TW585779B - Transparent solid detergent composition - Google Patents

Abstract

An object of the invention is to provide a transparent solid detergent composition having improved feeling of use and resistance to reducing solubility etc. A transparent solid detergent according to the invention includes 3.5 wt% or above of specific aminoethylsulfonate based equivalent ions of the fatty acid salt, sodium salt of fatty acid and/or potassium of the sodium salt thereof salt of fatty acid; humectant; and water.

Description

585779 A7 V. Description of the invention G) [Technical field of the invention] The present invention relates to a transparent solid detergent composition, and in particular to an improvement of the fatty acid counter ion composition. [Prior art] The transparent solid detergent composition has a sense of transparency because of its transparency. If a suitable amount of dyes and pigments are added, it can have a deep color tone and a metallic feel, so it is especially suitable for high-level face washing. Widely used in materials

Printed in the past by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. As a component of the transparent solid detergent composition, it is based on fatty acid soap and other substances, and is added with glycerin and strict sugar as transparent agents. For the mainstream. The fatty acid soap used as a base is mainly an alkaline metal soap using sodium, potassium, or the like as a counter ion of a fatty acid. These fatty acid basic metal soaps have the advantages of low cost, good foamability, and smooth foam, but on the contrary, they are slightly inadequate in reducing solubility, and exhibit tingling sensations after use. At the same time, because of concerns about tingling sensation after use, although soaps made from weak bases such as triethanolamine or 2,6-diaminohexanoic acid and fatty acids can also be used, they have not been sufficiently improved. [Disclosure of the Invention] The present invention has been made in view of the problems of the prior art described above, and aims to provide a transparent solid cleaning composition which improves the usability and the solubility, and the like. In order to achieve the above object, the inventors have conducted an intensive review and found that the use of fatty acid N-methylaminoethanesulfonic acid alkali metal salt, aminoethanesulfonic acid alkali metal salt, and sulfinylaminoethanesulfonic acid alkali metal salt , Can become non-destructive, transparent This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1 311810 r ------- order — line 585779 A7 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Description of the invention (2j has excellent transparent solid detergent composition with reduced dissolution, no tingling sensation, etc., and completed the present invention. That is, the present invention relates to a transparent solid detergent composition, which Features: 3.5% or more of one or two or more fatty acid salts selected from the group consisting of compounds represented by the formulae (I) to (ΠΙ): R- C00-H2N + (CH3)-CH2- CH2- S03 -Χ + ··· (I) R- COO-H2N +-CH2- CH2- S〇3-X + ... (II) R- COO—H2N +-CH2- ch2- S02-X + ... (III) ( However, 'where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and X represents a metal or organic test)' sodium salts of fatty acids and / or potassium salts of fatty acids , Humectant, and water compounded. One more, in the composition of the present invention, the balance ion of lipid fatty acid, expressed in Molar ratio, the general formula (I) to (m) of the balance ion: 5 ~ 50; Sodium: 40 ~ 95; Potassium: 0 ~ 20 is more suitable. In the composition related to the present invention, the total amount of fatty acid salts is 35 to 55% by weight, and the humectant is 15 to 35% by weight. It is preferably 15 to 25% by weight. In addition, in the composition related to the present invention, polyhydric alcohols containing 3 or more carboxyl groups in a molecular core are subjected to addition polymerization of 2 to 100 mol propylene oxide and 5 〇 Polyethylene-based polyether humectants below mol, accounting for 5 of the total amount of humectants. The paper size is applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) 311810 Read the note at the back Γ 【Page i IIIII Order

585779 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (It is more suitable to 50% by weight. In addition, in the composition related to the present invention, fatty acid salts, humectants, and water in the molten state are poured into the frame. It is more suitable to cool and solidify into a transparent solid detergent composition. At the same time, the "transparent solid detergent composition" in the present invention is substantially transparent in the state of removing colorants such as dyes and pigments. [Explanation of the drawings] FIG. 1 is an explanatory diagram of an appropriate manufacturing process of the transparent solid detergent composition related to the present invention. [Best Mode for Implementing the Invention] The following is a description of a preferred embodiment of the present invention. In the present invention, R in the general formulae (I) to (ΠΙ) is a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms; specific examples include heptyl, octyl, nonyl, decyl, and eleven Linear saturated hydrocarbon groups such as alkyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, and tetradecyl , 2-methylheptadecyl, 2-ethylpentyl, etc. Branched saturated hydrocarbyl, 8-heptadecenyl, oleenyl, 4,6-octadecadienyl, linear unsaturated hydrocarbon, 2-methyloctadecyl-6-alkenyl, etc. Unsaturated hydrocarbon groups, etc. In the general formulae (1), (II), and (III), X is an alkali metal such as sodium, potassium, or lithium, triethanolamine, diethanolamine, or 2,6-diamino group. Organic test of acid, etc. Also, in the present invention, R of fatty acid R — COO— of sodium fatty acid sodium salt or potassium salt of fatty acid and R of fatty acid in general formulae (I) to (IΠ) are defined above. Standard (CNS) A4 size (210 X 297 mm) 311810 Read the note on the back

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A7 A7 B7 1. Description of the invention (same. Therefore, the fats of the general formulae (I) to (m), sodium fatty acid, and potassium fatty acid are preferably the same substance. Furthermore, in the present invention, fatty acids heated and melted In particular, it is particularly suitable to add a basic agent containing a fatty acid as a counter ion and a substantially equivalent aminoethanesulfonic acid counter ion, sodium ion, and potassium ion. Also, in the present invention, more suitable moisturizers include, for example, Sucrose, sorbitol, glycerin, 1,3-butanediol, propylene glycol, dipropylene glycol, and other saccharin or polyalcohols. The humectants that are particularly suitable in the present invention are those with more than 3 carboxyl groups in each molecule. In the valence alcohol core, polyether compounds of 2 to 100 moles of propylene oxide and ethylene oxide of 50 moles or less are polyadditionally compounded. It is preferable that the blending amount of the polyether moisturizer accounts for the total moisturizing dose 5 to 5Q weight / 0. Examples of polyvalent alcohol cores at this time include glycerol, diglycerol, pentaerythritol, dipentaerythritol, and various monosaccharides, disaccharides, oligosaccharides, etc. as exemplified below. Disaccharides Examples can be listed Trehalose, sucrose I, sugar, printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs of the Milk Industry 2. Also, 'polysaccharides can be listed such as gentiotriose, raffinose, melezitose, threose, cellulose, hemiose Cellulose, powder, chitosan, etc. Examples of sugars include D-sorbitol liver, D-mannose, D-mannose, etc. As sugar carboxylic acids, examples include " mannose, D — Glycosylic acid, saccharin acid vinegar, etc. Examples of hydrocarbon derivatives include: hexaol, acornose, gluco_aldehyde, methylfructose hexacycline 7 alcohol anhydride, ethyl glucoside , Gluconolactone, arbutin, „Sorbus ^ sorbose, diethyl sorbitol sorbitol, sorbose post early acetamidine; __ sugar dianhydride lauric acid tablets, Yamamoto paper standard applicable Chinese National Standard (CNS) A4 Specifications (210 ^〉 公 楚)-4 311810 585779 A7 ---------— B7 V. Description of the invention (5) Sugar alcohol anhydride oleate, glucose phosphate, etc. In addition, it is relevant in the present invention. The transparent solid detergent composition is added with the above-mentioned essential ingredients, and if necessary, the detergent composition usually contains soap. Anionic surfactants such as alkyl sulfate vinegar (salt), polyethylene oxide alkyl sulfonic acid (magic acid, succinyl myrtic acid (salt), anionic surfactants, sialin-type amphoteric surfactants, beet test-type amphoteric interface) Amphoteric surfactants such as surfactants, non-ionic surfactants such as polyethylene oxide, ethoxylate, polyethylene oxide fatty acid vinegar, rigorous sugar fatty acid vinegar, glycosides, polysaccharide hydroxy aliphatic ethers, etc. Cationic surfactants such as ammonium alkylammonium, extractives from plants such as Coptis chinensis, Paeonia lactiflora, Iris, Brassica oleracea, trans-aminomethylcyclohexanoic acid, arbutin and other pharmaceutical ingredients, spices, preservatives, etc. It can be appropriately blended. Also, the transparent solid lotion composition according to the present invention is suitably manufactured as shown in FIG. 1. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, namely, ‘lower alcohols such as various fatty acids and ethanol are heated and melted in 40 to 600 c, and alkalis formed by counter ions are added for neutralization. Here, humectants such as sugars and polyalcohols, other additives, and medicaments are added to dissolve uniformly ', and then flavors and pigments are added as needed, and the liquid is flowed into the mold frame, and cooled and solidified. Thereafter, the mold frame is removed, and if necessary, the mold frame is cut, and dried and aged between 40 and 60 days. It can be ground, dried, shaped, wiped, and packed as needed. Hereinafter, preferred embodiments of the present invention will be described. Evaluation method In the following test examples, evaluation was performed as follows. Curability This paper is sized for China National Standard (CNS) A4 (210 X 297 mm) 5 311810

〇: The whole is in a solid state △ ... Although the whole is in a solid state, it is soft X: The whole cannot be in a solid state Transparency Each sample is cut to a thickness of 20 mm evenly and placed on a 26-pound typo. Can it be judged. ◎: Can be clearly interpreted 〇: Can be interpreted Δ: Barely interpretable X: Cannot be interpreted uniformly 0: The whole is transparent and uniform △: Although the whole is transparent but partially uneven X: The whole is crystallized and precipitated (20 people, 20 to 40 years old) Put the test solid in the normal state when washing your face, foam it with tap water, and then evaluate 0 ◎: Foaming pole 妤: Good foaming △: Foaming Normal X: The tingling sensation after washing with poor foaming was performed by female participants (20, 20 to 40 years old) in the same way as when washing their faces (please read the precautions on the back before filling this page). Order ----- ---- Online ip · Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with the Chinese National Standard (CNS) A4 (210 X 297 mm) 6 311810 Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Β7 5. Description of the invention (7) State: Put the tested solid soap on your hand, foam it with tap water, wash your face, and then evaluate it. :: No tingling sensation, very good 〇: No tingling sensation, good △: Normal X: Tingling sensation Dissolution reduction The friction solubility reduction was evaluated based on JIS K — 33 04. That is, on a film surface moistened with tap water prepared at 40 ° C, a specimen with a certain weight (section: 15 mm x 20 mm) is loaded, and the film is rotated and frictionally dissolved for 10 minutes. Thus, the weight before and after dissolution by friction, Obtain the equivalent frictional solubility of a certain area. ◎: 20 or less 〇: 20 to 35 △: 35 to 50 X: Review of counterions of fatty acids above 50 First, the present inventors used sodium, N-methylaminoethanesulfonic acid, N-aminoethanesulfonic acid, and subamino As a counter ion of the mixed fatty acid, ethanesulfonic acid and the like were used to prepare a transparent solid detergent composition, and various evaluations were performed. The results are shown in Table 1 below. Specifically, a salt of a mixed fatty acid (tallow fatty acid / coconut oil fatty acid = 8/2) is mixed at a ratio shown in the following table to form various fatty acid salts. The fatty acid salt is 40% by weight, sorbitan is 10% by weight, and glycerin is 5 4 Order ---- (Please read the precautions on the back before filling this page) Line ^ · This paper size applies to Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) 7 311810 〇 ◎ 〇〇 ◎◎ 〇 ◎ 〇〇 ◎◎ 〇 ◎ 〇〇 ◎◎ 〇 ◎ 〇 △ > < 〇 Printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economic Affairs 585779 A7- --Έί ------_ V. Description of the invention (8) The mixed ingredients of weight%, sugar 10 weight%, ethanol 15 weight%, and ion-exchanged water 20 weight% are used as raw materials, and they are washed by a frame method.剂 组合 物。 Composition. That is, the above-mentioned raw materials are heated in 70 to 800c to dissolve uniformly, and then injected into the mold frame. After that, it is cooled, and the solidified product is dried and cooked to form a solid detergent composition. . When the counter ion is not particularly limited, it is expressed as a molar ratio of fatty acid to equivalent weight. Table 1 _ Test Example 2 Test ^ Sodium 10080 80 80 Sodium N-methylaminoacetate _ 20 — Sodium N-aminoacetate _ 20 — Sodium sulfinamide — -20 Cured Transparentness, uniformity, foaming, tingling sensation and dissolution after face washing are reduced. From Table 1 above, for the same fatty acid, compared with the case with only sodium counterions, it is known that N-methylaminoethanesulfonic acid and N- In the case of sodium aminoethanesulfonate and aminoethanesulfonic acid counter ion of sodium N-sulfinic acid, there are significant improvements in foaming properties, tingling sensation after washing the face, and reduced dissolution. The acetic acid ratio of aminoacetic acid-based counterions is reviewed by the inventors, and the appropriate counterion ratio (mole ratio) of sodium N-methylaminoacetic acid is reviewed. The test method is based on Table 1 above. Examples are benchmarks.

