TW584616B - Porous formed object capable of removing harmful microorganism and method for producing the same - Google Patents

Abstract

A porous formed object capable of removing harmful microorganism comprises an anti-microorganism ingredient which is a quaternary ammonium. The present invention also relates to a method for producing a porous formed object capable of removing harmful microorganism. The invented porous formed object capable of removing harmful microorganism has a strong bonding and/or adhesion between the anti-microorganism ingredient and the porous formed object. Thus, the active ingredient thereon will not escape after a long period of operation so that the anti-microorganism function of the formed object can be maintained for a long period of time.

Description

584616 A7 B7 V. Description of the invention (i) 琎 明 镅 城 The present invention relates to a porous shaped article capable of removing harmful stimulants and a method for preparing the same. Lu Ming 赀 軎 With the advancement of society and science, and the increasing frequency of human-to-human contact, the danger of flooding harmful microorganisms into the environment is becoming increasingly serious. Public clinics, especially waters such as swimming pools, public baths, etc., are the best places for pathogenic bacteria to spread. If the health status of these waters is not maintained properly, people can easily become infected with skin diseases, eye diseases and other diseases. In order to prevent this, Harmful microorganisms in other waters are experiencing growth. Usually, "and other disinfectants" are added to the water to achieve thinning and sterilization. In the Ministry of Economic Affairs, the loss of Quercus spp. And the elimination of f.L. Disasters and fungicides can also be found in water supply plants, sanitary baths, or aquariums that provide water for people or animals. Traditionally, antimicrobial ingredients such as chlorine, bactericides, and algicides were directly added to waters such as one child to comply with the effects of disinfection and sterilization. However, with the loss of water, the content of these antimicrobial ingredients also decreases. Therefore, in order to maintain these waters, the anti-biological composition of the anti-biotic ingredients must be often added to these waters, which in fact adds a lot of economic costs, and the pollution caused by the loss of water will increase the burden. In addition, since these anti-biological components can be added into the «Qin Shui Rong Food 1, Rong 1 attached to the skin *, Jiu Zhi also has a bad effect on" Kang. " In addition, there have been several incidents in Japan recently caused by a 24-hour hot water® bath in the bathroom. This caused poisoning incidents in the creatures. The cause of the poisoning was f, etc .; 1.V4 ΊΝ (AS) Luo :: 1 (Bu: "," Zheng'i 1544401 584616 A7 __B7_ V. Description of the invention (2) (^ 丸 读 ^ # And; i: fp item ear itivrr Bentin) The bathroom is mainly provided in the home. Individual users, because they take into account the adverse effects of antimicrobial ingredients on human health, and are only used by people, most of these users are unwilling and have not considered the addition of antimicrobial ingredients to water, which makes the circulating water harmful to breed The human body ’s microorganisms are not known, and they are infected. In addition, air-borne diseases are increasing, for example, veterans' pathogens (Legionella pneumoniae; Legionella pneumophila) in the cooling tower of the central air conditioner The medium grows and is discharged by the air-conditioning system; bacteria such as Streptococcus pneumon iae and Coryn ^ bacterium diphtheriae are directly transmitted by the air. In order to prevent infection by these bacteria, it is also very necessary Objects with the function of removing harmful microorganisms placed in the air outlet of the air conditioning system or the laboratory's microbial safety prevention system 31. Based on the above reasons, the inventors have conducted research to develop certain anti-guest microorganism components such as quaternary ammonium Rhenium can be supported on truncated ruminants, which can effectively exert long-term antimicrobial function. Among them, quaternary ammonium radon is effective against bacteria (such as Staphylococcus aureus, Escherichia coli, Salmonella bacteria, etc.), yeast [such as Saccharomyces cerevisiae ( SaccharQniYCQS cerevisiae), Candida albicans], full species [such as M. phyllostachys, brown and phyllostachys), and bacteria [eg.] Genus, Chaetoiniu [g I qbqsum], Aspergillus spp. SS (P β nici 1 1 i υ m funiculo ^ uin) 1 has been proposed, but it has not been seen in this «伉 microbial constituents 10 捋« «on. And« So 肷 肷 沆银 Silver guide for biological effects 更 Let ’s learn more. Let ’s take a look at the four-stage pliers 16 dome effect and wait for P base «For example, Tao said h's 7 d -s in the above m. -崤 可 枓 π 芹, 啾 怅 · λ · 4 W pf «v, N:,: Bu 0,-, 11>, 584616

