉水溶液夕、;1 <杈 之添加噴嘴連接於 -24- x^4〇i4 述第-管體,上述酸性水溶液之添加喷嘴連接於上 :管體,且於上述第-管體及上述第二管體設置通水 溝’其係於上述稀釋混合單元内部排放在上述稀釋、、a 元下側板狀體附近之上述驗性水及上述酸性水者,: 述第三管體設置通水口或溝,農在 — ^ 異係在邊苐二管體内引 上述稀釋混合單元上側板狀體 版附近所製造之殺菌水者 因此根據像這樣之殺菌水製造 衣绝叔置及殺菌水製造方 P使設置由有充分容量之筒體 N暇所構成之稀釋混合單元 可小型化地來構成全體大小之 糾< > # — 丨』k 即使滯留於添加 附近之南》辰度次氣酸鈉水溶液 尤4坡η広,μ 和酉夂Γ生水洛液沉澱擴散 不會擴及原水供應管路,藉此Next, referring to Figs. 10 and 11, the inside of the cylinder 50 which is a dilution and mixing unit according to a modified example will be described, and three baffles 103 will be arranged up and down in the portion between the tubes. Next, a modification will be described with reference to FIGS. 12 and 13. This modification has a feature of preventing the sodium hypochlorite aqueous solution and the hydrochloric acid aqueous solution from being mixed and dispersed due to the precipitation of raw water when the supply of water is stopped. In other words, the grooves 67 of the lower plate-shaped body 52 are made to stay in the pipes 109 and 110 while the pipes 109 and 110 are provided outside the pipes 3 and 32, or no grooves 67 are provided. Instead, a cavity 112 is provided near the lower part of the tubes 31 and 32. The alkaline water and acidic water passing through the tubes 31 and 32 pass from the bottom to the inside of the tubes 1109 and 110 and are introduced into the tubes 109. A structure in which holes 114 and 115 provided on the upper part of the upper part 10 or grooves provided on the lower part of the auxiliary plate 53 are discharged into the dilution mixing unit 50 and mixed. In this case, due to the slight delay after stopping the raw water, the addition of the sodium hypogas solution and the hydrochloric acid aqueous solution is stopped. Even if the concentrated high-aqueous solution precipitates and diffuses near the addition nozzles 21 and 26, it will stay in the pipe body 109, In the vicinity of the lower part, it is not in contact with each other, and the generation of chlorine gas can be suppressed more completely. In addition, as shown in FIG. 12, in order to mix the sterilizing water 23-1224014 more fully in the mixing and stirring tank, a pipe body lu is provided in a concentric circle shape on the outside of the pipe body 33, and a water opening is provided near the lower part of the pipe body 111 i 丨 6, and the sterilizing water in the mixing and stirring tank 50 enters the pipe body U1 from the above-mentioned water port 116 to be mixed, and the mixed water flows into the outer body i 丨 丨 from above and below, passes through the hole 79 and flows in The inner tube body 3 3 to further promote mixing. [Effects of the invention] The main invention of this case is a sterilizing water manufacturing device, which is to add a sodium hypochlorite aqueous solution and an acidic aqueous solution such as hydrochloric acid, sulfuric acid, and acetic acid to raw water such as tap water or well water flowing in the feedwater e to produce a certain pH value. And / or sterilizing water with residual chlorine concentration, wherein the sterilizing water manufacturing device includes a dilution and mixing unit, which is connected to a water supply pipeline for supplying raw water, adding a spray of adding the above sodium hypochlorite aqueous solution, and adding acidity. The liquid adding nozzle and the discharge pipeline for discharging the sterilized water; the dilution mixing unit