TW526130B - Coextruded block and filter medium and application therefor - Google Patents

Coextruded block and filter medium and application therefor Download PDF

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Publication number
TW526130B
TW526130B TW85115119A TW85115119A TW526130B TW 526130 B TW526130 B TW 526130B TW 85115119 A TW85115119 A TW 85115119A TW 85115119 A TW85115119 A TW 85115119A TW 526130 B TW526130 B TW 526130B
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Taiwan
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agglomerate
extruded
patent application
item
particles
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TW85115119A
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Chinese (zh)
Inventor
Carol Ann Blaney
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Kimberly Clark Co
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Publication of TW526130B publication Critical patent/TW526130B/en

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Abstract

A coextruded block composite which includes a porous first block. The block is permeable to fluids and includes a granular component and a binder component. The block has interconnected pores therethrough having a first average diameter. The composite also includes a second block. In addition, at least one of the first and the second block is continuous and at least a portion of the second block is contiguous with at least a portion of the first block. The second block also may be permeable to fluids. Additional block may be present, if desired. One or more of the blocks other than the first block may be a porous block having a granular component and a thermoplastic binder component. The coextruded block composite may be employed as a filter medium.

Description

5126130 經濟部中央標準局員工消費合作社印製 五、發明説明( I明背景 A7 B7 本發明關於一個多巩茄人 口夕孔设合物破運用如一 個過濾器媒 般而。,過濾器牽涉將流體通過一 而從-個流體除去懸浮固體。 处夕孔性媒介’ 者金屬網布。後兩種形, 、” W旎為紙、布、或 叩*兩種形式的媒介特別著重於 ' 滾動鼓或皮帶過濾器之連續商業製造。 積’運用 然而,有許多運用需要較小、通常可 媒介。這類媒介句括鉍·姑 、工的’過濾器 紙,特利途的鋪床,這mu …以及固態多孔性過濾、元素。固態多孔 素特別被企求用於操作簡易並且可棄式的。 。濾疋 固態多孔性過濾元素可能以^固分批法製成 法既費時且勞力密集。近來,製造法利 方 4⑺辨出一個混合物 可旎形成連續,此混合物為一個熱塑 即材枓和一個 私末狀或顆粒初級材料例如一個活性碳。雖然如此,改善 擠出固態多孔性過濾器元素的機會仍在。 |羽概述 本發明重點指向上述討論一些困難以及問題而提供 一個共擠出團塊複合物其包括一個多孔性第一團塊。團塊 爲爲可透流體並且包括一個顆粒成份以及一個熱塑性黏 結成份。團塊連接彼此微孔具有一個第一平均直巧。複人 物也包括一個第二團塊。此外,第一團塊和第二團塊的至 少一個爲連續並且至少第二團塊的一個部份和第一團塊 的一個部份靠近。以範例來説,第一團塊的顆粒成份可能 介 (請先閲讀背面之注意事項再頁} -¾衣· 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 4 5 ο 3 τ-Η 6 經濟部中央標準局員工消費合作社印製 五、發明説明(2 ) ' : —~--- 爲活性碳,陶究顆粒,滞石顆粒,不活潑顆粒,砂子,表 面父換-修正顆粒,以及其混合物。 果而要第一團塊可能爲一個一個多孔性圏塊且爲 可、透流體的’並包括—個顆粒成份以及—個熱塑性黏結成 伤,並且具有連接微孔於其中此微孔具有一個第二平均直 控。顆粒成份舉例來説可能爲活性碳,陶党顆粒,滞石顆 粒’不活潑顆粒,砂子,表面交換_修正顆粒,以及其混 合物。第二團塊可能爲連續的或非連續的。在特定具體實 例:’第二平均直徑可能和第一平均直徑不同。共擠出圏 塊複合物可能包括一個第三團塊,其爲可透流體,並包含 有一個顆粒成份以及一個熱塑性黏結成份,並且具有連接 微孔於其中並具有一個第三平均直徑。第三團塊的至少一 個部份會靠近第一團塊或第二團塊的一部分。在特定的具 體實例中,第一,第二,和第三平均直徑被調整而提供共 擠出團塊一個漸層微孔結構。此外,第三團塊之顆粒成份 可能爲活性碳,陶瓷顆粒,沸石顆粒,不活潑顆粒,砂子, 表面交換-修正顆粒,以及其混合物。 更甚者,共擠出團塊成份可能包栝一個第四團塊,其 爲可透流體的,並包括一個顆粒成份以及一個熱塑性黏結 成彳刀’並具有連接微孔於其中,其具有一個第四平均丨亩 徑。第四團塊的至少一個部份靠近第一,第二或第三團塊 的一部分。第一,第二,第三,以及第四平均直徑可能被 調整而提供共擠出團塊一個漸層微孔結構。第四團塊的顆 粒成份可能爲活性碳,陶瓷顆粒,沸石顆粒,不活潑顆粒, (請先閲讀背面之注意事項再本瓦) 裝· 訂 -線 • - - - - nn 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X297公楚) 55126130 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economics 5. Description of the invention (Iming background A7 B7 The present invention relates to the use of a polyglyceride population as a filter medium. The filter involves the fluid Removal of suspended solids from a fluid by one. Porous media are metal mesh cloths. The latter two forms, "W 旎" are paper, cloth, or 叩 * two forms of media are particularly focused on the "rolling drum" Or belt filter for continuous commercial manufacturing. Plots' applications However, there are many applications that require smaller, usually media. Such media include bismuth, filter, filter paper, terry bed, this mu ... As well as solid porous filtration, elements. Solid porous elements are particularly sought for easy and disposable operation. Filtering solid porous filtration elements may be time-consuming and labor-intensive in a solid batch method. Recently, Manufacturing method 4 identifies a mixture that can be formed into a continuous mixture of a thermoplastic material and a primary or granular primary material such as an activated carbon. Opportunities for good extrusion of solid porous filter elements remain. | Feather Overview The present invention focuses on the difficulties and problems discussed above and provides a co-extruded agglomerate complex that includes a porous first agglomerate. The agglomerates are It is fluid permeable and includes a granular component and a thermoplastic bonding component. The lumps are connected to each other and the micropores have a first average dexterity. The complex also includes a second lumps. In addition, the first lumps and the second lumps At least one of them is continuous and at least one part of the second agglomerate is close to one part of the first agglomerate. As an example, the particle composition of the first agglomerate may be introduced (please read the precautions on the back before the page) } -¾ Clothing · This paper size is in accordance with Chinese National Standard (CNS) A4 (210X 297 mm) 4 5 ο 3 τ- 印 6 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of Invention (2) ': — ~ --- It is activated carbon, ceramsite particles, stagnant stone particles, inactive particles, sand, surface-replacement-correction particles, and mixtures thereof. As a result, the first mass may be one by one porous. The block is fluid-permeable and includes a particulate component and a thermoplastic adhesive wound, and has connected micropores in which the micropores have a second average direct control. The particulate component may be activated carbon, for example , Tao Dang particles, stagnant stone particles 'inactive particles, sand, surface exchange_correction particles, and mixtures thereof. The second agglomerate may be continuous or discontinuous. In a specific specific example:' the second average diameter may be and The first average diameter is different. The co-extruded lumpy composite may include a third mass which is permeable to fluid, contains a particulate component and a thermoplastic bonding component, and has micropores connected therein and a first Three average diameters. At least a portion of the third agglomerate will be close to a portion of the first or second agglomerate. In a specific specific example, the first, second, and third average diameters are adjusted to provide a co-extruded agglomerate microporous structure. In addition, the particle composition of the third agglomerate may be activated carbon, ceramic particles, zeolite particles, inactive particles, sand, surface exchange-correction particles, and mixtures thereof. What's more, the co-extruded agglomerate component may include a fourth agglomerate, which is permeable to fluids, and includes a particulate component and a thermoplastic bonded into a trowel, and has connecting micropores therein, which has a The fourth average 丨 acre trail. At least a portion of the fourth briquette is adjacent to a portion of the first, second or third briquette. The first, second, third, and fourth average diameters may be adjusted to provide a graduated microporous structure of co-extruded agglomerates. The particle composition of the fourth agglomerate may be activated carbon, ceramic particles, zeolite particles, and inactive particles. (Please read the precautions on the back before this tile.) Binding · Thread-----nn This paper size applies to China National Standard (CNS) Λ4 Specification (210X297)

