JP4299522B2 - Water purifier cartridge and water purifier - Google Patents

Water purifier cartridge and water purifier Download PDF

Info

Publication number
JP4299522B2
JP4299522B2 JP2002287563A JP2002287563A JP4299522B2 JP 4299522 B2 JP4299522 B2 JP 4299522B2 JP 2002287563 A JP2002287563 A JP 2002287563A JP 2002287563 A JP2002287563 A JP 2002287563A JP 4299522 B2 JP4299522 B2 JP 4299522B2
Authority
JP
Japan
Prior art keywords
water
filter medium
water purifier
cartridge
main body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2002287563A
Other languages
Japanese (ja)
Other versions
JP2004121937A5 (en
JP2004121937A (en
Inventor
昌彦 種池
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Chemical Corp
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp, Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Chemical Corp
Priority to JP2002287563A priority Critical patent/JP4299522B2/en
Publication of JP2004121937A publication Critical patent/JP2004121937A/en
Publication of JP2004121937A5 publication Critical patent/JP2004121937A5/ja
Application granted granted Critical
Publication of JP4299522B2 publication Critical patent/JP4299522B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D24/00Filters comprising loose filtering material, i.e. filtering material without any binder between the individual particles or fibres thereof
    • B01D24/02Filters comprising loose filtering material, i.e. filtering material without any binder between the individual particles or fibres thereof with the filter bed stationary during the filtration
    • B01D24/04Filters comprising loose filtering material, i.e. filtering material without any binder between the individual particles or fibres thereof with the filter bed stationary during the filtration the filtering material being clamped between pervious fixed walls
    • B01D24/08Filters comprising loose filtering material, i.e. filtering material without any binder between the individual particles or fibres thereof with the filter bed stationary during the filtration the filtering material being clamped between pervious fixed walls the filtering material being supported by at least two pervious coaxial walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/18Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/024Hollow fibre modules with a single potted end
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • C02F9/20Portable or detachable small-scale multistage treatment devices, e.g. point of use or laboratory water purification systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/14Specific spacers
    • B01D2313/143Specific spacers on the feed side
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/44Cartridge types
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • C02F2201/006Cartridges

