TW575627B - Conditioning agent and use thereof - Google Patents

Description

575627 Α7 Β7 V. Description of the Invention (1) Technical Field The present invention relates to a modifier composition that promotes the adsorption of palladium-tin colloidal catalysts on non-conductors such as plastics. More specifically, it relates to the use of even a low concentration of Palladium-tin colloidal catalysts can also make palladium-tin colloidal catalysts fully analyzable. Modifiers, modifier compositions, and methods of using these methods to precipitate palladium-tin colloidal catalysts on non-conductive polymer materials . The prior art has always been to form a metal film on non-conductive polymer materials such as plastic, and a fine-tin colloid catalyst (hereinafter referred to as ^ P d-S η catalyst) is precipitated on the surface of the polymer material. Afterwards, if necessary, electroless plating is followed by metal plating, which is the so-called plastic plating method. Further, recent printed circuit boards are generally multilayered by combining a plurality of printed substrates. Through-holes and countersinks are provided between these substrates, and metal is deposited in these holes to make each substrate conductive. In any of the above methods, in order to ensure that the metal film is formed in the target part of the subsequent steps, it is necessary to make the P d-S η catalyst fully and uniformly adsorb and precipitate during the catalytic treatment. Therefore, in order to obtain such adsorption and precipitation, it is necessary to use a Pd-Sri catalyst solution with a certain concentration or more. However, the pin itself is an extremely expensive metal. The higher the concentration of the pn catalyst liquid, the greater the economic loss of the catalyst due to the so-called "draining out" of the catalyst. There is a strong demand for catalytic treatment at a lower concentration. . Therefore, the subject in this field is to provide a method for reducing the concentration of the P d-S η catalyst solution and uniformly precipitating the P d-s η catalyst layer. 'The original paper size applies the Chinese National Standard (CNS) A4 specification < 210X297 public envy) (Please read the precautions on the back before filling out this page) Order printed by the Intellectual Property Bureau employee consumer cooperative of the Ministry of Economic Affairs 575627 A7 B7 Printed by the employee property cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (2) To be resolved . In addition, polyimide resins (especially laser apertured surfaces) or glass fiber-containing resins, which have been poorly adjusted by conventional regulators, are also expected to provide excellent tuning effects. Disclosure of the invention The steps before the chemical treatment were added to the middle group ^ Confession excellent 1/3 The inventor has studied various conditions related to catalytic treatment and learned that the catalyst is not only good, but not only the P d-S η catalyst solution used, but also It first adjusts the impact of processing. Therefore, it has been found that for a composition having a higher adjustment effect, a catalyst composition using a specific macromolecular component modifier or a modifier composition prepared with other specific macromolecular components can improve the catalytic effect, even if only the conventional one is used. The left and right concentrations of the P d — S η catalyst liquid can also precipitate the P d-S η catalyst layer without problems, and have excellent adjustment effects, and finally completed the present invention. That is, the first object of the present invention is to provide formula (I), (II) or (III) containing the following component (A) (A)

0々 \ 〇R / -CHrC- 、 〇—l 「-n—r4 CH SO; 3 4 (Please read the precautions on the back before filling this page)

, 1T (I) (where R represents a saturated or unsaturated fluorenyl group of 1 to 20 carbon atoms, and each of R 1 to R 5 is not a lower-level radical; L 1 is a lower-level radical; ^ and m are each (Numbers from 5 to 10) This paper size is applicable to the National Standard (CNS) A4 specification (210X297 mm) -5- 575627 Α7 Β7 V. Description of the invention (3) I Re \ —fN—CHrC—〇—— \ R7 0 / 丨 (wherein R 6 and R 7 each represent a lower alkyl group, and the number thereof) PEG—f—NH-L— “NH-PEg” ^ (wherein, .PEG represents a molecular weight of 1,000,000. Polyethylene glycol groups up to 10,000, L 2 represents a saturated or unsaturated alkynyl group having 12 to 20 carbon atoms, and P represents a number of 10 to 100). One or two or more of them are used as an effective degreasing adjuster. In addition, the second object of the present invention is to provide the above-mentioned ingredients (A) and the following ingredients (B), (please read the precautions on the back and fill in this page)

(B) The following formula (I V), (V) or (V I)

This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -6- 575627 A7 B7 V. Description of invention (4)

CH ~ C 卩 9

(V) (In the formula, Rs and R9 are not hydrogen or a lower grade number of 10, 0, 00).

CH-C ^ 8 卩 9

νη2 · η (VI) (Please read the precautions on the back before filling out this page) or two or more printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (where Z represents halogen ion, sulfate, nitrate or phosphate Ions, Rs, R9 and r are the same as above) The modifier composition of the polymer compound shown as an effective ingredient. Furthermore, the object of the present invention is to provide palladium-tin which is characterized by treating non-conductive polymer materials with the above-mentioned adjusting agent or adjusting agent composition and immersing them in a catalyst containing a palladium-tin colloid catalyst. Precipitation method of colloidal catalyst on non-conductive polymer material. BEST MODE FOR CARRYING OUT THE INVENTION The adjusting agent of the present invention is prepared by using the component (A) (first polymer component) selected from the polymer compounds represented by the formulae (I) to (I I I) as an effective component. In this component (A), the polymer compound represented by formula (I) has the paper size applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 575627 Α7 B7 5. The invention description (5) has the following formula ( VII) A structure in which the acrylate monomer represented by the formula (VIII) is copolymerized with the quaternary compound monomer represented by the formula (VIII).

OR 2q

• C, 〇

I 〇 2q

-C 〇

A 5 Ν-—R

H (Please read the precautions on the back before filling out this page) (where R, Ri to Rs and Li are the same as above) In the polymer compound (I), the ester group R can be 1 to 2 carbon atoms. Alkyl or alkenyl, specific examples thereof include 'stearyl, palmyl, and oleyl. Examples of the lower alkyl group of R i to R 5 include a methyl group, an ethyl group, a propyl group and the like, and an alkyl group having 1 to 4 carbon atoms. The lower alkenyl of L: may be methylene, vinyl, and the like. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The polymer compound (I) can be obtained by copolymerizing an acrylate monomer (V I I) and an acrylate quaternary compound monomer (V I 丨 丨) according to a general method. In addition, among the polymer compounds used as the component (A), a polymer having a polycondensation structure represented by the following formula (I X) is represented by formula (; [ί)). -8- This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 575627 A7 B7 V. Description of invention (6) X—N——CH2-C—〇H, (IX) I II ',' r7 (in the formula, X represents a leaving group such as halogen, and Re and R7 are the same as above) In the polymer compound (II), a lower radical represented by formulae R 6 and R 7 may be methyl, ethyl, propyl, etc. , An alkyl group having 1 to 4 carbon atoms. The polymer compound (1 1) can also be obtained by polymerizing and condensing a monomer (I X) according to a general method. Furthermore, in the component (A), the polymer compound (III) has, for example, a condensation structure of a diamine and a polyethylene oxide represented by the formula (X y), and the L 2 group in the formula (I Γ I) may be hard Fat group, palm group, oil group, etc. H2N-L2-NH2 (X) The polymer compound (1 1 1) can be produced by reacting diamine (X) with polyethylene oxide according to a general method. The above-mentioned local molecular compounds of the formulae (I) to (III) are all commercially available products and can be purchased from, for example, Japan Oils and Fats Co., Ltd. The adjusting agent of the present invention is the above-mentioned fluorene molecular compounds (I) to (III) Any one or more of them can be prepared by combining with an appropriate carrier or other ingredients if necessary. The above-mentioned ingredient (A) can be a concentration in the bath of about 0.1 to 20 g / liter, preferably 1 to 5 g / This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) ^ *-(Please read the precautions on the back before filling this page)

、 1T Φ ·. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 575627 A7 B7 V. Description of the invention (about 7 liters, with the second highest score of polymer (A) listed in ingredient (A) IV) low grade PVAD with sub-numbers 1 to 4, and other commercially available products such as "), and R 8 and R) of these partial amines with sub-numbers 1 to 4, or sulfuric acid, nitric acid, and regulators. Ming's modifier composition is based on the first polymer component, and is selected from the formula (

V to (V I) The component (B) of the compound is prepared. Among the sub-components' component (B), the polymer compounds (the radical R may include methyl'ethyl, propyl, etc., and carbon orthoalkyl groups. The polymer compounds V) include, for example, DiaClear "(all of which are Mitsubishi Chemical Corporation) Co., Ltd., can be used. In (B), the polymer compounds (v) and (v I lower alkyl 'can be methyl, ethyl, propyl, etc., carbon orthoalkyl. The sub-compounds are as follows The alkyl ethylene represented by formula (XI) is obtained by quaternizing the amine group of the polymer with a halogen acid such as hydrochloric acid or phosphoric acid. R8 / c = qv

(XI (Please read the precautions on the back before filling out this page) This product is printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. This product also has commercially available products such as PVA Μ (Mitsubishi Chemical Corporation). The component (A) of the adjusting agent composition of the present invention is formulated in the adjusting agent composition so that the concentration in the bath is about 0.1 to 20 g / liter, especially about 1 to 5 g / liter. It is better, and the composition (B) of this paper is in accordance with the Chinese National Standard (CNS) A4 specification (210X297 mm) -10- 575627 A7 _ ___ B7 V. Description of the invention (8) The concentration in the bath when used is 0. About 1 to 10 grams / liter, especially about 1 to 5 grams / liter, it is better to mix with the adjuster composition. (Please read the precautions on the back before filling this page) The adjuster or adjuster of the present invention The composition is prepared by using the component (A) alone or in combination with the component (B) as described above, and an appropriate carrier or other component may be added when necessary. The adjusting agent or adjusting agent composition of the present invention (Hereinafter referred to as "adjusting agent, etc.") Examples of the combined support or other components include organic amine compounds such as monoethanolamine and triethanolamine, inorganic alkaline compounds such as sodium hydroxide, sodium carbonate, and sodium silicate, nonylphenol ethoxide, and secondary alcohol ethoxide. Non-ionic surfactants, etc. Among these ingredients, organic substances such as organic amine compounds, inorganic test compounds, and other alkaline substances or surfactant modifiers are used to improve degreasing power, so they are not only used as modifiers. It can also be used as a degreasing adjuster. The preferred ingredients and the amount range when preparing the degreasing adjuster are exemplified below. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (A): 0 · 1 to 20 grams / L (1 to 5g / L) [ingredient (B) ·· 0.1 to 10g / L (1 to 5g / L)] Monoethanolamine: 2 to 30g / L (5 to 20G / L) ) Triethanolamine: 1 to 20 g / liter (2 to 10 g / metric paper size applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) _ '' _ 575627 Μ B7 V. Description of the invention (9 ) L) Hydroxide fishing: 0 to 5 G / L (0 to 20 g / L) Sodium carbonate: 0 to 50 g / L (0 to 20 G / L) Non-ionic surfactant: 0 to 3 0 g / L (2 to 10) (G / litre) (Note) The conditioner of the present invention obtained in the brackets is the preferred range. As in the past, the conditioner can be used in electroless plating, and it can be used for direct electroplating (DPS method) before electroless plating. For various non-conductive polymer materials, such as substrates of plastic materials, glass fiber epoxy resin, polyimide resin, etc., it can be used to enhance the precipitation of P d — S η catalyst. The use conditions of the adjusting agent and the like of the present invention are not particularly limited, and may be substantially the same as those known, and the amount of the P d-S η catalyst contained in the catalyst may be lower than in the past. That is, as in the following examples, the adjusting agent of the present invention is particularly a polyimide resin which is difficult to precipitate P d-S η catalyst, and only has P d-S of a concentration of 1/3 that has been required in the past. The catalyst with η catalyst concentration can also be completely precipitated. Therefore, by adjusting with the adjusting agent of the present invention, the catalyst concentration in the subsequent steps can be reduced. As a result, the amount of P d-S η catalyst can be reduced, which is extremely economically advantageous. This paper size is applicable to China National Standards (CNS) Α4 (21〇X 297 mm) (Please read the precautions on the back before filling out this page} ΙΊΙ.— ·· 1 Φ ·. Consumption by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the cooperative 575627 A7 B7 V. Description of the invention (10) In addition, when the adjusting agent of the present invention is used, the P d — S η catalyst is uniformly precipitated out of the non-conductive polymer material, compared with the use of conventional adjusting agents. It has the characteristics that it is not easy to generate pits and rough surfaces after metal plating. Furthermore, the use of the adjusting agent of the present invention can precipitate the P d-S η catalyst at a wide catalyst concentration, which also belongs to liquid bath management. Advantages. The following examples will be used to explain the present invention in more detail. However, the present invention is not limited to these examples in any way. Example 1 FPC substrate (polyimide resin; thickness of 50 microns, copper foil on both sides) 18 microns) Lasers are used for openings of through-holes with various apertures, and electroless copper plating is performed by the following processing steps. After electroless copper plating is completed, the cross-section of the through-hole is cut and observed with a microscope to explore the resin in the through-hole Surface copper Coverage rate: The composition shown below was used for degreasing adjustment. The results are not shown in Table 1. Test degreasing adjuster composition: (Product 1 of the present invention) A polymer of formula (I) (R = Ci8H37, R1 to R.5 = methyl, Li = ethylene, n = 8, m = 8) 5 gram / liter local molecule of formula (IV) (R '= C3H7, Y = Chinese paper standard (CNS) A4 specification applies to this paper size (210X297 mm) (Please read the notes on the back before filling this page)

, 1T ΦΤ. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 575627 A7 B7 V. Description of the invention (11) S 〇3 ，, q methylethanolamine triethanolamine nonanol ethoxylate 5 0 0) 2 g / liter 1 〇 Gram / liter 5 gram / liter 5 gram / liter product of the present invention 2) Polymer of formula (I) (R = C18H37, feet 1 to feet 5 = methyl, L 1 = ethane, η = 8, m = 8 ) (Please read the precautions on the back before filling this page) Monoethanolamine triethanolamine nonanol ethoxylate printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Comparative 1) Trimethylstearyl stearate monoethanolamine triethanolamine Nonyl ethoxylate treatment steps: .5 grams 0 grams 5 grams 5 grams liters liters 5 grams / liters 0 grams / liters 5 grams / liters 5 grams / liters of degreasing modifier (Table 1) 6 0 ° C 5 minutes Soft etching * 1 2 5 ° C 1 minute pre-immersion * 2 2 5 ° C 1 minute pre-order * 丨 -Φ ». This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) -14- 575627 A7 B7 V. Description of the invention (12) Catalyst * 3 3 0 ° C 5 minutes accelerator * 4 3 0 ° C 5 Bell electroless copper plating * 5 2 5 ° C 1 5 minutes * 1: PB 2 2 8 (manufactured by Ebara Ulite Technology Co., Ltd.) 1 0 0 g / L * 2: p B 2 3 2 (Ebara Ulat Technology Co., Ltd.) 200 g / L * 3: PB 3 1 8 (manufactured by Ebara Ulite Technology Co., Ltd.) 7 ml / L (30 mg / L in terms of P d) * 4: 100 g / sulfuric acid Liter PB-4 4 5 (manufactured by Ebara Ulite Technology Co., Ltd.) 5ml / L * 5: PB 5 0 3 AF (manufactured by Ebara Ulite Technology Co., Ltd.) 100ml / L PB 5 0 3 BF ( Liaoyuan Youlite Technology Co., Ltd.) 100 ml / liter (please read the precautions on the back before filling out this page) Printed on the paper standard of the China National Standards (CNS) A4 standard printed by the employee consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (210X297 mm) -15- 5 is 627 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (13) (Result) 袠 1 Aperture (mm must be) Coverage rate in the through hole (5 ^) Invention 1 Invention 2 Comparative 1 0.2 100 8 0 30 0.3 100 100 40 0.4 100 100 60 ._ 1.0 100 100 60 As shown in the results of Table 1, when the product 1 of the present invention containing the component (A) and the component (B) is used as a degreasing adjuster, it is most difficult to precipitate the electroless copper plating polymer. Through holes of 0 · 2 mm 0 in imide resin can be completely covered in the holes at a standard concentration of 1/3 or less. In addition, the product 2 of the present invention containing the component (A) is relatively inferior to the through hole of 0 · 2 mm 0, but has an overwhelmingly higher coverage rate than the comparative product 1 used in the past. Example 2 Use and implementation In Example 1, the performance of each degreasing modifier of Example 1 was compared with that of a sample with a through hole (hole diameter of 0.3 mm) drilled on the FPC substrate, and the catalyst concentration (Pd concentration of the catalyst) was changed. Except for the catalyst concentration, the measurement of each treatment step and the coverage ratio were the same as in Example 1. The results are shown in Table 2. IL ----------- Tt— 、 may ------- Φ, --- Γ (Please read the precautions on the back before filling this page) This paper size applies to Chinese national standards ( CNS) A4 specification (210X297 mm) _ 16-575627 A7 B7 V. Description of the invention (14) (Result) Table 2 P d concentration through-hole coverage rate (;%) (mg) Inventive product 1 Inventive product 2 Comparative product 1 10 70 5 0 5 20 95 90 20 30 100 100 40 50 100 100 70! 00__. 100 100 100 (Please read the precautions on the back before filling out this page) From the results in Table 2, we can see that the conventional degreasing adjustment Agent (comparative product 1), if it can be completely covered with copper in the pores, then it will catalyze! P d in 1 must be 100 mg / liter or more, while the products 1 and 2 of the present invention must be 300 mg / liter. The copper can be completely covered in the hole. Example 3 Printed on an rp C substrate (glass fiber epoxy resin; plate thickness 1.6 mm 'on both sides of copper foil 18 microns) printed on rp C substrate by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Openings were performed in the same way as in Example 1. _ € Plating 罙 罙 罙 * S ® Θ resin surface copper coverage. The degreasing adjustment ij series uses the product shown below 1 °, and the results are shown in Table 3. The degreasing adjustment agent composition for the test: (Invention product 3) This paper size applies the Chinese National Standard (CNS) A4 specification (210X297) Mm) -17 _ 575627 A7 B7 V. Description of the invention (15) Polymer of formula (II)

R Polymer (RC 1) of formula (VI), monoethanolamine triethanolamine secondary alcohol ethoxylate (comparative product 1) trimethylstearyl stearate monoethanolamine triethanolamine secondary alcohol ethoxylate (result) R 7 = methyl, &lt; = 2 0) 5 grams / liter methyl, R 9 = Η, Z = 2 0 0 0) 5 grams / liter 10 grams / liter 5 grams / liter 10 grams / liter 5 grams / Liter 0 gram / liter 5 gram / liter 5 gram / liter (please read the precautions on the back before filling out this page) Order-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy Table 3 Aperture (mm 0) Covered in the through hole Rate (%) Product of the invention 3 Comparative product 1 0.3 100 60 0.4 100 70 0.6 100 80 1.0 100 80 This paper size is applicable to Chinese National Standard (CNS) A4 specification (210 X 297 mm) -18- 575627 A7 B7 V. Explanation of the invention (16) As shown in the above results, using the degreasing modifier of the product 3 of the present invention, even if the P d concentration is only 1/3 of the standard 30 mg / liter, copper can be used in general RPC substrates. . 3 mm 0 small aperture through hole full coverage. In particular, at low palladium concentrations, the precipitation of copper on glass fibers that are usually difficult to coat indicates that the degreasing modifier of the present invention has extremely good performance. Example 4 Test for occurrence of rough pits: The conditions for obtaining the lowest pd concentration of 1000% in the test of Example 2 (Pd concentration in the product 1 of the present invention is 30 mg / liter, and in the comparative product 1 Pd concentration (1000 mg / liter) was adjusted. The following electroless copper electroplated substrates were subjected to copper sulfate electroplating under the following conditions. The obtained substrates were observed with a solid microscope to make a rough surface and pits. Compare. Table 4 shows the number of rough pits per square centimeter. In addition, rough surfaces and pits with a diameter of less than 10 microns are difficult to distinguish, and are expressed in terms of the number of combined rough surface pits. (Copper sulfate plating bath composition) Copper sulfate 7 5 g / litre sulfuric acid 18 0 g / / Litre chloride ion 60 mg / litre "Tongliang" T Μ I 5 mg / litre (manufactured by Ebara Ulite Technology Co., Ltd.) This paper size applies Chinese National Standard (CNS) A4 (210X 297 mm) ) (Please read the notes on the back before filling out this page) Order ·· ΦΤ. Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs-19- 575627 A7 B7 V. Description of the invention (17) (Copper sulfate plating conditions)

Current density plating time Stirring temperature (results) Table 4 3.0 amperes per square inch 50 minutes 2 5 ° C Rough surface of aeration, rough surface of pits, and number of pits (: / cm2 diameter (micron ) Inventive product 1 Comparative product 1_ 1〇 or less 1 5 1 1 to 3 0 1 2 _ 3 1 or more 〇〇_J (Please read the notes on the back before filling out this page) Order '· Staff of Intellectual Property Bureau, Ministry of Economic Affairs The consumer cooperative printed as shown in the above results, when using the product of the present invention with a pd concentration of 30 mg / L for the adjustment process, the final rough surface pits after copper sulfate plating were very few compared to the standard product. This can be made of copper foil. The tin and palladium adsorbed on the surface are evenly distributed, and large pieces are rarely explained. Example 5 A degreasing adjuster (product 4 of the present invention) was prepared according to the composition shown below. Because of the wettability and excellent permeability of the degreasing adjuster, it is particularly suitable for Multi-layer boards and other high aspect ratio substrates (substrates with small through-holes and high plate thickness). This paper size applies to China National Standard (CNS) M specifications (210X297 meals) -20- 575627 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention (18) (composition) Polymer of formula (III) (L2 = C16H32, PEG = polyethylene glycol with molecular weight of 40 0 0, p = 20) 5 g / liter polymer of formula (V) (Rs = 8, R9 = H, r = 50 0) 2 gram / liter 5 gram / liter 0 gram / liter 5 gram / liter Example 6 A degreasing adjustment agent (product 5 of the present invention) was produced according to the composition shown below. The degreasing adjustment agent was alkali It is highly suitable for direct electroplating because of its high adjustment effect. (Composition) The polymer of formula (I) (R = C18H37, ruler 1 to 115 = methyl, L 丄 = ethylene, η = 8, m = 8) 10 g / L polymer of formula (VI) (R8 = CH3, R9 = H, z = ◦ 1, ι · = 50000) 2 g / L monoethanolamine 10 g / L hydroxide Sodium 5g / L Monoethanolamine Nonyl Ethoxylate This paper is dimensioned to Chinese National Standard (CNS) A4 (210X297mm) -21-(Please read the precautions on the back before filling this page) 575627 A7 B7 V. Description of the invention (19) Nonyl ethoxylate 0 g / L Example 7 When using the degreasing modifier shown below, the comparison of the amount of palladium adsorption on the sample substrate. Processing steps In the same manner as in Example 1, the palladium adsorption amount was calculated by dissolving the catalyst adsorbed on the surface of the substrate after activation with aqua regia, and measuring the palladium concentration by atomic absorption spectrometry. The sample substrate was a slope fiber epoxy substrate (Panasonic, FR 4) Dissolve the copper foil with nitric acid to remove the exposed sample of the epoxy resin surface, and). The results are shown in Table 5. Polyimide (East Kapton adjuster composition) Product 6 of the present invention: Polymer of formula (I) (R group, L 1 diethylene, monoethanolamine triethanolamine (please read the precautions on the back before filling (This page) Printed this invention 7 by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs: 'R 1 to R 5 = A 8) 2 g / litre 10 g / litre 3 g / litre 5 g / litre Type (II) Polymer (Re = R 7 = methyl, &lt; = 2 0) 2 g / litre monoethanolamine 10 g / litre triethanolamine 3 g / litre 22- 575627 A7 B7 V. Description of the invention (20) Grade alcohol ethoxylate 5 g // liter Inventive product 8: polymer of formula (III) (L 2: = C 2 Η 1, ρ = ί] 0, average molecular weight of PEG 6 0 0) 2 g // 1 liter of monoethanolamine 10 gram // liter of triethanolamine 3 gram // liter of secondary alcohol ethoxide 5 gram // liter of comparative product 2: trimethylstearyl ammonium chloride 2 gram // liter of monoethanolamine 10 gram / / L Triethanolamine 3g // L Secondary Alcohol Ethoxide 5G / L (Please read the precautions on the back first (Write this page) Order · AWI. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Results) Table 5 Adsorption amount of degreasing modifier (mg / cm²) Polyimide film on the epoxy resin surface This product 6 0.19 0.24 Inventive product 7 0.19 0.23 Inventive product 8 0.18 0.17 Comparative product 2 0.16 0.12 The paper size is applicable to Chinese National Standard (CNS) A4 specification (210 X 297 mm) -23- 575627 A7 _B7 V. Description of the invention (21 ) Comparative product 2 is a composition generally used at present, compared with the products of the present invention, the 6 to 8 pins have a larger adsorption amount and better pin adsorption. In particular, the products 6 and 7 of the present invention have extremely excellent effects on polyimides which have been difficult to function as conventional degreasing regulators. Effect of the Invention The adjusting agent and the adjusting agent composition of the present invention have excellent adjusting effect, and the catalyst can be fully analyzed by using a catalyst with a pd concentration of about 1/3 in the past, and the subsequent plating has very few rough surfaces or pits, and the performance excellent. Therefore, it can replace the conventionally used adjusting agent, and it can perform high-performance and economical treatment before plating on various plastic materials or substrates. In particular, the polyimide resin (especially the laser perforated surface) or glass fiber-containing resin, which has a poor effect on conventional regulators, such as the regulator of the present invention, has excellent effects on the penetration of these substrates. Pd-S η catalyst can also be attached inside micropores such as pores and blind holes, which is a very useful modifier composition. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -24- This paper size applies to the Chinese National Standard (CNS) μ specification (210X297 mm)

Claims (1)

575627 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Public Λ8 B8 C8 D8 VI. Application for Patent Scope No. 901 0586 Patent Application No. 1 Chinese Application for Patent Scope Amendment February 21, 1992 Amendment 1. Composition of an adjusting agent It is characterized in that it contains the following ingredients (A) (A) formula (I), (II) or (III) in the bath at a concentration of 0.1 to 20 g / liter in use. (Where R represents a saturated or unsaturated alkyl group having 12 to 20 carbon atoms, R! To R5 each represents a lower alkyl group, L i represents a lower alkyl group, and η and m each represent 5 to 10 Number) Rs UN—CHrC—〇I II Rr 〇 (wherein R6 and R7 each show a lower alkyl group, &lt; shows a number from 1 ◦ to 1 〇 〇) ·. Peg-I-nhh ^ nh-peg) ^ (1 | 1) (In the formula, PEG shows a polymer having a molecular weight of 1,000 to 10,000. This paper size is applicable to China National Standards (CNS) A4 (21〇 × 29 * 7mm) (Please read the precautions on the back before filling out this page) • Installation · 1Γ 575627 A8 B8 C8. D8. · ', Patent application scope Glycol group, L 2 represents a saturated or unsaturated alkenyl group having 12 to 20 carbon atoms, P represents 10 to 100 number) one or two or more kinds of polymer compounds shown in the table As an active ingredient. 2. The modifier composition according to item 1 of the patent application scope, which further contains an alkanolamine and is used as a degreasing modifier. 3. The modifier composition according to item 1 of the scope of patent application, which further contains inorganic alkaline substances and / or non-ionic surfactants, and is used as a degreasing agent. 4 · A method for precipitating a palladium-rhenium colloidal catalyst on a non-conductive polymer material, which is characterized by: 'Using a non-conductive polymer material containing the following components: # (A) (A) Formula (I), (II) Or (III) _CHqiao · 0 OR / η • CHrC- N0—L—N—R4 CH3S0: · RS / (I) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (where R, R! To R 5 , L i, n and m are the same as above) 〇_ (II) This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) (#Read the notes on the back ^ before filling this page) -2- 575627 ABCD VI. Patent application scope (where, R6 and R7 each have the same meaning as above) PEG— (• —MH-L Plant NH-PEG ( ) (In the formula, PEG, L2 and p are the same as above.) One or two or more of the polymer compounds shown above are treated as an active ingredient regulator, and then immersed in a catalyst containing a palladium-tin colloid catalyst. 5. The method for precipitating a palladium-tin colloidal catalyst on a non-conductive polymer material according to item 4 of the scope of patent application, wherein the conversion concentration of the metal palladium of the catalyst's palladium-tin colloidal catalyst is 100 mg / ml to 30 mg / ml. 6. An adjusting agent composition, characterized in that it contains the component (A) and the component (B) at a concentration in the bath (M to 20 g / L or less), (A) the following formula (I), (II) ) Or (III) (Please read the notes on the back before filling out this page) • Equipment, -t — Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (In the formula, R, Ri to R5, Li, η and m are the same as above.) The paper size is applicable to the Chinese National Standard (CNS) Λ4 rule, and the grid (21 οχ297 mm) -3- 575627 A8 B8 C8 D8 Patent application scope I Rs -N —CH-C —ΟΙ ιι (where RR 7 and &lt; each are the same as above) (II) PEG- -NH-L plant NH-PEG, (III) (where PEG, L2 and p are each Same as above) One or two or more polymer compounds listed below (B) Formula (IV), (V) or (VI) (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Wisdom and Time Bureau of the Ministry of Economic Affairs (IV) (where R / shows hydrogen or lower alkyl, Y shows halogen ion, sulfate, nitrate or phosphate ion, and Q shows the number from 1 0 to 10, 0 0 0 (V) Paper Standards apply to China National Standards (CNS) Λ4 specifications (210X 297 mm) -4-575627 Λ8 B8 C8. D8, VI, patent application scope (where R8 and feet 9 show hydrogen or lower alkyl 1 0,0 〇〇 数） Show 100 to CH-C (VI) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (where Z represents halogen ions, sulfate, nitrate or phosphate ions, and Rs, Rg and r are the same as above). Is the active ingredient. 7. The modifier composition according to item 6 of the patent application, which further contains an alkanolamine and is used as a degreasing modifier. 8. The modifier composition according to item 6 of the patent application, which further contains an inorganic alkaline substance and / or a non-ionic surfactant, and is used as a degreasing modifier. 9 · A method for precipitating a non-conductive polymer material from a non-conductive polymer material, characterized in that: a non-conductive polymer material containing /, 3 U 卞 components (A) and (B (A) The following formula (I), (I Engineering · III (please read the precautions on the back before filling this page)-binding, f. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm)-5, 575627 ABCD 6. Scope of patent application C ο &quot; I c IC CH CH ο ο ο L 5 R to RR are the same as m and η η-0- in the formula (where R6, R7 and &lt; each are the same as above) PEG · -NH-L factory NH-PEG ^ -(In the formula, PEG, L2 and P are the same as above) One or two or more polymer compounds shown in the table, (B) the following formula (IV), (V) or (VI) (II) (III) (please first (Read the notes on the back and fill out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Where R /, Y, and Q are the same as above) The paper size applies to the Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) -6-575627 Λ8 B8 C8. D8 ·· Application for patent scope Re R9 CH- O NH '(V) (where, R F &gt; 8 CH-C νη2 · η (VI) (Please read the notes on the back before filling this page) Γ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (where Z, R8, R9 and r are the same as above) After one or two or more kinds of modifier composition having active ingredients are treated, they are immersed in a catalyst containing a palladium-tin colloid catalyst. 10. The method for precipitating a palladium-tin colloidal catalyst on a non-conductive polymer material according to item 9 of the scope of the patent application, wherein the conversion concentration of the metal palladium of the catalyst's palladium-tin colloidal catalyst is 100 mg / ml To 30 mg / ml. This paper size is applicable to Chinese National Standard (CNS) Λ4 (210X 297mm)