五、發明説明(3 砂子,表面交換-修正顆扣 稍仏,以及其混合物。 如果需要’共擠出圃始士、 秦:今 M ^ 圈塊成份之第二圏塊可能爲吁達",ϋ 姐的。弟二團塊可能爲連 % 一 運續的或非連續的。舉例來説,弟 一團塊可能爲一個鼽塑 …、2丨生聚埽烴團塊,例如聚丙烯團塊。 如果需要,第二團堍可处α · 八 此被碉整引導一個流體從一個第〆 邵伤沿著一個先設定的 路k通過弟一團塊而進入一個弟 二部份。 本發明也提供一俩制/巷, . 固氣備一個共擠出團塊成份的方,其 包括: 從一個擠出器桶進入一個模型擠出一個含有顆粒和 一個熱塑性黏結劑之混合物; 加熱混合物至—個溫度’此溫度必須大於熱塑性黏結 劑的軟化溫度而且小於顆粒的軟化溫度; 在模型内施加足夠的後壓力至加熱的混合物而將加 熱混合㈣化至-個複合材料; 冷卻複合材料至—彳^, 個溫度,此溫度低於熱塑性黏、纟士劑 的軟化溫度;以及 從模型擠出複合材料; 其中改善之處牵涉到: 激發此模型和/或擠出器桶至少其中一個位置配人有 次音速’音速,或超音波能量,其頻率和/或振幅不;, 其依照-個方法調整増加從一個擠出器桶進入—個模型 顆粒混合物的擠出以及—個熱塑性黏結劑的擠出,以及從 模型的複合材料的擠出。 本紙張尺度適财國_轉(^^7710 X 2;釐7 6 f 訂 卜線 I 經濟部中央標準局員工消費合作社印製 五、發明説明(4 本發明也提供一個過濾器媒介立包括本發明的一個 共擠出團塊成份。 簡單説 圖1至5以及圖8爲闡釋本發明之共擠出團塊成份不 同具體實例正視圖。 圖6爲本發明生產一個共擠出團塊成份可能使用的 一個模型之橫切圖。 圖7爲描繪由使用圖6之模型製成的一個共擠出團塊 成份正視圖。 glJ烊述 「連接其中微孔」一詞參考一個團塊意指必須所有出 現在團塊的微孔連接至鄰近的微孔,因而造成多數或多或 少扭曲路徑從一個表面或位置至另一個表面或位置。因為 微孔彼此連接,一個流體可能完全通過一個團塊。意即, 流體可能以一個位置進入一個團塊而通過團塊而離開另 一個位置。因而,團塊是可透流體的。 如此處所用,「流體」意指包括氣體以及液體。 如此處所使用,「多孔團塊」意指一個團塊其為多孔 性的且可通透流體。「顆粒」意指廣泛的結構圍繞任何的 顆粒材料,不管顆粒的尺寸之任何適用本發明的顆 而,此一詞意圖包括粉末。 如此處所使用,「熱塑性黏結劑」意指任何黏纟士劑 典型的為一個聚合物,其為熱塑性,意即當被加熱可以^ 化並流動並在冷卻後可以再硬化。熱塑性黏結劑之範例包 良纸張尺度適用t國國家標準(CNS ) A4規格(2〗〇Χ297公釐 7 (請先閱讀背面之注意事項再本頁) —裝·V. Description of the invention (3 sand, surface exchange-corrected buckle slightly, and its mixture. If you need to co-extrude the gardener, Qin: The second block of the M ^ circle block composition may be Yuda " Sister's. The second brother's block may be continuous or non-continuous. For example, the second brother's block may be a plastic block, such as a polypropylene block. If needed, the second group can be treated as α. The eighth group is guided to guide a fluid from a first group to a second group through a group of k and enter a second part. The invention One or two systems / lanes are also available.. Solid gas preparation of a co-extruded agglomerate composition, which includes: from an extruder barrel into a mold to extrude a mixture containing particles and a thermoplastic binder; heating the mixture to —A temperature 'This temperature must be greater than the softening temperature of the thermoplastic adhesive and less than the softening temperature of the particles; apply sufficient post-pressure to the heated mixture in the mold to heat the mixture to a composite material; cool the composite material to—彳 ^ , A temperature that is lower than the softening temperature of the thermoplastic adhesive and tincture; and extruding the composite material from the model; the improvement involves: stimulating the model and / or the extruder barrel at least one of the positions is equipped with Subsonic speed, or supersonic energy, whose frequency and / or amplitude are not; it adjusts in accordance with a method to increase the extrusion of a model particle mixture from an extruder barrel and the extrusion of a thermoplastic adhesive , And the extrusion of composite materials from the model. The paper size is suitable for financial countries _ Zhuan (^^ 7710 X 2; 77 6 f) Line I Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs The present invention also provides a filter medium including a co-extruded agglomerate component of the present invention. Briefly, FIGS. 1 to 5 and FIG. 8 are front views illustrating different specific examples of the co-extruded agglomerate component of the present invention. FIG. 6 is A cross-sectional view of a model that may be used in the present invention to produce a co-extruded briquette component. FIG. 7 is a front view depicting a co-extruded briquette component made using the model of FIG. 6. The term `` hole '' referring to a clump means that all micropores present in the clump must be connected to adjacent micropores, thus causing most or less distorted paths from one surface or location to another. Because micropores Connected to each other, a fluid may pass completely through a lump. That is, a fluid may enter a lump at one location and leave another through a lump. Thus, the lump is fluid-permeable. As used herein, "fluid "Means gas and liquid. As used herein," porous mass "means a mass that is porous and permeable to fluids." Particulate "means a broad structure surrounding any particulate material, regardless of the particle's Any particle of a size suitable for the present invention, this term is intended to include powder. As used herein, "thermoplastic adhesive" means that any adhesive agent is typically a polymer, which is thermoplastic, meaning that it can be heated when heated. ^ It melts and flows and can harden again after cooling. Examples of thermoplastic adhesives. Good paper sizes are applicable to national standards (CNS) A4 specifications (2) 0 × 297 mm 7 (Please read the precautions on the back before this page) —Packing ·

