TW588094B - Solid pigment composition - Google Patents

Solid pigment composition Download PDF

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Publication number
TW588094B
TW588094B TW88103301A TW88103301A TW588094B TW 588094 B TW588094 B TW 588094B TW 88103301 A TW88103301 A TW 88103301A TW 88103301 A TW88103301 A TW 88103301A TW 588094 B TW588094 B TW 588094B
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TW
Taiwan
Prior art keywords
pigment
dispersion
parts
composition
coating film
Prior art date
Application number
TW88103301A
Other languages
Chinese (zh)
Inventor
Kenji Iwasaki
Ichiro Kawase
Shingo Araki
Haruo Murata
Original Assignee
Dainippon Ink & Chemicals
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Priority to TW88103301A priority Critical patent/TW588094B/en
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Publication of TW588094B publication Critical patent/TW588094B/en

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Abstract

The invention related to an esterify compounds which are the ordinary solvents using for a various uses, such as butyl acetate, oleyl acetate etc as for a fluidity modifier of the pigment dispersing medium. The pigment composition of the present invention comprising a pigments and an above esterify compounds as a token of an essential ingredient. The pigment which are dispersed by a solvents may be improved the pigment dispersion and the dispersing medium fluidity greatly. Using the pigment compounds or pigment dispersing medium for a color filter can be obtained a homogeneous coating film having a high contrast.

Description

588094 A7 B7 五、發明説明( 經濟部智慧財產局員工消費合作社印製 建多材之 於料具求等依 形化系的的膠 此少無 ,墨的散 散顏應要彼, 晶定脂液目, 蓋甚, 板油片分 分之膜則足理 結安樹散為質 C 上時 網刷色K料好塗片滿處 整徑用分等體 料際驟 裝印滤予 顔良之色欲種 調子散料性料 顔實步 塗板或物 使有成滤 K 各。由粒分顔艶顔 之且項 ,凹,成 易,形於是予用經使料之鮮, 能而多 車相墨組 容}所至。胞使,,顔切之脂 性價予 汽照油料 如性液,等料料驟後種適膜松 項高施 如,刷顏 例散散等性原顔步置各M塗性 多但而 例墨印此 。分分性視粗為化處對,良變 有不能 ,油等將 能好料候透之做料等,性改及。具料性 在刷墨於 性良顔耐高得可顔小集散,脂理之顏種 用印油關 種ί布高,獲則之大凝分澤松處述之多 使販用係 各系塗,度而者料狀、好光或劑上能予 可平刷尤 有劑或性比成化顔形長良的物理如性賦 於或印, 求溶,艶襯合料粗之成予膜生處有項需 關,墨物 要或性鲜高由顔於子之賦塗衍之少多如 有料噴成。 中系動高有於為關粒晶系善料等鮮有 , 係塗,組液 當脂流,具對成,次結劑改顔脂上具即 域明等墨料散景料樹的澤應,形上 1 止溶,行樹際,亦 領發罐油顔分背顔用液光膜求理體整防種性進用實為 。 術本,能等料術在散散高塗要處具調而各動而化惟由用 技材功料顔技 分分有其之此 ,,或流,囊 理使 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X 297公釐) 588094 A7 B7 五、發明説明(2 多顔 加用 會使 則上 時場 數現 次的 理際 處實 重在 加。 ,格 又價 ,的 本料 成顔 的高 劑提 理而 處, 加數 增次 會業 疑作 所。 從擇 係選 而加 ,逕 料牌 顔品 之種 價數 高之 而中 異料 優顔 能廉 性價 及的 慮系 考劑 不溶 常或 通系 旨 9 i J? 時樹 料用 下 如 明 逑 。 物 能成 性組 之料 求顔 需之 所術 料技 顔有 牲既 犧於 會關 少有 多對 料針 顔玆 之 , 廉中 價其 但 1 表 , 予 整施 調劑 的理 形處 晶上 結 Μ 料用 顔使 粗不 由而 經 , 使整 即調 ,之 驟小 步大 化或 料狀 顔形 於子 關粒 次 圍凝 範 , 用 長 適成 可的 其晶 但結 廉有 低生 很發 格易 價容 無則 雖糸 ,散 料分 顔於 理至 處 , 無限 之有 理為 處極 面則 印 之 般1 墨 油 刷 印 。 版 題活 WO 辟 , 等墨 良油 不刷 性印 動販 流平 的於 液對 散 , 分面 及方,一 S 0 料者 顔勻 在均 即之 ,徑 脂粒 松料 性顔 變及 或糸 脂晶 松结 之料 績顏 實持 有保 具為 ,做 等用 途中 用理 墨處 油之 刷化 動問 流用 的使 液在 散上 分性 料適 顔通 礙流 阻的 會好 劑良 理有 處求 等要 此於 於對 由有 ,摘 而指 然被 〇 而 多 , 為性 —.J r--1·裝-- (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 顔料 質顔 體善 •改 物有 成然 組 , 料果 顔效 之的 成劑 形量 所增 料為 原做 質純 體單 與持 。 料擔 題顔無 問機不 有有有 上由雖 題 料 有料 具原 Κ質 而體 > 於 mr:m 效又 等。 性多 動為 流者 的徵 液特 散等 分性 料艶 顏鮮 進高 促 , 或膜 性塗 散澤 分光 之高 硬示 膜顯 塗晶 求疲 要於 在用 摘使 指 ,。 被弱題 惟脆問 。 膜等 用塗度 使有比 所則襯 物時低 成等有 組途則 料用時 顔料用 種塗使 各業 Η 為 Η 色 廉的瀘 價度之 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) 588094 A7 B7 五、發明説明(3 ) 除顔料Μ外,添加顔料衍生物或染料之顔料組成物, 有關於顔料分散液,確有改良顔料分散性,促進结晶之 生長與抑制凝集及改善流動性效果,而頗難受到各種溶 劑之影響。又塗膜即Κ提高光澤,鲜艶性,透視性,櫬 比度等為多。更且,成本低廉亦為其一種特徵。具體之 例子為,特開昭63-172772號公報所記載之含有4’-二胺 基-1,1’-二憩醇醇-3,3 丨-二磺酸之 C· I· Pigment 177 顔料,特開平4-1 46968號公報所記載之含有鋦gfe菁磺酸 衍生物之鋦鈦菁顔料,特公昭41 -2466號公報所記載之 含有鹵化鋦酞菁硝酸顔料衍生物之鹵化銅fife菁顔料等。 惟隨著顔料衍生物或染料含量的增加,大多會降低塗膜 之耐光性,耐候性,耐熱性等,而在塗膜表面泄放顔料 衍生物或染料之現象。 再者近年Μ來進行多項之研究,膠囊化顔料對於分散 顔料組成物所形成分散液於顔料分散性,安定性,流動 性方面各有很高之評價。然而對於在產業領域中要求價廉 之顔料而言,其中尚涉及有高成本之問題。 更且,關於利用與本發明相關之羧酸酯系化合物的既 有技術,即有特開昭62-1 8406 3號公報所記載之由酯處 理而成之鉻酸的金屬鹽顔料組成物,藉Κ改良其熱安定 性,化學安定性,耐光堅牢度等。 其次,玆針對既有技術肓關顔料分散液的液體性狀Μ 及塗膜性狀改良詳述如下。 顔料分散液係由顔料組成物,樹脂,分散助劑,溶劑 -5 - 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X 297公釐) (請先閲讀背面之注意事項再填寫本頁) 衣·588094 A7 B7 V. Description of the invention (Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and printed on multiple materials, such as plastics and materials, etc., there is no glue, and the scattered appearance of ink should be the same. Liquid eye, cover is very much, the film of the oil sheet is enough to make the Jieanshu scattered as the quality C. The net brush color K material is good. The whole area of the smear is printed with graded material and filtered to Yan Liang's lust. This kind of toned bulk material is actually coated with a sheet or material to make it into a filter K. From the grains, the color of the face is condensed, concave, easy to form, so I use the fresh material to make it more colorful. The composition of the skin is as follows. The fat value of Yan Qie is given to the photo oil such as sex fluid, etc. After the material is applied, the appropriate film is loose and the item is high, such as brushing the powder and the powder. There are many sexes, but the examples are printed on the ink. The separation is regarded as the rough, the good change is not possible, the oil and other materials will be ready to be prepared, etc., and the sex is improved. Yan Nai is as high as possible, and the small collection is distributed. The oily seeds are printed with oil inks. They are widely used. They are described by Ze Song. They are used by various departments to paint. Or the agent can give a flat brush, especially the agent, or the physical appearance of the long-lasting physical appearance, such as sex, or imprinting, seeking to dissolve, and the thick lining material into the film. There is an issue with the film. Or the freshness is high by Yan Yuzi's Fu Tuyan. If there is material spraying, there are rare in the middle system, high quality materials for the granular crystal system, etc., the system coating, the fluid as the fat flow, with pairs, The secondary agent to change the color of the grease, which is the ink bokeh material tree such as Yuming, should be in the shape of 1 to dissolve, line the tree, and also receive a can of oil. The application of the nature is practical. The textbook can be used to adjust the material in the scattered high-coating areas, and it can only be changed by the use of technical materials, materials, and skills. (Please read the precautions on the back before filling out this page) This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 588094 A7 B7 V. Description of the invention (2 Multi-color plus use will make it up to date The current number of games is really increasing. The quality of the material is so high that it can be used to improve the appearance of the agent. The number of times increases the doubts of the industry. The brand price of the brand brand product is high, and the reason why the foreign material is superior and the energy is cheap is that the test agent is insoluble or the general purpose is 9 i J? When the tree material is used as brightly as it is. What you need to do is to sacrifice the color of the pin needles, which are cheap and moderate. Table 1 shows the crystals on the physical shape of the conditioning agent. Make the rough go through, make the whole adjustment, the small steps become large or the material appearance in the Ziguan grains around the condensing fan, with the crystals that are suitable for growth but have low growth and low prices are very expensive. Although Rong Wuzhe is stingy, the bulk material is divided into different places, and the rationality of infinity is printed on the extreme side. 1 Ink brush printing. The version of the title is WO, and the good oil does not brush, and the leveling of the liquid is scattered, the facet and the square, a S 0 material is evenly distributed, the diameter of the fat particles is loose, and or The properties of the fat crystal loose knots are solid, and they are used to protect the fluids in the ink, and the fluids are used to make the liquid look good and prevent the flow resistance. The good reason to find the place should be based on the cause, and it is pointed out that it is more than 0, for sex—.J r--1 · install-- (Please read the precautions on the back before filling this page) Order The Ministry of Economic Affairs ’Intellectual Property Bureau ’s employees’ cooperatives printed pigments with good quality and good quality. • The modified product has a good quality group. The material has no problem, no question, no question, no reason, although the material has the original quality, and it is more efficient than mr: m. Sexual hyperactivity is the fluid-dispersing and dispersive material of the streamer. It can be divided into two parts: Yan Xian's advancement, or film coating, high dispersion, and spectroscopic hardness. Weak questions, but brittle questions. The coating degree of film and so on is lower than that of the normal lining. When there is a set of rules, the pigment is used for seed coating to make various industries Η cheap and cheap. The paper size of this paper is applicable to Chinese national standards (CNS). A4 specification (210X297 mm) 588094 A7 B7 V. Description of the invention (3) In addition to pigment M, a pigment composition containing a pigment derivative or a dye, regarding the pigment dispersion liquid, indeed has improved pigment dispersibility and promotes the growth of crystals And inhibit the agglomeration and improve the fluidity effect, but rather difficult to be affected by various solvents. In addition, the coating film, namely K, improves gloss, freshness, transparency, and ratio. Moreover, its low cost is also a feature. A specific example is the C · I · Pigment 177 pigment containing 4'-diamino-1,1'-digitolol-3,3 丨 -disulfonic acid described in JP-A-63-172772. , Japanese Unexamined Patent Publication No. 4-1 46968, a hafnium titanium cyanine pigment containing a gf cyanine sulfonic acid derivative, and copper halide fife cyanide containing a halogenated hafnium phthalocyanine nitric acid derivative described in Japanese Patent Publication No. 41-2466 Pigments, etc. However, with the increase of the content of pigment derivatives or dyes, the light resistance, weather resistance, and heat resistance of the coating film are often reduced, and the phenomenon of releasing the pigment derivatives or dyes on the surface of the coating film. Furthermore, in recent years, many researches have been carried out. Encapsulated pigments have highly evaluated the dispersion, stability, and fluidity of the dispersion formed by dispersing the pigment composition. However, for the pigments that are required to be inexpensive in the industrial field, there is still a problem of high cost. Furthermore, as for a prior art using a carboxylic acid ester-based compound related to the present invention, that is, a metal salt pigment composition of chromic acid obtained by ester treatment described in JP 62-1 8406 3, Improved thermal stability, chemical stability, light fastness, etc. by KK. Next, the improvement of the liquid properties M and coating film properties of the prior art Tongguan pigment dispersion liquid is described in detail below. Pigment dispersion is composed of pigment composition, resin, dispersing aid, solvent-5-This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling this page) clothes·

