TWI223377B - Method for isolating the active area of a memory cell with partial vertical channel - Google Patents
Method for isolating the active area of a memory cell with partial vertical channel Download PDFInfo
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【發明所屬之技術領域】 本發明係有關一種隔離元件的製造方法,特別係有關 於種隔離具有垂直電晶體(vertical transistor)以及 /朱溝槽電容(deep trench capacitor)之主動區的方法。 【先前技術】 在積體電路晶片上製作高密度植入之半導體元件時, 必須考慮如何縮小每一個記憶單元的大小與電力消耗,以 使其操作速度加快。在傳統的平面電晶體設計中,為了獲 得一個最小尺寸之記憶單元,必須盡量將電晶體的閘極長 度細短’以減少δ己憶早元的橫向面積。但是,這會使閘極 無法忍受較大的漏電流而必須相對應地降低位元線上的電 壓’進而使得電容所儲存的電荷減少,所以在縮短閘極的 橫向長度同時,還要考量如何製作一個具有較大電容量之 電容,例如:增加電容之面積、減少電容板之間的有效介 質厚度等等。由於在實際製作上無法同時滿足減少記憶單 元面積且增加電容面積的條件,也無法進一步縮小有效介 質的厚度,因此目前發展出一種垂直電晶體(vertical t r a n s i s t 〇 r)結構,可以將閘極長度維持在一個可得到低 漏電流的的適當值,不但不會減小位元線電壓,也不會增 加記憶單元的橫向面積。此外,還發展出一種深溝槽電容 (deep trench capacitor),是直接設置於垂直電晶體下 方,不會佔用記憶單元的額外面積。 在美國專利第6, 034, 389中揭示一種具有深溝槽電容[Technical field to which the invention belongs] The present invention relates to a method for manufacturing an isolation element, and more particularly, to a method for isolating an active region having a vertical transistor and a deep trench capacitor. [Previous Technology] When fabricating high-density implanted semiconductor components on integrated circuit wafers, it is necessary to consider how to reduce the size and power consumption of each memory cell in order to speed up its operation speed. In the traditional planar transistor design, in order to obtain a memory cell of the smallest size, the gate length of the transistor must be made as short as possible 'to reduce the lateral area of the delta element. However, this will make the gate unable to tolerate a large leakage current and must correspondingly reduce the voltage on the bit line, thereby reducing the charge stored in the capacitor. Therefore, while reducing the lateral length of the gate, it is also necessary to consider how to make a Capacitors with large capacitance, such as: increasing the area of the capacitor, reducing the effective dielectric thickness between the capacitor plates, and so on. Since the conditions for reducing the memory cell area and increasing the capacitor area cannot be met in actual production, and the thickness of the effective medium cannot be further reduced, a vertical transistor structure has been developed to maintain the gate length. At an appropriate value for obtaining a low leakage current, not only the bit line voltage is not reduced, nor the lateral area of the memory cell is increased. In addition, a deep trench capacitor has also been developed, which is placed directly below the vertical transistor without occupying an additional area of the memory cell. A deep trench capacitor is disclosed in U.S. Patent No. 6,034,389
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之自行對準式擴散源極垂直電晶體。 請參考第la-le圖,第la —le圖係顯示習知之具 垂直通道之電晶體之切面示意圖。 習知製作方法是於一P型矽基底1〇1上形成複數個深溝 槽104以及相對應凸出之柱形區1〇2,使深溝槽1〇4隔離每 二個柱形區102。如第la圖所示,柱形區1〇2表面上設有一 薄墊氧化物層103a以及一氮氧化物層103b,是用來定義柱 形區102區域。首先於深溝槽丨〇4下方區域的側壁上形成一 重度,雜氧化物1〇5(如砷玻璃ASG)作為源極擴散材料,然 後於鬲溫下進行短時間的退火製程,使砷擴散至柱形區 102側壁而形成一n型重摻雜(n+)擴散區1〇6,用來作為一# 源極區1 06以及後續製作之深溝槽電容的儲存電極。隨後 如圖1 b所示,將重度摻雜氧化物1 〇 5去除。 然後’如第1 c圖所示’在深溝槽1 〇 4内側壁上生長一 ΟΝΟ薄膜1〇7,作為深溝槽電容的介質。接著於深溝槽1〇4 内沈積一 η+多晶矽層1 〇 8,作為溝槽電容的電容板1 〇 8,並 將0Ν0薄膜107以及η+多晶矽層1〇8蝕刻至一預定深度。跟 著,如第Id圖所示,於深溝槽104内之η+多晶矽層1〇8上覆 盍一障蔽氧化層1 0 9,以便將後續製作之閘極隔離。隨後 ,於深溝槽104内之側壁上生長一閘極氧化物丨丨〇,再於深 溝槽1 0 4内填滿一 n+多晶石夕層111 ,作為一控制閘極111。然 後,如第1 e圖所示,蝕刻閘極111以便隔離各字線,再將 薄墊氧化物層103a以及氮氧化物層l〇3b去除之後,於每一 個柱形區1 0 2頂端植入一 n+汲極區11 2。