Description

【0001】
【発明の属する技術分野】
本発明は、水道水やその他の原水中に含まれる塩素や臭気原因物質、有害物質等を除去することにより、おいしく安全な水を供給するための浄水器用カートリッジ及び浄水器に関するものである。
【0002】
【従来の技術】
安全な水を供給するために、水道水には殺菌用の塩素添加が義務付けられている。そのために、水道水が雑菌により汚染される懸念は少ないものの、カルキ臭により水の味は損なわれてしまう。また、この塩素と水道水中に含まれるフミン質などの有機物質と反応することにより、発ガン性を有するトリハロメタンが水道水中に生成されることも確認されている。そして、近年の河川、湖沼の汚染等により、これらを原水とする水道水中には、2―メチルイソボルネオールのようなカビ臭原因物質が微量成分として含まれていることも確認されている。
【0003】
また水道水の配水に使用される配管に鉛管が使用されている場合、水道水の滞留、pH等により鉛管より溶解性の鉛が溶出し、この鉛を摂取した場合、人の健康を害することが分かってきた。これらの水の味を損ねる物質、有機物質及び有害物質等を除去するための浄水器が広く使用されている(例えば、特許文献1参照)。
【0004】
【特許文献1】
特開2001−353486号公報
また、この他にも、多様な形態の浄水器が使用されている。
【0005】
図7は、従来の浄水器用カートリッジの断面図である。原水は、図中矢印に示すように、入水部103より供給され、粒状濾過材107が入水部103側に移動するのを防止するための部材であり、水は通過させるが粒状濾過材107は通過させないように構成された目皿105を通った後、粒状濾過材107の中を通過する。その後、粒状濾過材107の圧力損失によって、水は集水管108の根元部108a付近を通過、中空糸膜モジュール106を通過した後、浄化された濾過水が出水部104から得られる。
【0006】
図8は、従来の浄水器用カートリッジの別の例を示す断面図である。このカートリッジは、中子上蓋216に中空糸膜モジュール206、プレフィルタ217を取りつけ、その間に粒状濾過材207を詰め中子下蓋218によって密封されたものを、上蓋215に取り付け、本体容器201によって密封されている。原水は、入水部203より供給され、プレフィルタ217と本体容器201の間に設けられた隙間を通過した後、プレフィルタ217の内側に配置した中空糸膜モジュール206方向に向かって流れ、浄化された濾過水が出水部204から得られる。
【0007】
図9は、従来の浄水器用カートリッジのもう一つ別の例を示す断面図である。このカートリッジは、外部スペーサ309に集水管308を取り付け、その間に粒状濾過材307を詰め濾過材押さえ板320を入れ、さらに不織布322を入れた後、外部スペーサ蓋321によって密封したものに、中空糸膜モジュール306を取り付け、これらを本体容器301に挿入し、底蓋302を装着したものからなっている。原水は、入水部303より供給され、外部スペーサ309の下部より、底蓋302と外部スペーサ309の間に設けられた隙間を通過した後、外部スペーサ309側面周辺部より、粒状濾過材307、集水管308を通過し、浄化された濾過水が出水部304から得られる。
【0008】
【発明が解決しようとする課題】
しかしながら、図7に示した従来例では、集水管108の根元部108a付近の粒状濾過材107まで圧力損失によって水が通過しづらく、粒状濾過材107を満遍なく有効利用することができず、目的とする除去性能が得られなかったり、不必要にカートリッジ形状が大きくなったりする不具合が生じる。
【0009】
また、図8に示した従来例では、中空糸膜モジュール根元部219付近の粒状濾過材207は有効に利用されることが無く、目的とする除去性能を得るための粒状濾過材207を不必要に使用しなければならず、工業生産的に不利である。不必要である中空糸膜モジュール根元部219付近の粒状濾過材7を無くしてしまうと、この個所に集中して水が流れ、いわゆるショートパス現象を引き起こし、目的とする除去性能が得られない。そして、この構造に起因して、プレフィルタ217の内側に配置した中空糸膜モジュール206との距離を均一にすることは極めて困難であるため、ここでもショートパス現象により粒状濾過材207を有効に利用することができない。また、構造が複雑であるため、製造工数及び部材点数が多くコストがかかり工業生産的に不利である。
【0010】
また、図9に示した従来例においても、集水管根元部308a付近の粒状濾過材307は有効に利用されることが無く、目的とする除去性能を得るための粒状濾過材307を不必要に使用しなければならず、工業生産的に不利である。この集水管根元部308a付近の粒状濾過材307を極力有効に利用するために、濾過材押さえ板320及び粒状濾過材307のばらつきを吸収するための不織布22を入れることでばらつき防止を図っているが、構造が複雑であるため、製造工数及び部材点数が多くコストがかかり工業生産的に不利である。
【0011】
また、粒状の濾過材を使用した浄水器の場合、浄水器用カートリッジのコンパクト化及び除去性能の向上の要求により、高除去性能の物が望まれており、そのため比表面積の大きい、水との接触時間が長い、粒径の小さな濾過材が使用されてきている。
【0012】
しかしながら、高除去性能を求めるため、濾過材の粒径を小さくしていくと、水の圧力損失が増大し、流量低下を招いてしまう。流量低下を招かないためには、濾過材粒度を大きくして、量を増やす方法が挙げられるが、これでは浄水器用カートリッジが大きくなってしまう問題が生じてしまう。
【0013】
また、水の流入する濾過材部の断面積を大きくとることにより、流量低下を招かない方法も挙げられるが、これでも径方向に浄水器用カートリッジが大きくなってしまう問題が生じてしまう。
【0014】
本願発明は、上記の問題を解決するためになされたものであり、簡便な構成で、粒状濾過層の有効利用とコンパクトな浄水器用カートリッジ及び浄水器を提供することを目的とする。
【0015】
【課題を解決するための手段】
上記目的を達成するため、本発明の浄水器用カートリッジは、本体容器に濾過材を備えてなる浄水器用カートリッジにおいて、流体は通過させるが濾過材は通過させないシートが配置されており、前記シートと前記本体容器の内壁面との間に、流体が通過可能であって内部に前記濾過材を有しない間隙を形成している
【0017】
また、本発明の浄水器用カートリッジは、シートが、メッシュ、繊維状シート、不織布、フェルトのいずれかであってもよい。
【0018】
また、本発明の浄水器用カートリッジは、分流手段内の濾過材を通過してきた流体を本体容器内に収納されている中空糸膜モジュールへと流入させる流入手段を分流手段内に有するものであってもよい。
【0019】
また、本発明の浄水器用カートリッジは、濾過材が、外周面に開口部を有する外部スペーサの内部に保持されており、シートは、外部スペーサの開口部の外周面側又は内周面側のいずれか一方に、接着又は融着されているものであってもよい。
【0020】
また、本発明の浄水器用カートリッジは、シート外部スペーサとが一体成形されているものであってもよい。
【0021】
また、本発明の浄水器用カートリッジは、外部スペーサの上流側に、さらに、成形濾過材を設けているものであってもよい。
また、本発明の浄水器は、本発明の浄水器用カートリッジを用いたものである。
【0022】
【発明の実施の形態】
次に、本発明の実施の形態について図面を参照して説明する。
(第1の実施形態)
図1は、本実施形態の浄水器用カートリッジの一実施形態を示す断面図である。
【0023】
本体容器1の一端面側に浄化すべき原水の流入口である入水部3、および浄化された濾過水が排出される出水部4が設けられており、他端面側には底蓋2がOリングでシールされて着脱可能に装着されている。
【0024】
本体容器1内には、粒状濾過材7の入水部3側への移動を防止し、かつ、水は通過させるが粒状濾過材7は通過させないように構成された部材である目皿5と、本体容器1の内壁面1aとの間に間隙1bを形成し、粒状濾過材7を保持する外部スペーサ9と、中空糸膜モジュール6を保持する保持容器6aと、外部スペーサ9内の粒状濾過材7を通過した水を集水し、保持容器6aへと流入させる集水管8とが設けられている。
【0025】
図2に本実施形態の外部スペーサの側面図を、図3および図4に本体容器に装着された状態の外部スペーサ近傍の一部拡大図をそれぞれ示す。なお、図3の外部スペーサは、図2のA−A線における断面を、また、図4は、図2のB−B線における断面を示している。
【0026】
本体容器1への装着方向に窄まるテーパを有する略円筒形状の外部スペーサ9は、その両端にOリングを装着可能な溝9c、9dがそれぞれ形成されたリング部9a、9bと、このリング部9a、9bに対して一体的に形成されたシート保持部9fと、シート保持部9fに接着あるいは融着された、水は通過させるが粒状濾過材7は通過させないシート14とを有する。
【0027】
シート保持部9fの外径は、リング部9a、9bに比べて小さくなっており、外部スペーサ9を本体容器1に装着した際、リング部9a側でシート保持部9fの外周と本体容器1の内壁面1aとの間に隙間Laの間隙1bが形成され、一方、リング部9b側で隙間Lbの間隙1bが形成される。なお、隙間La、Lbは同じであってもよいし、あるいは、必要に応じて異なる値とするものであってもよい。なお、これら隙間La、Lbは本体容器1の内壁面1aからシート保持部9fの外周までの距離であり、本体容器1の内壁面1aからシート14の表面までの距離は、図4に示すように概ねLcとなる。
【0028】
外部スペーサ9は、本体容器1に装着される際、リング部9bの端部に形成されたフランジ部9eが本体容器1の端面1cに当接して位置決めされる。外部スペーサ9は、本体容器1に装着されると、リング部9a、9bが本体容器1の内壁面1aに内接し、溝9c、9dに取り付けられたOリングによりリング部9a、9bと内壁面1aとの間は密封される。
【0029】
この浄水器の製造工程において、一方が開放した筒状の本体容器1の開放部側を上にし、目皿5、中空糸膜モジュール6、集水管8、外部スペーサ9を挿入した状態で、本体容器1の開放上部から粒状濾過材7を投入充填する。本体容器1の形状は必ずしも限定はされず、例えば多角柱状や円錐台状等の形状とすることも可能であるが、円筒形状とすると、耐圧性や成形性が向上し、かつ外部スペーサ9から集水管8の距離が等しく取れるのでより好ましい。
【0030】
本体容器1と底蓋2との結合方法は必ずしも限定はされず、両部材に穴を開けてボルトを通して結合する方法等を用いることができるが、両部材に雄ネジ/雌ネジを形成して嵌合する方法が、部品点数を少なくできるため好ましい。何れの結合方法であっても、粒状濾過材7のネジ部噛み込みによる嵌合不良を防止するために、粒状濾過材7を投入後、その上部に不織布12を載せた上で底蓋2を嵌合させることが好ましい。
【0031】
次に、以上のような構成の本実施形態の浄水器における水の流れ方について説明する。
【0032】
まず、原水は、入水部3より供給され、目皿5を通った後、粒状濾過材7の中を通過する。
【0033】
その後、図5の粒状濾過材を流れる水の拡大断面図で示すように、外部スペーサ入口部9gまで通過してきた水は、粒状濾過材7の粒径及び外部スペーサ入口部9g開口面積に起因する圧力抵抗によって、外部スペーサ9内の粒状濾過材7を流れる内層流10と外部スペーサ9と本体容器1との間に設けられた間隙1bを通過した後、再び外部スペーサ9内の粒状濾過材7を流れる外層流11に分流される。
【0034】
分流された内層流10と外層流11は、本体容器1の同心中央部に設けられた集水管8を通過した後、中空糸膜モジュール6を通過し、浄化された濾過水が出水部4から得られる。
【0035】
このように原水を、外部スペーサ入口部9gにて内層流10と外層流11に分流することにより、外部スペーサ内部の粒状濾過材7を流れる水は、外部スペーサ入口部9gから集水管根元部8aの間には内層流10が流れ、集水管8の中央部から集水管端部8bの間にかけては外層流11が流れ込むことによって、粒状濾過材7は満遍なく有効利用され、水の味を損ねる物質、有機物質及び有害物質等の除去性能を高めることができる。
【0036】
内層流10と外層流11に分流の効果は、本体容器1の配置方向には制限されず、垂直、水平及び斜め方向の何れの場合でも効果がある。また垂直方向の場合において、原水が入水部3より供給される際、原水の流れる方向が垂直上方向であっても垂直下方向の何れであっても効果がある。
【0037】
原水を、外部スペーサ入口部9gにて内層流10と外層流11に分流を引き起こされるの要因の一つとして挙げられるのは、粒状濾過材7の粒径によってである。粒状濾過材7の粒径は、#20〜#200メッシュの範囲であればよく、#30〜#180メッシュの範囲が好ましく、#40〜150メッシュの範囲がより好ましい。
【0038】
本発明の浄水器に用いられる、外部スペーサ9と本体容器1との間に設けられた隙間を作るためのシート14は、メッシュ、接着または融着した繊維状シート、不織布、フェルトなどが例示でき、望ましいのは、メッシュ、接着または融着した繊維状シート、不織布が挙げられる。
【0039】
本発明の浄水器に用いられる粒状濾過材7としては、粉末状活性炭、粒状活性炭、分子吸着樹脂、ゼオライト、モレキュラーシーブ、キレート樹脂、イオン交換樹脂、亜硫酸カルシウム、コーラルサンド、麦飯石、医王石、トルマリンなどが例示でき、これらのうちの1種、あるいは2種以上を用いて使用する方法が挙げられる。望ましくは、粉末状活性炭、粒状活性炭、ゼオライト、モレキュラーシーブ、イオン交換樹脂、亜硫酸カルシウム、これらのうちの1種、あるいは2種以上を用いることで、特に望ましいのは、粉末状活性炭、粒状活性炭を用いる場合である。