is composed of a plate-shaped body sealing the upper and lower cylinders, the above-mentioned water supply pipeline, and the above-mentioned secondary acid sodium aqueous solution The addition nozzle of the above-mentioned acidic aqueous solution is combined with the plate-shaped body on the upper side, and the raw water supplied by the above-mentioned raw water water supply line of Kota is the raw water of the dilution mixing unit. The branching path is divided into two or more paths, and at least one of the paths is configured with the above-mentioned sodium hypochlorite aqueous solution addition nozzle, and the residual In the remaining passage, a nozzle for adding an acidic aqueous solution; the first carcass of the late water to which the sodium hypochlorite aqueous solution has been added is set in the cylinder constituting the above-mentioned thin plate, and the cylinder that the Japanese teacher squeezes this early element, and the flow has been added to the above The second tube body of the acidic aqueous solution of the acidic aqueous solution is drained from the dilution mixing unit to mix the above-mentioned test water μ ° The third tube of the acid water $ & bacterial water; the above sodium hypochlorite aqueous solution; 1 <; The addition nozzle of the branch is connected to the--body of the -24- x ^ 4〇i4, and the addition nozzle of the above acidic aqueous solution is connected to the upper body: the body, and water is provided in the-body and the second body. The ditch 'is the inside of the above-mentioned dilution mixing unit, which discharges the above-mentioned test water and the above-mentioned acidic water near the above-mentioned diluted, a-shaped plate-shaped body, and the third pipe body is provided with a water outlet or a ditch, and the farmer is in-^ If the sterilizing water produced near the upper plate of the dilution mixing unit is introduced into the two tubes of the side, the sterilizing water manufacturing clothes such as the sterilizing water manufacturing method and the sterilizing water manufacturing method should be set to have sufficient capacity. Cylinder N leisure place The diluted mixing unit can be miniaturized to make up the entire size. ≪ ># — 丨 』k Even if it stays in the vicinity of the addition of the south, the aqueous solution of sodium hypochlorous acid, especially η 広, μ and 酉 夂 Γ The sedimentation and diffusion of raw water solution will not extend to the raw water supply pipeline, thereby

Jr ^ ^ ^ ^ ^ 务優越樂液混合防止效 月b防止氣化氣體產生之同時, 了 無須逆流防止闕,# 七、構造簡潔低價之殺菌水製造裝置。 【圖式簡單說明】 圖1係殺菌水製造裝置全體構成之區段圖。 圖2係稀釋混合單元之分解斜視圖。 圖3係辅助板之縱向剖面圖。 圖4係稀釋混合單元之縱向剖面圖。 圖5係圖4之A-A線剖面圖。 圖6係儲槽與添加噴嘴連接之配管圖。 圖7係儲槽與供應管之路連接部之縱向剖面圖。 圖8係同接連狀態之縱向剖面圖。 囷 圖9係構成控制部之區段圖。 圖10係變形例中稀釋混合單 卞%之縱向剖面圖。 述第 口或 合單 於上 進在 〇 法, ,也 噴嘴 ,也 果, 可提 -25- 1224014 圖11係用於同裝置之擋板之外觀斜視圖。 圖1 2係別的變形例中稀釋混合單元之縱向剖面圖。 圖13係於圖12之B-B線剖面圖。 圖14以先前殺菌水製造裝置之配管圖。 圖1 5係先前之別的殺菌水製造裝置之配管圖。 【圖式代表符號說明】 10 原 水 供 應 管 路 11 減 壓 閥 12 電 磁 閥 13、14 流 .