最後形成一與字線Self-aligned diffused source vertical transistor. Please refer to the la-le diagram. The la-le diagram is a schematic cross-sectional view of a conventional transistor with a vertical channel. A conventional manufacturing method is to form a plurality of deep trenches 104 and corresponding protruding columnar regions 102 on a P-type silicon substrate 101, so that the deep trenches 104 isolate every two columnar regions 102. As shown in FIG. 1a, a thin pad oxide layer 103a and an oxynitride layer 103b are provided on the surface of the columnar region 102 to define the region of the columnar region 102. First, a heavy layer is formed on the sidewall of the area below the deep trench, and a dopant oxide 105 (such as arsenic glass ASG) is used as a source diffusion material, and then a short-time annealing process is performed at high temperature to diffuse arsenic An n-type heavily doped (n +) diffusion region 106 is formed on the sidewall of the columnar region 102, and is used as a #source region 106 and a storage electrode of a deep trench capacitor to be manufactured later. Subsequently, as shown in FIG. 1 b, the heavily doped oxide 105 is removed. Then, as shown in FIG. 1c, a 100N thin film 107 is grown on the inner sidewall of the deep trench 104 as a medium for the deep trench capacitor. Next, an η + polycrystalline silicon layer 108 is deposited in the deep trench 104 as the capacitor plate 108 of the trench capacitor, and the ONO film 107 and the η + polycrystalline silicon layer 108 are etched to a predetermined depth. Then, as shown in FIG. Id, the n + polycrystalline silicon layer 10 in the deep trench 104 is covered with a barrier oxide layer 10 9 so as to isolate the gates made later. Subsequently, a gate oxide is grown on the sidewall in the deep trench 104, and an n + polycrystalline silicon layer 111 is filled in the deep trench 104 as a control gate 111. Then, as shown in FIG. 1e, the gate electrode 111 is etched to isolate the word lines, and the thin pad oxide layer 103a and the oxynitride layer 103b are removed, and then planted at the top of each pillar region 102. Into an n + drain region 11 2. Finally form an AND word line
1223377 五、發明說明(3) 垂直之位兀線金屬層11 3,便製作完成記憶單元陣列。 由上述可知,在每一個記憶單元中,控制閘極n〗、n+ 源極區106以及#汲極區112構成一垂直電晶體,而位於垂 直電晶體下方之n+擴散區1〇6、0N0薄膜1〇7以及n+多晶矽層 108則構成深溝槽電容。在一個開放位元線(〇pen bitline)的架構中,所有的記憶單元共用 多晶石夕電容板1〇8,電荷係儲存在每一個柱形區二二 擴散區1G6。_然柱形區1()2頂部可以用來作為n+源極區 以及n+汲極區112之間的通道,但是為了避免柱形區1〇2内 側壁上兩相鄰之源極區1〇6產生空乏區 region)過份接近而重疊的情形,柱形區1〇2的 隔錐之F Μ π ♦々I再縮 再加上將柱形區1 02有效 隔離之隔離&之見度,將使單位 密度降低。 積卜」沿烕之圮憶早7L 【發明内容】 有鑑於此,本發明夕a Μ + 、畜、蓄々θ ® - 月之目的在於棱供隔離具有部分Φ亩 通道吕己十思單70之主勤斤沾士 巧口丨刀至置 王動的方法,適用於動能隨 單元,有效隔離每一主動區。、用趴動心炚機存取記憶 根據上述目的,太旅 、蓄々Ρ 4 1 本么明&供一種隔離具有部八千古、基 運圮憶早70之主動區的士 i A, Θ外分垂直通 工取/ (he的方法,包括下列步 體基底,半導體美麻勺人士 卜到乂驟·棱供一半導 土 _匕g有一深溝槽,深道:描 有一深溝槽電容,且深、1 ^ φ h 木溝槽内分別形成 使深溝槽間成為一突出# ^ 、以丰^體基底表面, 大出柱狀之主動區;對露出表面之主動1223377 V. Description of the invention (3) The vertical bit line metal layer 11 3 will complete the memory cell array. It can be known from the above that in each memory cell, the control gate n, the n + source region 106, and the #drain region 112 constitute a vertical transistor, and the n + diffusion regions 106 and 0N0 films located below the vertical transistor. 107 and the n + polycrystalline silicon layer 108 constitute a deep trench capacitor. In an open bitline architecture, all memory cells share a polycrystalline silicon capacitor plate 108, and charges are stored in each columnar region 22 diffusion region 1G6. The top of the columnar region 1 () 2 can be used as a channel between the n + source region and the n + drain region 112, but in order to avoid two adjacent source regions 1 on the inner sidewall of the columnar region 102. 