TW505997B - Local formation method of self-aligned metal silicide - Google Patents
Local formation method of self-aligned metal silicide Download PDFInfo
- Publication number
- TW505997B TW505997B TW90118552A TW90118552A TW505997B TW 505997 B TW505997 B TW 505997B TW 90118552 A TW90118552 A TW 90118552A TW 90118552 A TW90118552 A TW 90118552A TW 505997 B TW505997 B TW 505997B
- Authority
- TW
- Taiwan
- Prior art keywords
- layer
- gates
- oxide layer
- forming
- diffusion regions
- Prior art date
Links
Landscapes
- Electrodes Of Semiconductors (AREA)
- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
Description
五、發明說明d) 5 - 1發明領域: θ 本發明係為一種形成自 是有關於一種在部分區域形 以順利在周邊電路區域與晶 邊電路區域上之擴散區域形 件獲得較低之電阻,且較不 對' 準金屬矽化物之方法,特別 成自對準金屬石夕化物之方法, 胞陣列區域上的閘極區域及周 成金屬矽化物,以使半導體元 會產生漏電流之缺陷。 5 - 2發明背景: ^ 一 當凡件的積集度(integrity)增加,使金氧半電晶體 元件的源極/汲極(source/drain)的電阻,逐漸的上升到 與金氧半電晶體元件通道(channel)的電阻相當時,為了 调降源極/沒極的片電阻(sheet resistance),並確保金 屬與金氧半電晶體間的「淺接合(s h a 1 1 〇 w j u n c t i ο η )」之 元正’種稱為「自行對準金屬石夕化物(self-aligned s i 1 i c i d e )」製程的應用,便漸漸地走入〇 . 5微米(m i c r 0 n ; // m)以下的超大型積體電路(very large scale integration; VLSI)製程。這個製程又因此而簡稱為自對 φ 準金屬矽化物(salic ide)製程。 一般最常用之金屬矽化物當首推鈦矽化物。鈦矽化物 之形成’一般皆採用兩階段快速加熱製程(r a p丨d t h e r m a 1V. Description of the invention d) 5-1 Field of the invention: θ The present invention relates to a shape formed in a partial area to smoothly obtain a low resistance in a diffusion area shape on a peripheral circuit area and a crystal edge circuit area. In addition, the method of quasi-metal silicide, especially the method of self-aligned metal silicide, the gate region on the cell array area and the surrounding metal silicide, so that the semiconductor element will generate the defect of leakage current. 5-2 Background of the Invention: ^ Once the integration of all parts is increased, the resistance of the source / drain of the metal-oxide-semiconductor element gradually rises to that of the metal-oxide-semiconductor. When the resistance of the channel of the crystal element is equivalent, in order to reduce the sheet resistance of the source / non-electrode and ensure the "shallow junction (sha 1 1 〇wjuncti ο η) between the metal and the metal-oxide semiconductor transistor" The application of "Zhengyuan's" type of process called "self-aligned si 1 pesticide" has gradually entered the ultra-lower than 0.5 micron (micr 0 n; // m) Very large scale integration (VLSI) process. This process is therefore simply referred to as the self-pairing salicide process. In general, the most commonly used metal silicide is titanium silicide. Titanium silicide formation ’generally uses a two-stage rapid heating process (r a p 丨 d t h e r m a 1
505997 五、發明說明(2) process; RTP)方式。首先,參照第一圖所示,提供一石夕 底材1 0,在底材1 〇上已經形成金氧半電晶體及淺渠溝隔離 層3 0。此金氧半電晶體具有源極/沒極1 2、閘極以及在閑 極的側壁形成間隙壁(s p a c e r ) 1 8,且此閘極至少包含間極 氧化物層1 4與多晶矽層1 6,然後以化學氣相沉積法( chemical vapor deposition; CMP)或是磁控直流電錢鍍 法(direct current magnetron sputtering)沉積一層鈦 金屬層2 0於底材1 0上,此鈦金屬層2 0的厚度大約為3 〇 〇埃 。接下來,進行第一快速加熱製程,使鈦金屬與接觸處之 矽層反應,以形成鈦矽化物,其厚度大約在6 〇 〇至7 間。此時的鈦矽化物的結構主要是電阻值龢古 、之 阻罕又阿之c - 4 9相的 結構。參照第二圖所示,利用RCA清洗的方十办本 ^ 與反應或反應後所殘留的鈦金屬,而將叙功^ Λ ’、 冬 π紙矽化合物 在金氧半電晶體的最表面上。此未參血;i虛上 "LL^ 〃 X應或反廍抬% 第二快速加熱製程,將C-49相之鈦矽化物 值較低的C - 5 4相之結構 結構轉換成電阻 留的鈦金屬不見得一定是以鈦的形式留下來 曰厂俊所殘 篦二換诚加埶邀裎,將C-49相之鍅功儿^ ° t I再執行 在深次微米元件的製程中,為了避免、、 串聯電阻引起之電晶體驅動電流衰退,對、原極人及極寄生 矽化處理乃為一重要且廣為應用的製程技彳^極人及^極加以 純之源極/汲極矽化處理,或由自行對準金T °此可藉由單 來達成。自行對準金屬矽化物製程可同日士土 ^屬石夕化物製程 與閘極之矽化處理。 了7^成源極/汲極 505997 五、發明說明(3) 在目前之邏輯電路上,也需要使用金屬矽化物以降低 傳導層之電阻並增加半導體元件之品質。但是為了配合在 邏輯電路的運作,在邏輯電路上有部分之區域不能形成金 屬矽化物,以防止半導體元件發生漏電流之缺陷。而傳統 的自對準金屬矽化物製程,若要在部分材料上形成金屬矽 化物,則必須經過相當複雜之程序,才能在所需之區域上 形成金屬矽化物。因此在目前講求效率之半導體製程中, 傳統較為耗時的步驟已無法配合目前之半導體製程。 5 - 3發明目的及概述: 鑑於上述的發明背景中,利用傳統的方法無法快速地 在邏輯電路上局部形成金屬矽化物,本發明主要的目的為 利用一氧化物層作為遮罩層,順利在周邊電路區域與晶胞 陣列區域上的閘極及周邊電路區域上之擴散區域形成金屬 矽化物,以降低晶胞陣列區域周邊電路區域之字元線( word 1 i ne )的電阻。 1 本發明的第二個目的為利用一氧化物層作為遮罩層, 順利在周邊電路區域與晶胞陣列區域上的閘極及周邊電路 區域上之擴散區域形成金屬矽化物,以避免晶胞陣列區域 上之擴散區域發生漏電流之缺陷。505997 V. Description of the invention (2) process; RTP) method. First, referring to the first figure, a stone substrate 10 is provided, and a gold-oxygen semi-transistor and a shallow trench isolation layer 30 have been formed on the substrate 10. The metal-oxide semiconductor transistor has a source / an electrode 1 2, a gate and a spacer 1 8 formed on a side wall of the free electrode, and the gate includes at least an interlayer oxide layer 14 and a polycrystalline silicon layer 1 6 Then, a chemical vapor deposition (CMP) method or a direct current magnetron sputtering method is used to deposit a titanium metal layer 20 on the substrate 10, and the titanium metal layer 20 The thickness is about 300 Angstroms. Next, a first rapid heating process is performed to make the titanium metal react with the silicon layer at the contact to form a titanium silicide, which has a thickness of about 600-7. The structure of the titanium silicide at this time is mainly the resistance value and the structure of the c-49 phase. With reference to the second figure, the RCA cleaning method and the titanium