Α7 經濟部中央標隼局員工消費合作社印製 Β7五、發明説明（1 ) 發明領Μ 本發明偽有關一種可去除有害撤生物之多孔狀成型物 件及其製法。 發明背晉 随著社會環境及科學之日益進步.且隨箸人與人間的 接觸日益頻繁，使有寄徹生物充斥於環境中的危險性日益 簌重。 公共場所，尤其是水域例如游泳池、公共浴室等更是 病原菌傳播的最佳場所，若此等水域的衛生狀況維護不當 ,易使人感染皮虜病、眼疾等傳染病，為防止此等水域的 有害徹生物過度滋長，通常於水中添加氯等消毒殺菌劑， 以達消毒、殺薗的功能。 水中添加消毒、殺菌剤之情形亦可見於自來水處理廠 、三溫暖浴池或水族箱等供给人或動物飲水或活動的場所 。傳統上，僳將氣、殺菌劑、殺藻劑等抗徹生物成分直接 添加至該等水域中，以逹消毒、殺菌之效果。然而，隨著 水的流失，此等抗徹生钧成分的含量亦隨之減少。因此， 為維持此等水域中抗徹生物成分之濃度必須經常添加抗徹 生物成分至此等水域，無形中增加許多經濟成本.更因隨 水之流失造成污染，增加環境負攉。此外.由於此等抗徹 生物成分可經飲水或食物直接進入體内，或直接附著於皮 虜，久之對健康亦有不良影W。 此外，日前在日本發生幾起因於24小時熱水循璟浴室 泡澡，而引發撖生钧感染之中毒事件，其肇因為此等循環 本紙張尺度適用中國囤家標準（CNS ) Α4規格（210X297公釐） , 1 ς ς 7 (請先閱讀背面之注意事項再填寫本頁) 42 1 64 Ο Α7 經濟部中央標隼局員工消費合作社印繁 Β7五、發明説明（2 ) 式浴室主要是於家庭中供個人使用者，因顧及抗徹生物成 分對人髏健康之不良影饗，且僅係供個人使用，該等使用 者大多不願亦未思及於水中添加抗徹生物成分，因而使循 璟水中滋生有害人體之撖生物而不自知，遂而遭致感染。 另外，經由空氣傳染的疾病亦日漸趨多，例如，退伍 軍人懣候群的病原菌（肺炎退伍軍人症捍菌；LesLQ.n』J丄a pneumophila)可藉空氣傳播。為防止此等病菌的感染，亦 極需一可置於空調系統出風口或實驗室之檝生物安全防護 条統等之具有去除有害撤生物功能的物件。 據報導四级銨塩對細菌（例如金黃色葡萄球菌、大腸 桿菌、沙門氏菌屬細菌等）、酵母菌[如釀酒酵母（ Saccharom.vces cerevisiae)、白假絲酵母（C a n .d i d a albicans)]、藻類[如藍緣藻門、褐藻門及緣藻門者）及真 菌[例如魏菌屬、球毛殼菌（ChaetomiuE g 1 〇 b 〇 s u a )、绳狀 青霉菌（P e η i c ? 1 1 i u m funiculosua)]等具抑制作用，而銀 之殺菌作用亦經報導。例如美國專利第3,817,739及 3,865,728號中提出以經四级銨塩處理過之砂及聚酯纖維 或醋酸酯纖維素之濾材，抑制藻類生長。但此合成雜維濂 材缺乏舆四级銨塩之強化學鍵結，因此抗徹生物成分易流 失而快速失去抗菌效果，進而無法長期發揮其功效。但將 此等抗徹生物成分擔持於載體上，而達長時效之抗撤生物 效杲則未見報導。更未有人提出將四级銨塩有效擔持於例 如陶瓷類載體的方法。基於上述理由，本發明者深入研究 ，發現一種可將該等抗徹生物成分有效擔持於載體上，製 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 2 1 5 5 7 3 4 21 6 4 0 Λ7 經濟部中央標隼局員工消費合作社印製 B7 _五、發明説明（3 ) 成具有搔佳抗有害微生物效果之物件的方法。藉由本發明 製得之物件可解決前述諸多問題，因而完成本發明。 發明曰的 本發明之一目的偽提供一種可去除有害徹生物之多孔 狀成型物件，該物件上載有具抗微生物功能之抗徹生物成 分，該成分傣由還自四级銨塩及銀所成組群組成者。 本發明之另一目的，偽提供一種可去除有害微生物之 多孔狀成型物件的製造方法，包括將一用以擔持抗撒生物 成分之多孔狀載體浸潰於含有抗徹生物成分之浸漬用液體 中，再進一步燒結而成。 _忒簡蜇説明 第1圖顯示本發明可去除有害徹生物之多孔狀成型物 件對肺炎退伍軍人症桿菌之抑菌效果。 第2圖顯示本發明可去除有害徹生物之多孔狀成型物 件對大腸桿菌之抑菌效果。 第3圖顯示本發明可去除有害徹生物之多孔狀成型物 件對鼠傷寒沙門氏菌之抑菌效果。 發明^註細説明 本發明偽有關一種可去除有害徹生物之多孔狀成型物 件，該物件上載有具抗橄生物功能之抗撤生物成分。更詳 言之，本發明僳有關一種可去除有害微生物之多孔狀成型 物件，該物件上載有選自四级銨塩及銀所成組群之抗徹生 物成分 本發明又有關一種可去除有害微生物之多孔狀成型物 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐) — ΓΓ77" ~ 1----:------裝-- (請先W讀背面之注意事項再填寫本頁) 4 2 1 6 4 0 A7 87 五、發明説明（4 ) 件之製造方法，包括將一用以擔持抗撤生物成分之多孔狀 經濟部中央標準局員工消費合作杜印製 步 物體用溶 抗明抗 。過，形目 於而型有 1 型載作之 等發期 等通詞盤需 持狀成除 進成之燒分 載該本長 狀體 一圓所 擔孔狀去 再狀分煅成 狀使用及bb綿氣 J、到 及多孔件 , 孔成過物 孔而利效 ί 海或件形達 體呈多物 古岡 中多物經生 多，並有。 、流物邊可 載像明明 體之生’徹 明用，且佳 狀體型多要 狀件發發 液 物徹液抗 發作上強更 W 網液成、只 孔物本本 用生抗溶等 本結體揮合⑧、使 Γ 形， 多明於加 漬微等或該 與鍵載發組 1 狀可之方制 一 發布增 浸害彼液含 可強狀可之-IM要用如限 括本分而 之有持漿於 銀之孔而間 蜂只 所例何 包於高 ， 分除擔之漬 及間多，02^|如，中，任 件由提量 成去以液浸 塩 2 於性TiL· 例制明狀無 物。以含 物可用散醴。銨10結特與 Η -限發形並 形分可的 生 種使擴載成级 W 鍵積尤 1 者無本需狀 成成故分 撤 一先面的而四3-地面銀b)並。所形 狀物，成 抗閼係表燒結用20固表中gfc量可種小 孔生者物 有有，結煅燒利A1穩高其 h 數即各大 多徹積生 含亦法粘經以卽、可之。ΦΡ與果為其 之抗面徹 於。明方助該予明02分體性月B/小效型，。明之表抗 漬成發造於使再發si成載活 ^ 大其成者可發上比的 浸而本製漬再 ，本之物狀物 洞揮經形卽本體高上 rKl 體結 之浸 ，中 中生孔生 ί 孔發指球者 載有件 Φ网 載燒 件先後液 髏微多徹 ί 其而傜或的 該具物 - --.—I— - - I ^n— I- . I 1-- 1 t^i^i ^ Jw. ---¾ (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標隼（CNS) Α4規格U10X297公釐） 4 1 5 57 3Α7 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs B7 V. Description of the Invention (1) Invention Field The present invention relates to a porous shaped article capable of removing harmful living organisms and a method for manufacturing the same. With the progress of the social environment and science, and the increasing frequency of contact between people, the danger of immersing organisms in the environment is becoming increasingly serious. Public places, especially waters such as swimming pools, public baths, etc. are the best places for pathogenic bacteria to spread. If the health status of these waters is not maintained properly, people may be infected with infectious diseases such as dermatosis and eye diseases. In order to prevent these waters, Harmful growth of harmful organisms is common, and disinfectants such as chlorine are usually added to water to achieve the functions of disinfection and sterilization. The addition of disinfection and sterilization in water can also be seen in places such as tap water treatment plants, saunas or aquariums that provide drinking water or activities for people or animals. Traditionally, radon adds anti-biological components such as gas, fungicides, and