6 produces empty regions (regions) are too close and overlapping, the F π of the septum cone of the cylindrical region 102 is reduced, plus the isolation & visibility that effectively isolates the cylindrical region 102 Will reduce the unit density. "Jibu" along the ridge of the remembrance 7L [Content of the invention] In view of this, the purpose of the present invention is a Μ +, animal, storage θ ®-month is for the purpose of isolation for some Φ acre channels Lu Ji Shi Si 70 The method of the main service is to apply the knife to the king, which is suitable for kinetic energy with the unit, and effectively isolates each active area. 2. Use memory to access the memory. According to the above purpose, Tailu, 々Ρ 4 4 1 Benmemin & For a kind of taxi i A, Θ with active area of 8000 and 7000, The method of external division and vertical work / (he) includes the following steps. The semiconductor chip can be used for half the soil. The deep groove has a deep groove, and the deep groove has a deep groove. 1 ^ φ h wooden grooves are formed in the wooden grooves so that the deep grooves become a protrusion # ^, the surface of the base of the body is large, and the columnar active area is large;
1223377 五、發明說明(4) 區之底部角 以作為一源 層及一導電 落進行 汲極區 層,導 離子植入 ;於主動 基底上形成一介電層,介電 以隔絕另一 根據上 通道記憶單 導體基底, 成有一深溝 ;於每_深 内填滿一罩 圖案化罩幕 表面;以第 導體基底至 區;去除第 動區進行離 源汲極區; 電層及一第 應主動區及 刻罩幕,餘 罩幕層;及 直閘極之頂 根據上 通道記憶單 主動區 述目的 元之主 半導體 槽電容 溝槽電 幕層; 層,其 一圖案 低於隔 一圖案 子植入 於半導 一圖案 罩幕層 刻導電 於半導 部等高 述目的 元之主 ^驟以形成一離子摻雜區’用 面上依序形成-閘極介電 作為—垂直閘極;及於半導體 層與垂直閘極之頂部等高,用 ,本發明 動區的方 基底包含 ,且深溝 容表面上 於深溝槽 中第一圖 化罩幕層 絕層之高 化罩幕層 步驟以形 體基底上 化罩幕層 之部分區 層以形成 體基底上 ,用以隔 ,本發明 動區的方 再提供一種隔 法,包括下列 有一深溝槽, 槽電容低於該 形成一隔絕層 間之半導體基 案化罩幕層覆 及罩幕層為餘 度,以形成一 及罩幕層;對 成一離子摻雜 依序形成一閘 ,第二 域;以 一垂直 形成一 系巴另^一 另提供 法,包 圖案化 第二圖 閘極; 介電層 主動區 離具有部分垂直 步驟:提供一半 深溝槽内分別形 半導體基底表面 ;於每一深溝槽 底上形成一第一 盍罩幕層之部分 刻罩幕’钱刻半 突出柱狀之主動 隔絕層側邊之主 區,用以作為一 極介電層、一導 罩幕層之位置對 案化罩幕層為餘 去除第二圖案化 ’且介電層與垂 一種隔離具有部分垂直 括下列步驟:提供一半1223377 V. Description of the invention (4) The bottom corner of the area is used as a source layer and a conductive layer for the drain region layer and ion implantation; a dielectric layer is formed on the active substrate to dielectrically isolate the other ground. The channel memory single conductor substrate is formed with a deep trench; a patterned mask surface is filled within each depth; the conductor substrate to the area; the movable area is removed to remove the source drain region; the electrical layer and a first active Area and engraved masks, the remaining mask layers; and the top gate of the straight gate according to the main channel memory single active area described in the main semiconductor trench capacitor trench electrical curtain layer; a layer whose pattern is lower than the spaced apart pattern The semiconductor layer is engraved on the semiconductor layer with a patterned mask layer, which is electrically conductive on the semiconductor layer and other high-order elements to form an ion-doped region. The surface is sequentially formed with gate dielectric as vertical gate. The semiconductor layer is at the same height as the top of the vertical gate, and the square substrate of the moving region of the present invention includes a step of increasing the height of the mask layer of the first patterned mask layer in the deep trench on the surface of the deep trench. The part of the mask layer on the substrate The partition layer is formed on the body substrate for isolation, and the movable region of the present invention further provides an isolation method, which includes the following: a deep trench having a trench capacitance lower than that of the semiconductor-based masking layer covering and covering forming an isolation layer; The curtain layer is left to form a mask layer; a gate and a second domain are sequentially formed by doping an ion dopant; a method of forming a series of gates is provided in a vertical direction, and a second