量 計 15 控 制 部 16 定 流 量 閥 17 逆 流 防 止 閥 21 次 氯 酸 納 添 加 喷 嘴 22 次 氯 酸 鈉 水 溶 液 儲 槽 23 幫 浦 24 開 閉 閥 26 鹽 酸 水 溶 液 添 加 喷 嘴 27 鹽 酸 水 溶 液 儲 槽 28 幫 浦 29 開 閉 閥 31 次 氯 酸 納 水 溶 液 稀 释 攪 拌槽(管體) 32 鹽 酸 水 溶 液 稀 釋 攪 拌 槽 (管體) 33 混 合 攪 拌 槽 (管體)Jr ^ ^ ^ ^ ^ It can prevent the generation of gasification gas while preventing the generation of gasification gas. At the same time, there is no need to prevent backflow. #VII. Simple and low-cost sterilizing water manufacturing device. [Brief Description of the Drawings] FIG. 1 is a block diagram of the overall structure of a sterilizing water manufacturing device. Fig. 2 is an exploded perspective view of a dilution mixing unit. Fig. 3 is a longitudinal sectional view of an auxiliary plate. Fig. 4 is a longitudinal sectional view of a dilution mixing unit. Fig. 5 is a sectional view taken along the line A-A in Fig. 4. Fig. 6 is a piping diagram of the connection between the storage tank and the addition nozzle. Fig. 7 is a longitudinal sectional view of a connecting portion between a storage tank and a supply pipe; Fig. 8 is a longitudinal sectional view of the connected state.囷 Figure 9 is a block diagram of the control unit. Fig. 10 is a longitudinal cross-sectional view of a diluted mixed monomer 卞% in a modification. The said mouth or combination is advanced in the 0 method, and also the nozzle, and if you can, you can mention -25- 1224014 Figure 11 is a perspective view of the appearance of the baffle for the same device. Fig. 12 is a longitudinal sectional view of a dilution mixing unit in another modification. Fig. 13 is a sectional view taken along the line B-B in Fig. 12. FIG. 14 is a piping diagram of a conventional sterilizing water production apparatus. Fig. 15 is a piping diagram of another conventional sterilizing water production device. [Illustration of representative symbols] 10 Raw water supply line 11 Pressure reducing valve 12 Solenoid valve 13 and 14 Flow meter 15 Control unit 16 Constant flow valve 17 Backflow prevention valve 21 Sodium hypochlorite addition nozzle 22 Sodium hypochlorite aqueous solution storage tank 23 Pump 24 On-off valve 26 Hydrochloric acid solution addition nozzle 27 Hydrochloric acid solution storage tank 28 Pump 29 On-off valve 31 Sodium hypochlorite solution dilution stirring tank (tube body) 32 Hydrochloric acid solution dilution stirring tank (tube body) 33 Mixing stirring tank (tube body)

-26- 1224014 34 pH計 35 排 水 管 路 36 手 動 閥 38 管 路 39 供 應 管 路 40 回 流 管 路 41 管 路 42 供 應 管 路 43 回 流 管 路 44 排 出 管 路 50 稀 釋 混 合 單 元 (筒體) 51 上 側 板 狀 體 52 下 側 板 狀 體 53 輔 助 板 56 原 水 供 應 D 57 '58 添 加 喷 嘴 插 入 D 60 溝 61 '62 添 加 噴 嘴 插 通 Π 63, -65 凹 部 67 溝 68 ^ 69 凹 部 70 排 出 管 路 插 通 孔 75 閥 體 76 彈 簧-26- 1224014 34 pH meter 35 drain line 36 manual valve 38 line 39 supply line 40 return line 41 line 42 supply line 43 return line 44 discharge line 50 dilution mixing unit (cylinder) 51 on Side plate-like body 52 Lower side plate-like body 53 Auxiliary plate 56 Raw water supply D 57 '58 Add nozzle insert D 60 groove 61 '62 Add nozzle insert Π 63, -65 Concave portion 67 Groove 68 ^ 69 Concave portion 70 Discharge pipe insertion hole 75 Valve body 76 Spring

-27- 1224014 77 喷 射 α 79 通 水 D 82 連 接 部 83 閥 體 84 彈 簧 85 氣 門 座 87 接 頭 88 突 部 89 通 路 93 電 源 電 路 94 開 關 控 制板 95 接 π 96 CPU 97 放 大 器 98 A_ 變換器 99 比 較 器 100 接 α 103 擋 板 104 桿 105 通 水 孔 106 凹 陷 部 109〜1 11 管 體 112〜1 16 通 水 π 120 原水供應管 1224014 121 逆 流 防 止 閥 123、 124 管 路 125、 126 逆 流 防 止 閥 127、 128 管 路 129 - 130 稀 釋 攪 拌 槽 132 次 氯 酸 鈉 水 溶 液 添 加喷嘴 133 供 應 管 路 134 幫 浦 135 儲 槽 137 鹽 酸 水 溶 液 添 加 喷 嘴 138 供 應 管 路 139 幫 浦 140 儲 槽 145、 146 管 路 147 合 流 管 路 148 混 合 攪 拌 槽 149 殺 菌 水 排 出 管 150 逆 流 防 止 閥-27- 1224014 77 Jet α 79 Water passing D 82 Connection 83 Valve body 84 Spring 85 Valve seat 87 Connector 88 Protrusion 89 Path 93 Power circuit 94 Switch control board 95 to π 