algicides directly to these waters for the effect of radon disinfection and sterilization. However, with the loss of water, the content of these anti-Cheng Shengjun ingredients also decreased. Therefore, in order to maintain the concentration of anti-biological components in these waters, anti-biological components must often be added to these waters, which adds a lot of economic costs. Furthermore, the pollution caused by the loss of water increases the environmental burden. In addition, because these anti-biological components can directly enter the body through drinking water or food, or directly attach to the skin, it has a negative effect on health over time. In addition, there have been several incidents of poisoning in the health caused by shengshengjun infection caused by a 24-hour hot bath bath in Japan a few days ago. The reason for these circulations is that the paper size is in compliance with the Chinese standard (CNS) Α4 specification (210X297). (Mm), 1 ς 7 (Please read the notes on the back before filling out this page) 42 1 64 〇 Α7 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Β7 V. Description of the invention (2) The bathroom is mainly in For personal users in the family, due to the adverse effects of anti-biological ingredients on the health of human skulls, and only for personal use, most of these users are unwilling and unaware of the addition of anti-biological ingredients to water, thus Infection in the water breeds harmful creatures without knowing it, and they become infected. In addition, airborne diseases are also increasing. For example, the pathogenic bacteria of the veterans' cohort (V. pneumoniae; LesLQ.n'J 丄 a pneumophila) can be transmitted by air. In order to prevent the infection of these germs, there is also a great need for an object with a function of removing harmful organisms, which can be placed in the air outlet of an air-conditioning system or a laboratory biological safety protection system. It is reported that quaternary ammonium thorium has effects on bacteria (such as Staphylococcus aureus, E. coli, Salmonella bacteria, etc.), yeast [such as Saccharom.vces cerevisiae, Candida albicans], Algae [such as those of the Phalaenopsis phylum, Phaecophyta and Phragmites phylum] and fungi [for example, Pseudomonas, ChaetomiuE g 1 〇b 〇sua), Penicillium funiculosum (P e η ic? 1 1 ium funiculosua)], etc., and the bactericidal effect of silver has also been reported. For example, U.S. Patent Nos. 3,817,739 and 3,865,728 propose to use quaternary ammonium gadolinium-treated sand and a filter material of polyester fiber or cellulose acetate to inhibit algae growth. However, this synthetic heterovitamin material lacks the strong chemical bond of quaternary ammonium hydrazone. Therefore, the anti-biological component is easily lost and the antibacterial effect is quickly lost, and the effectiveness cannot be exerted for a long time. However, these anti-biological components are supported on the carrier, and anti-withdrawal biological effects of long-lasting effects have not been reported. Furthermore, no method has been proposed to effectively support quaternary ammonium rhenium on, for example, a ceramic carrier. Based on the above reasons, the present inventors have conducted in-depth research and found that a system that can effectively support these anti-biological components on the carrier (please read the precautions on the back before filling this page) This paper size applies Chinese national standards (CNS ) A4 size (210X297 mm) 2 1 5 5 7 3 4 21 6 4 0 Λ7 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs B7 _V. Description of the invention (3) It has a good anti-harmful microorganism effect Methods. The objects made by the present invention can solve many of the aforementioned problems and thus complete the present invention. An object of the present invention is to provide a porous shaped article capable of removing harmful organisms. The object is provided with an anti-organic biochemical composition containing anti-organisms. The composition is made of quaternary ammonium and silver. Group