pattern gate is provided, including patterning the second gate. The active region of the dielectric layer has a partial vertical step: providing a semi-deep trench in the shape of the semiconductor substrate surface; forming a part of the mask on the bottom of each deep trench. The main area on the side of the active insulation layer is used as a polar dielectric layer and a conductive mask layer. The second pattern is removed from the mask layer and the dielectric layer is separated from the vertical layer. Partially verticalize the following steps: provide half
1223377 五、發明說明(5) 導體基底,半導體基底包含有二深溝槽;於每一深溝槽内 形成一深溝槽電容,深溝槽電容低於半導體基底表面,其 中每一深溝槽之頂部側壁上形成有一環狀絕緣層;於每一 深溝槽電容表面上形成一隔絕層;於每一深溝槽内填滿一 罩幕層;於深溝槽間之半導體基底上形成一第一圖案化罩 幕層,其中第一圖案化罩幕層覆蓋罩幕層之部分表面;以 第一圖案化罩幕層及罩幕層為蝕刻罩幕,蝕刻半導體基底 至低於隔絕層之高度;去除第一圖案化罩幕層及罩幕層, 其中深溝槽電容間之突出柱狀之半導體基底即為一主動區 ;於主動區外之半導體基底上順應性形成一犧牲層;於犧 牲層上形成一第一介電層;依序平坦化第一介電層及犧牲 層至露出主動區之表面,且第一介電層及犧牲層之高度低 於主動區頂部表面一既定距離;以第一介電層及犧牲層為 罩幕蝕刻主動區,以使主動區之頂部角落圓化;去除第一 介電層;對隔絕層側邊之主動區進行離子植入步驟以形成 一離子摻雜區,用以作為一源汲極區;去除犧牲層;對半 導體基底上進行氧化步驟以形成一閘極介電層;於半導體 基底上順應性形成一導電層;於導電層上形成一第二圖案 化罩幕層,第二圖案化罩幕層覆蓋對應主動區及罩幕層之 導電層之部分區域;以第二圖案化罩幕層為蝕刻罩幕,蝕 刻導電層以形成一垂直閘極;去除第二圖案化罩幕層;及 於半導體基底上形成一第二介電層,對第二介電層進行平 坦化步驟至露出垂直閘極以形成一隔離區,隔離區用以隔 絕另一主動區。1223377 V. Description of the invention (5) A conductive substrate, a semiconductor substrate including two deep trenches; a deep trench capacitor is formed in each deep trench, and the deep trench capacitance is lower than the surface of the semiconductor substrate, wherein the top sidewall of each deep trench is formed A ring-shaped insulating layer; forming an isolation layer on the surface of each deep trench capacitor; filling a cover layer in each deep trench; forming a first patterned cover layer on a semiconductor substrate between the deep trenches, The first patterned mask layer covers a part of the surface of the mask layer; using the first patterned mask layer and the mask layer as an etching mask, the semiconductor substrate is etched to a height lower than the isolation layer; the first patterned mask is removed Curtain layer and cover curtain layer, in which the protruding columnar semiconductor substrate between deep trench capacitors is an active area; a sacrificial layer is conformably formed on the semiconductor substrate outside the active area; a first dielectric is formed on the sacrificial layer Layer; sequentially planarize the first dielectric layer and the sacrificial layer to the surface exposing the active region, and the height of the first dielectric layer and the sacrificial layer is lower than a predetermined distance from the top surface of the active region; The sacrificial layer and the sacrificial layer etch the active region to round the top corner of the active region; remove the first dielectric layer; perform an ion implantation step on the active region on the side of the isolation layer to form an ion-doped region for As a source drain region; removing the sacrificial layer; performing an oxidation step on the semiconductor substrate to form a gate dielectric layer; compliantly forming a conductive layer on the semiconductor substrate; forming a second patterned mask on the conductive layer Layer, the second patterned mask layer covers a portion of the conductive layer corresponding to the active area and the mask layer; using the second patterned mask layer as an etching mask, the conductive layer is etched to form a vertical gate; removing the second Patterning the mask layer; and forming a second dielectric layer on the semiconductor substrate, performing a planarization step on the second dielectric layer until the vertical gate is exposed to form an isolation region, which is used to isolate another active region.