96 CPU 97 Amplifier 98 A_ Inverter 99 Comparator 100 connected to α 103 baffle 104 rod 105 through hole 106 recessed portion 109 ~ 1 11 pipe body 112 ~ 1 16 through water pi 120 raw water supply pipe 1224014 121 backflow prevention valve 123, 124 pipeline 125, 126 backflow prevention valve 127, 128 Lines 129-130 Dilution mixing tank 132 Sodium hypochlorite solution addition nozzle 133 Supply line 134 Pump 135 Storage tank 137 Hydrochloric acid solution addition nozzle 138 Supply line 139 Pump 140 Storage tank 145, 146 Line 147 Confluence line 148 Mixing Stirring tank 149 Sterile water discharge pipe 150 Backflow prevention valve

Claims (1)

拾、申請專利範園: 種T菌水製造裝置,其係在流動於給水管路之自來水或 t K =原水中,添加次氣酸鈉水溶液和鹽酸、硫酸、醋酸 =之酸性水溶液,來製造特定PH值及/或殘留氣濃度之殺 函水’其特徵在於: 含有一稀釋混合單元,其係連接供應上述原水之供水管 路、添加上述次氯酸鈉水溶液之添加喷嘴、添加上述酸性 水溶液之添加噴嘴及排出製造成之殺菌水之排出管路者; 該稀釋混合單元係由以板狀體封住上下《筒體所構I 噔述原良之供水官路、上述次氯酸鈉水溶液之添加噴 嘴和上述酸性水溶液之添加喷嘴與上侧之板狀體結合,由 述原水之供水官路所供應之原水係由稀釋混合單元内 2所構成之分歧通路來被分歧成2個以上之通路,且以至 於# it路内t方式配置上述次氯酸鈉纟溶液之添 加噴嘴,而於殘餘通路内至 — + V 個結合酸性水溶液之添加 幫嘴; 在構成上述稀釋混合單开夕@ μ & 跡 、 口早兀之旖體内,設置使已添加次氣 酉久鈉水溶液之鹼性水流過之第一 ^ 官體、使已添加上述酸性 水溶液之酸性水流過之第-技触 , 、 弟一官體,和從該稀釋混合單元排 出混合上述驗性水和上述酿从y 择 ^ ^性水之殺菌水之第三管體; 上述次氯酸納水溶液之、夭& + 從之添加贺嘴連接於上述第一管 體,上述酸性水溶液之添加喑 卜 M 連接於上述第二管體,且 於上述第^官體及上述第-其粞上 4弟一 &體在上述稀釋混合單元下 側板狀體附近設置通水口哎滏,甘及〜k〇 4 ^,其係於上述稀釋混合單元 内部排放上述鹼性水及上诚缺^ , 上攻g夂性水者,並於上述第三管體 1224014 在上述稀釋混合單元上側板狀體附近設置通水口或溝,其 係在該第三管體内引進所製造之殺菌水者。 2.如申請專利範圍第1項之殺菌水製造裝置,其中於上述稀 釋混合單元上側之板狀體内側重疊地配置輔助板,藉於該 辅助板所形成橫方向延伸之溝或穴來構成上述分歧通. 路,經上述上側板狀體之原水供應口,於上述分歧通路供 « 應原水。 3·如申請專利範圍第1項之殺菌水製造裝置,其中在構成上· 述稀釋混合單元之筒體内上下複數段地來配列擋板。 4 ·如申請專利範圍第1項之殺菌水製造裝置,其中介隔以流 過鹼性水之隙間在上述第一管體外側設置第四管體,介隔 以流過酸性水之隙間在上述第二管體外側設置第五管 體,介隔以流過殺菌水之隙間在上述第三管體外側設置第 六管體,於上述第四管體及上述第五管體來設置於上側板 狀體附近之通水口或通水溝,並在上述第六管體來設置於 下側板狀體附近之通水口或通水溝。 5 ·如申請專利範圍第1項之殺菌水製造裝置,其中對應上述馨 次氣酸鈉水溶液添加喷嘴及/或上述酸性水溶液添加喷嘴 分別連接水溶液供應管路且又各別連接別的管路,該別的 管路位於較上述次氯酸納水溶液添加噴嘴及/或酸性水溶 液添加噴嘴安裝於稀釋混合單元時所對應之水溶液供應 管路,更鉛直方向上方。 6·如申請專利範圍第5項之殺菌水製造裝置,其中具有於途 中連接有幫浦之水溶液供應管路,該幫浦從各對應水溶液 ==次氯酸納水溶液或酸性水溶w各添 =述水溶液供應管路與儲槽之連接部、上述幫浦上: +加噴嘴之順序於鉛直方向 上述 κ . ^ ^ + β又置上私側部份。 專利範圍第5項之殺菌水製造裝置,其 連接幫浦之水溶液供應管路,誃% 有仫中 ^ >ν ^ ^ μ繁庸從各對應水溶液儲槽 适-人氣自文鈉水溶液或酸性& 中洁扭 改水,谷液於各添加噴嘴,及於途 連接開閉閥並連接於對岸 、 述暂法„ 乩口机目路之上述開閉閥,以上 达幫浦將所送出之水溶液回流至儲槽。 如申請專利範圍第5項之殺菌水 水湓饬抑祕η ,上 国& I仏裝置,其中次氯酸鈉 4^合液儲槽及/或酸性水 路遠垃却4 — 合液儲槽分別具有兩個以上之管 關駚 ^ 卩/、備错弹性機構彈性地被施壓之 闕體,當上述管路連拯卹& 而卷 ^卩連接於管路,上述閥體會開啟, 而田從上述管路連接部告势 性機構來封鎖,一方之技政/路的話,上述闊體由上述彈 答% &路連接部連接於上述水溶液供應 9. B路’而其他方之營敗 _絲& # 路連接部連接於上述回流管路。 種殺i水製造方法,复 ( 永榮κ, ,、係在流經給水管路之自來水或井1 寻原水中添加次氣酿 酸祕 > 〜 鼠8欠鋼水溶液和鹽酸、硫酸、醋酸等之 水,甘处/ ^特疋ΡΗ值及/或殘留氣濃度之殺菌 具特徵在於:梯田 气紙从 使用一種殺菌水製造裝置, 5亥軏囷水製造裝詈人 诚;&有一稀釋混合單元,其連接供應上 迷原水之供水管路、六a l * 十 嗜、、長丄 4、加上述次氯酸鈉水溶液之添加喷 角添加上述酸性水、、六 水夕μ山— ’合液之添加噴嘴及排出製造成之殺菌 、辨出管路; 該稀釋混合單开& I、, . 疋係由以板狀體封住上下之筒體所構 ,上述原水之供水管路、上述次氯酸鈉水溶液之添加噴 和上述酸性水溶液之添加噴嘴與上側之板狀體結合,由 上述原水之供水管路所供應之原水係由稀釋混合單元内 Z所構成之分歧通路來被分歧成2個以上之通路,且以至 少位於一方通路内之方式配置上述次氯酸鈉水溶液之添· 加噴嘴,而於殘餘通路内至少一個結合酸性水溶液添加 嘴; I 、〜在構成稀釋混合單元之筒體,設置使已添加次氣酸鈉水鲁 岭液之鹼性水流過之第一管體、使已添加上述酸性水溶液 之酸性水流過之第二管體,和從該稀釋混合單元排出混合 上述驗性水和上述酸性水之殺菌水之第三管體·, 上述次氣酸鈉水溶液之添加噴嘴連接於上述第一管 體,上述酸性水溶液之添加喷嘴連接於上述第二管體,且 於上述第一管體及上述第二管體在上述稀釋混合單元下 側板狀體附近設置通水口或溝,其係於上述稀釋混合單元 内部排放上述鹼性水及上述酸性水者,並於上述第:管體# 在上述稀釋混合單元上侧板狀體附近設置通水口或溝,其 係在該第二管體内引進所製造之殺菌水者。 * 如申請專利範圍第9項之殺菌水製造方法, . /、τ舟有於途 中連接有幫浦之水溶液供應管路,該幫浦從各對應水溶液 儲槽輸送次氣酸鈉水溶液或酸性水溶液於各添加噴嘴^ 2 依上述水溶液供應管路與儲槽之連接部、上述幫浦、、厂 添加喷嘴之順序於鉛直方向下方來設置上游側部份。