TW591076B - Epoxy resin of electromagnetic interference suppression and manufacturing method thereof and an inductor applied in the electromagnetic interference suppression - Google Patents

Epoxy resin of electromagnetic interference suppression and manufacturing method thereof and an inductor applied in the electromagnetic interference suppression Download PDF

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TW591076B
TW591076B TW92105146A TW92105146A TW591076B TW 591076 B TW591076 B TW 591076B TW 92105146 A TW92105146 A TW 92105146A TW 92105146 A TW92105146 A TW 92105146A TW 591076 B TW591076 B TW 591076B
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epoxy
electromagnetic interference
ferrite
epoxy resin
emi
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TW92105146A
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Chinese (zh)
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TW200401001A (en
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Chaby Hsu
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Abc Taiwan Electronics Corp
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Abstract

According to the prevent invention, the components of the inductor include a ferrite and an epoxy. The sintered powder of the ferrite is mortared, and is added with the epoxy which functions as the binder. The initial permeability of the ferrite is greater than 250 (mui > 250), and the diameter of the powder of the ferrite is smaller than 0.35 (phi < 0.35). Thus, the fine powder will entirely shield the electromagnetic waves to prevent the electromagnetic interference. The epoxy includes two parts, that is, bisphenol A and epichlorohydrin to make the universal epoxy having an epoxy equivalent weight (EEW) ranged between 185 and 195. The hardener adopts the modified amine whose amine value is 170 ± 20. In such a manner, the epoxy and the hardener are added into the powder of the ferrite the mixture is stirred evenly, thereby making the EMI epoxy resin that can prevent electromagnetic interference. An epoxy resin of electromagnetic interference (EMI) suppression includes a ferrite and an epoxy. The EMI epoxy resin can be hardened quickly, has great resistance to heat and has great resistance to acid and alkaline. Thus, the EMI epoxy resin can be directly coated on the high frequency response member of the communication equipment to prevent interference of noise in the air addition, the EMI epoxy resin can be applied on package the inductor to enhance the feature of the inductor, that the inductance of the inductor can be enhanced by least two times.

Description

591076 五、發明說明(1) 發明所屬之技術領域 本發明屬防止電磁干擾材料技術領域,特別係有關以 鐵氧磁體材料(F e r r i t e )添加環氧樹脂(Ε ρ ο X y )來製備具有 防止電磁干擾之膠體,其製程及應用於電感元件。/、 【先前技術】 隨著電子產品的小型化及高速運算電子元件的需求增 加,對於電磁波干擾(EMI,Electgr〇magnetic591076 V. Description of the invention (1) The technical field of the invention The invention belongs to the technical field of electromagnetic interference prevention materials, and particularly relates to the preparation of ferrite magnet materials (Ferrite) and epoxy resin (E ρ ο X y) to prevent Electromagnetic interference colloid, its manufacturing process and its application to inductive components. /, [Previous technology] With the miniaturization of electronic products and the increase in demand for high-speed computing electronic components, electromagnetic interference (EMI, Electromagnetic)

Interference)、無線電波干擾(RFI,Radi〇 Fre叫⑽”Interference), radio wave interference (RFI, Radio Fre called)

Interference)及靜電放電(ESD,Electrostatic ,防護也曰益重要。小型化、高密度化的電子 :磁波遮蔽及靜電防護處理,並且電子元件在製;要^丁 二Ϊ輸:Ϊ終產品使用均需要靜電防護材料,以防止各 靜I電壓,-旦超過電子元件可忍受程 的絕緣常運作。一般高分子材料是良好 分子表:產:通常均大於1012Q/cm2 ’極易在高 質(如:生電何聚集。因此,直接在高分子中做導電改 黑、全屬=111 ne等)或添加導電性填充劑(如:導電碳 聚集或二電齊U可^ 之電阻需求,及常 電性冋刀子之用途,依照不同 -為抗靜電材料,常區分’主要包括四部份:第 常用在包裝材料或摔作工^t料、。第二為ESD防護,通 應用在電子次却、,、乍具。第二為EMI/RFI遮蔽,主要 貝°及通矾產品之外殼,也可以應用再高壓電 591076Interference) and electrostatic discharge (ESD, Electrostatic, protection is also very important. Miniaturization and high density of electrons: magnetic wave shielding and electrostatic protection treatment, and electronic components are in production; it is necessary to ensure that the final product is used uniformly. Electrostatic protection materials are needed to prevent the static I voltage.-Once the insulation of electronic components can withstand the process, the general polymer materials are good molecular tables: production: usually greater than 1012Q / cm2 'easy in high quality (such as : How to gather electricity. Therefore, do conductive modification to black directly in the polymer, all belong to 111 ne, etc.) or add conductive fillers (such as conductive carbon accumulation or the resistance requirements of the two electric devices, and often The use of electric trowels is based on different-as antistatic materials, often divided into 'mainly includes four parts: the first commonly used in packaging materials or falling materials ^ t materials. The second is ESD protection, commonly used in electronic secondary The second is the shielding of EMI / RFI. The main shells of shells and aluminum products can also be applied with high voltage 591076.