【0040】
この中空糸膜を使用する場合、中空糸膜モジュール6の素材としては特に制限はないが、セルロース系、ポリオレフィン(ポリエチレン、ポリプロピレン)系、ポリビニリデンフロライド(PVDF)、ポリビニルアルコール系、エチレン・ビニルアルコール共重合体、ポリエーテル系、ポリメタクリル酸メチル(PMMA)系、ポリスルフォン系、ポリアクリロニトリル系、ポリ四弗化エチレン(PTFE)系、ポリカーボネイト系、ポリエステル系、ポリアミド系、芳香族ポリアミド系等の各種材料が挙げられる。望ましくは、ポリオレフィン(ポリエチレン、ポリプロピレン)系、ポリビニリデンフロライド(PVDF)を用いることができ、特に望ましくは、ポリオレフィン(ポリエチレン、ポリプロピレン)系を用いる場合である。
【0041】
本発明の浄水器を構成する本体容器は、コスト、成形加工性を考慮すると、ABS樹脂、AS樹脂、PP樹脂、PE樹脂、ポリカーボネイト樹脂等のプラスチックで構成することが好ましい。肉厚は、耐圧性を考慮し3mm以上が好ましい。
(第2の実施形態)
図6に本実施形態の浄水器用カートリッジの側断面図を示す。
【0042】
本実施形態の浄水器用カートリッジは、水の味を損ねる物質、有機物質及び有害物質等の除去性能を高める目的として、粒状濾過材7の前段に成型状濾過材13が配置されている。なお、本実施形態の浄水器用カートリッジは、成型状濾過材13が設けられた以外の構成は、第1の実施形態で説明した浄水器用カートリッジと同じである。よって、以下の説明では第1の実施形態と同じ符号を用いるものとする。
【0043】
成型状濾過材13は、粉末活性炭、粒状活性炭、繊維状活性炭、イオン交換繊維、ゼオライト、モレキュラーシーブ、キレート樹脂、イオン交換樹脂、亜硫酸カルシウム、コーラルサンド、麦飯石、医王石、トルマリンなどが例示でき、これらのうちの1種、あるいは2種以上を用いて成型し使用する方法が挙げられる。
【0044】
望ましくは、粉末活性炭、粒状活性炭、繊維状活性炭、イオン交換繊維、ゼオライト、モレキュラーシーブ、キレート樹脂、イオン交換樹脂、亜硫酸カルシウム、これらのうちの1種、あるいは2種以上を用いて成型し使用することで、特に望ましいのは、粉末活性炭、粒状活性炭、繊維状活性炭、イオン交換繊維である。
【0045】
本実施形態においても、第1の実施形態と同様に、水は内層流10と外層流11とに分流され、粒状濾過材7は満遍なく有効利用され、水の味を損ねる物質、有機物質及び有害物質等の除去性能を高めることができる。
【0046】
【発明の効果】
本発明によると、筒状の本体容器に濾過材を配した浄水器用カートリッジにおいて、濾過材を通過する流体の流れを、粒状の濾過材の粒径及び外部スペーサ入口部の開口面積に起因する圧力抵抗により少なくとも2方向以上に分流させることによって、濾過材全体を満遍なく有効利用しながら流量低下を招かない。
【図面の簡単な説明】
【図1】本発明に係る第1の実施形態の浄水器用カートリッジの一例を示す断面図である。
【図2】本発明に係る第1の実施形態の外部スペーサの外観図である。
【図3】本体容器への外部スペーサの装着状態を示す、浄水器用カートリッジの一部拡大図である。
【図4】本体容器とシート材との間に形成された間隙を示す、浄水器用カートリッジの一部拡大図である。
【図5】粒状濾過材を流れる水の拡大断面図である。
【図6】本発明に係る第2の実施形態の浄水器用カートリッジの一例を示す断面図である。
【図7】従来の浄水器用カートリッジの一例を示す断面図である。
【図8】従来の浄水器用カートリッジの一例を示す断面図である。
【図9】従来の浄水器用カートリッジの一例を示す断面図である。
【符号の説明】
1 本体容器
1a 内壁面
1b 間隙
1c 端面
2 底蓋
3 入水部
4 出水部
5 目皿
6 中空糸膜モジュール
6a 保持容器
7 粒状濾過材
8 集水管
8a 集水管根元部
8b 集水管端部
9 外部スペーサ
9a、9b リング部
9c、9d 溝
9e フランジ部
9f シート保持部
9g 外部スペーサ入口部
10 内層流
11 外層流
12 不織布
13 成型状濾過材
14 シート
22 不織布
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a water purifier cartridge and a water purifier for supplying delicious and safe water by removing chlorine, odor-causing substances, harmful substances, and the like contained in tap water and other raw water.
[0002]
[Prior art]
In order to supply safe water, tap water is obliged to add sterilizing chlorine. For this reason, although there is little concern that tap water is contaminated by various germs, the taste of water is impaired by the odor of lime. It has also been confirmed that carcinogenic trihalomethane is produced in tap water by reacting with chlorine and organic substances such as humic substances contained in tap water. And due to pollution of rivers and lakes in recent years, it has been confirmed that tap water using these as raw water contains a mold odor-causing substance such as 2-methylisoborneol as a trace component.
[0003]
In addition, when lead pipes are used in pipes used to distribute tap water, soluble lead elutes from the lead pipes due to stagnation of the tap water, pH, etc., and if this lead is ingested, human health may be impaired. I understand. Water purifiers for removing these substances that impair the taste of water, organic substances and harmful substances are widely used (see, for example, Patent Document 1).
[0004]
[Patent Document 1]
JP, 2001-353486, A In addition to this, various forms of water purifiers are used.
[0005]
FIG. 7 is a cross-sectional view of a conventional water purifier cartridge. As shown by the arrows in the figure, the raw water is supplied from the water inlet 103 and is a member for preventing the granular filter medium 107 from moving to the water inlet 103 side. After passing through the eye plate 105 configured not to pass, it passes through the granular filter medium 107. Thereafter, due to the pressure loss of the particulate filter 107, the water passes through the vicinity of the root portion 108 a of the water collection pipe 108, passes through the hollow fiber membrane module 106, and then purified filtered water is obtained from the discharge portion 104.
[0006]
FIG. 8 is a cross-sectional view showing another example of a conventional water purifier cartridge. In this cartridge, a hollow fiber membrane module 206 and a pre-filter 217 are attached to a core upper lid 216, and a granular filter material 207 is packed between them and sealed by a core lower lid 218. Sealed. The raw water is supplied from the water inlet 203, passes through a gap provided between the prefilter 217 and the main body container 201, and then flows toward the hollow fiber membrane module 206 disposed inside the prefilter 217 to be purified. The filtered water is obtained from the water outlet 204.
[0007]
FIG. 9 is a cross-sectional view showing another example of a conventional water purifier cartridge. In this cartridge, a water collecting pipe 308 is attached to an external spacer 309, a particulate filter medium 307 is packed between them, a filter medium pressing plate 320 is inserted, a nonwoven fabric 322 is further inserted, and then sealed with an external spacer lid 321. The membrane module 306 is attached, these are inserted into the main body container 301, and the bottom lid 302 is attached. The raw water is supplied from the water inlet 303, passes through a gap provided between the bottom lid 302 and the outer spacer 309 from the lower part of the outer spacer 309, and then collects the granular filter material 307 and the collecting material from the peripheral part of the side surface of the outer spacer 309. The filtered water that has passed through the water pipe 308 and has been purified is obtained from the water outlet 304.
[0008]
[Problems to be solved by the invention]
However, in the conventional example shown in FIG. 7, it is difficult for water to pass through to the granular filter medium 107 near the root portion 108a of the water collecting pipe 108 due to pressure loss, and the granular filter medium 107 cannot be effectively used evenly. In this case, the removal performance cannot be obtained, or the cartridge shape becomes unnecessarily large.