訂I 線 I- -- 1- 1 5126130 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明(5 ) 括,僅為了敘述之便,末端-覆蓋聚乙縮醛,例如聚(氧 化亞甲基)或聚甲酸,聚(三氣乙醛),聚(^戊搭), 聚(乙醛)’聚(丙酸),以及類似物;丙烯聚合物,例 如聚丙烯醯胺,聚(丙烯酸),聚(甲基丙烯酸),聚(乙 基酸),聚(曱基甲基丙烯酸),以及類似物;碳氟化 合物聚合物,例如聚(四氟乙烯),高氟酸乙烯_丙烯共 聚合物,乙烯-四氟乙烯過聚合物,聚(氣三氟乙烯), 乙烯-氯三伏乙烯過聚合物,聚(氟亞乙烯基),聚(氟 乙婦基)’以及類似物,聚酿胺,例如聚(6 _胺基己酸) 或者(ε -己内醯胺),聚(六甲樓己二酿二胺),聚(六 甲撐sebacamide ),聚(1 1-氨基十一烷酸),以及類似 物;polyaramides,例如聚(亞氨基-丨,%次苯基亞氨基間 苯二醯)或聚(間-次苯基鄰苯二醯胺),以及類似物; parylenes,例如 P〇ly-a-xylylene,polykhloro-kxylylene) 聚芳基酯,例如 p〇ly(oxy-2,6-dimethyl-l,4-phenylene)或 p〇ly(p_-phenylene oxide),以及類似物;聚芳基 ,例如 (oxy-l54-phenylenesulfony-l54-phenyleneoxy-l54-phenylene-isopropylidene-l54-phenylene)?poly(sulfonyl-l,4-phenylleneoxy-l54-phenylenesulfonyl-4?4,-biphenylene),以及類似物;聚碳酸鹽類,例如 poly(bisphenol A)或 poly(carbonyldioxy- l?4-phenylene-isopropylidene-1,4_phenylene),以及類似物;聚酯類,例 如 poly(ethylene terephthalate)5poly(tetramethylene tere-phthalate), poly(cyclohe xylene -1,4-dim ethylene 本紙張尺度適用中國國家標準(CNS ) Λ4規格(21〇X297公釐) (請先閱讀背而之注意事項再本頁) i. 線 526130 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明(6 ) terephthalate)或 poly(oxym ethylene - 1,4-cyclohexylene- methyleneoxytere-phthaloyl),以及類似物;聚芳基硫醚, 例如 poly(p_-phenylenesulfide)或(thio-l,4-phenylene,以 及類似物,聚亞胺’例如p〇ly(pyromellitimido-l,4-phenylene),以及類似物;聚烯烴,例如聚乙稀,聚丙烯, 聚(1-丁烯),聚(2-丁烯)聚(1-戊烯)聚(2-戊烯), 聚(3 -甲基-1-戊烯),聚(4-甲基-1-戊烯),以及類似 戊,乙稀基聚合物,例如聚(乙稀基乙酸),聚(氣亞乙 烯),聚(氣乙烯),以及類似戊物;二烯聚合物,例如 1’2-1-1,3 -丁 一 稀 ’ 1,4-聚-1,3-丁二埽,聚異戍間二稀, 聚氯丁二烯,以及類似戊;聚苯乙烯;上述之共聚合物, 例如丙稀 -丁二烯-苯乙嫦(&(^1〇11丨1:1>丨16-1)1^(1丨61^-styrene) (ABS)共聚合物,以及類似物。 如此處所使用,「漸層微孔結構」意指一個或多個微 孔團塊構成本發明共擠出團塊成份之平均微孔直徑從第 一團塊到每一個接下來的團塊漸增加或漸減少。當一個共 擠出團塊成份僅包括兩個微孔團塊,只要兩個微孔團塊具 有不同平均微孔直徑,成份將具有一個漸層微孔結構。因 而’一個流體進入必要之兩個團塊之一並須通過進入並穿 過一個團塊,其具有一個平均微孔直徑,此直徑或大於或 小於流體流出微孔團塊的直徑。當一個成份包括兩個以上 微孔團塊,當一個流體通過成份進入一個微孔團塊並接著 進入且穿過剩餘的微孔團塊一個漸層微孔結構將存在,漸 層的每一個微孔團塊之平均微孔直徑漸大於或漸小於前Order I line I--1- 1 5126130 Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (5) Includes, for narrative purposes only, end-covered polyacetal, such as poly (oxidation Methylene) or polyformic acid, poly (trifluoroacetaldehyde), poly (acetal), poly (acetaldehyde) 'poly (propionic acid), and the like; propylene polymers, such as polyacrylamide, poly (Acrylic acid), poly (methacrylic acid), poly (ethyl acid), poly (fluorenyl methacrylic acid), and the like; fluorocarbon polymers, such as poly (tetrafluoroethylene), perfluoroethylene Propylene copolymer, ethylene-tetrafluoroethylene perpolymer, poly (gas trifluoroethylene), ethylene-chlorotrifluoroethylene perpolymer, poly (fluorovinylidene), poly (fluoroethynyl) 'and the like Polyamines, such as poly (6-aminocaproic acid) or (ε-caprolactam), poly (hexamethylene hexamethylene diamine), poly (hexamethylene sebacamide), poly (1 1-aminodeca Monoalkanoic acid), and the like; polyaramides, such as poly (imino- 丨,% phenylimino M-phenylene difluoride) or poly (m-phenylene o-phenylenediamine), and the like; parylenes, such as Poly-a-xylylene, polykhloro-kxylylene) polyaryl esters, such as poly (oxy -2,6-dimethyl-l, 4-phenylene) or poly (p-phenylene oxide), and the like; polyaryl groups, such as (oxy-l54-phenylenesulfony-l54-phenyleneoxy-l54-phenylene-isopropylidene- l54-phenylene)? poly (sulfonyl-l, 4-phenylleneoxy-l54-phenylenesulfonyl-4? 4, -biphenylene), and the like; polycarbonates, such as poly (bisphenol A) or poly (carbonyldioxy-l? 4 -phenylene-isopropylidene-1,4_phenylene), and the like; polyesters, such as poly (ethylene terephthalate) 5poly (tetramethylene tere-phthalate), poly (cyclohe xylene -1,4-dim ethylene) The paper dimensions are applicable to Chinese national standards (CNS) Λ4 specification (21 × 297 mm) (please read the precautions on this page first and then this page) i. Line 526130 A7 B7 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (6) terephthalate) Or poly (oxym ethylene-1,4-cyclohexylene- methyleneoxy tere-phthaloyl), and the like; polyaryl sulfide, such as poly (p-phenylenesulfide) or (thio-l, 4-phenylene, and the like, polyimide ', such as poly (pyromellitimido-l, 4 -phenylene), and the like; polyolefins such as polyethylene, polypropylene, poly (1-butene), poly (2-butene) poly (1-pentene) poly (2-pentene), poly (3-methyl-1-pentene), poly (4-methyl-1-pentene), and polymers similar to pentyl and ethylene, such as poly (ethylene vinyl