上述 10Pick up and apply for patent Fan Yuan: A kind of T bacteria water production device, which is manufactured by adding tap water or t K = raw water flowing in the water supply pipe, adding sodium hypoxia solution and hydrochloric acid, sulfuric acid, acetic acid = acidic aqueous solution to manufacture The killing water with specific pH value and / or residual gas concentration is characterized by containing a dilution mixing unit which is connected to a water supply pipeline for supplying the raw water, an addition nozzle for adding the above sodium hypochlorite aqueous solution, and an addition nozzle for adding the above-mentioned acidic aqueous solution. And the discharge line for the sterilized water produced; the dilution and mixing unit is a plate-shaped body that seals the upper and lower sides of the cylinder body I, said the original water supply official road, the above-mentioned sodium hypochlorite aqueous solution addition nozzle, and the above-mentioned acidic aqueous solution The addition nozzle is combined with the upper plate-shaped body, and the raw water supplied by the water supply official road of the raw water is divided into two or more channels by the diluent mixing unit in the diluent mixing unit, so that # it In the way of the road, the nozzle for adding the above sodium hypochlorite and yttrium solution is configured, and in the residual path, up to + + V combined with an acidic aqueous solution is added. Help the mouth; In the body that constitutes the above-mentioned dilution and mixing single Kaixi @ μ & snails and mouths, set the first ^ body that allows the alkaline water that has been added with the secondary gas sodium persulfate solution to flow, and add the The third technical body through which the acidic water of the above-mentioned acidic aqueous solution flows, the third body, and the third tube discharged from the dilution and mixing unit to mix the above-mentioned test water and the above-mentioned sterilizing water from the selective water; The above-mentioned sodium hypochlorite aqueous solution, 夭 & + is added to the first pipe body, and the acidic aqueous solution is added to the second pipe body. The first-its upper 4th brother & body is provided with a water outlet near the plate-like body on the lower side of the above-mentioned dilution and mixing unit. Hey, Gan and ~ k0 ^, it is the inside of the above-mentioned dilution and mixing unit that discharges the above-mentioned alkaline water and water. Sincerely ^, the person who attacked g water, and set a water passage or groove near the upper plate of the above-mentioned dilution mixing unit 1224014, which is a sterilization manufactured by introducing the third pipe body Waterman. 2. The sterilizing water manufacturing device according to item 1 of the scope of patent application, wherein an auxiliary plate is arranged on the inside of the plate-shaped body on the upper side of the dilution mixing unit, and the above-mentioned groove or hole formed by the auxiliary plate extends in the horizontal direction to constitute the above. Bifurcation. Road, through the raw water supply port of the upper plate, supplies raw water to the bifurcation path. 3. The sterilizing water manufacturing device according to item 1 of the patent application scope, wherein the baffles are arranged in a plurality of sections in the cylinder body constituting the dilution mixing unit. 4 · The sterilizing water manufacturing device according to item 1 of the patent application scope, wherein a fourth pipe body is provided on the outside of the first pipe body through a gap flowing through alkaline water, and a gap between the gap through which acid water flows A fifth pipe body is provided on the outside of the second pipe body, and a sixth pipe body is provided on the outside of the third pipe body through a gap through which sterilizing water flows, and the fourth pipe body and the fifth pipe body are provided on the upper side plate A water opening or a water channel near the shape body, and a water outlet or a water channel located near the lower plate-shaped body in the sixth pipe body. 5 · If the sterilizing water production device according to item 1 of the scope of patent application, wherein the nozzle for adding the sodium nitrite solution and / or the nozzle for adding the acidic aqueous solution are respectively connected to the aqueous solution supply pipeline and are connected to other pipelines, This other pipeline is located above the vertical direction of the aqueous solution supply pipeline corresponding to the above-mentioned sodium hypochlorite aqueous solution addition nozzle and / or acidic aqueous solution addition nozzle installed in the dilution mixing unit. 6. If the sterilizing water manufacturing device of item 5 of the patent application scope has an aqueous solution supply pipeline connected to a pump in the middle, the pump is added from each corresponding aqueous solution == sodium hypochlorite aqueous solution or acidic water solution = The connection between the aqueous solution supply pipe and the storage tank, and the above pump: + The order of adding the nozzle is in the vertical direction to the above κ. ^ ^ + Β is placed on the private side. The sterilizing water production device of the fifth item in the patent scope, which is connected to the aqueous solution supply pipeline of the pump, is 誃% 仫 ^ > ν ^ ^ μ from the corresponding aqueous solution storage tanks-popular sodium aqueous solution or acid & Zhongjie twisted the water, added the liquid to each nozzle, and connected the on-off valve on the way to the opposite bank. The above-mentioned on-off valve of the 乩 口 机 目 路 mentioned above, the above pump will return the aqueous solution sent back. To the storage tank. For example, the sterilizing water and water sterilization inhibitor of Item 5 of the scope of the patent application, Shangguo & I 仏 device, in which sodium hypochlorite 4 ^ liquid storage tank and / or acidic waterway far waste 4-liquid storage The tanks have two or more pipes, respectively. 卩 卩 /, and the body with the wrong elastic mechanism is elastically pressurized. When the above pipeline is connected to the pipeline and the ^ 卩 is connected to the pipeline, the valve body will open. And Tian from the above-mentioned pipeline connection section to the potential agencies to block, if one party's technology / road, the above wide body is connected by the above-mentioned popping% & road connection section to the above-mentioned aqueous solution supply 9. Road B 'and other parties Defeat_ 丝 &# The road junction is connected to the This is the return line. A method for manufacturing i-killing water, compound (Yong Rong κ, ,, is added to the tap water or wells through the water supply line, adding secondary gas fermentation acid secrets to the original water > ~ rat 8 The sterilization tools for water such as hydrochloric acid, sulfuric