[0009]
Further, in the conventional example shown in FIG. 8, the particulate filter material 207 in the vicinity of the hollow fiber membrane module base 219 is not effectively used, and the particulate filter material 207 for obtaining the desired removal performance is unnecessary. This is disadvantageous in terms of industrial production. If the unnecessary particulate filter material 7 in the vicinity of the root portion 219 of the hollow fiber membrane module is eliminated, water flows concentrating on this portion, causing a so-called short path phenomenon, and the intended removal performance cannot be obtained. Due to this structure, it is extremely difficult to make the distance from the hollow fiber membrane module 206 arranged inside the pre-filter 217 very uniform. It cannot be used. Moreover, since the structure is complicated, the number of manufacturing steps and the number of members are large, which is disadvantageous in terms of industrial production.
[0010]
In the conventional example shown in FIG. 9 as well, the granular filter medium 307 in the vicinity of the water collecting pipe root portion 308a is not effectively used, and the granular filter medium 307 for obtaining the desired removal performance is unnecessary. It must be used, which is disadvantageous for industrial production. In order to utilize the granular filter material 307 near the water collecting pipe root portion 308a as effectively as possible, the non-woven fabric 22 for absorbing the dispersion of the filter material pressing plate 320 and the granular filter material 307 is inserted to prevent variation. However, since the structure is complicated, the number of manufacturing steps and the number of members are large, which is disadvantageous in industrial production.
[0011]
In addition, in the case of a water purifier using a granular filter medium, a product with high removal performance is desired due to the demand for compactness of the cartridge for water purifier and improvement of removal performance. Therefore, contact with water with a large specific surface area is desired. Filter media with long particle sizes and small particle sizes have been used.
[0012]
However, if the particle size of the filter medium is reduced to obtain high removal performance, the pressure loss of water increases and the flow rate decreases. In order not to cause a decrease in the flow rate, there is a method of increasing the amount of the filter medium and increasing the amount, but this causes a problem that the water purifier cartridge becomes large.
[0013]
In addition, there is a method in which the flow rate is not reduced by increasing the cross-sectional area of the filter material portion into which water flows, but this still causes a problem that the cartridge for the water purifier becomes large in the radial direction.
[0014]
This invention is made | formed in order to solve said problem, and it aims at providing the effective use of a granular filtration layer, and the compact cartridge for water purifiers and water purifiers with a simple structure.
[0015]
[Means for Solving the Problems]
In order to achieve the above object, the water purifier cartridge of the present invention is a water purifier cartridge comprising a main body container provided with a filter medium, wherein a sheet that allows fluid to pass but not filter medium is disposed. A gap that allows fluid to pass therethrough and does not have the filter medium is formed between the inner wall surface of the main body container .
[0017]
In the water purifier cartridge of the present invention, the sheet may be a mesh, a fibrous sheet, a nonwoven fabric, or a felt.
[0018]
Further, the water purifier cartridge of the present invention has an inflow means in the diversion means for allowing the fluid that has passed through the filter medium in the diversion means to flow into the hollow fiber membrane module housed in the main body container. Also good.
[0019]
Further, in the water purifier cartridge of the present invention, the filtering material is held inside an outer spacer having an opening on the outer peripheral surface, and the sheet is either on the outer peripheral surface side or the inner peripheral surface side of the opening portion of the outer spacer. Either one may be bonded or fused.
[0020]
Further, the water purifier cartridge of the present invention may be one in which a sheet and an external spacer are integrally formed.
[0021]
Moreover, the cartridge for water purifiers of this invention may provide the shaping | molding filter material further in the upstream of an external spacer.
Moreover, the water purifier of this invention uses the cartridge for water purifiers of this invention.
[0022]
DETAILED DESCRIPTION OF THE INVENTION
Next, embodiments of the present invention will be described with reference to the drawings.
(First embodiment)
FIG. 1 is a cross-sectional view showing an embodiment of the water purifier cartridge of the present embodiment.
[0023]
A main body container 1 is provided with a water inlet 3 that is an inlet of raw water to be purified and a water outlet 4 through which the purified filtered water is discharged. Sealed with a ring and detachably mounted.
[0024]
In the main body container 1, a plate 5 that is a member configured to prevent the granular filter material 7 from moving toward the water inlet 3, and to allow water to pass but not to pass the granular filter material 7, A gap 1b is formed between the inner wall 1a of the main body container 1 and an outer spacer 9 for holding the granular filter material 7, a holding container 6a for holding the hollow fiber membrane module 6, and a granular filter material in the outer spacer 9. A water collection pipe 8 is provided for collecting the water that has passed through 7 and flowing it into the holding container 6a.
[0025]