residue remaining after the reaction are used, and the Sungong ^ Λ and winter π paper silicon compounds are on the outermost surface of the gold-oxygen semi-electric crystal. . This blood is not involved; i is deficient " LL ^ 〃 X should be reversed or increased by the second rapid heating process to convert the C-49 phase C-5 49 phase structure with lower titanium silicide value into resistance The remaining titanium metal may not necessarily be left in the form of titanium. It is said that the remnants of the factory have been changed for the first time, and the C-49 phase can be used to perform the process of deep sub-micron components. In order to avoid the degradation of the transistor drive current caused by series resistance, the primary and parasitic silicidation is an important and widely used process technology. Extremely pure and extremely pure source / The silicide treatment of the drain electrode, or self-aligned gold T ° can be achieved by a single. The self-aligned metal silicide process can be performed in the same way as the Japanese Shixun process and the gate silicide process. It has become a source / drain 505997. V. Description of the invention (3) In current logic circuits, metal silicides are also needed to reduce the resistance of the conductive layer and increase the quality of semiconductor devices. However, in order to cooperate with the operation of the logic circuit, a metal silicide cannot be formed in a part of the logic circuit to prevent the defect of leakage current of the semiconductor device. In the conventional self-aligned metal silicide process, if a metal silicide is to be formed on some materials, it must go through a quite complicated process to form a metal silicide on the required area. Therefore, in the current semiconductor process that requires efficiency, the traditional time-consuming steps can no longer match the current semiconductor process. 5-3 Objects and Summary of the Invention: In view of the above background of the invention, conventional methods cannot be used to quickly form a metal silicide locally on a logic circuit. The main purpose of the present invention is to use an oxide layer as a masking layer. A metal silicide is formed in the peripheral circuit region, the gate on the cell array region, and the diffusion region on the peripheral circuit region to reduce the resistance of word lines (word 1 in) in the peripheral circuit region of the cell array region. 1 The second object of the present invention is to use an oxide layer as a masking layer to smoothly form a metal silicide on the gates on the peripheral circuit region and the cell array region and on the diffusion region on the peripheral circuit region to avoid the cell A defect of leakage current occurs in a diffusion region on the array region.
505997 五、發明說明(4) 本發明的第三個目的為利用一氧化物層作為遮罩層, 順利在周邊電路區域與晶胞陣列區域上的閘極及周邊電路 ' 區域上之擴散區域形成金屬矽化物,以減少周邊電路區域 上之電阻。 本發明的第四個目的為利用一氧化物層作為遮罩層, 順利在周邊電路區域與晶胞陣列區域上的閘極及周邊電路 區域上之擴散區域形成金屬矽化物,以提高半導體元件之 品質。 ⑩ 本發明之再一個目的為利用一氧化物層作為遮罩層, 順利在周邊電路區域與晶胞陣列區域上的閘極及周邊電路 區域上之擴散區域形成金屬矽化物,以提高半導體元件之 製程運作效率。 根據以上所述之目的,本發明提供了一項方法,利用 一氧化物層作為遮罩層,順利在周邊電路區域與晶胞陣列 區域上的閘極及周邊電路區域上之擴散區域形成金屬矽化 物,以降低晶胞陣列區域及周邊電路區域之字元線的電阻 並避免晶胞陣列區域上之擴散區域發生漏電流之缺陷。本 發明之方法也可減少周邊電路區域上之電阻。本發明之方 法更可提高半導體元件之品質並提高半導體元件之製程運 作效率。505997 V. Description of the invention (4) The third object of the present invention is to use an oxide layer as a masking layer to smoothly form a gate on a peripheral circuit region and a cell array region and a diffusion region on a peripheral circuit region. Metal silicide to reduce resistance in peripheral circuit areas. A fourth object of the present invention is to use an oxide layer as a masking layer to smoothly form metal silicides on the gates on the peripheral circuit region and the cell array region, and on the diffusion regions on the peripheral circuit region, so as to improve the semiconductor device. quality.再 Another object of the present invention is to use an oxide layer as a masking layer to successfully form a metal silicide on the peripheral circuit region, the gate on the cell array region, and the diffusion region on the peripheral circuit region to improve the semiconductor device. Process operation efficiency. According to the above-mentioned object, the present invention provides a method for successfully forming metal silicidation on a gate electrode on a peripheral circuit region and a cell array region and a diffusion region on a peripheral circuit region by using an oxide layer as a mask layer. In order to reduce the resistance of the word lines in the cell array region and the peripheral circuit region, and to avoid the defect of leakage current in the diffusion region on the cell array region. The method of the present invention can also reduce the resistance in the peripheral circuit area. The method of the present invention can further improve the quality of the semiconductor device and the process operation efficiency of the semiconductor device.
第8頁 505997 五、發明說明(5) 5 - 4發明詳細說明: 本發明的一些實施例會詳細描述如下。然而,除了詳 細描述外,本發明還可以廣泛地在其他的實施例施行,且 本發明的範圍不受限定,其以之後的專利範圍為準。 線的 元線 位元 )#字 6 ο η •1 件 元 d r體 ο - W導 C半 線之 元上 字路 由電 藉輯 •d^· 4ST. 是邏 要接 主連 路來 \)/ e 輯 η 邏1 t • 1 b 類接 之連 號線 訊元 定位 判而 為, 則極 的閘 目之 之件 線元 元體 位導 而半 ,至 置接 位連 之線 號元 訊字 義此 定因 為, 的型 極 及 />資 極輸 源傳 之度 上速 件輸 元傳 體之 導高 半較 至有 料 言 而 線 元 字 於 對 要 需 其 法 方 之 明 發 本 用 利 須 必 此 因 降 以 物 化 矽 〇 金度 一速 成輸 形傳 上之 極線 閘元 之字 件高 元提 體, 導阻 半電 及之 線線 元元 字字 在低 晶域 為區 域列 區陣 一胞 之晶 〇 其域 ,區 域路 區電 大邊 兩周 為為 分則 區域 要區 主一 上另 路, 電域 輯區 邏列 胞 列算 *-el^3一 一 胞及 晶導 在傳 存為 儲則 式能 模功 的之 荷域 電區 以路 料電 資邊 將周 ,而 料。 資内 存之 儲件 為元 能存 功儲 法藉必 減並件 是後元 或之的 器完域 法理區 加處列 是,陣 像理胞 ,處晶 件行此 元進因 之料。 内資域 域之區 區理他 路處其 電需致 邊所導 周對傳 由,路 藉件電 ,元邊 料等周 資器由Page 8 505997 V. Description of the invention (5) 5-4 Detailed description of the invention: Some embodiments of the present invention will be described in detail as follows. However, in addition to the detailed description, the present invention can also be widely implemented in other embodiments, and the scope of the present invention is not limited, which is subject to the scope of subsequent patents.线 的 元 线 位元) # 字 6 ο η • 1 piece of dr bodyο-W-guide C half-line of the word on the word routing borrowing series • d ^ · 4ST. It is logical to connect to the main link \) / e series η logic 1 t • 1 b connected serial line cell positioning judgment, then the position of the line element of the pole is half, until the connected line serial number word meaning It must be because the type of the electrode and the degree of transmission of the source and the source of the speed of the speed of the speed of the transmission element transmission body is more than half as high as expected. Due to the high-level lifting of the polar wire gate element on the rapid transmission of physical silicon, the conductive semi-electric element and the wire element element are in the low crystal domain as a regional array. The domain of the crystal, the two sides of the area of the electric road in the regional road area are divided into two parts, and the main area of the electric area is on the other side. The logical area of the electric area is counted as * -el ^ 3, and the crystal guide is stored. The electric field of the charge area for the storage mode energy model will be rounded off by road materials and materials. The internal storage of the asset is the element energy storage. The power storage method must be subtracted and the merged part is the ancestor or the end of the domain. The legal area is added. Yes, the array cell is the source of the element. Domestically-owned districts, districts, other roads, other roads, electricity demand, side guides, weekly pass, road borrowing, yuan, etc.
505997 五、發明說明(6) 須個別獨立以防止因短路的缺陷所造成資料的流失。而周 邊電路區域之元件則必須相互連結,以加快資料之處理速 度。所以必須運用本發明之方式,在周邊電路區域上之閘 極與擴散區域上形成金屬矽化物,同時在晶胞陣列區域上 之閘極形成金屬矽化物,並避免金屬矽化物形成於晶胞陣 列區域上的擴散區域’以加快周邊電路區域之貢料傳輸能 力與資料運算能力,並防止晶胞陣列區域發生漏電流之現 象而導致貧料的流失。 參照第三圖所示,首先提供一包含底材1 0 0之晶圓並 在底材1 0 0上形成一第一氧化物層1 2 0,接下來在此第一氧 化物層1 2 0上形成一第一氮化物層1 4 0,最後在此第一氮化 物層1 4 0上形.成一第二氧化物層1 6 0。通常此第一氧化物層 1 2 0之厚度約為7 0至9 0埃,第一氮化物層1 4 0之厚度約為6 0 至8 0埃,而第二氧化物層1 6 0之厚度大約為6 0至8 0埃。在 目前的製程中通常採用第一氧化物層1 2 0的厚度為8 0埃, 第一氮化物層1 4 0的厚度為7 0埃,而第二氧化物層1 6 0的厚 度則為7 0埃。但是隨著製程寬度曰漸縮小,第一氧化物層 1 2 0、第一氮化物層1 4 0與第二氧化物層1 6 0之厚度也必須 隨著縮小,以符合製程上之需求。 參照第四圖所示,接下來在晶圓上定義晶胞陣列區域 1 0 4與周邊電路區域1 0 2後,藉由一微影( photolithography)及I虫刻(etching)之方式移除周邊電路 505997 五、發明說明(7) 區域1 0 2上之第一氧化物層1 2 0、第一氮化物層1 4 0與第二 . ] 氧化物層1 6 0,使周邊電路區域102露出底材。參照第五圖 所示,在周邊電路區域1 0 2之底材上形成一第三氧化物層 ' 2 0 0,此第三氧化物層2 0 0之厚度約為4 0至6 0埃,在目前之 製程中,第三氧化物層2 0 0之厚度通常為5 0埃。但是隨著 製程寬度曰漸縮小,第三氧化物層2 0 0之厚度也必須隨著 縮小,以符合製程上之需求。通常第一氧化物層1 2 0、第 二氧化物層1 6 0及第三氧化物層2 0 0之材料為二氧化石夕( s i 1 i c ο n d i ο X i d e ),而氮化物層1 4 0的材料通常為氮化石夕( siliconnitride)。 傷 在本實施例中,晶圓上的晶胞陣列區域與周邊電路區 域在底材上採用不同形式之介電層。在晶胞陣列區域上採 用氧化物/氮化物/氧化物的三明治型態作為介電層,而在 周邊電路區域則採用單——層氧化物作為介電層。隨著製 程需求之不同’在晶胞陣列區域與周邊電路區域在底材上 也可採用相同形式之介電層以發揮半導體元件之效能。此 介電層可為一氧化物層。 參照第六圖所示,形成一矽層3 0 0於第二氧化物層1 6 0 L· 與第三氧化物層2 0 0之上,並施以一再氧化(reoxide)之製 程以在矽層上形成一第四氧化物層2 2 0。此矽層3 0 0為一閘 極層而此第四氧化物層2 2 0為一緩衝層。接下來在第四氧 化物層2 2 0上形成一第二氮化物層2 4 0。此緩衝層之目的為505997 V. Description of Invention (6) It must be independent to prevent the loss of data due to short circuit defects. Components in the peripheral circuit area must be interconnected to speed up data processing. Therefore, the method of the present invention must be used to form metal silicide on the gate and diffusion regions on the peripheral circuit area, and to form metal silicide on the gate on the cell array area, and prevent metal silicide from forming on the cell array. The "diffusion region on the region" speeds up the material transmission capability and data operation capability of the peripheral circuit region, and prevents the leakage of the lean material caused by the leakage current in the cell array region. Referring to the third figure, a wafer including a substrate 100 is first provided and a first oxide layer 12 is formed on the substrate 100, and then the first oxide layer 12 is A first nitride layer 140 is formed thereon, and finally a second oxide layer 160 is formed on the first nitride layer 1440. Generally, the thickness of the first oxide layer 12 is about 70 to 90 angstroms, the thickness of the first nitride layer 1 40 is about 60 to 80 angstroms, and the thickness of the second oxide layer 1 60 is The thickness is approximately 60 to 80 angstroms. In the current process, the thickness of the first oxide layer 120 is 80 angstroms, the thickness of the first nitride layer 140 is 70 angstroms, and the thickness of the second oxide layer 16 0 is 70 Angstroms. However, as the process width gradually decreases, the thicknesses of the first oxide layer 120, the first nitride layer 140, and the second oxide layer 160 must also be reduced to meet the requirements of the process. Referring to the fourth figure, after defining the cell array region 104 and the peripheral circuit region 102 on the wafer, the periphery is removed by a photolithography and I etching method. Circuit 505997 V. Description of the invention (7) The first oxide layer 1 2 0, the first nitride layer 1 40 and the second on the region 102. The oxide layer 16 causes the peripheral circuit region 102 to be exposed. Substrate. Referring to the fifth figure, a third oxide layer '2 0 0 is formed on the substrate of the peripheral circuit region 102, and the thickness of the third oxide layer 2 0 is about 40 to 60 angstroms. In the current process, the thickness of the third oxide layer 200 is usually 50 angstroms. However, as the process width gradually decreases, the thickness of the third oxide layer 200 must also be reduced to meet the requirements of the process. Generally, the material of the first oxide layer 120, the second oxide layer 160, and the third oxide layer 2000 is silicon dioxide (si 1 ic ο ndi ο X ide), and the nitride layer 1 The material of 40 is usually siliconnitride. In this embodiment, the cell array region on the wafer and the peripheral circuit region use different forms of dielectric layers on the substrate. The oxide / nitride / oxide sandwich type is used as the dielectric layer on the unit cell array area, while the single-layer oxide is used as the dielectric layer in the peripheral circuit area. With different process requirements, the same form of dielectric layer can be used on the substrate in the cell array region and the peripheral circuit region to exert the performance of the semiconductor device. The dielectric layer may be an oxide layer. Referring to the sixth figure, a silicon layer 300 is formed on the second oxide layer 160 L · and the third oxide layer 200, and a reoxidation process is performed on the silicon layer. A fourth oxide layer 2 2 0 is formed on the layer. The silicon layer 300 is a gate layer and the fourth oxide layer 220 is a buffer layer. Next, a second nitride layer 24 is formed on the fourth oxide layer 220. The purpose of this buffer layer is
)05997 五、發明說明(幻 :。Γ:與A二Λ化物層24°之結合能力,但可隨製程 ,求而決疋疋否形成此一緩衝層。參照第七圖所示 極之=在周邊電路區域1〇2及晶胞陣列區域1〇4上定義閘 置,並藉由一微影及蝕刻的製程移除部分之矽声、 周化物層2 2 0與部分之第二氮化物層24〇,二在 擴ΐ, 2上形成多數個第一閘極4〇0與多數個第一 5(/〇鱼\4 5 0,=在晶胞陣列區域104上形成多數個第二閘極 /、夕數個第二擴散區5 5 0。此多數個第一擴散區45〇位 衍二Ϊ個第一閘極4 0 0的兩側,而此多數個第二擴散區550 位於多數個第二閘極5 〇 〇的兩側。 、苓照第八圖所示,形成一第一遮罩層6 〇 〇於晶胞陣列 區域1 0 4之第二氧化物層1 6 〇與第二氮化物層2 4 〇上,並進 行輕摻雜汲極(lightly doped drain; LDD)之製程,以在 周邊電路區域102上之多數個第一擴散區450内形成一輕度 摻雜之沒極區域3 2 0。此製程的目的為用以降低熱載子效 應(hot carrier effects)所造成之缺陷。參照第九圖所 示’接下來將弟一遮罩層β 〇 〇移除以露出晶胞陣列區域° 1 〇 4 之第二氧化物層16 0與第二氮化物層240。 參照第十圖所示,沉積一層第五氧化物層2 6 〇於第二 氧化物層160、弟二.氧化物層20 〇與第二氮化物層2 4 〇上。 在沉積第五氧化物層2 6 0之製程中,可利用基板之差異性 讓第五氧化層2 6 0在第二氮化物層2 4 0上形成速率較慢而在) 05997 5. Description of the invention (Fantasy: .Γ: 24 ° binding ability with A Λ Λ compound layer, but it can be determined depending on the process, whether to form this buffer layer. Refer to the pole shown in the seventh figure = A gate is defined on the peripheral circuit area 102 and the cell array area 104, and a part of the silicon acoustic, peripheral material layer 2 2 0 and a part of the second nitride are removed by a lithography and etching process. Layers 24, 2 form a plurality of first gates 400 and a plurality of first 5 (/ 0fish \ 4 50, 2) on the expansion, 2; a plurality of second gates are formed on the cell array region 104 Poles, and a plurality of second diffusion regions 5 50. The majority of the first diffusion regions 540 are located on both sides of the two first gates 400, and the majority of the second diffusion regions 550 are located at the majority The two gates are on both sides of 500. As shown in the eighth figure, a first mask layer 600 is formed on the cell array region 104, and the second oxide layer 16 and A lightly doped drain (LDD) process is performed on the dinitride layer 2 4 0 to form a lightly doped pattern in the plurality of first diffusion regions 450 on the peripheral circuit region 102. Polar region 3 2 0. The purpose of this process is to reduce defects caused by hot carrier effects. Refer to the ninth figure, 'Next, remove the first mask layer β 〇〇 to expose the crystal The second oxide layer 160 and the second nitride layer 240 in the cell array region ° 1 〇 4 Referring to the tenth figure, a fifth oxide layer 26 is deposited on the second oxide layer 160 and the second On the oxide layer 20 and the second nitride layer 240. In the process of depositing the fifth oxide layer 260, the difference between the substrates can be used to make the fifth oxide layer 260 on the second nitride Formation rate is slower on layer 2 4 0
第12頁 505997 五、發明說明(9) 第二氧化物層1 6 0與第三氧化物層2 0 0上形成速率較快以達 到不同之沉積厚度。 參照第十一圖所示,經過一回蝕之步驟移除部分之第 五氧化物層2 6 0以使多數個第一閘極4 0 0與多數個第二閘極 5 0 0之頂部露出第二氮化物層2 4 0,並使第五氧化物層2 6 0 之厚度低於矽層3 0 0之厚度。參照第十二圖所示,移除第 二氮化物層2 4 0與第四氧化物層2 2 0,使得多數個第一閘極 4 0 0與多數個第二閘極5 0 0之頂部露出矽層3 0 0。 參照第十三圖所示,形成一第二遮罩層6 5 0於晶胞陣 列區域1 0 4上之第五氧化物層2 6 0與矽層3 0 0上,並用非等 向性蝕刻移除周邊電路區域1 0 2上之部分的第五氧化物層 2 6 0,以在多數個第一閘極4 0 0之側壁上形成間隙壁7 0 0, 並使多數個第一擴散區域4 5 0露出第三氧化物層2 0 0。接下 來植入製程所需之離子以在多數個第一擴散區域上形成源 極/没極75 0之區域。 參照第十四圖所示,移除第二遮罩層6 5 0後,形成一 金屬層8 0 0於晶胞陣列區域1 0 4上之第五氧化物層2 6 0、多 數個第一閘極4 0 0、多數個第一擴散區4 5 0與多數個第二閘 極5 0 0上。在沉積金屬層8 0 0前,首先先使用濕式清潔法清 除矽層3 0 0與基板上的氧化物,使得金屬矽化物較易形成 。大部分使用化學氣相沉積法或是磁控直流電濺鍍法來沉Page 12 505997 V. Description of the invention (9) The second oxide layer 160 and the third oxide layer 2000 are formed at a faster rate to achieve different deposition thicknesses. Referring to the eleventh figure, a part of the fifth oxide layer 26 is removed through an etch-back step so that the tops of the plurality of first gates 4 0 and the plurality of second gates 5 0 0 are exposed. The second nitride layer 2 40 has a thickness of the fifth oxide layer 26 0 that is lower than the thickness of the silicon layer 300. Referring to the twelfth figure, the second nitride layer 2 40 and the fourth oxide layer 2 2 0 are removed, so that the tops of the plurality of first gates 4 0 and the plurality of second gates 5 0 0 The silicon layer is exposed. Referring to the thirteenth figure, a second mask layer 6 50 is formed on the fifth oxide layer 2 6 0 and the silicon layer 3 0 0 on the cell array region 104, and anisotropic etching is used. A portion of the fifth oxide layer 2 6 0 on the peripheral circuit region 102 is removed to form a spacer 7 0 0 on the sidewalls of the plurality of first gate electrodes 4 0 0 and to make the plurality of first diffusion regions 4 5 0 exposes the third oxide layer 2 0 0. Next, the ions required for the implantation process are formed to form a source / inverter region of 75 ° on most of the first diffusion regions. Referring to the fourteenth figure, after removing the second mask layer 6 50, a metal layer 8 0 is formed on the cell array region 10 5 and the fifth oxide layer 2 6 0, most of the first The gates 4 0 0, the plurality of first diffusion regions 4 50 and the plurality of second gates 5 0 0. Before depositing the metal layer 800, the silicon layer 300 and the oxide on the substrate are first removed by a wet cleaning method, so that the metal silicide is easier to form. Most of them are deposited by chemical vapor deposition or magnetron DC sputtering.
第13頁 505997 五、發明說明(ίο) 積此金屬層8 0 0。接下來,將晶圓送入反應室中進行第— 2速加熱製程,使金屬層80 0與接觸處之矽反應,以形成 石夕化物(silicide)層。第一快速加熱製程的溫度大約 :〇至7 0 0 C。此時的金屬矽化物的結構主要是電阻值較 =^-49相的結構。參照第十五圖所示,利用Rca清洗的 將去除未參與反應或反應後所殘留的金屬層800,而 —垆^矽化合物層8 5 0留在多數個第一閘極4〇〇、多數個第 速,^區4 5 0與多數個第二間極5〇〇上。最後再執行第二二 低的Ά呈’將c—49相之金屬矽化物結構轉換成電阻值較 至85(TC H结Λ。第二快速加熱製程的溫度大約為750 使用# 主屬層8〇0的材質可為鈦、鈷及白金等,通當 用鈇為此金屬層8 0 0的材質。 料。:太?現在自對準金屬石夕化物製程中最常使用的金屬材 料,力太=一種氧吸能力(oxygen gettering)不錯的金屬 源極ί t f的溫度了’鈦極易與金氧半電晶體上的汲極/ 化合:t,的石夕因交互擴散而形成-電阻率很低的敘石夕 〜、titanium silicide; TiSi2)。 240 ,因田為第五氧化物層26 0不容易形成在第二氮化物層上 5 0 0上”在移除多數個第一閘極40 0與多數個第二閘極 迷率Λ五氧化物層26G時較為容易,可加速製程運作之 其厚二^數個第二擴散區域550上之第五氧化物層260, 予度夠厚以阻擔在後續製作自對準金屬石夕化物Page 13 505997 V. Description of the Invention (ίο) Build this metal layer 8 0 0. Next, the wafer is sent into the reaction chamber for a second-second speed heating process, so that the metal layer 800 reacts with the silicon at the contact to form a silicide layer. The temperature of the first rapid heating process is about: 0 to 700 ° C. The structure of the metal silicide at this time is mainly a structure having a relatively low resistance value = ^-49 phase. Referring to the fifteenth figure, the Rca cleaning will remove the metal layer 800 that has not participated in the reaction or remaining after the reaction, while the silicon compound layer 8 50 remains at most of the first gate electrodes 400, and most The second speed, the area 504 and the majority of the second interpole 500. Finally, the second and second low-level rendering is performed to convert the metal silicide structure of the c-49 phase into a resistance value higher than 85 (TC H junction Λ. The temperature of the second rapid heating process is about 750 using # Principal Layer 8 The material of 〇0 can be titanium, cobalt, platinum, etc. The material used for this metal layer is 8000. Material: Too? Now the most commonly used metal material in the self-aligned metal oxide process. Too = a good metal source for oxygen gettering. The temperature of tf is too high. Titanium is easy to combine with the drain / combination of the gold-oxygen semitransistor: t, Shi Xi is formed due to cross-diffusion-resistivity. Very low Su Shixi ~, titanium silicide; TiSi2). 240, because the field is the fifth oxide layer 26 0 is not easy to be formed on the second nitride layer 5 0 0 ”After removing the majority of the first gates 40 0 and the majority of the second gates 5% The material layer 26G is relatively easy, and the fifth oxide layer 260 on the second diffusion region 550, which can accelerate the operation of the process, is thick enough to hinder the subsequent production of self-aligned metal oxide compounds.
505997 五、發明說明(ίο ,金屬層之離子穿透過此第五氧化物層而和底部之底材反 應形成金屬矽化物。此第五氧化物層2 6 0可防止金屬矽化 物形成於多數個第二擴散區域5 5 0内,使多數個第二閘極 5 0 0發生互相連結之現象而產生漏電流之缺陷。 隨著製程需求之不同,通常可不形成第四氧化物層 2 2 0與第二氮化物層2 4 0,以使製程步驟更為簡化。而當製 程步驟不形成第四氧化物層2 2 0與第二氮化物層2 4 0時,在 沉積第五氧化物層2 6 0之製程中,可利用基板之差異性讓 第五氧化層2 6 0在矽層3 0 0上形成速率較慢而在第二氧化物 層1 6 0與第三氧化物層2 0 0上形成速率較快以達到不同之沉 積厚度。 用 根據 氧化 列區域上 物,以降 區域上之 邊電路區 並提南半 ,並且為 故已符合 審查委員 以上所 物層作 的閘極 低晶胞 擴散區 域上之 導體元 前所未 專利法 詳予審 述之 為遮 及周 陣列 域發 電阻 件之 見之 之要 查, 實施例 罩層, 邊電路 區域之 生漏電 。本發 製程運 設計, 件,爰 並祈早 ,本發 順利在 區域上 字元線 流之缺 明更可 作效率 具有功 依法具 曰賜准 明提供 周邊電 之擴散 的電阻 陷。本 提南半 ,不僅 效性與 文申請 專利, 了 項 路區域 區形成 並避免 發明也 導體元 具有實 進步性 之。為 至感德 方法,利 與晶胞陣 金屬石夕化 晶胞陣列 可減少周 件之品質 用功效外 之增進, 此,謹貴 便0505997 V. Description of the invention (ίο, the ions of the metal layer penetrate through the fifth oxide layer and react with the substrate at the bottom to form a metal silicide. The fifth oxide layer 2 60 can prevent the metal silicide from being formed on most Within the second diffusion region 5 50, the defect that a plurality of second gate electrodes 500 are connected to each other and cause a leakage current is generated. As the process requirements are different, the fourth oxide layer 2 2 0 and The second nitride layer 2 40 is used to simplify the process steps. When the fourth oxide layer 2 2 0 and the second nitride layer 2 4 0 are not formed in the process steps, a fifth oxide layer 2 is deposited. In the process of 60, the difference of the substrate can be used to make the fifth oxide layer 2 60 be formed on the silicon layer 3 0 at a slower rate, while the second oxide layer 16 0 and the third oxide layer 2 0 0 The formation rate is faster to achieve different deposition thicknesses. The lower cell is used to lower the edge of the circuit area and lift the southern half of the area according to the oxide column area. Details of unpatented law on conductors in diffusion areas The review is to review the observations of the peripheral array field resistance components, the implementation of the cover layer, the side circuit area of the current leakage. This process is designed, parts, and pray for early, the hair is smooth on the area The lack of character line flow can also be used as a resistor trap with efficiency and power according to the law. It can provide the diffusion of peripheral electricity. This southern half not only applies for patents, but also prevents the formation of project roads and prevents inventions. Also, the conductor element has real progress. For the most sensible method, the cell array and the metal array can reduce the quality of the peripheral parts and improve the performance.
第15頁 505997 五、發明說明(12) 以上所述僅為本發明之較佳實施例而已,此 係用來說明而非用以限定本發明之申請專利範圍 離本發明之實質内容的範®壽内仍可予以便化而加 此等變化應仍屬本發明之範圍。因此,本發明之 以下之申請專利範圍所界定。 施例僅 在不脫 實施, 疇係由 505997 圖式簡單說明 第一圖為運用傳統技術在金氧半電晶體上沉積一鈦金 屬層之示意圖; 第二圖為運用傳統技術在閘極區域與源極/汲極區域 上形成鈦石夕化物之示意圖; 第三圖為在晶圓底材上形成第一氧化物層、氮化物層 與第二氧化物層之示意圖; 第四圖為移除周邊電路區域之第一氧化物層、氮化物 層與第二氧化物層之示意圖; 第五圖為形成一第三氧化物層於周邊電路區域之底材 上之不意圖, 化 氣 二 第; 一 圖 與意 層示 物之 化上 氧層 四物 第化 一 氧 、三 層第 矽與 一 層 成物 形化 為氧 圖二 六第 於 層 物 I...........·...................................... 數與 多極 與閘 極二 閉第 一個 第數 個多 數成 多形 成域 形區 域列 區陣 路胞 電晶 邊在。 周並區 在,散 為區擴 圖散二 七擴第 第一 個 第數 個多 化輕 氧成 二形 第内 與區 層散 物擴 化一 氮第 二個 第數 之多 域在 區並 列層 陣罩 胞遮 晶 一 在第 為一 圖成 八形 第上 層 物Page 15 505997 V. Description of the invention (12) The above description is only a preferred embodiment of the present invention, and it is intended to illustrate, not to limit the scope of the patent application of the present invention, which is beyond the essence of the present invention. It is still within the scope of the present invention, and such changes should still be within the scope of the present invention. Therefore, the scope of patent application of the present invention is defined below. The embodiment is only implemented without fail. The domain system is briefly described by the 505997 diagram. The first diagram is a schematic diagram of depositing a titanium metal layer on a gold-oxygen semi-electric crystal using traditional techniques. Schematic diagram of the formation of titanium oxide on the source / drain region; the third diagram is the diagram of forming the first oxide layer, the nitride layer and the second oxide layer on the wafer substrate; the fourth diagram is the removal The schematic diagram of the first oxide layer, the nitride layer and the second oxide layer in the peripheral circuit area; the fifth figure is the intention of forming a third oxide layer on the substrate in the peripheral circuit area; A picture and the meaning of the layer of the display of the upper layer of the four objects of the first oxygen, three layers of silicon and a layer of the formation of oxygen into the second layer of the object I .............. ........................ Number and multipole and gate two closed first The plurality of matrix cells are located in the form of a plurality of domain-shaped regions. The area is divided into two, the area is expanded, the area is enlarged, the area is enlarged, the area is enlarged, and the area is enlarged. Layer array mask
第17頁 505997 圖式簡單說明 掺雜沒極之示意圖; 圖 意 示 之 層 罩 遮 1 第 除 移 圖 九 第 第 層 物 化 氧 二 第 ·, 於圖 層意 物示 化之 氧上 五層 第物 層化 一 氮 成二 形第 為與 圖層 十物 第化 氧 三Page 505997 The diagram briefly illustrates the schematic diagram of the doped dipole; the layer mask shown in the figure is shown in Figure 1; the first shift is shown in Figure 9; the first layer of materialized oxygen is the second layer; Layering one nitrogen into two forms
一 圖 第意 個示 數之 多層 使物 以化 層氮 物二 化第 氧出 五露 第部 之頂 分之 部極 除閘 移二 為第 圖個 數 得意 使示 ,之 層層 物矽 化出 氧露 四部 第頂 與之 層極 物閘 化二 氮第 二個 第數 除多 移與 為極 圖閘 二一 十第 第個 數; 多圖 第十三圖為形成一第二遮罩層於晶胞陣列區域上之第 五氧化物層與矽層上,並移除周邊電路區域上之部分的第 五氧化物層,以在多數個第一閘極之側壁上形成間隙壁, 並使多數個第一擴散區域露出第三氧化物層之示意圖; 第十四圖為形成一金屬層於晶胞陣列區域上之第五氧 化物層、多數個第一閘極、多數個第一擴散區與多數個第 二閘極5 0 0上之示意圖;及The multi-layered objects shown in the figure of the first figure are shown in the figure. The layers are silicided out of silicon. The top and bottom layers of the oxygen dew are gated and the second number is divided by the second number. The sum is the twenty-first number of the pole figure gate. The thirteenth figure of the multi-graph is a second mask layer. The fifth oxide layer on the cell array region and the silicon layer, and a portion of the fifth oxide layer on the peripheral circuit region is removed to form a gap wall on the sidewalls of the plurality of first gates, and make the majority A schematic diagram of a third oxide layer exposed in each of the first diffusion regions; a fourteenth diagram is a fifth oxide layer, a plurality of first gates, a plurality of first diffusion regions, and a metal layer formed on the cell array region; Schematic diagrams of a plurality of second gates 500; and
第18頁Page 18
505997 圖式簡單說明 第十五圖為形成一金屬矽化合物層於多數個第一閘 極、多數個第一擴散區與多數個第二閘極上之示意圖。 主要部份 10 12 14 16 18 20 22 30 100 120 140 160 200 22 0 240 260 300 320 400 450 之代表符號: 底材 源極/沒極區域 閘極氧化物層 多晶矽層 間隙壁 鈦金屬層 鈦矽化合物層 淺渠溝隔離層 底材 第一氧化物層 第一氮化物層 第二氧化物層 第三氧化物層 第四氧化物層 第二氮化物層 第五氧化物層 矽層 輕度摻雜之沒極區域 多數個第一閘極 多數個第一擴散區域505997 Brief Description of Drawings Figure 15 is a schematic diagram of forming a metal silicon compound layer on a plurality of first gates, a plurality of first diffusion regions, and a plurality of second gates. Main part 10 12 14 16 18 20 22 30 100 120 140 160 200 22 0 240 260 300 320 400 450 Representative symbols: substrate source / electrode area gate oxide layer polycrystalline silicon layer gap wall titanium metal layer titanium silicon Compound layer shallow trench isolation layer substrate first oxide layer first nitride layer second oxide layer third oxide layer fourth oxide layer second nitride layer fifth oxide layer silicon layer lightly doped Non-polar region majority first gate majority diffusion region
第19頁 505997 圖式簡单說明 5 0 0多數個第一閘極 5 5 0多數個第一擴散區域 6 0 0第一遮罩層 650第二遮罩遮罩層 7 0 0間隙壁 7 5 0源極/汲極 8 0 0金屬層 8 5 0金屬石夕化物層 參Page 19 505997 Schematic illustration 5 0 0 majority first gate 5 5 0 majority first diffusion region 6 0 0 first mask layer 650 second mask layer 7 0 0 gap wall 7 5 0 source / drain 8 0 0 metal layer 8 5 0 metal oxide layer
第20頁Page 20
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW90118552A TW505997B (en) | 2001-07-31 | 2001-07-31 | Local formation method of self-aligned metal silicide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW90118552A TW505997B (en) | 2001-07-31 | 2001-07-31 | Local formation method of self-aligned metal silicide |
Publications (1)
Publication Number | Publication Date |
---|---|
TW505997B true TW505997B (en) | 2002-10-11 |
Family
ID=27621879
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW90118552A TW505997B (en) | 2001-07-31 | 2001-07-31 | Local formation method of self-aligned metal silicide |
Country Status (1)
Country | Link |
---|---|
TW (1) | TW505997B (en) |
-
2001
- 2001-07-31 TW TW90118552A patent/TW505997B/en not_active IP Right Cessation
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6153485A (en) | Salicide formation on narrow poly lines by pulling back of spacer | |
US7098514B2 (en) | Highly integrated semiconductor device with silicide layer that secures contact margin and method of manufacturing the same | |
CN101069281B (en) | Method for forming self-aligned dual salicide in CMOS technologies | |
TW200417013A (en) | Tri-gate and gate around MOSFET devices and methods for making same | |
JP3563530B2 (en) | Semiconductor integrated circuit device | |
JP4718104B2 (en) | Semiconductor device | |
US6150266A (en) | Local interconnect formed using silicon spacer | |
KR100871754B1 (en) | Method for manufacturing semiconductor memory device | |
JP3545592B2 (en) | Method for manufacturing semiconductor device | |
US6509264B1 (en) | Method to form self-aligned silicide with reduced sheet resistance | |
US6352899B1 (en) | Raised silicide source/drain MOS transistors having enlarged source/drain contact regions and method | |
US6162691A (en) | Method for forming a MOSFET with raised source and drain, saliciding, and removing upper portion of gate spacers if bridging occurs | |
JP3161408B2 (en) | Semiconductor device and manufacturing method thereof | |
US6258682B1 (en) | Method of making ultra shallow junction MOSFET | |
JPH05166835A (en) | Self-aligning polysilicon contact | |
CN102709192A (en) | Manufacturing method of MOS (Metal Oxide Semiconductor) transistor structure integrated with resistive random access memory | |
TW505997B (en) | Local formation method of self-aligned metal silicide | |
US6258651B1 (en) | Method for forming an embedded memory and a logic circuit on a single substrate | |
TWI231547B (en) | Short channel transistor fabrication method for semiconductor device | |
KR100258347B1 (en) | Manufacture method of semiconductor apparatus | |
JPH09172063A (en) | Semiconductor device and its manufacture | |
TW492152B (en) | Method to form salicide locally | |
JPH1065171A (en) | Manufacture of mos transistor | |
US20050196912A1 (en) | Planar pedestal multi gate device | |
JP3110054B2 (en) | Semiconductor device and manufacturing method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
GD4A | Issue of patent certificate for granted invention patent | ||
MK4A | Expiration of patent term of an invention patent |