acid, acetic acid, etc. are characterized by the use of a sterilizing water manufacturing device for terraced gas paper. ; &Amp; There is a dilution mixing unit, which is connected to the water supply pipeline that supplies the original raw water, six al * ten add, long 丄 4, add the above-mentioned sodium hypochlorite aqueous solution, add the above-mentioned acidic water, and Liushuixi μ mountain — 'The added liquid nozzle and the sterilization and identification pipeline produced by the discharge; The diluted mixing single opening & I ,,... Is composed of a plate-shaped body sealing the upper and lower cylinders, and the above-mentioned raw water supply pipe Road, the above-mentioned sodium hypochlorite aqueous solution addition spray and the above-mentioned acidic aqueous solution addition nozzle are combined with the upper plate-shaped body, and the raw water supplied by the raw water supply pipeline is a branching path formed by the dilution in the mixing unit Z It is divided into two or more channels, and the above-mentioned sodium hypochlorite aqueous solution addition / addition nozzle is arranged in at least one of the channels, and at least one of the acidic aqueous solution addition nozzles is combined in the residual channel; I, ~ The cylinder is provided with a first tube through which the alkaline water to which sodium hypophosphite hydroluline has been added, and a second tube through which the acidic water to which the above-mentioned acidic aqueous solution has been added, is discharged and mixed from the dilution and mixing unit. The third pipe body of the test water and the sterilizing water of the acidic water, the nozzle for adding the sodium hypoxia aqueous solution is connected to the first pipe body, and the nozzle for adding the acidic aqueous solution is connected to the second pipe body, and A water opening or a groove is provided near the first pipe body and the second pipe body near the lower plate-like body of the dilution mixing unit, which discharges the alkaline water and the acidic water inside the dilution mixing unit, and第: 管 体 # A water opening or a groove is provided near the upper plate-shaped body of the above-mentioned dilution and mixing unit, and it is manufactured by introducing into the second pipe body Water sterilization by. * For the method of producing sterilizing water according to item 9 of the scope of patent application, ./, τ boat is connected with an aqueous solution supply line of pumps on the way, and the pumps deliver sodium hypoxia or aqueous acid solutions from the corresponding aqueous solution storage tanks. At each addition nozzle ^ 2 the upstream side portion is set in the vertical direction below the order of the connection portion of the aqueous solution supply pipe and the storage tank, the above pump, and the factory addition nozzle. Above 10
TW091133830A 2001-11-30 2002-11-20 Device and method for producing sterilized water TWI224014B (en)

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JP2009101282A (en) * 2007-10-22 2009-05-14 Masakazu Uzawa Apparatus of manufacturing high-concentration mixed solution for sterilization
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CN113713645A (en) * 2021-09-09 2021-11-30 宁波铧洲科技有限公司 Machine for producing high-concentration hypochlorous acid water

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