TWI221521B - Electrolysis water oxidation-reduction potential calibration system and its adjustment compensation constant output method - Google Patents

Electrolysis water oxidation-reduction potential calibration system and its adjustment compensation constant output method Download PDF

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TWI221521B
TWI221521B TW92104884A TW92104884A TWI221521B TW I221521 B TWI221521 B TW I221521B TW 92104884 A TW92104884 A TW 92104884A TW 92104884 A TW92104884 A TW 92104884A TW I221521 B TWI221521 B TW I221521B
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water
reduction potential
current
oxidation
circuit
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TW92104884A
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Chinese (zh)
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TW200417730A (en
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Wen-Shing Shiu
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Wen-Shing Shiu
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Abstract

The present invention provides an electrolysis water oxidation-reduction potential calibration system and its adjustment compensation constant output method. The experimental data is converted into (1) electrolysis current, (2) electrolysis time, and (3) relation between electrolyte type and electrolysis water oxidation-reduction potential and its coordination parameters stored in a microcomputer database. The actual data detected by the detection device is employed and calculated by the microcomputer to compare the liquid crystal display value with the oxidation-reduction potential of actual electrolyte and correct the data. Further, based on the actual display value, an ideal segment of the oxidation-reduction potential is taken, and a segmenting control is performed based on the current density corresponding to the ideal segment, so as to obtain a segment selection for the oxidation-reduction potential. Moreover, the current density of electrolytic vessel can be precisely controlled by using the detection circuit to detect the change of inner resistance in the electrolytic vessel and using a comparison circuit to adjust the voltage, thereby making the output constant and thus achieving the purpose of the present invention.

Description

1221521 玖、發明說明(1) 【發明所屬之技術領域】 一種電解水氧化還原電位定位系統及其校正補償恒定 輸出方法,該系統係由微電腦、偵測元件、主控電路、操 控糸統所組成’其争微電腦可以根據輸入的實驗數據,經 演算比對並具有訊號輸击功能,偵測元件可以偵測出電流 密度、進水流速及電解槽阻抗變化,主控電路受微電觸控 制可以由比較電路自動昇降電壓,操控系統可以設定及校 正液晶顯示幕之氧化還原電位數值,本方法係利用微電腦 將偵測元件測得的數據,與資料庫演算、比對,並經校正 後’即可依據結果,選擇理想區段(該區段亦可分段控制 ),再藉由比較電路自動調整電壓,精確控制電解槽之電 流密度,使其氧化還原電位恒定輸出,達成氧化還原電位 恒定在有效理想區段的目的者。 【先前技術】 按’通常在檢驗電解水所產生的鹼性還原水,以飲用 水為例,如果還原電位介於一2〇{)m v (毫伏)至一 v (毫伏)時,具有較佳的抗氧化效果,以工業用洗淨設 備為例,選擇還原電位介於—8〇〇mv (毫伏)至一 1〇〇〇 mv (毫伏)時,具有較佳的分解油污及抗氧化防鏽效果 ,如果氧化電位於+750 mv (毫伏)左右之微酸性水, 則適用於一般美容用水,如果氧化電位上昇至+ 96〇 (毫伏)至+ 1200m v(毫伏)時,則稱為強酸性水,可適 用於一般醫療用或農業用之殺菌水。 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) U21521 發明說明(2 ) 惟’早期的電解水生成器,均無法自動镇測顯示及補 償電麻氧化縣粒,只能被統定_驗測儀器檢 測電解水的氧化還原電位,又因所使用的檢測儀器,經常 會因為水中_料網造成感測馳塞,使得檢測的結 果產生誤差’本f申权將提供—些目_錢的_A 水質測試儀器之型錄(敬請參閱附件—所示)與猶Εχ TS 卜TS2手提式酸驗度氧化還原溫度_定儀之操傾明書( 敬請參_件二所示),_件—第六頁的綱内容,以 及附件二第七頁的第五項「保養」項目中,即可非常清楚 瞭解到目前所使_水質職儀器以及酸驗度氧化還原溫 度測定儀’在實際使料’會因為水中齡質或賴造成 檢測儀器的感應$阻塞,或是因為檢帛懷(氣化卸1 )長期使用而失效,必須進行校正與清潔或更換電極,方 能確保篁測的精確度,,否則會導致檢測的結果出錯及產生 誤差,為目前檢驗電解水其既存尚待克服解決的問題盘缺 失。 由於,早期所販售的電解水生成器,均沒有設定及顯 示電解水氧化還原電位的功能,只能靠定期檢測,來得知 電解水的氧化還原電位,但是這些檢測儀器價格昂貴,一 般使用者並不會購買,廠商也不會隨機附送,只能在廠商 定期維修保養時一併檢測,如此一來使用者每天所使用之1 電解水,根本就無從得知其氧化還原電位是否符合標準。 雖然目前已經有電解水機裝置在微處理器輸入端上分 @續次頁(發明說明頁不敷使用時,請註記並使用續頁) 1221521 發明說明(3) 別連接有一溫度感應器及一流量感應器、一總固容量感應 器,該溫度感應器與流量感應器與總固容量感應器係設於 迴水回路上,而濾心壽命感應器則設於水流回路與電解槽 間的濾心上,電解槽的變壓器連接至微處理器的輸出端; 藉由微處理器可利用溫度感應器與流量感應器與濾心壽命 感應器與總固容量感應器所顯示的水源數據,直接改變電 解槽的電解電壓,而構成一個可依水源實際流量進行電解 的電解裝置;另外該電解水機的微處理器設有一pΗ值0 RP值感應器’該ΡΗ值ORP值感應器係設於電解槽的 _ 出水回路,且微處理器通過一推動電路I C連接背光型的 液晶顯示器電路,利用檢測到的ΡΗ值ORΡ值通過微處 理器推動電路I C改變液晶顯示器的背光顏色,讓使用者 可以立即得知電解水之ρΗ值ORρ值者。 惟,當水被電解時,陰極管的管壁内部會因為吸收陽 離子(如鈣離子),所以在使用一段時間之後,陰極管的 營壁内部即會有積鈣的情形產生,因而造成電解槽内部的 阻抗增加,使得電解時的電流密度逐漸減少,逕而導致電 解水之氧化還原電位亦逐漸相對減少(即氧化還原電位均 趨近於原水的原始電位),根據實驗顯示氧化還原電位除 了與電流密度有關之外,亦與電解時間(進水流速)、電 解質種類(水中陰陽離子分佈比例及濃度)有關。 @續次頁(翻翻頁不敷使用時,請註記雌用願) 發明說明(4) 而目前所知的電解水機裝置,係將總固容量感應器設 於電解槽的迴水回路上,以及將PH值〇Rp值感應器設 於電解槽的出水回路,會因為水中的雜質或積鈣造成總固 容量感應器與P Η值OR P值感應器阻塞,使得檢測的結 果產生誤差,如此一來使用者每天所使用之電解水,根本 就無從得知其氧化還原電位是否符合標準。 同時,又因PΗ值ORP值感應器的檢測液(氣化鉀 κC1)長期使用失效’而導致檢測結果出錯。 有鑑於此,本發明人於是積極投入研究開發與創新改 良之精神,終於完成之本發明係在提供一種電解水氧化還 原電位定位系統及其校正補償恒定輸出方法。 【發明内容】 【發明所欲解決之技術問題】 本發明所欲解決之技術問題一係在於:目前所知的電 解水機裝置,將總固容量感應器設於電解槽的迴水回路上 ,以及將PΗ值ORP值感應器設於電解槽的出水回路, 經常會因為水中的雜質或積鈣造成總固容量感應器與pΗ 值〇RP值感應器阻塞,使得檢測的結果產生誤差;為其 既存尚待克服解決的問題與缺失之一。 本發明所欲解決之技術問題二係在於:目前所知的電 解水機裝置,將該PH值ORP值感應器所測得水源數據 的PH值〇RP值,利用微處理器推動電路j (^連接背光 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 1221521 發明說明(5) 型的液晶顯示器電路,藉以改變液晶顯示器的背光顏色, f知電解水之PH值〇RP值;惟液晶顯示器的背光顏色 最多=有十幾種,如何顯示還原電位(_ 8 〇 〇 m v毫伏 )至氧化電位(+12G0mV毫伏)範圍之内,將近有 2 0 0 〇侧度的數值,所以细改變液晶顯示器的背光 顏色,得知電解水之ΡΗ值ORp值,實施上並不切實用 ,而且PH值所代表的酸、鹼性,並不等同於〇Rp值所 代表的氧化還原電位,因為PH8·5的驗性水,立氧化 還原電㈣Q R P值可能是_ 2 Q Q m v級的還原電位 :也有可能是+15 Qmv毫伏的氧化電位,所以根本就 然法利用液晶顯示器的背光顏色,同時顯示PH值與⑽ P值;為其既存尚待克服解決的問題與缺失之二。 本發明所欲解決之技姻題三係在於^目前所知的電 2水機裝置,絲設置檢知電路细電解槽触之變化, 田電解槽的内阻因為積鈣而增加時,並無法調昇工作電壓 使得電解時的電流密度逐漸減少,逕而導致電解水之& 化還原電㈣稍械減少(即氧化綱電綱趨近於1 水的原始電位),或是當電解槽軸闕為電解質種類的' 不同而使導電率增加或減少時,亦無法調降或調昇工作電 屢’使得電解時的電流密度逐料加或減少,逕而 解水之氧化還原電位因為不穩定而產生誤差;為其 待克服解決的問題與缺失之三。 " 本發明所欲解決之技術問題四係在於:目前所知的電 0績次頁(發明說明頁不敷使用時,請註記並使用顧) !221521 發明說明(6) 解水機裝置,將總固容量感應器設於電解槽的迴水回略上 ,以及將Pii值ORP值感應器設於電解槽的出水回路, 然而總固容量感應器、PH值〇RP值感應器的價格昂貴 ,勢必會增加電解水機裝置的成本,使售價提高好幾倍, 不具市場競爭力,而被淘沃,為其既存尚待克服解決的問 題與缺失之四。 本發明所欲解決之技術問題五係在於··目前所知的電 解水機裝置,將總固容量感應器設於電解槽的迴水回路上 ’以及將PΗ值ORP值感應器設於電解槽的出水回路, 然而總固容量感應器' PH值〇Rp值感應器,必須經常 保養維修,造成維修成本的增加,亦突顯出其產品設計的 不良與瑕疵,為其既存尚待克服解決的問題與缺失之五。 【發明解決問題之技術手段】 本發明解決問題之技術手段係在於··經實驗發現,在 電解槽結構固定型態下(如:電極材料、隔膜種類、總相 對陰、陽電極面積或電極距離)影響電解水氧化還原電位 的主要因素,包括: 一 ·電解時間(進水流速)。 一電解電流(電流密度)。 二·電解質種類(陰陽離子分佈比例及濃度)。 本發明主要係以實驗數據換算出關係式與座標參數: 敬晴參閲第一圖所示:係電解時間與電解水氧化還原 電位之實驗數據座標圖。與第二圖所* :係進水流速與電 3續次頁(翻誦頁不雖卿,請註記並使用顧) 1221521 發明說明(了) 解水氧化還原電位之實驗數據座標圖。即隨著電解時間增 加,亦即進水流速變慢: 其陽極取得之氧化水氧化還原電位遞增,如:氧化水 之氧化電位以正值表示,可由+2〇0mv(毫伏)上羿至+ 1 200m v (毫伏)。 其陰極取得之還原水氧化還原電位逐漸下降,如:還 原水之還原電位以負值表示,可由+2〇〇mv(毫伏)逐漸 下降至一800mv(毫伏)。 上述氧化水電位遞增,表示氧化力愈強,還原水電位 逐漸下降,表示還原力愈強。 敬請參閱第三圖所示:係電解電流(電流密度)與電 解水氧化還弱位之實驗數據座標圖。即隨著電解電流( 電流密度)增加: 其陽極取狀氧化水氧倾原雜遞增,如:氧化水 之氧化電位以正值表示,可由(毫伏)上弃至+ 1 200m v (毫伏)。 ’、陰極取得之還原水氧化還原電位逐漸下降,如··還 原水之還原電位以負值表示,可由+2GGmv(毫伏)逐漸 下降至— 800m v (毫伏)。 還原水電位 、、上述減水驗遞增’絲氧化力愈強 逐新下降,表示還原力愈強。 “敬請參閱第四圖所示:係電㈣種類(陰陽離子 ί:列與電解水氧倾原紐之實驗數據座標圖。即: ID續次頁(發明_頁不雜用時,請註記鎌用顚) 1221521 發明說明(8 ) 當電解質之陽離子(如:鈣、鎂、鉀、鈉…等)分佈 比例增加時,陰極取得之還原水電位逐漸下降,表示還原 力愈強。 當電解質之陰離子(如:草酸、碳酸、磷酸、氯···等 )分佈比例增加時,陽極取得之氧化水電位遞增,表示氧 化力愈強。 敬請參閱第五圖所示:係電解質種類(陰陽離子濃度 )與電解水氧化還原電位之實驗數據座標圖。即: 當電解質之陰陽離子濃度增加時,陰極取得之還原水 電位逐漸下降,表示還原力愈強。 當電解質之陰陽離子漠度增加時,陽極取得之氧化水 電位遞增,表示氧化力愈強。 根據上述電解時間(進水流速)、電解電流(電流密 度)、電解質種類(陰陽離子分佈比例及濃度)與電解水 氧化還原電位之關係,經實驗取得相關之數據,製作成座 標參數,同時在電解時間(進水流速)與電解質種類(陰 陽離子分佈比例及濃度)條件固定之下,即: 電解時間(進水流速)為: 每分鐘四公升進水流速。 