*1T 經濟部智慧財產局員工消費合作社印製 。帥 094 A7 1'發明説明(4 ) 等所構成,在構成原料之一種以上組合具有改良顔料分 散液性狀之功能。通常,塗料係將以樹脂和溶劑所固定 之顔料相互交換進行多種顯色,一般係以持有可資改善 賴料組成物或在分散劑中之顏料分散液的性狀功情況。 尤Μ本發明有關連之習知技術,如於特開昭47-677 1號 公報,特開昭60-215651號公報,特開昭63-214330號公 報,特開平2-129147號公報,特開平3-227371號公報, 特開平4-506225號公報,特開平7-25824號公報,特開 平7-50662 1號所記載者一般,係因將羧酸酯糸化合物做 為展色料或分散劑使用,屬於改良顔料分散性等例子。 惟此等公報所記載之羧酸酯糸化合物,無論為何種就其 化學構造面而言,並非與本發明相應一致。 摒除樹脂用著色劑之產業領域觀點,利用羧酸醅系化 合物之前例,雖有特開昭52-5856號公報,特開昭 54-10515號公報,特開昭60-90232號公報,特開昭 62-68834虢公報,特開平04-298572號公報,但無論為 何種公報,其他學構造與本發明者不盡相同。特別是與 本發明具有類似構造之使用羧酸酯系化合物之特開昭 50-50460號公報,但就彼此發明所屬之技術領域與使用 目的,效果的層面而言,實質上與本發明不同性。 如上述以往係W低成本實規顔料分散液的液性狀(顔 料分散性,流動性)Κ及塗膜性狀(光澤,鮮餓性,観 比度,透視性等)之改良所做的方式,對於顔料分敗液 一般係使用適合於分散糸之顔料組成物或樹脂,分散肋 -6 一 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) I I 1 ϋ— h fl^i (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 588094 A7 B7 五、發明説明(5 而 料膜等阻效系組提適 料 顏塗度生有劑料需之 原 高成比發具溶顔因度 液求形襯狀外或之,比 散要 ,高性 Μ 系性言對 分係性,膜} 脂動而或 料 狀定性塗等樹流片澤 顔性安視及脂用液色光 成液存透狀松散散濾的 構散貯高性,分分就膜 為分及,液料料及其塗 做 為性性散原顔性尤於 ,◊做動艶分質種散。對 法法中流鮮的體各分的高 方方液液高液 ί 於料目提 之之散散,散劑對顔為 Κ 合能分分澤分理 ,異液故 組功料之光料處劑優散 , 而狀顔好高顔前理有分性 等性在良有起之處發料散。示 劑良,,求引用廉開顔分的揭 溶改此性要中採價 Μ 及料目之 ,κ 依散則其所及則物顏為明 劑得 分時。礙果,成高性發 經濟部智慧財產局員工消費合作社印製 散散不態 ,。下完良本做 分分要狀料可 Κ 而改在稱 微於必散原不與遽性。物 與賴有分等夫料,動性成 化有則微液工顏分流動組 散化,的散加有成為流之 分散定期分施含之做液成 微分安初料法物缺 1 散構 之微得持顏方成或物分所 料的獲維或作組可合之 I 顔料料而物製料不化的物 由顔顔集成的顔為將目合 藉。之凝組液在物時一化 可成化行料散作合同另有 ,達|散進顔分製化。明含 良而|分或成料因之良發與 改化-微化構顏等表改本料 之定-使晶對或者代之於顔 性安一欲结要物明所性鼷此 散之ί ,子必成發I)散良將 分料能粒有組本(1分改中 料顔功料而料中式料而書 顔後的顔因顔其學顏,明 化機使,與 化成劑發 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) 588094 A7 B7 五、發明説明(6 ) 為「顔料組成物1」。 (請先閲讀背面之注意事項再填寫本頁) 含有該組成物1之顔料(對於後述之副顔料有時稱做 為主顏料)如為酸性顔料時,則更具有效果。但其中所 記述之酸性顔料係指含有酸性官能基之顔料,而酸性所 處理之顏料,具有電子受容性顔料當中之1種或2種Μ 上顔料。 (但,R1為Η或碳原子數為1〜3之任一飽和烷基,R2 為碳原子數1〜30之任一飽和烷基,不飽和烷基。) 但依照顔料之種類,顔料組成物1係在於改良顏料分 散性而有不能期待改良分散液流動性之倩形。其原因係 認為化合物1對於顔料不具有效果上作用之緣故。 經濟部智慧財產局員工消費合作社印製 是以,本發明者旨在於解決此問題,首先除顔料(主 顏料)之外因製作含有副顔料或顏料衍生物或染料之顔 料混合物,進行顔料粒子之結晶化或凝集之抑制而遽予 改良顔料分散性。但改良顔料分散性後(尤其進行顔料 之微分散化)使分散流動性變成更為低劣,一般可使顔 料分散性的改良與分散流動性的改良表現出顯著之相反 關係。Μ上之顔料化合物亦不例外分散液的流動性變成 劣化。 其中,本發明者由於製作Μ上顔料混合物與化合物1 所形成之組成物,而成功達成Μ保持顔料之高分散性狀 態下亦能改良顔料分散液的流動性。此顔料組成物稱做 一8 一 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) 588094 A7 B7 五、發明説明(7 ) (請先閲讀背面之注意事項再填寫本頁) 為「顔料組成物2」。顔料組成物2係由主顔料成分與 色素成分(特別是副顔料,顔料衍生物,染料)與化合 物2所構成,可將所有顔料適合作為顔料使用,而可獲 得良好之顔料分散性及分散液流動性。 構成顔料組成物2之副顔料,顏料衍生物,染料宜用 酸性顔料,酸性顔料之衍生物,酸性染料,較佳者係使 用含有磺酸基之副顔料,含有磺酸基之顔料衍生物,含 有磺酸基之染料。 顔料組成物1及顔料組成物2欲能發揮優異之顔料分 散性與分散流動性效果,將此等顔料組成物尤其是做為 濾色Μ材料使用時,可K獲得具有高對比度之均勻塗膜。 經濟部智慧財產局員工消費合作社印製 其次針對顔料或顔料混合物分散成顔料分散液逕加說 明之。通常於製作顔料分散液時,至少組合顔料,樹脂 與溶劑而予Μ作成。樹脂一般為改良顔料分散性與分散 液流動性所不可或缺者。惟將顔料組成物1或顔料組成 物2單獨分散在溶劑所形成之顔料分散液,僅此亦能改 善顔料分散性與分散液流動性。又如在顔料或顔料混合 物分散於溶劑時再加入化合物時則能期待與使用顔料組 成物1或顏料組成物2時之類似結果。 將顔料組成物1或顏料組成物2分散在溶劑時註如含 有單體或樹脂,比較僅將分散在溶劑者更能提高顔料分 散性與分散液流動性。尤Μ使用丙烯系單體,丙烯系樹 雨旨更為適合。 欲改良顔料分散性與分散流動性,如含有Κ下化學式 -9- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) 588094 Α7 Β7 五、發明説明(8 化物 下合 Μ化 ώ ( 或物 \ 合 及化 }狀 2 環 物之 合合 化結 ί 上 物Μ 合組 化 1 狀之 鐽表 之代 表所 代> 1 所ί. }式 Ε ( 學 3 3 物 合 化 或 2 物 學 化 如 ο mrc 身 效 有 具 更 則 劑 肋 散 分 為 做 著 顯 為 更 果 效 其 時 物 合 化 胺 醸 為* 1T Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Shuai 094 A7 1 'Invention Description (4), etc., has the function of improving pigment dispersion properties in one or more combinations of constituent materials. Generally, coatings are developed by exchanging pigments fixed by resins and solvents with each other for various color developments. Generally, they are used to improve the properties of pigment dispersions in the composition of dispersants or in dispersants. In particular, related technologies of the present invention are described in Japanese Patent Application Laid-Open No. 47-677 1, Japanese Patent Application Laid-Open No. 60-215651, Japanese Patent Application Laid-Open No. 63-214330, Japanese Patent Application Laid-Open No. 2-129147, The documents described in Kaiping Publication No. 3-227371, Japanese Patent Publication No. 4-506225, Japanese Patent Publication No. 7-25824, and Japanese Patent Publication No. 7-50662 No. 1 are generally due to the use of a carboxylic acid ester hafnium compound as a coloring material or dispersion. The use of additives is an example of improved pigment dispersibility. However, the carboxylic acid ester hydrazone compounds described in these publications are not consistent with the present invention in terms of their chemical structure. Excluding the industrial field of colorants for resins, the previous examples of using carboxylic acid fluorene-based compounds include JP 52-5856, JP 54-10515, JP 60-90232, and Sho 62-68834, Gazette No. 04-298572, but no matter what kind of gazette, the other structures are different from those of the inventor. In particular, Japanese Patent Application Laid-Open No. 50-50460 using a carboxylic acid ester-based compound having a structure similar to the present invention is substantially different from the present invention in terms of the technical field, purpose of use, and effects of the inventions. . As mentioned above, it is a way of improving the liquid properties (pigment dispersibility, fluidity) of the low-cost regular pigment dispersion liquid and the coating film properties (gloss, freshness, ratio, transparency, etc.), For pigment liquids, pigment compositions or resins suitable for dispersing concrete are generally used. Dispersing ribs-6 A paper size is applicable to Chinese National Standard (CNS) A4 specifications (210X297 mm) II 1 h— h fl ^ i ( Please read the notes on the back before filling in this page) Order printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives printed 588094 A7 B7 V. Invention Description (5) The anti-effective group such as the film and film can be used to improve the color of the paint. The original high proportion of hair is required to have the appearance and shape of the solution, or it is more important than the loose, the high-quality M series is a bisect, and the film is qualitatively coated or tree-like. Zanyan AnTV and lipid liquid liquid light-storage liquid loose-filtration loose loose filter structure high storage performance, the points are divided into films, liquid materials and coatings are used as sexual powder, and the original color is especially good. Do a good job of separating germplasm and seedlings. The high-precision liquid and high-liquid solution of fresh body parts in the method The powder is scattered, the powder is divided into κ synergy and separation, and the liquid material of the liquid composition is excellent, and the shape is good and the quality is good. Disperse when there is a good point. The indicator is good. Seek to use Lian Kaiyan to reveal the solution and change the nature of the price M and the material. Κ According to San, the material is the score of the agent. Obstruction As a result, the high-level development of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the dispersive situation. The next good version can be divided into sub-materials and can be changed to be inferior to the indispensable. Graduation of materials, the dynamic formation of the micro-liquid industrial facial flow group disperse, the dispersion of the addition of the flow into the regular distribution of the liquid into the differential preparation method, the lack of a primary material method 1 It can be used to maintain the beauty of the face or material, and can be used as a combination of pigment materials, but the materials that are not made of materials can be combined by the face of the face. There is also a separate contract for the transformation of materials, which can be achieved by the system of scattered into the face. The development and modification of the reason that the good and the minute or the material cause-the miniaturization of the structure and the modification of the material-make the crystal pair or It is replaced by Yan Xingan, who wants to make things clear, and this will be scattered. I) San Liang will divide the material into particles and make it into a group (1 point to change the material and the material to the Chinese formula. The face of the book, the face of the face, the face of the face, the face of the face, the chemical agent, and the chemical agent issued. The paper size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 588094 A7 B7 5. The description of the invention (6) is "Pigment Composition 1 "(Please read the precautions on the back before filling out this page) Pigments containing this composition 1 (sometimes referred to as the sub pigments mentioned below are sometimes referred to as main pigments) are more effective when they are acidic pigments. However, the acidic pigments described therein refer to pigments containing acidic functional groups, and the pigments treated with acidity have one or two pigments among the electron-accepting pigments. (However, R1 is fluorene or any saturated alkyl group having 1 to 3 carbon atoms, and R2 is any saturated alkyl group or unsaturated alkyl group having 1 to 30 carbon atoms.) However, according to the type of pigment, the pigment composition Object 1 is a pill shape which cannot improve the fluidity of a dispersion liquid because it improves pigment dispersibility. The reason is that the compound 1 is considered to have no effect on the pigment. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the inventor aims to solve this problem. In addition to pigments (primary pigments), the pigment particles containing the secondary pigments or pigment derivatives or dyes are used to crystallize pigment particles Suppression of coagulation or agglomeration may improve pigment dispersibility. However, the improvement of pigment dispersibility (especially the micro-dispersion of pigments) makes the dispersion fluidity even worse, and generally the improvement of pigment dispersibility and the improvement of dispersion fluidity show a significant opposite relationship. The pigment compounds on M are no exception, the fluidity of the dispersion liquid is deteriorated. Among them, the inventors have succeeded in achieving a state in which the pigment maintains high dispersibility by improving the fluidity of the pigment dispersion liquid because the composition formed by the pigment mixture and Compound 1 on M is successfully produced. This pigment composition is referred to as a 8-size paper. It is applicable to Chinese National Standards (CNS) A4 specifications (210 × 297 mm) 588094 A7 B7 5. Description of the invention (7) (Please read the precautions on the back before filling this page) as "Pigment composition 2". The pigment composition 2 is composed of a main pigment component and a pigment component (especially a sub-pigment, a pigment derivative, a dye) and a compound 2. All pigments can be suitably used as pigments, and good pigment dispersibility and dispersion liquid can be obtained. fluidity. The sub-pigments, pigment derivatives, and dyes constituting the pigment composition 2 are preferably acid pigments, acid pigment derivatives, and acid dyes. It is preferable to use a sub pigment containing a sulfonic acid group and a pigment derivative containing a sulfonic acid group. Dyes containing sulfonic groups. Pigment composition 1 and pigment composition 2 are intended to exhibit excellent pigment dispersibility and dispersion fluidity effects. When these pigment compositions are used especially as a color filter material, K can obtain a uniform coating film with high contrast. . Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Secondly, the pigment or pigment mixture is dispersed into a pigment dispersion liquid path, and the explanation will be given. Usually, when preparing a pigment dispersion, at least a pigment, a resin, and a solvent are combined to prepare the pigment dispersion. Resins are generally indispensable for improving pigment dispersibility and dispersion fluidity. However, a pigment dispersion liquid in which the pigment composition 1 or the pigment composition 2 is separately dispersed in a solvent can also improve pigment dispersibility and dispersion fluidity. Also, when a compound is added while the pigment or pigment mixture is dispersed in a solvent, a result similar to that when the pigment composition 1 or the pigment composition 2 is used can be expected. When the pigment composition 1 or the pigment composition 2 is dispersed in a solvent, if a monomer or a resin is contained, the pigment dispersibility and dispersion fluidity can be improved more than those dispersed in the solvent alone. In particular, a propylene-based monomer is used, and a propylene-based tree is more suitable for rain. To improve pigment dispersibility and dispersion fluidity, if it contains chemical formula -9 under K, this paper size is applicable to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 588094 Α7 Β7 5. Description of the invention (8 compounds under the chemical formula) (OR matter \ combination and combination} State 2 ring combination of combination combination 上 上 Μ 合 合 化 1 state of the representative of the table > 1 place ί.} Formula Ε (学 3 3 物 合 化 or 2 physicochemicals such as ο mrc have the effect of the body, the ribs scattered into the agent is significantly more effective.