時的静電防護。第四為導電接著部分,主要應用再 漆、銀膠及異方向性導電壓。 ” 隨著全球電子科技應用持續不斷的改進, 之革新繼續扮演當中一個不可或缺的角色,而鐵氧斗 為電感器、濾波器及電磁干擾濾波器等電子裝置之核…, 伤市場上對鐵氧體材料的導磁率及操作頻率要求日P 格。 q趨嚴 【發明内容】ESD protection. The fourth is the conductive bonding part, which is mainly used for repainting, silver glue and anisotropic conductive voltage. With the continuous improvement of global electronic technology applications, innovation continues to play an indispensable role, and ferrite buckets are the core of electronic devices such as inductors, filters and electromagnetic interference filters ... The magnetic permeability and operating frequency of ferrite materials require P grids per day.

Ik著電子產品的發展走向短、小、輕、薄的設 有的主動兀件與被動元件都必須配合製作成小尺 所 ,的電子元件。本發明係針對電感元件之開發所做的^ 二,f :件材料主就是鐵氧磁•,而鐵氧磁體的材 感::ΐ止電磁干擾的功能。若有-種膠體可以將】 ::。:電益特性提ί ’是目前全世界電感廠商所研笋的 ^ 本發明即以鐵氧磁體(F e r r i t e)材料製作且χ 、 ^磁干擾(EMI)功能之環氧樹脂(Ep〇xy)膠,以&amp; =止 ^ i i ί (Ferle)V/ &quot;//Λ }; ^ ^ ^ t . 凌用膠體材料是最佳的考量。理論上乳糾知做成的封 件添加EM丨膠可以將電残值提; 閉磁路電感元 的其他特性針對元件 因子Q value、標準差Tolerance)進行改善γ *IDC、品質 本發明主要成分包括有鐵氧磁體及環。氧樹脂,其係利 591076Ik's development of electronic products is to make short, small, light, and thin active components and passive components must be made into small electronic components. The present invention is directed to the development of inductive elements. Second, f: The material of the piece is mainly ferrite magnet, and the material of the ferrite magnet is: to prevent electromagnetic interference. If there is-a kind of colloid can be]: ::. : The electrical properties are improved. This is the current research of inductor manufacturers all over the world. ^ The present invention is an epoxy resin (EpOxy) made of ferrite material and χ, ^ magnetic interference (EMI) function. Glue with & = 止 ^ ii (Ferle) V / &quot; // Λ}; ^ ^ ^ t. The colloidal material for ling is the best consideration. Theoretically, the seal made of milk can be added with EM glue to improve the electrical residual value; other characteristics of the closed magnetic circuit inductor are improved for the element factor Q value and standard deviation Tolerance) * IDC, quality The main components of the present invention include There are ferrite magnets and rings. Oxygen resin

用已經燒結完成的鐵氧 化,之後添加少許==經過研磨過程將粉末細緻 的初導磁率在2 50以二:月;=黏結劑’該鐵氧磁體材料 〇·35 以下(0&lt;〇 35( \&gt;25λ〇),鐵氧磁體粉末粒徑在 產生電磁干擾的電』二::·即可藉由粉末的… 型環氧樹浐rAr 2rohydrin)作為原料,製成的泛用 性胺 的劑和硬化劑添加入鐵氧磁體粉末中均 :2 0製乍成加溫快速硬化、耐熱性佳、耐酸鹼性 佳具有防止電磁波干擾的環氧樹脂膠體。 再者,電感元件中若以一個相同尺寸及單位電感值的 與閉磁路線圈比較,閉磁路線圈的電感值會比 開磁路線圈南,Q值也會比較好,但是耐電流值會較低一 2。若單獨以-個有遮閉(shielded)的閉磁路電感元件而 吕,在製作上會有以下的技術考量:Oxidation with sintered iron, and then adding a little == After the grinding process, the fine initial magnetic permeability of the powder is between 2 and 50: two months; = Binder 'The ferrite magnet material is less than 0.35 (0 &lt; 〇35 ( \ &gt; 25λ〇), the particle size of the ferrite magnet powder is generating electromagnetic interference. "Second :: · can be made of powdered ... type epoxy tree (rAr 2rohydrin) as a raw material, made of universal amine Additives and hardeners are added to the ferrite magnet powder: 20 made of Cheng Cheng, rapid curing, warming, good heat resistance, good acid and alkali resistance, epoxy resin colloids to prevent electromagnetic interference. In addition, if the inductance element is compared with the closed magnetic circuit coil with a same size and unit inductance value, the closed magnetic circuit coil will have a higher inductance value than the open magnetic circuit coil south, and the Q value will be better, but the withstand current value will be lower. minus 2. If a single shielded magnetic circuit inductance element is used, the following technical considerations will be made in the production:

1.鼓型鐵芯(DR core)必須盡可能的在環型鐵芯(RI % cor e)中央。 2 ·繞線要求平坦化。 3 ·元件組裝力求整體密閉。 但是,若使用本發明之環氧樹脂膠體填充於鼓型鐵芯 (DR core)與環型鐵芯(RI core)中央,以上問題的要求 將可大幅不降。因為環氧樹脂勝體的鐵氧磁體材料已經1. The drum core (DR core) must be in the center of the ring core (RI% cor e) as much as possible. 2 · The winding is required to be flat. 3 · Component assembly strives to be hermetically sealed. However, if the epoxy resin colloid of the present invention is used to fill the center of a DR core and a RI core, the requirements of the above problems can be greatly reduced. Because the ferrite magnet material of the epoxy resin has been

591076 五、發明說明(6) 【實施方式】 本發明之「鐵氧磁體與環氧樹脂的防電磁干擾膠體」 製備,以實施例方式說明如下: 1.配製&quot;i = 700的鐵氧磁體粉末。Fe2〇3 = 327.7g、Ni0 二 32.7g、ZnO = l〇8.5g、CuO 二 34.5g。放入球磨罐中 (内含lKg 0二1〇氧化鍅球)加水40 0 ml及分散劑BYK-111 —2 g。球磨混合2 hrs。 2 ·將上述混合均勻的漿料以1 2 〇 °C烘乾。591076 V. Description of the invention (6) [Embodiment] The "anti-electromagnetic interference colloid of ferrite magnets and epoxy resins" of the present invention is prepared, which is described by way of example as follows: 1. Preparation &quot; i = 700 ferrite magnet powder. Fe2O3 = 327.7g, Ni0 2 32.7g, ZnO = 108.5g, CuO 2 34.5g. Put it in a ball mill tank (containing 1Kg 0-20 osmium oxide ball), add 40 0 ml of water and BYK-111 — 2 g of dispersant. Ball milled for 2 hrs. 2 · Dry the above mixed slurry at 120 ° C.

3·烘乾後的粉塊以篩網(mash = 80)粉碎,之後以9 0 0 °C3. The dried powder is crushed with a sieve (mash = 80), and then crushed at 90 ° C.

燒結3 hrs。即得到具有防止電磁干擾功能的鐵氧磁體粉 末〇 4 ·燒結完成的鐵氧磁體粉末具有磁性,之後放入内含 0 30 : 4 1〇 : 0 3 = 2 : 3 : 5氧化鍅球的球磨罐中,設定低速 2 5 rpm研磨1 8小時。粉末粒徑&lt;〇 . 3 5 // m。 5·將細微化的鐵氧磁體粉末烘乾後,用細篩網2〇〇 粉碎。 :_取環氧樹脂主劑=1〇 g、硬化劑 6.配製鐵氧 Epoxy Resin .…,…叫丄用一丄υ g 、硬化劑 = (主劑:硬化劑=1 〇 〇 : 1 6〜2 ]、、日人i组uSintered for 3 hrs. That is, a ferrite magnet powder having a function of preventing electromagnetic interference is obtained. 4 The sintered ferrite magnet powder has magnetic properties, and is then put into a ball mill containing 0 30: 4 1: 0: 0 3 = 2: 3: 5 Grind in a jar at a low speed of 25 rpm for 18 hours. Particle size &lt; 0.3 5 // m. 5. Dry the fine ferrite magnet powder and crush it with a fine sieve 200. : _ Take the epoxy resin main agent = 10 g, hardening agent 6. Formulate ferrite Epoxy Resin ..., ... called 丄 用 一 丄 υ g, hardening agent = (main agent: hardening agent = 1 〇〇: 1 6 ~ 2] ,, Japanese i group u

i0 “ )混合攪拌均勻,之德3 Fernte = 108g及分散劑Βγκ —n 々俊力 ^ . 火士曰1Λ J八111 = 1§。混合攪拌均i0 ") Mix and stir well, the quality of 3 Fernte = 108g and dispersant Bγκ —n 々 Junli ^. Huo Shi said 1 Λ J eight 111 = 1§.

