TW546438B - A self-cleaning screen and production method thereof - Google Patents

A self-cleaning screen and production method thereof Download PDF

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Publication number
TW546438B
TW546438B TW91135768A TW91135768A TW546438B TW 546438 B TW546438 B TW 546438B TW 91135768 A TW91135768 A TW 91135768A TW 91135768 A TW91135768 A TW 91135768A TW 546438 B TW546438 B TW 546438B
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Taiwan
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titanium dioxide
self
gauze
cleaning
scope
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TW91135768A
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Chinese (zh)
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TW200409853A (en
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Kuo-Chung Chou
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Chen Chang Plastics Co Ltd
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Priority to US10/728,380 priority patent/US20040224147A1/en
Publication of TW200409853A publication Critical patent/TW200409853A/en

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Abstract

This invention provides a self-cleaning screen composed by a net base material, which contains photo catalysis active photocatalysis (TiO2) or is applied over a layer of photo catalysis active photocatalysis (TiO2), as well as a production method thereof.

Description

546438 月 修正 曰 案號911357防 五、發明說明(2) 首ί發述之具有自潔能力之紗網的製造方法。 網狀基材= ι織成-網狀基材。然後,將該 :::塗或是含浸的方式塗佈一層具有光催:性 層基材h此外,亦可直接將具有光ί化 到網中驟所使用的樹脂中或是添加 或是製造網狀基㈣::;佈二氧化鈦的步驟合併到定型 之:於化活性的二氧化鈦被特定波長的光線激發 =直會產生催化作用,將其周圍之氧氣以及水分子激發 = ·0Η及·〇2_自由基,這些氧化力極強的自由 :己1立”分解許多有機物質以及部分無機物質。本發明提 表面具有—具有光催化活性的二氧化鈦或是二 :八解U丨ΐ Τ此可將附著☆紗網上之灰塵或是雜質加 以分解,達到清潔之目的。 【實施方式】 :m:只施例所提供之紗網係包含一網狀基材以 ^ φ ^化活性的二氧化鈦塗層覆蓋於該網狀基材 ί化化活性的二氧化•(-種藉由光進行 e Λ 〜”;丨物貝)塗層能進行光催化反應。「光催化 反應」由字面上可瞼銥甘从_ 作用,進一牛接觸M ,、係利用光提供能量來進行的催化 v 某周圍之氧氣或水分子轉換成極具活性546438 Month Amendment Case No. 911357 Prevention V. Description of the Invention (2) The first method of manufacturing a gauze with self-cleaning ability, which was described first. Reticulated substrate = woven into-reticulated substrate. Then, apply the ::: coating or impregnation method to a layer with a photocatalyst: base material h. In addition, the photoresist can be directly added to the resin used in the net or added or manufactured. Reticulated substrate ::; The step of fabricating titanium dioxide is incorporated into the setting: the chemically active titanium dioxide is excited by light of a specific wavelength = it will have a catalytic effect, and the oxygen and water molecules around it will be excited = · 0Η and · 〇2 _Free radicals, these oxidizing powers are free: they have many organic substances and some inorganic substances. The surface of the present invention has-titanium dioxide with photocatalytic activity or two: eight solutions U 丨 ΐ Adhesion ☆ The dust or impurities on the gauze net are decomposed to achieve the purpose of cleaning. [Embodiment]: m: The gauze net provided in the example only includes a net-like substrate with a ^ φ ^ titanium dioxide coating active The oxidized dioxide covering the net-shaped substrate ((a kind of e Λ ~ "by light; coating) can perform photocatalytic reaction. The "photocatalytic reaction" is literally catalyzed by the action of iridium and glycan, and it is catalyzed by the use of light to provide energy. V The surrounding oxygen or water molecules are converted into highly active

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的·0Η及· Of等自由配位基(free radicals),藉由這 些自由基分解對人體或環境有害或是造成污染的的3有機物 質和無機物質。 一般而言,太陽光在3〇〇〜80Οηπι波長範圍間的能量較強 且較不易受到地球溫室效應及大氣層污染影響,因此可利 用太陽光所提供之光化學能作為激發光觸媒的來源。 要成為光觸媒材料的條件,首先是此化合物需具有半導 體的特性且其價電帶(vaIence band)和導電帶 (conductive band)的能量距(bandgap)要適當。藉 此,在光的照射下,其電子可被激發由價電帶躍遷至導電 帶,所產生的電位能足以提供水的電解產生&和%。就本 發明使用之二氧化鈦而言,激發二氧化鈦所需的能量距為 3· 2eV,相對所需光能量的波長相當於38〇nm。而本發明使 用二氧化鈦為光觸媒材料的原因在於二氧化鈦具有強大的 氧化還原能力、高化學穩定度及無毒的特性。 ^ 當波長小於400 nm之紫外光照射在二氧化鈦時,二氧化| 鈦在價電帶的電子被紫外線的能量激發而跳升至導電帶, 同時在價電帶產生帶正電之電洞,而形成一組電子電$對 (electron-hole pair),其反應時間僅數微秒(“μ。 )。在二乳化鈦表面進行光催化反應可分為下列幾個步 驟: 夕 1 ·反應物、氧氣及水分子吸附於二氧化鈦表面; 2 ·經紫外線光照射後’二氧化鈦產生電子及電洞; 3 ·電子和電洞被捕捉而分別存在二氧化鈦表面;Free radicals such as · 0Η and · Of, which decompose 3 organic and inorganic substances that are harmful to the human body or the environment or cause pollution. Generally speaking, sunlight has a strong energy in the wavelength range of 300-80nm, and is less susceptible to the effects of the global warming and atmospheric pollution. Therefore, the photochemical energy provided by sunlight can be used as a source of exciting photocatalyst. To become a photocatalyst material, the compound must first have the characteristics of a semiconductor and its energy band (vaIence band and conductive band) must be appropriate. Thus, under the irradiation of light, its electrons can be excited to transition from the valence band to the conductive band, and the generated potential is sufficient to provide the electrolytic production of water & and%. For the titanium dioxide used in the present invention, the energy distance required to excite the titanium dioxide is 3.2 eV, and the wavelength corresponding to the required light energy is equivalent to 38nm. The reason for using titanium dioxide as a photocatalyst material in the present invention is that titanium dioxide has strong redox capacity, high chemical stability, and non-toxic properties. ^ When ultraviolet light with a wavelength less than 400 nm is irradiated on titanium dioxide, the electrons of titanium dioxide in the valence band are excited by the energy of ultraviolet rays and jump to the conductive band. At the same time, positively charged holes are generated in the valence band, and A group of electron-hole pairs is formed, and the reaction time is only a few microseconds ("μ."). The photocatalytic reaction on the surface of di-emulsified titanium can be divided into the following steps: Oxygen and water molecules are adsorbed on the surface of titanium dioxide; 2 · Titanium dioxide generates electrons and holes after being irradiated with ultraviolet light; 3 · Electrons and holes are captured and exist on the titanium dioxide surface, respectively;

五、發明說明(4) ::及水分子形成氫氧自由基; 6.產基與反應物進行氧化反應; 根據本發明之一/Λ鈦表面脫離。 加有具有光催化活性m:紗網之網狀基材本身便添 (A::t)v晶所之使二用,化二氧化鈦’其較佳地包含^ (Rut i le)的混合纟Γ/1(並欽曰顆^或銳鈦礦與金紅石 石分子數比為80 之比例較佳地為銳欽礦:金紅 較佳係為奈米尺寸7超顆粒 ,加,以提高電子-電= 催化反應的效率大幅提高。 從尤 聚基材係由金屬材料、陶兗材料或是 烯對苯二酸醋(m)二咖)、聚丙稀(PP)或是聚f 2明亦提供一種製造前述紗網的方法n,將線狀 金屬或疋聚合物織成一網狀基材,或是利用陶瓷材 -網狀基材。若是經過紡織步驟所得到的網狀基材,$要 利用一樹脂含浸過後加以定型。然後,再將含有適當二 化鈦的塗料以刷塗、喷塗或是含浸的方式塗佈在該網:基 材上另外,亦可直接將二氧化鈦添加入用以定型網狀基 ::樹脂巾’直接將塗佈二氧化欽塗層步驟合併於定型步 546438 五、發明說明(5) 本發明另提供一種 加二氧 由於 被二氧 氧化鈦 以該緩 面形成 氧化鈦 免二氧 分子包 本發 簾、摺 層具有 無機物 在空氣 f的細 雖然 發明, 0 ’當 才見後附 化鈦, 一般紗 化鈦分 塗層時 衝介面 微胞(Π! 塗層中 化鈦直 含至少 明所提 疊式紗 光催化 ’因此 通過紗 菌,因 本發明 任何熟 可作各 之申請 方法, 狀基材 狀基材 此根據 使得網 網的網 解,因 ’於^一氧化欽 分子的一端與 i ce 11 ) 之其他 接與該 一個矽 供之紗 簾或是 活性, 不但具 網時能 此具有 已以前 習此技 種之更 專利範 ’並且 組成物 網狀基 原子用 網適用 汽車紗 能分解 有自我 分解空 自潔、 述實施 藝者, 動與修 圍所界 在製造 本身便 多為有 本發明 塗料中 二氧化 以該缓 或是該 材接觸 以與二 於紗窗 簾等設 其表面 清除灰 氣中的 除臭含 例揭示 在不脫 改,因 定者為 網狀基材的材料時 具有二氧化鈦。 機聚合物材質,矸 之實施例,可在形 緩衝介面分 ,添 能會 添加一 鈦鍵結 衝介面 網狀基 。較佳 氧化鈦 、紗門 備上, 大部分 塵或雜 臭氣或 殺菌等 ’然其 離本發 此本發 準。 成; 子, 於二氧化鈦表 與二 此避 介面 分子另一 材結合’精 地,該緩衝 鍵結。 或是捲軸式 由於其表面 有機物以及 質的功能, 是破壞空氣 功能。 並非用以限 明之精神和 明之保護範 紗 之塗 部分 還能 中 翁 定本 範圍 圍當V. Description of the invention (4) :: and water molecules to form hydroxide radicals; 6. Oxidation reaction between the product group and the reactant; according to one of the invention / Λ titanium surface is detached. Adding a photocatalytically active m: gauze mesh substrate itself adds (A :: t) v crystals for dual use, titanium dioxide 'which preferably contains a mixture of ^ (Rut i le) 纟 Γ / 1 (Bing Qin said that the ratio of anatase to rutile stone is 80 is preferably a sharp ore: Rutile is preferably a nano-size 7 superparticles, plus to increase the electron- Electricity = The efficiency of the catalytic reaction has been greatly improved. Also available from special polymer substrates are metal materials, pottery materials, or terephthalic acid (m) dica), polypropylene (PP) or polyf 2 A method n for manufacturing the aforementioned gauze, weaving a linear metal or a rhenium polymer into a mesh substrate, or using a ceramic material-a mesh substrate. If the net-like substrate is obtained after the spinning step, it should be shaped by impregnation with a resin. Then, a coating containing appropriate titanium dioxide is applied to the web by brushing, spraying or impregnation: the substrate can also be directly added with titanium dioxide to shape the mesh base :: resin towel 'The step of directly coating the dioxin coating is combined with the setting step 546438. 5. Description of the invention (5) The present invention also provides a titanium dioxide-free dioxin-free molecular encapsulation due to the addition of dioxygen by the titanium dioxide to the retarded surface. The hair curtain and the folding layer have the fineness of inorganic matter in the air f. Although it was invented, when the titanium is attached, the interface cells are usually punched when the titanium is sub-coated (Π! The titanium in the coating contains at least The photocatalysis of stack-type yarns is therefore passed through the yarn fungus. As any method of the present invention can be applied for each application method, the substrate-like substrate is based on the network solution, because the end of the molecule ice 11) The other screen or activity that is connected to the silicon supply is not only when it has a net, it also has a more patented model that has been used in this technology, and the composition is based on a net-based atomic net suitable for automotive yarn energy. break down There are self-decomposing, self-cleaning, performing artists, and the boundary between the action and repair is mostly in the manufacture of the coating in accordance with the present invention, the oxide should be slow, or the material should be in contact with the surface of the curtain, etc. Examples of deodorization in the gas show that titanium dioxide is used when the material is a net-like substrate without being modified. The organic polymer material, an example of 矸, can be divided in the shape of the buffer interface. Adding a titanium bonding interface can be added to the mesh base. It is better to prepare titanium oxide and screen door, and most of the dust or stink odor or sterilization, etc., then it is accurate. It is bonded to the titanium dioxide surface and the two molecules to avoid the interface molecules, and the buffer bonds. Or the scroll type destroys the air function due to its surface organic matter and quality function. It is not used to limit the spirit of the Ming and the protection of the painting. The painted part can still be included in the scope.

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Claims (1)

546438 六、申請專利範圍 1、 一種具有自潔能力之紗網,其包含: 一網狀基材;以及一具有光催化活性的二氧化鈦(Ti〇2) 塗層設於該網狀基材上。 2、 依申凊專利範圍第1項之具有自潔能力之紗網,其中該 具有光催化性質的二氧化鈦塗層包含銳鈦礦(Anatase)結 晶或銳鈦礦與金紅石(Ru t i i e)的混合結晶之二氧化鈦顆 粒。 3、 "依申請專利範圍第2項之具有自潔能力之紗網,其中該 一氧化鈦顆粒係為銳鈦礦:金紅石分子數比為8 〇 : 2 〇之混合 結晶。 口546438 6. Scope of patent application 1. A gauze with self-cleaning ability, comprising: a mesh substrate; and a photocatalytically active titanium dioxide (Ti〇2) coating provided on the mesh substrate. 2. The gauze with self-cleaning ability according to item 1 of the patent scope, wherein the titanium dioxide coating with photocatalytic properties contains anatase crystals or a mixture of anatase and rutile Crystalline titanium dioxide particles. 3. The self-cleaning gauze according to item 2 of the scope of patent application, wherein the titanium oxide particles are a mixed crystal of anatase: rutile molecular ratio of 80:20. mouth 5、 依申請專利範圍第!項之具有自潔能力之 網狀基材係由-聚合物材料形成,該聚合物材料係:中該 龍、聚氯乙締(PVC)、聚對苯二甲酸乙二係由尼 稀(PP)以及聚丁稀對笨二酸醋⑽)所組成之群組選:丙 6、 依申請專利範圍第i項之具有自 二氧化鈦塗層包含—緩衝介面分子, 其中該 一端與二氧化欽鍵結,以該緩衝介面分子i衝介面分子的 另一端與二氧化5, according to the scope of patent application! The mesh-like substrate with self-cleaning ability is made of polymer material. The polymer material is: Zhongkelong, polyvinyl chloride (PVC), and polyethylene terephthalate. ) And polybutylene terephthalate ⑽): C6. According to item i of the patent application, it has a self-titanium dioxide coating containing-buffering interface molecule, in which the one end is bonded with dioxin. , Use the buffer interface molecule i to punch the other end of the interface molecule and the dioxide IHH 第10頁 546438 六、申請專利範圍 精此避免一 ϊ ί: I之其他組成物或是該網狀基材結合 乳化鈦直接與該網狀基材接觸。 淫;申明專利範圍第6項之具有自潔能力之紗網’其中該 *面刀子包含至少一個石夕原子用以與二氧化鈦鍵結。 之紗網的製造方法,其包含下列步 8、一種具有自潔能力 驟: 匕將,數條線織成一網狀基材;將該網狀基材含浸於一樹 脂=f此定型該網狀基材;以及塗佈一層具有光催化性質 的二氧化鈦塗層於該網狀基材上。 9、依申請專利範圍第8項之具有自潔能力之紗網的製造方 法’其中該塗佈步驟係以喷或刷塗的方式達成。 1 0、依申睛專利範圍第8項之具有自潔能力之紗網的製造 方法’其中該塗佈步驟係以含浸的方式達成。 11、依申請專利範圍第8項之具有自潔能力之紗網的製造 方法,其中該具有光催化性質的二氧化鈦塗層包含銳鈦礦 (Anatase)結晶或銳鈦礦與金紅石(Rutile)的混合結晶之” 二氧化鈦顆粒。 1 2、依申請專利範圍第11項之具有自潔能力之紗網的製造IHH Page 10 546438 VI. Scope of patent application To avoid this: I: I other components or combination of the mesh substrate The emulsified titanium is in direct contact with the mesh substrate. A net of self-cleaning ability is stated in item 6 of the patent scope, wherein the * face knife contains at least one Shi Xi atom for bonding with titanium dioxide. A method for manufacturing a gauze net includes the following steps: 8. A step with self-cleaning ability: a dagger, a plurality of threads are woven into a net-like substrate; and the net-like substrate is impregnated with a resin = f to shape the net. A substrate; and coating a layer of titanium dioxide with photocatalytic properties on the mesh substrate. 9. The method for manufacturing a gauze with self-cleaning ability according to item 8 of the scope of the patent application, wherein the coating step is achieved by spraying or brushing. 10. The method of manufacturing a self-cleaning gauze according to item 8 of the patent application ', wherein the coating step is achieved by impregnation. 11. The method for manufacturing a self-cleaning gauze according to item 8 of the application, wherein the titanium dioxide coating having photocatalytic properties includes anatase crystal or anatase and rutile. Mixed crystallized "titanium dioxide particles. 1 2. Manufacture of self-cleaning gauze according to item 11 of the scope of patent application 第11頁 546438 六、申請專利範圍 方法,其中該二氧化鈦顆粒係為銳鈦礦··金紅石分子數比 為8 0 : 2 0之混合結晶。 1 3、依申請專利範圍第11項之具有自潔能力之紗網的製造 方法,其中該二氧化鈦顆粒係為奈米尺寸。 1 4、依申請專利範圍第8項之具有自潔能力之紗網的製造 方法’其中該線係由一聚合物材料形成,該聚合物材""料1"係 由尼龍、聚氣乙烯(Ρ V C)、聚對苯二曱酸乙二酷(ρ ε τ)、取、 丙烯(ΡΡ)以及聚丁烯對笨二酸酯(ΡΒΤ)所組成之群組選水 出。 ^ 15、依申請專利範圍第8項之具有自潔能力之紗網的製 方法’其中該二氧化鈦塗層包含一緩衝介面分子,以該 衝介面分子的一端與二氧化鈦鍵結,以該緩衝介面八 一端與二氧化鈦塗層中之其他組成物或是該網狀基^钍 合,藉此避免二氧化鈦直接與該網狀基材接觸。土 潔忐力之紗網的製造 一個矽原子用以與二Page 11 546438 VI. Patent application method, wherein the titanium dioxide particles are a mixed crystal of anatase ·· rutile molecular ratio of 80:20. 1 3. The method for manufacturing a self-cleaning gauze according to item 11 of the scope of patent application, wherein the titanium dioxide particles are nano-sized. 14. The method of manufacturing a self-cleaning gauze according to item 8 of the scope of the patent application, wherein the thread is formed of a polymer material, and the polymer material is made of nylon, polygas The group consisting of ethylene (P VC), polyethylene terephthalate (ρ ε τ), extraction, propylene (PP), and polybutene terephthalate (PBT) was selected for extraction. ^ 15. A method for producing a self-cleaning gauze according to item 8 of the scope of the patent application, wherein the titanium dioxide coating includes a buffer interface molecule, one end of the punching interface molecule is bonded with titanium dioxide, and the buffer interface is eight One end is combined with other components in the titanium dioxide coating or the mesh substrate, thereby preventing the titanium dioxide from directly contacting the mesh substrate. Manufacture of soil gauze mesh One silicon atom is used for two 1 6、依申請專利範圍第1 5項之具有自 方法,其中該緩衝介面分子包含至少 氧化鈦鍵結。 其包含下列步16. The self-method according to item 15 of the scope of patent application, wherein the buffer interface molecule includes at least a titanium oxide bond. It contains the following steps 第12頁 1 7、一種具有自潔能力之紗網的製造方法 驟: 546438 六、申請專利範圍 將複數條線織成一網狀基材;以及將該網狀基材含浸於 一樹月曰中藉此定型該網狀基材,其中該樹脂包含具有光 化性質的二氧化鈦。 18、依中請專利範圍第17項之具有自潔能力之紗 :法’其中該曰具有光催化性質的二氧化鈦係為銳鈦礦^ (natase )結日日或銳鈦礦與金紅石(Rut u e )曰人 二氧化鈦顆粒。 的化a π晶之 1 9、依申請專利範圍第丨8項之且有自 方法,其中該二氧化鈦顆粒係為銳欽礦H之紗網的製造 為80 : 20之混合結晶。 ·金、、工石义子數比 20、依申請專利範圍第18項之具有自Page 12 1 7. Method for manufacturing a self-cleaning gauze step: 546438 VI. Patent application scope Weaving a plurality of threads into a net-like substrate; and impregnating the net-like substrate with a tree month This shapes the mesh substrate, wherein the resin comprises titanium dioxide having actinic properties. 18. Yarn with self-cleaning ability according to item 17 of the patent: Method 'wherein the titanium dioxide with photocatalytic properties is anatase ^ (natase) or anatase and rutile (Rut ue) said human titanium dioxide particles. According to the method of the patent application No. 8 and the method of self-propagation, the titanium dioxide particles are made of 80:20 mixed crystals of the gauze of Ruiqin H. The ratio of the number of gold, masonry and zizi is 20, according to 方法,其中該二氧化鈦顆粒係為奈米:;力之紗網的製造 21、依申請專利範圍第丨7項之具有自4 * 方法,其中該線係由一聚合物材料形=祀力之紗網的製造 由尼龍、聚氣乙烯(PVC)、聚卦笑-m ’該聚合物材料係 气烯(PP)以及聚丁烯對笨二酸醋(ρβ 己二酯(PET)、聚 出 所級成之群組選 22、依申請專利範圍第丨7項之具有自 方法,其中該二氡化鈦塗層包含一緩^ =力之紗網的製造 衝介面分子,以該缓Method, wherein the titanium dioxide particles are nanometers; manufacturing of a power mesh 21, according to the method of patent application No. 丨 7, the method has a 4 * method, wherein the thread is formed by a polymer material shape = sacrifice yarn The net is made of nylon, polyvinyl chloride (PVC), and polyhexanox-m '. The polymer material is gaseous olefin (PP) and polybutene paraben acid (ρβ adipate (PET). The selected group is 22, and has a self-method according to item 7 of the scope of the patent application, wherein the titanium dioxide coating contains a fabricating interface molecule of a gauze mesh, which uses the cushioning 第13頁 546438 六、申請專利範圍 衝介面分子的一端與二氧化鈦鍵結,以該緩衝介面分子另 一端與二氧化鈦塗層中之其他組成物或是該網狀基材結 合,藉此避免二氧化鈦直接與該網狀基材接觸。 2 3、依申請專利範圍第2 2項之具有自潔能力之紗網的製造 方法’其中該緩衝介面分子包含至少一個石夕原子用以與二 氧化鈦鍵結。 24、一種具有自潔能力之紗網,其包含·· 一網狀基材’其中該網狀基材包含具有光催化活性的二 氧化鈦(Ti02)顆粒。 _ 力之紗網,其中 含銳銥礦 )的混合結晶之Page 13 546438 VI. Patent application scope One end of the interface molecule is bonded with titanium dioxide, and the other end of the buffer interface molecule is combined with other components in the titanium dioxide coating or the mesh substrate, thereby avoiding direct contact between titanium dioxide and The mesh substrate is in contact. 2 3. The method for manufacturing a self-cleaning gauze according to item 22 of the scope of the patent application, wherein the buffer interface molecule contains at least one stone atom for bonding with titanium dioxide. 24. A gauze with self-cleaning ability, comprising: a mesh substrate 'wherein the mesh substrate comprises titanium dioxide (Ti02) particles having photocatalytic activity. _ The gauze of force, which contains a sharp iridium) 25、依申請專利範圍第24項之具有自潔能 該具有光催化性質的二氧化鈦顆粒係為包 (Anatase)結晶或銳鈦礦與金紅石(Rut丨le 二氧化鈦顆粒。 2 6、依申睛專利範圍第2 5項之具有自潔能力之紗網,复25. According to the scope of the patent application No. 24, the self-cleaning titanium dioxide particles having photocatalytic properties are Anatase crystals or anatase and rutile titanium dioxide particles. 2 6. Yishen patent Self-cleaning gauze in the scope of item 25, 該二氧化鈥顆粒係為銳鈦礦:金紅石分子數比為8 〇 '、中 合結晶。 ·、、、 :20之混 27、依申請專利範圍第24項之具有自潔能力之紗網,复 該二氧化鈦顆粒係為奈米尺寸。 其中The particle system of the dioxide 'is anatase: rutile molecular ratio of 80 ′, and the crystalline phase is neutral. · ,,,: 20 mix 27. According to the self-cleaning gauze of item 24 of the scope of application for patent, the titanium dioxide particles are nano-sized. among them 546438 六、申請專利範圍 28、依申請專利範圍第24項之具有自潔能力之紗豆 該網狀,材係由-聚合物材料形成,該聚合物材料係由尼 龍、聚氯乙烯(PVC)、聚對苯二甲酸乙二酯(ρΕτ)、聚丙 烯(ΡΡ)以及聚丁烯對苯二酸酯(ΡβΤ)所組成之群組選^。 29 :,申請專利範圍第24項之具有自潔能力之紗網,其中 該二氧化鈦塗層包含一緩衝介面分子,以該緩衝介面为;子 的一端與二氧化鈦鍵結,以該緩衝介面分子另一端與二氧 化鈦塗層中之其他組成物或是該網狀基材結合,藉此=免 二氧化鈦直接與該網狀基材接觸。 曰 3〇、依申請專利範圍第29項之具有自潔能力之紗網,豆中 該緩衝介面分子包含至少_個㈣子用以與二氧化欽鍵 結0 31、一種具有自潔能力之紗網的製造方法,其包含下 的一氧化鈦顆粒的線織成 將複數條含有具有光催化性質 一網狀基材。 32、依申請專利範圍第31項之具有自潔能力之紗網的製造 方ΐ“其中該具有光催化性質的二氧化鈦顆粒係為包含銳 鈦礦Unatase)結晶或銳鈦礦與金紅石(RutUe)的混合結 晶之二氧化鈦顆粒。 第15頁 546438 }546438 VI. Application patent scope 28, according to the scope of application patent scope 24, self-cleaning yarn beans. The mesh is made of-polymer material, which is made of nylon, polyvinyl chloride (PVC) , Polyethylene terephthalate (ρΕτ), polypropylene (PP), and polybutylene terephthalate (PβΤ). 29: A gauze with self-cleaning ability in the scope of application for patent item 24, wherein the titanium dioxide coating includes a buffer interface molecule, with the buffer interface as one end of the child and titanium dioxide, and the other end of the buffer interface molecule In combination with other components in the titanium dioxide coating or the mesh substrate, thereby preventing the titanium dioxide from directly contacting the mesh substrate. 30. According to the self-cleaning gauze of item 29 in the scope of the patent application, the buffer interface molecule in the bean contains at least _ zongzi for bonding with dioxin. 31. A self-cleaning gauze A method for manufacturing a net, which comprises weaving a thread of titanium oxide particles into a plurality of webs including a net-like substrate having photocatalytic properties. 32. According to the manufacturing method of self-cleaning gauze according to item 31 of the scope of patent application, "wherein the titanium dioxide particles with photocatalytic properties are crystals containing anatase Unatase) or anatase and rutile (RutUe) Mixed crystalline titanium dioxide particles. Page 15 546438} 能力之紗網的製造 金紅石分子數比 3 3、、依申請專利範圍第3 2項之具有自潔 =法其中該二氧化鈦顆粒係為銳鈦碑 為8 〇 : 2 0之混合結晶。 戸、 =、依申請專利範圍第3丨項之具有 方法,其中該二氧化鈦顆粒係為奈米=力之紗網的製造 35、依申請專利範圍第31項之具有自 方法,其中該線係由一聚合物材料形: = :造 由尼龍、聚氣乙烯(PVC)、聚對笨二甲成該二 =料係 :輸)以及聚丁稀對苯二酸_所匕 t依Πί利範圍第31項之具有自潔能力之紗網的製造 方法,/、中邊二氧化鈦塗層包含一緩衝介面分子,以該J 衝;I面刀,的缟與二氧化鈦鍵結,以該緩衝介面分ρ -端f二氧化鈦塗層中之其他組成物或是該網狀基材結 合,藉此避免二氧化鈦直接與該網狀基材接觸。 37 :依申請專利範圍第36項之具有自潔能力之紗網的製 方法,其中該緩衝介面分子包含至少一個矽原子用以鱼一 氧化鈦鍵結。 τ 〇 一Manufacture of gauzes of ability rutile molecular ratio 3 3. The method of self-cleaning according to item 32 of the scope of patent application. The titanium dioxide particles are a mixed crystal of 80:20 anatase.戸, =, according to the method of claim 3 in the scope of the patent application, wherein the titanium dioxide particles are manufactured by nano = force of the gauze net 35, according to the method of claim 31 in the scope of the patent application, where the line is made by A polymer material shape: =: made of nylon, polyethylene gas (PVC), poly-paraben dimethyl = the material system: lose) and polybutylene terephthalic acid The method for manufacturing a gauze with self-cleaning ability according to item 31, // The middle-side titanium dioxide coating contains a buffer interface molecule, the J punch; the I surface knife, 缟 and titanium dioxide are bonded, and the buffer interface is divided into ρ- The other components in the terminal f titanium dioxide coating or the mesh substrate are combined to prevent the titanium dioxide from directly contacting the mesh substrate. 37: The method for making a self-cleaning gauze according to item 36 of the patent application, wherein the buffer interface molecule contains at least one silicon atom for fish-titanium oxide bonding. τ 〇 1 第16頁 546438 案號 91135768Page 16 546438 Case number 91135768 五、發明說明(1)【發明所屬之技術領域】 本發明係有關於一種紗網。 【先前技術】 曰处t f門囪上常设有紗網。紗網具有複數網眼, 疋月匕士 一、旎讓空軋流通,並且適當地控制網眼的 蟲等不受歡迎的外來物。但是紗網使用過 間:灸,灰塵或不乾淨的雜質容易堆積在其網眼周圍 ,隔-段時間就必須清洗—次,十分麻煩。【發明内容】 因此,本發明之目的係提供一種具有自潔能力之 使用的過程中能自我清潔’不需要額外的清潔手 根據本發明一實施例之紗網,其主要包含一網狀 及一層具有光催化活性的二氧化鈦塗層於該網狀基 精由二乳化鈦塗層的光催化活性使該紗網具有自潔 根據本發明另一實施例之紗網,其一網狀基材中含 光催化活性的二氧化鈦,藉此使該紗網具有自潔能 該網狀基材可由金屬、陶瓷材質或是聚合物材料形 用以作為本發明網狀基材之聚合物材料包含尼龍、 烯(PVC)、聚丙烯(PP)以及聚對苯二甲酸乙二酯 其優點 大小可 一段時 ,因此 紗網, 續。 基材以 材上, 能力。 有具有 力。 成。可 聚氣乙 (PET) • · · · · · 等 該具有光催化活性的二氧化鈦塗層可包含銳鈦礦 (Anatase)結晶之二氧化鈦顆粒或銳鈦礦與金紅石 (Rut 1 1 e)的混合結晶之二氧化鈦顆粒,且較佳為奈 之顆粒。銳鈦礦與金紅石的混合結晶其混合比例較 鈦礦:金紅石分子數比為8 〇 : 2 〇。 米尺寸 佳為銳V. Description of the invention (1) [Technical field to which the invention belongs] The present invention relates to a gauze. [Prior art] A gauze is standing on the doorway at t f. The gauze has a plurality of meshes. The moon dagger 1. The maggots let the air roll circulate and properly control the undesired foreign objects such as insects in the mesh. However, the gauze has been used for some time: moxibustion, dust or dirty impurities are easy to accumulate around its mesh, and it must be cleaned once every time, which is very troublesome. [Summary of the Invention] Therefore, the object of the present invention is to provide a self-cleaning process capable of self-cleaning during use. No additional cleaning hand is required. A gauze according to an embodiment of the present invention mainly includes a mesh and a layer The photocatalytic activity of a titanium dioxide coating on the mesh-like substrate. The photocatalytic activity of the di-emulsified titanium coating makes the gauze self-cleaning. According to another embodiment of the present invention, a gauze substrate contains The photocatalytically active titanium dioxide allows the gauze to have self-cleaning properties. The mesh substrate can be made of metal, ceramic or polymer material. The polymer material used as the mesh substrate of the present invention includes nylon, olefin ( PVC), polypropylene (PP), and polyethylene terephthalate have their advantages over a period of time, so gauze, continued. The ability of the substrate to material. There is power. to make. Polymerizable Gas B (PET) • The photocatalytically active titanium dioxide coating can include anatase (Titanium dioxide) crystals or a mixture of anatase and rutile (Rut 1 1 e) Crystalline titanium dioxide particles, and preferably nano particles. The mixed crystal of anatase and rutile has a higher mixing ratio than the titanate: rutile molecular ratio of 80:20. Meter size Jiaweirui H:\⑻589-TW.ptcH: \ ⑻589-TW.ptc 第4頁Page 4
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