FIG. 2 is a side view of the external spacer of the present embodiment, and FIGS. 3 and 4 are partially enlarged views of the vicinity of the external spacer in a state where it is mounted on the main body container. 3 shows a cross section taken along the line AA in FIG. 2, and FIG. 4 shows a cross section taken along the line BB in FIG.
[0026]
The substantially cylindrical outer spacer 9 having a taper that is narrowed in the mounting direction to the main body container 1 includes ring portions 9a and 9b in which grooves 9c and 9d in which O-rings can be mounted are formed at both ends, and the ring portions. The sheet holding unit 9f is formed integrally with 9a and 9b, and the sheet 14 is bonded or fused to the sheet holding unit 9f and allows water to pass but does not allow the granular filter material 7 to pass.
[0027]
The outer diameter of the sheet holding portion 9f is smaller than that of the ring portions 9a and 9b. When the external spacer 9 is attached to the main body container 1, the outer periphery of the sheet holding portion 9f and the main body container 1 on the ring portion 9a side. A gap 1b of the gap La is formed between the inner wall surface 1a and the gap 1b of the gap Lb on the ring portion 9b side. The gaps La and Lb may be the same, or may be different values as necessary. The gaps La and Lb are distances from the inner wall surface 1a of the main body container 1 to the outer periphery of the sheet holding portion 9f, and the distances from the inner wall surface 1a of the main body container 1 to the surface of the sheet 14 are as shown in FIG. Is generally Lc.
[0028]
When the outer spacer 9 is attached to the main body container 1, the flange portion 9 e formed at the end of the ring portion 9 b contacts the end surface 1 c of the main body container 1 and is positioned. When the outer spacer 9 is attached to the main body container 1, the ring portions 9a, 9b are inscribed in the inner wall surface 1a of the main body container 1, and the ring portions 9a, 9b and the inner wall surface are formed by O-rings attached to the grooves 9c, 9d. It is sealed between 1a.
[0029]
In the manufacturing process of this water purifier, with the open side of the cylindrical main body container 1 opened on one side facing up, the main body 5, the hollow fiber membrane module 6, the water collection pipe 8 and the external spacer 9 are inserted. The granular filter medium 7 is charged and filled from the open top of the container 1. The shape of the main body container 1 is not necessarily limited. For example, the shape of the main body container 1 can be a polygonal column shape, a truncated cone shape, or the like. Since the distance of the water collection pipe | tube 8 can be taken equally, it is more preferable.
[0030]
The method of connecting the main body container 1 and the bottom lid 2 is not necessarily limited, and a method of making a hole in both members and connecting them through bolts can be used. The method of fitting is preferable because the number of parts can be reduced. Regardless of the coupling method, in order to prevent poor fitting due to biting of the thread portion of the granular filter material 7, after the granular filter material 7 is introduced, the non-woven fabric 12 is placed on the top and the bottom lid 2 is then attached. It is preferable to make it fit.
[0031]
Next, how water flows in the water purifier of the present embodiment having the above-described configuration will be described.
[0032]
First, raw water is supplied from the water inlet 3, passes through the eye plate 5, and then passes through the granular filter material 7.
[0033]
Thereafter, as shown in the enlarged cross-sectional view of the water flowing through the granular filter material in FIG. 5, the water that has passed to the outer spacer inlet portion 9g is caused by the particle size of the granular filter material 7 and the opening area of the outer spacer inlet portion 9g. After passing through the inner laminar flow 10 flowing through the granular filter medium 7 in the outer spacer 9 and the outer spacer 9 and the main body container 1 by the pressure resistance, the granular filter medium 7 in the outer spacer 9 is again passed. To the outer laminar flow 11 flowing through
[0034]
The separated inner laminar flow 10 and the outer laminar flow 11 pass through the water collecting pipe 8 provided at the concentric central part of the main body container 1, then pass through the hollow fiber membrane module 6, and the purified filtered water is discharged from the outlet part 4. can get.
[0035]
In this way, by dividing the raw water into the inner laminar flow 10 and the outer laminar flow 11 at the outer spacer inlet 9g, the water flowing through the granular filter medium 7 inside the outer spacer is supplied from the outer spacer inlet 9g to the water collecting pipe root 8a. The inner laminar flow 10 flows between them, and the outer laminar flow 11 flows between the central part of the water collecting pipe 8 and the end 8b of the water collecting pipe, so that the particulate filter 7 is used evenly and effectively, and the substance impairs the taste of water. Moreover, the removal performance of organic substances and harmful substances can be enhanced.
[0036]
The effect of the diversion of the inner laminar flow 10 and the outer laminar flow 11 is not limited to the arrangement direction of the main body container 1, and is effective in any of the vertical, horizontal and oblique directions. Further, in the case of the vertical direction, when the raw water is supplied from the incoming water section 3, there is an effect whether the direction of the raw water flowing is the vertical upward direction or the vertical downward direction.
[0037]
One of the factors that cause the raw water to be split into the inner laminar flow 10 and the outer laminar flow 11 at the outer spacer inlet 9 g is due to the particle size of the granular filter material 7. The particle size of the granular filter medium 7 may be in the range of # 20 to # 200 mesh, preferably in the range of # 30 to # 180 mesh, and more preferably in the range of # 40 to 150 mesh.
[0038]
Examples of the sheet 14 for forming a gap provided between the outer spacer 9 and the main body container 1 used in the water purifier of the present invention can be a mesh, a bonded or fused fibrous sheet, a nonwoven fabric, a felt, and the like. Desirably, a mesh, a bonded or fused fibrous sheet, and a non-woven fabric are preferable.
[0039]
As the granular filter material 7 used in the water purifier of the present invention, powdered activated carbon, granular activated carbon, molecular adsorption resin, zeolite, molecular sieve, chelate resin, ion exchange resin, calcium sulfite, coral sand, barley stone, Ioishi, A tourmaline etc. can be illustrated and the method of using 1 type or 2 types or more of these is mentioned. Desirably, powdered activated carbon, granular activated carbon, zeolite, molecular sieve, ion exchange resin, calcium sulfite, one or more of these are used. This is the case.
[0040]
When this hollow fiber membrane is used, the material of the hollow fiber membrane module 6 is not particularly limited, but is cellulose, polyolefin (polyethylene, polypropylene), polyvinylidene fluoride (PVDF), polyvinyl alcohol, ethylene / vinyl. Alcohol copolymer, polyether, polymethyl methacrylate (PMMA), polysulfone, polyacrylonitrile, polytetrafluoroethylene (PTFE), polycarbonate, polyester, polyamide, aromatic polyamide, etc. The various materials are mentioned. Desirably, polyolefin (polyethylene, polypropylene) and polyvinylidene fluoride (PVDF) can be used, and particularly desirable is the case of using polyolefin (polyethylene, polypropylene).
[0041]
The main body container constituting the water purifier of the present invention is preferably made of a plastic such as ABS resin, AS resin, PP resin, PE resin, polycarbonate resin, etc. in consideration of cost and moldability. The wall thickness is preferably 3 mm or more in consideration of pressure resistance.
(Second Embodiment)
FIG. 6 shows a side sectional view of the water purifier cartridge of the present embodiment.
[0042]
In the cartridge for water purifier of the present embodiment, the molded filter medium 13 is disposed in front of the granular filter medium 7 for the purpose of enhancing the removal performance of substances that impair the taste of water, organic substances, and harmful substances. The water purifier cartridge of the present embodiment is the same as the water purifier cartridge described in the first embodiment, except that the molded filter medium 13 is provided. Therefore, in the following description, the same reference numerals as those in the first embodiment are used.
[0043]
Examples of the molded filter medium 13 include powdered activated carbon, granular activated carbon, fibrous activated carbon, ion exchange fiber, zeolite, molecular sieve, chelate resin, ion exchange resin, calcium sulfite, coral sand, oat stone, Io stone, tourmaline, and the like. , And a method of molding and using one or more of these.
[0044]
Desirably, powdered activated carbon, granular activated carbon, fibrous activated carbon, ion exchange fiber, zeolite, molecular sieve, chelate resin, ion exchange resin, calcium sulfite, one or more of these are used. Particularly desirable are powdered activated carbon, granular activated carbon, fibrous activated carbon, and ion exchange fiber.
[0045]
Also in the present embodiment, as in the first embodiment, water is divided into the inner laminar flow 10 and the outer laminar flow 11, and the granular filter medium 7 is used evenly and effectively. The removal performance of substances and the like can be improved.
[0046]
【The invention's effect】
According to the present invention, in a water purifier cartridge in which a filter medium is disposed in a cylindrical main body container, the flow of fluid passing through the filter medium is caused by pressure caused by the particle diameter of the granular filter medium and the opening area of the external spacer inlet. By diverting in at least two directions by resistance, the flow rate is not reduced while the entire filter medium is effectively used evenly.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view showing an example of a water purifier cartridge according to a first embodiment of the present invention.
FIG. 2 is an external view of an external spacer according to the first embodiment of the present invention.
FIG. 3 is a partially enlarged view of a water purifier cartridge showing a state in which an external spacer is attached to a main body container.
FIG. 4 is a partially enlarged view of a water purifier cartridge showing a gap formed between a main body container and a sheet material.
FIG. 5 is an enlarged cross-sectional view of water flowing through a granular filter medium.
FIG. 6 is a cross-sectional view showing an example of a water purifier cartridge according to a second embodiment of the present invention.
FIG. 7 is a cross-sectional view showing an example of a conventional water purifier cartridge.
FIG. 8 is a cross-sectional view showing an example of a conventional water purifier cartridge.
FIG. 9 is a cross-sectional view showing an example of a conventional water purifier cartridge.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Main body container 1a Inner wall surface 1b Gap 1c End surface 2 Bottom cover 3 Water inlet part 4 Water outlet part 5 Eye plate 6 Hollow fiber membrane module 6a Holding container 7 Granular filter material 8 Water collecting pipe 8a Water collecting pipe root part 8b Water collecting pipe end part 9 External spacer 9a, 9b Ring portion 9c, 9d Groove 9e Flange portion 9f Sheet holding portion 9g External spacer inlet portion 10 Inner layer flow 11 Outer layer flow 12 Non-woven fabric 13 Molded filter medium 14 Sheet 22 Non-woven fabric