RIC I 4 N丨R I 3 R 但 烷 和 飽 不 基 烷 和 包 或 Η 表 代 立 獨 此 彼 係 種 1 何 任 之 基 氧 烷 和 飽 不 基 氧 烷 和 飽 基 (請先閱讀背面之注意事項再填寫本頁) .裝· R 6 —N — C =〇 ……(ffl)RIC I 4 N 丨 RI 3 R, but alkane and unsaturated alkane and bag or Η represents the only one of this kind. 1 Any of oxyalkane and unsaturated alkane and saturated group (please read the note on the back first) (Please fill in this page for more details). Equipment · R 6 —N — C = 〇 …… (ffl)

I I (但,R6為H或飽和烷基或不飽和烷基。) 本發明之顔料分散液特別適用於濾色片。由於有良好 之顔料分散性與分散液流動性,故能獲得具有高對比性 之均質塗膜。又本發明之顔料組成物或顏料分散液,例 如含有至少一種由光聚合性單體及/或寡聚體與光聚合 起始劑等所形成之光聚合性樹脂組成物時,則可經由塗 覆,露光,顯像而形成為任意花紋之滤色片用色阻體。 實陁發明所需之最佳形態 實施本發明之最具典型及最佳形態,雖具體例示在後 述之實施例,惟針對實施本發明可供選擇之各種構成要 件詳细說明之。 關於本發明之顔料組成物1 ,係含有顔料與由Μ上化 學式(I)所代表之化合物1為不可或缺之成分。 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐)I I (However, R6 is H or a saturated alkyl group or an unsaturated alkyl group.) The pigment dispersion liquid of the present invention is particularly suitable for a color filter. Due to the good pigment dispersibility and fluidity of the dispersion, a homogeneous coating film with high contrast can be obtained. When the pigment composition or pigment dispersion of the present invention contains, for example, at least one photopolymerizable resin composition formed of a photopolymerizable monomer and / or oligomer and a photopolymerization initiator, it may be applied by coating. Cover, expose, and develop to form a color resist for color filters with any pattern. Best Modes Needed to Realize the Invention The most typical and best modes for implementing the present invention will be described in detail in the following embodiments, but will be described in detail with regard to various constituent elements that can be selected to implement the present invention. The pigment composition 1 of the present invention contains a pigment and the compound 1 represented by Chemical Formula (I) above as essential components. This paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm)

、1T 經濟部智慧財產局員工消費合作社印製 588094 A7 B7 五、發明説明(9 ) 經濟部智慧財產局員工消費合作社印製 於燥捏 合劑粉予 ,與 料過之料似 在淤乾合於乾 ,乾以 化溶,再 外物 顔由體顔類 即料,化或 , 時,, 與之燥 , }合 副經粉或有 ,染洗在,機 體洗體 料解乾後 料混K,自料具 時或水加法和 液水液。顔溶,融 顔料 配後各顔與 體漿,添方揑 為,物理使體滤熔。主顔 混拌用副料 液淤溏物之 K 1 滹合處等固過熱等{之 漿攪採M顔 為物過合碎再 物過化M機之,加法料料 淤於或面主 1生,混粉 , 合,之加和1 拌經方顔染 料,,表擇。物衍拌料 ,1 化拌量等捏物攪 1 之由或 顔漿法料選料合料搅顔燥物 如攪要機K合由物碎係物 於淤方顔必染化顔由述乾合 ,Μ 霈合有化經合粉,生 係料之主不或如或經上,化 法,加混即使再化 ,2衍 ,染驟在而物,漿,將滹之 製後添氏,可,加燥物料 法或步需,成法淤後或過量 之 1 料亨時在料添乾成顔。製漿碎必理組製料之,,用 1 物顔,體或顔於,組或成的淤粉,處料之顔 1式拌需 物合在機固,與漿洗料料形物物 ,κκ顔物副物方攪所 成化或碎為練 1 淤水顔顔所合生燥是加或成加合之 Κ 入 組加,粉 1 混物料,中副 1 混衍乾。料料組添化驟予加 料添式式物體合顔濾明他物料料,式染顔料漿加步而物 顔漿方乾合固化對過發其合顔顔洗方或副顔淤添碎,合 於淤碎,化之入或,本有化於或水合物之於料於粉中混 至料粉機如 1 置,拌在含述至漿,混生格Rl顔 ,,1 料 顔,和 物中碎攪 尚上 淤滤乾衍骨 主漿燥物顔 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 588094 A7 B7 五、發明説明(l〇 物 合 化 將 〇 物 等合 法混 方料 之顏 理在 處有 M即 加 , 等時 機體 合 固 混為 氏 1 亨物 機合 碎化 粉如 式 體 , 固拌 之攪 1 由 物經 合 , 化物 使合 可混 在料 或顔 ,與 法 1 方物 之合 練化 混入 機加 和中 捏劑 Μ 溶 體之 固解 之溶 料經 原1 副物 加合 添化 漿入 淤加 料另 顏 , 主漿 於淤 或料 ,染 法或 , 方漿拌 之淤攪 碎物 Κ 粉生予 ,衍 , 燥料後 乾顔融 ,或熔 濾漿熱 過淤加 驟 步 碎 粉 燥 乾 洗 水0 過 期 預 得 獲 2 物 成 組 料 顔 或 11 物 成 組 料 顔 之 明 。 發 等本 式使 方為 之 化大 ,言J 果而2-效料在 之顔即 物為 合約 對 但 異 差 有 而 物 合 化 與 量 用 使 之 果得 效獲 之能 高不 較時 得少 獲 過 欲。 如果 ,效 % 有 量具 重最 3 圍 ~ 範 5之 所 時 2 物 〇 成 形組 情料 之顔 害或 弊 1 生物 發成 有組 則料 時顔 多作 過製 而對 , 針 效玆 功 , 之次 期其 預 Μ 可 料 染 物 生 衍 料 顔 料 顔 。 副 下 , 如料 述顔 斜主 料於 原關 之先 用首 使 β 有 括 包 如 例 制 〇 限 者之 素別 色特 機無 無並 用 , 使者 或素 素色 色機 機有 有用 用使 使 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 系0 酮 吖 url 系 酮 吖 url 系 嗪 噁 二 糸 醒M 系 菁 系 酮 丹 陰 糸0M 嵌MM 氮 系00 黃 藍咪 靛並 ,苯 糸 , _ 系 酞啉 βϊ« ,吲 系異 咯 , 吡系 並酮 咯滿 ft 八木 RH HM β 引 ΠΗ 二異 系系 酮藍 嵌靛 苯代 二碕 系系 括 包 如 例 制 限 之 別 特 有 無 亦 素 〇 色 等機 系無 氮之 偶用 , 使 糸所 酮又 咪 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) 588094 A7 B7 五、發明説明(11 ) 有,碳系,钛系,鋇系,鋁系,鈣系,鐵系,鉛系,鈷 系等。 對於主顔料進一步言及者,其中特別具有顯著效果者 ,有二胺憩酲系紅色顔料,酞花青系藍色顔料。 如對副顏料,顔料衍生物及染料而言,特別有顯著效 果者,有酞花青系,二胺憩酲系,哇吖醑条,雙偶氮系 ,異吲昤滿酮糸,二酮吡咯並毗咯系之酸性顔料或酸性 顔料衍生物,酸性染料。較佳者為顔料或顔料衍生物, 而以在染料中包含有磺酸基者為佳。 構成顔料組成物2之最適合的顏料,乃為主顔料與具 有類似構造之酸性副顏料或酸性顔料衍生物或酸性染料 與主顏料所組合而成,如此可望有良好之結果。 可做為構成顔料化合物1及顔料化合物2使用之化合 物1 ,並無特別之限制,例如包括有醋酸乙酯,醋酸丁 酯,醋酸硬脂酸酷,醋酸油酸酯,甲酸丁酯,甲酸硬脂 酸酷,甲酸油酸酯,丙酸丁酯,丙酸硬脂酸酯,丙酸油 酸酯,丁酸丁酯,丁酸硬脂酸酯,丁酸油酸酯之脂肪酸 酯系化合物。而特別有效果者為醋酸酯系化合物。 其次,玆針對顔料,顔料混合物,或顔料組成物的分 散遂加說明之。 首先,在分散顔料或顔料混合物時,於加入上述化合 物1之情形加K說明。添加化合物1之時期K分散前為 佳,於分散中或分散後亦屬可行。但在化合物1於分散 後加入時則宜使用容易溶解或擴散之化合物。可供使用 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) —i —- -- (請先閲讀背面之注意事項再填寫本頁) 訂· 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 588094 A7 B7 五、發明説明(U ) 之分散機有輥磨機,球磨機,珠磨機,乾式粉碎機,分 散攪拌機等◊最好為對顔料或顔料混合物使化合物1可 達成有效果之作用,宜使用輥磨機等分散機K不揮發分 量的高混合進行分散(即固練),如有必要時可將不揮 發分量適度調整降低其混合而Μ珠磨機加K分散者為佳 。此時,如後述亦有可能使用分散助劑。特別是Μ上逑 化學式(Ε)所代表之鐽狀化合物(化合物2 )及/或由 Μ上化學式(I )所代表之結合有1組Μ上之環狀化合物 (化合物3 ),與氨基甲酸乙酯糸化合物,宜Κ併用聚 氨基甲酸乙酯系化合物做為分散助劑,則更能改善顔料 顔料分散性與分散液潦動性。 其次,针對分散含有化合物1之顔料組成物1或顔料 組成物2時遂加說明之。分散機可使用分散顏料混合物 所敘述說明者。個別之顔料組成物1或顔料組成物均具 有良好之顔料分散性與分散液流動性。在此案例中,如 併用上述化合物2及/或化合物3所賦予之化合物,與 氨基甲酸乙酯系化合物,特別是聚氨基甲酸乙酯系化合 物做為分散肋劑,則更能改善顔料分散性與分散液流動 性。 其中,於分散顔料,顔料混合物,或顔料組成物時可 供使用為分散肋劑者表示如次。 在化合物2中可資分類者,並無特別限制,例如包括 有,甲醯胺,Ν·甲基甲醯胺,Ν,Ν-二甲基甲醯胺,Ν, Ν-二乙基甲醯胺,乙醯胺,Ν-甲基已醯胺,Η,Ν-二甲基 一 14- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) JL-------βϋ裝------^丨訂------ (請先閱讀背面之注意事項再填寫本頁) 588094 A7 B7 五、發明説明(l3 ) (請先閱讀背面之注意事項再填寫本頁) 乙醸胺,N-乙基乙醯胺,N-甲基丙醯胺之醯胺系化合物 ,油酸醯胺之不飽和脂肪酸醯胺系化合物,硬脂酸醯胺 之飽和脂防酸醯胺系化合物,氨基甲酸,氨基甲酸甲酯 ,氨基甲酸乙酯,氨基甲酸異丙氨基甲酸丁酯,氨 基甲酸苄酯之氨基甲酸系化合物,N -甲基氨基甲酸乙酯 ,H -乙基氨基甲酸乙酯之氨基甲酸乙酯系化合物。而特 別有效果者為醯胺系化合物或氨基甲酸乙酯系化合物。 又在化合物3中可資分類者,並無特別之限制,例如 包括有,7-丁内酯,N-甲基-2-毗咯烷酮,H-乙基-2 -毗咯烷嗣,N-丙基-2_毗鉻烷醑,N-異丙基-吡咯烷銅, N-丁基_2-吡咯烷酮,7 -戊内酯,甲基-7 -戊内酯, N -乙基-7 -戊內酯,α -哌啶酮,N-甲基-α -哌啶酮, 己内酯,H -甲基己内酯之内酯糸化合物,巴比土酸,1, 3-二甲基巴比土酸之巴比土酸系化合物,酞亞醯胺,Ν-甲基酞亞醯胺之亞醯胺系化合物,異氰尿酸,異氰尿酸 單甲酯,異氰尿酸單乙酯之異氰尿酸系化合物,二酮吡 咯並吡咯系化合物。而特別有效果者為内酷系化合物或 巴比土酸系化合物。 經濟部智慧財產局員工消費合作社印製 至於其他之分散助劑,並無特別限制,例如包括可使 用聚醸胺系化合物或聚氨基甲酸乙酷系化合物之樹脂型 分散劑(市面上則以迪斯巴克1 30 ,迪斯巴克1 6 1 ,迪 斯巴克162 ,迪斯巴克163 ,迪斯巴克170 ,愛夫卡46 ,愛夫卡47商標名稱出售)。又,關於化合物2及/或 化合物3 Μ外者,可併用丙烯系,聚乙烯系,聚酷系之 一 15 - 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) 588094 A7 B7 五、發明説明(14 ) (請先閱讀背面之注意事項再填寫本頁) 樹脂分散劑,矽嗣系或非矽嗣糸之矯正劑,矽氧烷系, 鋁糸之偶合劑,陰離子系,非離子糸,陽離子糸之界面 活性劑等。 在分散顔料或顔料組成物時可供使用之樹脂,並無特 別限制例如包括有,醇酸系樹脂,丙烯酸系樹脂,蜜胺 系樹脂,氨基甲酸乙酯系樹脂,環氧系樹脂,矽_糸樹 聚酯系樹脂,聚贐胺酸系樹脂,聚亞醯胺系樹脂苯 乙烯馬來酸系樹脂,笨乙烯無水馬來酸系樹脂等。亦可 適用各種丙烯酸系單體,丙烯酸酯糸單體。特別適宜之 樹脂,單體即包括有氨基甲酸乙酯系樹脂,丙烯系樹脂 ,丙烯系單體。 經濟部智慧財產局員工消費合作社印製 在分散顔料或顔料組成物時可供使用之溶劑,並無特 別限制,例如包括有,甲苯或二甲笨,甲氧苯等芳香族 系溶劑,醋酸乙酯或醋酸丁酯,丙二醇-甲醚醋酸酯, 丙二醇-乙醚醋酸酯等醋酸乙酯糸溶劑,乙氧乙基丙酸 酯等之丙酸酯系溶劑,甲醇,乙醇等醇系溶劑,丁基溶 纖劑,丙二醇-甲醚,二乙二醇乙醚,二乙二醇二甲醚 等之醚系溶劑,甲乙_,甲異丁酮,環己酮等之酮系溶 劑,己烷等脂肪族烴系溶劑,-二甲基甲醯胺,7-丁內酯,甲基-2-毗咯烷_,苯胺,吡啶等氮化合物 系溶劑,丁内酿等内酯系溶劑,氨基甲酸甲醅與氨 基甲酯之48:52混合物一般之氨基甲酸酯,水等。尤其 使用樺性溶劑時更能獲得預期之效果。 K上係針對顔料組成物1 ,顔料組成物2 , Μ及顔料 一 16- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210 X 297公釐) 588094 A7 B7 五、發明説明(IS ) (請先閱讀背面之注意事項再填寫本頁) 混合物之構成與製法,以及顔料分散液之構成與製法所 做之斜述,並將添加化合物1及化合物2及/或化合物 3之時刻,Μ最具效果之順序斜逑如次。 1. 於製作顔料組成物1或顏料組成物之階段加入。 2. 於製顔料分散液之階段加入(在固練分散時效果較大)。 3. 製作顔料分散液後加入。 其次,针對滤色片用色阻體的製法斜述如下。基本上 如前述將所製作成之顔料分散液Μ分散攪拌機予Μ攪拌 ,加入適量之光聚合性單體與光聚合起始劑,溶劑而得 Μ製作溏色片用色阻體。 製作滹色片用色胆體可供使用之光聚合性單體,並無 特別之限制,例如包括有,1 , 6 -己二醇二丙烯酸酯,乙 二醇二丙烯酸酯,新戊二醇二丙烯酸酯,三乙二醇二丙 烯酸酯,雙(丙烯氧乙氧基)雙酚A , 3 -甲戊二醇二丙烯 酸酯等之2官能單體,三甲醇丙酮三丙烯酸酯,季戊四 醇三丙烯酸酯,三個(2-羥乙基)異氰酸酯,二季戊四醇 己丙烯酸酯,二季戊四醇戊丙烯酸酯等多官能單體。尤 以多官能單體最為適用。 經濟部智慧財產局員工消費合作社印製 關於製作滤色Η用色阻體可供使用之光聚合起始劑, 並無特別限制,例如包括有乙醯苯,二苯甲嗣,苄二甲 基縮酮笨醸過氧化物,2-氯硫雜憩嗣,1,3-雙(4^叠氮 苯醯基)-2-丙烷-2’-磺酸,4,4’-二叠氮苯乙烯並-2,2’ -二磺酸,鹵代甲基噁二唑,鹵代甲基-S-三嗪等。尤其 從流動性與溶解性加Μ考量,即Ml,3-雙_(4’_叠氮苄 -17- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 588094 A7 B7 五、發明説明() 叉)-2_丙烷-2’-磺酸,4,4’-二叠氮苯醯基-二磺酸者為 佳。 (請先閱讀背面之注意事項再填寫本頁) 製作滹色Η用色阻體可供使用之溶劑,並無特別之限 制,在上述溶劑中Κ丙烯酸酯系,醇系,醚系,酮系, 氮化合物系,内酯系,水等極性溶劑比較親水性者最為 適用。 [簧施例] 其次揭示實施例及比較例具體說明本發明,惟本發明 並不受其限制。以下實施例及比較例所使用之原料,如 無特別指明,皆為大日本油墨化學工業公司製售之產品 ,其他公司產品之商品名稱即將製造公司記載於括弧内 。又Μ下所記述之「份」全為重量基準。 經濟部智慧財產局員工消費合作社印製 製作顏料分散液時分散法及評估法係如下述。在混合 有各種原料之混合液加入200份0.5ΐί»ιηΨ之膠球(珊可 邦公司製造),Κ東洋精機之塗料塗佈機分散1小時調 製成顏料分散液後,Μ卜麥克公司之Ε型黏度計測定分 散液之l〇rPm黏度。再將此顔料分散液Κ塗佈輥塗抹在 lmiB厚之玻璃板,在140 ΐ下燒结10分鐘經由乾燥製作 乾膜厚度為1/im之塗膜板。將此塗膜之20° - 20°光澤 以村上色研公司之GM-26D,將塗膜反差遮光由以下配置 加以測定。 背向燈/偏光膜1 /塗板/偏光膜2 /色彩輝度計 背向燈:LCD用燈(明拓系統公司製造) 偏光膜1及2 : NPE-G 1220 DUN (日東電工公司製造) 一 18 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 經濟部智慧財產局員工消費合作社印製 588094 A7 B7 五、發明説明(l7 ) 色彩輝度計:BM-7 (妥普康公司製造) 偏光膜2與色彩輝度計之間隔:50cm (實_例1 ) 在C* I. Pigment Green 36顔料游獎(含100份顔料 固形分)中加入5份醋酸油酸酯,於70 1C加熱攪拌30分 鐘。然後,經由過滹,水洗,90TC乾燥,粉碎,而得Μ C. I. Pigment Green 36為主要成分之顔料組成物。將 此做為G 1 - 1。 (實施例2 ) 攪拌將 P Η 調整為 8 . 5 〜9 , 0 之 C . I . P i g m e n t G r e e η 3 6 顔料淤漿(含95份顏料固形分),加入磺基銅酞花青顔 料淤漿(含5份重固形分),在70 C下加熱30分鐘。加 熱後,調整pH至6.0〜6.5,經由過濾,水洗,90*0乾燥 ,粉碎,而得以C.I. Pigment Green 36為主要成分之 顔料組成物。將此做為G 2 - 1。 (實_例3 ) 攪拌將 pH 調整為 8.5 〜9.0 之 C. I. Pigment Green 36 顏料淤漿(含95份重顔料固形物),加入5份磺基銅酞 花青淤漿(含5份重固形分)及醋酸油酸酯,於7 0 C下 加熱30分鐘。加熱後,調整pH至6.0〜6.5,經由過滤, 水洗,9〇1〇 乾燥,粉碎,得 MC.I. Pigment Green 36 為主要成分之顔料組成物。將此做為G3-1。 (實廝例4 ) 在 pH調整於 8*5〜9·0之 C, I· Pigment Blue 15:6顔 -19- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) J l· J--^---φ裝------訂------ (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 588094 A7 B7 五、發明説明(沾) 料淤漿(含有95份重顔料固形分)中加入10份磺基銅酞 花青顏料淤漿(含5份重固形分)及醋酸丁酯(大西耳 化學工業),攪拌60分鐘。然後,將pH調整至6.0〜6.5 ,經由過滤,水洗,901C乾燥,粉碎,而得MC.I. Pigment Blue 15:6為主要成分之顔料組成物。將此做 為 B3-1 。 (實施例5 ) 在 pH調整於 8·5〜9.0之 C· I. Pigment Blue 15:6顏 料淤漿(含95份重顏料固形分)中加入10份磺基銅酞花 青顏料淤漿(含5份重固形分)及甲酸正丁酯,並搅拌 60分鏞。然後,調整pH至6.0〜6.5,經由過濾,水洗, 90D乾燥,粉碎後得以C.I. Pigment Blue 15: 6為主要 成分之顔料組成物。將此做為B3-2。 · (實施例6 ) 於將 pH調整至 8.5〜9.0之 C· I. Pigment Blue 15:6 顔料淤漿(含95份重顏料固形分)中,加入10份磺基酮 酞花青顏料淤漿(含5份重固形分)及丙酸正丁酯,搅 拌β〇分鐽。然後,調整pH至6.0〜6.5,經由過漶,水洗 ,90^乾燥,粉碎,而得以(:.1.?丨811^«1:8丨1^15:6為 主要成分之顔料組成物。將此做為B3-3。 (實嫌例7 ) 在將 pH調整至 8.5 〜9.0 之 C· I. PUment Blue 15:6 顔料淤漿(含95份重顔料固形分)中加入5份磺基銅酞 花青顏料淤漿(含5份重固形分)及醋酸正十八烷酸酯 -20- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) JLJ-----·裝------訂------AW (請先閲讀背面之注意事項再填寫本頁) 588094 A7 B7 五、發明説明(19 ) (請先閱讀背面之注意事項再填寫本頁) ,在701C下加熱攪拌30分鐘。然後將pH調整至6.0〜6.5 ,經由過滹,水洗,901^乾燥,粉碎,而得KC.I· Pigment Blue 15: 6為主要成分之顏料組成物。將此做 為 B3-4。 ί實撫例8 ) 攪拌調整 pH 至 8.5 〜9.0 之 C. I· Pigment Blue 15:6 顔料淤漿(含95份重顔料固形分),加入磺基銅酞花青 顔料淤漿(含5份重固形分),於701C加熱分鐘。加熱 後,將pH調整至6.0〜6.5,經由過滤,水洗,90C乾燥 ,粉碎,而得KC.I. Pigment Blue 15:6為主要成分之 顔料化合物。將此做為B2-1。 Μ下,針對顔料分散液的實施例遂加說明。 (實施例9 ) 本例係對含有化合物1 G1-1之分散所做的述明。 G1-1 20· 00份 愛夫卡-46 (愛夫卡) 10 · 00份 (4氨基甲酸乙酯系分散劑,Κ下相同) 友卡酯ΕΕΡ (聯合電石) 35.00份 經濟部智慧財產局員工消費合作社印製 (4丙酸酯系溶劑,Μ下相同) ΡΜΑ (協和發酵工業) 35 · 00份 (4醋酸酯系溶劑,Μ下相同) 總計 1 00.00份 將上述組成分散後,進行評估分散液流動性與塗膜性 狀。其結果如表1所示。其中分散液流動性與比較例1 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) 588094 A7 B7 五、發明説明(2〇) L之比對顯然可知在lOrpm之黏度為低。又塗膜光澤的數 倩則大於比較例1 。 (請先閱讀背面之注意事項再填寫本頁) (比較例1 ) 本例係針對C. I. Pigment Green 36無處理的分散所 做之敘述。 C· I, Pigment Green 36無處理顔料 20.00份 愛夫卡46 (愛夫卡) 10· 00份 友卡酯EEP (聯合電石) 35 · 00份 PMA (協和發酵工業) 35·00份 總計 1 0 0 , 0 0份 將以上組成分散後,進行評估分散液流動性與塗膜性 。其結果如表1所示。 表1 :綠色顏料之分散淤漿 10r pm黏度 單位:nt P a · s 塗膜光澤 1 實施例9 144 81 比較例1 1630 38 經濟部智慧財產局員工消費合作社印製 (實施例1 0 ) 本例係針對含有化合物1之G3-1之分散所做的敘述 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X 297公釐) 588094 A7 B7 五、發明説明(21 ) G3-1 20.00份 愛夫卡46 (愛夫卡) 10·00份 友卡酯ΕΕΡ (聯合電石) 35.00份 ΡΜΑ (協和發酵工業) 35·00份 總計 100 · 00份 將W上組成分散後,進行分散液流動性與塗膜性狀之 評估。其結果如表2所示。分散液流動性與比較例2比 對,在lOrpio黏度時,顯然較低,而塗膜光澤的數值亦 大於比較例2 。 (比較例2 ) 本例係對不含有化合物1之G2-1分散所做之斜述。 G2- 1 20,00份 愛夫卡-46 (愛夫卡) 10.00份 友卡酯ΕΕΡ (聯合電石) 35.00份 ΡΜΑ (協和發酵工業) 35 · 00份 總計 1 0 0 . 0 0份 將Μ上組成分散後,進行分散液流動性與塗膜性狀之 評估。其结果如表2所示。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 -23- 本紙張尺度適用中國國家標準(CNS ) A4· ( 210Χ297公釐) 588094 A7 B7 五、發明説明(22 表2 ··綠色顔料之分散淤漿 實施例10 比較例2 1 0 r p m黏度 單位:in P a _ 108 582 塗膜光澤 85 44 (請先閱讀背面之注意事項再填寫本頁) (實嫌例1 1 ) 2 0 . 0 0 份 10 ♦ 00份 70 ♦ 00份 1 00 · 00份 B3-1 愛夫卡46 (愛夫卡) PMA (協和發酵工業) 總計 經濟部智慧財產局員工消費合作社印製 將以上組成分散後,進行分散液流動性與塗膜性狀之 評估。其結果如表3所示。分散液流動性如黏度愈低則 愈能獲得均勻膜厚之塗膜層。如與比較例3比對,在1 0 rpm黏度時顯示有較低之數。又塗膜光澤數值愈大則可 評估顏料亦能被分散,關於此點其數值亦大於比較例3 (實fife例1 2 ) 本例係在分散B 2 - 1之際,添加K具有化合物1之醋酸 丁酯。 一 24- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 588094 A7 B7 五、發明説明(23 ) B2-1 20,00份 醋酸丁酯(大西爾化學工業) 2.00 JL -------- (請先閲讀背面之注意事項再填寫本頁) 愛夫卡46 (愛夫卡) 10. 00份 PMA (協和發酵工業) 68.00份 總計 1 00 . 00份 將K上組成分散後,進行分散液流動性與塗膜性狀之 評估,其結果如表3所示。分散液流動性與比較例3比 對,顯然在lOrpro黏度為低◊又塗膜光澤數值亦大於比 較例3 。 ί實施例〗3 ) 本例係對含有化合物1之Β3-2的分散所做之斜述。 Β3-2 20,00份 愛夫卡46(愛夫卡) 10.00份 ΡΜΑ (協和發酵工業) 70 · 00份 總計 1 0 0 . 0 0份 經濟部智慧財產局員工消費合作社印製 將Κ上組成分散後,進行分散液流動性與塗膜性狀之 評估,其結果如表3所示。分散液流動性從與比較例3 比對顯然可知在lOrpni黏度為低。又塗膜光澤数值亦大 於比較例3 。 (實施例1 4 ) 本例係對含有化合物1之B3-3的分散所做之斜述。 -25- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 588094 A7 B7 五、發明説明(24 ) 經濟部智慧財產局員工消費合作社印製 B3-3 愛夫卡 PMA ( 總計 將K上組 估,其結果 比較例3對 較例3 。 (實施例15) 本例係针 B3 - 4 愛夫卡 PMA ( 總計 將K上組 評估。其結 黏度時與比 於比較例3 (比較例3 ) 本例係針 B2 - 1 愛夫卡 PHA ( 總計 20 · 00份 10.00份 70 · 00份 100 · 00份 成分散後,進行分散液流動性與塗膜性狀評 如表3所示。分散液流動性在lOrpin黏度與 比顯然可知為低。又塗膜光澤數值亦大於比 46 (愛夫卡) 協和發酵工業) 對含有化合物1之B3-4的之散所做之斜逑。 20 · 00份 46 (愛夫卡) 10 · 00份 協和發酵工業) 70·00份 100 · 00份 成分散後,進行分散液流動性與塗膜性狀的 果如表3所示。已知分散液流動性於lOrpin 較例3對比顯然較低。又塗膜光澤數值亦大 對含有化合物1之B2-1的之散所做之斜述。 2 0 · 0 0 份 46 (愛夫卡) 協和發酵工業) 10 ♦ 00份 7 0 · 0 0 份 100 · 00份 —r ; -- (請先閲讀背面之注意事項再填寫本頁) ----1 訂、 -26 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 經濟部智慧財產局員工消費合作社印製 588094 A7 B7 五、發明説明(25 ) 將Μ上組成分散後,進行分散液流動性與塗膜性狀之 評估。其結果如表3所示。 表3 :藍色顏料之分散淤漿 1 0 r p m黏度 單位:m P a · s 塗膜光澤 實施例11 23 144 實胞例1 2 27 108 實施例1 3 28 102 實施例1 4 32 99 實胞例15 21 120 比較例3 39 85 (實_例16) 從本例開始係針對瀘色片色阻體的實施例逕加說明。 首先,由Μ下之組合製作降低透明劑。 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) (請先閱讀背面之注意事項再填寫本頁)1T printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 588094 A7 B7 V. Description of the Invention (9) The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed on the dry kneading agent powder. Dry, dry to dissolve, and then the external appearance is made from body color. When it is, or dry, dry with it.} Combined with powder or yes, dyed and washed, the body wash material is dried and mixed with K. , When adding materials or water addition and liquid water liquid. Yan Rong, melting pigment After blending each face with body paste, adding formula is used to physically melt the body. The K 1 mixture of the auxiliary material liquid sludge used for the main color mixing is solid and overheated, etc. {The slurry is stirred and crushed, and the material is crushed, and then the material is processed by the M machine. Raw, mixed powder, mixed, combined with 1 mixed with Yanfang Dye, express choice. Material mixing, 1 mixing amount and other kneading materials, stirring 1 reason, or pigment selection method, mixing materials, drying materials such as kneading machine K, combining materials, crushing materials, etc. Drying, mingled with chemical warp powder, the main ingredients of raw materials are not the same as or through the above, chemical method, even if remixed, mixed, dyed, and dyed, the pulp is added to Yes, you can add dry materials or steps, after the method becomes silt or an excess of 1 material, add dry ingredients to the face. For the pulping and crushing of the powder group, use 1 material powder, body powder, or powder powder, which is composed or formed powder, and the material powder type 1 is mixed with the machine solid, and the material is mixed with the slurry material. κκ face and side objects are mixed into pieces or broken into practicable ingredients. 1 Shui Yan Yan is combined with raw materials and dried. K is added into the group, powder 1 is mixed with materials, and medium and vice 1 are mixed and dried. The material group is added to the material to add the additive-type object to make up the complexion and filter out the other materials. The dyed pigment paste is added in one step while the object-colored paste is dry and solidified. Combining with mashing, chemistry, or hydration, mixing the ingredients in the powder to the powder machine, such as 1 set, mixing in the content to the pulp, mixed cells Rl Yan ,, 1 Yan Yan, and The contents of the paper are still stagnant and filtered, and the dried bones are dried and the main pulp is dried. (Please read the precautions on the back before filling this page.) This paper size applies to China National Standard (CNS) A4 (210X 297 mm) 588094 A7 B7 V. Description of the invention (10 物 合 化 will be added to the legal composition of 〇 物 and other legal mixtures wherever M is added, isochronous body solid-mixed to 1 Hengwu machine crushed powder such as formula, solid mixing Mixing 1 by the material, the compound can be mixed in the material or color, mixed with the method 1 recipe mixing machine and the kneading agent M solution solid solution of the solution is added by the original 1 by-product addition slurry Add the silt and add another color. The main pulp is in the silt or the material. After drying, dry the face after melting the material, or heat the molten filter slurry and add crushed powder to dry and dry clean the water. 0 expired to get 2 groups of materials or 11 groups of materials. The effect is large, the effect is J, and the effect of 2-effect is that the contract is a pair, but there are differences, and the combination and quantity of the effect make the effect of the effect no higher than the less desirable. . If the effectiveness% is measured, the weight is the most 3 rounds ~ the place of Fan 5 2 things 0 the appearance damage or disadvantages of the forming group 1 If the creature is in the group, the face is more pre-made, and the effect is correct. In the next period, its pre-M can be dyed, pigmented, pigmented, and pigmented. Vice, as described in the description of the oblique main materials in the original level, the first use of β, including, for example, the limitless, special color special machine without No use, the messenger or plain color machine is useful (please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 0 Ketoacl URL Ketoacr URL Urazine Erzhi Xing M series cyanine ketone Danyin糸 0M MM nitrogen nitrogen 00 yellow blue imidene, benzopyrene, _ series phthaloline βϊ «, indole isopyrrole, pyridone ketone ft Yagi RH HM β Η 异 two heterologous ketone blue indobenzoyl The system includes the special and non-existent products such as the limit of non-zero color, which is used for example. It is used for nitrogen-free devices, so that the standard of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 588094 A7 B7 V. Description of the invention (11) Yes, carbon, titanium, barium, aluminum, calcium, iron, lead, cobalt, etc. For the main pigments, those who have particularly significant effects include red diamine pigments and phthalocyanine blue pigments. For example, for secondary pigments, pigment derivatives, and dyes, those that have particularly significant effects include phthalocyanine series, diamine dihydroxide series, wow acridine strips, bisazo series, isoindolinone ketones, and diones. Pyrrolopyrrole-based acid pigments or acid pigment derivatives, acid dyes. A pigment or a pigment derivative is preferable, and a sulfonic acid group is preferably contained in the dye. The most suitable pigment constituting the pigment composition 2 is a combination of a main pigment and an acidic sub-pigment or an acid pigment derivative having a similar structure or an acid dye and a main pigment, and good results are expected. The compound 1 can be used as the pigment compound 1 and the pigment compound 2 and is not particularly limited. Examples include ethyl acetate, butyl acetate, stearic acid acetate, oleic acid acetate, butyl formate, and hard formate. Fatty acid esters, fatty acid ester compounds of oleate formate, butyl propionate, stearate propionate, oleate propionate, butyl butyrate, butyrate stearate, butyrate oleate . Particularly effective are acetate compounds. Secondly, the dispersion of pigments, pigment mixtures, or pigment compositions is explained below. First, when dispersing a pigment or a pigment mixture, adding K to the case where the above-mentioned compound 1 is added is explained. The compound K is preferably added before the dispersion, and it is also feasible during or after the dispersion. However, when compound 1 is added after dispersion, a compound which is easily dissolved or diffused is preferably used. Available paper size Applicable to China National Standard (CNS) A4 specification (210X297 mm) —i —--(Please read the notes on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and Economics 588094 A7 B7 V. Dispersing machine of the invention (U) includes roller mill, ball mill, bead mill, dry grinder, dispersing mixer, etc. The mixture enables Compound 1 to achieve an effective effect. It is suitable to use a high-mixing non-volatile component of a disperser such as a roll mill to disperse (ie, solidify). If necessary, the non-volatile content can be adjusted appropriately to reduce its mixing and M The bead mill plus K dispersion is better. In this case, a dispersion aid may be used as described later. In particular, the hydrazone compound (compound 2) represented by the chemical formula (E) on M and / or the cyclic compound (compound 3) on the group M combined with the cyclic compound (compound 3) represented by the chemical formula (I) on M is combined with carbamic acid. For ethyl ester compounds, it is better to use polyurethane compounds as dispersion aids, which can better improve the dispersibility of pigments and pigments and the flexibility of dispersion liquids. Next, a description will be given for the case where the pigment composition 1 or the pigment composition 2 containing the compound 1 is dispersed. The dispersing machine can be described using a dispersion pigment mixture. Individual pigment composition 1 or pigment composition has good pigment dispersibility and dispersion fluidity. In this case, if the compound given by the above compound 2 and / or compound 3 is used in combination with a urethane-based compound, especially a polyurethane-based compound as a dispersing rib agent, the pigment dispersibility can be further improved. With dispersion fluidity. Among them, those that can be used as dispersing ribs when dispersing pigments, pigment mixtures, or pigment compositions are described below. Those who can be classified in Compound 2 are not particularly limited, and include, for example, formamidine, Νmethylformamide, Ν, Ν-dimethylformamide, Ν, Ν- diethylformamide Amine, Ethylamine, N-Methylhexylamine, N, N-Dimethyl- 14- This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) JL ------- βϋ Install ------ ^ 丨 Order ------ (Please read the precautions on the back before filling this page) 588094 A7 B7 V. Invention Description (l3) (Please read the precautions on the back before filling in this Page) Acetamide, N-Ethylacetamide, N-Methylpropanamine, Ammonium compounds, Unsaturated fatty acids, Ammonium compounds, Ammonium stearate Ammonium compounds, carbamate, methyl carbamate, urethane, butyl carbamate isopropyl carbamate, carbamate compounds of benzyl carbamate, N-methyl carbamate, H-ethyl A urethane-based compound. Particularly effective are fluorene-based compounds or urethane-based compounds. Those that can be classified in Compound 3 are not particularly limited, and include, for example, 7-butyrolactone, N-methyl-2-pyrrolidone, H-ethyl-2 -pyrrolidine, N-propyl-2_pyrrochromene, N-isopropyl-pyrrolidine copper, N-butyl_2-pyrrolidone, 7-valerolactone, methyl-7-valerolactone, N-ethyl -7-valerolactone, α-piperidone, N-methyl-α-piperidone, caprolactone, H-methylcaprolactone lactone compound, barbituric acid, 1, 3- Barbituric acid-based compounds of dimethyl barbituric acid, phthalimide, N-methylphthalimide-based imidene compounds, isocyanuric acid, monomethyl isocyanurate, isocyanuric acid mono Ethyl isocyanurate compounds, diketopyrrolopyrrole compounds. Particularly effective are endocrine compounds or barbituric acid compounds. There are no special restrictions on the printing of other dispersing additives by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. For example, resin dispersants including polyamine-based compounds or polyurethane-based compounds can be used. Spak 1 30, Disbak 1 6 1, Disbak 162, Disbak 163, Disbak 170, Efka 46, Efka 47 are sold under the brand names). For compounds other than Compound 2 and / or Compound 3 M, one of propylene, polyethylene, and polyurethane can be used in combination. 15-This paper size applies to China National Standard (CNS) A4 (210X297 mm) 588094 A7 B7 V. Description of the invention (14) (Please read the precautions on the back before filling out this page) Resin dispersants, silicone or non-silicon rectifiers, silicone based, aluminum rhenium coupling agents, anionic, Non-ionic rhenium, cationic rhenium surfactant. Resins that can be used when dispersing pigments or pigment compositions are not particularly limited and include, for example, alkyd resins, acrylic resins, melamine resins, urethane resins, epoxy resins, and silicon resins. Linden polyester resin, polyamic acid resin, polyimide resin styrene maleic acid resin, stupid ethylene anhydrous maleic acid resin, etc. It can also be used for various acrylic monomers and acrylate monomers. Particularly suitable resins include urethane-based resins, propylene-based resins, and propylene-based monomers. There are no special restrictions on the solvents that can be used when dispersing pigments or pigment compositions in consumer cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Examples include aromatic solvents such as toluene, dimethylbenzyl, methoxybenzene, and ethyl acetate. Ester or butyl acetate, propylene glycol-methyl ether acetate, propylene glycol-diethyl ether acetate and other ethyl acetate solvents, propionate solvents such as ethoxyethyl propionate, alcohol solvents such as methanol and ethanol, butyl cellulose Agents, ether solvents such as propylene glycol-methyl ether, diethylene glycol ether, diethylene glycol dimethyl ether, ketone solvents such as methyl ethyl, methyl isobutyl ketone, cyclohexanone, and aliphatic hydrocarbons such as hexane Solvents, dimethylformamide, 7-butyrolactone, methyl-2-pyrrolidine, aniline, pyridine and other nitrogen compound solvents, lactone solvents such as butyrolactone, carbamate and amino 48:52 mixtures of methyl esters are generally carbamates, water, etc. Especially when using birch solvents, the expected results can be obtained. K is for Pigment Composition 1, Pigment Composition 2, M and Pigment 16- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 588094 A7 B7 V. Description of the Invention (IS) ( Please read the precautions on the back before filling out this page.) The composition and preparation of the mixture, and the composition and preparation of the pigment dispersion are described obliquely. When compound 1 and compound 2 and / or compound 3 are added, The order of effect is oblique. 1. Add at the stage of making pigment composition 1 or pigment composition. 2. Add at the stage of making pigment dispersion (the effect is greater when solid dispersion). 3. Add after making pigment dispersion. Next, a method for manufacturing a color filter for a color filter is described below. Basically, the prepared pigment dispersion liquid M dispersion stirrer is stirred as described above, and an appropriate amount of a photopolymerizable monomer and a photopolymerization initiator are added to the solvent to obtain a color resist for producing a cyan dye. There are no particular restrictions on the photopolymerizable monomers that can be used in the production of color capsules for tinctures, such as 1,6-hexanediol diacrylate, ethylene glycol diacrylate, and neopentyl glycol. Difunctional monomers such as diacrylates, triethylene glycol diacrylates, bis (propyleneoxyethoxy) bisphenol A, 3-methylpentanediol diacrylate, trimethylolacetone triacrylate, pentaerythritol triacrylate Esters, three (2-hydroxyethyl) isocyanates, dipentaerythritol hexaacrylate, dipentaerythritol pentacrylate and other polyfunctional monomers. Polyfunctional monomers are particularly suitable. There are no special restrictions on the use of photopolymerization initiators for the production of color filters for color filters by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, including, for example, acetophenone, dibenzidine, and benzyldimethyl Acetal ketone peroxide, 2-chlorosulfanil, 1,3-bis (4 ^ azidobenzyl) -2-propane-2'-sulfonic acid, 4,4'-diazide Vinyl-2,2'-disulfonic acid, halomethyloxadiazole, halomethyl-S-triazine and the like. Especially from the consideration of fluidity and solubility plus M, that is, Ml, 3-bis_ (4'_azidobenzyl-17-) This paper size applies to China National Standard (CNS) A4 (210X297 mm) 588094 A7 B7 V. Description of the invention () Fork) -2_propane-2'-sulfonic acid, 4,4'-diazidophenylfluorenyl-disulfonic acid is preferred. (Please read the precautions on the back before filling this page) There are no particular restrictions on the solvents that can be used in the color resists for cyanocyanine. Among the above solvents, acrylates, alcohols, ethers, and ketones , Nitrogen compounds, lactones, water and other polar solvents are more suitable for hydrophilic ones. [Spring Example] Next, the present invention will be specifically described with reference to examples and comparative examples, but the present invention is not limited thereto. Unless otherwise specified, the raw materials used in the following examples and comparative examples are products manufactured and sold by Dainippon Ink Chemical Industry Co., Ltd. The trade names of products of other companies will be listed in parentheses. All "parts" described under M are based on weight. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The dispersion method and evaluation method when making pigment dispersions are as follows. After adding 200 parts of 0.5 ΐ »ιηΨ gel ball (manufactured by Sancobond Co., Ltd.) mixed with various raw materials, the coating coating machine of K Toyo Seiki was dispersed for 1 hour to prepare a pigment dispersion. The viscosity of the dispersion was measured by a viscometer. This pigment dispersion liquid K coating roller was applied to a glass plate having a thickness of 1 miB, and sintered at 140 ° F for 10 minutes to prepare a film plate having a dry film thickness of 1 / im by drying. The 20 °-20 ° gloss of this coating film was measured with the following configuration using the GM-26D of Murakami Seken Co., Ltd. and contrast shading of the coating film. Backlight / Polarizing Film 1 / Coated Plate / Polarizing Film2 / Color Luminance Meter Backlight: Lamp for LCD (Made Extension Systems) Polarizers 1 and 2: NPE-G 1220 DUN (Nitto Denko Corporation)-18 -This paper size is in accordance with China National Standard (CNS) A4 (210X297 mm). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 588094 A7 B7. 5. Description of the invention (l7). Color luminance meter: BM-7 (Tupcon) Manufacturing) The distance between polarizing film 2 and color luminosity meter: 50cm (actual example 1) Add 5 parts of acetate oleate to C * I. Pigment Green 36 Pigment Prize (including 100 parts of pigment solids), at 70 1C Heat and stir for 30 minutes. Then, the pigment composition containing MG C. I. Pigment Green 36 as a main component was obtained by washing with water, drying at 90TC, and pulverizing. Let this be G 1-1. (Example 2) P Η was adjusted to C. I. Pigment Gree η 3 6 pigment (containing 95 parts of pigment solid content) by stirring, and sulfonated copper phthalocyanine pigment was added. The slurry (containing 5 parts by weight of solids) was heated at 70 C for 30 minutes. After heating, adjust the pH to 6.0 to 6.5, and filter, wash with water, dry 90 * 0, and pulverize to obtain a pigment composition with C.I. Pigment Green 36 as the main component. Think of this as G 2-1. (Actual example 3) CI Pigment Green 36 pigment slurry (containing 95 parts by weight of pigment solids) whose pH was adjusted to 8.5 to 9.0 by stirring, and 5 parts of sulfo copper phthalocyanine slurry (containing 5 parts by weight of solid content) ) And acetic acid oleate, heated at 70 C for 30 minutes. After heating, the pH was adjusted to 6.0 to 6.5, and filtered, washed with water, dried with 9100, and pulverized to obtain a pigment composition with MC.I. Pigment Green 36 as the main component. Use this as G3-1. (Example 4) C, I · Pigment Blue 15: 6 Yan-19 at pH adjustment between 8 * 5 ~ 9 · 0- This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) J l · J-^ --- φpack ------ Order ------ (Please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives 588094 A7 B7 V. Description of the invention (dip) Add 10 parts of sulfo copper phthalocyanine pigment slurry (containing 5 parts by weight of solids) and butyl acetate (Da Siler Chemical Industry) to the slurry (containing 95 parts by weight of solid matter) And stir for 60 minutes. Then, the pH was adjusted to 6.0 to 6.5, and filtered, washed with water, dried at 901C, and pulverized to obtain a pigment composition containing MC.I. Pigment Blue 15: 6 as a main component. Think of this as B3-1. (Example 5) To a C.I. Pigment Blue 15: 6 pigment slurry (containing 95 parts by weight of pigment solids) adjusted to a pH of 8 · 5 to 9.0, 10 parts of a sulfocopper phthalocyanine pigment slurry ( Contains 5 parts of heavy solids) and n-butyl formate, and stir for 60 minutes. Then, the pH was adjusted to 6.0 to 6.5, filtered, washed with water, dried at 90D, and pulverized to obtain a pigment composition having C.I. Pigment Blue 15: 6 as a main component. Think of this as B3-2. · (Example 6) To C. I. Pigment Blue 15: 6 pigment slurry (containing 95 parts by weight of pigment solids) adjusted to pH 8.5 to 9.0, 10 parts of sulfone phthalocyanine pigment slurry was added (Contains 5 parts by weight of solid content) and n-butyl propionate, stirring β0 minutes. Then, the pH is adjusted to 6.0 to 6.5, and the pigment composition is composed of (: .1.? 811 ^ «1: 8 丨 1 ^ 15: 6) as the main component by washing with water, drying with 90 ^, and pulverizing. This is referred to as B3-3. (Case 7) 5 parts of C.I. PUment Blue 15: 6 pigment slurry (containing 95 parts by weight of pigment solids) was adjusted to pH 8.5 to 9.0. Copper phthalocyanine pigment slurry (containing 5 parts by weight of solid content) and n-octadecanoic acid acetate-20- This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) JLJ ----- ·· Install ------ order ------ AW (Please read the precautions on the back before filling this page) 588094 A7 B7 V. Description of the invention (19) (Please read the precautions on the back before filling this page ), Heating and stirring at 701C for 30 minutes, and then adjusting the pH to 6.0 to 6.5, and then rinsing, washing with water, drying at 901, and pulverizing to obtain KC.I. Pigment Blue 15: 6 as the main component of the pigment composition. This is referred to as B3-4. Ί Practice Example 8) C. I. Pigment Blue 15: 6 pigment slurry (containing 95 parts by weight of pigment solids) was added to adjust the pH to 8.5 to 9.0, and sulfocopper phthalate was added. Cyan pigment slurry (Contains 5 parts by weight of solids), heat at 701C for minutes. After heating, the pH was adjusted to 6.0 to 6.5, and filtered, washed with water, dried at 90C, and pulverized to obtain a pigment compound having KC.I. Pigment Blue 15: 6 as the main component. Make this B2-1. Below, examples of pigment dispersions will be described. (Example 9) This example explains the dispersion containing Compound 1 G1-1. G1-1 20 · 00 parts Afka-46 (Afka) 10 · 00 parts (4 urethane-based dispersant, the same below K) Eucalypse EEP (United calcium carbide) 35.00 parts Intellectual Property Bureau of the Ministry of Economic Affairs Printed by employee consumer cooperatives (4 propionate-based solvents, the same under M) PMA (Kyowa Fermentation Industry) 35 · 00 parts (4 acetate-based solvents, the same under M) Total 100.00 parts The above composition is dispersed and evaluated Dispersion fluidity and coating film properties. The results are shown in Table 1. Among them, the fluidity of the dispersion liquid and Comparative Example 1 The paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 588094 A7 B7 V. Description of the invention (20) The comparison of L clearly shows that the viscosity at 10 rpm is low. The gloss of the coating film was larger than that of Comparative Example 1. (Please read the precautions on the reverse side before filling out this page) (Comparative Example 1) This example describes the untreated dispersion of C. I. Pigment Green 36. C · I, Pigment Green 36 Untreated Pigment 20.00 parts Afka 46 (Afka) 1 00 parts Eucarbate EEP (Joint Calcium Carbide) 35 · 00 parts PMA (Kyowa Fermentation Industry) 35 · 00 Parts Total 1 0 After dispersing the above composition in 0, 0 part, the dispersion fluidity and coating film property were evaluated. The results are shown in Table 1. Table 1: Dispersion slurry of green pigment 10 r pm Viscosity unit: nt P a · s Coating film gloss 1 Example 9 144 81 Comparative Example 1 1630 38 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Example 10) The example is a description of the dispersion of G3-1 containing compound 1. The paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 588094 A7 B7 V. Description of the invention (21) G3-1 20.00 parts love Fuka 46 (Afka) 10.00 parts yucarate EEP (combined calcium carbide) 35.00 parts PMA (Kyowa Fermentation Industry) 35.00 parts total 100 · 00 parts After dispersing the upper composition, the dispersion fluidity and Evaluation of coating film properties. The results are shown in Table 2. The fluidity of the dispersion was compared with that of Comparative Example 2. The viscosity of the Orpio was obviously lower, and the gloss value of the coating film was larger than that of Comparative Example 2. (Comparative Example 2) This example is an oblique description of G2-1 dispersion which does not contain Compound 1. G2- 1 20,00 parts Afka-46 (Afka) 10.00 parts Eucarbate EEP (United calcium carbide) 35.00 parts PMA (Kyowa Fermentation Industry) 35 · 00 parts Total 1 0. 0 0 parts After the composition was dispersed, the fluidity of the dispersion and the properties of the coating film were evaluated. The results are shown in Table 2. (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -23- This paper size applies to Chinese National Standard (CNS) A4 · (210 × 297 mm) 588094 A7 B7 V. Description of the invention (22 Table 2 · Dispersion slurry of green pigment Example 10 Comparative example 2 10 rpm Viscosity unit: in P a _ 108 582 Coating film gloss 85 44 (Please read the precautions on the back before filling this page) (Actual Case 1 1) 2 0. 0 0 parts 10 ♦ 00 parts 70 ♦ 00 parts 1 00 · 00 parts B3-1 Afka 46 (Afka) PMA (Kyowa Fermentation Industry) Total employee consumption of the Intellectual Property Bureau of the Ministry of Economic Affairs Cooperative prints the above composition after dispersing, and then evaluates the dispersion fluidity and coating film properties. The results are shown in Table 3. The lower the fluidity of the dispersion liquid, the more uniform coating film layer can be obtained. Compared with Comparative Example 3, it shows a lower number at a viscosity of 10 rpm. The larger the gloss value of the coating film is, the more the pigment can be evaluated. The value is also larger than that of Comparative Example 3 1 2) In this example, when B 2-1 is dispersed, K is added to have a compound Butyl acetate of substance 1. 24- This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 588094 A7 B7 V. Description of the invention (23) B2-1 20,00 parts of butyl acetate (Daxi Chemical Industry) 2.00 JL -------- (Please read the notes on the back before filling this page) Afka 46 (Afka) 10. 00 PMA (Kyowa Fermentation Industry) 68.00 total 1 After the composition of K was dispersed in 1.00 parts, the fluidity of the dispersion liquid and the properties of the coating film were evaluated. The results are shown in Table 3. Compared with the comparative example 3, the fluidity of the dispersion liquid was obviously low when the Orpro viscosity was low. The gloss value of the coating film is also larger than that of Comparative Example 3. ί EXAMPLE 3) This example is an oblique description of the dispersion of Compound B3-2 containing Compound 1. Β3-2 20,000 copies of Afka 46 (Afka) 10.00 parts PMA (Kyowa Fermentation Industry) 70 · 00 parts Total 1 0. 0 0 After dispersion, the fluidity of the dispersion and the properties of the coating film were evaluated. The results are shown in Table 3. It is clear from the comparison of the fluidity of the dispersion with Comparative Example 3 that the viscosity of Orpni is low. The gloss value of the coating film was also larger than that of Comparative Example 3. (Example 14) This example is an oblique description of the dispersion of B3-3 containing Compound 1. -25- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 588094 A7 B7 V. Invention Description (24) Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economics B3-3 Affka PMA (Total will K is evaluated on the group, and the results are compared with Comparative Example 3 and Comparative Example 3. (Example 15) This example is a needle B3-4 Evka PMA (K is evaluated in total. Its knot viscosity is compared with that of Comparative Example 3 ( Comparative Example 3) In this example, needle B2-1 Efka PHA (a total of 20 · 00 parts 10.00 parts 70 · 00 parts 100 · 00 parts are dispersed, and the dispersion fluidity and coating film properties are evaluated as shown in Table 3 The liquidity of the dispersion is obviously low at the viscosity and ratio of Orpin. And the gloss value of the coating film is also greater than 46 (Efka) Kyowa Fermentation Industry) The obliqueness of the dispersion containing B3-4 of compound 1. 20 · 00 parts 46 (Efka) 10 · 00 parts Kyowa Fermentation Industry) 70 · 00 parts 100 · 00 parts are dispersed, and the results of the dispersion fluidity and coating film properties are shown in Table 3. Known dispersion The fluidity of lOrpin is obviously lower than that of Example 3. And the gloss value of the coating film is also large. The oblique description of the dispersal of B2-1 of Wu 1 1. 2 0 · 0 0 parts 46 (Efka) Xiehe Fermentation Industry) 10 ♦ 00 parts 7 0 · 0 0 parts 100 · 00 parts —r;- (Please read the precautions on the back before filling this page) ---- 1 Order, -26-This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 588094 A7 B7 V. Explanation of the invention (25) After dispersing the composition on M, the fluidity of the dispersion and the properties of the coating film are evaluated. The results are shown in Table 3. Table 3: Dispersion slurry of blue pigment 10 rpm Viscosity unit: m P a · s Coating film gloss Example 11 23 144 Cell example 1 2 27 108 Example 1 3 28 102 Example 1 4 32 99 Cell Example 15 21 120 Comparative Example 3 39 85 (Actual Example 16) Starting from this example, the examples of the color resist body of the ocher sheet will be described. First, a transparent reducing agent is produced from a combination under M. This paper size applies to Chinese National Standard (CNS) A4 specification (210 × 297 mm) (Please read the precautions on the back before filling this page)

588094 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(26 ) 阿羅尼克斯M7100 (東亞合成化學工業製造)11·00份 (4聚酯丙烯酸醅樹脂) KAYARAD DPHA (日本化藥公司製造) 10·00份 (4二季戊四醇丙烯酸己酯,光聚合性單體) KAYACURE ΒΡ - 1 00 (日本化藥公司製造) 2.00份 二苯甲酮,光聚合起始劑) 友卡酯ΕΕΡ (聯合電石公司製造) 27.00份 總計 50 . 00份 其次將實施例10所記載50.00份組成之顔料分散液, Μ 50 r pm攪拌機予Μ攪拌,將Μ上組成之降低透明劑50 份以10分鐘時間滴下,再撹拌10分鐘得綠色色阻體。此 色(5Β體的分散液流動性與塗膜性狀的評估結果如表4所 示。分散液流動性即以黏度愈低愈能獲得均勻膜厚之塗 膜,已知在1 0 r P iR黏度與比較例4比對顯然較低。又塗 膜光澤及塗膜對比,數值愈大愈表示顔料可被微分散, 據此可逕加評估。關於此其數值則大於比較例4 。 (比較例4 ) 將5 0. 00份於比較例2所述及組成之顔料分散液,由 500 rpm分散攪拌機加Μ攬拌,將50份於實施例16所述組 成之降低透明劑以10分鐘時間使之滴下,再攪拌10分鐘 而得綠色色阻體。此色阻體的分散液流動性與塗膜性狀 的評估結果如表4所示。 本紙張尺度適用中國國家襟準(CNS ) Α4規格(210Χ297公釐) —------•衣-----ί ^------0· (請先閱讀背面之注意事項再填寫本頁) 588094 A7 B7 五、發明説明(27 ) 表4 :綠色色阻體 lOrpie黏度 塗膜光澤 塗膜 單位:πι P a · s 襯比度 實施例1 6 7. 2 133 915 比較例4 35 · 6 112 797 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 (實施例17) 將50.00份實施例15所述組成之顔料分散液M 500rpm 之分散攪拌機加K攪拌,Μ 50份由實施例16所述組成之 降低透明劑共花10分鐘時間予Κ滴下,再攪拌10分鐘而 得籃色色阴體。此色阻體的分散液流動性與塗膜性狀的 評估结果,如表5所示。比對比較例5 , Κ本例較具有 優異之分散液流動性與塗膜性狀。 (實施例1 8 ) 本實施例係在實拖例15之顔料分散液組成追加Κ具有 化合物2之DMF(N,N-二甲基甲醯胺/三菱瓦斯化學公司 製造,Μ下相同)做為分散肋劑製作成顔料分散液,並 用此製作色阴體。 顏料分散液係由Μ下組成所製作。 一29 - 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) 訂 Φ 588094 A7 B7 五、發明説明(28 ) B 3-4 20,00份 DMF (三菱瓦斯化學) 2 , 0 0份 愛夫卡46 (愛夫卡) 10.00份 PMA (協和發酵工業) 68.00份 總計 1 0 0 . 0 0份 接著,將5 0.00份顔料分散液以500^1〇分散攪拌機加 以攪拌,Μ 10分鐘的時間滴下50份實施例16所述組成之 降低透明劑,再攪拌10分鐘而得藍色色阻體。此色阻體 的分散液流動性及塗膜性狀之評估結果如表5所示。與 比較例5對比則以本例之分散液流動性及塗膜性狀較為 優異,如與實施例17比較亦Μ本例更能獲得優良之結果、, (比較例5 ) 將50.00份由比較例3所述組成之顏料分散液以500 rpro分散攪拌機加Μ攪拌,並Κ10分鐘的時間滴下50份 由甯施例16所述組成之降低透明劑,再攪拌10分鐘而得 Μ色色(5目體。此色阻體之分散液流動性與塗膜性狀之評 估結果如表5所示。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 一30- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) 588094 A7 B7 五、發明説明(29 ) 表5 :藍色色阻體 1 0 r ρ οι黏度 塗膜光澤 塗膜 單位:m P a · s 襯比度 實施例1 7 4 · 6 102 512 實施例1 8 4.1 110 560 比較例5 7.4 88 369 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 產業上之可利用性 依照本發明得知K往相同程度的低成本改良超越既有 之可供使用於各種塗料,印刷油墨,或滹色片材料等顏 料分散液的分散液性狀及塗膜性狀。如將本發明之顔料 組成物或顔料分散液做為滤色片使用時,因顔料分散性 高的結果,可大幅改善塗膜光澤或塗膜襯比度適性,而 可獲得具有高襯比度之均質塗膜。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 申請曰期 案 號 ---{- j/r .,_/ 0-„ 19fe9, 3,4 88imni . 類 別 % •一........ -A4 C4 9915182 厂、μ工合猢田尽局填狂) (93年1月口丨吵丄/ —Ί II專利説明書588094 發明 一、新型名稱 中文 固體狀顏料組成物 英 文 SOLID PIGMENT COMPOSITION 姓 名 國 籍 發明 創作v 1. 岩崎健二 2. 河瀨一郎 3. 荒木慎悟 4. 村田春夫 1 -4皆屬日本 裝 住、居所 1. 鹿兒島縣國分市野口叮21-21-111 2. 千葉縣成田市吾妻1 丁目23-210 3. 大阪府高槻市南芥川町4-26_504 4. 千葉縣佐原市與倉699 - 35 訂 姓 名 (名稱) 大日本油墨化學工業股份有限公司 (大日本Y >牛化學工業株式畲社) 經濟部中央標準局員工消費合作社印製 線 國 籍 曰本 申請人 住、居所 (事務所) 代表人 姓 名 東京都板橋區坂下3 丁目35番58號 奥村晃三 本纸張尺度適用中國國家榡準(CNS ) A4胁(21GX297公瘦)588094 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (26) Aronix M7100 (manufactured by Toa Synthetic Chemical Industry) 11.00 parts (4 polyester acrylic resin) KAYARAD DPHA (Japanese Chemicals) Manufactured by the company) 10,000 parts (4 dipentaerythritol hexyl acrylate, photopolymerizable monomer) KAYACURE BP-1 00 (manufactured by Nippon Kayaku Co., Ltd.) 2.00 parts of benzophenone, photopolymerization initiator) yucalate ΕΕΡ (Manufactured by United Calcite Corporation) 27.00 parts in total 50. 00 parts Next, 50.00 parts of the pigment dispersion liquid of the composition described in Example 10 was stirred by a Μ 50 r pm mixer to Μ, and 50 parts of the reducing agent of the composition on Μ was removed for 10 minutes. Time dropped, and stirred for another 10 minutes to obtain a green color resist. The results of the evaluation of the dispersion fluidity and coating film properties of this color (5B body) are shown in Table 4. The dispersion fluidity is that the lower the viscosity, the more uniform the thickness of the coating film can be obtained. It is known to be at 10 r P iR The viscosity is obviously lower than that of Comparative Example 4. In addition, the gloss of the coating film and the comparison of the coating film, the larger the value, the more the pigment can be finely dispersed, which can be evaluated based on this. The value is larger than that of Comparative Example 4. (Comparison Example 4) 50. 00 parts of the pigment dispersion liquid of the composition and composition described in Comparative Example 2 were mixed with a 500 rpm dispersing mixer and mixed with M, and 50 parts of the transparent reducing agent with the composition described in Example 16 was taken for 10 minutes. Let it drip and stir for another 10 minutes to obtain a green color resist. The evaluation results of the dispersion fluidity and coating film properties of this color resist are shown in Table 4. The paper size applies to China National Standard (CNS) Α4 specifications (210 × 297 mm) ———---- • 衣 ----- ί ^ ------ 0 · (Please read the precautions on the back before filling out this page) 588094 A7 B7 V. Description of the invention ( 27) Table 4: Green color resist lOrpie viscosity coating film gloss coating film unit: π P a · s contrast ratio Example 1 6 7. 2 133 915 Comparative Example 4 35 · 6 112 797 (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Example 17) 50.00 parts of pigment with the composition described in Example 15 are dispersed Disperse the mixer with liquid M at 500 rpm and stir with K. The 50 parts of the reducing transparent agent composed of Example 16 took a total of 10 minutes to drop to K, and then stirred for 10 minutes to obtain a basket color shade. Dispersion of this color resist The evaluation results of liquid fluidity and coating film properties are shown in Table 5. Compared with Comparative Example 5, this example has superior dispersion liquidity and coating film properties. (Example 1 8) This example is based on The pigment dispersion liquid composition of Example 15 was supplemented with DMF (N, N-dimethylformamide / Mitsubishi Gas Chemical Co., Ltd., the same under M) with compound 2 as a dispersing rib agent to prepare a pigment dispersion liquid, and used This color shade body is made. The pigment dispersion is made of M. I 29-This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) Order Φ 588094 A7 B7 V. Description of the invention (28) B 3-4 20,00 DMF (Mitsubishi Gasification 2) 0 0 parts of Afka 46 (Afka) 10.00 parts of PMA (Kyowa Fermentation Industry) 68.00 parts for a total of 1 0. 0 0 parts Next, 5 0.00 parts of the pigment dispersion is dispersed in a 500 ^ 10 blender After stirring, 50 parts of the transparent reducing agent having the composition described in Example 16 was dropped for 10 minutes, and then stirred for 10 minutes to obtain a blue color resist. Table 5 shows the evaluation results of the dispersion fluidity and coating film properties of this color resist. Compared with Comparative Example 5, the dispersion fluidity and coating film properties of this example are excellent. If compared with Example 17, this example can obtain better results. (Comparative Example 5) 50.00 parts from the comparative example The pigment dispersion liquid of the composition 3 was stirred with a 500 rpro disperser and Μ, and 50 parts of the lowering transparent agent of the composition described in Example 16 was dripped for 10 minutes, and then stirred for 10 minutes to obtain a MU color (5 mesh body). The evaluation results of the dispersion liquid and coating film properties of this color resist are shown in Table 5. (Please read the precautions on the back before filling this page.) Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) 588094 A7 B7 V. Description of invention (29) Table 5: Blue color resist 1 0 r ρ οι Viscosity coating film gloss coating film unit: m P a · s Contrast Example 1 7 4 · 6 102 512 Example 1 8 4.1 110 560 Comparative Example 5 7.4 88 369 (Please read the precautions on the back before filling this page) Intellectual Property Bureau, Ministry of Economic Affairs, Consumer Consumption Cooperative, Printing Industry Availability According to the present invention, it is learned that the same low-cost improvement of K is beyond the existing dispersion and coating film properties of pigment dispersions that can be used in various coatings, printing inks, or ocher sheet materials. When the pigment composition or pigment dispersion is used as a color filter, the gloss of the coating film or the compatibility of the coating film contrast ratio can be greatly improved due to the high pigment dispersibility, and a homogeneous coating film having a high contrast ratio can be obtained. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) Application date number --- {-j / r., _ / 0- „19fe9, 3,4 88imni. Category% • One .... ...... -A4 C4 9915182 Factory, μ Engineering Co., Ltd. Putting it all together (January 1993 Mouth 丨 Noisy / --Ί II Patent Specification 588094 Invention One, New Name Chinese Solid Pigment Composition English SOLID PIGMENT COMPOSITION Name Nationality Invention Creation v 1. Iwasaki Kenji 2. Kawase Ichiro 3. Araki Shingo 4. Murata Haruo 1-4 are all Japanese houses and residences 1. Noguchi, Noguchi 21-21, 111, Kagoshima Prefecture 2. Agatsuma 1, Narita 23-210, Narita City, Chiba Prefecture 3. Osaka 4-26_504, Minamikugawa-cho, Takahata City 4. 699-35, Yakura, Sawara, Chiba Prefecture Name (Name) Dainippon Ink Chemical Industry Co., Ltd. (Danippon Y > Niu Chemical Industries Co., Ltd.) Employees, Central Standards Bureau, Ministry of Economic Affairs Consumption Cooperative Printed Line Nationality Japanese applicant's residence, residence (office) Name of representative Representative No. 3, 35, Sakashi, Banqiao District, Tokyo No. 58, Okumura, No. 3 Paper size applies to China National Standards (CNS) A4 (21GX297) thin)

Claims (1)

588094 —______1:」,_ 六、申請專利範圍 第88 1 03 30 1號「固體狀顏料組成物」專利案 (93年1月12日修正) Λ申請專利範圍: 1 · 一種固體狀顏料組成物,其包含顏料及相對於該顏 料而言0 · 5〜30重量%的由以下化學式(I )所代表之 化合物1, 〇 = c-o-r2 式中1^爲Η或碳數1〜3之飽和烷基,R2爲碳數4 〜1 8之飽和烷基或不飽和烷基。 2 ·如申請專利範圍第1項之顏料組成物,其中顏料爲 酸性顏料。 3 ·如申請專利範圍第1或2項之顏料組成物,其中包 含有1種或2種以上副顏料、顏料衍生物、染料。 4 · $請專利範圍第3項之顏料組成物,其中副顏料 爲酸性顏料,而顏料衍生物爲酸性顏料之衍生物, 染料爲酸性染料。 5 · $[] ψ §靑$ %範圍第4項之顏料組成物,其中副顏料 、顏料衍生物以及染料係具有磺酸基。 6 ·如申g靑專利範圍第1或2項之顏料組成物,其係用 爲濾色片材料。 7 · $ g靑專利範圍第3項之顏料組成物,其係用爲濾 一 1 一 588094 六、申請專利範圍 色片材料。 8 .如申請專利範圍第4項之顏料組成物,其係用爲濾色 片材料。 9 .如申請專利範圍第5項之顏料組成物,其係用爲濾色 片材料。 -2 -588094 —______ 1: ”, _ VI. Patent Application No. 88 1 03 30 No. 1“ Solid Pigment Composition ”(Amended on January 12, 1993) Λ Application Patent Range: 1 · A solid pigment composition It contains a pigment and a compound represented by the following chemical formula (I) 0.5 to 30% by weight relative to the pigment 1. 〇 = co-r2 where 1 ^ is saturated with Η or carbon number 1 ~ 3 Alkyl, R2 is a saturated or unsaturated alkyl having 4 to 18 carbon atoms. 2. The pigment composition according to item 1 of the patent application scope, wherein the pigment is an acidic pigment. 3. The pigment composition according to item 1 or 2 of the patent application scope, which contains one or more secondary pigments, pigment derivatives, and dyes. 4. The pigment composition according to item 3 of the patent, wherein the auxiliary pigment is an acidic pigment, the pigment derivative is an acidic pigment derivative, and the dye is an acidic dye. 5 · $ [] ψ § 靑 $% The pigment composition of item 4 in which the subpigments, pigment derivatives, and dyes have a sulfonic acid group. 6. The pigment composition as claimed in item 1 or 2 of the patent application, which is used as a color filter material. 7. The pigment composition of item 3 in the patent scope, which is used as a filter. 1-1 588094 6. Patent scope of color material. 8. The pigment composition according to item 4 of the scope of patent application, which is used as a color filter material. 9. The pigment composition according to item 5 of the patent application scope, which is used as a color filter material. -2 -
TW88103301A 1999-03-04 1999-03-04 Solid pigment composition TW588094B (en)

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