即可。Epoxy添加ΐ:ΐ〇〜15% J 註 釋 :EMI Epoxy resin 黏度若 太高可以加入少許甲苯稀 以 下試驗設計分別針對現 有市售的三 種不同電感元件Just fine. Epoxy added ΐ: ΐ〇 ~ 15% J Note: EMI Epoxy resin can be added with a little toluene if the viscosity is too high. The following test design is for three different inductor components on the market.

591076 發明說明(9) 請參閱第十圖 請參閱第十一圖 請參閱第十二圖 RH 0910系列 SH 5028系列 S S 0 6 0 3系列 結論 : 2路與閉磁路的電感值提昇的比較 小對U芯DR C〇re上下擺與環型鐵芯RI core間隙大 小對所靖真正閉磁路的探討 際電;t Γ f與環氧樹脂的防電磁干擾膠體(A)對實 I不电U 7L件早位電感值的提昇 就RH 0910系列而古,闵焱严⑴ 县朔臌予丄/ 因為裱型鐵芯RI core的設計 疋以塑膠電木為外殼,琴 闲朴w a u w °亥几件不具有磁遮蔽的功能。若利 用針同注射將鐵氧磁體盥璟董 ^八脾植綠&amp; * ,、衣乳树月日的防電磁干擾膠體(A) ΐ:Ι: :那!該元件就是-個具有磁遮蔽的 r、:閉磁踗二:ί門發現早就開磁路與閉磁路的電感值比 車乂’閉磁路的電感值提昇2倍。 接下來我們利用上沭二德丁 m ^ L 逑一種不同糸列的產品作鼓型鐵芯 DR core 上下擺盥環形锚τ 土執。 # ώ l田鐵心RI Core壁面間距大小對直正 磁遮敝效果的比較。RH系列的^ … 型鐵芯RI core完全接觸,s 鐵,剔⑶『6與塑膠環 ’ 糸列有一點點間 列的間隙最大。由原本以—般環氧樹脂 磁 遮蔽電感對具有ΕΜΙ工力能㈣氧樹脂 /電的磁 的提昇做比較。 P ^ ^ j衣^感值 由第十三圖可以發現,盾士日日 …τ 原本開磁路電感元件封萝产荆 鐵芯RI core變成閉磁路電感,其表J衣型 、电饮值的誕歼隨間隙的591076 Description of the invention (9) Please refer to the tenth figure Please refer to the eleventh figure Please refer to the twelfth figure RH 0910 series SH 5028 series SS 0 6 0 3 series U core DR C〇re the gap between the hem and the ring-shaped iron core RI core to discuss the true closed magnetic circuit; t Γ f and epoxy anti-electromagnetic interference colloid (A) is not electric U 7L The improvement of the early inductance value is as old as the RH 0910 series. Min 焱 Yan⑴ County Shuoyu 臌 / Because of the design of the framed iron core RI core 疋 The plastic bakelite is used as the shell, and the piano is wauw ° With magnetic shielding function. If you use a needle to inject the ferrite magnet, ^ eight spleen plant green &amp; *, anti-electromagnetic interference colloid (A) 乳: Ι:: that! This component is a magnetically shielded r :: closed magnetic field. Second: the gate finds that the inductance value of the open magnetic circuit and the closed magnetic circuit has been increased by 2 times compared to the inductance value of the car's closed magnetic circuit. Next, we use a different type of m m L 沭 德 德 L L 作 products as a drum core DR core hem ring anchor τ soil anchor. # FREE l Tian Tiexin's RI Core wall-to-wall distance comparison of straight magnetic shielding effect. ^ Series of RH series RI cores are completely in contact with each other, s iron, and there is a small gap between the rows of "6 and plastic rings". From the original magnetic shield of ordinary epoxy resin, the magnetic enhancement of the epoxy resin / electricity with EMI working force is compared. From the thirteenth figure, it can be found that the sense value of P ^^^ is shown in Figure 13. The shield ri ... τ originally opened the magnetic circuit inductance element Feng Luo Jingjing iron core RI core into a closed magnetic circuit inductance, its table J-shaped, electric drink value Gap-following