電解質種類(陰陽離子分佈比例)為: 陰離子分佈比例5 0% 陽離子分佈比例5 0% 電解質種類(陰陽離子濃度)為: 0續次頁(發明說明頁不敷使用時,請註記並使用纘頁) 1221521 發明說明(9)1221521 (1) Description of the invention (1) [Technical field to which the invention belongs] An electrolyzed water redox potential positioning system and a constant compensation method for correction compensation. The system is composed of a microcomputer, a detection element, a main control circuit, and a control system. 'The competition microcomputer can calculate and compare with the input experimental data, and has a signal input function. The detection element can detect changes in current density, water flow velocity and impedance of the electrolytic cell. The main control circuit can be controlled by micro-electric touch. The comparison circuit automatically raises and lowers the voltage, and the control system can set and correct the oxidation-reduction potential value of the LCD screen. This method uses a microcomputer to calculate and compare the data measured by the detection element with the database, and after correction, that is, According to the results, select the ideal section (the section can also be controlled in sections), and then automatically adjust the voltage through the comparison circuit to precisely control the current density of the electrolytic cell so that its redox potential is constant and the redox potential is constant at Effective destination of ideal sector. [Previous technology] According to 'usually testing alkaline reduced water produced by electrolyzed water, taking drinking water as an example, if the reduction potential is between -20 {) mv (millivolt) to one v (millivolt), it has Better anti-oxidation effect. Taking industrial cleaning equipment as an example, when the reduction potential is selected from -800mv (millivolt) to 10,000mv (millivolt), it has better decomposition of oil and Anti-oxidation and anti-rust effect, if the oxidation electricity is slightly acidic water at +750 mv (millivolt), it is suitable for general beauty water, if the oxidation potential rises to + 96〇 (millivolt) to + 1200mv (millivolt) When it is called strong acid water, it can be used for general medical or agricultural sterilizing water. 0 Continued pages (Please note and use the continuation page when the invention description page is not enough.) U21521 Invention description (2) However, the early electrolyzed water generators could not automatically test and display and compensate the electric anesthesia. Can be set _ inspection and testing equipment to detect the redox potential of electrolyzed water, and because of the detection equipment used, often the sensing congestion caused by the water _ material network causes errors in the test results. — Some items_qian_A A catalog of water quality testing equipment (please refer to the attachment—shown) and Εχ TS bu TS2 portable acid test redox temperature _ Dingyi's operation manual (please refer to _ (Shown in Case 2), _ Case—the outline of the sixth page, and the fifth item “Maintenance” on page 7 of Annex II, you can clearly understand the current _ water quality equipment and acidity oxidation The reduction temperature measuring instrument 'actually used' will cause the sensing instrument to block due to the age or quality of the water, or it will fail due to the long-term use of the inspection device (gasification discharge 1). Calibration and cleaning must be performed or the electrodes must be replaced. To ensure the accuracy of speculation Otherwise, the results will lead to error detection and error occurs, it is currently testing its existing electrolysis of water to be overcome to solve the problem of missing disk. Because the electrolyzed water generators sold in the early days did not have the function of setting and displaying the redox potential of the electrolyzed water, they can only know the redox potential of the electrolyzed water by regular inspection, but these detection instruments are expensive and the average user It will not be purchased, and the manufacturer will not accompany it. It can only be inspected during the regular maintenance of the manufacturer. As a result, the electrolyzed water used by the user every day has no way of knowing whether its redox potential meets the standard. Although there is already a water ionizer device on the microprocessor input terminal @ Continue 次 页 (When the description page of the invention is insufficient, please note and use the continued page) 1221521 Description of the invention (3) Do not connect a temperature sensor and a Flow sensor, a total solid capacity sensor, the temperature sensor and the flow sensor and the total solid capacity sensor are provided on the return water circuit, and the filter life sensor is provided on the water circuit and the electrolytic cell. In mind, the transformer of the electrolytic cell is connected to the output of the microprocessor; the microprocessor can use the water source data displayed by the temperature sensor, flow sensor, filter life sensor and total solid capacity sensor to directly change The electrolytic voltage of the electrolytic cell constitutes an electrolytic device that can perform electrolysis according to the actual flow of the water source. In addition, the microprocessor of the water ionizer is provided with a pΗvalue 0 RP value sensor. The pΗvalue ORP value sensor is set in the electrolysis. _ Outlet circuit of the tank, and the microprocessor is connected to the backlight type liquid crystal display circuit through a driving circuit IC, and the detected circuit is used to push the circuit IC through the microprocessor. Change the backlight color of the LCD, so that the user can immediately know the ρΗ value ORρ value of the electrolyzed water. However, when water is electrolyzed, the inside of the tube wall of the cathode tube will absorb cations (such as calcium ions), so after using it for a period of time, there will be calcium accumulation inside the camp wall of the cathode tube, which will cause an electrolytic cell. The internal impedance increases, which causes the current density during electrolysis to gradually decrease, which leads to the relative reduction of the oxidation-reduction potential of the electrolyzed water (that is, the oxidation-reduction potential approaches the original potential of the raw water). According to experiments, the oxidation-reduction potential is different from that of the original water. In addition to the current density, it is also related to the electrolysis time (flow rate of water), the type of electrolyte (proportion and concentration of anion and cation in water). @Continue 次 页 (If the page is not enough, please note the female wish) Invention description (4) The currently known electrolyzed water machine device is a total solid capacity sensor set on the return circuit of the electrolytic cell , And the PH value 〇Rp value sensor is set in the water outlet circuit of the electrolytic cell, the total solid capacity sensor and the P OR value OR P value sensor will be blocked due to impurities or calcium deposits in the water, causing an error in the