acetate), poly (ethylene vinylene) , Poly (gas ethylene), and similar pentenes; diene polymers, such as 1'2-1-1,3-butanexylene '1,4-poly-1,3-butanefluorene, polyisobutylene Dilute, polychloroprene, and similar pentylene; polystyrene; the above-mentioned co-polymers, such as propylene-butadiene-styrene (& (^ 1〇11 丨 1: 1 > 丨 16- 1) 1 ^ (1 丨 61 ^ -styrene) (ABS) copolymer, and the like. As used herein, "gradient microporous structure" means that the average micropore diameter of one or more microporous masses constituting the co-extruded mass composition of the present invention increases from the first mass to each subsequent mass. Or gradually decrease. When a co-extruded agglomerate composition includes only two microporous agglomerates, as long as the two microporous agglomerates have different average micropore diameters, the composition will have a graded microporous structure. Therefore, a fluid enters one of the two necessary masses and must pass through and pass through a mass having an average micropore diameter which is larger or smaller than the diameter of the fluid flowing out of the microporous mass. When a component includes more than two microporous clumps, when a fluid enters a microporous clump through a component and then enters and passes through the remaining microporous clumps, a gradient microporous structure will exist. The average micropore diameter of the pore mass is gradually larger or smaller than before

(請先閱讀背面之注意事項再本頁) —裝 木 訂, 線 5(26130 A7 五、發明説明(7 ) ' ' 述平均微孔直徑。 一般而言,「熱塑性聚烯烴」使用於此意指任何可以 熔化-擠出的熱塑性聚烯烴。熱塑性聚烯烴的範例包括聚 乙稀,線性低密度聚乙稀,聚丙烯,聚(^丁烯),聚(^ 戊烯),聚(2-戊烯),聚(3_甲基戊烯),聚(^ 甲基-1-戊烯),以及類似物。此外,此項目意指包括兩 個或多個聚烯烴的混雜物,以及從兩個或多個不同未飽和 單體製備而成的隨機以及團塊共聚物。因其商業上的重要 性,最被企求的聚烯烴為聚乙稀,線性低密度聚乙稀,以 及聚丙婦。 如較早所述之,本發明提供一個共擠出團塊成份,其 包括一個多孔性第一團塊以及一個第二團塊。第一團塊為 可透流體的,包括一個顆粒成份以及一個熱塑性黏結劑成 份,以及具有彼此連接微孔其具有一個第一平均直徑。此 外,第一團塊和第二團塊至少一個為連續的並且第二團塊 的至少一個部份靠近第一團塊至少一個部份。以範例來 說,第一團塊之顆粒成份可能為活性碳,陶瓷顆粒,沸石 顆粒,不活潑顆粒,砂子,表面交換_修正顆粒,以及其 混合物。 在一些具體實例中,第二團塊為可透流體,包括一個 顆粒成份以及一個熱塑性黏結劑成份,並含有一個第二平 均直役具有彼此連接微孔。第二平均直徑可能相同或相異 於第一平均直徑。第二團塊之顆粒成份可能選自包含活性 碳,陶瓷顆粒,沸石顆粒,不活潑顆粒,砂子,表面交換 ^^—尺^^用中國—國家標準(匸叫八4規格(21^97公釐) ----—(Please read the precautions on the back first, then this page) — Wood binding, thread 5 (26130 A7 V. Description of the invention (7) '' Mean average pore diameter. Generally speaking, "thermoplastic polyolefin" is used for this purpose Refers to any thermoplastic polyolefin that can be melt-extruded. Examples of thermoplastic polyolefins include polyethylene, linear low density polyethylene, polypropylene, poly (^ butene), poly (^ pentene), poly (2- Pentene), poly (3-methylpentene), poly (^ methyl-1-pentene), and the like. In addition, this item means a hybrid that includes two or more polyolefins, and from Random and agglomerated copolymers made from two or more different unsaturated monomers. Due to their commercial importance, the most sought after polyolefins are polyethylene, linear low density polyethylene, and polypropylene. As mentioned earlier, the present invention provides a co-extruded agglomerate component that includes a porous first agglomerate and a second agglomerate. The first agglomerate is fluid permeable and includes a particulate component and A thermoplastic adhesive composition, and having a micropore connected to each other A first average diameter. In addition, at least one of the first and second clumps is continuous and at least a portion of the second clump is close to at least a portion of the first clump. By way of example, the first clump The particle composition of the block may be activated carbon, ceramic particles, zeolite particles, inactive particles, sand, surface exchange_correction particles, and mixtures thereof. In some specific examples, the second block is a permeable fluid, including a particle component And a thermoplastic adhesive component, and contains a second average direct-acting micropores connected to each other. The second average diameter may be the same or different from the first average diameter. The particle composition of the second agglomerate may be selected from the group consisting of activated carbon, Ceramic particles, zeolite particles, inactive particles, sand, surface exchange ^^-foot ^^ use China-National Standard (howling eight 4 specifications (21 ^ 97 mm) -----