0548-9650twF(nl) ; 91299 ; Claire.ptd 第9頁 12233770548-9650twF (nl); 91299; Claire.ptd page 9 1223377
為使本發明之上述和其他目 顯易t董,下文特舉—較佳 細說明如下: 的、特徵、和優點能更明 ,並配合所附圖式,作詳In order to make the above and other objects of the present invention easier, the following is enumerated—preferably described as follows: The features, characteristics, and advantages can be made clearer, and will be described in detail with the accompanying drawings.
【實施方式】 請參考第2a-21圖,楚9 〇1 有部分垂直通道記憶單元之a=圖係顯示本發明之隔離具 請參考第2a圖,首先,提之切面示意圖。 體基底2〇1上形成有—塾声2、—=導體基底201 ’半導 ’且半導體基底201包含有 一冰溝槽201a,此二深溝槽2〇1&彼此間相距一 此既定距離間之半導體基底即為後續定義之主動區,因 此’此既定距離可根據需要來決定,例如是12〇〇至14〇〇 A。其中,塾層202例如是墊氧化〇xide)層或墊氮化 (pad nitride) >f 〇 於該深溝槽2 01 a中帛入- $電層以作為一 $溝槽電容 203,深溝槽電容2〇3的高度低於半導體基底2〇1之表面, 深溝槽電容203的高度可以根據需要來決定,深溝枰 203與半導體基底201表面間之距離可決定後續形成之閘極 之垂直通道長度。其中,每一深溝槽2〇la之頂部側壁上形 成有一領型(collar)的環狀絕緣層2〇4,用以與後續ι可繼[Embodiment] Please refer to Figs. 2a-21, Chu 9 〇1 a part of a vertical channel memory unit a = diagram showing the isolator of the present invention Please refer to Fig. 2a, first, a schematic cross-sectional view. A body substrate 201 is formed with —sounds 2, — = conductor substrate 201 'semiconducting' and the semiconductor substrate 201 includes an ice trench 201a. The two deep trenches 201 are separated from each other by a predetermined distance. The semiconductor substrate is the active area defined later, so 'this predetermined distance can be determined as needed, such as 12,000 to 1400A. Wherein, the hafnium layer 202 is, for example, a pad oxide layer or a pad nitride > f. In the deep trench 2 01a, a-$ electric layer is used as a $ trench capacitor 203, a deep trench. The height of the capacitor 203 is lower than the surface of the semiconductor substrate 201. The height of the deep trench capacitor 203 can be determined as needed. The distance between the deep trench 203 and the surface of the semiconductor substrate 201 can determine the length of the vertical channel of the subsequently formed gate. . Among them, a collar-shaped ring-shaped insulating layer 204 is formed on the top side wall of each deep trench 20a, which can be used to continue with subsequent ones.
續形成之閘極作為隔絕之用。其中,導電層例如是多晶石夕 層;環狀絕緣層2 0 4例如是氧化層。 M 請參考第2b圖,接著,於半導體基底2〇1、深溝槽 201a及深溝槽電容203上順應性形成一隔絕層,並對^絕Continued gates are used for isolation. Among them, the conductive layer is, for example, a polycrystalline stone layer; the ring-shaped insulating layer 204 is, for example, an oxide layer. M Please refer to FIG. 2b. Next, an isolation layer is formed on the semiconductor substrate 201, the deep trench 201a and the deep trench capacitor 203 in conformity, and the insulation layer
1223377 五、發明說明(7) " " 層進行等向性儀刻步驟以去除深溝槽2〇la侧壁上之隔絕 層’、直至留下深溝槽電容203上之隔絕層205。因為隔絕層 7成於深溝槽20 la側壁與深溝槽電容2〇3表面上之厚度比 2小於1 : 8,因此去除深溝槽2〇la侧壁上之隔絕層時,對 深屢槽電容2〇3上之隔絕層2〇5不會有相當大的影響。其 中’隔絕層20 5例如是頂溝槽氧化層(top trench oxide) 〇 請參考第2c圖,於墊層202上形成一罩幕層206,罩幕 層206會填滿深溝槽2〇 la。其中,罩幕層2〇6例如是有機抗 反射層如氮氧化矽(Si ON)層等。 接下來,對罩幕層2 〇 6進行平坦化步驟至露出墊層2 〇 2 之表面為止,並留下深溝槽2〇la内之罩幕層2〇6a,如第2d 圖所示。其中,平坦化步驟例如是化學機械研磨 (chemical mechanical polish)步驟或回蝕刻(etch b a c k)步驟。 凊參考第2e圖,於二深溝槽201a間之半導體基底2〇l 上形成一光阻層207,光阻層207為了將半導體基底2〇1完 全覆蓋,因此會覆蓋部分之罩幕層2〇6a。 请參考第2f圖,以光阻層207及罩幕層206a為姓刻罩 幕’對半導體基底2 0 1進行非等向性钱刻,直到未被遮蔽 之半導體基底201之高度低於隔絕層205為止,被蝕刻之半 導體基底201之深度約為2600至3300A。