591076591076

五、發明說明(10) 增加而大幅下降。在填充鐵氧磁體與環氧樹脂的防電磁干 擾膠體(EMI epoxy resin)後的狀況也是一樣,間隙越大 電感值提昇越小。當然電感值所提昇的倍率只是一種現 象,若要詳細探討必須考慮環型鐵芯RI c〇re的單位電感 值0 我們已經知迢在電感元件中封填鐵氧磁體與環氧樹浐 的防電磁干擾膠體(EMI epoxy resin)對元件的電感值提 昇有所幫助三之後就可以從事以下的後續研究開發。 1. 製作超南電感值的小尺寸特殊品電减元件 2. 在一定的電感值要求下,藉由更f文的線徑來提 昇元件的RDC、IDC特性 尺仕木徒 3. 產品的正負標準差(丁〇lerance)太大,可以藉由 較低單位電感的鼓型鐵芯DR c〇re,將T〇lerance下 (理論上磁性材料的單位感值越大初導磁 論,:項相當矛盾的電場與磁場搭“理 受到場較大)’那麼相對的電場將會 比環型鐵^ 型鐵芯c〇r^單位電感值會 磁二位電感值小0.3倍左右。若以鐵氧 re—作為Μ Λ 以上(&quot;1&gt;25G)所製作_ 以上。故需要以鐵氧磁體的初導磁率在:;值下降二A 改善電感器特性的材料。…在8以下““8”乍為V. Description of the invention (10) Increased and decreased significantly. The situation is the same after filling the EMI epoxy resin with ferrite magnet and epoxy resin. The larger the gap, the smaller the inductance value increases. Of course, the increase rate of the inductance value is only a phenomenon. In order to discuss in detail, the unit inductance value of the ring-shaped iron core RI core must be considered. We have already known that the prevention of the ferrite magnet and epoxy resin in the inductor element Electromagnetic interference gel (EMI epoxy resin) is helpful to increase the inductance value of the component. After three, you can engage in the following research and development. 1. Manufacture special small-size electric reduction components with super-South inductance value 2. Under certain inductance value requirements, the RDC and IDC characteristics of the components are improved by more f wire diameter. 3. Product positive and negative The standard deviation is too large, you can use the drum core DR core with a lower unit inductance to reduce the Tolerance (theoretically, the greater the unit inductance of a magnetic material is, The rather contradictory electric field and magnetic field are "reached by the larger field", then the relative electric field will be about 0.3 times smaller than the toroidal iron core core C0r ^ unit inductance value. Oxygen re-made as above Μ Λ (&quot; 1 &gt; 25G) or above. Therefore, it is necessary to use the ferrite magnet ’s initial magnetic permeability at :; the value decreases by two A to improve the characteristics of the inductor.… Below 8 " At first

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Claims (1)

591076 _案號 92105146_年月日__ 六、申請專利範圍 , 脂的防電磁干擾膠體者。 5. —種「防止電磁干擾之開磁路電感元件—,主要包 括有E字型圓型鐵芯(E type ring core)、表面黏著磁珠 (Surface mount base type core)及線包,其特徵在 於:該E字型圓型鐵芯與表面黏著磁銖鐵芯之間及線包的 局部表面具有主成分為鐵氧磁體與環氧樹脂的防電磁干擾 膠體者。 6. —種「防止電磁干擾之電感元件^ ,該電感元件線· 包表面具有一層主成分為鐵氧磁體與環氧樹脂的防電磁干 擾膠體者。591076 _Case No. 92105146_year month__ Sixth, the scope of the patent application, the anti-electromagnetic interference colloid of grease. 5. —A kind of "open magnetic circuit inductance element to prevent electromagnetic interference", which mainly includes E-shaped round core (E type ring core), Surface mount base type core (core bead) and wire package, its characteristics The reason is that the E-shaped round iron core and the surface adhered with the magnetic baht iron core and a part of the surface of the wire package have anti-electromagnetic interference colloids whose main components are ferrite magnets and epoxy resins. Interference inductive element ^, the surface of the inductive element line has a layer of anti-electromagnetic interference colloid whose main components are ferrite magnet and epoxy resin. 第18頁 2003. 12. 15.020Page 18 2003. 12. 15.020
TW92105146A 2003-03-05 2003-03-05 Epoxy resin of electromagnetic interference suppression and manufacturing method thereof and an inductor applied in the electromagnetic interference suppression TW591076B (en)

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