This paper size applies Chinese National Standard (CNS) A4 specification (21 × 297 mm) 8 311810 585779 、 Instructions of the invention (9 Cases Sodium Sodium Acetate SlTbli 'Transparency Uniformity Foaming Stinging After Washing Face Reduced sensation of dissolution Table 2 6 7 99 ^ 90 1 5 10 ◎ ◎ ◎ 〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇 8 9 10 11 12 Τ〇Γ " To 50 40 20 30 40 50 60 〇〇〇 〇 ◎ ◎ ◎ Δ △ 〇〇〇〇〇 × 〇〇〇〇__ ◎ ◎ ◎ ◎ ◎ ◎ ◎ — The balance of the sulfonic acid ion ^ 欤 is equal to 5 or more, and it is effective to have a molar ratio of 5 or more. The present inventors conducted a further review of N-methylaminoacetic acid. The presence of 35% by weight or more in the composition determines the addition effect. The addition effect is generally potassium ions, in addition to the cleaning power. In addition to improving the foaming property, there is also a tendency to promote softening. Here, the present inventors reviewed the effect of potassium ion addition under various compounding amounts of sodium N-methylaminoethanesulfonate. Based on the above, balance off Molar ratio is used. The test case printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed potassium potassium N-methylaminoethane sulfonate sodium bisulfate " transparency uniformity foaming tingling sensation after face washing is reduced table 3

The private paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 311810 ○ ◎ ◎ ◎ 〇 〇 〇 〇 X 〇 Δ 〇 A7 B7

XII 〇 ◎ 〇 ◎◎ 〇 〇 ◎ 〇 ◎◎◎ 〇 ◎ 〇 ◎◎◎ 〇 ◎ 〇 ◎ 〇〇 〇 ◎ 〇 ◎ 〇 X Δ

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 585779 V. Description of invention Q) Table 4 Test example 21 22 23 24 25 26 Μ 80 7 5 ^ 〇 ~ 60 ^ Τ〇 ^ Τ〇 ^ Ύ () Potassium 20 20 20 20 20 20 20 Sodium N-methylaminoethanesulfonate 0 5 10 20 30 40 50 Curing transparency uniformity foaming tingling sensation after face washing is reduced Table 5 Test example ί 60 50 40 60 ~ ΤΓΤ ^ 3 〇30 30 30 40 40! 〇Ν-methylaminoethanoic acid sodium 〇10 20 30 0 ι〇2〇Ϊ1Ϊ ± 〇 ~ 〇 ~ 〇 ~ χ ~ 〇 ~ Transparency © ΧΧχχχ Foaming property- — — — — — Stinging sensation after washing face X ~ ~ ~ ~ — Dissolution reduction X —— — — ~ _ 1 It can be seen from the above Tables 3 to 5 that the potassium balance can improve the foaming property, but it exceeds At 20 o'clock, curing is difficult, and it will also affect uniformity. Next, the inventors reviewed the compounding amount of fatty acid salts in the composition. That is, the fatty acid salt portion and the remaining portion are prepared as follows and mixed at an appropriate ratio to obtain a composition. Fatty acid salt portion Mixed mixed fatty acids (C14 / C16 / C1 8 / isoCl 8 = 60/20/10/10) The standard scales of China, China, and Shanghai are applicable to China National Standard (CNS) A4 (21G x 2g7)

311810 585779 The rate is A7. V. The salt of the invention (11) is compounded into sodium fatty acid / fatty acid potassium / month fatty acid N-methylamino acid sodium = 70/10/20. The remainder consisted of 10 parts of sorbitan, 5 valent glycerol, 10 parts of sand bran, 15 parts of alcohol and 20 parts of ion-exchanged water. The above-mentioned fatty acid salt portion and the remaining portion were heated at 40 to 6 G ° C to dissolve them at a ratio shown in Table 6. The solidified product was dried and matured to obtain a solid-derived solid-state detergent composition. Table 6

The amount of moisturizing agent in the acupuncture composition such as the "human" inventor was reviewed. At the same time, the test was performed by adding ethanol to a mixed fatty acid (C14 / C16 / C18 / iSoC18 = 60/20/1/10/1), and heating it to about 6 (rc, Add & sodium sulfide / N-methylaminoethane sulfonate at the ratio shown in the table below to obtain a fatty acid soap portion. ^ The fatty acid soap portion is mixed with the humectant at the ratio shown in the table below. 20 weight 0/0 ion-exchanged water was heated to dissolve in 70-80t, and the detergent composition was prepared by the frame method. The results are shown in Table 7 to 〖〇 ^ (Please read the precautions on the back before filling This page} -------- ^ 0 — — — — — — — — • • ··· Printed by the Employees ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

311810 585779 A7 B7_ V. Description of the invention (12) Table 7 Test example_42 43 44 45 46 Na / N-methylaminoacetic acid 95/5 Soap part 25 35 45 55 60 Total moisturizing dose 45 35 25 15 10 Curability, transparency, uniformity, foaming, tingling dissolution after washing the face is reduced. ◎ ○ 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 △ △ 〇 〇 〇 △ can not manufacture Table 8 Test Example 47 48 49 50 51 Sodium / N-methylaminoethanesulfonic acid 75/25 Soap part 25 35 45 55 60 Total moisturizing dosage 45 35 25 15 10 (Please read the note on the back first? Matters before filling out this page) Uniform curing and transparency The tingling sensation after facial washing is reduced. △△ 〇〇〇〇〇〇〇〇〇 ◎ ◎ ◎ 〇〇 ◎◎ 〇 ◎ 〇〇 ◎ 〇X ----- -------- Order · 1

Line V Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Table 9 Test example 52 53 54 55 56 Sodium / N-methylaminoethanesulfonic acid 50/50 Soap portion 25 35 45 55 60 Total moisturizing dose 45 35 25 15 10 Curability, transparency, uniformity, foaming, tingling dissolution after face washing is reduced △△ 〇〇 ◎ 〇〇〇 ◎◎◎ 〇 ◎ 〇 ◎◎◎ ◎ ◎◎ 〇〇 ◎◎ X ----- This paper size Applicable to China National Standard (CNS) A4 (210 X 297 mm) 12 311810 ^ «5779 A7

58 59 60 T〇 / 60 35 45 55 j5 25 15 〇

△ X X

△ XX △ 〇〇 ◎ ◎ ◎ _ 〇 ◎ ◎. Ethyl sulphur can be seen from the table above ... 0, when the ratio of N-methylamino ^ in the counter ion is increased, the brightness is slightly reduced, but the Moderate addition is expected to improve both transparency, especially when the blending amount of the moisturizing agent is 15 to 35% by weight in the composition, it can improve the transparency of the shirt and reduce the tingling sensation. The addition of 1AAJ moisturizing agent was mixed. Ethanol was added to the mixed fatty acid (C14 / C16 / C18 / isoCl 8 = 60/20/10/10), and it was placed in a reaction pot and heated to about 600c with hydrogen. The ratio of sodium chloride / potassium hydroxide / sodium N-methylaminoethanesulfonate = 80/10/10 is printed and neutralized by the employee consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs to obtain the fatty acid soap portion. Mix 40% by weight of this fatty acid soap portion, 25% by weight of humectant in the ratio (weight ratio) shown in the table below, 15% by weight of ethanol / ❹, and 1% by weight of ion-exchanged water at 40 to 60 °. The solution was heated and uniformly dissolved in C, poured into a cooling frame, and the solidified product was dried and matured to obtain a solid detergent composition.

311810 585779 V. Description of the invention Test example __ Sorbose glycerol sugar oil ether curing uniformity foaming tingling sensation after face washing is reduced by 1 Table 40 shows that 40 20 40 0 0 0 0 0 0 40 15 40 0 0 0 〇〇64 ~ 4〇 " 10 40 10 〇 " 〇〇 ◎◎ 65 ^ ^ 40 0 40 _50 〇〇〇 ◎ ◎ Please read the polyether moisturizer printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs to improve stinging In addition, compared with other moisturizing ingredients, it has an excellent effect. The cyano-ethane ethanesulfonic acid is the most invented. The present inventors reviewed the general formulae (m) to (m). That is, 'add ethanol to mixed fatty acids (cl4 / cl6 / cl8 / isocl8 = 60/20/10/10)' and place it in the reaction steel and heat it to about ° C with sodium hydroxide / potassium hydroxide / Add the aminoethanesulfonic acid counter ion at a ratio of 70/10/20 as shown in the table below to obtain a neutralized fatty acid soap portion. A mixture of 40% by weight of fatty acid soap portion, sorbitan i 0% by weight, 5% by weight of glycerol, 10% by weight of sugar, 15% by weight of ethanol, and 20% by weight of ion-exchanged water was used as raw materials. The frame method is used to prepare a detergent composition. Less dissolve minus 311810

Page order 4 585779 A7 B7 V. Description of the invention (15 Test examples Table 12 Balance ion dissolution reduction Stinging blistering uniformity curing 66 N-methylaminoethanesulfonic acid sodium 67 N-methylaminoethanesulfonic acid Potassium 68 N—Sodium aminoethanesulfonate 69 N—Sodium potassium aminoethanesulfonate 70 N—Sodium sulfinamilide 71 N—Nine aminoacetic acid bell 72 N-methylaminoethanesulfonic acid triethanolamine ◎ ◎◎◎ It can be understood from the results in Table 12 that the alkali metal of the aminoethanesulfonic acid counter ion is There are no particular restrictions. [Examples] The following is a description of suitable blending examples of the present invention. Any blending example is produced by a commonly used method. In addition, any of them has excellent transparency, reduced resistance to dissolution, and a feeling of use. . Printing and Coordination Example of Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1 Dodecanoic acid 7.0% by weight Tetradecanoic acid 10.0 Hexadecanoic acid 3.0 Stearyl stearate 6.0 Isostearyl stearate 1.5 Sorbitol anhydride 7.5 Alcohol 15.0 B Diamine tetraacetate 0.1

This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 15 311810 585779 A7 B7 V. Description of the invention (i6) Sodium hydroxide 1.1 N_methylamino printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Sodium ethanesulfonate 9.2 Sodium hydroxyalkyl ether carboxylate 3.0 Common salt 0.5 Granulated sugar 10.0 POP (9) diglyceryl ether 5.0 BHT 0.1 Pigment amount of ion-exchanged water Remainder Example 2 Dodecanoic acid 5.0% by weight Tetradecanoic acid 10.0 Hexadecanoic acid 3.0 octadecanoic acid 5.0 isooctadecanoic acid 3.0 glycerol 10.0 diglycerol 3.5 sorbitol anhydride 4.0 alcohol 10.0 ethylenediamine tetraacetate 0.1 sodium hydroxide 3.6 N-fluorenylaminoethanesulfonate 3.5 via Sodium alkyl ether carboxylate 2.0 POP (60) Hardened castor oil 2.0: --- ij ^-L ----------- Order ---- (Please read the precautions on the back before filling This page) Thread < (· This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) 16 311810 585779 A7 B7

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (Π) Dodecaneimidazole betaine 2.0 Common salt 0.5 Granulated sugar 10.0 BHT 0.1 Pigment Amount Ion-exchanged water Remaining Example 3 Dodecanoic acid 8.0 Weight? Tetradecanoic acid 12.0 Hexadecanoic acid 4.0 Stearyl acid 6.0 Oleic acid 4.0 Sorbitol anhydride 11.0 Glycerin 5.0 Alcohol 16.5 Ethylenediamine tetraacetate 0.1 Sodium hydroxide 4.2 N-methylaminoethanesulfonic acid sodium 5.5 Table salt 0.5 Granulated sugar 11.0 BHT 0,1 Titanium dioxide 0.1 Pigment amount Amount of ion-exchanged water The remainder of this paper applies Chinese National Standard (CNS) A4 (210 X 297 mm) 17 311810/79 Compound Example 4 Dodecanoic acid 7.0 weight % Tetradecanoic acid 10.0 Hexadecanoic acid 3.0 Stearyl acid 6.0 Isoctadecanoic acid 1.5 Sorbitol anhydride 7.5 Alcohol 15.0 Ethylenediamine tetraacetate 0.1 Sodium hydroxide 6.0 N —Aminoethanoic acid clock 2.1 Hydroxyl Sodium ether carboxylate 3.0 common salt 0.5 granulated sugar 10.0 POP (9) diglyceryl ether 0.1 pigment appropriate amount of ion-exchanged water remaining portion of the Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperation printing [Effect of the invention] As explained above, according to the above The transparent solid detergent K product related to the invention, especially using aminoethanesulfonic acid-based alkali agent as the counter ion of fatty acid, can obtain excellent transparency, resistance to dissolution reduction, washing After the sense of use. .-------- Order ---- (Please read the notes on the back before filling in this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 18 311810

Claims (1)

585779 γτ; only Amendment to the Patent Scope of Patent Application No. 891 1 8933 (December 12, 1992) 1. A transparent solid detergent composition characterized in that 3.5 to 54.9% by weight is selected from the following formula ( I) to one or two or more fatty acid salts of the group consisting of the compounds represented by (III), R-C〇-h2N + (CH3) -CH2-CH2-S03 ~ X + ... (I ) R- co〇-h2n +-ch2- ch2- so3 ~ x + (II) R- C〇〇-H2N +-ch2- ch2- so2-x + (...) (However, in the formula, R represents carbon A saturated or unsaturated hydrocarbon group of 7 to 23, X represents an alkali metal or an organic base), and is composed of a fatty acid sodium salt and / or a fatty acid potassium salt, a humectant, and water, in which the fatty acid salt accounts for 3 5 to 55 weight %, Humectant accounts for 15 to 35% by weight, and water accounts for 15 to 25% by weight. 2 _ As in the transparent solid detergent composition of item 1 of the patent application, the balance ion of fatty acid R — COO — in the composition is expressed in mole ratio as the general formulae (Ϊ) to (ΠΙ) The counter ion is 5 to 50 and the nano is 40 to 95. The transparent solid detergent composition as described in item (2) of Shenyan Patent, the counter ion of fatty acid R-COO- in the composition, in molar ratio. The '' is represented by the general formulae (I) to (III), and the counter ion is 5 to 50, sodium is 40 to 95, and potassium is 0.01 to 20. 4. The transparent solid detergent composition according to item 丨 of the patent application scope, which contains 2 to i in addition to the polyvalent alcohol master compound 311810 x containing 3 to 10 hydroxyl groups in the molecule () 〇 Mole propylene oxide polyether humectant, which accounts for 5 to 50% by weight of the total moisturizing dose. 5. The transparent solid detergent composition according to the scope of the patent application (1). In the composition, Hegu A VIII + human s has a polyvalent alcohol masterbatch containing 3 to 10 hydroxyl groups in a knife. Addition of 2 to 100 moles of propylene oxide and 1 to 50 moles of ethylene oxide ^ molybdenum ether moisturizer, which accounts for 5 to 50% by weight of the total moisturizing dose. The transparent solid detergent composition of the first item is a mixture of heated fatty acids, moisturizers, and water into the molding frame, which is cooled to form a solid solid detergent. Detergent composition. 2 3H810