Claims (6)

本体容器に粒状の濾過材を備えてなる浄水器用カートリッジにおいて、
流体は通過させるが前記濾過材は通過させないシートが配置されており、前記シートと前記本体容器の内壁面との間に、流体が通過可能であって内部に前記濾過材を有しない間隙が形成されており、
前記濾過材は、外周面に開口部を有する略円筒形状の外部スペーサの内部に保持されており、前記シートは、前記外部スペーサの前記開口部に配置されており、
前記外部スペーサは、その端面側流体前記外部スペーサの内部へと流入させる外部スペーサ入口部が形成されており、かつ前記外部スペーサ入口部まで通過してきた流体が、前記外部スペーサ内の前記濾過材を流れる内層流と、前記間隙を通過した後、再び外部スペーサ内の前記濾過材を流れる外層流とに分流されるように前記本体容器内に配されている浄水器用カートリッジ。
In a water purifier cartridge comprising a granular filter medium in the main body container,
A sheet that allows the fluid to pass but not the filter medium is disposed, and a gap that allows the fluid to pass therethrough and does not have the filter medium is formed between the sheet and the inner wall surface of the main body container. Has been
The filter medium is held inside a substantially cylindrical outer spacer having an opening on the outer peripheral surface, and the sheet is disposed in the opening of the outer spacer,
The outer spacer, the fluid on the end face side of that has outer spacer inlet for flowing is formed into the interior of the outer spacers, and the fluid that has passed through to the external spacer inlet port, said in the outer spacer A water purifier cartridge disposed in the main body container so as to be divided into an inner laminar flow flowing through the filter medium and an outer laminar flow flowing through the filter medium in the outer spacer after passing through the gap .
前記シートが、メッシュ、繊維状シート、不織布、フェルトのいずれかである請求項1に記載の浄水器用カートリッジ。  The water purifier cartridge according to claim 1, wherein the sheet is one of a mesh, a fibrous sheet, a nonwoven fabric, and felt. 前記濾過材を通過してきた流体を前記本体容器内に収納されている中空糸膜モジュールへと流入させる流入手段を有する、請求項1又は2に記載の浄水器用カートリッジ。  The cartridge for water purifiers of Claim 1 or 2 which has the inflow means to which the fluid which has passed the said filter medium flows in into the hollow fiber membrane module accommodated in the said main body container. 前記シートと前記外部スペーサとが一体成形されている、請求項1ないし3のいずれか1項に記載の浄水器用カートリッジ。  The water purifier cartridge according to any one of claims 1 to 3, wherein the sheet and the external spacer are integrally formed. 前記外部スペーサの上流側に、さらに、成形濾過材を設けた請求項1ないし4のいずれか一項に記載の浄水器用カートリッジ。  The cartridge for water purifiers as described in any one of Claim 1 thru | or 4 which further provided the shaping | molding filter material in the upstream of the said external spacer. 請求項1ないし5のいずれか一項に記載の浄水器用カートリッジを用いた浄水器。  The water purifier using the cartridge for water purifiers as described in any one of Claims 1 thru | or 5.
JP2002287563A 2002-09-30 2002-09-30 Water purifier cartridge and water purifier Expired - Fee Related JP4299522B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2002287563A JP4299522B2 (en) 2002-09-30 2002-09-30 Water purifier cartridge and water purifier

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2002287563A JP4299522B2 (en) 2002-09-30 2002-09-30 Water purifier cartridge and water purifier

Related Child Applications (2)

Application Number Title Priority Date Filing Date
JP2008182433A Division JP5081749B2 (en) 2008-07-14 2008-07-14 Water purifier cartridge
JP2008182434A Division JP5081750B2 (en) 2008-07-14 2008-07-14 Water purifier cartridge

Publications (3)

Publication Number Publication Date
JP2004121937A JP2004121937A (en) 2004-04-22
JP2004121937A5 JP2004121937A5 (en) 2005-11-17
JP4299522B2 true JP4299522B2 (en) 2009-07-22

Family

ID=32280296

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2002287563A Expired - Fee Related JP4299522B2 (en) 2002-09-30 2002-09-30 Water purifier cartridge and water purifier

Country Status (1)

Country Link
JP (1) JP4299522B2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4512326B2 (en) * 2003-06-13 2010-07-28 三菱レイヨン株式会社 Water purification system
JP4085077B2 (en) 2004-07-15 2008-04-30 株式会社日本技術開発センター Household water purifier filter container
JP5040279B2 (en) * 2006-12-01 2012-10-03 東レ株式会社 Water purification cartridge
JP5682863B2 (en) * 2011-09-14 2015-03-11 三菱レイヨン株式会社 Water purifier cartridge
JP2014021074A (en) * 2012-07-23 2014-02-03 Toda Kogyo Corp Monitoring system of tap water contaminated with radioactive substance
JP6669579B2 (en) * 2016-04-28 2020-03-18 三菱ケミカル・クリンスイ株式会社 Water purification cartridge
CN105858923B (en) * 2016-05-31 2019-09-10 海南立昇净水科技实业有限公司 Passway for water for water purifier

Also Published As

Publication number Publication date
JP2004121937A (en) 2004-04-22

Similar Documents

Publication Publication Date Title
CA2350292C (en) Water purifying apparatus
RU2596747C2 (en) Cartridge for purifying water and water treatment plant
CN102249458B (en) Efficient multifunctional water purification filter
KR101088862B1 (en) Combination Filter for Water Purifier
KR101912869B1 (en) Integrated uf-sediment filter for water purification
JP4299522B2 (en) Water purifier cartridge and water purifier
WO2013039194A1 (en) Cartridge for water purifier
WO2011159196A1 (en) Filter module and device for purifying a liquid
JP5081749B2 (en) Water purifier cartridge
JP5081750B2 (en) Water purifier cartridge
CN102612496B (en) Water purifier cartridge and water purifier
CN103108835A (en) Water purification cartridge
CN108430930B (en) Water purification cartridge
JP6447239B2 (en) Water purification cartridge
KR20090116438A (en) Filter for water purifier
TWI295583B (en) Water purifier
KR200296368Y1 (en) Filter cartridge having doule hollow filled up filter-materials
JP4255070B2 (en) Water purification cartridge, method for producing the same, and water purifier provided with the same
CN215756703U (en) Composite filter element end sleeve
CN210367184U (en) Multiple filter core structure of water purifier
JPH11253935A (en) Water purifier
CN210367185U (en) Multiple filter core structure of water purifier
JP4646282B2 (en) Water purifier
JP2003062561A (en) Cartridge for water purifier
JP4187601B2 (en) Water purifier

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050930

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20050930

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20071025

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20071107

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20071227

RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20071227

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080130

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080328

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20080514

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080714

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080829

RD13 Notification of appointment of power of sub attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7433

Effective date: 20080829

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20080829

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20081001

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090218

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090303

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20090401

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20090417

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120424

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120424

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130424

Year of fee payment: 4

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130424

Year of fee payment: 4

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130424

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130424

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140424

Year of fee payment: 5

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees