TW524872B - Sputtering film formation device and process of sputtering film formation - Google Patents

Sputtering film formation device and process of sputtering film formation Download PDF

Info

Publication number
TW524872B
TW524872B TW089107738A TW89107738A TW524872B TW 524872 B TW524872 B TW 524872B TW 089107738 A TW089107738 A TW 089107738A TW 89107738 A TW89107738 A TW 89107738A TW 524872 B TW524872 B TW 524872B
Authority
TW
Taiwan
Prior art keywords
target
magnetron
sputtering
magnetic circuit
film
Prior art date
Application number
TW089107738A
Other languages
Chinese (zh)
Inventor
Hidekazu Suzuki
Hiroshi Iwata
Original Assignee
Anelva Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anelva Corp filed Critical Anelva Corp
Application granted granted Critical
Publication of TW524872B publication Critical patent/TW524872B/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3411Constructional aspects of the reactor
    • H01J37/345Magnet arrangements in particular for cathodic sputtering apparatus
    • H01J37/3455Movable magnets
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/35Sputtering by application of a magnetic field, e.g. magnetron sputtering

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Analytical Chemistry (AREA)
  • Physical Vapour Deposition (AREA)
  • Electrodes Of Semiconductors (AREA)

Abstract

The present invention relates to a sputtering film formation device and a process of sputtering film formation, which is a sputtering film formation device can be provided an oscillating magnetron magnetic circuit on the back side of the target, lowers the formation of nodules on the surface of the target, and further increases the rate of operation of the device and facilitates to promote the production efficiency without recovering the surface of the target into the initial state by lowering the formation of nodules on the surface of the target. The sputtering film formation device of the present invention comprises: a target 20 facing the substrate 42; and a magnetron magnetic circuit 24 provided on the back side of the target; in addition, the sputtering film formation device oscillates the magnetron magnetic circuit along a certain direction so as to carry out the process of sputtering film formation on the surface of the substrate. The sputtering film formation device of the present invention further comprises a control circuit 272, and the control circuit 272 controls the oscillating velocity of the magnetron magnetic circuit so as to produce a plasma area 7 possessing the sputter ability on the surface of the target via the magnetron magnetic circuit, and further to carry out the sputter etching process successively over 1 second against each region of the surface of the target via the plasma area 7 possessing the sputter ability.

Description

524872 五、發明說明(l) 【發明之詳細說明】 【發明所屬之技術領域】 本發明係關於一種濺鍍成膜裝置及濺鍍膜形成方法;特 別是,本發明係關於一種至少具備有丨個之面對著基板之 所配置之磁控管磁性電路,並且,還藉由以相當緩ι慢之 度而搖動著該磁控管磁性電路,以便於在基板之表面上, 進行著濺鍍成膜處理之濺鍍成膜裝置及濺鍍膜形成方法。 【先如技術】 向=,在先前技術中’係已經知道有例如使用磁控管陰 "之歹1型濺鍍成膜裝置(例如日本專利特開平第7 _ ^ 18 = 5號公報)。就該濺鍍成膜裝置之基本構造 概略之說明。 &彳丁者 f該濺鍍成膜裝置中,係在該用以於基板 =理1濺鑛成膜室内,具備有許多個 各個之磁控管陰極,一般俜在 s u枉。在 使侍忒軚靶,能夠面對著該所搬送 神# 在陰極體之背二ί 而被安裝於陰極體上。 磁控管磁性電路,並且 "係扠置有 广振幅,,沿著相同=向電=能”所 乾磁性電路:係位處於標乾之背面i,而:J 藉由磁場,i便::::場’並且’還在標靶之表面上7 域。所謂搖動磁控管磁性電路,係為4 524872 五、發明說明(2) 移動著該由來自電漿之荷電粒 而形成之標靶之表面上之俨.二之所造成之濺鍍蝕刻處理 效率。該作為搖動磁控管磁性電路=:提高標革巴之利用 學上之所熟知之將圓周運動、—,一般係為機構 搖動機構。單振動式搖動機構=運動之單振動式 性: 彳糸具備有以下所敘述之特 在磁控管磁性電路改變其搖 動機構中之搖動速度,係、 緩P端部’單振動式搖 陰極之幾乎中心 =為、友陵,亚且,在磁控管 係變得最為#速口。 又動式搖動機構中之搖動速度, ★在沿著特定方向(基板搬送方向、 f t兹控f磁性電路之_成膜裝置中,_ rf二) 之侵蝕部之搖動;而賤鍍蝕刻著標靶之所形成 之標靶之長上'方向長度’磁控管磁性電路之搖動方向上 小,係配:二ΐ被決定成為比較長。該侵蝕部之面積大 而被封閉電路之所製造出之磁力線 能力:所謂能夠決定標乾表面之侵姓部之錢 管磁性電:義:為r胃侵触實施區4。當磁控 表面 :止之枯’則亚無法全面地使用標靶之整個 就正如前面所敘述的,係沿著特定太 在『磁控管磁性電路。隨著磁控管磁性電路之搖動,而 沿著搖動方向,搖動著前述之=實: 1,在該侵蝕實施區域,通過標靶之表面上之各 89l〇7738.ptd 第6頁 524872 五、發明說明(3) 個部位之日寺 實際上,由 進行著往復 標革巴之表面 靶之表面上 位,進行著 姓實施區域 上之各個部 刻處理之日夺 上之各個部 動方向上呈 標把之各個 標把之各個 磁控管磁性 向上之長度 時,成為所 鏟钱刻時間 了提高膜厚 約0 · 2 6秒鐘 習知之先前 電路之搖動 【發明所欲 在習知之 上之各個部 灰鑛I虫刻著該桿辈矣 於係沿著據私士 Γ靶表各個部位。在 運動,因,4 ϋ ,而使得該侵蝕實施區域, 上之夂個部位该侵蝕實施區域,係反覆地通過 之久二邻1之’士而在該侵餘實施區域通過該標 不:鋒 ”對於標靶之表面上之各個部 連’之濺鍍蝕刻處理。在另一方面,於 位:Βΐ間狀態而連續地通過1次之標靶之表面又 :之時:該標“表面上之各個部位之4敍 二’係等於該侵蝕實%區域i過該標靶之;面 連續之命門壯妒 也士疋说在精由該於搖 、^ 恷之侵餘實施區域,以便於斜於 ::位,進行著她刻處理之時,該二d σ位之濺鍍蝕刻處理之所需要之時間T,係在 電路,搖動速度為ν而侵蝕實施區域之搖動方 ^了也__就疋知蝕部之搖動方向上之長度)為w之 明1 =W^V之公式。係稱呼該時間Τ為「連續濺 」。在習知之先前技術之濺鍍成膜裝置中,為 之均勻性,因此,係設定時間τ,成為所謂大 左右之比較短暫之時間。換句話說,如果藉由 技衍之灰鑛成膜裝置的話,係設定磁控管磁性 速度’成為比較高速度。 解決之問題】 先Θ技術之濺鑛成膜裝置中,由於標革巴之表面 位之連續濺鍍蝕刻處理之時間Τ,係相當地短524872 V. Description of the invention (l) [Detailed description of the invention] [Technical field to which the invention belongs] The present invention relates to a sputtering film forming apparatus and a sputtering film forming method; in particular, the present invention relates to a method having at least one The magnetron magnetic circuit configured to face the substrate, and the magnetron magnetic circuit is also shaken at a relatively slow speed to facilitate sputtering on the surface of the substrate. Sputtering film forming device for film processing and method for forming sputtered film. [Preceding technology] To =, in the prior art, 'system has been known to use, for example, a type 1 sputter film forming apparatus using a magnetron cathode (for example, Japanese Patent Laid-Open No. 7 _ ^ 18 = 5) . The basic structure of the sputtering film forming apparatus will be briefly described. & Finer f. The sputtering film-forming device is provided in the substrate-forming sputtering film-forming chamber, and is provided with a plurality of individual magnetron cathodes, which are generally located at s u 枉. After making the target, the head can be installed on the cathode body facing the transported god # on the back of the cathode body. The magnetic circuit of the magnetron, and the "fork is placed with a wide amplitude, along the same = to the electric = energy" dry magnetic circuit: the position is on the back of the standard trunk i, and: J by the magnetic field, i: ::: The field is "and" is still on the surface of the target. The so-called rocking magnetron magnetic circuit is 4 524872. V. Description of the invention (2) The standard formed by the charged particles from the plasma is moved. Sputter etch processing efficiency caused by 俨 on the surface of the target. 2. It is used as a magnetic circuit for rocking the magnetron. Shaking mechanism.Single-vibration shaking mechanism = single-vibration type of movement: 彳 糸 It has the following special characteristics in the magnetron magnetic circuit to change the shaking speed in its shaking mechanism. Almost the center of the swinging cathode = 、, Youling, Asia, and the most #speed mouth in the magnetron system. The swinging speed in the reciprocating swinging mechanism, ★ in a specific direction (substrate transfer direction, ft control) f magnetic circuit of _ film formation device, _ rf 2) of The shaking of the erosion part; and the "direction length" of the target formed by the base plating etching the target is smaller in the shaking direction of the magnetron magnetic circuit, and the matching is: the second part is determined to be relatively long. The erosion part The area of the magnetic field line produced by the closed circuit is large: the so-called magnetic tube that can determine the invading part of the standard surface: meaning: for the stomach to interfere with the implementation area 4. When the magnetron surface: stop the dead ' Zeya's inability to fully use the target is just as described above. It follows the specific magnetic circuit of the magnetron. With the magnetron's magnetic circuit shaking, it shakes along the aforementioned direction along the shaking direction. = Real: 1. In the area where the erosion is carried out, pass each of 89l07738.ptd on the surface of the target. Page 6 524872 V. Description of the invention (3) In fact, the Risi Temple is reciprocated. When the surface of the target is on the upper surface, and the various parts on the implementation area are engraved on the day, the length of each magnetron in the direction of the movement of the various parts in the moving direction is the length of the magnetron. Time to mention The high film thickness is about 0.26 seconds before the shaking of the conventional circuit [the ash mines of the various parts of the invention on which the invention is intended are engraved with the rods engraved along the various parts of the target surface according to the private person Γ. In the movement, because of 4 ,, the erosion area, the upper part of the erosion area, passed through the long-neighboring neighbour 1 and repeatedly passed the mark in the area where the erosion was carried out: Feng "Sputter etching process for each part on the surface of the target. On the other hand, the surface of the target that passes through once in the in-position: Bΐ state and again: Time: the mark "Each area on the surface is equal to the 4% of the erosion area." The target of the target; the face of continuous life, the gate of jealousy, and the jealous man said that in the implementation area of the Yuyou, ^ 恷 the invasion of the implementation area, so as to be inclined to the :: bit, while she is processing, the two d σ The time T required for the sputter etching process of the bit is in the circuit, and the shaking speed is ν, and the shaking side of the erosion area is ^ _. I know the length in the shaking direction of the etching part) is w 1 = W ^ V formula, which refers to the time T as "continuous splash". In the conventional prior art sputtering film-forming apparatus, for uniformity, the time τ is set, which is a relatively short time called a large time. In other words, if the ash ore film-forming apparatus is used, the magnetron magnetic speed is set to a relatively high speed. The problem to be solved] In the former Θ technology sputtering deposit film forming device, the continuous sputtering and etching time T of the surface of the standard leather is relatively short.

524872 五、發明說明(4) 暫’因此,就會右M IT & & 係參照圖9〜圖! 4,而艾逑之問題發生。 、乂 — 成朕衣置中,磁控管磁性電路和電漿,係 姑;^ 者個之運動方向,而在標靶之表面上,進行著 :。=9係為用以顯示出習知之先前技術之濺鍍成膜裝 f: ί管磁性電路之搖動速度之位置依存性之代表性 於萬3 :。圖1 2係為用以顯示出在習知之先前技術之磁 ΓΓ、ϊ 時刻u下之標靶20之表面經過滅鍍蝕刻處理 Μ】t之圖式。在標靶20之背面上,係配置有該能夠自由 搖動=磁控管磁性電路(永久磁鐵)24,並且,還藉由 ;二3 :磁性電路(永久磁鐵)24 ’而形成該根據所謂該 ==標把2。之表面部位上之磁力線6之磁場。在該藉7 :士 :良6之所形成之密閉狀態之空間内,係生成有電裝7。 =電漿7,而製造出前述之侵蝕實施區域。如果在圖 j =上方進行觀察的話,該藉由電漿7之所形成之侵蝕 貝施區域,係具備有整體呈環形之形狀,但是,在圖卫2 中,由於該侵蝕實施區域和標靶20之表面上之 之間之關係’因此’該具備有沿著搖動方知 之幅寬之部分,就成為各個之侵姓實施區域。 在杈蝕部2〇a,係藉由該存在於正上方之電、 蝕實施區域,而進行著濺鍍蝕刻處理。 1 =叉 路24之搖動,電聚7係也在標革巴表面上,磁性電 且,還隨著該電漿7之移動,以致於該進行著濺鍍’, 理之侵蝕部2 〇 a,也跟著進行移動。 /又 ^ 1 1 | I 11 I 1 11 1 11 89107738.ptd524872 V. Description of the invention (4) For the time being, therefore, M IT & & refers to Fig. 9 ~ Fig. 4 and the problem of Ai Yi occurs. , 乂 — In the center of the clothes, the magnetic circuit of the magnetron and the plasma are the direction of the movement of each person, and on the surface of the target, proceed:. = 9 is representative of the position dependence of the shaking speed of the magnetic circuit of the f: ί tube magnetic circuit. FIG. 12 is a diagram for showing that the surface of the target 20 at the time u at the conventional prior art magnetic field ΓΓ is subjected to an etch-down etching process M] t. On the back surface of the target 20, the freely swingable = magnetron magnetic circuit (permanent magnet) 24 is arranged, and also by 2: 3: magnetic circuit (permanent magnet) 24 'is formed according to the so-called == 标 把 2. The magnetic field of the magnetic field lines 6 on the surface part. Denso 7 is generated in the closed space formed by the loan 7: taxi: good 6. = Plasma 7 to create the aforementioned erosion area. If viewed from the top of figure j =, the eroded basal area formed by the plasma 7 has a circular shape as a whole. However, in Figure 2, due to the eroded area and the target The apparent relationship between the 20's is therefore that the part with the width known along the shaking side becomes the area where each surname is implemented. In the etched portion 20a, a sputter etching process is performed by using the area where the electric and etching is performed directly above. 1 = Shake of fork road 24, Electropoly 7 series is also on the surface of the standard leather, magnetic and also with the movement of the plasma 7, so that sputtering should be performed, the erosion of the part 2 〇a , Followed by the move. / Again ^ 1 1 | I 11 I 1 11 1 11 89107738.ptd

第8頁 24872 五、發明說明 此外, 蝕部上, 8卜 接著, 陰極中之 刻處理之 非侵飿部 非侵I虫部 部。在時 位9 2上之 處理。但 I虫刻處理 之時,再 9 2上。當 而使得前 質現象, 並不容易 82。當長 時,就正 是,藉由 有所謂並 於會殘留 理之物質 (nodule (5) 在標把2 0之表面上,於侵飯部2 〇 a之周圍之非侵 就正如圖1 2之所顯示的,係堆積有再附著用粒&子 在圖1 3中’係顯示出在習知之先前技術之磁总 時^“下之標把20之表面經過賤 狀態。在時刻11之時,係由於電漿7,在該成為 之部位9 2之正上方,進行著移動,以致於該成為 之部位9 2,成為被進行著濺鍍蝕刻處理之侵蝕 刻11之時’部位9丨係相當於侵蝕部。該堆積於部 ,附著用粒子81之一部分,係被進行著濺鍍蝕^ 是,該對於全部之再附著用粒子8丨而進行著濺鍍 之=需要之時間,係並不足夠,因此,在時刻 附著用粒子8 1,係殘留於該成為非侵蝕部之部位 、、二過某又之規定時間之時,係會由於電漿7, 述之所殘留之再附著用粒子81,發生有加熱及變 以致^該所殘留之再附著用粒子81,變成為所謂 進行著濺鍍蝕刻處理之再附著用粒子之變質物 日"r間地進行著標革巴2 0之表面之錢鑛飯刻處理之 如圖1 4之所顯示的,係挖掘著標靶2 0之表面,但 反$地進行著前述之現象,係並無法挖掘該附著 不^易進行著濺鍍蝕刻處理之物質之部位,以致 有f述之附著有所謂並不容易進行著濺鍍蝕刻處 之部位。前述之挖掘殘餘部83,稱為「球粒 )」。球粒(nodule )」,係會使得標靶2〇之利 89107738.ptd 第9頁 524872 五、發明說明(6) 用效率呈變差惡化。 在習知之先前技術之濺鍍成膜裝置中,標靶2〇之表面上 之各個部位之連續減:艘钱刻處理時間τ (= w / 乂、 大約0.26秒鐘左右,因此,係會由於形成H’l為 ),以致於僅能夠得到大約35%左右之標靶利I 此外’由於係並不容易濺鍍蝕刻著球粒/ 此,當在標乾之表面上而形成有球粒(_uJ :: 會隨著該所投入之電力量之增加,以致 ^ ^ 係 低。圖U中之” X·,所示之特性52,係;;以速度: 術之濺鍍成膜裝置中之成膜速度之所投入二二之先二技 性。由於係隨著該所投入之電力量之增 J::二 度降低,因此’為了在基板上,W著上相心逮 係必須適時地進行著該所投入之電力之修正處理。/ 、 此外’像在基板上,使用Ar (氬)氣體和J而 In-Sn-Ο (銦-錫—氧)系透明導電膜( ; '' 所導入之反應性氣體之流量而形成 對= 當值之薄膜之狀態下,t改變該所投到= 寻該反應性氣體之最適當導入量生變化。二糸 2之表面上,形成有球粒(n〇dule),而導致其= :::臭:ί ’還進行著該所投入之電力之修正^理,、以 ;在土板上,附著上相同膜厚之薄膜之 到最適當之薄膜特性, 心下為了付 性氣體之氧氣之導入量。 ” μ彡、要修正該成為反應 89107738.ptd 第10頁 524872 、發明說明(7) 此外,由於球粒(η 〇 d u 1 e )之比雷阳 電阻,因此,該由電漿之所照射出之行糸问於払靶之比 當容易地帶電。當該荷電粒子之帶電it子,就變得相 之時,該荷電粒子係成為電弧,而由雷將:某種程度以上 弧,以致於會有所謂造成該位處於桿夕姐丄拜 ®以电 郎% <射向部位上之某 板之外觀損傷之現象發生。圖1 1中之"γ ^ ^ τ < χ 所示之特性5 4, 係表示著習知之先前技術之濺鍍成膜裝置中 所投入電力量之依存性。 此外,錢之電弧,係改變電漿之化學狀態。像在使用 Ar (氬)氣體和氧氣而對於no膜(In —Sn —〇 (銦—錫—氧) 系透明導電膜)進行著反應性濺鍍成膜處理之狀能下、以 及在相對於IT〇膜中之所放入之氧氣量而形成所謂^薄膜特 性達到最適當值之薄膜之狀態下,係、弧改變該所發 生之電漿之化學狀態,以致於改變該放入至Ιτ〇膜中之氧 氣量,而會有所謂膜質呈劣化之問題發生 、 〆^發明之目的,係為了解決前述之問題,因此,本發明 係提供種在標靶之背面上而具備有搖動式磁控管磁性電 路之歲鑛成膜裝置及錢鑛膜形成方法中,可以降低標把表 面士之球粒(n〇dule)之形成現象,並且,還藉由降低標 巴^ =上之球粒(n〇dule )之形成現象,以致於並不需要 2 ί乾表面,回復至初期狀態,而能夠提高裝置之運轉 '^ ’並且’造成所謂生產效率之提升之構造以及方 法η 【解決問題之手段及作用Page 8 24872 V. Description of the invention In addition, on the etched part, 8b. Next, the non-invaded part and the non-invaded part of the etched part in the cathode are processed. Processing at time 92. But when I was engraved, I went on 9 2 again. This makes prodromal phenomena not easy82. When it is long, it is precisely the non-aggression around the invading rice section 2 〇a on the surface of the marker 20 by the so-called condensed matter (nodule (5)) as shown in Figure 1 2 What is shown is that the particles for re-attachment are piled up in FIG. 13 'showing the total time of the magnetic field of the prior art ^ "The lower surface of the standard 20 passes through the base state. At time 11 At this time, due to the plasma 7, the moving part 9 2 is directly above the part 9 2 to be moved, so that the part 9 2 to be formed becomes the part 11 when it is etched and etched 11 by sputtering etching. Corresponds to the eroded part. The part deposited on the part and the particles 81 for attachment is sputtered ^ Yes, the sputtering is performed for all the re-adhesion particles 8 丨 = time required, It is not enough. Therefore, at the time of attachment of the particles 81, the remaining non-eroded portion, and after a certain period of time, the remaining adhesion due to the plasma 7 will be described. The particles 81 are heated and changed so that the remaining particles 81 for re-adhesion become The so-called spoiled particles with sputter etching treatment are re-adhered to the particles on the surface of the surface of the standard metal engraved on the surface of the standard metal bar 20 as shown in Figure 14 is the excavation of the standard The surface of the target 20, but the aforementioned phenomenon is reversed, it is impossible to excavate the site of the substance that is not easy to be sputtered and etched, so that the so-called not easy to sputter is described in f The etched portion is plated. The above-mentioned excavation residue 83 is called a "spheroid". "Nodule" will make the target 20 profit 89107738.ptd page 9 524872 V. Description of the invention (6) The utilization efficiency becomes worse. In the conventional prior art sputtering film-forming device, the continuous reduction of various parts on the surface of the target 20: the processing time τ (= w / 乂, about 0.26 seconds, etc.). H'l is formed), so that only about 35% of the target target I can be obtained. In addition, since the pellets are not easily etched by sputtering, the pellets are formed on the surface of the standard stem ( _uJ :: will increase with the increase of the amount of electric power input, so that ^ ^ is low. "X · in the figure U, the characteristic shown in 52, series; at the speed of: Film formation speed of the first two technology. Since the amount of power is increased with the increase of J :: two degrees, so 'in order to be on the substrate, the system must be timely The correction process of the input electric power is being performed. / 、 In addition, like on a substrate, Ar (argon) gas and J are used, and In-Sn-O (indium-tin-oxygen) -based transparent conductive film (;) The flow rate of the introduced reactive gas forms a pair = in the state of the thin film of value, t changes the thrown = finds the optimum for the reactive gas When the amount of introduction is changed. On the surface of 糸 2, nodules are formed, which results in == :: 臭:: 'The correction of the input electric power is also being performed, and so on; On the soil plate, a film with the same film thickness is attached to the most appropriate film characteristics, and the amount of oxygen introduced into the gas in order to support the gas. ”Μ 彡, the reaction should be corrected 89107738.ptd page 10 524872, invention Explanation (7) In addition, because the ratio of spheres (η 〇du 1 e) to thunder resistance, therefore, the ratio of the target irradiated by the plasma to the target should be easily charged. When the charged particles When the charged it becomes phase, the charged particle system becomes an arc, and the lightning will: arc above a certain level, so that there is a so-called cause that the position is in the pole. Sister Worship® with Electricity% & lt The phenomenon of appearance damage to a certain plate on the shot site occurs. The characteristic shown by " γ ^ ^ τ < χ in Fig. 11 is 5 4 which represents the conventional prior art sputtering film forming device. Dependence on the amount of power input. In addition, the arc of money changes the chemical state of the plasma. Like With the use of Ar (argon) gas and oxygen, the no film (In-Sn-〇 (indium-tin-oxygen) transparent conductive film) is subjected to a reactive sputtering film formation process, and it 〇 In the state where the amount of oxygen placed in the film forms a so-called thin film with the most appropriate film characteristics, the chemical state of the plasma generated by the system is changed by the arc, so that the film is changed to Ιτ〇 The amount of oxygen in the film may cause the problem of so-called degradation of the film quality. The purpose of the invention is to solve the aforementioned problems. Therefore, the present invention provides a kind of swing magnetron on the back of the target. In the old-time ore film forming device and the money ore film forming method of the magnetic circuit, the phenomenon of nodule formation on the surface of the handle can be reduced, and by reducing the standard bar ^ = upper nodule (n 〇dule) formation phenomenon, so that it does not need 2 ί dry surface, return to the initial state, and can improve the operation of the device '^' and 'cause the structure and method to increase the so-called production efficiency effect

89107738.ptd 第11頁 524872 五、發明說明(8) 而=成前述之目的’因此,本發明係正如以下之敛述 本發明之濺鍍成臈裳置,其係具備有··與存在於 膜室内之基板相對配置的標靶;以及設置於該標之又 巧磁控管磁性電路,本發明之賤鑛成膜裝置:、係至;沿 磁控管磁性電路’以便於在基板之表面 進仃濺鍍成膑處理。該濺鍍成膜裝置 機構,係控制磁控管磁性電路之搖動速度,以便 5管磁:電路’而在標乾之表面上,製造出具備有濺:能 力之電漿區域(也就是藉由磁控管磁性電路之所形成:磁 漿;以便於對於標乾之表面,進行細 ::且,在該具備有濺鏟能力之《 ;:,Γί之各個部位時,使得標靶表面之各個 靶夺面之2 J印留在電漿區域中1秒鐘以上之時間。在標 連續地滯留在電聚區域中之時間成為1 。理之二則1亥標巧面之t個部位連續地進行濺㈣ # ά' Λ 1 ί! 就疋刖述連續濺鍍蝕刻處理之時間Τ, 係成為1秒鐘以上。 之=:成方L:其係藉由前述本發明 、、…“: 本發明之濺鍍膜形成方 荖某板之二沿者一方向,而搖動設置於所謂配置成為面對 if乾之背面上的磁控管磁性電路,以便於在基板 ^ ^ r進仃濺鍍成膜處理,其中本發明之濺鍍膜形成 方法’係為搖動磁控管磁性電路,以便於根據磁控管磁性89107738.ptd Page 11 524872 V. Description of the invention (8) And = to achieve the aforementioned purpose 'Therefore, the present invention is as follows to describe the sputtering of the present invention into a sloppy dress, which has ... A target with a substrate disposed oppositely in the membrane chamber; and a magnetron magnetic circuit provided in the target, the basement film-forming device of the present invention:, tied to; along the magnetron magnetic circuit 'to facilitate the surface of the substrate It is sputtered into a plutonium. The sputtering film-forming device mechanism controls the shaking speed of the magnetron's magnetic circuit so that the 5 tube magnetic: circuit 'is on the surface of the standard stem, and a plasma region with a sputtering: ability is produced (that is, by the The formation of the magnetron's magnetic circuit: the magnetic slurry; in order to make the surface of the standard stem fine: ::, and when the parts of the ";:, Γ" with the shovel ability are made, each of the target surface The target 2 of the target surface is left in the plasma area for more than 1 second. The time that the target stays in the electrode area continuously becomes 1. The second reason is that t parts of the 1H standard surface are continuously Perform sputtering # ά 'Λ 1 ί! The time T of the continuous sputtering etching treatment is described above, which is more than 1 second. It is =: 成方 L: It is based on the foregoing invention, ... ": 本The invention of the sputtered film is formed in the direction of the two sides of a certain plate, and the magnetron magnetic circuit disposed on the so-called back surface facing the if stem is shaken, so as to facilitate sputtering and forming a film on the substrate ^ ^ r Processing, wherein the method for forming a sputtered film according to the present invention is to shake a magnetron magnetic circuit to Easy to magnetize based on magnetron

89107738.ptd 第12頁 524872 五、發明說明(9) 電路,而在標靶之表面上,製造出該具備有濺鍍能力之 漿區域,並且,在該具備有濺鍍能力之電漿區域,通過 革巴表面之各個部位之時,使得標靶表面之各個部位,$二 地滯留在電漿區域中1秒鐘以上之時間之方法。 # 在具備有習知之先前技術之搖動式磁控管磁性電路义 鍍成膜裝置中,係優先於球粒(n〇dule ) 機 低膜厚不均現象,料優先目的,以便於控二= 電路之搖動動作,因此,係設定控制磁控管磁性電路 動動作’以便於能夠以儘可能之高速度(例如時搖 約〇. 26秒鐘左右),進行著磁控管磁 ‘、、、 相=具備有習知之先前技術之搖動=路 問題,因此,传可以設定ί、二球粒(n〇dule)之 ” :便於能夠達到所謂膜厚不 :動 亚且’逛可以解決球粒(nodule )之 ]正σ放果, 在習知之先前技術巾,當磁控管磁性 、♦,來, 現象,因此,係並不存在;多之球粒(n〇dule) 磁性電路之搖動動作之構想。: =進:著磁控管 解決球粒(n〇dule)問題之最適者H,發現到所謂能夠 動速度。 田之磁控管磁性電路之搖 【發明之實施形態】 以下,係根據所附之圖式,而就本發明之適當之實施形 89107738.ptd 第13頁 五、發明說明(10) 態’進行著說明。 翌係為用以絲員示出本發明每 △匕 膜裳置之圖式;係由上面而_爽\施形恶之直列型濺鍍成 置’以便於顯示出該直列型=型濺鍍成膜襄 先,係說明該滅鑛成膜裝置之内部構造。首 係在與圖12〜圖14之所說明之月 加上相同之元件編號。 ”相同之要素,附 以:匕中’係藉由各個之閘閥4°2、4〇3,而分隔開該用 ^構成為㈣成臈裝置之裝載鎖定用室m、 = 用室;。:載=室3,以便於呈串聯地配置 m ^ 焱鍍成膜至200和卸載鎖定用室300。在濺鍍成 =2 0之兩側側壁(圖i中之上下壁部),係設置有二 =徵之磁控管陰極2a〜2d。係藉由該並未圖式出之乾 ^ ^ 而對於裝載鎖定用室1 0 0和卸載鎖定用室3 0 〇,進 仃者排氣處理,並且,還藉由低溫式幫浦(cryopump ) 5a 、5 d而對於濺鍍成膜室2 0 0,進行著排氣處理。在濺鍍 成膜至2 0 0中,係藉著由圖1中之左側開始而朝向右側之並 未圖式出之盤碟搬送用機構,以便於連續地搬送著該裝設 於例^=2組之盤碟41上之例如合計4片之基板42。在搬送基 板42時’係藉由相對應之磁控管陰極2a〜2d,而對於基板 42 ’進行著濺鍍成膜處理。此外,元件編號4〇ι係為用以 搬入基板42之入口閥,而元件編號4〇4係為用以搬出基板 4 2之出口閥。箭號4 0 5係顯示出基板之搬送方向。 遭2係為圖1之濺鍍成膜裝置中之磁控管陰極2a〜2d之俯89107738.ptd Page 12 524872 V. Description of the invention (9) Circuit, on the surface of the target, the plasma area with sputtering ability is manufactured, and in the plasma area with sputtering ability, When passing through various parts of the surface of the leather, the method of making each part of the target surface stay in the plasma area for more than 1 second. # In the conventional prior art film forming device of the swing type magnetron magnetic circuit, it is preferred to the low film thickness unevenness of the nodule machine, and the material is preferred for the purpose of control = The rocking action of the circuit, therefore, is set to control the magnetron's magnetic circuit action 'so as to be able to perform the magnetron magnetization' at the highest possible speed (for example, about 0.26 seconds when shaking) ,,,, Phase = shake with conventional prior art = road problem, therefore, it can be set to 、, two ball (n0dule): to facilitate the so-called film thickness is not: moving Asia and 'shopping can solve the ball ( nodule) positive σ results, in the conventional prior art towels, when the magnetron is magnetic, the phenomenon appears, therefore, there is no existence; the motion of the nodule magnetic circuit's shaking action Conception: = Into: The most suitable person H who solved the nodule problem with the magnetron, and found the so-called moving speed. Tian Zhi's Shake of the Magnetic Circuit [Implementation Mode of the Invention] The following is based on The accompanying drawings are appropriate for the invention The implementation form 89107738.ptd Page 13 V. Description of the invention (10) State 'is explained. It is a pattern for the silk maker to show the arrangement of each △ dagger membrane of the present invention; from the top _ Shuang \ The in-line sputtering system for forming evil is used to show the in-line type sputtering deposition film. This is to explain the internal structure of the ore-depositing film-forming device. The month of the description is added with the same component number. "The same elements are attached with:" Zhongzhong "is divided by the gate valve 4 ° 2, 4 0 3, and the use of ^ is constituted as a loading device Locking room m, = using room ;. : Load = chamber 3, in order to arrange m ^ 焱 plating film to 200 and unload lock chamber 300 in series. Magnetron cathodes 2a to 2d are arranged on the two side walls (upper and lower wall portions in Fig. I) of two sides sputtered to = 20. This is not shown in the figure ^ ^ for the load lock chamber 100 and the unload lock chamber 300, the exhaust gas is treated by the inlet, and the cryopump is also used. At 5a and 5d, the sputtering film forming chamber 200 was subjected to an exhaust treatment. In the sputtering film formation to 2000, a disc transfer mechanism not shown in the figure is started from the left side in FIG. 1 to the right, so that the installation is continuously carried in the example ^ = For example, a total of four substrates 42 are mounted on the two sets of disks 41. When the substrate 42 'is transported, the substrate 42' is subjected to a sputtering film-forming process through the corresponding magnetron cathodes 2a to 2d. In addition, the component number 400 is an inlet valve for carrying in the substrate 42, and the component number 400 is an outlet valve for carrying out the substrate 42. The arrow 405 indicates the direction of the substrate. 2 is the downside of the magnetron cathodes 2a ~ 2d in the sputtering film-forming device of FIG.

89107738.ptd89107738.ptd

第14頁 524872Page 524872

524872 五、發明說明(12) 圍磁鐵’並且’這此中心磁钟4 m 之磁控管磁性電路24。在中it24 ''鐵,係形成為前述 空間中,係形成有電裝7中:果磁^ 體形狀中之元件編號7A〇fa狀之成正如圖3所示之整 知£域7人,如果再分割來看的灵 線部η、下侧直線部72和左右兩側曲=,而= 该貫施形態巾’就正如後面所敘述的,各個之直線部”在 :係垂直於磁控管磁性電路24之搖動方向,並且, 於標革巴2 0之表面上之各個部位,、灰 义 、子 =所=’:述之各個之直線部71、72,係被作為 地受到重視。 又I杈蝕只%區域,而分別 之Ϊ :卜雷:件編唬28,係為該用以施加直流電場至標靶2〇 源。而且,元件編號29 ’係為氣體導入用機構。 ::::入用機構29中,元件編號291,係為朝向著賤鍍524872 V. Description of the invention (12) The magnetron 24 of the magnetron and the central magnetic clock 4 m. In it24 ”, iron is formed in the aforementioned space, and Denso 7 is formed: the component number 7A in the shape of the fruit magnet is shaped as shown in FIG. 3, and it is known to 7 people. If the spirit line section η, the lower straight section 72, and the left and right sides are curved when viewed in further segmentation, and the constant shape pattern is' as described later, each straight section "is: perpendicular to the magnetron The direction in which the magnetic circuit 24 is shaken, and the various parts on the surface of the standard bar 20, gray meaning, sub ===: each of the linear portions 71 and 72 described above are taken seriously as ground. In addition, I etch only a% area, and the difference is as follows: Bree: Piece 28 is used to apply a DC electric field to the target 20 source. Moreover, the component number 29 'is a mechanism for introducing gas.: ::: In the application mechanism 29, the component number is 291, which is oriented toward the base plating.

As:開二狀之氣體導入用喷嘴’並且,該氣體導入 用^為291,係分別地透過質量流控制器292、2 93,而 成為減鑛用氣體來源之訐(氬氣)高壓氣體筒2以 :^成為反應性氣體來源之氧氣高壓氣體筒 另該作為濺制氣體仏(氬氣)和氧氣,導人至^賤便於 膜室2 0 0内。 守八主,賤鍍成 f濺鍍成膜室200,係透過該並未圖示出之電導式閥, =Γ f有低溫式幫浦(cryopump),以便於能夠藉由調整 者乳粗之導入流量和電導式閥之開度,而調整著濺鑛成膜 89107738.ptd 第16頁 524872 五、發明說明(13) 室200内之壓力 磁控管磁性電路24之搖動,二二磁:電路24。係隨著 上之電漿7,也在桿侍忒生成於標靶20之表面 對於標㈣面/Λ1;·?/,㈣,以便/ 蝕刻處理。在像前沭、 耆反復且不連續之濺铲 控制著馬達二=之狀1'下,控制用電路⑺: 電路272搖動著磁控管:性、之,:'。也就一是說,在控制用 上,移動著電裝7之二兹=,’而在標㈣之表面 位,呈連續地通過了 μ吏侍標靶20之表面上之各個部 域。在通過直線部7 ^直線部71之所形成之侵餘實施區 2 0之#而u ' 之所开》成之侵餘實施區域之時,4® (電漿)t之立’係連續地滯留於該侵蝕實施‘: 而控制前述之桿靶,係根據控制用電路272,_ 為1秒鐘以上。拖^Λ 上之各個部位之滯留時間,成 動速度,成為μ· 1 σ诺矹,係控制磁控管磁性電路24之挖 滅鑛钱刻時間τ,==狀態’以便於使得前述之連續 形成之侵蝕竇# r 為·即使疋在有關於直線部72之所 τ。此外,有關域’也可以適用該連續滅鑛餘刻時間 條件,而受到Λ所述之時間之上限值,係會由於其他之 係參照圖4〜ϋ,但是,係至少確保住1秒鐘之時間。 —一^Lb,而就在本實施形態之濺鍍成膜裝置 89107738.ptd 第17頁 五、發明說明(14) =無在標靶20之表面上,形成球粒(nodule)之理 田’進行著說明。 鲈^ 係^為帛以顯T出在日夺刻t1中之標把2 0之表面經過濺1 處理之狀態之圖式。該在正上方而存在有電鲂之 ς餘口 20a,就正如圖6之所顯㈣,係進行㈣錢刻處 m ^外,在侵蝕部20a之周圍之非侵蝕部,就正如圖4之 不㈣,係堆積有再附著用粒子81。在圖4所示之2個之 ,水係顯示出前述之侵蝕實施區域以之直線部” 將所^成之侵飯貫施區域之剖面。前述之各個之2個之電 水了 \係分別地具備有所謂搖動方向上之長度w。 接著,在圖5,係顯示出在時刻t 2中之標靶2 〇之表面妳 過濺鍍蝕刻處理之狀態。係藉由移動著正上方之電漿7了 以便於使得該在時刻tl時而成為非侵蝕部之部位92,成 所謂進行著濺鍍蝕刻處理之侵蝕部。部位91,係為該對應 於犄刻11時之侵蝕部之部位。由於磁控管磁性電路之搖 動速度,係成為如前面所敘述之低速度之狀態,因此,在 该於時刻11時而成為非侵餘部之部位9 2之正上方,妒過相 當充分之時間,而連續地移動著電漿7 (直線部7 2之所形 成之侵餘實施區域),結果,就正如前面所敘述的,前^ 之部位9 2之各個點,係連續地滯留在電漿7中丨秒鐘以^ a 所以,係對於時刻11時之所堆積之全部之再附著用粒子 8 1,進行著濺鍍蝕刻處理,以便於挖掘出如圖5所示之找 靶20之表面。當反覆地進行著像前述這樣之處理,而對『於 標把2 0之表面,進行著長時間之濺鑛蝕刻處理之時,在伊、As: Open the two-shaped gas introduction nozzle ', and the gas introduction ^ is 291, which passes through the mass flow controllers 292 and 293, respectively, and becomes a high-pressure gas cylinder of argon (argon) that is used as a source of reducing gas. 2: The oxygen high-pressure gas cylinder which becomes the source of the reactive gas should also be used as the sputtering gas krypton (argon) and oxygen, leading to the base film chamber 200. Shoubazhu, base plating f sputtering chamber 200, through the conductivity valve (not shown) = Γ f has a low-temperature type cryopump, so that it can be adjusted by the adjuster. The flow rate and the opening of the conductance valve are introduced, and the ore-spattering film is adjusted 89107738.ptd Page 16 524872 V. Description of the invention (13) The pressure of the magnetron 24 in the chamber 200 is shaken. twenty four. With the plasma 7 above, it is also generated on the surface of the target 20 by the pole support. For the target surface / Λ1; ·? /, ㈣ in order to / etch processing. Under the repeated and discontinuous splash shovel like the front 沭 and 耆 control the motor 2 = 1 ', the control circuit ⑺: The circuit 272 shakes the magnetron: sex, it,:'. That is to say, for control purposes, Denso 7bis is moved, and at the surface of the target, it passes through various areas on the surface of the target 20 continuously. When the encroachment implementation area 20 formed by the straight portion 7 ^ straight portion 71 is formed by the encroachment implementation area 20, the formation of 4® (plasma) t is continuous. Staying in this erosion implementation ': The control of the above-mentioned shot target is controlled by the control circuit 272, where _ is more than 1 second. The dwell time and operating speed of each part on ^ Λ become μ · 1 σ Nuo 矹, which is the time τ for controlling the magnetron magnetic circuit 24's mining time, == state, in order to make the aforementioned continuous The formed erosion sinus # r is even if it is located τ with respect to the straight portion 72. In addition, the relevant domains can also apply the condition of the remaining time of continuous ore extinction, and subject to the upper limit of time described by Λ, because other systems refer to Figure 4 ~ ϋ, but they must be kept for at least 1 second. Time. —One ^ Lb, and in the sputtering film-forming device of this embodiment 89107738.ptd Page 17 V. Description of the invention (14) = Rita where nodule is formed on the surface of the target 20 ' Explained. Perch ^ is a diagram showing the state where the surface of 20 has been treated with splash 1 in order to show the target in t1. The electric opening 20a, which is directly above, is shown in Fig. 6, as shown in Fig. 6, except for the engraved portion m ^, and the non-eroded portion around the eroded portion 20a is shown in Fig. 4 No, the particles 81 for re-adhesion are deposited. In the two shown in FIG. 4, the water system shows a cross section of the above-mentioned erosion implementation area in a straight line. The section of the invasion application area is formed. Each of the foregoing two is electro-water. The ground is provided with a length w in the so-called shaking direction. Next, in FIG. 5, the state of the surface of the target 2 0 at time t 2 has been subjected to sputtering etching treatment. The paste 7 is used so that the portion 92 that becomes a non-eroded portion at time t1 becomes a so-called etched portion subjected to sputtering etching. The portion 91 is a portion corresponding to the etched portion at 11:00. Because the rocking speed of the magnetron magnetic circuit is a low speed state as described above, therefore, immediately above the portion 92 that should become the non-invading portion at time 11 o'clock, I have been jealous for a sufficient time. And the plasma 7 (the encroachment implementation area formed by the linear portion 72) is continuously moved. As a result, as described above, each point of the front part 9 2 is continuously retained in the plasma 7 Middle 丨 seconds ^ a, so, for the time 11 o'clock All of the reattachment particles 81 are subjected to a sputter etching process in order to excavate the surface of the target 20 as shown in FIG. 5. When the process like the above is repeatedly performed, the "on the label" When the surface of 20 was subjected to a long-time ore-sputter etching process,

89107738.ptd 52487289107738.ptd 524872

524872 五、發明說明(16) 之^^為供用:顯不出標革巴2 0之利用效率、也就是標革巴2 0 婷娘二走刻處理之時間依存性之圖式。在標靶2 0之連 中,之〇·26秒鐘之濺鍍成膜裝置 用效率’係為35%,相對地,在標㈣之 f :鍍:刻處理之時間為習知之i秒鐘以上之濺鍍成膜 7 ’於在標乾20之表面上,係並無形成球粒 (no u e ),因此,係可以實現45%之標靶⑼之利用效 罕 〇 Μ回闽^為用以顯示出該成膜速度之所投入電力量之依存 # ^^。圖10中之所示之特性51,係為前述之實施 y心之動作中之成膜速度之所投入電力量之依存性。由圖 ίο係y以相當清楚地得知:如果藉由前述之實施形態之 動作的話,由於係並無形成該成為成膜速度降低之原因之 球粒(nodu 1 e ),因此,一直到該所投入之電力量成為 3 0 0W · hr/cm2為止,其成膜速度係完全並無呈降低。 圖11係為用以顯示出電孤次數之所投入電力量之依存性 =圖式。圖11中之”〇”所示之特性53,係為前述之實施形 態之動作中之電弧次數之所投入電力量之依存性。由圖 11 ’係可以相當清楚地得知:如果藉由前述之實施形態之 動作的話,由於係並無形成該成為電弧原因之球粒 (nodule ),因此,一直到該所投入之電力量成為3〇〇w · hr /cm2為止,係完全並無產生電弧。 此外’在本發明之裝置中,於磁控管磁性電路2 4之速度 相對於基板搬送速度之絕對值成為某一定值以下之狀態524872 V. Description of the invention (16) ^^ is for supply: it does not show the utilization efficiency of Biegeba 2 0, which is the time-dependent pattern of Biegeba 2 0 Ting Niang's processing. In the target 20 chain, the efficiency of the sputtering deposition film forming device of 0.26 seconds is 35%. In contrast, the time of the f: plating: engraving process in the target is more than the conventional i second. The sputtering film 7 ′ on the surface of the standard 20 does not form no ues. Therefore, the system can achieve the utilization efficiency of 45% of the target target. The dependence of the amount of input power on the film formation speed is shown as # ^^. The characteristic 51 shown in FIG. 10 is the dependency of the amount of input power on the film-forming speed in the aforementioned operation of performing the core operation. From the figure, it is clear that y, if the action of the foregoing embodiment is used, no spheres (nodu 1 e) that are the cause of the decrease in film-forming speed are formed. Until the amount of power input was 300 W · hr / cm2, the film-forming speed did not decrease at all. Fig. 11 is a graph showing the dependency of the amount of input power on the number of electric isolations. The characteristic 53 shown by "0" in Fig. 11 is the dependence of the amount of electric power inputted on the number of arcs in the operation of the aforementioned implementation form. From Fig. 11 ', it can be clearly understood that if the operation of the aforementioned embodiment is used, the system does not form the nodule which is the cause of the arc. Therefore, until the amount of electric power input becomes Up to 300w · hr / cm2, no arc was generated at all. In addition, in the device of the present invention, the absolute value of the speed of the magnetron magnetic circuit 24 with respect to the substrate transfer speed becomes a certain value or less.

89107738.ptd89107738.ptd

第20頁 524872 五、發明說明(17) ----- 時,係在基板42上,沿著基板搬送方向,而會有 和膜質呈不均勻之現象發生。但是,係可以藉由=直二 特願平第1 0 -6 6 1 78號之所揭示之技術,而消除像前揭 之膜厚和膜質呈不均勻之現象。 化樣 此外,雖然前述之實施形態之濺鍍成膜裝置, ,賤鍍成膜裝置,但是,本發明係也可以被適用 矢員之濺鍍成膜裝置、例如在止美 ' 牙 之扇葉型濺铲成胺狀 板上而形成該濺鍍膜Page 20 524872 V. Description of the invention (17) ----- When it is attached to the substrate 42 and along the substrate conveying direction, unevenness with the film quality may occur. However, it is possible to eliminate the non-uniformity of the film thickness and film quality as previously disclosed by the technique disclosed by No. 2 Takahei No. 10-6-6178. In addition, although the sputtering film-forming device and the base film-forming device of the foregoing embodiments are used, the present invention can also be applied to the sputtering film-forming device of Yamoto, such as the blade of the tooth Type sputtering shovel into amine-like plate to form the sputtering film

Ii成鍍成膜裊置和分批式濺鍍成膜裝置 在本杳明中,該作為用以進行著 4此外, 子,則除了前述之ITO胺/ 處之薄膜之例 電膜)之外’係也可以上Γ0 (銦—錫-氧)系透明導 而發生有球粒(n〇duie u:您:相著用粒子之原因 (ZnO )、皆、 象之乳化銦(In2〇3 )、氧化辞 雖缺 火和鍺銻碲(GeSbTe )等。 _電:匕實:?態:,係假定在有關於電浆生成之 態下,如果標把;面= =電或者間歇放電 也能夠發揮= ;理時間τ之條件的話,係 【發明之致果】 文果。 明=上ίί:控;:=當清楚地得知:如果藉由本發 ,此’在標乾之ΪΠ性動速度,成為低速度, 象,而得到良好之桿靶之刹田s形成球粒(nodule )現 並不會發生有經時變化,而 並且’其成膜速度係 此夠付到所謂並不會有由於電 89107738.ptd 第21頁 524872 五、發明說明(18) 弧之發生之所帶來之基板之外觀損傷以及基板上之所附著 之ITO膜(In-Sn-0 (銦-錫-氧)系透明導電膜)之膜質呈 劣化之現象發生之效果。此外,由於係並無進行著所謂切 削掉球粒(nodu 1 e )之作業,因此,係可以提高裝置之運 轉利用率,並且,還能夠提升其生產效率。 【元件編號之說明】 T :濺鍍所需要之時間 11 :時刻 12 :時刻 v :磁控管磁性電路之搖動速度 w :侵蝕實施區域之搖動方向上之長度 2a •磁 控 管 2b :磁 控 管 2c :磁 控 管 2d :磁 控 管 5a :低 溫 式 5b :低 溫 式 5c :低 溫 式 5d :低 溫 式 6 : 磁力線 7 : 電漿 7A :侵 ik 實 20 ••標 靶 2 0 a :侵姓部 cryopump cryopump cryopump cryopumpIi plating and film deposition and batch-type sputtering filming devices are used in this document to carry out 4 methods, in addition to the above-mentioned ITO amine / film (such as the electrical film) The 'system' can also be transparent with Γ0 (indium-tin-oxygen) system and nodules (n〇duie u: you: the reason for the use of particles (ZnO), the same as the emulsified indium (In2〇3) Although the oxidant is lacking in fire and germanium antimony tellurium (GeSbTe), etc. _Electricity: Reality:? State: It is assumed that in the state of plasma generation, if the indicator; surface = = electricity or intermittent discharge can also be Exercising the condition of time τ is the fruit of [invention]. Ming = 上 ίί: 控;: = When it is clear that if you use this hair, the speed of sexual movement in the standard. Becomes a low-speed phenomenon, and the brake field s forming a nodule with a good shot target will not change over time, and its film-forming speed is sufficient to meet the so-called no Due to electricity 89107738.ptd Page 21 524872 V. Description of the invention (18) The appearance damage of the substrate caused by the occurrence of the arc and the attachment on the substrate The ITO film (In-Sn-0 (In-Sn-O) transparent conductive film) has the effect of deteriorating the film quality. In addition, the so-called nodu 1 e Therefore, it can improve the operating utilization rate of the device, and also improve its production efficiency. [Explanation of the component number] T: the time required for sputtering 11: time 12: time v: the magnetron magnetic circuit Shaking speed w: length 2a in the shaking direction of the erosion area 2 magnetron 2b: magnetron 2c: magnetron 2d: magnetron 5a: low temperature type 5b: low temperature type 5c: low temperature type 5d: low temperature type 6 : Magnetic field line 7 : Plasma 7A: Invasion IK 20 •• Target 2 0 a: Invasion department cryopump cryopump cryopump cryopump

89107738.ptd 第22頁 524872 五、 發明說明(19) 21 :内 概 板 22 ••陰 極 體 23 :鐵 氟 龍 板 24 :磁 控 管 磁 永久磁鐵) 24a 24b 25 26 27 28 29 41 42 51 53 54 71 72 73 81 82 83 91 92 :中心磁鐵 :外圍磁鐵 曲轴棒 圓盤 圓盤 直流電源 氣體導入用機構 盤碟 基板 特性 特性 特性 上側直線部 下側直線部 左右兩側曲線部 再附著用粒子 變質物 挖掘殘餘部 部位 部位89107738.ptd Page 22 524872 V. Description of the invention (19) 21: Inner plate 22 • • Cathode body 23: Teflon plate 24: Magnetron permanent magnet) 24a 24b 25 26 27 28 29 41 42 51 53 54 71 72 73 81 82 83 91 92: Center magnet: Peripheral magnet Crank rod Disc Disk DC power supply gas plate mechanism Characteristics of the disc characteristics Upper linear part Lower linear part Excavation

89107738.ptd 第23頁 524872 五、發明說明 (20) 100 裝 載 鎖 定 用 室 200 濺 鍍 成 膜 室 201 壁 部 241 箭 號 ( 振 幅 ) 271 馬 達 272 控 制 用 電 路 291 氣 體 導 入 用 喷嘴 292 質 量 流 控 制 器 293 質 量 流 控 制 器 294 Ar ( 氬 ) 壓氣體 筒 295 〇2 (. 氡 ) 南壓氣體 筒 300 卸 載 鎖 定 用 室 401 入 口 閥 402 閘 閥 403 閘 閥 404 出 π 閥 405 基 板 搬 送 方 向89107738.ptd Page 23 524872 V. Description of the invention (20) 100 Load lock chamber 200 Sputtered film chamber 201 Wall 241 Arrow (amplitude) 271 Motor 272 Control circuit 291 Gas introduction nozzle 292 Mass flow controller 293 Mass flow controller 294 Ar (argon) gas cylinder 295 〇2 (. 氡) South pressure gas cylinder 300 Unlocking chamber 401 Inlet valve 402 Gate valve 403 Gate valve 404 Out π valve 405 Substrate transfer direction

89107738.ptd 第24頁 524872 圖式簡單說明 圖1係為本發明之實施形態之濺鍍成膜裝置之俯視 圖。 圖2係為用以說明磁控管陰極之構造之俯視概略圖。 圖3係為用以顯示出該根據電漿之所形成之侵飯實施巴 域之整體形狀之俯視圖。 D〇 圖4係為用以顯示出在磁控管陰極中之標革巴經過錢錢餘 刻處理之第1狀態之圖式。 &89107738.ptd Page 24 524872 Brief description of drawings Figure 1 is a top view of a sputtering film-forming device according to an embodiment of the present invention. Fig. 2 is a schematic plan view for explaining the structure of a magnetron cathode. FIG. 3 is a plan view showing the overall shape of the rice paddle implemented by the plasma. D〇 FIG. 4 is a diagram for showing the first state of the standard bar in the cathode of the magnetron after being processed for a long time. &

圖5係為用以顯示出在磁控管陰極中之標革巴經過錢鍍餘 刻處理之第2狀態之圖式。 X 圖6係為進行者長時間》賤鍛飯刻處理之標革巴之剖面圖。 圖7係為磁控管磁性電路之搖動速度之位置依存性之圖 式。 圖8係為用以顯示出連續丨賤鍍钱刻時間和標革巴利用效率 之間之關係之圖式。 圖9係為用以顯示出習知之先前技術之濺鍍成膜裝置中 之磁控管磁性電路之搖動速度之位置依存性之圖式。 圖1 〇係為用以顯示出該所投入之電力量和成膜速度之間 之關係之圖式。 Β 圖11係為用以顯示出該所投入之電力量和電弧次數之間 之關係之圖式。 圖1 2係為用以顯示出在習知之先前技術之磁控管陰極中 之標把經過濺鍍蝕刻處理之第1狀態之圖式。 圖1 3係為用以顯示出在習知之先前技術之磁控管陰極中 之標把經過濺鍍蝕刻處理之第2狀態之圖式。Fig. 5 is a diagram showing the second state of the standard magnet in the cathode of the magnetron after the coin plating is processed. X Figure 6 is a cross-sectional view of the standard leather bar that was processed by the performer for a long time. Fig. 7 is a diagram showing the position dependence of the shaking speed of the magnetron magnetic circuit. Fig. 8 is a diagram for showing the relationship between the continuous time of cheap money plating and the utilization efficiency of standard leather. Fig. 9 is a diagram showing the position dependence of the shaking speed of a magnetron magnetic circuit in a conventional prior art sputtering film forming apparatus. Fig. 10 is a diagram showing the relationship between the amount of electric power input and the film forming speed. Β Figure 11 is a graph showing the relationship between the amount of electric power input and the number of arcs. Fig. 12 is a view showing the first state of the target in the known prior art magnetron cathode subjected to sputtering etching. Fig. 13 is a diagram showing the second state of the target in the known prior art magnetron cathode subjected to sputtering etching.

89107738.ptd 第25頁 524872 圖式簡單說明 圖1 4係為用以顯示出在習知之先前技術之磁控管陰極中 之所形成之球粒(η 〇 d u 1 e )之剖面圖。 ilii 89107738.ptd 第26頁89107738.ptd Page 25 524872 Brief description of the drawings Figure 14 is a cross-sectional view showing the pellets (η 〇 d u 1 e) formed in a conventional prior art magnetron cathode. ilii 89107738.ptd Page 26

Claims (1)

52 52 9ί, 5· ί3 修正52 52 9ί, 5 · ί3 correction yju 5 · 修正 1 · 一種濺鍍成膜裝置,其係具備有··與存在於濺 室(200)内之基板(42)相對配置的標靶(20);以及設^於、 该標靶(2 0 )之背面上的磁控管磁性電路(2 4 ),該裝置至;小 沿著一方向,而搖動前述磁控管磁性電路(24),以便於= W述基板(4 2 )之表面上進行濺鍍成膜處理,其特徵為: 具備有控制機構,係控制前述磁控管磁性電路(之搖 d’J:於根據前述磁控管磁性電路(24),而在前述 =,(20)之表面上,製造出具備有濺鍍能力之電漿區域, 钿⑴’、在該具備有濺鍍能力之電漿區域,通過前述標 邻位ΪΪ之各個部位時,使得前述標靶(2〇)表面之各個 4位,連績地滯留在前述電漿區域中丨秒鐘以上之時門 設2置;Ϊ =形成方法,其係至少沿著…,而㈣ 磁性電路明己f成為ί對著基板之標靶之背面上的磁控管 理,其特徵^更於在前述基板之表面上進行滅鑛成膜處 電ί動:= f性電路’以便於根據前述磁控管磁性 電毁區::靶之表面·^ ’製造出具備有踐鍍能力之 前述彳* 2 #、且,在該具備有濺鍍能力之電漿區域,通過 位,;Ϊί:,各個部位時,使得前述標乾表面之各個部 只⑼遠在前述之電漿區域中1秒鐘以上之時間。yju 5 · Amendment 1 · A sputtering film-forming device provided with a target (20) arranged opposite to a substrate (42) existing in a sputtering chamber (200); and (2 0) on the back of the magnetron magnetic circuit (2 4), the device to; small along a direction, while shaking the aforementioned magnetron magnetic circuit (24), so that = W described substrate (4 2) The surface is subjected to sputtering and film-forming treatment, which is characterized by: equipped with a control mechanism that controls the aforementioned magnetron magnetic circuit (the d'J: based on the aforementioned magnetron magnetic circuit (24), and in the aforementioned = , On the surface of (20), a plasma region with a sputtering capability is manufactured, 钿 ⑴ ′, when the plasma region with a sputtering capability passes through each part of the adjacent mark, the foregoing mark is made. Each of the 4 bits on the surface of the target (20) stays in the plasma area for more than one second in a row; 门 = the formation method, which is at least along ... f becomes the magnetron management on the back of the target facing the substrate, and its features are more on the surface of the aforementioned substrate The electric deactivation at the ore-depositing film formation: = f circuit to facilitate the magnetic and electrical destruction of the magnetron according to the aforementioned :: the surface of the target · ^ 'produce the aforementioned 具备 * 2 # with plating ability, and The plasma area with the sputtering capability passes through the position; at each location, each part of the standard surface is kept far from the plasma area for more than 1 second. 第27頁Page 27
TW089107738A 1999-06-01 2000-04-25 Sputtering film formation device and process of sputtering film formation TW524872B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15360399A JP4453850B2 (en) 1999-06-01 1999-06-01 Sputtering film forming apparatus and sputtered film forming method

Publications (1)

Publication Number Publication Date
TW524872B true TW524872B (en) 2003-03-21

Family

ID=15566105

Family Applications (1)

Application Number Title Priority Date Filing Date
TW089107738A TW524872B (en) 1999-06-01 2000-04-25 Sputtering film formation device and process of sputtering film formation

Country Status (3)

Country Link
JP (1) JP4453850B2 (en)
KR (1) KR100367318B1 (en)
TW (1) TW524872B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI399448B (en) * 2007-09-21 2013-06-21 Hon Hai Prec Ind Co Ltd Aparatus and method of sputtering deposition
TWI400347B (en) * 2007-08-10 2013-07-01 Hon Hai Prec Ind Co Ltd Apparatus and method of sputtering deposition

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5380784B2 (en) 2007-04-12 2014-01-08 ソニー株式会社 Autofocus device, imaging device, and autofocus method
JP4336739B2 (en) 2007-06-04 2009-09-30 キヤノンアネルバ株式会社 Deposition equipment
KR102054533B1 (en) * 2011-11-04 2019-12-10 인테벡, 인코포레이티드 Linear scanning sputtering system and method
US10106883B2 (en) 2011-11-04 2018-10-23 Intevac, Inc. Sputtering system and method using direction-dependent scan speed or power
KR101689016B1 (en) 2015-03-13 2016-12-22 (주) 씨앤아이테크놀로지 In-line Sputtering System with Rotary Tray Holders and Manufacturing Method of Packages Shielding Thereof
JP6746011B2 (en) * 2018-06-26 2020-08-26 株式会社アルバック Film forming method and film forming apparatus
JP7242293B2 (en) * 2018-12-27 2023-03-20 キヤノントッキ株式会社 Film forming apparatus, film forming method, and electronic device manufacturing method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI400347B (en) * 2007-08-10 2013-07-01 Hon Hai Prec Ind Co Ltd Apparatus and method of sputtering deposition
TWI399448B (en) * 2007-09-21 2013-06-21 Hon Hai Prec Ind Co Ltd Aparatus and method of sputtering deposition

Also Published As

Publication number Publication date
KR100367318B1 (en) 2003-01-09
KR20010014752A (en) 2001-02-26
JP4453850B2 (en) 2010-04-21
JP2000345335A (en) 2000-12-12

Similar Documents

Publication Publication Date Title
TW524872B (en) Sputtering film formation device and process of sputtering film formation
Arnell et al. Recent advances in magnetron sputtering
TW200916598A (en) Sputter coating device and method of depositing a layer on a substrate
US4600490A (en) Anode for magnetic sputtering
WO2004055233A1 (en) Transparent conductive film and film forming method therefor
CN105018880A (en) System and method for sputtering a tensile silicon nitride film
JP2003524706A5 (en)
EP0861921A1 (en) Deposition of titanium nitride films
CN104992905A (en) Boron nitride substrate surface step etching method
CN106282639A (en) A kind of platinum-nickel alloy sputtering target material and preparation method thereof
Krantzman et al. Cluster induced chemistry at solid surfaces: Molecular dynamics simulations of keV C60 bombardment of Si
JP4670530B2 (en) Noble metal electrode for electrolysis and method for producing the same
CN102051497B (en) Preparation methods of gold and silver embedded target and film thereof
CN103924200B (en) A kind of film deposition apparatus
CN110429160A (en) A kind of high brightness PSS compound substrate and preparation method thereof
CN101956160B (en) Method for evaporating metal film on surface of flexible substance in gas scattering way
CN1940136A (en) Magnesium-alloy surface treatment
JPS59179784A (en) Sputtering device
Jablonka et al. Metal filling by high power impulse magnetron sputtering
CN101570851B (en) Method for applying magnetic field to sputtering coated cathode
JP5003667B2 (en) Thin film manufacturing method and thin film manufacturing apparatus
CN112981333A (en) Preparation method of refined crystal grain type high-aluminum coating for difficult-to-machine material
JP3602861B2 (en) Method of forming metal silicide film
CN109735818A (en) A kind of toner cartridge preparation method of combination high-power impulse magnetron sputtering technology
TWI327178B (en) Method for surface treatment of magnesium alloy and product thereof

Legal Events

Date Code Title Description
GD4A Issue of patent certificate for granted invention patent
MK4A Expiration of patent term of an invention patent