composition. Another object of the present invention is to provide a method for manufacturing a porous shaped article capable of removing harmful microorganisms, comprising immersing a porous carrier for supporting the anti-spreading biological component in an impregnating liquid containing the anti-biological component. Medium and further sintered. _ 忒 Brief description Fig. 1 shows the antibacterial effect of the porous shaped article of the present invention that can remove harmful organisms against veterinary pneumoniae. Fig. 2 shows the bacteriostatic effect of the porous shaped article capable of removing harmful organisms according to the present invention on E. coli. Fig. 3 shows the bacteriostatic effect of the porous shaped article capable of removing harmful organisms according to the present invention against Salmonella typhimurium. Detailed description of the invention ^ Note The present invention relates to a porous shaped article capable of removing harmful organisms, and the article is provided with an anti-removal biological component having an olive-resistant function. In more detail, the present invention is related to a porous shaped article capable of removing harmful microorganisms, and the article is loaded with an anti-biological component selected from the group consisting of quaternary ammonium gadolinium and silver. The present invention also relates to a method capable of removing harmful microorganisms. The porous shape of this paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) — ΓΓ77 " ~ 1 ----: ------ installation-(Please read the precautions on the back first (Fill in this page again.) 4 2 1 6 4 0 A7 87 V. Manufacturing method of the invention (4), including the production cooperation of a staff of the Central Standards Bureau of the Ministry of Economics to support anti-withdrawal biological components Step objects with dissolved anti-Ming Kang. However, the omnidirectional discs with the same type of period and type as the type 1 must be held in shape, divided into the burned and divided, and then loaded into the hole shape of the round body to be reshaped and used. Bb Mianqi J, and the porous pieces, the holes become through the holes and benefit ί sea or piece-shaped body is multi-things and many things in the ancient Gang, and there are many. The side of the fluid can carry a clear and clear body, and it has a clear shape, and the shape of the body is more important. The hair fluid and the liquid are more resistant to seizures, and the omentum is formed, and only the pores are used. The body is sculpted into a shape of Γ, which is more obvious than adding a stain, etc., or the same as the key-carrying group, which can be released in one step. The solution can be strong and can be used. -IM should be used as a limited edition. There is a hole in the silver, and the bee is an example of how it is covered in high, except for the burden of the stain and the amount of time. 02 ^ | For example, in the middle, any part can be immersed in liquid to increase the amount. Sexual TiL · Exemplified without any substance. Can be used to loosen the contents. Ammonium 10 knots and Η-hair-restricted and formable breeding seeds make the expansion into a grade W bond product especially 1 if there is no need to form it, so the first and the third ground ground b) and . The shape of the object, the gfc content in the 20 solid table used for sintering resistance to surface sintering can be planted with small pores. The calcination profit A1 is stable and its h number is high. Okay. ΦP and fruit are their resistance. Ming Fang helped the Ming Ming 02 split sex month B / small effect type. The anti-staining hair formation of the Ming Dynasty is made to make the re-transmission si become alive. The person who is more capable can send a better dip. , The middle school student Kong Sheng, the hole sender refers to the player carrying a piece of Φ net-carrying parts, the liquid skull has more than one, and the object--..-I---I ^ n- I-. I 1-- 1 t ^ i ^ i ^ Jw. --- ¾ (Please read the notes on the back before filling in this page) This paper size applies to China National Standard (CNS) Α4 size U10X297 mm) 4 1 5 57 3
4 2 1 6 4 U Μ B7 五、發明説明（5 ) 害微生物的效果。 本發明所用之四级銨塩為結構中含矽（SU且在與水混 合後可被水解，形成具-Si(0H)3之結構的化合物，當被覆 於結構含有Sj〇2、Ti〇2及/或Al2〇3成分之載髏（如陶瓷） 表面後，々與該載體成分中的Si〇2、Ti〇2及/或Al2〇3形成 化學鍵結，而強烈鍵結於該物件表面進而可長期發揮其作 用。 本發明所用之四级銨塩尤指具有下述化學結構之四级 銨塩 CH, [Y3 - Si - (CH2)m~N+~ (CH2)n - CH3] Χ ΟΗ, (讀先閱讀背面之注意事項再填寫本頁〉 I —裝 _ 訂 經濟部中央榡準局負工消f合作社印裝 (其中m為1至11之整數，n為9至17之整數，id 整數，X為鹵素；Y為可水解基或羥基）；具 化3-(三甲氧基甲矽烷基）丙基十八烷基二甲 本發明所用之銀可源生自硝酸銀、齒化 本發明中所用之多孔狀載體又可視需要 成分浸漬前以肋粘結表面擴散劑處理，而進 表面積（增加約15至1 0 0 0倍），由而更提高本 型物件之抗微生物效果。 所用之助粘結表面稹擴散劑例如二氣化 積二氧化矽、氧化鋁、高比表面積之氣化鋁 可購自德國Condea公司]、二氣化鈦、高比 鈦、或任何成分中含有二氧化矽、氧化铝及 + n為1 6至23之 髏實施例如氣 基銨。 銀及醋酸銀。 在以抗徹生物 一步提昇載體 發明多孔狀成 矽、高比表面 如 Boetimite[ 表面積二氣化 /或二氣化鈦 本紙張尺度適用中國國家標準i CNS ) A4規格（210X297公釐） 5 1 55 73 4 2 1 6 4 0 A7 經濟部中央標準局員工消費合作社印裝 B7五、發明説明（6 ) 之物質。 可使用作為多孔狀載髏之材料並無待殊限制，只要是 含有選自Si〇2、 Τί〇2及Al2〇3之成分，以使本發明所用之 抗微生物成分吸附於其上卽可。 本發明之多孔狀載體之製法，可使含Si〇2 、Ti〇2及 /或Al2〇3之陶土或瓷土或使陶土或瓷土與選自S〖〇2、 Ti〇2及Al2〇3之成分之混合物經過煅燒而得多孔狀載體。 前述煅燒俗在400至1500t下進行，較佳於800至 1 2 0 0 t進行。 接著將此經缎燒之多孔狀載體浸漬於經溶劑預先稀釋 之抗撤生物成分之溶液中，取出後再進行燒結，在抗撤生 物成分為四级銨塩之例中，燒結溫度為50至200亡，較好 60至150艺，更好為80至120t。而抗徹生物成分為銀之例 中，燒結溫度為300至6001,宜為300至500C。燒結所需 時間並無絶對限制，端視所用之多孔狀成型物件之大小及 相對應之溫度而定，溫度高則時間較短，溫度低則時間長 〇 本發明之多孔狀載體在以四级銨塩溶液浸漬前，亦可 視需要以助粘結表面擴散劑處理，以得到具高比表面積之 多孔狀載體。該處理步驟包括使前述助粘結表面擴散劑與 水以1:1至1:10之比例混合，研磨成漿料，再使前述裂得 之多孔狀載體浸漬於其中，再以前述煅燒溫度予以煅燒而 得具高比表面積之多孔狀載鹾。 前述用以稀釋四级銨塩之溶劑例如水、醇類（如甲醇 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標隼（CNS ) Λ4規格（2ίΟΧ297公釐） 6 1 5 5 7 3 五 42 164 0 _ 丙 如 /V \--/ 類 (7_ 明、 兑 } ^ 0 發乙 醚 乙 二 \ 喃 呋 氫 四 如 /IV 類 醚 等 磺 化 0 四、 仿 氣 如 /11· 類 烴 化 氣 及 烷 乙 烷 甲 0丨Μ " 為 類好 烴較 濃 液 溶 之 分 成 物 ， ¾ 生 ο 徹 1 抗至 . 1 之 · J. 體 載 狀 孔 多 , ¾ 該 ο 潰2. 浸至 以05 用 ο , 為 又好 較 度 為 好 更 為 好 最 至 型及 成結 狀鍵 孔力 多強 之之 物間 生件 撤物 害該 有與 除分 去成 可物 之生 得撤 製抗 法之 方上 明其 發於 本由 以 > 件 物 會 不 亦 分 成 性 活 之 上 。 其果 , 效 後之 用物 使生 期徹 長抗 使其 01持 而保 因期 , 長 合可 黏而 或失 / 流 使 ， 可者 俗物 件生 物微 型害 成有 狀之 孔中 多其 之除 物去 生而 撤统 害条 有調 除空 去 、 可域 之水 明的 發動 本流 於 用 的環 用循 水水 飲熱 或時 動 小 活 四 物十 動 二 或 、 人池 供浴 指共 是公 > r 域池 水泳 式游 動如 流例 之域 指水 所式 ft 動 在流 可徹 亦之 件室 物驗 明實 發或 本器 〇 淨 等清 機氣 水空 飲 、 或置 器裝 水濾 濾過 、 用 場驗 殖實 養或 産療 水醫 、 於 室用 浴使 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 如去生 例可微 域之害 水明有 圍發止 範本防 小用到 為使達 域下可 水形亦 之情 ， 理的件 處止物 欲靜型 所為成 當水狀 。 之 孔 統中多 糸其之 護若物 防 -生 全時撖 安箱害 物族有 生水除 於水 置之 件中 物域 型水 成該 狀在 孔置 多安 之好 物較 生 ， 撒時 。害用 果有使 效除以 的去予 長可而 生之域 中明水 域發式 水本動 該將流 於 述 物 前 之室 大浴 更環 揮循 發時 件小 物四 明十 發二 本於 使用 更使 以如 中例 置 ， 裝果 環效 循的 流物 水生 或徹 口害 入有 出除 流去 本纸張尺度適用中國國家標準（CNS ) Λ4規格（210X297公犮） 7 1 55 7 3 經濟部t央標準局員工消費合作社印製 4 2 1 6 4 0 A7 B7五、發明説明（3 ) 時，將本發明物件置於其中之循環泵，使水不斷流經其中 ，而去除在水中滋長的有害榭生物。當本發明物件使用於 空調糸統、空氣清淨器、醫療或實驗用過濾裝置或實驗室 之徹生物安全防護糸統時，需將本發明物件安置於該等裝 置之氣體送出口或濾液出口前方，俥使得本發明物件發揮 最大的去除有害微生物的功能。 Η以下述實施例及試驗例進一步說明本發明。但本發 明範圍並不受限於此。 曹旃例1:以四紐銶煊作為杭榭牛物活件成分夕多：?丨.狀成 型物件剪備 以膠水狀Si〇2(5-30>rt% )、高比表面積Si〇2(15-70 wt% )及水（30-80wt% )所組成混合液中加人適量硝酸，調 整p Η於3 - 6。利用溶液-凝膠（S ο 1 - g e I )技術，以球磨機將 前述混合物研磨成細緻化之凝瘳狀漿液。使作為載體之蜂 巢陶瓷浸漬其中，取出該蜂篥陶瓷，吹掉阻塞孔洞之多餘 漿液。於800至9001C的溫度中燒結固化，製得高比表面積 之蜂巢陶瓷。 將此具高比表面積之蜂箪狀陶瓷浸漬於經水稀釋為 0.4%之四级銨塩溶液中，於80至12010的溫度下烘乾，製 得本發明可去除有害微生物之多孔狀成型物件。 窨旃例？：以鎇作為杭榭牛物沃袢成分：>劣孔狀成型物炸p m m 取Ti〇2原料與陶瓷粉末以1:1重量比及適量水混合， 以製模機模塑成蜂巢狀，再於900至lioot之溫度下煅燒 --i!J;· -I! - 1- I . - I —-f I -I s I I i ——I ^—J. - .--° (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210'乂 297公釐） 8 1 5 5 73 經濟部中央標準扃員工消費合作社印繁 4 2 1 6 4 0A7 B7 五、發明説明（9 ) ,製得含Ti〇2之多孔狀蜂巢陶瓷。 製備O.lwt% 硝酸銀水溶液，使所製得之多孔狀蜂巢 陶瓷浸於該硝酸銀水溶液中，取出後，再於400至6001C之 溫度燒結而固化乾燥，得本發明之可去除有害撤生物之多 孔狀成型物件。 窖旃例3 :以銪作為杭撤生物活袢成分多孔狀成铟物件 ^靱備 取Ti(0H)4(高比表面積Ti〇2之前驅物）17重量份及 Ti〇2 17重量份及水66重量份混合而得混合液，置於球磨 機研磨成細緻狀之漿液後，使此漿液之溫度控制於70至 ιοου之溫度，利用溶液-凝膠技術調成凝膠狀漿液，使預 先製得之蜂巢陶瓷浸於其中，取出該蜂巢陶瓷，吹掉阻塞 孔洞之多餘漿液，於500至6 0 0 ¾之溫度燒結固化，製得具 高比表面積Ti〇2塗層之多孔狀載醱。 製備O.lwt % 硝酸銀水溶液，使所製得之多孔狀蜂巢 陶瓷浸於該硝酸銀水溶液中，取出後，再於300至6 0 0 υ之 溫度燒結而固化乾燥，得本發明之可去除有害微生物之多 孔狀成型物件。 試驗例1:陆炎锻ffi簠λ症捏馘鉛閿钕粜測試 試驗前先取得肺炎退伍軍人症桿菌（Legionella piiejimopJii IaJ的細胞懸浮液，該懸浮液是將該細菌接種在 Lesione丨la CYS液體培養基中f 搖動（120「ρπ)24小 時後得到的，培養基包含活性碩（0.2¾，w/v),酵母萃取 物（1.0¾ , Difco)及 Legionella BCYE生長補充物質（11¾本紙張尺度逋用中國國家標準（CMS ) A4規格（210X297公釐）9 15573 •-1 FT- IJ -- I : -- 1= —* I 扯衣-1 ί - - I. . __ (請先閲讀背面之注意事項再填寫本頁) 4 2 16 4 0 A7 經濟部中央標準局員工消費合作社印— __B7 五、發明説明（10 ) ，v/v, Oxoid)。懸浮液中肺炎退伍軍人症捍菌的菌落數 ，是用 Legionella CYE 培養基（Oxoid)加入 Legionella BCYE生長補充物質在35¾培養48小時後計數的。在試驗前 將實施例1所製得具高比表面積之蜂巢陶瓷放在烘箱中消 毒（1001C, 3小時），然後將其掛在無菌之500ml燒杯内， 燒杯底部放有一攪拌子。將500ml用無菌水稀釋的細菌懸 浮液注入燒杯（約2〇xi07CFl)/mU ,摄動懸浮液使液體表 面産生通渦，在試驗期間0、 10、20、30、60分鐘時計數 懸浮液細菌菌落數，重複該實驗，並用未吸附四级銨塩之 高比表面稹蜂箪陶瓷做比對實驗。懸浮液中L. pneumophi la細菌存活曲線如第1圖所示。 試驗例2 :太隄揑_方鼠傷案沖門ffi喆殺蘭钕里測試 1 .活化試驗菌（3 5 Ό . 2 4 h r )，並if 1其原始菌數。分別 以大腸捍菌（Escherichia co 1 i ) CCRC11634及鼠傷寒沙門 氏菌（S a 1 m a n e I 1 a tvDhimuriuffl) 為試驗菌。 2. 取其菌液5al加入無菌水495ιπ1中混合均勻。 3. 將實施例1所製得具高比表面積之蜂巢陶瓷放在烘 箱中消毒（100它，3小時），並置於燒杯中，注人400ml細 菌懸浮液。 4. 開始搜拌，毎隔10分鐘測菌數一次，至30分鐘為止 0 5. 取0.1ml塗抹於PCA盤.，在351C培養48小時後計數菌 落數，細胞存活曲線分別如第2及3圖。 由試驗例1及2之結果可看出本發明之多孔狀成型物件 '^訂 I.-----^ (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 10 1 5 5 7 3 4 21 b 4 U A7 B7五、發明説明（11 ) 確實具有去除有害徹生物之功效。 發明功效 成分各 物成至 生物散 微生流 抗撤水 之抗随 能之而 功用域 物所水 生明於 微發加 抗本添 有故因 具 ，不 之上如 中醴例 件載 丨 物狀中 明孔境 發多環 本於於 於持失 由擔流 傺 會 分不 經觀 的 點 費觀 耗之 性本 鑛成 持業 及 Η 康省 健節 體及 人生 害衛 有境 , 環 染昇 污提 境就 環 〇 有題 沒問 此等 因本 )>成 地濟 物而 明因 發 -本物 , 生 者徹 甚害 有有 尤的 〇 中 者氣 成空 達或 能統 所条 法諝 方空 知除 習去 於於 優用 遠使 實可 , 尚 之件4 2 1 6 4 U Μ B7 V. Description of the invention (5) Effect of harmful microorganisms. The quaternary ammonium phosphonium used in the present invention is a compound containing silicon in the structure (SU and can be hydrolyzed after being mixed with water to form a compound having a structure of -Si (0H) 3. When coated on the structure, it contains Sj〇2, Ti〇2 And / or the surface of the crossbones (such as ceramics) of the Al2O3 component, plutonium forms a chemical bond with Si02, Ti02, and / or Al2O3 in the carrier component, and is strongly bonded to the surface of the object, thereby It can exert its function for a long time. The quaternary ammonium phosphonium used in the present invention is particularly a quaternary ammonium phosphonium CH having the following chemical structure, [Y3-Si-(CH2) m ~ N + ~ (CH2) n-CH3] χ ΟΗ, (Read the precautions on the back before you fill in this page> I — Order _ Order printed by the Ministry of Economic Affairs, Central Bureau of Standards and Commerce, F Cooperatives (where m is an integer from 1 to 11, n is an integer from 9 to 17, id An integer, X is a halogen; Y is a hydrolyzable group or a hydroxyl group); 3- (trimethoxysilyl) propyloctadecyldimethyl has silver which can be derived from silver nitrate, The porous carrier used in the process can be treated with a rib bonding surface diffusing agent before impregnation as required, and the surface area (increased by about 15 to 100 times) can be further improved. Improve the anti-microbial effect of this type of object. The used co-adhesive surface 稹 diffusing agents such as digasified silicon dioxide, alumina, high specific surface area of aluminum vaporized aluminum can be purchased from the German company Condea], titanium dioxide, High specific titanium, or any component containing silicon dioxide, aluminum oxide, and a skeleton with + n of 16 to 23, such as ammonium ammonium. Silver and silver acetate. In the step of improving the carrier through the anti-biological process, the porous silicon is formed. High specific surface such as Boetimite [Surface area two-gasification / or two-gasification titanium This paper size is applicable to Chinese national standard i CNS) A4 specification (210X297 mm) 5 1 55 73 4 2 1 6 4 0 A7 Employees of the Central Standards Bureau of the Ministry of Economic Affairs Consumption cooperative prints B7 V. Invention description (6). The material that can be used as a porous carrier is not limited, as long as it contains a component selected from Si02, Τί02 and Al203. The antimicrobial component used in the present invention can be adsorbed thereon. The method for preparing the porous carrier of the present invention can make the clay or porcelain clay containing Si02, Ti〇2 and / or Al203 or the clay or porcelain clay and Select from S 〖〇2, Ti〇2 and Al2〇3 Part of the mixture is calcined to obtain a porous carrier. The aforementioned calcination process is performed at 400 to 1500 t, preferably 800 to 12 0 t. Then, the satin-fired porous carrier is dipped in a solvent diluted in advance. The anti-removal biological component solution is taken out and then sintered. In the case where the anti-removal biological component is a quaternary ammonium hafnium, the sintering temperature is 50 to 200 ° C, preferably 60 to 150 ° C, more preferably 80 to 120 t. In the case where the anti-piercing biological component is silver, the sintering temperature is 300 to 6001, preferably 300 to 500C. There is no absolute limit on the time required for sintering. It depends on the size of the porous shaped object used and the corresponding temperature. The higher the temperature, the shorter the time, and the lower the temperature. The porous carrier of the present invention is Before the ammonium rhenium solution is impregnated, it can also be treated with a cohesive surface diffusing agent to obtain a porous carrier with a high specific surface area, if necessary. This processing step includes mixing the aforementioned cohesive surface diffusing agent with water at a ratio of 1: 1 to 1:10, grinding into a slurry, immersing the cracked porous support therein, and applying the same at the aforementioned calcining temperature. Calcined to obtain a porous carrier with high specific surface area. The aforementioned solvents for diluting quaternary ammonium phosphonium, such as water and alcohols (such as methanol (please read the precautions on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (2ί〇 × 297 mm) 6 1 5 5 7 3 5 42 164 0 _ Bingru / V \-/ Class (7_ Ming, Ding) ^ 0 Ethyl ether ethane \ Furfuryl tetrarule / IV ether and other sulfonation / 11 · Hydrocarbon-like gas and ethaneethane 0 丨 M " It is a good liquid-soluble hydrocarbon-like fraction, which is ¾ ο ο 1 resistance to. 1 of J. There are many body-like pores, ¾ This ο 2 2. Dipping to 05 with ο, for the better than the better, the better and the best, and the formation of knot-shaped key holes with strong hole between the physical parts of the removal of material damage should be divided into the removal The object of life can be resisted by the party who clearly stated that it was issued on the basis that the item will be divided into sexual activity. As a result, the use of the effect will make the life period completely resistant to its 01 and keep the factor period , Long-term can be sticky or lost / can cause the common objects to damage the micro-shaped holes Removal of the system from the birth of the things is to remove the empty, clear water to start the current use of circulating water to drink heat or move small things four things ten or two, people pool bathing fingers It is public > r domain pool water swimming style swimming, such as the flow of the domain refers to the water type ft movement in the flow can be a piece of room material to verify the actual delivery or the machine ○ clean and clean air water empty drink, or set Filtered with water in the container, used for incubation or maternity treatment, used in the room (please read the precautions on the back before filling out this page), printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs The harm of the differentiable domains is clear. The template for sending out and stopping is used to prevent the small ones from reaching the realm of water, and the only things that can be stopped are the water-like forms. Protecting the physical protection-whole-time Lu'an box harms the clan with raw water and removes it from the water. The water of the area type becomes more like this, and the good things that are placed in the hole are more healthy. In the water where the long-term can be born, the water in the Ming Dynasty should be moved In the room in front of the object, the large bath is more circular and the small items are clear and the hair is clear. The two copies are used in the same way as in the example, and the flow of the fruit is aquatic or completely harmful. The paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X297 cm) 7 1 55 7 3 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 4 2 1 6 4 0 A7 B7 V. Description of the invention (3) At that time, the circulating pump in which the object of the present invention is placed allows water to continuously flow through it to remove harmful organisms that grow in the water. When the object of the present invention is used in an air conditioning system, an air cleaner, a medical or experimental filtering device or a complete biological safety protection system in a laboratory, the object of the present invention needs to be placed in front of the gas outlet or filtrate outlet of the device Therefore, the object of the present invention can exert the function of removing harmful microorganisms to the greatest extent. Η The following examples and test examples further illustrate the present invention. However, the scope of the present invention is not limited to this. Example 1 of Cao Yu: Using Si Niuyu as a living ingredient of Hangxie cattle:? 丨. Shaped articles are cut with glue-like Si〇2 (5-30 > rt%), high specific surface area Si〇2 (15 -70 wt%) and water (30-80 wt%) were added with a suitable amount of nitric acid, and adjusted p to 3-6. The solution-gel (S 1-g e I) technique was used to grind the aforementioned mixture into a finely coagulated slurry with a ball mill. The honeycomb ceramic as a carrier was immersed therein, and the honeycomb ceramic was taken out, and the excess slurry blocking the pores was blown off. Sintering and curing at a temperature of 800 to 9001C to produce a honeycomb ceramic with a high specific surface area. The honeycomb-shaped ceramic with high specific surface area was immersed in a quaternary ammonium hydrazone solution diluted to 0.4% with water, and dried at a temperature of 80 to 12010 to obtain a porous shaped object capable of removing harmful microorganisms according to the present invention. . Example? : Use 鎇 as the ingredients of the Hangxie beef product: > Pore-shaped shaped product fried pmm Take Ti02 raw material and ceramic powder in a 1: 1 weight ratio and mix with an appropriate amount of water, and mold it into a honeycomb shape with a molding machine. Then calcined at a temperature of 900 to lioot --i! J; -I!-1- I.-I --- f I -I s II i --I ^-J.-.-- ° (please first Read the notes on the reverse side and fill out this page) This paper size applies to China National Standard (CNS) A4 (210 '乂 297 mm) 8 1 5 5 73 Central Standard of the Ministry of Economic Affairs 扃 Employee Consumer Cooperatives India and India 4 2 1 6 4 0A7 B7 5. Description of the invention (9), a porous honeycomb ceramic containing Ti02 was prepared. A 0.1 wt% silver nitrate aqueous solution was prepared, and the porous honeycomb ceramic prepared was immersed in the silver nitrate aqueous solution. After being taken out, the porous honeycomb ceramic was sintered at a temperature of 400 to 6001C to solidify and dry. Shaped objects. Cellar Example 3: Porous indium-containing objects using osmium as a living organism component of ^^ Preparation of 17 parts by weight of Ti (0H) 4 (precursor of Ti02 with high specific surface area) and 17 parts by weight of Ti〇2 and 66 parts by weight of water are mixed to obtain a mixed solution. After being placed in a ball mill to grind into a fine slurry, the temperature of the slurry is controlled to a temperature of 70 to ιοου. The solution-gel technology is used to adjust the gel to a slurry. The honeycomb ceramic obtained was immersed in it, the honeycomb ceramic was taken out, the excess slurry blocking the pores was blown out, and sintered and solidified at a temperature of 500 to 600 ° C to obtain a porous carrier having a high specific surface area Ti02 coating. A 0.1 wt% silver nitrate aqueous solution was prepared, and the porous honeycomb ceramic prepared was immersed in the silver nitrate aqueous solution. After being taken out, it was sintered at a temperature of 300 to 600 υ to be solidified and dried to obtain the removable harmful microorganisms of the present invention. Porous shaped objects. Test Example 1: A cell suspension of Legionella piiejimopJii IaJ was obtained prior to the test of Lu Yandong 簠 簠 λ 症 症 症 症 症 症 馘 馘 馘 馘 馘 馘 馘 馘 症 症 症 症 症 症 簠 簠 簠 症 症 disease disease Obtained after 24 hours of shaking (120 "ρπ) in the culture medium. The culture medium contains active masterbatch (0.2¾, w / v), yeast extract (1.0¾, Difco), and Legionella BCYE growth supplement (11¾ paper size. China National Standard (CMS) A4 specification (210X297 mm) 9 15573 • -1 FT- IJ-I:-1 = — * I 衣衣 -1 ί--I.. __ (Please read the note on the back first Please fill in this page again for matters) 4 2 16 4 0 A7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs — __B7 V. Description of the invention (10), v / v, Oxoid). Number of colonies of pneumonia veterinary disease defenders in suspension , Was counted after adding Legionella BCYE growth supplement material with Legionella CYE medium (Oxoid) at 35¾ for 48 hours. Before the test, the honeycomb ceramic with high specific surface area prepared in Example 1 was sterilized in an oven (1001C, 3 Hours) and then hang it in sterile In a 500ml beaker, a stirrer is placed at the bottom of the beaker. 500ml of bacterial suspension diluted with sterile water is injected into the beaker (about 20xi07CFl) / mU, and the suspension is perturbed to cause a vortex on the liquid surface. During the test, 0, 10 At 20, 30, and 60 minutes, count the number of bacterial colonies in the suspension, repeat the experiment, and use a high specific surface non-adsorbed quaternary ammonium gadolinium bee sting ceramic as a comparison experiment. The survival curve of L. pneumophi la bacteria in the suspension is as follows Shown in Figure 1. Test Example 2: Taiji pinch_fang rat injury case punching door to kill blue neodymium test 1. activation test bacteria (35 5 Ό 24 hr), and if 1 its original number of bacteria. Escherichia co 1 i CCRC11634 and Salmonella typhimurium (S a 1 mane I 1 a tvDhimuriuffl) were used as test bacteria. 2. Take the bacterial solution 5al and add it to 495 μπ1 of sterile water and mix well. 3. Examples 1. The honeycomb ceramics with high specific surface area prepared were sterilized in an oven (100 hours, 3 hours), and placed in a beaker, and filled with 400ml of bacterial suspension. 4. Start searching, and measure the bacteria count every 10 minutes. 0 times until 30 minutes 5. Take 0.1ml and apply to PCA dish. Count the number of colonies at 351C after 48 hours of incubation, cell survival curves 2 and 3 as in FIG. From the results of Test Examples 1 and 2, it can be seen that the porous shaped article of the present invention '^ Order I .----- ^ (Please read the precautions on the back before filling this page) This paper size applies Chinese national standards ( CNS) A4 specification (210X297 mm) 10 1 5 5 7 3 4 21 b 4 U A7 B7 V. Description of the invention (11) It does have the effect of removing harmful organisms. The functional ingredients of the invention are composed of various substances, and the biological anti-water-removal resistance is with the energy, and the functional domains are aquatic. The micro-fabrication is added to the resistance, and the reason is not as above. In the state of affairs, Ming Kong's realm has a multi-ring nature that is based on the nature of the loss and the cost of consumption. The health of the mine and the health of the province are healthy and healthy. Contamination is lifted. There is no question about this because of the text.) ≫ Become a geo-physical thing and it is clear that it is due to the hair-the thing, the living is completely harmful. The middle of the air is the air or the law. Fang Kongkong knows how to get rid of Yu Youyong, so you can still use it.
捍 症 人 軍 伍 退 炎 肺 如 例 C , 者 菌成 原達 病以 的難 播中 傳藝 氣技 空知 藉習 些 是 某更 防這 預 〇 可 S (請先閱讀背面之注意事項再填寫本I) -Φ 經濟部中央標準扃貞工消费合作社印掣 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X 297公釐〉 ix 1 5 5 73The defendant army Wu Wuyan inflammation lungs as in Example C, the difficult to broadcast the pathogenic bacteria to cause disease in the spread of the art of air skills to learn some of these precautions can prevent this (Please read the precautions on the back before filling out this I) -Φ Central Standard of the Ministry of Economic Affairs 扃 Gonggong Consumer Cooperative Co., Ltd. The size of this paper is applicable to China National Standard (CNS) A4 (21〇X 297mm) ix 1 5 5 73