W (請先閱讀背面之注意事項再本頁) i - 線 經濟部中央標準局員工消費合作社印製 ^6130 五、發明説明(8 ::?粒’以及其混合物等這些物質。第二團塊可能爲 連續的或非連續的。 /、杈出團塊成份可能包括一個可透流體之第三團 塊—包括一個顆粒成份,並具有彼此連接微孔並具有一個 第三平均直徑。至少第三團塊之一部分靠近第一團塊或第 々團塊至少一部分。在一些具體實例,第一,第二,以及 第三^均直徑調整提供共擠出團塊成份一個漸層微孔結 構。第-團塊之顆粒成份可能選自活性碳,陶是顆粒,滞 石顆板,不活潑顆粒,砂子,表面交換-修正顆粒,以及 其混合物之物質。 卜八擠出團塊成份可能包括一個可透流體的第四 團塊包括一個顆粒成份以及一個熱塑性黏結劑成份,並 ^有彼此連接微孔其具有平均直徑。第四團塊的至少一個 邵份靠近第一,第二,或第三團塊之一個部份。第一,第 一,罘二以及第四平均直徑可能調整提供共擠出團塊成份 個漸層铖孔結構。第四團塊之顆粒成份選自包含活性 碳,陶完顆粒,滞石顆粒,不活潑顆粒,砂子,表面交換 -修正顆粒,以及其混合物等至些物質。 經濟部中央標準局員工消費合作社印製 士果而要’第一團塊可能不遠液體並可能連續的或非 連續的。更甚者,第二團塊可能調整沿著先訂定路徑從一 弟步彳刀到個弟二部份引導一個流體通過第一團 塊以範例來説,第二團塊可能爲一個熱塑性聚烯烴團 塊,例如一個聚丙烯團塊。 本發明也提供一個製備一個共擠出團塊成份成份的 本紙張尺纽财_ 526130 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明(9 ) 方法,其包括: 從一個擠出器枯 、 擠出一個包含有顆粒以及一個執蜜 性黏結劑之混合物Μ、 1U…玉 7廼入一個模型; 加熱混合物至_ ^ ^ π , 彳固溫度,此溫度大於熱塑性黏結劑的 軟化溫度並且小於黯1 p〜 、’板的軟化溫度; 在模型内施力σ篇t ^ -b 4h ^ hh ^ yv β 9後壓力至加熱過的混合物而賴 換加熱過的混合物抢υ 、 入一個實質上均質複合物材料; 冷卻復合物材料5 、 ^ 一個溫度,此溫度低於熱塑性黏結 劑的軟化點;以及 從模型擠出複合物材料; 其中改進之處包括: 以次音波,音油►,+ & a 或超曰波能源加發模型和/或擠出 姦桶至少一個部价柃处A匕、比、士 °二把源碉整其頻率和/或振幅,依照 一個方法調整增加顆舲π人仏、& ' '任 , 顆粒,此合物《擠出或從一個擠出器桶 進入一個模型擠出一個敎 固…·^性黏結劑,以及從模型擠出複 合物材料。 擠出粒子混合物和一個熱塑性黏結劑而製成一個多 ::图塊,參照於此擠出團塊技術,被熟知爲(例如克思 象(K〇Sl〇W)之美國專利編號 5,1 89,092 、 5 249 948 、 5’331,〇37,每一個合併於此作爲參考資料)。扼要的説, :粒-個混合物以及—個熱塑性黏結劑被擠出從一個擠 f器桶進入一個模型。混合物被加熱至_個溫度,此溫度 大於熱塑性黏結劑的軟化溫度,並小於顆粒的軟化溫度。 足夠後壓力接著施加至加熱過混合物在模型之内換 (請先閱讀背面之注意事項再本頁) —裝. 太 -一口 • —B^i en —— - - m i In m 本紙張尺度翻巾關家標準(CNS ) A4規格(21GX 297公髮) 526130 A7 ---~__ B7 五、發明説明(1 Ο) '~~~ -- 加熱過的混合物進入一個實質上均質複合物材料。複合物 成份被冷卻至一個溫度低於熱塑性黏結劑之軟化點,並且 •從模型擠出。 一個關鍵性挑戰於製造擠出團塊技術包括半固狀混 合物顆粒以及熱塑性黏結劑而沿著一個擠出器流動並通 過-個模型。根據本發明的方法,在製造期間振動能量被 施加入擠出器和/或模型,增加顆粒黏結劑混合物的流通 過擠出器和模型。此振動能量可能被施加至擠出器和/或 模型依照此技藝熟知的技術之壓電介質裝置。增加混合物 流動最適當頻率和振幅必須依據每一個設備設計、製造速 度、粒子尺寸、黏結劑挑選、以及製造條件(例如溫度和 壓力)而改變。此外,最適當頻率和振幅可能依據時間而 改變。接下來,一個電腦控制生產器被建議,使用建造於 其中回饋L Ο Ρ,連續的將頻率和振幅模型最適當化設定 爲時間之功能。這些模型沿著擠出器的長和/或模型不同位 置不斷改變,而頻率範圍包括次音波、音波、和/或超音波 振動。 在這個最簡單的形式中,本發明之共擠出團塊成份包 含有一個多孔性第一團塊,以及一個第二團塊,其中一個 具體實例以圖一闡釋。在圖一中,—個共擠出團塊成份ι〇 含有一個圓柱形多孔性第一團塊丨丨以及一個圓柱形第二 團塊12其亦為多孔性。多孔性團塊"和12為同心圓且連 續的;第二團塊12外表面13靠近第一團塊u的内表面。 以圖1解釋之複合物可能被製成經由擠出兩個不同顆粒黏 本紙張尺度適用中國國家標準(CNS ) Λ4規格(21〇Χ 297公釐) (請先閱讀背面之注意事項再·W (Please read the precautions on the back before this page) i-Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ^ 6130 V. Description of the invention (8 ::? Grains) and mixtures of these substances. Second mass May be continuous or discontinuous. /. The composition of the clumps may include a fluid-permeable third clump—including a granular component, with micropores connected to each other and a third average diameter. At least a third A portion of the mass is close to at least a portion of the first mass or the third mass. In some specific examples, the first, second, and third average diameters are adjusted to provide a co-extruded micro-porous structure of the components of the mass. -The granule composition of the agglomerates may be selected from activated carbon, pottery granules, stagnant stone plates, inactive granules, sand, surface exchange-correction granules, and mixtures thereof. [8] The extruded agglomeration ingredients may include a The fluid-permeable fourth mass includes a particulate component and a thermoplastic adhesive component, and has micropores connected to each other and has an average diameter. At least one portion of the fourth mass is close to the first, Part of the second or third briquette. The first, first, second and fourth average diameters may be adjusted to provide co-extruded briquette components with a stepped pore structure. The particle composition of the fourth briquette is selected Self-contained activated carbon, pottery finished particles, sludge particles, inactive particles, sand, surface exchange-corrected particles, and mixtures of these and other substances. The Central Cooperative Bureau of the Ministry of Economic Affairs, the Consumer Cooperative, prints fruit and needs to be the first The clump may not be far from the liquid and may be continuous or discontinuous. Furthermore, the second clump may be adjusted to follow a predetermined path from one brother to the other to guide a fluid through the first pellet For example, the second agglomerate may be a thermoplastic polyolefin agglomerate, such as a polypropylene agglomerate. The present invention also provides a paper ruler for preparing co-extruded agglomerate ingredients. 526130 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (9) A method comprising: drying up from an extruder, extruding a mixture containing particles and a honey-binding adhesive M, 1U ... Yu 7 is a model; heat the mixture to _ ^ ^ π, the curing temperature, which is higher than the softening temperature of the thermoplastic adhesive and less than 1 p ~, the softening temperature of the board; force σ in the model t ^ -b 4h ^ hh ^ yv β 9 After the pressure reaches the heated mixture, it is necessary to change the heated mixture to enter a substantially homogeneous composite material; cooling the composite material 5, a temperature, this temperature is low For the softening point of thermoplastic adhesives; and extruding composite materials from the model; improvements include: subsonic, sound oil ►, + & a or super-wave energy plus model and / or squeeze barrel At least one of the two sources, A, B, and Shi, adjusts the frequency and / or amplitude of the source, and adjusts and increases the number of particles and particles according to a method. Or enter a mold from an extruder barrel to extrude a solid ... · ^ adhesive, and extrude the composite material from the mold. Extruding a mixture of particles and a thermoplastic binder to make a multi :: block, referring to this extrusion agglomeration technology, is well known as (for example, U.S. Patent No. 5,1 of K0S10W) 89,092, 5 249 948, 5'331, 037, each of which is incorporated herein by reference). In a nutshell, a mixture of pellets and a thermoplastic adhesive is extruded from an extruder barrel into a mold. The mixture is heated to a temperature that is greater than the softening temperature of the thermoplastic adhesive and less than the softening temperature of the particles. After enough pressure is applied to the heated mixture and changed within the model (please read the precautions on the back first and then this page) —pack. Too —a bite • —B ^ i en ——--mi In m This paper scale towel Closed House Standard (CNS) A4 specification (21GX 297) 526130 A7 --- ~ __ B7 V. Description of the invention (1 0) '~~~-The heated mixture enters a substantially homogeneous composite material. The composite ingredients are cooled to a temperature below the softening point of the thermoplastic adhesive, and • extruded from the mold. A key challenge is the technology for making extruded agglomerates, which includes semi-solid mixture particles and thermoplastic binders, flowing along an extruder and passing through a model. According to the method of the present invention, vibration energy is applied to the extruder and / or mold during manufacturing, increasing the flow of the particulate binder mixture through the extruder and mold. This vibration energy may be applied to an extruder and / or a piezoelectric dielectric device modeled according to techniques well known in the art. Increasing the optimum frequency and amplitude of the mixture flow must vary depending on each device design, manufacturing speed, particle size, binder selection, and manufacturing conditions (such as temperature and pressure). In addition, the most appropriate frequency and amplitude may change over time. Next, a computer-controlled producer was proposed to use the function built in which the feedback L οp was continuously optimized to set the frequency and amplitude model to time. These models change continuously along the length of the extruder and / or different locations of the model, and the frequency range includes subsonic, sonic, and / or ultrasonic vibrations. In this simplest form, the co-extruded agglomerate component pack of the present invention contains a porous first agglomerate and a second agglomerate, a specific example of which is illustrated in Figure 1. In Figure 1, a co-extruded agglomerate component ι0 contains a cylindrical porous first agglomerate and a cylindrical second agglomerate 12 which is also porous. The porous masses "12" are concentric and continuous; the outer surface 13 of the second mass 12 is close to the inner surface of the first mass u. The compound explained in Figure 1 may be made by extruding two different particles. The paper size applies the Chinese National Standard (CNS) Λ4 specification (21〇 × 297 mm) (Please read the precautions on the back first.

經濟部中央標準局員工消費合作社印製 經濟部中央標準局員工消費合作社印製 5|26130 A7 Γ--—_______Β7 五、發明説明(11) 1 ' 結劑混合物通過一個模型,此模型包含兩個同心圓的圓形 開口。 夕孔性第一團塊11舉例來說,可能為活性碳團塊, 此團塊具有一個平均孔洞直徑3微米。多孔性第二團塊12 舉例來說,可能為一個陶瓷顆粒團塊,其具有一個第二平 均孔洞直徑〇·3微米。使用複合物ίο為一個過濾媒介,一 個流體,例如水或空4,可能由多孔性團塊"的外表面進 入媒介並由第二團塊〖2之内表面i 6離開媒介。如果需要, 流體流通成份10的路徑可能為可逆的,此路徑簡單的交換 多孔性團塊1 1和1 2的成份。 以圖一以複合物製成的產品的一個具體實例敘述為 一個水過濾器其外行為中空管,兩個成份形成兩個同心圓 柱體。外圓柱體為一個3微米絕對活性碳團塊過濾,其能 除去第一級氣,味道、以及臭味,第一級鉛,以及第一級 混濁度,其移除原蟲囊胞(例如cyspt〇sp〇ridium ghrdia 囊胞)。内圓柱體是一個〇·3微米絕對陶瓷顆粒團塊過濾 器其移除所有殘留的細菌(水流向中空管過濾器的中心)。 一如果需要,一個第三團塊可能被加入至圖一顯示的複 合物10。一個具有三個團塊的複合物圖示於圖二。在圖二 中 個共擠出團塊成份2 0包含有一個圓柱形多孔性第一 團塊21 ,一個亦為多孔性之圓柱形第二團塊22,以及一 個多孔性圓柱形第三團快23。多孔性團塊21、22、以及 23為同心圓且連續的。第二團塊22的外表面靠近第一團 塊21的内表面25。同樣的,第三團塊23的外表面%靠 冢紙張尺度適财CNS ) Α4“( 210X 297公釐)〜^^ - 14 (請先閱讀背面之注意事項再本頁〕 |裝- 本 5p6l3〇 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明(12) -- 近第一團塊22的内矣而27。 旧丨ΛΙ衣曲2/。圖不於於二的複合物可能已 擠出一種不π顆粒黏結劑混合物通過一個模型而製成,此 模型含有三個同心圓形的開口。 多孔性第一團塊21舉例來說,可能為一個不活潑顆 粒團塊,其具有一個第一平均孔洞直徑5 0微米。多孔性第 二團塊22舉例來說,可能為一個活性碳團塊,其具有一個 第一平均孔洞直杈3微米。多孔性第三團塊23舉例來說, 可能為一個陶瓷顆粒團塊,其具有一個第三平均孔洞直徑 〇·3微米。使用複合物20為一個過濾器媒介,一個流體, 例如水或空氣,可能進入多孔性第一團塊21的外表面而從 第三團塊23的内表面29離開媒介。如果需要,流體流通 複合物20的路徑可以是可逆的,只要交換第一和第三多孔 性團塊21、23的成份即可。 本發明的共擠出團塊成份可能為任何可以過擠出的 外型。圖一和圖二顯示的圓柱形複合物。一個矩形的複合 物顯現於圖三。在圖三中,一個共擠出團塊成份3〇包含有 個矩幵)多孔性第一團塊3 1,一個亦為多孔性的矩形第二 團塊3 2,以及一個多孔性矩形第三團塊。三個多孔性團塊 31 、32、以及33皆是連續的。第二團塊32的外表面34 靠近第一團塊31的餒表面。同樣的,第三團塊33的外表 面Λ近第二團塊32的内表面。使用於製造複合物30的模 型舉例來說,可能包括一個具有三個開口或三個模型並排 放置的單一模型。 做爲一個過濾器媒介,多孔性第一團塊3 1可能具有 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X 297公釐) 15 (請先閱讀背面之注意事項再$本頁) li水. ,1Ti 5β6130 A7 五、發明説明(13) 個相對較大的平均孔洞直徑以及如一個先過濾器之功 厶匕 女 把。多孔性第二團塊3 2可能具有一個第二平均孔洞直徑, 其爲一個中等尺寸或者爲一個中等媒介値。多孔性第三團 塊3 3可能具有一個細微的第三平均孔洞直徑。將複合物 使用於一個空氣過丨慮器,舉裡來説,空氣由多孔性第 一團塊31的外表面38可能進入媒介並從第三團塊33之 内表面39離開媒介。 一個包括一個多孔性第一團塊以及四個額外團塊的 共擠出團塊成份列於圖四。在圖四中,一個共擠出團塊成 伤40包含有一個連續之多孔性第一團塊* 1,並具有一個 弟表面42以及一個第二表面43 。多孔性第一團塊41 舉例來説,可能爲一個活性碳團塊。複合物也包括第二至 第五團塊44、45、46、以及47,每一個皆是非透性且 非連續的。非透性團塊44、45、46、以及47舉例來説, 可能爲聚烯烴,例如聚丙烯,團塊。在圖四中,第二至第 五團塊每一個皆非連續的。因而,團塊44包含有非連續 Μ刀44A、44B。同樣的’團塊45和47分別包含有非連 續部份45Α、45Β以及47Α、47Β。 使用於製備複合物40的模型可能具有一個單—開 口,其放置多數和第二至第五團塊符合的較小開口。第i 至第五團塊可能被賦予非連續的藉由停止和開啟餵入言 類多數較小開口之幫浦。第二至第五團塊可能為相同的: 料。可改變的’最多可能有四種不同的材料可被使用。 因而,圖四肢複合物40為一個石炭團塊過渡器之1 (請先閱讀背面之注意事項再·Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5 | 26130 A7 Γ --——_______ Β7 V. Description of the Invention (11) 1 'The knotting agent mixture passed a model. This model contains two Concentric circular opening. For example, the first porous mass 11 may be an activated carbon mass, and this mass has an average pore diameter of 3 micrometers. The porous second mass 12 may be, for example, a ceramic particle mass having a second average pore diameter of 0.3 m. Using the compound ο as a filter medium, a fluid such as water or air 4 may enter the medium from the outer surface of the porous mass " and leave the medium from the inner surface i 6 of the second mass [2]. If desired, the path of the fluid circulation component 10 may be reversible, and this path simply exchanges the components of the porous masses 11 and 12. A specific example of the product made of composites in Figure 1 is described as a water filter with a hollow tube outside, and two components forming two concentric cylinders. The outer cylinder is a 3 micron absolute activated carbon mass filter that removes first-stage gas, taste, and odor, first-grade lead, and first-order turbidity, which removes protozoan cysts (such as cyspt 〇sp〇ridium ghrdia). The inner cylinder is a 0.3 micron absolute ceramic particle agglomerate filter which removes all remaining bacteria (water flows to the center of the hollow tube filter). -If desired, a third pellet may be added to the complex 10 shown in Figure 1. A complex with three clumps is shown in Figure 2. In FIG. 2, the co-extruded agglomerate component 20 includes a cylindrical porous first agglomerate 21, a cylindrical second agglomerate 22 that is also porous, and a porous cylindrical third agglomerate. twenty three. The porous masses 21, 22, and 23 are concentric and continuous. The outer surface of the second mass 22 is close to the inner surface 25 of the first mass 21. Similarly, the outer surface of the third mass 23 is based on the gravel paper scale CNS) Α4 "(210X 297 mm) ~ ^^-14 (Please read the precautions on the back before this page] | Packing-this 5p6l3 〇 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (12)-Near the first clump 22 and 27. The old 丨 ΛΙ 衣 曲 2 /. A non-π particle binder mixture may have been extruded and made through a mold containing three concentric circular openings. The porous first mass 21 may be, for example, an inactive particulate mass, which It has a first average pore diameter of 50 microns. The porous second mass 22 may be, for example, an activated carbon mass having a first average pore straight 3 microns. Examples of the porous third mass 23 For example, it may be a ceramic particle clump, which has a third average pore diameter of 0.3 micron. Using compound 20 as a filter medium, a fluid such as water or air may enter the porous first clump 21 outer surface from the third ball The inner surface 29 of 23 leaves the medium. If desired, the path of the fluid circulation complex 20 may be reversible, as long as the components of the first and third porous masses 21, 23 are exchanged. The co-extruded mass of the present invention The block composition may be any shape that can be over-extruded. The cylindrical composites shown in Figures 1 and 2. A rectangular composite is shown in Figure 3. In Figure 3, a co-extruded block composition 30 contains There is a moment 幵) a porous first clump 31, a rectangular second clump 3 2 which is also porous, and a porous rectangular third clump. Three porous clumps 31, 32, and 33 They are all continuous. The outer surface 34 of the second mass 32 is close to the condyle surface of the first mass 31. Similarly, the outer surface Λ of the third mass 33 is near the inner surface of the second mass 32. It is used in manufacturing composites For example, the model of object 30 may include a single model with three openings or three models placed side by side. As a filter medium, the porous first mass 3 1 may have this paper size applicable to Chinese national standards ( CNS) Λ4 size (210X 297 mm) 15 ( Read the precautions on the back before you go to this page) Li water., 1Ti 5β6130 A7 V. Description of the invention (13) A relatively large average pore diameter and a dagger handle like a filter. Porosity second The mass 32 may have a second average pore diameter, which is a medium size or a medium medium. The porous third mass 33 may have a fine third average pore diameter. Use the composite for one The air filter, for example, may enter the medium from the outer surface 38 of the porous first mass 31 and leave the medium from the inner surface 39 of the third mass 33. One includes a porous first mass The co-extruded agglomerate composition of the four additional agglomerates is shown in Figure 4. In Fig. 4, a co-extruded mass 40 comprises a continuous porous first mass * 1, and has a younger surface 42 and a second surface 43. The porous first mass 41 may be, for example, an activated carbon mass. The composite also includes second to fifth clumps 44, 45, 46, and 47, each of which is impermeable and discontinuous. The impermeable masses 44, 45, 46, and 47 may, for example, be polyolefins, such as polypropylene, for example. In Figure 4, each of the second to fifth clumps is non-continuous. Therefore, the agglomerates 44 include discontinuous M knives 44A and 44B. The same 'clumps 45 and 47 contain discontinuous portions 45A, 45B and 47A, 47B, respectively. The model used to prepare the composite 40 may have a single-opening, which places smaller openings that mostly conform to the second to fifth clumps. The i-th to fifth clumps may be given discontinuous pumps that feed most of the smaller openings by stopping and opening. The second to fifth clumps may be the same: feed. There may be up to four different materials that can be used. Therefore, the extremity complex 40 in the figure is one of the charcoal briquette transition devices (please read the precautions on the back first, then

-Ur 經濟部中央標準局員工消費合作社印製-Ur Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

526130 A7 B7 五、發明説明(I4) 範例’此過濾器建造於通道之内而引導流體流通,複合物 的一個成份為一個活性碳團塊。其他成份為不透流體的聚 丙烯團塊’其作用為如同障礙物並且引導流體流動。此結 構4加μ體流通進入並通過活性碳團塊的路徑長度,允許 更長的阻礙時間和/或移轉質量,因而改善過濾作用/吸附 作用之效率。 圖五顯示一個圓柱形共擠出團塊成份,其中第二團塊 疋不透泥體的。在圖五中,一個共擠出團塊成份5〇包含 有一個連續微孔第一團塊51 ,其橫切面爲爲螺旋狀並具 有一個外表面52以及一個内部份53。多孔性第一團塊5 i 舉例來説,可能活性碳團塊。此外,複合物5〇包括一個 非透性之連續第二團塊54。第二團塊54舉例來説,可能 爲一個聚丙烯團塊。第二團塊54橫切面也為螺旋狀的並且 和第一團塊5 1成同心圓形。 用於製備複合物50的模型將有兩個同心圓,螺旋狀 開口,第一和第二團塊分別包含其材料。 經濟部中央標準局員工消費合作社印製 導入一個待過濾流體於複合物50之第一團塊5丨外表 面52,流體以一個螺旋路徑朝向第一團塊^之内部份μ 被引導。流體接者從複合物5 〇允許離開。 一個螺旋流體路徑也可能形《,藉由使用一個圖六顯 現的模型。在圖六中,模型60包含有一個第一開口 6: ’以 及-個第二開口 62。第二開口 62具有一個圓形部份Μ以 及一個矩形部份64。一個連續多孔性第—團塊從第—開口 61被擠出,而一個連續、非透性第二團塊從第二開:二 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210x297公楚)---___ 17 526130 A7 -------_B7_ 五、發明説明(1 5) 一一~^ ---- 被擠出。多孔性第—團塊61舉例來說,可能為一個活性碳 團塊,而非透性第二團塊舉例來說,可能為—個聚丙烤團 塊。 第一和第二團塊被擠出進入一個可轉動金屬接受盤 (未列出)其靠近模型。如擠出過程,金屬盤轉動並且漸 漸從模型移開,此移開速度相同於擠出速度。接收盤的轉 動傳授一個螺旋外型至第二團塊,如圖七所示,其中一個 螺旋形狀第二團塊70被圖示。 圖六之模型60的使用造成的一個共擠出團塊成份圖 示於圖八。在圖八中,一個共擠出團塊成份複合物8〇包含 一個連續多孔性第一團塊8丨以及非透性且螺旋狀的一個 連續第二團塊82。如箭頭84所示,一個流體被導入複合 物80的頂表面83。流體接著如箭頭85所示,被引導螺旋 狀的向下。 當説明書藉由特殊的具體實例仔細説明,在了解前述 事項後’這些技術將獲得激賞,並且可以接受這些具體實 例的相同的修正以及改變。 (請先閱讀背面之注意事項再526130 A7 B7 V. Description of Invention (I4) Example ‘This filter is built in a channel to guide the flow of fluid. One component of the compound is an activated carbon mass. The other component is a fluid-impermeable polypropylene mass ' which acts as an obstacle and directs the fluid to flow. This structure 4 plus the length of the path through which the μ-body circulates into and through the activated carbon mass allows longer obstruction times and / or transfer quality, thereby improving the efficiency of filtration / adsorption. Figure 5 shows the composition of a cylindrical co-extruded agglomerate, of which the second agglomerate is impervious to mud. In Fig. 5, a co-extruded agglomerate component 50 includes a continuous microporous first agglomerate 51 whose cross section is spiral and has an outer surface 52 and an inner portion 53. Porous first agglomerates 5 i may be activated carbon agglomerates, for example. In addition, the complex 50 includes an impermeable continuous second mass 54. The second mass 54 may be, for example, a polypropylene mass. The second lump 54 is also helical in cross section and concentric with the first lump 51. The model used to prepare the composite 50 will have two concentric circles, with helical openings, and the first and second masses will each contain its material. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. A fluid to be filtered is introduced into the outer surface 52 of the first mass 5 of the compound 50, and the fluid is guided in a spiral path toward the inner part μ of the first mass ^. The fluid receiver is allowed to leave from the complex 50. A spiral fluid path may also be shaped by using a model shown in Figure 6. In FIG. 6, the model 60 includes a first opening 6: ′ and a second opening 62. The second opening 62 has a circular portion M and a rectangular portion 64. A continuous porous first mass is extruded from the first opening 61, and a continuous, non-permeable second mass is opened from the second: two paper sizes apply the Chinese National Standard (CNS) Λ4 specification (210x297) ) ---___ 17 526130 A7 -------_ B7_ 5. Description of the invention (1 5) One by one ~ ^ ---- Extruded. The porous first mass 61 may be, for example, an activated carbon mass, and the non-permeable second mass may be, for example, a polypropylene baking mass. The first and second masses are squeezed into a rotatable metal receiving pan (not listed) near the model. For example, during the extrusion process, the metal disk rotates and gradually moves away from the mold. The removal speed is the same as the extrusion speed. The rotation of the receiving pan imparts a spiral shape to the second mass, as shown in Fig. 7, in which a spiral-shaped second mass 70 is illustrated. The composition of a co-extruded agglomerate caused by the use of the model 60 in Fig. 6 is shown in Fig. 8. In Fig. 8, a co-extruded agglomerate component complex 80 includes a continuous porous first agglomerate 8 and an impermeable and spiral continuous a second agglomerate 82. As indicated by arrow 84, a fluid is introduced into the top surface 83 of the composite 80. The fluid is then directed downward spirally as indicated by arrow 85. When the specification is carefully explained with special specific examples, after understanding the foregoing matters, these technologies will be rewarded, and they can accept the same amendments and changes to these specific examples. (Please read the notes on the back first

、-r 經濟部中央標準局貝工消費合作社印製, -R Printed by Shellfish Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs

5 26130 A7 B7 五、發明説明(16) 圖示簡單說明 經濟部中央標準局員工消費合作社印製 10 共 擠 出 團 塊 成 份 39 第 團 塊 的 外 表面 11 多 孔 性 第 一 團 塊 40 共擠 出 團 塊 成 份 12 多 孔 性 第 一丨一 團 塊 41 多 孔 性 第 一 團 塊 13 第 一 團 塊 之 外 表 面 42 第 一 表 面 14 第 一 團 塊 之 内 表 面 43 第 二 表 面 15 第 二 團 塊 之 外 表 面 44 第 二 表塊 16 第 團 塊 之 内 表 面 45 第 表塊 20 共 擠 出 團 塊成 份 46 第 四 表塊 21 多 孔 性 第 __ _ 團 塊 47 第 五 表塊 22 多 孔 性 第 —— 團 塊 50 共 擠 出 團 塊 成 份 23 多 孔 性 第 三 團 塊 5 1 第 一 團 塊 24 第 二 團 塊 的 外 表 面 52 外 表 面 25 第 一 團 塊 的 内 表 面 53 内 部 份 26 第 三 團 塊 的 外 表 面 54 第 ——* 團 塊 27 第 二 團 塊 的 内 表 面 60 模 型 28 第 一 團 塊 的 外 表 面 61 第 一 開 a 29 第 團 塊 的 外 表 面 62 第 二 開 a 30 共 擠 出 團 塊 成 份 63 圓 形 部 份 3 1 多 孔 性 第 --- 團 塊 64 矩 形 部 份 32 多 孔 性 第 團 塊 70 螺 旋 形 狀 第 一1 一 團塊 33 多 孔 性 第 團 塊 80 共 擠 出 團 塊成 份 34 第 團 塊 的 外 表 面 81 多 孔 性 第 ,— 團 塊 35 第 一 團 塊 的 内 表 面 8 2 連續 第 二 團 塊 36 第 三 團 塊 的 外 表 面 83 頂 表 面 37 第 二 團 塊 的 内 表 面 84 箭 頭 38 第 一 團 塊 的 外 表 面 85 箭 頭 (請先閱讀背面之注意事項再5 26130 A7 B7 V. Description of the invention (16) The diagram briefly illustrates the printing by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 10 Co-extruded agglomerate composition 39 The outer surface of the agglomerate 11 Porous first agglomerate 40 Co-extrusion Agglomerate composition 12 Porous first 丨 One agglomerate 41 Porous first agglomerate 13 Outer surface of the first agglomerate 42 First surface 14 Inner surface of the first agglomerate 43 Second surface 15 Out of the second agglomerate Surface 44 Second table block 16 Inner surface of block 45 Table block 20 Co-extruded block composition 46 Fourth block 21 Porosity __ _ Block 47 Fifth Table block 22 Porosity-Group Block 50 Co-extruded block composition 23 Porous third block 5 1 First block 24 Outer surface of second block 52 Outer surface 25 Inner surface of first block 53 Internal portion 26 Third block Outer surface 54 The first-* lump 27 The inner surface of the second lump 60 Model 28 The first lump Outer surface of block 61 First open a 29 Outer surface of second block 62 Second open a 30 Co-extruded agglomerate component 63 Round part 3 1 Porous No. --- Agglomerate 64 Rectangular part 32 Porosity The first lump 70 spiral shape 1 the first lump 33 the porous lump 80 co-extruded briquette component 34 the outer surface of the lump 81 the porosity,-the lump 35 the inner surface of the first lump 8 2 Second continuous mass 36 Outer surface of third mass 83 Top surface 37 Inner surface of second mass 84 Arrow 38 Outer surface of first mass 85 Arrow (Please read the precautions on the back first

呑< 本紙張尺度適用中國國家標準(CNS ) Λ4規格(21 OX 297公釐) 19呑 & This paper size applies to Chinese National Standard (CNS) Λ4 specification (21 OX 297 mm) 19

Claims (1)

526130 A8 B8 C8 D8 六、申請專利範圍 6、 如申請專利範圍第3項之共擠出團塊複合物,其進一 步包括一個第三團塊,其 (請先閱讀背面之注意事項再填寫本頁) 為可透流體的; 包含有一個顆粒成份以及一個熱塑性黏結劑成 份;以及 具有彼此連接孔洞,其具有一個第三平均直徑; 其中至少第三團塊的一個部份靠近第一或第二團 塊至少一個部份。 7、 如申請專利範圍第6項之共擠出團塊複合物,其中調整 第一、第二、以及第三平均直徑而提供共擠出團塊一個 漸層的孔洞結構。 8、 如申請專利範圍第6項之共擠出團塊複合物,其中第 三團塊之顆粒成份選自活性碳,陶瓷顆粒,沸石顆 粒,不活潑顆粒,砂子,表面交換-修正顆粒,以及 其混合物等物質。 9、 如申請專利範圍第6項之共擠出團塊複合物,其中進一 步包含一個第四團塊,其 為可透流體的; 經濟部智慧財產局員工消費合作社印製 包含有一個顆粒成份以及一個熱塑性黏結劑成份; 以及 具有彼此連接孔洞,其具有一個第四平均直徑; 其中第四團塊至少一個部份靠近第一、第二、以及第 三團塊的至少一個部份。 1 〇、如申請專利範圍第9項之共擠出團塊複合物,其中調 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) C:\ Eunice\PK-001-03\PK-00l-0372\PK-00l-0372-cln-chi-2.doc 21 526130 A8 B8 C8 D8 六、申請專利範圍 整第一、第二、第三、以及第四平均直徑而提供共擠出 團塊一個漸層孔洞結構。 11、如申請專利範圍第9項之共擠出團塊複合物,其中第 四團塊的顆粒成份選自活性碳,陶瓷顆粒,沸石顆 粒,不活潑顆粒,砂子,表面交換·-修正顆粒,以及其 混合物等物質。 1 2、如申請專利範圍第1項之共擠出團塊複合物,其中第 二團塊為可透流體的。 1 3、如申請專利範圍第1 2項之共擠出團塊複合物,其中 第二團塊是連續的。 14、如申請專科範圍第1 2項之共擠出團塊複合物,其中 第二團塊非連續的。 1 5、如申請專利範圍第1 2項之共擠出團塊複合物,其中 第二團塊為一個熱塑性聚烯烴圑塊。 1 6、如申請專利範圍第1 5項之共擠出團塊複合物,其中 熱塑性聚烯烴團塊為一個聚丙烯團塊。 1 7、如申請專利範圍第1 2項之共擠出團塊複合物,其中 第二團塊為一個熱塑性聚烯烴團塊。 1 8、如申請專利範圍第1 7項之共擠出圑塊複合物,其中 熱塑性聚烯烴團塊為一個聚丙烯團塊。 1 9、一種製造共擠出團塊複合物的方法,其包括: 從一個擠出器桶擠出一個含有許多顆粒以及一個熱塑 性黏結劑之混合物至一個模型; 加熱混合物至一個溫度,此溫度大於熱塑性黏結劑的 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 22 C: \ Eunice. \ ΡΚ-00Ί-03 \ ΡΚ-00Ί-0372\ ΡΚ-00Ί-0372-dn-chi-2.doc (請先閱讀背面之注意事項再填寫本頁)526130 A8 B8 C8 D8 6. Scope of patent application 6, such as the co-extruded agglomerate compound of item 3 of the patent application, which further includes a third agglomerate, (Please read the precautions on the back before filling this page ) Is fluid permeable; contains a particulate component and a thermoplastic adhesive component; and has interconnected holes having a third average diameter; wherein at least a portion of the third mass is close to the first or second mass Block at least one part. 7. The co-extruded agglomerate composite as described in item 6 of the patent application, wherein the first, second, and third average diameters are adjusted to provide a co-extruded agglomerated hole structure. 8. If the co-extruded agglomerate composite of item 6 of the patent application, wherein the particle composition of the third agglomerate is selected from activated carbon, ceramic particles, zeolite particles, inactive particles, sand, surface exchange-corrected particles, and Its mixtures and other substances. 9. For example, the co-extruded agglomerate complex of item 6 of the patent application, which further includes a fourth agglomerate, which is permeable to fluids; printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, which contains a granular component and A thermoplastic adhesive component; and having interconnected holes having a fourth average diameter; wherein at least a portion of the fourth agglomerate is adjacent to at least a portion of the first, second, and third agglomerates. 1 〇 As for the co-extruded agglomerate compound in item 9 of the scope of patent application, the paper size is adjusted to Chinese National Standard (CNS) A4 (210 X 297 mm) C: \ Eunice \ PK-001-03 \ PK-00l-0372 \ PK-00l-0372-cln-chi-2.doc 21 526130 A8 B8 C8 D8 VI. Apply for patents covering the first, second, third, and fourth average diameters to provide coextrusion A clumped hole structure. 11. If the co-extruded agglomerate composite of item 9 of the patent application range, wherein the particle composition of the fourth agglomerate is selected from activated carbon, ceramic particles, zeolite particles, inactive particles, sand, surface exchange · corrected particles, And their mixtures. 1 2. The co-extruded agglomerate compound as described in the first patent application, wherein the second agglomerate is fluid permeable. 13 3. The co-extruded agglomerate compound as described in item 12 of the patent application, wherein the second agglomerate is continuous. 14. For the co-extruded agglomerate complex of item 12 of the application scope, in which the second agglomerate is discontinuous. 15. The co-extruded agglomerate compound according to item 12 of the patent application scope, wherein the second agglomerate is a thermoplastic polyolefin agglomerate. 16. The co-extruded agglomerate compound according to item 15 of the patent application scope, wherein the thermoplastic polyolefin agglomerate is a polypropylene agglomerate. 17. The co-extruded agglomerate compound according to item 12 of the patent application scope, wherein the second agglomerate is a thermoplastic polyolefin agglomerate. 18. The co-extruded agglomerate composite as described in item 17 of the patent application, wherein the thermoplastic polyolefin agglomerate is a polypropylene agglomerate. 19. A method of manufacturing a co-extruded agglomerate composite, comprising: extruding a mixture containing a plurality of particles and a thermoplastic binder from a extruder barrel to a mold; heating the mixture to a temperature greater than The paper size of the thermoplastic adhesive is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 22 C: \ Eunice. \ ΡΚ-00Ί-03 \ ΡΚ-00Ί-0372 \ ΡΚ-00Ί-0372-dn- chi-2.doc (Please read the notes on the back before filling out this page) 526130 A8B8C8D8 六、申請專利範圍 20 21 22 痤齊Srlnr慧讨查01?員11肖費6W0乍‘土中鞮 23 軟化溫度’並小於顆粒的軟化溫度; 在模型内施加足夠後壓力至加熱過的混合 .L 旳轉化力c 熱過的混合物成一個實質上均質的複合材料,· 冷卻複合成份至一個溫度低於熱塑性黏 w的軟化 點;以及 從模型擠出複合材料; 其中改進處包括: 以次音波、音波、或超音波能源激發模型和/或擠 器桶至少一位置,這些能源之頻率和/或振幅依照j 個方法以便增加從一個擠出器桶進入一個模型的 粒混合物的擠出以及一個熱塑性黏結劑的擠出以及 從模型播出複合材料而加以改變。 一種過濾器媒介,其包含申請專利範圍第 不i貝之共擠 出團塊複合物。 一種過濾器媒介 出團塊複合物。 一種過濾器媒介 出團塊複合物。 一種過濾器媒介 出團塊。 其包含申請專利範圍第2項之共 其包含申請專利範圍第6項之共: 其包含申請專利範圍第9項之共; 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -- 2 3 °^Eumce^p^-001-03\ΡΚ-00Ί-0372\PK-001-0372-dn-chi-2.doc —丨· !!裝 i I (請先閱讀背面之注意事項再填寫本頁} 訂-526130 A8B8C8D8 VI. Application for patent scope 20 21 22 Acrylic Srlnr Hui to investigate 01 member 11 Xiao Fei 6W0 'soil in the soil 23 softening temperature' and less than the softening temperature of the particles; after applying enough pressure in the model to the heated Mixing. L 旳 conversion force c The heated mixture into a substantially homogeneous composite material, cooling the composite component to a softening point below the thermoplastic viscosity; and extruding the composite material from the model; improvements include: Subsonic, sonic, or ultrasonic energy sources excite the model and / or the extruder barrel at least one position. The frequency and / or amplitude of these energy sources are in accordance with j methods to increase the extrusion of the pellet mixture from an extruder barrel into a model. And the extrusion of a thermoplastic adhesive and the composite material being broadcast from the mold. A filter medium comprising a co-extruded agglomerate complex in the scope of patent application. A filter medium produces agglomerates. A filter medium produces agglomerates. A filter medium produces clumps. It contains the total of the scope of the patent application No. 2 It contains the total of the scope of the patent application No. 6: It includes the total of the scope of patent application No. 9; This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) )-2 3 ° ^ Eumce ^ p ^ -001-03 \ ΡΚ-00Ί-0372 \ PK-001-0372-dn-chi-2.doc — 丨 !! Install i I (Please read the note on the back first Matters refill this page} Order-
TW85115119A 1996-04-10 1996-12-06 Coextruded block and filter medium and application therefor TW526130B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US57501096A 1996-04-10 1996-04-10

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