7 7 A B clearly states that it is easy to have five micro-damages, and S is good. Some are excellent. *} Obviously, the original body of the S is finished. However, due to the law, the effective S has a number of things, and the result is that the micro-organisms have an anti-biodegradation before the effect is 0. 0 Biodegradable microbe resistant to 1 item 1 on the lifting system. In this case, the material in the shape of the exposed part is slightly harmful, and there is a removal of ammonium grade of the 1 detoxification system. ≫ 塩One or four other parts are clearly issued. This sub-table is made of glutinous sticky dipping ribs-it is a combination of some ingredients that will be included in the package. This type has a large number of multi-faceted holes. The composition is formed by the entropy of the enzymatic growth micro-I, anti-advance, and so on. The medium carrier is immersed with 1 stain. Use the solution before the solution in the solution or the immersion solution. Ingredients into. Bark-like perforations, pores, micro-organisms, micro-organisms, micro-organisms, anti-micro-energy, micro-¾, energy damage, energy, energy, energy, and biological removal < » One of the kinds of resistance is related to the on-load, the on-load, the on-line, the on-line, the on-line, the on-line, the on-line, the on-line, the on-line, the on-line, the on-line, the on-hole, and the on-the-ground things that have many holes and can be removed. 1 有 有 〇 And Ming Ming clamp hair four grades are divided into f, will be 洱 洱, 洱 激 solution in the raw solution of its anti-corrosive liquid 溲 浆 明 明 合 明 合 状 发 发 混 本 本 the agent Defeated «Expanding the system into a surface. The surface of the method to produce the side of the 坫 坫 micro-costal system made of 荠 special special pieces called a 5? Μ and the use of Μ: ^: 1¾ ^^ 'and ;; L: $ Choose two T < '45 κ 7 Ordering hole Z is called the middle one > ¾ the original one and 5? I & I Gao Genffi Φ ¾ ΡΚΚΙ .4 r tr N k Ο. ≪Λ:; 〇 < yr 584616

AT _B7_ 5. Description of the invention (4) (high surface area / body-to-body ratio), such as nest-like, reticulate, etc. The size of the pores is not limited, as long as a liquid flow or a gas can be passed to exert its effect. The term "molded article" as used in the present invention refers to those shaped into various desired shapes, such as square, polygonal, disc-shaped, or spherical, and there are no restrictions on their size and shape, as long as the desired purpose can be achieved. can. The porous shaped article of the present invention includes a porous carrier and an antimicrobial component supported on the carrier. Since the object of the present invention is porous and has a high specific surface area, it can increase the content of anti-scourge biological components distributed on the porous shaped object of the present invention, and increase the effect of the present invention on removing harmful microorganisms. The porous carcass used in the present invention may be composed of materials that are resistant to temperature and pressure such as ceramics, plastic steel, and the like, and is preferably composed of ceramics. The invention can remove the anti-microbial component contained in the porous shaped articles of harmful stimulants, and is a quaternary ammonium sulfonium. The fourth-order technical structure used in the present invention contains silicon (S 丨). After mixing with water, it is hydrolyzed to form a compound with a structure of -S ί (Ο Η) 3. When it is s, the structure contains Si. After the surface of the object (such as ceramics) composed of 2 and / or A 丨 203, it can form an ib structure with Si02 and / or Al203 in the component of the object, and attach to the surface of the object. Although the four-stage clamp can form a chemical bond with a substance containing Si02 and / Rong A [2 03 (or "Zhao"), and it is attached to the child substance Rong (Rong), 1: After this ffl, the ft knot effect is only four (+ tears on the face of the object 愤 愤), and the four-level clamp attached to the object (Rong Jianlai t, for the four (jing Read Jingjin first; -i.if item ear 4 (& ting)