detection result, In this way, the electrolyzed water used by the user every day has no way of knowing whether its redox potential meets the standard. At the same time, the detection result of the PΗORP value sensor (gasified potassium κC1) has been ineffective for a long period of time, resulting in an error in the detection result. In view of this, the present inventors have actively invested in the spirit of research and development and innovation and improvement. The invention that has finally been completed is to provide an electrolyzed water oxidation reduction potential positioning system and a constant output method for correction and compensation. [Summary of the Invention] [Technical Problems to be Solved by the Invention] One of the technical problems to be solved by the present invention is that the currently known electrolyzed water machine device is provided with a total solid capacity sensor on the return circuit of the electrolytic tank. And the PΗ value ORP value sensor is set in the water outlet circuit of the electrolytic cell. The total solid capacity sensor and the pΗ value RP value sensor are often blocked due to impurities or calcium deposits in the water, which makes the detection result error; One of the existing problems and shortcomings to be resolved. The second technical problem to be solved by the present invention lies in: the currently known electrolyzed water machine device, the pH value of the water source data measured by the pH ORP value sensor is the RP value, and the microprocessor is used to push the circuit j (^ Connect to the backlight 0 continuation page (if the description page of the invention is inadequate, please note and use the continuation page) 1221521 Description of the invention (5) type liquid crystal display circuit to change the backlight color of the liquid crystal display and know the pH value of the electrolytic water. RP value; but the backlight color of the LCD display is at most = there are more than a dozen, how to display the reduction potential (_ 8 00mv millivolt) to the oxidation potential (+ 12G0mV millivolt), nearly 2 0 0 side Therefore, it is not practical to implement the pH value ORp value of the electrolyzed water by finely changing the backlight color of the liquid crystal display, and the acidity and alkalinity represented by the pH value are not the same as those represented by the 〇Rp value. The redox potential, because of the pH 8 · 5 test water, the redox Q RP value may be _ 2 QQ mv-level reduction potential: it may also be +15 Qmv millivolt oxidation potential, so the use of liquid crystal Monitor back Color, showing PH value and ⑽ P value at the same time; it is the second and existing problem to be solved. The third aspect of the technical problem to be solved by the present invention lies in the currently known electric 2 water machine device, wire setting Detect the change in the contact of the fine electrolytic cell of the circuit. When the internal resistance of the Tian electrolytic cell is increased due to the accumulation of calcium, the working voltage cannot be adjusted so that the current density during the electrolysis gradually decreases, resulting in the & It is also impossible to reduce or increase the working power when the mechanical power is reduced slightly (that is, the electrical potential of the oxidation class is approaching the original potential of water), or when the conductivity of the electrolytic cell is different from the type of electrolyte and the conductivity is increased or decreased. Repeatedly, the current density during electrolysis is increased or decreased one by one, and the oxidation-reduction potential of the dehydration solution causes errors due to instability; the third problem and deficiency to be solved. &Quot; The technology to be solved by the present invention The fourth problem lies in the current known electrical performance pages (if the invention description page is insufficient, please note and use Gu)! 221521 Description of the invention (6) Water dehydration device, the total solid capacity sensor is set in the electrolytic Trough backwater Slightly speaking, and the Pii ORP value sensor is set in the water outlet circuit of the electrolytic tank, but the total solid capacity sensor and PH value RP value sensor are expensive, which will inevitably increase the cost of the water ionizer device and make the sale The price has been increased several times, and it is not competitive in the market. Instead, it is the fourth of the existing problems and shortcomings that need to be solved. The fifth technical problem to be solved by the present invention lies in the currently known electrolyzed water machine device. , The total solid capacity sensor is set on the return circuit of the electrolytic cell 'and the PΗORP value sensor is set on the water outlet circuit of the electrolytic cell. However, the total solid capacity sensor' PH value and Rp value sensor must always be Maintenance and repair, resulting in an increase in maintenance costs, also highlights the poor and flawed product design, which is the fifth and existing problem to be solved. [Technical means for solving the problem of the invention] The technical means for solving the problem of the present invention lies in: · It has been experimentally found that under the fixed structure of the electrolytic cell (such as: electrode material, type of separator, total relative negative, positive electrode area, or electrode distance) ) The main factors affecting the redox potential of electrolyzed water include: 1. Electrolysis time (flow rate of water). An electrolytic current (current density). Electrolyte two species (anion and cation concentration and distribution ratio). The present invention is mainly based on experimental data to convert the relationship and coordinate parameters: Jing Qing Refer to the first figure: the experimental data coordinate chart of electrolysis time and electrolyzed water redox potential. And the second picture *: Department of water flow rate and electricity 3 Continued page (The page is not clear, please note and use Gu) 1221521 Description of the invention (a) The experimental data coordinate diagram of the water redox potential. That is, as the electrolysis time increases, that is, the flow velocity of the water decreases: the oxidation-reduction potential of the oxidized water obtained by the anode increases, such as: the oxidation potential of the oxidized water is expressed as a positive value, which can be increased from + 200mv (millivolts) to + 1 200m v (millivolts). The oxidation-reduction potential of the reducing water obtained by the cathode gradually decreases. For example, the reduction potential of the reducing water is expressed as a negative value, and can gradually decrease from + 200mv (millivolt) to -800mv (millivolt). The above-mentioned oxidizing water potential increases, indicating that the stronger the oxidizing power, and the reducing water potential gradually decreases, indicating that the reducing power is stronger. Please refer to the third figure: the experimental data coordinate chart of electrolytic current (current density) and electrolytic water oxidation. That is, as the electrolytic current (current density) increases: its anode takes the form of oxidized water, and the oxygen impurity increases. For example, the oxidation potential of the oxidized water is expressed as a positive value, which can be discarded from (millivolts) to + 1 200m v (millivolts). ). “The redox potential of the reducing water obtained by the cathode gradually decreases, such as the reduction potential of the reducing water is expressed as a negative value, which can gradually decrease from + 2GGmv (millivolt) to −800mv (millivolt). The reducing water potential, and the above-mentioned water reduction test increase, the stronger the silk oxidation power is, the lower it is, which indicates the stronger the reducing power. "Please refer to the fourth figure: the coordinate data of the experimental data (anion and cation: column and electrolyzed water oxygen depletion). That is: ID continuation page (invention_ page is not miscellaneous, please note Sickle for sickle) 1221521 Description of the invention (8) When the distribution ratio of cations (such as calcium, magnesium, potassium, sodium, etc.) of the electrolyte increases, the potential of the reducing water obtained by the cathode gradually decreases, indicating that the reducing power is stronger. When the distribution ratio of anions (such as oxalic acid, carbonic acid, phosphoric acid, chlorine, etc.) increases, the potential of the oxidizing water obtained by the anode increases, indicating that the oxidizing power is stronger. Please refer to the fifth figure: the type of electrolyte (anion and cation) Coordinate plot of the experimental data of the concentration and the oxidation-reduction potential of the electrolyzed water. That is: When the anion and cation concentration of the electrolyte increases, the reduced water potential obtained by the cathode gradually decreases, indicating that the reducing power is stronger. When the anion and cation of the electrolyte increases, The potential of the oxidized water obtained by the anode increases, which indicates the stronger the oxidizing power. According to the above electrolysis time (water inlet flow rate), electrolysis current (current density), electrolyte type (negative The relationship between ion distribution ratio and concentration) and the oxidation-reduction potential of electrolyzed water is obtained through experiments to obtain coordinate data. At the same time, the conditions of electrolysis time (water flow rate) and electrolyte type (anion and cation distribution ratio and concentration) are fixed. Below, namely: Electrolysis time (water inlet flow rate): Four liters of water inlet flow rate per minute. Electrolyte type (anion and cation distribution ratio) is: Anion distribution ratio 50%, cation distribution ratio 50%, electrolyte type (anion and cation concentration) For: 0 Continued pages (Note when the invention description page is insufficient, please note and use the title page) 1221521 Invention description (9)

陰陽離子濃度1 5 0 PPM 敬請參閱第六圖所示:係電解時間與電解質種類條件 固定之下,電解電流(電流密度)與電解水氧化還原電位 之實驗數據座標圖。其令:依據電流密度大小與氧化還原 電位(0 R P)數值之實際關係,取其氧化還原電位之理 想區段,例如: 還原水氧化還原電位可設定於一200m v (毫伏)至一4 00m v (毫伏)之間; 氧化水氧化還原電位可設定於+960m v (毫伏)至+ 1 200m v (毫伏)之間。 再根據該理想區段之相對電流密度,作分段控制(例 如:該理想區段電解電流從2 a (安培)至8 a (安培) ,則可從2A (安培)至8A (安培)分成五段或多段控 制)’作為取得氧化還原電位之段位選擇,即可獲得下 演算式:Anion and cation concentration 1 50 0 PPM Please refer to the sixth figure: the experimental data coordinate chart of the electrolytic current (current density) and the electrolytic water redox potential under the conditions of fixed electrolytic time and electrolyte type. It makes: According to the actual relationship between the current density and the redox potential (0 RP) value, take the ideal section of its redox potential, for example: the redox potential of reducing water can be set from a 200mv (mV) to a 4 00m v (millivolt); oxidation water redox potential can be set between + 960mv (millivolt) to + 1 200mv (millivolt). According to the relative current density of the ideal section, the control is performed in sections (for example: the electrolytic current of the ideal section is from 2 a (amps) to 8 a (amps), then it can be divided from 2A (amps) to 8A (amps) Five or more stages of control) 'as the stage selection to obtain the redox potential, you can get the following calculation formula:

〇RP (顯示值)=〇RP(L)+〔A(X)-A(L)〕X 〔〇 R P ⑻ - 0 R p (L)/A ⑻-A (L)〕 其中: 〇RP (顯示值):為液晶螢幕實際顯示值。 S3、).為所測得第一段之氧化還原定位數值。 =:為_得最後—段之祕還原粒數值 a(l).為所洌得第—段泣。 ::所·最後一段之最高;流。 、(發明說明頁不雖用時,請|^記並使 用顧) 1221521 發明說明(1〇) A(X):為實際區段選擇之電流。 舉例說明: 當ORP〇〇 = —4 0 〇mv (毫伏)時,需8 A (安培)電流密度 〇RP(L) = —2 0 〇mv (毫伏)時,需2 A (安培)電流密度 若選擇第三段6A (安培)電流密度時, A(X):為實際區段選擇之電流,為6 A (安培)。 〇RP (顯不值)為何?將上述數值代入演算式中: ORP (顯示值)=〇RP(L)+〔A(X) — A(L)〕X 〔〇 R P (fl) — 〇 R P (L)/A (Η) — A (L)〕 由下列演算,得知·· 〇RP(顯示值)= -2〇〇mv+ (6a-2a) X ((-4〇〇mv) ^ (—200 my ))/8 A— 2a) =—2〇〇niv + 4AX (—20〇mv/6A) 2〇〇mv + 4:AX ( — 33 · 3mv/A) --200^^+ ( — 133 · 3mv) ~~333 · 3mv 即氧化還原電位ORP(顯示值以負值表示)為:〜 3 3 3 * 3mv 將上述實驗數據、演算式貯存於微電腦(c p u)資 料庫中’並利用偵測元件即流量計、分流電阻檢知電路i, 偵测出進水流速與電解槽的内阻變化,藉由微電腦演算、〇RP (display value) = 〇RP (L) + [A (X) -A (L)] X [〇RP ⑻-0 R p (L) / A ⑻-A (L)] where: 〇RP ( Display value): It is the actual display value of the LCD screen. S3,). It is the measured redox localization value of the first stage. =: For _ get the last paragraph of the secret reduction value a (l). For the obtained first paragraph of the cry. :: So the highest in the last paragraph; stream. (When the description page of the invention is not used, please remember it and use Gu) 1221521 Description of the invention (1〇) A (X): The current selected for the actual section. For example: When ORP〇〇 = —4 0 〇mv (millivolt), 8 A (Amp) current density 〇RP (L) = —2 0 〇mv (millivolt), 2 A (Amp) If the current density is 6A (Amp) in the third stage, A (X): The current selected for the actual segment is 6 A (Amp). 〇What is the value of RP? Substitute the above values into the calculation formula: ORP (display value) = 〇RP (L) + [A (X) — A (L)] X [〇RP (fl) — 〇RP (L) / A (Η) — A (L)] From the following calculations, we know that 〇RP (display value) = -2〇〇mv + (6a-2a) X ((-4〇〇mv) ^ (—200 my)) / 8 A— 2a) = —2〇niv + 4AX (—20〇mv / 6A) 2 00mv + 4: AX (— 33 · 3mv / A) --200 ^^ + (— 133 · 3mv) ~~ 333 · 3mv is the redox potential ORP (the displayed value is expressed as a negative value): ~ 3 3 3 * 3mv The above experimental data and calculation formulas are stored in a microcomputer (cpu) database, and the detection elements are flow meters and shunt resistors. The detection circuit i detects the change of the inlet water flow rate and the internal resistance of the electrolytic cell.

比對結果,再藉由液晶顯示幕顯示之氧化還原電位(〇R 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 1221521 發明說明(11) P )數值與實際電解液之氧化還原電位(〇R P )數值比 對,並加以上、下限校正。 敬請參閱第七圖所示:係實際電解液之氧化還原電位 作上、下限校正之實驗數據座標圖。一般水_的陰、陽離 子比例均衡約各佔5 0%,呈中性反應,ρη值為7,但 是當實際電解液ρΗ值為弱鹼性時,其陽離子比例為5 4 少〇 (陰離子比例為4 6%)時,濃度為1 5 〇 Ρ ΡΜ時, 其還原電位之斜率變化較大,表示該陰極取得之還原電位 比第六圖争之還原電位較大,即: A >(Η):所測得最後一段之最高電流,為8 a (安培)。 A (L):所測得第一段之最低電流,為2 A (安培)。 0 R P > (H):所測得最後一段之氧化還原定位數值,為 一48〇mv (毫伏)。 OR P > (L):所測得第一段之氧化還原定位數值,為 一 2 2 0 m v (毫伏)。 若選擇第三段6A (安培)電流密度時, A(X):為實際區段選擇之電流,為6 A (安培)。 ORP (顯示值)為何?將上述數值代入演算式中: ORP (顯示值)=0RP(L)+〔A(X) — A(L)〕X C 0 R Ρ (Η) - 〇 R P (L)/A (Η) - A (L)] 由下列演算,得知: 〇RP (顯示值)= 〜2 2〇mv+ (6a-2a) X〔(-48 0mv) 一 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 1221521 發明說明(12) (―2 2 〇mv)〕/ 8a—2a) =一 2 2〇mv + 4AX (―2 6〇hiv/6a) ——22〇hiv + 4aX ( — 43 * 3mv/a) ——22〇mv+ (— 173 e 2mv) =一 393 · 即實際氧化還原電位ORP(顯示值以負值表示)為 ••一 3 9 3 · 2 m v 此時再藉由液晶顯示幕得知電流密度大小與氧化還原 電位(0 R P)數值之實際關係,再根據實際顯示之氧化 還原電位(ORP)數值,取其電流密度或相對氧化還原 電位之理想區段,當該區段氧化還原電位之相對電流密度 設定時,本發明同時藉由檢知電路偵測電解槽内阻之變化 ,經比對電路調變電壓,由電壓(V)=電流(I)乘以 電阻(R)之關係式,根據選擇區段精確控制電解槽之電 流密度,如電解槽内阻增加,則調昇工作電壓,電解槽内 阻減少時,則調降工作電壓。 【發明對照先前技術之功效】 本發明對照先前技術之功效一係在於:使用者可以根 據實際電解液之氧化還原電位比對液晶顯示幕之氧化還原 電位,作上、下限之校正,由於本發明並未將總固容量感 知 j 應器與P Η值OR p值感應器設於電解槽的迴水回路與出 水回路上’所以並不會因為水中的雜質或積鈣造成總固容 量感應器與PH值ORP值感應器阻塞,影響其精確性的 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 1221521 發明說明(13) 情形,故精確性高。 一本發明對照先前技術之功效二係在於:根據液晶顯示 暮之氧化還原電位(0 R p)數值,取其氧化還原電位之 理想區段,再根據該理想區段之相對電流密度,作分段控 制,作為取彳f氧化還原電位之段位選擇;同時使用者可以 依照液晶顯示幕所顯示之氧化還原電位(〇Rp)數值, 作理想區段選擇,該電路控制系統可根據區段選擇之相對 電流密度,藉比較電路調變電壓,使其電流恒定輸出,其 目的在於使氧化還原電位恒定於理想區段。 Φ 本發明對照先前技術之功效三係在於:當電解槽内阻 增加至上限,致使調變電壓亦上昇至極限時,可由液晶顯 示幕指示其氧化還原電位(或由警示系統例如:蜂鳴器或 指不燈告之),當氧化還原電位不在理想區間時,使用者 即應進行電解槽清洗工作,使電解槽内阻恢復正常狀態。 本發明對照先前技術之功效四係在於:本發明並未將 總固容量感應器、〇Rp值感應器,裝設在電解水機裝置 上,而是以實驗數據換算出電解電流、電解時間、電解質 ❿ 種類與電解水氧化還原電位之關係式與座標參數,貯存於 微電腦資料庫中,再根據ORP檢測儀器檢驗出實際電解 液之氧化還原電位比對液晶顯示幕之氧化還原電位,作上 、下限之校正,所以成本比目前所知的電解水機裝置低, 具有競爭力,勢必成為市場的主流商品。 本發明對照先前技術之功效五係在於:由於本發明只 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 1221521 發明說明(14) 需要定期藉由OR P檢測儀器檢驗岀未電解前以及已電解 後的水中之氧化還原電位,重新輸入微電腦(cpu)中 ,比對作上、下限之校正即可,所以僅需作例行性的保養 維修工作,並不會造成維修成本的增加。 【具體實施例】 為使專精熟悉此項技藝之人仕業者易於深入瞭解本發 明的系統方法以及所能達成的功能效益,茲列舉一具體實 施例,並配合圖式詳細介紹說明如下: 一種電解水氧化還原電位定位系統及其校正補償恒定 輸出方法’敬請參閱第八圖所示:係本發明之控制方塊示 意圖。主要係在於:該電路係由微電腦C p u χ、c P U2 (1 〇 )、( 2 0 )、偵測元件(3 0 )、主控電路(4 0 )、 操控系統(5 〇)所組成,其中: 微電腦C P U i ( 1 0 ),可以輸入實驗數據(如第一 '二、三、四、五、六、七圖所示:係電解時間、進水流 速、電解電流(電流密度)、電解質種類(陰陽離子分佈比 例及濃度)與氧化還原電位之實驗數據座標圖)以及演算 式’該微電腦C P U 1 ( 1 0)並具有演算、比對與訊號輸 入、輸出功能;該演算式為: ORP (顯示值)=ORP(L)+〔A(x) — Att)〕X 〔〇 R Ρ (Η) - 0 R P (L)/A ⑻-A (L)〕 微電腦CP U2 (2 0),作為主控電路(4 0)〔内包 含酸驗控制(4 1 )、段位控制(4 2 )、電解控制(4 3 ) 0續次頁(發明說明頁不敷使用時,諝註記並使用續頁) 1221521 發明說明(15) 、電流偵測(4 4 )、電壓補償(4 5 )〕之處理; 偵測元件(3 0 ),包括流量計(3 1 )、分流電阻( 3 2)等;其中: 流量計(3 1 )主要係偵測電解槽的進水流速’流速 的大小訊號亦會傳遞至微電腦CPU i ( 1 0 )的資料庫 中,由手動或自動定水量控制(31 1)作進水流速與電 解時間之恒定控制; 將已電解之電解液,由ORP檢測儀器測知其氧化還 原電位,將所測得之數據與微電腦C P U1 ( 1 0 )的資 料庫比對,作上、下限校正; 敬請參閱第九圖所示:係本發明之控制電路示意圖。 主要係在電解槽設置分流電阻(3 2),再經由電流偵測 比較電路(4 4)及電壓補償比較電路(4 5),驅使主 控電路(4 0)的電壓調諧昇降電路與定電流控制(4 6 )的閘極驅動器調變電壓。 當電解槽有裝設手動或自動定水量控制(311)時 ,敬請參閱苐十圖所示:係本發明進水流速固定時之分流 電阻電路示意圖。其中: v:為實際電解之工作電壓。 1:為實際流經電解槽之總電流。 R :為電解槽之實際電阻(為可變電阻,例如··當電解槽 積鈣時内阻增加,或當電解槽的内阻因為電^質種^ 的濃度不同而使導電率增加或減少,濃度高、導電率 @續次頁(發明說明頁不敷使用時,請註記並使用續頁) 1221521 發明說明Cl 6) 增加,内阻減少,反之濃度低、導電率減少,内阻增 加)〇Compare the results and display the redox potential on the liquid crystal display screen (0R0 continuation page (when the description page of the invention is insufficient, please note and use the continuation page) 1221521 Description of the invention (11) P) Value and actual electrolysis The oxidation-reduction potential (〇RP) values of the liquids were compared, and the upper and lower limits were corrected. Please refer to the seventh figure: the experimental data coordinates of the redox potential of the actual electrolyte for upper and lower limit correction. In general, the anion and cation ratios of water are about 50%, and they are neutral. The ρη value is 7, but when the actual electrolyte ρΗ value is weakly alkaline, the cation ratio is 5 4 less. 0 (anion ratio At 4 6%), when the concentration is 15 RP PM, the slope of the reduction potential changes greatly, indicating that the reduction potential obtained by the cathode is greater than the reduction potential of the sixth figure, namely: A > (Η ): The highest current measured in the last paragraph is 8 a (Ampere). A (L): The lowest current measured in the first stage is 2 A (Ampere). 0 R P > (H): The measured redox localization value in the last segment is -480 mv (millivolts). OR P > (L): The measured redox localization value of the first segment is -220 mv (millivolt). If the third stage 6A (Amp) current density is selected, A (X): The current selected for the actual segment is 6 A (Amps). What is the ORP (display value)? Substitute the above values into the calculation formula: ORP (display value) = 0RP (L) + [A (X) — A (L)] XC 0 R Ρ (Η)-〇RP (L) / A (Η)-A (L)] The following calculations show that: 〇RP (display value) = ~ 2 2〇mv + (6a-2a) X [(-48 0mv)-0 Continued pages (when the invention description page is insufficient, please Note and use the continuation page) 1221521 Description of the invention (12) (―2 2 〇mv)] / 8a—2a) = 1 2 2mv + 4AX (—2 6〇hiv / 6a) —— 22〇hiv + 4aX ( — 43 * 3mv / a) ——22〇mv + (— 173 e 2mv) = one 393 · That is, the actual redox potential ORP (the displayed value is represented by a negative value) is •• one 3 9 3 · 2 mv The actual relationship between the current density and the oxidation-reduction potential (0 RP) value is obtained from the liquid crystal display screen, and then based on the actual displayed oxidation-reduction potential (ORP) value, the ideal section of its current density or relative oxidation-reduction potential is taken. When the relative current density of the oxidation-reduction potential in this section is set, the present invention simultaneously detects the change in the internal resistance of the electrolytic cell through a detection circuit, adjusts the voltage by the comparison circuit, and multiplies the voltage (V) = current (I) by Relationship between resistance (R) Selecting segments precise control of the current density of the electrolytic cell in accordance with the internal resistance increases as the cell, the operating voltage is raised, reducing the resistance when the cell, the operating voltage is lowered. [Effects of the invention compared with the prior art] One of the effects of the invention compared with the prior art is that the user can correct the redox potential of the liquid crystal display screen according to the redox potential of the actual electrolyte, and correct the upper and lower limits. The total solid capacity sensing device and the P ΗOR p value sensor are not installed on the return circuit and the outlet circuit of the electrolytic cell ', so the total solid capacity sensor and the calcium accumulation will not cause the total solid capacity sensor and The PH value ORP value sensor is blocked, which affects its accuracy. Continued page 0 (When the description page of the invention is insufficient, please note and use the continued page) 1221521 Description of the invention (13) The situation is high, so the accuracy is high. The second effect of the present invention compared with the prior art is that according to the value of the redox potential (0 R p) of the liquid crystal display, take the ideal segment of its redox potential, and then divide it according to the relative current density of the ideal segment. Segment control, as the selection of the f-redox potential; At the same time, the user can choose the ideal segment according to the redox potential (〇Rp) value displayed on the LCD screen. The circuit control system can select the segment according to the segment. With respect to the current density, the voltage is adjusted by the comparison circuit so that its current is constantly output, the purpose of which is to make the redox potential constant in the ideal section. Φ The third effect of the present invention compared with the prior art is that when the internal resistance of the electrolytic cell increases to the upper limit, which causes the modulation voltage to rise to the limit, its redox potential can be indicated by the liquid crystal display (or a warning system such as a buzzer or It means no warning), when the redox potential is not in the ideal range, the user should perform electrolytic cell cleaning to restore the internal resistance of the electrolytic cell to a normal state. The four functions of the present invention compared with the prior art are: The present invention does not install the total solid capacity sensor and the ORP value sensor on the water ionizer device, but converts the electrolytic current, electrolytic time, The relationship between the type of electrolyte 与 and the oxidation-reduction potential of the electrolyzed water and its coordinate parameters are stored in the microcomputer database, and then the actual oxidation-reduction potential of the electrolyte is compared with the oxidation-reduction potential of the liquid crystal display screen according to the ORP detection instrument. The lower limit is corrected, so the cost is lower than the currently known water ionizer device, and it is competitive and is bound to become the mainstream commodity in the market. The five aspects of the efficacy of the present invention compared with the prior art are: Because the present invention has only 0 continuation pages (when the description page of the invention is insufficient, please note and use the continuation page) 1221521 Description of the invention (14) It needs to be checked regularly by the OR P testing instrument氧化 The redox potential in the water before electrolysis and after electrolysis is re-entered into the microcomputer (cpu), and the upper and lower limits can be compared, so only routine maintenance and repair work is required, and it will not cause Increased maintenance costs. [Embodiment] In order to make it easy for people who are familiar with this technology to understand the system method of the present invention and the functional benefits that can be achieved, a specific embodiment will be enumerated, and it will be described in detail in conjunction with the drawings as follows: The electrolyzed water redox potential positioning system and its constant output method for correction and compensation 'Please refer to FIG. 8 for a schematic diagram of a control block of the present invention. The main reason is that the circuit is composed of a microcomputer C pu χ, c P U2 (1 0), (2 0), a detection element (3 0), a main control circuit (4 0), and a control system (50). Among them: Microcomputer CPU i (1 0), you can enter experimental data (as shown in the first two, three, four, five, six, and seven: the electrolysis time, water flow rate, electrolysis current (current density), Electrolyte type (anion and cation distribution ratio and concentration) and experimental data coordinate graph of redox potential) and calculation formula 'The microcomputer CPU 1 (10) has calculation, comparison, and signal input and output functions; the calculation formula is: ORP (display value) = ORP (L) + [A (x) — Att)] X [〇R Ρ (Η)-0 RP (L) / A ⑻-A (L)] Microcomputer CP U2 (2 0) As the main control circuit (4 0) [contains acid test control (4 1), segment control (4 2), electrolytic control (4 3)) 0 Continued pages (when the invention description page is insufficient, use 谞 note and use Continued) 1221521 Invention description (15), current detection (4 4), voltage compensation (4 5)] processing; detection element (3 0), including flow meter (3 1) , Shunt resistance (3 2), etc .; among them: the flow meter (3 1) is mainly used to detect the water flow velocity of the electrolytic cell, and the signal of the flow rate will also be transmitted to the database of the microcomputer CPU i (1 0) by manual Or automatic constant water volume control (31 1) for constant control of water inlet flow rate and electrolysis time; the electrolytic solution is electrolyzed by the ORP testing instrument to determine its redox potential, and the measured data is microcomputer CP U1 (1 0) database comparison for upper and lower limit correction; please refer to the ninth figure: it is a schematic diagram of the control circuit of the present invention. The shunt resistor (3 2) is mainly installed in the electrolytic cell, and then the voltage tuning and lifting circuit and constant current of the main control circuit (40) are driven by the current detection comparison circuit (4 4) and the voltage compensation comparison circuit (4 5). The gate driver of the control (4 6) regulates the voltage. When the electrolytic cell is equipped with manual or automatic constant water volume control (311), please refer to Figure 10: it is a schematic diagram of the shunt resistor circuit when the water inlet flow rate of the present invention is fixed. Among them: v: is the working voltage of actual electrolysis. 1: is the total current actually flowing through the electrolytic cell. R: is the actual resistance of the electrolytic cell (it is a variable resistance, for example, the internal resistance increases when the electrolytic cell accumulates calcium, or when the internal resistance of the electrolytic cell increases or decreases due to different concentrations of the electric species ^) , High concentration, conductivity @continued page (When the description page of the invention is insufficient, please note and use the continuation page) 1221521 Description of the invention Cl 6) Increase, the internal resistance decreases, otherwise the concentration is low, the conductivity decreases, and the internal resistance increases) 〇

Ri、R2 :為串接於電解槽之分流電阻。 由於: I = I i + 12Ri, R2: shunt resistors connected in series to the electrolytic cell. Because: I = I i + 12

Vi= I iXRi= V2= 12XR2 當電阻R增加時(表示電解槽内阻增加),總電流I 減少(表示電解電流減少);相對使分流電阻(3 3 )中 之11及12均減少。 因為Ri及R2為固定電阻,所以當I減少時,V亦 相對減少,由於V1= I V2= 12XR2 ;所以可 以藉由Vi的變化,偵測出總電流j的變化,此時再經由 電流偵測比較電路(4 4 )及電壓補償比較電路(4 5) ’驅使主控電路(4 〇)的電壓調諧昇降電路與定電流控 制(4 6)的閘極驅動器調變實際電解之工作電壓,由於 Ri與R2為固定電阻,即可使I恢復原設定值,因此也可 使Ιι及Is恒定,相對使%恒定。 由1"^^ 12之關係式,當Ii及12恒定時,I亦 恒定。 當電解槽沒有裝設手動或自動定水量控制(311) 時’敬睛參閱第十一圖所示:係本發明進水流速不固定_ 之分流電阻電路示意圖。其中:上式說明,主要是當電解 槽因為内在因素,所導致内阻增加或減少時之電流變化情 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 1221521 發明說明(17 ) 形,伹是當電解槽因為外在因素,如進水流迷改變時,則 由流量計(31)將所偵測到的進水流速,其大小變化的 訊號傳遞至微電腦C p u 1 (1〇)的資料庠中,經演算 比對之後,由主控電路的比較電路自動調昇或調降電壓: 即在進水流速變慢(電解時間增長)時,自動調降工作電 壓,在進水流速變快(電解時間縮短)時,自動調昇工作 電壓,故流經電解槽之實際電流應為Ι + ίχ,而實際工 作電壓應為V +Vx。 $ 主控電路(4 0)的電壓調諧昇降電路可為一交換式 電源麵ϋ,或為-高賴振麵㈣路,由微電滕c p U2 ( 2 0 )控制’作增加或減少電壓,藉以昇高或降低電 流,使電流I恒定輸出; 一 一 操控系統(5 0 ),至少包括段位選擇(5 j )、〇R P顯示(52)。 藉由上述各元件組成之本發明,係在提供一種電解水 氧化還原電位定位系統及其校正補償恒定輸出方法,在實 際應用上’例如: 使用者如果取用倾的還原水時,可以將還原水的還 原電位設定在介於-2 〇 〇mv(毫伏)至_4⑽财(毫伏 )的標準範圍之内。 如果使用者取用殺菌的氧化水時,可以將氧化水的氧 化電位設定在介於+ 9 6 Omv (毫伏)至+丄2 (毫伏)的標準範圍之内。 0續次頁(發明說明頁不敷使用時記並使用顢) 1221521 發明說明(18 ) 綜合上述所陳之本發明係在提供一種電解水氧化還原 電位疋位乐統及其校正補償恒定輸出方法,經過本發明人 實際製做完成以及反覆操作測試之後,證實的確可以達到 本發明所預期的功能效益,同時又為目前坊間尚無見聞之 1首先創作」,具有!產業上的利用價值」,誠然已經符 合發明專利1實用性」與「進步性」之成立要義,爱依專 利法之規定向鈞局提出發明專利之申請。 【圖式簡單說明】 第一圖·係電解時間與電解水氧化還原電位之實驗數據 座標圖。 第二圖:係進水流速與電解水氧化還原電位之實驗數據 座標圖。 第三圖:係電解電流(電流密度)與電解水氧化還原電 位之實驗數據座標圖。 第四圖:係電解質種類(陰陽離子分佈比例)與電解水 乳化還原電位之實驗數據座標圖。 第五圖:係電解質種類(陰陽離子濃度)與電解水氧化 還原電位之實驗數據座標圖。 第六圖:係電解時間與電解質種類條件固定之下,電解 電流(電流密度)與電解水氧化還原電位之實 驗數據座標圖。 第七圖:係實際電解液之氧化還原電位作上、下限校正 之實驗數據座標圖。 0續次頁(發明說明頁不敷使®時’請註記並使用親g)Vi = I iXRi = V2 = 12XR2 When the resistance R is increased (indicating that the internal resistance of the electrolytic cell is increased), the total current I is decreased (indicating that the electrolytic current is decreased); relative to 11 and 12 of the shunt resistance (3 3) are both reduced. Because Ri and R2 are fixed resistors, when I decreases, V also decreases relatively. Because V1 = I V2 = 12XR2; therefore, the change in total current j can be detected by the change in Vi, and then the current detection The test comparison circuit (4 4) and the voltage compensation comparison circuit (4 5) 'drive the voltage tuning and lifting circuit of the main control circuit (4 0) and the gate driver of the constant current control (4 6) to adjust the actual electrolytic working voltage, Since Ri and R2 are fixed resistors, I can restore I to the original set value, so Im and Is can also be kept constant, and relative% can be kept constant. From the relationship of 1 " ^^ 12, when Ii and 12 are constant, I is also constant. When the electrolyzer is not equipped with manual or automatic constant water volume control (311), please refer to Figure 11 carefully: it is a schematic diagram of the shunt resistor circuit of the present invention where the inlet water flow rate is not fixed. Among them: The above formula description is mainly the current change when the internal resistance of the electrolytic cell increases or decreases due to internal factors. 0 Continued page (When the description page of the invention is insufficient, please note and use the continued page) 1221521 Description of the invention The shape of (17) is that when the electrolytic cell is changed due to external factors, such as the water inlet fan, the flowmeter (31) transmits the detected signal of the water inlet flow rate and its size to the microcomputer C pu 1 In the data of (10), after the calculation and comparison, the comparison circuit of the main control circuit automatically raises or lowers the voltage: that is, when the water inlet flow rate becomes slower (the electrolysis time increases), the working voltage is automatically reduced. When the water flow rate becomes faster (the electrolysis time is shortened), the operating voltage is automatically increased, so the actual current flowing through the electrolytic cell should be Ι + ίχ, and the actual operating voltage should be V + Vx. The voltage tuning and lifting circuit of the main control circuit (40) can be a switching power supply circuit or a Gao Lai vibration circuit, which is controlled by the micro-electric Teng U2 (2 0) to increase or decrease the voltage. By increasing or decreasing the current, the current I is constantly output; the control system (50) includes at least a segment selection (5j) and an ORP display (52). The invention composed of the above elements is to provide an electrolyzed water redox potential positioning system and a constant output method for correction and compensation. In practical applications, for example, if a user uses poured reduced water, he can restore the reduced water. The reduction potential of water is set within a standard range of -200 mv (millivolts) to -4 millivolts (millivolts). If the user takes sterilized oxidized water, the oxidation potential of the oxidized water can be set within the standard range of + 9 6 Omv (millivolt) to + 丄 2 (millivolt). 0 Continued pages (Inventory description pages are not enough when used and recorded and used) 215 1221521 Invention description (18) In summary, the present invention is to provide an electrolytic water redox potential system and its constant compensation compensation output method After the inventor's actual production and repeated operation tests, it is confirmed that the expected functional benefits of the present invention can be achieved, and at the same time, it is the first to be created for the first time that has not been heard in the world. "Utilization value in industry", of course, has already complied with the founding principles of "Practicalness of Invention Patent 1" and "Progressiveness", and loved to file an application for an invention patent with the Bureau in accordance with the provisions of the Patent Law. [Schematic description] The first graph is the experimental data of electrolysis time and redox potential of electrolyzed water. The second figure: the experimental data of the inlet water flow rate and the redox potential of the electrolyzed water. The third graph: is the experimental data coordinate graph of electrolytic current (current density) and electrolytic water redox potential. Figure 4: Coordinate graph of experimental data of electrolyte types (anion and cation distribution ratio) and emulsification reduction potential of electrolyzed water. Fifth graph: Coordinate graph of experimental data of electrolyte type (anion and cation concentration) and redox potential of electrolyzed water. Figure 6: Coordinate graph of experimental data of electrolysis current (current density) and redox potential of electrolyzed water under constant conditions of electrolysis time and electrolyte type. The seventh graph: the experimental data coordinate graph of the upper and lower limits of the redox potential of the actual electrolyte. 0 Continued pages (When the invention description page is insufficient, please note and use pro-g)

Claims (1)

12215211221521 申請專利範圍 1 . 一種電解水氧化還原電位定位系統及其校正補償 恒定輪出方法,該定位系統包括微電腦、偵測元件、主控 電路、操控系統,主要係將電解水氧化還原電位與電解時 間(進水流速)、電解電流(電流密度)、電解質種類(陰 陽離子分佈比例及濃度)之實驗數據、座標參數與演算式 ,貯存於微電腦資料庫中,並利用偵測元件所偵測之實際 數據,由微電腦演算,將液晶顯示值與實際電解液之氧化 還原電位比對,並加以校正,再根據實際顯示值,取其氧 化還原電位之理想區段,再根據該理想區段之相對電流密 度乍分段控制,藉以取得氧化還原電位之段位選擇,同 時藉由檢知電路偵測電解槽内阻之變化,經比較電路調變 電壓,精確控制電解槽之電流密度,並使其氧化還原電位 恒定輸出。 2如申响專利範圍第1項所述之一種電解水氧化還 原電位粒祕及其校正婦恒定輸A方法,其中偵測元 件係在電解槽設置分流電阻,由電流_比較電路及電壓 補償比較電路,驅使主控電路的電廢調諧昇降電路與定雷 流控制的閘極驅動器調變電壓。 办〜3 :如申請專利範圍第1項所述之電解水氧化還原電 疋立祕及其校正纖恒定輸出方法 括段位選擇與〇RP (氧化還原電位)顯示。呆控系統已 位定=糸專利範圍第1項所述之電解水氧化還原電 ’、,、、/、权正補償恒定輸出方法,其中該理相區段 原ϊί電流密度,亦可作無段控制,以取得相對之i化還Patent application scope 1. An electrolyzed water redox potential positioning system and a method for correcting and compensating constant rotation. The positioning system includes a microcomputer, a detection element, a main control circuit, and a control system. (Inlet water flow rate), electrolytic current (current density), electrolyte type (anion and cation distribution ratio and concentration) experimental data, coordinate parameters and calculation formulas are stored in the microcomputer database, and the actual detected by the detection element is used The data is calculated by a microcomputer, the liquid crystal display value is compared with the redox potential of the actual electrolyte, and corrected. Then, based on the actual displayed value, the ideal segment of the redox potential is taken, and then the relative current of the ideal segment is taken. Density control in stages to select the stage of the redox potential. At the same time, the detection circuit detects the change in the internal resistance of the electrolytic cell. The voltage is adjusted by the comparison circuit to precisely control the current density of the electrolytic cell and make it redox. Constant potential output. 2 As described in item 1 of Shenxiang's patent scope, a method of electrolyzed water redox potential particles and a method for correcting a constant output A, wherein the detection element is provided with a shunt resistor in the electrolytic cell, and is compared by a current_comparison circuit and a voltage compensation. The circuit drives the electrical waste tuning and lifting circuit of the main control circuit and the gate driver of the fixed lightning current control to regulate the voltage. Office ~ 3: The method of constant output of electrolyzed water redox battery and its correction fiber as described in item 1 of the scope of patent application, including segment selection and 0RP (redox potential) display. The control system has been set = the electrolyzed water redox power described in the first item of the patent scope, the constant output method of the right compensation, where the current density of the physical phase section can also be used as a stepless Control to obtain relative
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Publication number Priority date Publication date Assignee Title
US8419926B2 (en) 2007-09-19 2013-04-16 Honda Motor Co., Ltd. Electrolyzed water producing method and apparatus

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8419926B2 (en) 2007-09-19 2013-04-16 Honda Motor Co., Ltd. Electrolyzed water producing method and apparatus

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