其中,非等向性 #刻例如是電漿蝕刻(plasma etching)或反應性離子钱刻 (reactive ion etching);反應氣體為含溪化氫(HBr)氣1223377 V. Description of the invention (7) The layer is subjected to an isotropic engraving step to remove the insulating layer on the side wall of the deep trench 20a, until the insulating layer 205 on the deep trench capacitor 203 is left. Because the insulation layer 7 is formed on the sidewall of the deep trench 20 la and the thickness ratio 2 on the surface of the deep trench capacitor 20 is less than 1: 8, when removing the insulation layer on the sidewall of the deep trench 20 la, the deep trench capacitor 2 is removed. The isolation layer 205 on 〇3 will not have a considerable impact. The 'isolation layer 20 5 is, for example, a top trench oxide. Please refer to FIG. 2C. A mask layer 206 is formed on the cushion layer 202. The mask layer 206 will fill the deep trenches 20 la. The mask layer 206 is, for example, an organic anti-reflection layer such as a silicon oxynitride (Si ON) layer. Next, a planarization step is performed on the mask layer 206 until the surface of the cushion layer 200 is exposed, and the mask layer 206a in the deep trench 20a is left, as shown in FIG. 2d. The planarization step is, for example, a chemical mechanical polish step or an etch b a c k step.凊 Referring to FIG. 2e, a photoresist layer 207 is formed on the semiconductor substrate 201 between the two deep trenches 201a. In order to completely cover the semiconductor substrate 201, the photoresist layer 207 will cover a part of the mask layer 2. 6a. Please refer to FIG. 2f, and use the photoresist layer 207 and the mask layer 206a as the last name to engrav the mask. Up to 205, the depth of the etched semiconductor substrate 201 is about 2600 to 3300A. Among them, the anisotropic #etch is, for example, plasma etching or reactive ion etching; the reaction gas is a hydrogen-containing hydrogen (HBr) gas.
0548-9650twF(nl) ; 91299 ; Claire.ptd 第 11 頁 1223377 五、發明說明(8) ~" 體與含氧(〇2)氣體之混合氣體,含溴化氫(HBr)氣體對多晶 石夕層與氮化層具有良好選擇蝕刻,可減少蝕刻基底時對其 他構造之影響。 〃 請芩考第2g圖’依序將光阻層207及罩幕層2〇6a去 除,如此一來即使二深溝槽2 〇 1 a間之半導體基底2 〇丨b呈一 突出柱狀,如此一來,二深溝槽20 la間之突出柱狀之半導 體基底20 lb即為後續形成電晶體位置之主動區。 請參考第2h圖,利用N型離子對主動區2 〇丨b露出部分 之底部角落進行離子植入步驟。 請麥考第2 1圖,進行離子植入步驟後,在隔絕層2 〇 5 側壁之主動區201b中會形成離子植入區21〇,用以作為源 汲極區,犧牲層208a可以在離子植入過程中保護主動區 201b被破壞;然後,將犧牲層2〇8a去除。 請參考第2j圖,對半導體基底2〇1進行熱氧化 (thermal oxidation)步驟,以在半導體基底 2〇la&2〇lb 硌出之表面上形成一氧化層,用以作為閘極介電層2丨i。 因為隔絕層205之材質同樣為氧化層,因此隔絕層2〇5上不 會再次氧化。0548-9650twF (nl); 91299; Claire.ptd Page 11 1223377 V. Description of the invention (8) ~ " Mixed gas of gas and oxygen-containing (〇2) gas, hydrogen bromide (HBr) -containing polycrystalline The Shi Xi layer and the nitride layer have good selective etching, which can reduce the influence on other structures when etching the substrate. 〃 Please refer to Figure 2g, 'Sequentially remove the photoresist layer 207 and the mask layer 206a. In this way, even if the semiconductor substrate 2 〇 丨 b between the two deep trenches 2 〇a is a protruding column, so As a result, the protruding columnar semiconductor substrate 20 lb between the two deep trenches 20 a is the active area for the subsequent formation of the transistor position. Referring to FIG. 2h, the ion implantation step is performed by using the N-type ion to the bottom corner of the exposed portion of the active region 20b. Please refer to FIG. 21 of McCaw. After the ion implantation step, an ion implantation region 21 will be formed in the active region 201b of the side wall of the isolation layer 205, which is used as a source drain region. The sacrificial layer 208a can The protective active region 201b is destroyed during the implantation; then, the sacrificial layer 208a is removed. Referring to FIG. 2j, a thermal oxidation step is performed on the semiconductor substrate 201 to form an oxide layer on the surface of the semiconductor substrate 201a & 20lb, which is used as a gate dielectric layer. 2 丨 i. Because the material of the insulating layer 205 is also an oxide layer, the insulating layer 205 will not be oxidized again.
接著,於半導體基底201上順應性形成一導電層212a 及硬罩幕層212b,導電層212例如是多晶矽(p〇ly)層與金 屬矽化物(silicide)層組成之複合層,用以在後續作為閘 極之用;其中’金屬矽化物層例如是矽化鎢(WSi 硬罩 幕層21 2b例如是氮化層。 然後,於導電層212a及硬罩幕層21 2b上形成一圖案化Next, a conductive layer 212a and a hard mask layer 212b are formed conformably on the semiconductor substrate 201. The conductive layer 212 is, for example, a composite layer composed of a polycrystalline silicon (poly) layer and a metal silicide layer for subsequent use. Used as a gate electrode; where the metal silicide layer is, for example, tungsten silicide (WSi hard mask layer 21 2b is, for example, a nitride layer. Then, a pattern is formed on the conductive layer 212a and the hard mask layer 21 2b.
〇548-9650twF(nl) ; 91299 ; Clairc.ptd 第12頁 1223377 五、發明說明(9) 罩幕層2 1 3 ’圖案化罩幕層2 1 3例如是光阻層’形成於對應 主動區201b之導電層212a及硬罩幕層212b上;並且,為了 能夠完全覆蓋對應主動區201b之導電層212a及硬罩幕層 2 1 2b的緣故,圖案化罩幕層2 1 3亦會覆蓋住部分對應隔絕 區205之導電層212a及硬罩幕層212b。 請參考第2k圖’以圖案化罩幕層203為钱刻罩幕,對 導電層212a及硬罩幕層212b依序進行#刻至露出未被圖案 化罩幕層2 0 3覆蓋之閘極介電層2 11及隔絕層2 0 5為止,以 形成一環繞於主動區201b之導電層212c及硬罩幕層212d。 接著’將圖案化罩幕層203去除後,於半導體基底2〇1 上形成一介電層2 1 4,並對介電層2 1 4進行平坦化步驟以使 介電層214與導電層212c及硬罩幕層212d之頂部大體等 高,如第2p圖所示。其中,介電層214例如是高密度電漿 (high density plasma,HDP)氧化層,用以作為主動區 2 0 1 b間之隔離區。 根據本發明所提供之適用於動態隨機存取記憶單元之 八有4刀垂直通道電晶體之主動區製程中,可藉由在深溝 槽中形成抗反射層來作為自對準之罩幕,可減少光罩之數 目,有效減少製作時間及成本。同時,因為有抗反射層作 ^蝕刻罩幕的緣故,可避免蝕刻至深溝槽之領型環狀絕緣 層1此可使精多晶碎層及氮化層具有良好選擇㈣比 之乳體,例如溴化氫氣體來作為蝕刻反應氣體。 發明已以較佳實施例揭露如上,然其並非用以 限疋本發明,任何熟習此技藝者,在不脫離本發明之精神〇548-9650twF (nl); 91299; Clairc.ptd Page 12 1223377 V. Description of the invention (9) Mask layer 2 1 3 'The patterned mask layer 2 1 3 is, for example, a photoresist layer' formed in the corresponding active region The conductive layer 212a of 201b and the hard cover curtain layer 212b; and in order to completely cover the conductive layer 212a and the hard cover curtain layer 2 1 2b corresponding to the active area 201b, the patterned cover curtain layer 2 1 3 will also be covered. Partly corresponds to the conductive layer 212a and the hard mask layer 212b of the isolation region 205. Please refer to FIG. 2k ', using the patterned mask layer 203 as the money mask mask, sequentially perform #etching on the conductive layer 212a and the hard mask layer 212b to expose the gate electrode that is not covered by the patterned mask layer 2 0 3 The dielectric layer 2 11 and the insulating layer 2 05 are formed to form a conductive layer 212 c and a hard mask layer 212 d that surround the active region 201 b. Next, after the patterned mask layer 203 is removed, a dielectric layer 2 1 4 is formed on the semiconductor substrate 201, and a planarization step is performed on the dielectric layer 2 1 4 to make the dielectric layer 214 and the conductive layer 212c. And the top of the hard cover curtain layer 212d is substantially the same height, as shown in FIG. 2p. The dielectric layer 214 is, for example, a high density plasma (HDP) oxide layer, and is used as an isolation region between the active regions 2 0 1 b. According to the present invention, in the active-area process of eight-blade vertical channel transistors suitable for dynamic random access memory cells, an anti-reflection layer can be formed in a deep trench as a self-aligned mask. Reducing the number of photomasks effectively reduces production time and costs. At the same time, because the anti-reflection layer is used as the etching mask, the collar-shaped ring-shaped insulating layer 1 that can be etched to the deep trenches can be avoided. As the etching reaction gas, for example, hydrogen bromide gas is used. The invention has been disclosed as above with preferred embodiments, but it is not intended to limit the present invention. Anyone skilled in the art will not depart from the spirit of the present invention.
II,II,
0548-9650twF(nl) ; 91299 ; Claire.ptd 1223377 五、發明說明(ίο) 和範圍内,當可作更動與潤飾,因此本發明之保護範圍當 視後附之申請專利範圍所界定者為準。 IBii 0548-9650twF(nl) ; 91299 ; Clairc.ptd 第14頁 1223377 圖式簡單說明 第1 a- 1 e圖係顯示習知之具有部分垂直通道之電晶體 之切面示意圖。 第2 a-21圖係顯示本發明之隔離具有部分垂直通道記 憶單元之主動區的方法之切面示意圖。 符號說明: 1 0 1〜p型矽基底; 1 0 2〜柱形區, 1 0 3 a〜薄塾氧化物層; 103b〜氮氧化物層; 1 0 4〜深溝槽; 1 0 5〜重度摻雜氧化物; 1 0 6〜n+擴散區; 1 0 7〜頂氧化層-氮化層-底氧化層; 1 0 8〜電容板; 1 0 9〜障蔽氧化層; 11 0〜閘極氧化物; 111〜控制閘極; 11 2〜n+沒極區; 11 3〜位元線金屬層; 201、201b〜半導體基底; 2 0 1 a〜深溝槽; 2 0 2〜塾層; 203〜深溝槽電容;0548-9650twF (nl); 91299; Claire.ptd 1223377 V. Within the scope of the invention description (ίο) and modifications can be made and retouched, so the scope of protection of the present invention shall be determined by the scope of the attached patent application . IBii 0548-9650twF (nl); 91299; Clairc.ptd Page 14 1223377 Brief description of the diagrams Figures 1 a-1 e are schematic cross-sectional views of conventional transistors with partial vertical channels. Figures 2a-21 are schematic cross-sectional views showing the method for isolating the active area of a memory cell with a partial vertical channel according to the present invention. Explanation of symbols: 1 0 1 ~ p-type silicon substrate; 10 2 ~ columnar area, 1 0 3 a ~ thin hafnium oxide layer; 103b ~ oxynitride layer; 104 ~ deep trench; 105 ~ heavy Doped oxide; 106 ~ n + diffusion region; 107 ~ top oxide layer-nitriding layer-bottom oxide layer; 108 ~ capacitor plate; 109 ~ barrier oxide layer; 110 ~ gate oxidation Object; 111 ~ control gate; 11 2 ~ n + non-electrode region; 11 3 ~ bit line metal layer; 201, 201b ~ semiconductor substrate; 2 0 1 a ~ deep trench; 2 0 2 ~ 0 layer; 203 ~ deep trench Slot capacitance
0548-9650twF(nl) ; 91299 ; Clairc.ptd 第15頁 1223377 圖式簡單說明 2 0 4〜環狀絕緣層; 2 0 5〜隔絕層; 20 6〜罩幕層; 2 0 7〜光阻層; 2 1 0〜離子植入區; 2 11〜閘極介電層; 212a、212c〜導電層; 212b、212d〜硬罩幕層; 213〜圖案化罩幕層; 2 1 4〜介電層。0548-9650twF (nl); 91299; Clairc.ptd Page 15 1223377 The diagram briefly explains 2 0 4 ~ ring insulation layer; 2 5 5 ~ insulation layer; 20 6 ~ cover layer; 2 0 7 ~ photoresist layer 2 1 0 ~ ion implantation area; 2 11 ~ gate dielectric layer; 212a, 212c ~ conductive layer; 212b, 212d ~ hard cover curtain layer; 213 ~ patterned cover curtain layer; 2 1 4 ~ dielectric layer .
0548-9650twF(nl) ; 91299 ; Clairc.ptd 第16頁0548-9650twF (nl); 91299; Clairc.ptd page 16
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