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1 5 U ΜK 584616 A7 ____B7_ V. Description of the Invention (5) (Qi Xian iw read ^: and Λ /; ΐ .; ΐρ Term Mi ,; the adsorption surface area of the class clamp increases, the inventors conducted in-depth research, Hair buns can rely on the use of a rib bonding surface extender to increase the adsorption surface area of quaternary ammonium rhenium (by about 15 to 1000 times), thereby improving the antimicrobial effect of the porous shaped articles of the present invention. The quaternary ammonium sulfonium of the antimicrobial component of the present invention is a surface bonding agent for rib-bonding surface expanders which is combined with the surface area of the porous shaped article of the present invention, such as silicon dioxide, high specific surface value silica, alumina, and high specific surface area. Oxidation 18 such as Boehmite [available from Condea, Germany] or any substance containing silica and / or alumina. When ordering to manufacture the porous shaped article of the present invention, the ammonium quaternary ammonium is used as an antimicrobial component. The aforesaid co-binder and water are mixed at a ratio of 1: 1 to 1:10, and are ground into a slurry, and the porous body to be used is immersed in the body, and then sintered to obtain a high specific surface area. Tightly adhered to quaternary ammonium The porous support is carried out at 400 to 1500t, preferably at 500 to 800t. ¾ Jilang Central 懔 Mushroom 妁 only X consumption cooperation ft India disaster, and then this verse is highly Than the surface of the porous «body immersion 5 $ dilute with solvent 湏 first quaternary ammonium 塩 solution, and then at 50 to 200, preferably 60 to 150t, and better than 30 to 120TC for starving. Entropy knot There is no absolute limit on the time, depending on the temperature of the porous shaped object used. The temperature is shorter, the temperature is lower, and the time zone is lower. Sol__ such as water, leaven (such as formamidine, ethyl leaven), copper (such as acetone), ether (such as tetrahydrofuran, diacetyl) |, | welding tin (such as methane, dioxane) and cyanide丨 dagger (such as cyanide (Λ, tetracyanide! B carbon 1 荠, 1

1 5 4 U) I 584616 A7 B7 V. Description of the invention (water is better than good and better than 6 degrees ο concentrated to -3. Dipping Μ2 is good to 3%. The best is ¾. It is not necessary to grade ammonium. There are four types of objects in the dip-shaped connection hole. The dry medium K Ming Yufa reprinted the liquid-soluble type pores with many things. The harmful effects of sudden steps and micro-organisms can be removed by removing the expandable surface. Advancing and will not bond but also force and force the intersexual living things should be combined with each other, after the separation of the use of things to make life intimidating and resistance to make it up and because of, by cooperation, glue or objects / Make the shape of the thing. The multi-effects of the fruit and the fruit have a micro-organism that is resistant to the long-term bright that can be removed and the warranty period can be sent out, and the person who uses the product can grow soft or guests. The living thing moves it or removes the person to provide it, and it refers to the system, which regulates the water in the region, and moves the water in the region. The moving finger flow is used here in the ring-shaped micro-circular water parts room for the physical examination of the small hair or four local ten. Net second-class economy, gas-lined water bath air soft, total or public equipment, Water filter "Swimming, using swimming tests such as colonization or field treatment water B type, using a flow bath in the moving room to make the damage of the field can be clear, and the template is small. It is used to make the water-proof and under-reasonable parts of the realm reach the water-like state. The Confucian system is mostly protected by physical protection, and the full-time micro-amp box is harmful to the clan. The water is removed from the place where the objects are shaped like holes. 0 ο If the fruit has been removed, the thief's hair should be sent to the water'r-Zhong Li Cheng pa water hair. Ming'anfa tfF this «make. More time IF use fif in order to hold f hectares of water and water type« I mouth into the outflow flow Μ 浪 Μ d- \ · r \ s ·: 0-^ 1 5 U 1 0 1 (Reading noodles in between-t; χ: ί matters again) 584616 A7 ____B7_ V. Description of the invention (7) The effect of removing harmful microorganisms, such as making Twenty - four hour cycle in the bath, the articles of the present invention, wherein the circulation pump is placed, wherein the water flows continuously, and the removal of harmful microorganisms in the water fear of AIDS. When the articles of the present invention are used in air-conditioning systems, air cleaners, medical treatment or experimental equipment or laboratories; microbial safety protection systems, the articles of the present invention need to be placed in the gas outlets or In front of the liquid outlet, the radon enables the object of the present invention to exert the function of removing harmful microorganisms to the greatest extent. The invention is further illustrated by the following S examples. However, the scope of the present invention is not limited by this embodiment. g _ Example Order 25 replacement parts of Boehmite (purchased from Condea, Germany) were mixed with 75 parts by weight of 1 part water. Using the solution-gel technique (SO g e 1), the foregoing mixture was ground into a finely gelatinous slurry with a ball mill (containing multiple alumina balls of different sizes). The honeycomb-shaped ceramic as a carrier is immersed therein, the honeycomb-shaped ceramic is taken out, the excess slurry blocking the holes is blown out, and sintered and solidified at a temperature of 500 to 800 t: to obtain a honeycomb-like ceramic with a high specific surface area. The Ministry of Economic Affairs, Central China Economic and Technical Bureau, Consumer and Industrial Cooperation, ft. Printing Disaster This immersed ceramic with a high specific surface area was immersed in a quaternary ammonium rhenium solution diluted to 0.4% with water at a temperature of 80 to 120 t: Drying to obtain the porous shaped object with the animal fowls of the present invention. »Mingongmu Because the microbial component of the present invention has a biological function of 5? Porous 12 body, the stimulating biological component used in the present invention will not flow in bad performance (such as Do not defeat each other with the addition of 5?, Κ 娀 | A »1 'ir. · Α] λ; ν' ft ν {\ S \ 4 \ fr:! U ^: Ί '» φ 584616 A7 B7 V. Description of the invention (8) land), so there is no environmental pollution, harmful to human health and Burmese cost-effective point-of-view observation. The province of Lung is particularly festive. Middle example. In the case of anger, those who produce germs can become Weida or Yuanda. «Can be used in the ascension of the disease to raise the difficulty of the method of raising the air fufang». Xi Qukongzhi S Yu Yu Bo Xi asks you to wait for some more to prevent a certain fact from happening. It can be used for sterilization through reading things (please read the precautions on the back before filling out this page).

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Claims (1)

584616 Notice A8 B8 C8 D8 Λ amendment '8710040; —1 —t Ι »·· ι u " · 丨 丨' _ J VI. Scope of patent application (please read the precautions on the back before filling this page) 1. A porous shaped object capable of removing harmful microorganisms, characterized in that the porous shaped object contains an antimicrobial component with antimicrobial function, the component is a quaternary ammonium salt, wherein the quaternary ammonium salt is chemically bonded to the porous Shaped shaped objects are joined. 2. The porous shaped article according to item 1 of the patent application scope, wherein the porous shaped article is made of clay or porcelain clay. 3. For example, the porous shaped article of the scope of patent application, wherein the porous shaped article is a honeycomb ceramic. 4. A method for manufacturing a porous shaped article capable of removing harmful microorganisms according to item 1 of the scope of patent application, comprising immersing the porous shaped article in the antimicrobial component and sintering and solidifying the porous shaped article. 5. The method according to item 4 of the patent application, wherein the porous shaped object is made of clay or porcelain. 6. The method according to item 5 of the patent application, wherein the porous shaped object is a honeycomb ceramic. 7. According to the method in the fourth item of the patent application, the porous shaped object is first immersed in an adhesion-promoting surface diffusing agent, and after sintering at a temperature of 4 ° to 1500 ° C, the porous shaped object is immersed in the resistance. Microbial components, and then sintered and solidified. Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs I-— ^ 8. If the method of the scope of patent application is No. 7, the adhesion-promoting surface diffusing agent is selected from silicon dioxide, high specific surface area silicon dioxide, alumina, A group of high specific surface area alumina and any substance containing silicon dioxide and / or alumina. 9. If the method of applying for the fourth item of the patent scope, wherein the sintering temperature is 50 to 20 (TC. 9) This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm)