TW576799B - Fabricating process of an inkjet print head - Google Patents

Fabricating process of an inkjet print head Download PDF

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Publication number
TW576799B
TW576799B TW92112288A TW92112288A TW576799B TW 576799 B TW576799 B TW 576799B TW 92112288 A TW92112288 A TW 92112288A TW 92112288 A TW92112288 A TW 92112288A TW 576799 B TW576799 B TW 576799B
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Taiwan
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layer
print head
inkjet print
patent application
substrate
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TW92112288A
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Chinese (zh)
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TW200424068A (en
Inventor
Chih-Chang Tsai
Ming-Hsun Yang
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Nanodynamics Inc
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Publication of TW200424068A publication Critical patent/TW200424068A/en

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Abstract

A fabricating process of an inkjet print head is described. A master mold with a plurality of notches whereon is provided. A material layer is formed to cover the master mold and fill the notches whereon for manufacturing an ink chamber layer and a vibrating layer as an integrative unit. Then, at least an actuator is disposed on the vibrating layer and the master mold is removed. Finally, disposing a nozzle plate on the ink chamber layer to form at least an ink chamber. The ink chamber comprises the vibrating layer, the ink chamber layer and the nozzle plate with at least an ink inlet and the ink inlet connects through the ink chamber. By manufacturing the ink chamber layer and the vibrating layer as an integrative unit, the jointing ability between the ink chamber layer and the vibrating layer can be enhanced and the fabricating process of the inkjet print head can be simplified.

Description

576799 五、發明說明α) 【發明所屬之技術領域】 本發明是有關於一種喷墨印頭(I n k j e t p r i n t h e a d )之製程,且特別是有關於一種係以一體成型的方式製作 墨腔層(Ink chamber layer)與振動層(vibrating layer )的噴墨印頭之製程。 【先前技術】 近年來,在高科技產業的帶動之下,所有電子相關產 業無不蓬勃發展。以印表機為例,在短短幾年的時間内, 列印技術已經從早期的撞針式列印及單色雷射列印,進步 到目前的彩色喷墨列印及彩色雷射列印,甚至出現熱轉印 列印等列印技術。 目前出現在市面上的噴墨印表機,大多採用熱泡式 (thermal bubble)及壓電式(piezoelectric)的喷墨 印頭,用以將墨水散佈到紙張表面,而完成文字或圖案輸 出之列印工作。其中,氣泡式之列印技術乃是利用一加熱 器(h e a t e r )將墨水瞬間氣化,因而產生高壓氣泡來推動 墨水,.將墨水由喷孔噴出。此外,壓電式之列印技術乃是 利用一因施加電壓而可產生形變的壓電材料 (piezoelectric material)來瞬間擠壓位於墨水腔 (ink chamber)内的墨水,以將墨水由喷孑L噴出。 第1圖為習知壓電式喷墨印頭的剖面示意圖。請參閱 第1圖,壓電式喷墨印頭1 0 0主要係由一振動層1 1 0、一墨 腔層120、一噴孔片(nozzle plate) 130以及至少一致動 元件(actuator) 140 (僅繪示其一)所構成。其中,墨576799 V. Description of the invention α) [Technical field to which the invention belongs] The present invention relates to a process of an inkjet printhead (Inkjetprinthead), and in particular relates to a method of manufacturing an ink chamber layer (Ink chamber) by an integral molding method. layer) and vibrating layer process. [Previous technology] In recent years, driven by the high-tech industry, all electronics-related industries have flourished. Taking the printer as an example, in just a few years, the printing technology has improved from the early striker printing and monochrome laser printing to the current color inkjet printing and color laser printing. , And even print technologies such as thermal transfer printing. Most of the inkjet printers currently on the market use thermal bubble and piezoelectric inkjet print heads to spread ink onto the surface of the paper and complete the output of text or patterns. Print jobs. Among them, the bubble-type printing technology uses a heater (h e a t e r) to instantaneously vaporize the ink, so that high-pressure bubbles are generated to push the ink, and the ink is ejected from the nozzle holes. In addition, the piezoelectric printing technology uses a piezoelectric material that can deform due to the application of voltage to instantly squeeze the ink located in the ink chamber to eject the ink from the ink jet. ejection. FIG. 1 is a schematic cross-sectional view of a conventional piezoelectric inkjet print head. Please refer to FIG. 1. The piezoelectric inkjet print head 100 is mainly composed of a vibration layer 110, an ink cavity layer 120, a nozzle plate 130 and at least an actuator 140. (Only one is shown). Among them, Mo

11159twf.ptd 第6頁 576799 五、發明說明(2) 腔層1 2 0係配置於振動層1 1 0與喷孔片1 3 0之間,且振動層 1 1 0、墨腔層1 2 0及喷孔片1 3 0構成至少一墨水腔1 5 0 (僅繪 示其一)。致動元件1 4 0配置於振動層1 1 0上,且其位置對 應墨水腔1 5 0的位置,其致動元件1 4 0之功能係用以直接或 間接地提供瞬間推擠墨水的力量。此外,喷孔片1 3 0具有 多個噴孔1 3 2 (僅繪示其一),並與墨水腔1 2 0連通,而喷 孔1 3 2之功能係用以於讓受到致動元件1 4 0瞬間擠壓的墨水 由墨水腔1 5 0内喷出至喷墨印頭1 0 0之外。 值得注意的是,由於習知壓電式喷墨印頭1 0 0中之振 動層1 1 0及墨腔層1 2 0係分別經由單一材料層所製作而成, 並以高溫共燒或黏著的方式以接合振動層1 1 0及墨腔層 1 2 0。其中,當振動層1 1 0及墨腔層1 2 0之材質選用陶瓷 時,係採用高溫共燒的方式將振動層1 1 0及墨腔層1 2 0接 合。此外,當致動元件1 4 0中之壓電層(圖未示)其材質 選用壓電陶瓷時,係會對壓電層進行一燒結的步驟,以使 壓電層具有壓電特性。故從上可知,當振動層1 1 〇、墨腔 層1 2 0以及壓電層之材質皆是選用陶瓷時,通常會對振動 層1 1 0、墨腔層1 2 0以及壓電層進行高溫共燒,以同時達到 接合振動層1 1 0與墨腔層1 2 0以及使壓電層具備壓電特性目 的。 然而,以高溫共燒的方式接合振動層1 1 0及墨腔層 1 2 0,會因高溫共燒之後體積收縮率的不同,使得振動層 1 1 0及墨腔層1 2 0之間的相對位置產生偏移,而造成配置於 振動層1 1 0上之致動元件1 4 0與墨水腔1 5 0之間產生對位不11159twf.ptd Page 6 576799 V. Description of the invention (2) The cavity layer 1 2 0 is arranged between the vibration layer 1 1 0 and the orifice plate 1 3 0, and the vibration layer 1 1 0 and the ink cavity layer 1 2 0 And the nozzle hole sheet 130 constitutes at least one ink cavity 150 (only one is shown). The actuating element 1 40 is disposed on the vibration layer 1 10, and its position corresponds to the position of the ink cavity 150. The function of the actuating element 1 40 is to directly or indirectly provide the force of instantaneously pushing the ink. . In addition, the nozzle hole sheet 130 has a plurality of nozzle holes 1 32 (only one of which is shown), and communicates with the ink chamber 120, and the function of the nozzle hole 1 32 is to let the actuated element The ink that was squeezed instantaneously at 1 40 was ejected from the ink chamber 150 outside the inkjet print head 100. It is worth noting that since the vibration layer 110 and the ink cavity layer 120 in the conventional piezoelectric inkjet print head 100 are made of a single material layer, they are co-fired or adhered at high temperature. The method is to join the vibration layer 110 and the ink cavity layer 120. Among them, when the material of the vibrating layer 110 and the ink cavity layer 120 is ceramics, the vibrating layer 110 and the ink cavity layer 120 are joined by high temperature co-firing. In addition, when the piezoelectric layer (not shown) in the actuating element 140 is made of piezoelectric ceramics, the piezoelectric layer is subjected to a sintering step so that the piezoelectric layer has piezoelectric characteristics. Therefore, it can be seen from the above that when the materials of the vibration layer 1 10, the ink cavity layer 120 and the piezoelectric layer are ceramics, the vibration layer 1 110, the ink cavity layer 120, and the piezoelectric layer are usually processed. Co-firing at high temperature to achieve the purpose of joining the vibration layer 110 and the ink cavity layer 120 together and the piezoelectric layer to have piezoelectric characteristics. However, joining the vibration layer 110 and the ink cavity layer 120 in a high-temperature co-firing manner will result in a difference in the volume shrinkage rate after the high temperature co-firing. The relative position is shifted, resulting in misalignment between the actuating element 1 40 disposed on the vibration layer 1 10 and the ink chamber 150.

11159twf.ptd 第7頁 576799 五、發明說明(3) 準確的問題,導致喷墨印頭1 0 0的良率下降,而降低噴墨 印頭1 0 0之列印品質。 另外,以黏著的方式接合振動層1 1 0及墨腔層1 2 0,對 於黏著膠的選擇、黏著參數以及黏著強度的要求度甚高, 且因採用黏著的方式接合振動層1 1 0及墨腔層1 2 0,需要藉 由高精密度對位系統進行對位,以避免配置於振動層1 1 0 上之致動元件1 4 0與墨水腔1 5 0之間產生對位不準確的問 題,如此會增加整個製程的複雜度。再者,由於墨水之組 成成分主要包括染料(d y e )或顏料(p i g m e n t )及溶劑 (solvent )等,所以墨水十分容易侵#黏著膠,而使振 動層1 1 0及墨腔層1 2 0之間產生縫隙,導致墨水由此縫隙處 滲透(即產生漏墨的情形),而降低喷墨印頭1 〇 〇之列印 品質。 【發明内容】 因此,本發明的目的就是在提供一種喷墨印頭之製 程,其在製造過程中以一體成型之方式製作喷墨印頭的墨 腔層與振動層,用以提高墨腔層與振動層之間的接合性, 並能有效解決習知墨腔層與振動層間的滲透問題及降低噴 墨印頭製作的複雜度。 本發明的目的另一目的是提供一種喷墨印頭之製程, 係以曝光、顯影及電鍍等方式製作一母模,用以在母模上 一體成型製作噴墨印頭的墨腔層與振動層。 基於上述目的,本發明提出一種噴墨印頭之製程,首 先提供一母模,其母模具有複數個開口 ,且凹陷於母模之11159twf.ptd Page 7 576799 V. Description of the invention (3) The problem of accuracy leads to a decrease in the yield of the inkjet print head 100, and reduces the print quality of the inkjet print head 100. In addition, the vibrating layer 110 and the ink cavity layer 120 are bonded in an adhesive manner, and the selection of the adhesive, the adhesive parameters, and the adhesive strength are very high, and the vibrating layer 1 110 and the adhesive layer are bonded in an adhesive manner. The ink cavity layer 1 2 0 needs to be aligned by a high-precision alignment system to avoid inaccurate alignment between the actuating element 1 4 0 and the ink cavity 1 5 0 disposed on the vibration layer 1 1 0 This problem will increase the complexity of the entire process. In addition, because the ink's constituents mainly include dye (dye), pigment (pigment), solvent (solvent), etc., the ink is very easy to invade #adhesive glue, so that the vibration layer 1 10 and the ink cavity layer 1 2 0 There is a gap between them, which causes the ink to penetrate through the gap (that is, the situation of ink leakage), which reduces the printing quality of the inkjet print head 1000. [Summary of the Invention] Therefore, the object of the present invention is to provide an inkjet print head manufacturing process, in which the ink cavity layer and the vibration layer of the inkjet print head are integrally formed during the manufacturing process, so as to improve the ink cavity layer. The adhesiveness with the vibrating layer can effectively solve the problem of penetration between the conventional ink cavity layer and the vibrating layer and reduce the complexity of manufacturing the inkjet print head. Another object of the present invention is to provide a process of inkjet print head, which is to make a master mold by means of exposure, development and electroplating, etc., for integrally forming the ink cavity layer and vibration of the inkjet print head on the master mold. Floor. Based on the above objectives, the present invention proposes a process for manufacturing an inkjet print head. First, a master mold is provided. The master mold has a plurality of openings and is recessed in the master mold.

11159twf.ptd 第8頁 576799 五、發明說明(4) 一表面,接著形成一材料層,其材料層填滿這些開口 ,並 覆蓋住母模之具有這些開口的表面,其中填滿於這些開口 之局部材料層係構成一圖案化墨腔層,而覆蓋於母模之表 面的局部材料層係構成一振動層,接著將至少一致動元件 連結於振動層上,然後移除母模,最後配置一喷孔片於墨 腔層之上,以使振動層、圖案化墨腔層及喷孔片構成至少 一墨水腔,其中喷孔片具有至少一喷孔,並與墨水腔相連 通0 依照本發明的較佳實施例所述,上述母模的製作,係 先提供一基材,接著形成一圖案化光阻層於基材上,以形 成母模之開口 。其中,形成圖案化光阻層之方法包括曝光鲁 及顯影,而基材例如是矽基材,圖案化光阻層之材質例如 是環氧化物。 依照本發明的較佳實施例所述,上述母模的製作,係 先提供一基材,接著形成一圖案化光阻層於基材上,然後 形成一導體層在未覆蓋此圖案化光阻層之基材上,最後移 除此圖.案化光阻層,以形成母模之開口 。其中,形成圖案 ’ 化光阻層之方法包括曝光及顯影,而基材例如是矽基材或 金屬基材,圖案化光阻層之材質例如是聚甲基丙烯酸甲酯 (Poly methyl methacrylate » P MM A ) o 此外,當基材係選用金屬材質時,例如以電鍍之方式 直接在基材形成上述之導體層,而當基材係選用非金屬材 ® 質(如矽基材)時,則在形成圖案化光阻層於基材上之 前,先形成一電鑛種子層(s e e d 1 a y e r ),之後再例如以11159twf.ptd Page 8 576799 V. Description of the invention (4) A surface is then formed with a material layer which fills these openings and covers the surface of the master mold with these openings, which fills in these openings. The local material layer constitutes a patterned ink cavity layer, and the local material layer covering the surface of the master mold constitutes a vibration layer. Then, at least a moving element is connected to the vibration layer, then the master mold is removed, and finally a The orifice plate is above the ink cavity layer, so that the vibration layer, the patterned ink cavity layer and the orifice plate form at least one ink cavity, wherein the orifice plate has at least one orifice and communicates with the ink cavity. 0 According to the present invention According to a preferred embodiment of the present invention, the above-mentioned master mold is manufactured by first providing a substrate, and then forming a patterned photoresist layer on the substrate to form an opening of the master mold. The method for forming the patterned photoresist layer includes exposure and development, and the substrate is, for example, a silicon substrate, and the material of the patterned photoresist layer is, for example, an epoxide. According to a preferred embodiment of the present invention, the above-mentioned master mold is manufactured by first providing a substrate, then forming a patterned photoresist layer on the substrate, and then forming a conductor layer without covering the patterned photoresist. On the substrate of the layer, the photoresist layer is finally removed to form an opening of the master mold. The method for forming a patterned photoresist layer includes exposure and development, and the substrate is, for example, a silicon substrate or a metal substrate. The material of the patterned photoresist layer is, for example, polymethyl methacrylate (P MM A) o In addition, when the substrate is made of metal, for example, the aforementioned conductive layer is directly formed on the substrate by electroplating, and when the substrate is made of non-metallic material (such as silicon substrate), then Before the patterned photoresist layer is formed on the substrate, a seed layer is first formed (seed 1 ayer).

11159twf.ptd 第9頁 576799 五、發明說明(5) 電鍍之方式在基材上形成上述之導體層。 依照本發明的較佳實施例所述,上述致動元件的製 作,係先形成一下電極層於振動層上,之後形成一壓電層 於下電極層上,最後形成一上電極層於壓電極層上。其 中,連結致動元件與振動層之方式例如採用高溫燒結的方 式。此外,壓電層之材質例如壓電陶瓷,而構成振動層及 墨腔層之材料層的材質例如是陶瓷、高分子聚合物或金 屬。當壓電層之材質選用壓電陶瓷時,更進一步進行一燒 結壓電層的步驟,以使壓電層具有壓電特性。 本發明係藉由提供一母模,以於母模上一體成型製作 喷墨印頭之墨腔層及振動層,由於墨腔層及振動層在製作 過程中即一體成型,因此墨腔層與振動層之間的接合性 佳,且能有效解決習知墨腔層與振動層間的滲透問題及降 低噴墨印頭製作的複雜度。 為讓本發明之上述和其他目的、特徵、和優點能更明 顯易懂,下文特舉一較佳實施例,並配合所附圖式,作詳 細說明.如下: 【實施方式】 請依序參考第2 A〜2 E圖,其為本發明之一較佳實施例 之壓電式噴墨印頭的剖面流程圖。如第2 A圖所示,係先提 供一母模2 0 0,其母模2 0 0具有多個開口 2 0 2,其凹陷於母 模2 0 0之一表面。接著,如第2 B圖所示,形成一材料層 2 1 0,其材料層2 1 0填滿這些開口 2 0 2,並覆蓋住具有上述 開口 2 0 2的母模2 0 0表面。其中,填滿於這些開口 2 0 2之部11159twf.ptd Page 9 576799 V. Description of the invention (5) The above-mentioned conductor layer is formed on the substrate by electroplating. According to a preferred embodiment of the present invention, the above-mentioned actuating element is manufactured by first forming an electrode layer on the vibration layer, then forming a piezoelectric layer on the lower electrode layer, and finally forming an upper electrode layer on the pressure electrode. On the floor. Among them, the method of connecting the actuator and the vibration layer is, for example, a high-temperature sintering method. In addition, the material of the piezoelectric layer is, for example, piezoelectric ceramics, and the materials of the material layers constituting the vibration layer and the ink chamber layer are, for example, ceramics, polymers, or metals. When the piezoelectric layer is made of piezoelectric ceramics, a step of sintering the piezoelectric layer is further performed to make the piezoelectric layer have piezoelectric characteristics. The invention is to provide a master mold for integrally forming the ink cavity layer and the vibration layer of the inkjet print head on the master mold. Since the ink cavity layer and the vibration layer are integrally formed during the manufacturing process, the ink cavity layer and the The vibrating layer has good jointability, and can effectively solve the problem of penetration between the conventional ink cavity layer and the vibrating layer, and reduce the complexity of manufacturing the inkjet print head. In order to make the above and other objects, features, and advantages of the present invention more comprehensible, a preferred embodiment is given below and described in detail in conjunction with the accompanying drawings. As follows: [Embodiment] Please refer to it in order Figures 2A to 2E are cross-sectional flowcharts of a piezoelectric inkjet print head according to a preferred embodiment of the present invention. As shown in FIG. 2A, a master mold 200 is provided first, and the master mold 200 has a plurality of openings 202, which are recessed on one surface of the master mold 200. Next, as shown in FIG. 2B, a material layer 2 10 is formed, and the material layer 2 10 fills the openings 2 2 and covers the surface of the female mold 2 0 2 having the openings 2 2. Among them, the part that fills these openings 2 2

11159twf.ptd 第10頁 576799 五、發明說明(6) 分材料層2 1 0係構成一圖案化之墨腔層2 2 0,而覆蓋於母模 2 0 0表面之部分材料層2 1 0係構成一振動層2 3 0。此外,構 成上述之圖案化墨腔層2 2 0及振動層2 3 0之材料層2 1 0的材 質例如是選用陶瓷、高分子聚合物或金屬。 如第2 C圖所示,接著將至少一致動元件2 4 0 (本圖繪 示四個)配置於振動層2 3 0上。此外,製作致動元件2 4 0的 步驟,係先形成一下電極層2 4 2於振動層2 3 0上,之後形成 一壓電層244於下電極層242上,最後形成一上電極層246 於壓電極層244上,而壓電層244之材質例如是選用壓電陶 瓷。值得注意的是,若壓電層2 4 4之材質選用壓電陶瓷, 其需進一步進行一燒結壓電層244的步驟以使壓電層244具 有壓電特性(即施加電壓會對應產生形變的特性)。 如第2 D圖所示,接著將母模2 0 0移除,此時圖案化之 墨腔層220即與振動層230 —體成型。此外,母模200與前 述材料層2 1 0的材質可選用密合性不高者為佳,用以順利 移除母模2 0 0。另外,上述高溫燒結與脫模的步驟並不侷 限其先後順序,若母模2 0 0與致動元件2 4 0以及前述材料層 2 1 0先進行高溫燒結,再進行脫模的步驟,母模2 0 0之材質 則需選用耐熱性材質。 如第2 E圖所示,再移除母模2 0 0之後,接著配置一喷 孔片250於圖案化墨腔層220之上,以使振動層230 、圖案 化墨腔層220及喷孔片250構成至少一墨水腔260 (本圖繪 示四個),其中噴孔片250具有至少一噴孔252 (本圖繪示 四個),並與墨水腔2 6 0相連通,如此即完成喷墨印頭之11159twf.ptd Page 10 576799 V. Description of the invention (6) The material layer 2 1 0 constitutes a patterned ink cavity layer 2 2 0, and a part of the material layer 2 1 0 covering the surface of the master mold 2 0 0 A vibration layer 2 3 0 is formed. In addition, the material constituting the material layer 2 10 of the patterned ink cavity layer 2 2 0 and the vibration layer 2 3 0 is, for example, a ceramic, a polymer, or a metal. As shown in FIG. 2C, at least the moving element 2 4 0 (four are shown in this figure) is then disposed on the vibration layer 2 3 0. In addition, the step of manufacturing the actuating element 240 is to first form an electrode layer 2 42 on the vibration layer 2 30, then form a piezoelectric layer 244 on the lower electrode layer 242, and finally form an upper electrode layer 246. The piezoelectric electrode layer 244 is made of piezoelectric ceramic. It is worth noting that if the material of the piezoelectric layer 2 4 4 is a piezoelectric ceramic, it needs to further perform a step of sintering the piezoelectric layer 244 to make the piezoelectric layer 244 have piezoelectric characteristics (that is, the applied voltage will correspondingly produce deformation. characteristic). As shown in FIG. 2D, the master mold 200 is then removed. At this time, the patterned ink cavity layer 220 and the vibration layer 230 are integrally formed. In addition, the material of the master mold 200 and the aforementioned material layer 2 10 may be selected with a low adhesion, so as to smoothly remove the master mold 200. In addition, the above-mentioned steps of high-temperature sintering and demolding do not limit their sequence. If the master mold 200, the actuating element 2 40, and the aforementioned material layer 2 1 0 are first subjected to high-temperature sintering, and then the demolding step is performed, The material of mold 2 0 0 needs to choose heat-resistant material. As shown in FIG. 2E, after removing the master mold 200, an orifice plate 250 is then disposed on the patterned ink cavity layer 220 to make the vibration layer 230, the patterned ink cavity layer 220, and the orifice The sheet 250 constitutes at least one ink cavity 260 (four are shown in this figure), and the nozzle hole sheet 250 has at least one spray hole 252 (four are shown in this figure), and communicates with the ink cavity 260. Of inkjet print head

11159twf.ptd 第11頁 576799 五、發明說明(7) 製作。因此,藉由施加一電壓於上電極層246及下電極層 2 4 2間,使壓電層2 4 4受到一電壓差,而對應產生形變去瞬 間推移振動層2 3 0,進而直接或間接地瞬間施壓墨水腔2 6 0 之内的墨水,使得部分接近喷孔2 5 2之墨水將從喷孔2 5 2喷 出。 故從上述可得知,本發明係藉由提供一母模,用以在 母模上一體成型製作喷墨印頭中的墨腔層與振動層,而有 關母模的製作,將於下文中詳細說明。 請依序參考第3 A〜3 C圖,其為本發明之一較佳實施例 之母模的剖面流程圖。首先,如第3 A圖所示,提供一基材 3 0 0,例如是石夕基材。接著,如第3 B圖所示,全面性形成 鲁 一材質例如是環氧化物(e ρ ο X y )之光阻層3 1 0 (Photo-Resist,PR)於基材300之上,並利用曝光 (exposure )及顯影(development)等製程,將光阻310 層圖案化,而形成多個開口 3 1 2。 在本實施例中,係配置一圖案化之光罩3 2 0於光阻層 3 1 0上方進行曝光,其照射之光線例如是採用紫外光 ^ (UV-1 ight ),且曝光光阻層310之局部區域後,例如使 用負片型之顯像液,將光阻層3 1 0上之其餘未曝光區域去 除,而形成多個開口 3 1 2 ,用以填充第2 B圖所繪示之材料 層210,以一體形成墨腔層220及振動層230。 請依序參考第4A〜4E圖,其為本發明之另一較佳實施 _ 例之母模的剖面流程圖。首先,如第4 A圖所示,提供一基 材4 0 0,例如是矽基材或金屬基材。接著,如第4B圖所11159twf.ptd Page 11 576799 V. Description of Invention (7) Production. Therefore, by applying a voltage between the upper electrode layer 246 and the lower electrode layer 2 4 2, the piezoelectric layer 2 4 4 is subjected to a voltage difference, and a corresponding deformation is caused to instantaneously move the vibration layer 2 3 0, and then directly or indirectly. Press the ink within the ink chamber 260 instantly, so that part of the ink close to the nozzle hole 2 5 2 will be ejected from the nozzle hole 2 5 2. Therefore, it can be known from the foregoing that the present invention is to provide a master mold for integrally forming the ink cavity layer and the vibration layer in an inkjet print head on the master mold. The manufacture of the master mold will be described below. Detailed description. Please refer to FIGS. 3A to 3C in sequence, which is a cross-sectional flowchart of a master mold according to a preferred embodiment of the present invention. First, as shown in FIG. 3A, a substrate 300 is provided, for example, a Shi Xi substrate. Next, as shown in FIG. 3B, a photoresist layer 3 1 0 (Photo-Resist (PR)), such as an epoxide (e ρ ο X y), is formed on the substrate 300 in a comprehensive manner, and The photoresist 310 layer is patterned using processes such as exposure and development to form a plurality of openings 3 1 2. In this embodiment, a patterned photomask 3 2 0 is disposed above the photoresist layer 3 1 0 for exposure. The light irradiated is, for example, ultraviolet light (UV-1 ight), and the photoresist layer is exposed. After the partial area of 310, for example, a negative-type developing solution is used to remove the remaining unexposed areas on the photoresist layer 3 10 to form a plurality of openings 3 1 2 to fill the areas shown in FIG. 2B. The material layer 210 forms an ink cavity layer 220 and a vibration layer 230 as a whole. Please refer to FIGS. 4A to 4E in sequence, which is a cross-sectional flowchart of a mother mold according to another preferred embodiment of the present invention. First, as shown in FIG. 4A, a substrate 400 is provided, such as a silicon substrate or a metal substrate. Next, as shown in Figure 4B

11159twf.ptd 第12頁 576799 五、發明說明(8) 示,全面性形成一材質例如是聚曱基丙烯酸曱酯(PMMA ) 之光阻層410 (PR)於基材400之上,並利用曝光及顯影等 製程,將光阻層4 1 0圖案化。 在本實施例中,係配置一圖案化之光罩4 2 0於光阻層 4 1 0上方進行曝光,其照射之光線例如是採用X光 (X - 1 i g h t ),且曝光光阻層4 1 0之局部區域後,例如使用 負片型之顯像液,將光阻層4 1 0上之其餘未曝光區域去 除。 如第4D圖所示,在將光阻層410上之未曝光區域去除 之後,接著形成一導體層4 3 0在未覆蓋此圖案化光阻層4 1 0 之基材4 0 0上。值得注意的是,當基材4 0 0係選用金屬材質 · 時,例如以電鍍之方式直接在基材4 0 0形成上述之導體層 4 3 0,而當基材係選用非金屬材質(如矽基材)時,則在 形成圖案化光阻層410於基材400上之前,先形成一電鍍種 子層(seed layer)(圖未示出)於此基材400上,之後 再例如以電鍍之方式在基材400上形成上述之導體層430。 最後,如第4 E圖所示,移除此圖案化光阻層4 1 0,以 形成多個開口 4 4 0 ,用以填充第2 B圖所繪示之材料層2 1 0 , 以一體形成墨腔層220及振動層230。 綜上所述,本發明之喷墨印頭之製程其主要特徵係在 於提供一母模,並在母模上一體成型製作噴墨印頭之墨腔 層及振動層。值得注意的是,由於一體成型製作喷墨印頭 ® 之墨腔層及振動層,故墨腔層及振動層之間的接合性較 佳,且不需如習知技術以高溫共燒或黏著的方式另行接合11159twf.ptd Page 12 576799 5. The description of the invention (8) shows that a photoresist layer 410 (PR), such as polymethyl acrylate (PMMA), is comprehensively formed on the substrate 400, and exposure is performed by using And developing processes, patterning the photoresist layer 410. In this embodiment, a patterned photomask 4 2 0 is arranged above the photoresist layer 4 1 0 for exposure. The irradiated light is, for example, X-ray (X-1 ight), and the photoresist layer 4 is exposed. After a local area of 10, for example, a negative-type developing solution is used to remove the remaining unexposed areas on the photoresist layer 4 10. As shown in FIG. 4D, after removing the unexposed areas on the photoresist layer 410, a conductor layer 4 3 0 is formed on the substrate 4 0 which does not cover the patterned photo resist layer 4 1 0. It is worth noting that when the substrate 400 is made of a metal material, for example, the conductive layer 4 3 0 described above is directly formed on the substrate 400 by electroplating, and when the substrate is made of a non-metal material (such as Silicon substrate), before forming the patterned photoresist layer 410 on the substrate 400, a plating seed layer (not shown) is formed on the substrate 400, and then, for example, electroplating In this way, the above-mentioned conductive layer 430 is formed on the substrate 400. Finally, as shown in FIG. 4E, the patterned photoresist layer 4 1 0 is removed to form a plurality of openings 4 4 0, which are used to fill the material layer 2 1 0 shown in FIG. 2 B to be integrated. An ink cavity layer 220 and a vibration layer 230 are formed. In summary, the main feature of the inkjet print head manufacturing process of the present invention is to provide a master mold, and integrally mold the master mold to form the ink cavity layer and the vibration layer of the inkjet print head. It is worth noting that because the ink cavity layer and the vibration layer of the inkjet printhead® are integrally formed, the adhesion between the ink cavity layer and the vibration layer is better, and it is not necessary to co-fire or adhere at high temperature as in conventional techniques Way to join separately

1 Γ159rwf. ptd 第13頁 576799 五、發明說明(9) 振動層及墨腔 位置即固定, 間即不會發生 此外,更 層,所以本發 墨腔層間不會 好的列印品質 另外,本 母模,用以在 動層,且母模 雖然本發 以限定本發明 神和範圍内, 護範圍當視後 層,所以 如此配置 對位不準 由於 明噴墨印 產生縫隙 本發明之振動層及墨腔層間的相對 於振動層上之致動元件與墨水腔之 確的問題。 體成型製作喷墨印頭之墨腔層及振動 頭之製程將可簡單化,且振動層及 ,而發生漏墨之情形,故可維持良 發明係藉由曝光、顯影及電鍍等方式製作一 母模上一體成型製作噴墨印頭的墨腔層與振 可重複使用,進而降低製程的成本。 明已以一較佳實施例揭露如上,然其並非用 ,任何熟習此技藝者,在不脫離本發明之精 當可作些許之更動與潤飾,因此本發明之保 附之申請專利範圍所界定者為準。1 Γ159rwf. Ptd Page 13 576799 V. Description of the invention (9) The position of the vibrating layer and the ink chamber is fixed, and it will not occur in between. In addition, the layer will be better, so the printing quality between the ink chamber layers of the hair will not be good. The master mold is used in the moving layer, and although the master mold is to limit the scope of the present invention, the protective range is regarded as the rear layer, so the alignment is not allowed due to the gap caused by the bright inkjet printing. The vibration layer of the present invention And the problem between the ink chamber layer and the actuator element on the vibration layer and the ink chamber is indeed a problem. The process of forming the ink cavity layer and the vibrating head of the inkjet print head by volume molding can be simplified, and the vibration layer and the case of ink leakage, so it can be maintained. The invention is made by exposure, development, and plating. The ink cavity layer and the vibration of the inkjet print head that are integrally formed on the master mold can be reused, thereby reducing the cost of the process. The Ming has disclosed the above with a preferred embodiment, but it is not useful. Anyone skilled in this art can make some changes and retouch without departing from the essence of the present invention. Therefore, the scope of the patent application attached to the present invention is defined Whichever comes first.

11159twf.ptd 第14頁 576799 圖式簡單說明 第1圖是習知壓電式喷墨印頭的剖面示意圖; 第2 A〜2 E圖是本發明之一較佳實施例之壓電式喷墨印 頭的剖面流程圖; 第3 A〜3 C圖是本發明之一較佳實施例之母模的剖面流 程圖;以及 第4 A〜4 E圖是本發明之另一較佳實施例之母模的剖面 流程圖。 【圖式標示說明】 100 壓 電 式 喷墨印頭 110 振 動 層 120 墨 腔 層 130 噴 孔 片 132 喷 孔 140 致 動 元 件 150 墨 水 腔 200 母 模 202 開 U 21 0 材 料 層 220 墨 腔 層 230 振 動 層 240 致 動 元 件 242 下 電 極 層 244 壓 電 層 246 上 電 極 層11159twf.ptd Page 14 576799 Brief description of the drawings Figure 1 is a schematic cross-sectional view of a conventional piezoelectric inkjet print head; Figures 2 A to 2 E are piezoelectric ink jets according to a preferred embodiment of the present invention Sectional flow chart of the print head; Figs. 3A to 3C are cross-sectional flow charts of a master mold according to a preferred embodiment of the present invention; and Figs. 4A to 4E are another preferred embodiment of the present invention. Sectional flow chart of the master mold. [Illustration of Graphical Indication] 100 Piezoelectric inkjet print head 110 Vibration layer 120 Ink cavity layer 130 Nozzle piece 132 Nozzle 140 Actuating element 150 Ink cavity 200 Female mold 202 Open U 21 0 Material layer 220 Ink cavity layer 230 Vibrating layer 240 Actuating element 242 Lower electrode layer 244 Piezoelectric layer 246 Upper electrode layer

11159twf.ptd 第15頁 576799 圖式簡單說明 250 252 260 300 310 3 12 320 430 喷孔片 喷孔 墨水腔 400 410 440 420 導電層 基材 光阻層 開口 光罩11159twf.ptd Page 15 576799 Brief description of the drawings 250 252 260 300 310 3 12 320 430 Nozzle sheet Nozzle Ink cavity 400 410 440 420 Conductive layer substrate Photoresist layer opening Photomask

11159twf.ptd 第16頁11159twf.ptd Page 16

Claims (1)

576799 六、申請專利範圍 1 · 一種喷墨印頭之製程,包括下列步驟: 提供一母模,該母模具有複數個開口,其凹陷於該母 模之一表面; 形成一材料層,該材料層填滿該些開口 ,並覆蓋住該 母模之該表面,其中填滿於該些開口之局部該材料層係構 成一圖案化墨腔層,而覆蓋於該母模之該表面的局部該材 料層係構成一振動層; 配置至少一致動元件於該振動層上; 移除該母模;以及 配置一噴孔片於該墨腔層之較遠離該振動層的一面, 以使該振動層、該圖案化墨腔層及該喷孔片構成至少一墨 _ 水腔,其中該喷孔片具有至少一喷孔,且該噴孔係與該墨 水腔相連通。 2. 如申請專利範圍第1項所述之喷墨印頭之製程,其 中該母模之製作,包括下列步驟: 提供一基材;以及 形成一圖案化光阻層於該基材上,以形成該些開口。 3. 如申請專利範圍第2項所述之喷墨印頭之製程,其 中形成該圖案化光阻層之方法包括曝光及顯影。 4. 如申請專利範圍第2項所述之喷墨印頭之製程,其 中該基材包括石夕基材。 5. 如申請專利範圍第2項所述之喷墨印頭之製程,其 · 中該圖案化光阻層之材質包括環氧化物。 6. 如申請專利範圍第1項所述之喷墨印頭之製程,其576799 VI. Scope of Patent Application 1. A process of inkjet print head, including the following steps: Provide a master mold, the master mold has a plurality of openings, which are recessed on one surface of the master mold; forming a material layer, the material The layer fills the openings and covers the surface of the master mold, wherein a part of the material layer filled in the openings forms a patterned ink cavity layer, and a part of the surface of the master mold covers The material layer constitutes a vibrating layer; at least a uniform moving element is disposed on the vibrating layer; the master mold is removed; and an orifice plate is disposed on a side of the ink cavity layer farther from the vibrating layer so that the vibrating layer The patterned ink cavity layer and the spray hole sheet form at least one ink_water cavity, wherein the spray hole sheet has at least one spray hole, and the spray hole is in communication with the ink cavity. 2. The process of the inkjet print head described in item 1 of the scope of patent application, wherein the production of the master mold includes the following steps: providing a substrate; and forming a patterned photoresist layer on the substrate to These openings are formed. 3. The process of the inkjet print head described in item 2 of the scope of patent application, wherein the method of forming the patterned photoresist layer includes exposure and development. 4. The process of the inkjet print head as described in item 2 of the scope of patent application, wherein the substrate comprises a Shixi substrate. 5. The process of the inkjet print head described in item 2 of the scope of patent application, wherein the material of the patterned photoresist layer includes an epoxide. 6. The process of inkjet print head as described in item 1 of the patent application scope, which 11159twf.ptd 第17頁 576799 六、申請專利範圍 中該母模之製作,包括下列步驟: 提供一基材; 形成一圖案化光阻層於該基材上; 形成一導體層在未覆蓋該圖案化光阻層之該基材上; 以及 移除該圖案化光阻層,以形成該些開口。 7.如申請專利範圍第6項所述之噴墨印頭之製程,其 中該基材包括石夕基材及金屬基材其中之一。 8 .如申請專利範圍第6項所述之喷墨印頭之製程,其 中該圖案光阻層之材質包括聚甲基丙烯酸甲酯。 9 .如申請專利範圍第6項所述之喷墨印頭之製程,其 中形成該導體層之方式包括電鍍。 1 0 .如申請專利範圍第6項所述之喷墨印頭之製程,其 中在形成該圖案化光阻層於該基材上的步驟之前,更包括 以電鍍之方式形成一電鍍種子層於該基材上。 1 1。如申請專利範圍第1項所述之喷墨印頭之製程,其 中該材料層之材質包括陶瓷、高分子聚合物及金屬其中之 --- 1 2 .如申請專利範圍第1項所述之喷墨印頭之製程,其 中該致動元件之製作,包括下列步驟: 形成一下電極層於該振動層上; 形成一壓電層於該下電極層上;以及 形成一上電極層於該壓電極層上。 1 3,如申請專利範圍第1 2項所述之喷墨印頭之製程,11159twf.ptd Page 17 576799 6. The production of the master mold in the scope of patent application includes the following steps: providing a substrate; forming a patterned photoresist layer on the substrate; forming a conductor layer without covering the pattern Patterning the photoresist layer on the substrate; and removing the patterned photoresist layer to form the openings. 7. The process of inkjet print head as described in item 6 of the scope of patent application, wherein the substrate comprises one of a stone substrate and a metal substrate. 8. The process of inkjet print head as described in item 6 of the scope of patent application, wherein the material of the pattern photoresist layer includes polymethyl methacrylate. 9. The process of inkjet print head described in item 6 of the scope of patent application, wherein the method of forming the conductor layer includes electroplating. 10. The process of the inkjet print head described in item 6 of the patent application scope, wherein before the step of forming the patterned photoresist layer on the substrate, it further comprises forming a plating seed layer by electroplating. On the substrate. 1 1. For example, the process of the inkjet print head described in item 1 of the scope of the patent application, wherein the material of the material layer includes ceramics, high molecular polymers and metals-1 2. In the manufacturing process of the inkjet print head, the manufacturing of the actuating element includes the following steps: forming a lower electrode layer on the vibration layer; forming a piezoelectric layer on the lower electrode layer; and forming an upper electrode layer on the pressure On the electrode layer. 1 3. According to the process of inkjet print head described in item 12 of the scope of patent application, 11159twf. pid 第18頁 576799 六、申請專利範圍 其中該壓電層之材質包括壓電陶瓷。 1 4 .如申請專利範圍第1 3項所述之喷墨印頭之製程, 其中在配置該喷孔片於該墨腔層之較遠離該振動層的一面 的步驟之前,更包括對該壓電層進行燒結。11159twf. Pid Page 18 576799 6. Scope of patent application Where the material of the piezoelectric layer includes piezoelectric ceramics. 14. The process of the inkjet print head described in item 13 of the scope of patent application, wherein before the step of arranging the nozzle plate on the side of the ink cavity layer farther from the vibration layer, the method further includes The electrical layer is sintered. 11159twf.ptd 第19頁11159twf.ptd Page 19
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