TW557493B - Cleaning machine with dual-nozzle inert-gas spurting tube - Google Patents
Cleaning machine with dual-nozzle inert-gas spurting tube Download PDFInfo
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557493 五、發明說明(1) 發明領域: 本發明係一種關於清洗晶圓之機台,特別是一種具有 雙噴口喷管以徹底移除位於晶圓上表面污染微粒之清洗機 台。 發明背景: 在超大型積體電路(ULSI)製程中,晶圓(wafer) 清洗的技術及潔淨度,是影響元件(device )品質及其可 靠度(reliability)最重要的因素之一,尤其是當製程 技術精進到深次微米0. 1 5 mm以下的領域,元件密度達數 千萬至十億個以上,且製造流程超過數百個步驟。因此在 製程中,通常需要非常潔淨的晶圓表面來製作如此精密複 雜的產品。有鑑於此’如何清洗晶圓以達到超潔淨度的需 求’是目前ULSI半導體廠製程中最重要也最嚴謹的步驟之 — 〇 晶圓清洗的目的,主要在於清除晶圓表面的污染物 (contamination),如微粒(particies)、有機化合物 (organic compunds)以及金屬離子(metal i〇ns)等。 舉例來說,當閘極氧化層的厚度已低於丨〇 〇埃以下,在其 製作過程中’便需要審慎考慮晶圓表面的微粗糙度 (micro-roUghness)與原始氧化層(native 〇xide)之 清除,以達到半導體元件對超薄閘極氧化層電性參數與特 性之需求,進而增進元件的品質及可靠性。 一般說來’晶圓在進入熱爐管(furnace)以進行擴557493 V. Description of the invention (1) Field of the invention: The present invention relates to a machine for cleaning wafers, particularly a cleaning machine with a double nozzle nozzle for completely removing contaminated particles on the surface of a wafer. Background of the Invention: In the ultra large integrated circuit (ULSI) process, wafer cleaning technology and cleanliness are one of the most important factors affecting the quality of the device and its reliability, especially When the process technology is advanced to the sub-micron area of 0.15 mm or less, the component density reaches tens of millions to one billion or more, and the manufacturing process exceeds hundreds of steps. Therefore, in the process, a very clean wafer surface is usually required to make such a sophisticated and complex product. In view of this, 'how to clean wafers to achieve the need for ultra-cleanliness' is one of the most important and rigorous steps in the current ULSI semiconductor factory process. 〇The purpose of wafer cleaning is mainly to remove contamination on the wafer surface. ), Such as particles (particies), organic compounds (organic compunds), and metal ions (metal ion). For example, when the thickness of the gate oxide layer is less than 丨 00 angstroms, in the fabrication process, it is necessary to carefully consider the micro-roUghness of the wafer surface and the native oxide layer (native 〇xide ) In order to meet the semiconductor device's requirements for the electrical parameters and characteristics of the ultra-thin gate oxide layer, thereby improving the quality and reliability of the device. Generally speaking, a wafer is entering a furnace for expansion.
第4頁 557493Page 4 557493
散或氧化_ &二 w 均需經過化學二沈積前或蝕刻程序後’此晶圓 除污染物,:=ti與高純度去離子水的洗條,以去 說,唯有使曰圓的矣曰曰圓進行除濕乾化程序。也就是 半導體電子L牛:ί:ί到非常高的潔淨⑨,製作出來的 付/所需之電器特性(eleCtriCal 染物的主要來、、Λ / 要是清除污染物,而這些污 以及容哭ίΐ:境、機台設備”卜氣體、化學物品 第-圖列舉了各種污染源對電 ’此圖揭露了 的機台1 0。當 被位於其中的 轉的同時,由 酸管(m e d i u m 動運動外,亦 液,以利用此 入等程序後沾 圓旋轉運動的 甩至晶圓外。 請接著參閱第二圖 (photo resist)雜質 台1 〇中的清洗槽1 2,而 顯示於圖中)抓取並旋 延伸至清洗槽1 2上方之 圖中箭頭所示之圓周擺 名稱為S T - 2 5 0之酸性溶 移除微影钱刻或離子植 阻碎屑,並同時藉著晶 雜質之ST-2 5 0酸性溶液 一種可移除光阻 晶圓被傳送至位於機 抓夾(chuck)(未 分配槽1 3側壁開口 1 5 arm ) 16除了會做如 會從管徑中噴出型號 溶液中之化學成分, 附於晶圓上表面之光 離心力將摻雜了光阻 、隨後,對此晶圓施以高純度去離子水(de —i〇n water )清洗程序。其方法同上所述,係利用去離子水管丨8喷出 之高純度去離子水,以進一步清洗正在旋轉之晶圓,並移 除前述酸洗步驟後所剩餘之ST-25 0溶液。 當完成此兩個步驟後,利用氮管2 〇中所喷出之氮氣吹Scattered or oxidized _ & two w need to go through the chemical two deposition or after the etching process' this wafer to remove contaminants: = ti and high-purity deionized water washing strips, to say, only make the round Afterwards, a dehumidification and drying process is performed. That is, semiconductor electronics L cattle: ί: ί to very high cleanliness, the electrical characteristics of the produced / required (the main source of eleCtriCal dyes, Λ / if the pollutants are removed, and these pollutants and Rong cry ΐ: Environment, machine equipment ", gas, chemicals, the first picture-a variety of pollution sources to electricity" This picture reveals the machine 10. When it is located in the turn, by the acid tube (medium motion outside the movement, also The liquid is transferred to the outside of the wafer by the circular motion after using this loading procedure. Please refer to the cleaning tank 12 in the photo resist impurity stage 10 (shown in the figure) and grab it. The circular pendulum that extends to the top of the cleaning tank 1 and 2 indicated by the arrow in the figure above is named ST-2 50. The acidic solution is removed to remove lithographic engraved or ion-implanted debris. 5 0 acid solution A removable photoresist wafer is transferred to the chuck (undistributed groove 1 3 side wall opening 1 5 arm) 16 except that it will do the chemical in the model solution if it will be sprayed from the pipe diameter Composition, the optical centrifugal force attached to the upper surface of the wafer will be doped After the photoresist is applied, the wafer is subjected to a high-purity deionized water (de-ion water) cleaning procedure. The method is the same as described above, and the high-purity deionized water sprayed from the deionized water pipe 8 is used. To further clean the rotating wafer, and remove the ST-25 0 solution remaining after the foregoing pickling step. After completing these two steps, use the nitrogen blown from the nitrogen tube 20 to blow.
第5頁 557493 五、發明說明(3) 乾晶圓’並將位於晶圓線路圖案開口甲之污染微粒吹出 來。然而值得注意的是,此氮管2 〇並非是作如前所述之圓 周擺動運動’而是先移動至晶圓之中心區域,然後才從管 径中噴出氮氣,並同時往晶圓的外圍移動。這樣的運作機 制加上晶圓本身的旋轉運動,除了可旋乾前述步驟之液體 並吹乾晶圓外,亦可將殘留於線路圖案(pattern )開口 中之光阻碎屑吹至晶圓上表面,繼而吹掃至晶圓外。 口請參閱第三圖,由於氮管20中噴出的氮氣是由晶圓14 圓心往晶圓14外圍(亦即由圖中氮管2〇的左側往右側)移 動(如斜線箭頭所示),因此可將位於氮管2〇右側的光阻 碎屑有效移除。然而,這樣的結果卻導致位於晶圓丨4左側 j光阻碎屑仍然殘留在晶圓14上表面,因此如何有效移除 這些殘留的光阻碎屑,以大幅提高製程良率,便成了半 體工業界重要的課題之一。 發明目的及概述: 於提供一種促進位於晶圓上表面 本發明之主要目的在 污染微粒移除之清洗機台 管, 鈍氣嗜 。此機台包括了清洗 以及具有雙喷口之第 ^發明提供一種清洗晶圓之機台 槽、分配槽、第一噴管、第二噴管、Page 5 557493 V. Description of the invention (3) Dry wafer 'blows out the contaminated particles located on the opening of the wafer circuit pattern. However, it is worth noting that the nitrogen tube 20 does not perform a circular oscillating motion as described above, but first moves to the center area of the wafer, and then ejects nitrogen from the diameter of the tube, and simultaneously goes to the periphery of the wafer. mobile. Such an operation mechanism coupled with the rotation motion of the wafer itself can not only spin-dry the liquid in the previous steps and blow dry the wafer, but also blow the photoresist debris remaining in the opening of the circuit pattern onto the wafer. The surface is then purged out of the wafer. Please refer to the third figure, because the nitrogen sprayed from the nitrogen tube 20 is moved from the center of the wafer 14 to the periphery of the wafer 14 (that is, from the left to the right of the nitrogen tube 20 in the figure) (as shown by the diagonal arrow), Therefore, the photoresist debris on the right side of the nitrogen tube 20 can be effectively removed. However, such a result causes the photoresist debris on the left side of the wafer 4 to remain on the upper surface of the wafer 14. Therefore, how to effectively remove these residual photoresist debris to greatly improve the process yield, it becomes One of the important topics in the half-body industry. SUMMARY OF THE INVENTION The present invention aims to provide a cleaning machine tube which can be located on the upper surface of a wafer. This machine includes cleaning and the second invention with a double nozzle. A machine for cleaning wafers is provided. A groove, a distribution groove, a first nozzle, a second nozzle,
第6頁 557493 五、發明說明(4) 三喷管。其 由此開口向 係用以使晶 溶液,以移 particles 〕 以清洗晶圓 液。第三噴 鈍氣吹乾該 氣,而將位 上表面,而 氣,以尾隨 吹掃至該晶 中,在 分配槽 圓進行 除位於 。第-表面, 管,係 晶圓。 於晶圓 大管徑 小管徑 圓外。 分配槽 外延伸 清洗程 晶圓表 噴管; 並移除 具有小 其中, 線路圖 噴口係 噴口, 之側壁上具有開口,以使喷管經 ’而位於清洗槽上方。清洗槽, 序,而第一喷管係用以喷出酸性 面之聚合物微粒(ρ 〇 1 y m e r 係用以喷出高純度去離子水, 半導體製程中所殘留之化學溶 管徑喷口與大管徑噴口,以噴出 小管徑喷口係用以喷出集中鈍 案開口中之污染微粒吹出至晶圓 用以在晶圓上表面噴出擴散鈍 而將位於晶圓上表面之污;:粒 發明詳 本 中之雙 除,並 述。 請 件,包 以及具 中,分 之側壁 三喷管 細說明: 發明提供-種清洗晶圓之機台,藉由 喷口鈍,噴管,以促進晶圓上表面污 進而提高製程良率。有關本發明之詳 參閱第四圖’此圖顯示了清洗機台40 括清洗槽50、分配槽52、第一喷 有小管徑噴口 58與大管徑噴口 60之第 配槽52係與清洗槽50之側壁相連接, 上具有開口62 ’以使第—喷州 可經由此開口 62由分配槽52向外延伸 位於清洗機台 染微粒之移 細說明如下所 的各個組成元 、第二喷管56 三喷管。其 且在分配槽5 2 二喷管5 6與第 至清洗槽5 0上Page 6 557493 V. Description of the invention (4) Three nozzles. This opening is used to make the crystal solution to remove particles] to clean the wafer liquid. The third spray blunt gas blows the gas dry, and the upper surface of the gas is blown into the crystal in a trailing manner, and is removed in the circle of the distribution groove. First-surface, tube, wafer. Outside the wafer, the large diameter and the small diameter. The distribution tank is extended outside, cleaning process, wafer table, and the nozzle is removed. There is a small one, the circuit diagram, the nozzle is a nozzle, and the side wall has an opening so that the nozzle is located above the cleaning tank via ′. Cleaning tank, sequence, and the first nozzle is used to spray polymer particles on the acid surface (ρ 〇 1 ymer is used to spray high-purity deionized water, the remaining diameter of the chemical solution tube in the semiconductor process nozzle and large The nozzle with a small diameter is used to eject the contaminated particles in the opening of the concentrated blunt case to the wafer to spray the diffused blunt on the upper surface of the wafer to contaminate the dirt on the upper surface of the wafer; Detailed description of the double elimination in this book, please describe. Please explain the details of the three nozzles in the side wall of the package, package, and tool: The invention provides a machine for cleaning wafers, with blunt nozzles and nozzles to promote wafers. The upper surface is stained to improve the process yield. For details of the present invention, refer to the fourth figure. This figure shows the cleaning machine 40 including the cleaning tank 50, the distribution tank 52, and the first nozzle with a small-diameter nozzle 58 and a large-diameter nozzle. The 60th distribution tank 52 is connected to the side wall of the cleaning tank 50, and has an opening 62 'so that the first spray state can extend outward from the distribution tank 52 through the opening 62. The movement of the dye particles on the cleaning machine is described in detail below. Each component, second nozzle 56 Three nozzles, and on the distribution tank 5 2 two nozzles 5 6 and the first to the cleaning tank 50 0
第7頁 557493 五、發明說明(5) 方。 第一喷管5 4 ’係用以喷出型说名稱為S T - 2 5 0之酸性溶 液’以利用此溶液中所含之化學成分移除位於晶圓表面之 聚合物微粒。當晶圓被傳送至機台4 〇中的清洗槽5 〇内,而 被位於其中的抓夾(c h u c k )(未顯示於圖中)抓取後, 此晶圓會進行旋轉。在此同時,位於清洗槽上方之第一喷 管54會做如圖中箭頭所示之圓周擺動運動(亦即第一喷管 54之喷口會在晶圓的中心與邊緣反覆來回擺動),並利用 由喷口中喷出ST-2 5 0酸性溶液,以利用其所含之化學成 分’移除在半導體製程中沾附於晶圓表面上之聚合物微 粒。之後’再藉由晶圓旋轉運動的離心力,將夾雜了聚合 物微粒之S T _ 2 5 0酸性溶液甩至晶圓外。 接著仍請參照第四圖。圖中所示之第二喷管係用以喷 出高純度去離子水,以稀釋掉殘留於晶圓上之ST_25〇酸性 溶液,並進一步清洗晶圓表面與移除半導體製程中所產生 之污染物。其方法同上所述,係利用去離子水管丨8在晶圓 的中心與邊緣反覆來回擺動,與其所喷出之高純度去離子 水,對旋轉的晶圓進行清洗,之後再藉由晶圓旋轉運動的 離心力將前述S T - 2 5 0酸性溶液清洗步驟後所殘餘之ς τ - 2 5 0 浴液以及此程序所使用之高純度去離子水甩至晶圓外。 第三喷管’係用以喷出鈍氣以吹乾晶圓。其中,此第 三喷管具有雙喷口,分別為小管徑噴口 5 8與大管徑喷口 60,且喷出之鈍氣為氮氣。小管徑嘴口 58,係用以喷出集 中(f 〇 c u s e d )鈍氣,以將位於晶圓上表面線路圖案開口Page 7 557493 V. Description of Invention (5) Fang. The first nozzle 5 4 ′ is used to eject an acidic solution of the type called S T-2 50 to remove polymer particles located on the surface of the wafer by using chemical components contained in the solution. When the wafer is transferred to the cleaning tank 50 in the machine table 40 and picked up by a gripper (c h u c k) (not shown in the figure) located therein, the wafer is rotated. At the same time, the first nozzle 54 above the cleaning tank will perform a circular swing motion as shown by the arrow in the figure (that is, the nozzle of the first nozzle 54 will swing back and forth between the center and the edge of the wafer), and The ST-2 50 acidic solution is sprayed from the nozzle to remove the polymer particles attached to the surface of the wafer during the semiconductor process by using the chemical components contained therein. After that, the S T _ 2 50 acidic solution containing polymer particles is thrown out of the wafer by the centrifugal force of the wafer rotating motion. Then still refer to the fourth figure. The second nozzle shown in the figure is used to spray high-purity deionized water to dilute the ST-25 acid solution remaining on the wafer, and further clean the wafer surface and remove the pollution generated in the semiconductor process. Thing. The method is the same as described above. It uses a deionized water pipe to swing back and forth between the center and the edge of the wafer, and cleans the rotating wafer with the high-purity deionized water sprayed from it, and then rotates the wafer. The centrifugal force of the motion throws the residual τ-2 50 bath solution and the high-purity deionized water used in this procedure to the outside of the wafer. The third nozzle 'is used to blow out the inert gas to dry the wafer. Among them, the third nozzle has dual nozzles, which are a small-diameter nozzle 5 8 and a large-diameter nozzle 60, and the inert gas emitted is nitrogen. The small-diameter mouthpiece 58 is used to spray a concentrated (f oc c s e d) blunt gas to open the circuit pattern on the upper surface of the wafer.
557493 五、發明說明(6) 中之污染微粒,吹出至晶圓上表面。然而值得注意的是, 此第三喷管並非是作如前所述之圓周擺動運動,而是先將 其喷口移至旋轉晶圓的中心區域,接著同時喷出鈍氣並往 晶圓邊緣移動,而將位於晶圓上表面線路圖案開口中之污 染微粒吹出至晶圓上表面,再進而將之吹掃至晶圓外。易 言之,此程序除了可藉由晶圓本身的旋轉運動,將前述步 驟所使用之液體甩至晶圓外,亦可藉著鈍氣吹乾晶圓,並 將殘留於晶圓上表面或是圖案中之污染微粒吹至晶圓上表 面,再進而吹掃至晶圓外。 大管徑喷口 6 0,係用以在晶圓上表面喷出擴散 (spread )鈍氣,以尾隨小管徑喷口 58喷出之集中鈍氣, 而將殘留於晶圓上表面之污染微粒吹掃至晶圓外。其中, 前述之小管徑與大管徑係為平行並列並互相貫通,且大管 徑喷口 6 0在晶圓上表面喷出之鈍氣範圍,大於小管徑喷口 5 8所喷出之鈍氣範圍。在一較佳實施例中,此小管徑喷口 58之口徑為1〜2公釐,而大管徑喷口 60之口徑為4〜5公 釐,且此小管徑與大管徑係以焊接方式並列連接在一起。 值得注意的是,由於大管徑噴口 6 0係與小管徑喷口 5 8並 列,因此其運作方式與小管徑喷口 5 8相同,亦即會先隨著 小管徑噴口 5 8移至旋轉晶圓的中心區域,接著再對此晶圓 喷出擴散鈍氣,以更徹底清除殘留於晶圓上表面之污染微 粒。也就是說,大管徑喷口 6 0喷出之擴散鈍氣可如第五圖 所示,尾隨在小管徑喷口 5 8喷出之集中鈍氣後面,將仍然 殘留於晶圓6 4上表面之污染微粒更有效的移除至晶圓外。557493 V. Contamination particles in the description of the invention (6) are blown out to the upper surface of the wafer. However, it is worth noting that this third nozzle does not perform a circular swing motion as described above, but first moves its nozzle to the center area of the rotating wafer, and then simultaneously sprays blunt gas and moves toward the edge of the wafer. And blow out the contaminated particles in the circuit pattern opening on the upper surface of the wafer to the upper surface of the wafer, and then blow it out of the wafer. In other words, in addition to rotating the wafer itself, this procedure can throw the liquid used in the previous steps to the wafer. It can also dry the wafer with blunt gas and leave it on the top surface of the wafer or The contamination particles in the pattern are blown to the upper surface of the wafer, and then blown out of the wafer. The large-diameter nozzle 60 is used to spray spread blunt gas on the upper surface of the wafer, and to concentrate the blunt gas sprayed from the small-diameter nozzle 58 to blow the contaminated particles remaining on the upper surface of the wafer. Scan out of the wafer. Among them, the aforementioned small-diameter and large-diameter systems are parallel and parallel to each other, and the range of the blunt gas ejected from the large-diameter nozzle 60 on the upper surface of the wafer is greater than the bluntness ejected by the small-diameter nozzle 58.气 范围。 Gas range. In a preferred embodiment, the diameter of the small-diameter nozzle 58 is 1 to 2 mm, and the diameter of the large-diameter nozzle 60 is 4 to 5 mm, and the small-diameter and large-diameter are welded together. Ways are connected side by side. It is worth noting that, because the large-diameter nozzle 60 is juxtaposed with the small-diameter nozzle 5 8, its operation mode is the same as the small-diameter nozzle 5 8, that is, it will first move to rotate with the small-diameter nozzle 58. The central area of the wafer is then sprayed with a diffusion inert gas on the wafer to more completely remove the contaminated particles remaining on the upper surface of the wafer. In other words, as shown in the fifth figure, the diffuse inert gas discharged from the large-diameter nozzle 60 can follow the concentrated inert gas discharged from the small-diameter nozzle 5 8 and will still remain on the upper surface of the wafer 64. The contaminated particles are more effectively removed from the wafer.
第9頁 557493 五、發明說明(7) 使用本發明之方法,除了可將ST-2 5 0酸性溶液有效移 除外,並由於晶圓上表面之污染微粒被徹底移除,因此可 大幅增進半導體製程良率,以提高產能。 本發明雖以一較佳實例闡明如上,然其並非用以限定 本發明精神與發明實體,僅止於此一實施例爾。是以,在 不脫離本發明之精神與範圍内所作之修改,均應包含在下 述之申請專利範圍内。Page 9 557493 V. Description of the invention (7) In addition to the effective removal of ST-2 50 acidic solution, the method of the present invention can be greatly improved because the contaminated particles on the upper surface of the wafer are completely removed. Yield of semiconductor process to increase production capacity. Although the present invention is explained as above with a preferred example, it is not intended to limit the spirit and the inventive substance of the present invention, but only to this embodiment. Therefore, all modifications made without departing from the spirit and scope of the present invention should be included in the scope of patent application described below.
第10頁 557493 圖式簡單說明 藉由以下詳細之描述結合所附圖示,將可輕易的了解上述 内容及此項發明之諸多優點,其中: 第一圖揭露各種污染源對電子元件之影響; 第二圖為習知技術之清洗機台示意圖,顯示機台内各 組成元件間之連結關係; 第三圖為習知技術之氮管示意圖,顯示氮管由晶圓中 心往邊緣移動之情形; 第四圖為本發明之清洗機台示意圖,顯示機台内各組 成元件間之連結關係;以及 第五圖為本發明之鈍氣喷管示意圖,顯示鈍氣喷管由 晶圓中心往邊緣移動之情形。 圖號對照表: 清洗槽1 2 晶圓1 4 酸管1 6 氮管20 清洗槽50 第一喷管54 小管徑噴口 5 8 開口 62 移除光阻雜質機台1 0 分配槽1 3 開口 1 5 去離子水管1 8 清洗機台4 0 分配槽5 2 第二喷管56 大管徑喷口 6 0 晶圓6 4Page 557493 Brief description of the diagrams The above description and the many advantages of this invention can be easily understood through the following detailed description combined with the attached drawings, where: The first diagram reveals the effects of various pollution sources on electronic components; The second picture is a schematic diagram of the cleaning machine of the conventional technology, showing the connection relationship between the various components in the machine; the third picture is the schematic diagram of the nitrogen tube of the conventional technology, showing the nitrogen tube moving from the center of the wafer to the edge; The fourth figure is a schematic diagram of the cleaning machine of the present invention, showing the connection relationship between the various components in the machine; and the fifth figure is a schematic diagram of the blunt gas nozzle of the present invention, showing situation. Drawing number comparison table: Cleaning tank 1 2 Wafer 1 4 Acid tube 1 6 Nitrogen tube 20 Cleaning tank 50 First nozzle 54 Small-diameter nozzle 5 8 Opening 62 Removing photoresist impurity machine 1 0 Distribution tank 1 3 Opening 1 5 Deionized water pipe 1 8 Cleaning machine 4 0 Distribution tank 5 2 Second nozzle 56 Large diameter nozzle 6 0 Wafer 6 4
第11頁Page 11
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TW91118197A TW557493B (en) | 2002-08-13 | 2002-08-13 | Cleaning machine with dual-nozzle inert-gas spurting tube |
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TW91118197A TW557493B (en) | 2002-08-13 | 2002-08-13 | Cleaning machine with dual-nozzle inert-gas spurting tube |
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