TW505562B - Print resin film for decorative sheet lamination and the decorative sheet laminated with the said resin film - Google Patents
Print resin film for decorative sheet lamination and the decorative sheet laminated with the said resin film Download PDFInfo
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- TW505562B TW505562B TW88121233A TW88121233A TW505562B TW 505562 B TW505562 B TW 505562B TW 88121233 A TW88121233 A TW 88121233A TW 88121233 A TW88121233 A TW 88121233A TW 505562 B TW505562 B TW 505562B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/24—Pressing or stamping ornamental designs on surfaces
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Abstract
Description
505562 五、發明說明α) 技術領域 本發明係有關由施加層合至各種家具類或建築内部裝 飾材等所使用的裝飾板上之印刷樹脂薄膜及已層合該印刷 樹脂薄膜之裝飾板。 術 技 景 背 來 向 已 板 飾 ,知 裝 之 等 材 飾 裝 β, 立口 内 築 建 或 類 具 家 ¢-81 一 種 各 作 用 使 被 有 層 脂 樹 之 材 基 為 成 於 刷 印 加 施 法 方 的 常 通 用 採 樹 匕曰 S 胺 脂 樹 酸 醇 基 胺 有 置 ¾ 口 ^回 ·, 表膜 之薄 層飾 刷裝 印之 護層 保覆 為被 ,等 上脂 劑 著 上 接 之 經 膜 介 薄 ’膜稀 後I乙 刷 印 聚 口fA 力之夂 層旨加 脂D施 樹I法 ^方 & ^ f 為Μ通 成爿用 於日採 2合3 /IV > /(\ 層 層 後薄505562 V. Description of the invention α) TECHNICAL FIELD The present invention relates to a printed resin film laminated on a decorative board used for various furniture or building interior decoration materials, and a decorative board laminated with the printed resin film. The background of the technical skills has been decorated with decorative materials, such as decorative materials β, inside the building or the like ¢ -81. Each effect makes the base of the layered resinous tree become the common method of printing and adding spells. The universal tree picker is called S amine resin alcohol amine. It has ¾ mouth ^ back. The surface of the film is decorated with a thin layer of brush. The protective layer of the printing is covered with a quilt. 'After the film is thinned, the second layer is printed, the second layer is printed, and the force of the layer is intended to be fattened, and the method is applied to the tree, and the method is used for daily mining 2 in 3 / IV > / (layer Back thin
DD
等 ,摸 库F 飾或 裝板 之合 膜、 薄板 匕日岡 S 杂 聚鋅 伸鍍 拉於 轴合 雙層 或劑 膜著 薄接 烯經 乙介 氯 , 聚膜 的薄 明飾 透裝 合的 層等 者 成 而 上 板 基 裝 於 由 板 飾 裝 之 膜 薄 飾 裝 的 X)/ 1-1 /1\ 述 上 合 層 以 而 然 割」等 7落- 切纟工 V 加 加又U包,宝口 ^ 切 在裂Vi ,龜加 足會施 不膜於 度薄適 強飾不 之裝並 膜時, 薄工題 飾加問 等容 工有 加墨 }由 CU之 V-分 β, Ji口 合 層 已 Ο 途 用 的 ,的裝 形落的 情剝2) 的易 性之} 物高(3 面較合 表度層 等溫已 性化。 劑軟紋 溶於花 耐由花 、,壓 性性與 染軟賦 污柔難 耐之較 在膜, 然薄時 雖面工 ,表加 板缺花 飾欠壓 裝而加 之然施 膜,在 薄越, 飾優故Wait, F library F decorative or mounting of the film, thin plate Hikaoka S heteropolyzinc drawing and drawing on the shaft double layer or agent film with a thin film of ethylene chloride, thin transparent decoration of the poly film The upper layer base is installed on the thin film decoration of the plate decoration X) / 1-1 / 1 \ Said on the upper layer to cut and then cut "and so on 7"-Cut 纟 工 V 加加 又 U Bao, Baokou ^ Cut in the crack Vi, when the turtle is full, it will apply the film to the thin and strong decoration. When the film is thin, the thin work is decorated with questions, and the equal volume is filled with ink. From V- 分 β, Ji of CU The buccal layer has been used in the field, and it is easy to use. 2) The ease of the material} (3 sides are more isothermal than the superficial layer. The soft lines of the agent are soluble in flowers, resistant to flowers ,, Compared with film, compressibility and soft dyeing are soft and difficult to resist. Although the surface is thin, the surface plus plate lacks the flower decoration and the pressure is applied. In addition, the thinner, the better the decoration.
第6頁 505562 污處 耐棄 故廢 ,行 膜進 薄燒 烯焚 乙在 氣又 聚, 用劣 採低 係性 於物 由面 ,表 板的 飾等 裝性 之劑 ⑵膜溶 d薄耐 說飾、 I裝性 P的染 氣之 毒爐 有燒 該焚 於傷 因損 歸有 及亦 體際 氣之 毒燒 有焚 之在 體, 氣境 氫環 化染 氣污 生而 發質 會物 ,害 際有 之之 理體 聚 的 用 習 用 採 與 .有 實 Μ 問 述 上 決 解 。係 在的 存目 題之 問明 的發 等本 慮 顧 花裝 的的 越越 優優 性性 計物 設面 觀表 外等 的性 上劑 以溶 等耐 同、 板性 飾染 裝污 之耐 膜供 薄提 脂以 樹, 烯案 乙圖 氯紋 為 板 飾 裝 之 膜 薄 脂 樹 亥 =口 合 層 已 及 膜 薄 脂 樹 刷 印 用 合 層 〇 板題 飾課 示 揭I 之| 明發一 樹 刷 印 用 合 層 板 飾 裝 之 項 11 第 圍 利 專 請 申 之 明 發 本 層樹 護材 保基 面述 表前 、於 層設 刷係 印層 、刷 層印 脂述 接前 材, 基膜 對薄 於飾 在裝 徵的 特合 其層 ,序 膜依 薄下 脂由 第層 圍刷 範印 利對 。專於 成請在 而申徵 上之特 面明其 全發, 之本膜 層 薄 匕曰 匕曰 板 飾 裝 之 項 樹 刷 印 用 合 序 依 下 由 層 護 保 面 表 合 面 表 述 前 於 設 而 塗 刷 底 見 用 利 第 係。圍 層成範 刷而利 印上專 述面請 前全 ,面之 膜背明 薄之發 飾層本 裝護 的保 樹 刷 印 用 合 層 板 飾 裝 之 項 上層 之刷 層印 刷案 印圖 案紋 圖#化 紋述。 花前成 由與而 係賦層 層且下 刷面的 印全層 述層刷 前脂印 於樹面 在材全 徵基之 特述色 其前底 ,蔽基 膜遮刷 薄及印 脂層之Page 6 505562 The polluted place is resistant to abandonment and waste, and the film is fed into the thin burned olefin and then burned in the gas, and the polymer is used. The film is dissolved and resistant to the surface. It is said that the poisoning furnace of the dyeing gas containing I and P is burned in the body due to injury and the poisonous burning of the interstitial gas is burned in the body. The practical use of physical, harmful and social gatherings is resolved with the use of customary solutions. The problematic issue of the question is to consider the more and more superior the quality of the flower dress, the better the surface properties, the surface and the surface of the surface, such as the top-up agent, the solvent resistance, the plate decoration dyeing resistance Membrane for thin lipid extraction with tree, vinyl case B Figure chlorine pattern for plate decoration. Membrane thin film helium = mouth laminated layer and membrane thin palm tree for printing and printing. 0 board title decoration lesson I | Ming Send a tree brush printing with laminated board decoration item 11 Di Wei Li specially asked Shen Zhiming to send this layer of tree protection material in front of the surface description table, set the printing system layer on the layer, and brush the printing layer to connect the front material. The film pair is thinner than the special layer decorated on the bag, and the sequence film is brushed by the second layer to cover Fan Yinli. Specializing in the application, please indicate the full characteristics of the application on the application. The film of the thin layer of the film is decorated with a decorative plate, and the tree is printed with the order of the protective surface and the surface. Let's use the Lidi system for painting. The surrounding layer is brushed and printed with special descriptions, please complete the front surface, the back of the surface is thin, and the hair decoration layer is protected. Figure # 化 纹 述. The front layer of the flower is layered and printed on the lower surface of the full layer. The front layer is printed on the tree surface. The front side is characterized by the special color of the material. The base film is masked by the thin layer and the printed layer. Of
第7頁 五、發明說明(3) 前述裝 以由聚S旨樹 前述裝 聚對笨二甲 前述裝 上施加壓花 層為佳。 前述裝 以由聚苯二 本發明 至少單面上 脂薄膜而成 前述裝 裝飾板層合 前述裝 板較佳。 飾板層合用 脂而成為宜 飾板層合用 酸丁二酯樹 飾板層合用 加工,又於 飾板層合用 甲酸丁二酯 之裝飾板, ’已層合前 〇 飾板,以介 用印刷樹脂 飾板以基板 丹中表 其中聚 其中於 再設置 其中基 樹脂薄 飾板層. 印刷樹脂薄膜, 0 印刷樹脂薄膜, 脂為佳。 印刷樹脂薄膜, 表面保護層之上 印刷樹脂薄膜, 樹脂而成為佳。 其特徵在於層合 述的裝飾薄膜裝 $接著劑層層合 4膜之間而成者 為鍍鋅鋼板、或 說明 -例2 面為圖表。丁本^明之裝飾板層合用印刷 其他Γ的圖截為面表圖示本發明之“板層合用印刷 其他ί3的圖截為面表圖示本發明之裝飾板層合用印刷 保護層係 樹脂係以 面保護層 色澤調^ 樹脂層係 之基板的 用印刷樹 裝飾薄膜 或無機質 ‘薄膜之 薄膜之 薄膜之 505562 五 4 /ίν 明 說 明 發 板板 飾飾 裝裝 之之 明明 發發 本本 示示 表表 為為 圖圖 4 5 第第Page 7 V. Description of the invention (3) The aforementioned equipment is preferably composed of a poly-S tree, the aforementioned equipment, a pair of stupid Dijia, and the aforementioned equipment is preferably provided with an embossing layer. The aforementioned device is made of a polyphenylene diene film of at least one side of the present invention. The aforementioned device is preferably a decorative board laminated with the aforementioned device. The veneer lamination grease becomes suitable for veneer lamination using butyric acid tree veneer laminating and processing, and the veneer laminating with butyl formate for decorative board, 'the veneer has been laminated before the printing. Resin veneer is based on the substrate, and then the resin veneer layer is set. Printing resin film, 0 printing resin film, preferably grease. Printing resin film, resin on the surface protection layer is better. It is characterized in that the decorative film is laminated and the adhesive layer is laminated between the 4 films, and the galvanized steel sheet is used, or the example 2 is shown in the chart. Ding Ben ^ Ming's print of decorative board lamination printing other Γ is cut out to show the surface of the present invention, "Board laminating printing other ί3" is cut out to show the surface of the decorative board lamination printing protective layer resin system of the present invention Adjust the color of the surface protective layer ^ Resin-based substrates with printed tree decorative films or inorganic 'films' films 505562 5 4 / ί ν 发 发 发 发 明 发 发Figure 4 5 for the first
圖圖 面面 截截 的的 例例 實施 質, 樹脂 性等 以檢 刷基 及全 予施 擇性 性之 膜, 可 0 質板 性, 例 發現在外觀設計性方面亦係優越的 以下說明本發明之内容。 第1圖為表示本發明之裂飾板層合用印刷樹 的截面圖。 第2圖及第3圖為表示本發明 最佳形態 聚氯乙烯樹脂薄膜,有會發生歸因於焚燒時的有害物 而污染環境之顧慮的問題。經對具有可取代聚氯乙稀 之外觀設計性優越的花紋圖案,且耐污染性、耐溶劑 表面物理性優越的裝飾板可層合且印刷的樹脂薄膜予 討。其結果,可採用聚對苯二甲酸丁二酯薄膜作為印 材之基材樹脂層。加上形成由花紋圖案印刷層之I芦 面印刷層之下層而成的印刷層,利用由下依序層合二 加選擇性的壓花加工之表面保護層,及於其上^ 裝飾板的樹脂薄膜。 上攻要永特 又,於表面保護層方面採用聚對苯二甲酸丁二 p 加上形成利用襯底刷塗之印刷層,省略基村^ :薄 倒' 知層亦 再者,將上述的樹脂薄膜層合於金屬板、合 等之上的裝飾板,加上樹脂薄膜之上述優 往無機 發現在外觀設計性方面亦卷傷勒.从’專膜物 脂薄膜之 之裝飾板層合用印刷樹月旨The examples of the examples are shown in the figure, and the quality of the resin is based on the brush base and the film with full selectivity. The quality can be 0. The example shows that the design is also superior in terms of design. Contents of the invention. Fig. 1 is a cross-sectional view showing a printed tree for laminated veneer lamination according to the present invention. Figures 2 and 3 show the best form of the polyvinyl chloride resin film of the present invention, and there is a concern that the environment may be polluted due to harmful substances during incineration. Resin films that can be laminated and printed with decorative patterns that can replace polyvinyl chloride and have a good design appearance, and that are superior in stain resistance and solvent resistance on the physical surface are discussed. As a result, a polybutylene terephthalate film can be used as the base resin layer of the printing material. A printed layer formed by forming a pattern printed layer and a lower layer of an ash surface printed layer is added, and a surface protection layer with selective embossing processing is laminated in sequence from the bottom, and a decorative board is formed thereon. Resin film. On the attack, Yongte will use polybutylene terephthalate on the surface protection layer plus a printing layer formed by brushing with the substrate, omitting the base village ^: thin down, and knowing the layer, and the above Resin films are laminated on metal plates, decorative plates, etc. The above-mentioned superior inorganic materials with resin films are also found to be damaged in appearance and design. From the 'special film' fat film to the decorative plate laminate printing Shuyuezhi
505562 五、發明說明(5) 薄膜之其他例子的截面圖。 第4圖及弟5圖為表示本發明夕姑 圖。圖中,1為裝飾板層合用印飾板之一例的截面 為接著劑層,4為基材樹脂層,5二义溥膜,2為基板,—3 紋圖案印刷層,6為表面保‘層"、、王面/卩刷層,5 b為花 調整層,9為裝飾板。 9 為塗化凹部’ 8為色澤 -^ ϊ ί # i 1«^ 圖案印刷層5b而成的印刷叹J ^王$印刷層5a、花紋 ,保護層6,係不7Λ5著 所示,亦可採用已二J:::!樹脂薄膜1 ’如第2圖 圖所示,於表= ίί6#之板單層面合上用印刷樹脂胃膜1,如第3 f 5b ^ ^ ^ ;V/5a 〇 ^ ^ ^ ;:?r其上層設置色“心 的基材树脂層4,雖以使用具有固有 505562505562 V. Description of the invention (5) Sectional views of other examples of films. Fig. 4 and Fig. 5 are diagrams showing the aunt of the present invention. In the figure, 1 is an example of a decorative plate for decorative board lamination. The cross-section is an adhesive layer, 4 is a base resin layer, 5 is a diisocyanate film, 2 is a substrate, a -3 pattern print layer, and 6 is a surface protection layer. Layers ", King face / 卩 brush layer, 5 b is the flower adjustment layer, 9 is the decorative board. 9 for the coating recessed part '8 for the color-^ ϊ ί # i 1 «^ Printed from the pattern printing layer 5b J ^ 王 $ Printing layer 5a, pattern, protective layer 6, shown as 7Λ5, can also be Adopted J :::! Resin film 1 'As shown in Figure 2, the printed resin gastric membrane 1 is closed on a single layer of the table = ίί6 #, such as 3f 5b ^ ^ ^; V / 5a ○ ^ ^;:? r The base resin layer 4 with a color "heart" is provided on the upper layer, although it has inherent 505562
五、發明說明(6) 黏度(IV值)1· 0〜2· 0之聚對苯二曱酸丁二醋薄膜為宜,惟 固有黏度由製膜性方面在1 · 5以下,财水經時性(耐水劣化 性)方面在1 · 2以上為宜。又,基材樹脂層4在採用擠壓機 製膜之際,將著色顏料混練成著色樹脂層亦可。 印刷層5係由已表現出例如木紋、石紋、天然皮革之 表面花紋、布紋、抽象畫等的圖案之花紋圖案印刷層5 b及 遮蓋基材樹脂層4之全面,給予花紋圖案印刷層5 b之印刷 基材顏色,同時賦與基材樹脂層4及表面保護層6之熱接著 性之已施加印刷至基材樹脂層4之全面上的全面印刷層5a 而成’至於形成印刷層5之油墨載色劑(V e h i c 1 e ),雖然可 使用例如硝基纖維素、醋酸纖維素等纖維素衍生物,聚酯 胺S旨樹脂等公知者,然而其中由附著及熱接著性之兩觀點 則以硝基纖維素醇酸樹脂系油墨為宜。 至 用具有 膜。此 樹脂而 述的全 藉由襯 至 以下組 軟鏈般 伸烷基 二酸、 於保 固有 聚酉旨 成者 面印 底刷 於構 成之 ,係 —醇 二元 護層6 黏度1. 樹脂薄 為特徵 刷層5 a 塗方式 成此聚 共聚合 較合適 或聚ε 酸等具 ,宜為採用聚酯樹脂薄膜,其中較宜採 0〜2· 0之聚對苯二曱酸丁二酯樹脂薄 膜,以由可塑劑及不含南族元素之聚酯 。又,於此表面保護層6之上設置由上 、花紋圖案印刷層5 b而成之印刷層5, ’省略上述的基材樹脂層4亦可。 酯樹脂之材料的一例,較合適採用具有 聚酯樹脂等。亦即’至於形成樹脂之柔 採用聚乙二醇’聚四亞甲二醇等聚氧基 -己内酯、壬二酸、癸二酸、正十二烷 有H00C-[CH ] -C00H之分子構造的脂肪V. Description of the invention (6) Poly (butylene terephthalate) film with a viscosity (IV value) of 1 · 0 ~ 2 · 0 is suitable, but the inherent viscosity is below 1.5 from the aspect of film formation. In terms of timeliness (resistance to water deterioration), it is preferably 1 or 2 or more. When the base resin layer 4 is formed into a film using an extruder, the colored pigment may be kneaded into a colored resin layer. The printing layer 5 is a pattern printing layer 5 b and a substrate resin layer 4 covering the entire surface of the pattern printing layer 5 b which has shown patterns such as wood grain, stone grain, surface pattern of natural leather, cloth pattern, abstract painting, etc. The layer 5b is printed with the color of the base material, and simultaneously imparts the thermal adhesiveness of the base resin layer 4 and the surface protective layer 6 to the full-print layer 5a that has been applied to the entire surface of the base resin layer 4 '. Although the ink vehicle (V ehic 1 e) of the layer 5 can be a known cellulose derivative such as nitrocellulose or cellulose acetate, or a polyesteramine S resin, it is known for its adhesion and thermal adhesiveness. The two viewpoints are preferably a nitrocellulose alkyd resin ink. To use with a membrane. This resin is all made by lining to the following group of soft chain-like alkylene diacids, which is printed on the surface of the original polymer, and the bottom is brushed. It is an alcohol-based binary protective layer. Viscosity 1. Resin thin The characteristic brush layer 5 a coating method is suitable for this copolymerization or poly-ε acid, etc., preferably a polyester resin film, of which a polybutylene terephthalate resin of 0 to 2 · 0 is more suitable. The film is made of plasticizer and polyester without South element. Further, a printed layer 5 made of the upper and pattern printed layer 5b is provided on the surface protective layer 6, and the base resin layer 4 described above may be omitted. As an example of the material of the ester resin, a polyester resin or the like is preferably used. That is, as for the softness of the resin, polyoxyl-caprolactone, azelaic acid, sebacic acid, and n-dodecane such as polyethylene glycol and polytetramethylene glycol are used. H00C- [CH] -C00H Molecularly structured fat
505562 五、發明說明(7) 脂環族 而成的脂肪族聚酯 甲酸乙二 環 ;,羧酸,與脂妨姨及/或 酉逢、對苯二f g f樹骑之堅硬鏈段,以由^ f院二亞τ環己境7 2、對苯二τ酸環己燒1亞;3 香族y或脂環族酿伸丁基2,6二羧酸: ^,;:, f ΐ ;, 醇成 ,,係可予如下明y部板層合用印刷樹脂 面豐合至基材樹脂1 i作:亦即,將表面保護層6之下 ,層4及表面保護曰4上:之,刷層5的上φ,在保曰J: 間,並予挾掊Η厭—· 予®合的狀態下通過一對Γ ί f ίίί薄㈣:藉由熱ίί並層合,製造、出 基材樹脂層4之印刷面声5、j f从f表面保護層6炫著於 刷樹脂薄膜i。刷面層5上並製作出-片裝飾板層合者用印 用壓花妒二基材樹脂層4及表面保護層6之r .. :莖化秦b輪作為上述的熱輥輪,可同時膏V f際,糟由使 工,於表面保護層6之表面上可得 ^貫知層合及壓花加 j所示的裝舞板層合用印刷樹脂薄幵膜1有當$凹部7之第2 層4由於尺度安定性優越,故可 ' ^,基材樹脂 ”申縮變動,可製成具有印刷花紋]:口花拉力或熱引起 兩外觀設計之壓花裝飾薄膜,上/的 g ,同色調的 j ^ 口作業或壓花加工 第12頁 五、發明說^ 寻的步驟 —t 作業。再去I: ΐ用的聚氯乙烯樹脂薄膜者相同停钍 澤調整;8者’如第3圖所*,於表面保護.層心”f行 合用eP Z 亦可作成外觀設計性進一步提$ 加色 用印刷樹脂薄膜1。 /徒n的裝飾板層 光的f #調整層8係不論無色透明或著奔 η共調整裝飾板層?以 酯樹脂、璟a舛ί ί色劑,可採用酚醛樹脂、不飽^取 通常係使=i i ί ΐ、、i ΐ形成色澤調整層8之途料方面 光劑可採用雲母、二氧^ J亚ί與所期待的光澤度,惟消 石夕砂、石夕中空球等。S j銘' 碳酸詞、石夕藻土、 相凹版塗布、親塗、;ϊ t i ί f之塗布方法,可採用照 又’藉由將利用上述方;:j 3 3 f布方式。 脂薄膜1,介經接著劑層3二抑2 = 2衣飾板層合用印刷樹 5圖所示的裝飾板9。至於^缸口 土板2 ’可得第4圖或第 木材合板、粒片板、MDF、箄反i 4’例如可採用木材單板、 板、或辞合金板之鍍鋅鋼拓胃板^鋼板、鋁合金板、辞 鈣板、石棉岩板等無機^ J 4的金屬板、或石膏板、矽酸 至於供裝飾板層合用gp试丨 — 用的接著劑層3之接著劑,卩以刷一私丨知溥膜1及基板2之貼合所 烯酯樹脂系、乙烯-醋酸Γ哈二般的接著劑,例如醋酸乙 次乙稀S旨樹脂系、.尿素樹脂系、胺505562 V. Description of the invention (7) Aliphatic aliphatic polyester formic acid bicyclo; a carboxylic acid, a hard segment of adipose and / or dibenzyl fgf tree, and ^ f courtyard di-tau cyclohexene 7 2, terephthalic acid cyclohexyl benzene 1; 3 aromatic y or cycloaliphatic butyl 2,6 dicarboxylic acid: ^,;:, f ΐ; It can be made as follows: The printing resin surface for the lamination of the y-parts can be laminated to the substrate resin 1 as follows: That is, the surface protection layer 6 is below, the layer 4 and the surface protection are above 4: of, The upper φ of the brush layer 5 passes through a pair of Γ ί f ίί ㈣ in the state of Bao J: and 挟 掊 Η 挟 掊 Η—combined with heat: ί f laminated and laminated by heat to make and produce the base The printing surface sounds 5 and jf of the resin layer 4 are dazzled from the f surface protective layer 6 to the resin film i. Brush the surface layer 5 and make-a piece of decorative plate for embossing for printing, embossing of the second substrate resin layer 4 and the surface protection layer 6... On the surface of the surface protection layer, the surface protection layer 6 can be obtained on the surface of the surface protection layer 6 ^ consistent lamination and embossing plus j shows the printed resin thin film for lamination board lamination 1 2 layer 4 can be made into a printed pattern due to its excellent scale stability, and it can be made into a printed pattern]: embossed decorative film with two designs caused by tensile force or heat, The same color j ^ mouth operation or embossing processing page 12 5. The invention finds ^ the search step-t operation. Then go to I: the same polyvinyl chloride resin film is used for the same stop 8ze adjustment; 8 'as the first As shown in Figure 3 *, eP Z can be used in combination with f protection on the surface protection and core layer. It can also be used to make design resins. The decorative board layer of the light n's f #Adjusting layer 8 is to adjust the decorative board layer regardless of whether it is colorless or transparent? Ester resin, 璟 a 舛 ί color agent, phenolic resin, unsaturated ^ taken usually to make = ii ί 、, i ΐ to form the color adjustment layer 8, the material can be used mica, dioxy ^ J Yaί and the expected gloss, but eliminate Shi Xisha, Shi Xi hollow ball and so on. S j Ming 'carbonic acid word, Shi Xi algae earth, phase gravure coating, self-coating, ϊ t i ί f coating method, can be used according to the use of the above; j 3 3 f cloth method. Lipid film 1, through the adhesive layer 3, two inhibitions 2 = 2 printed board for lamination of decorative panels 5 decorative panel 9 shown in the figure. As for the ^ cylinder mouth soil plate 2 can be obtained in Figure 4 or the wood plywood, particle board, MDF, 箄 i i 4 ', for example, a wood veneer, a plate, or a galvanized steel plate can be used. Steel plates, aluminum alloy plates, calcium plates, asbestos rock plates and other inorganic ^ J 4 metal plates, or gypsum plates, silicic acid. For the gp test of decorative board lamination. Brush the adhesive 丨 know the film 1 and the substrate 2 bonding olefin resin resin type, ethylene-acetic acid Γ Kazakh-like adhesives, such as ethylene acetate S purpose resin, urea resin, amine
505562505562
五、發明說明(9) 酯樹脂系等乳液型接著劑,對火氣係安全的,且無臭味 價格上亦低廉,故較宜使用。 $ 實施例 以下利用實施例再詳細說明本發明。 實施例1V. Description of the invention (9) Emulsion-type adhesives such as ester resins are safe to the fire and gas system, have no odor and are inexpensive, so they are more suitable for use. Examples Hereinafter, the present invention will be described in detail using examples. Example 1
採用市售的聚對苯二甲酸丁二酯樹脂(p〇1yplasties 公司製造,Duranex 8 0 0FP),於利用擠壓製膜機製作的乂 度1 0 0 # m之未拉伸薄膜之單面上,採用硝基纖維素—' · 系油墨(昭和油墨公司製造,SAM),利用照相凹版轉 ^ 在線上印刷著色全面印刷層級花紋圖案印刷層。 、 +其次將厚度2 5 // m之透明雙軸拉伸聚對苯二一 酯薄膜(一帝人公司製造)及已施加上述印刷的聚對\ - 丁二酯薄。膜之花紋圖案印刷層面,以壓著用輥輪之:: 度·· 2 0(^ C ’樹脂薄膜之傳送速度:2〇m/min,壓 ^ ,夾ί壓力(nip Pressure) :245 1 6 6 2 Pa之條件下力丄 者兩π並以二板層以 n r . A 糸接者劑以5g/m2之塗布置塗布於戶痒A single side of an unstretched film with a degree of 100 # m of a commercially available polybutylene terephthalate resin (manufactured by P0yplasties Co., Ltd., Duranex 8 0FP) was produced using an extrusion film forming machine. On the other hand, a nitrocellulose-based ink (manufactured by Showa Ink Co., Ltd., SAM) was used, and gravure printing was used to print and print a full-scale printing pattern on the layer. , + Next, a transparent biaxially stretched polyethylene terephthalate film (manufactured by a Teijin company) with a thickness of 2 5 // m and a polyethylene terephthalate film with the above printing applied. The pattern of the pattern is printed on the surface of the film, and the rollers for pressing are used: Degree · 2 0 (^ C 'Resin film conveying speed: 20 m / min, pressure ^, nip Pressure: 245 1 Under the condition of 6 6 2 Pa, apply two π and use two layers of nr. A adhesive agent to apply 5g / m2 coating to households.
裝飾板層合用印4V。加熱壓著前述 實施例24V for decorative board lamination. Heating and pressing the foregoing embodiment 2
505562 五、發明說明(ίο) _ 使與實施例1同法之姑;,n w 二甲酸丁二酯樹脂之未拉伸薄膜的的/::1相同的聚對苯 與實施m之加熱壓著的旨薄膜對向,以 苯二甲酸丁二s旨薄膜面為壓花條/牛,以透明聚對 及由聚矽氧橡膠輥輪而成的壓 ^错由通過壓花輥輪 作出於透明聚對苯二甲酸τ二:3 ^之間並予壓著,製 之裝飾板層合用印刷樹脂薄膜。曰】^表面上具有壓花凹部 t凹版輥輪塗布二液硬化型胺酯::澤:二深30 /ζ m之照 油墨公司製造,ΟΡ-Νο· 81)於此梦德周整用塗料(昭和 膜之壓花加工面,製作外_私 /合用印刷樹脂薄 將聚胺醋系接著劑以50g/m2之^‘布旦炎裂娜薄膜。其次 材合板上,在加熱溫度:16〇€ f 厚度6_之木 ?,壓著時間:15秒之條件下e加埶接//m〇〇〇 印刷樹脂薄膜,而得裝飾板。… 引述袭飾板層合用 例於薄丁施相為丁 施I 伸酸實件作酸 拉甲與條面曱 上上 C /» 例面脂 施單樹 實的SI 與膜二 同 目 才 使除 印 件 條 的 同 相 曱由花 二藉壓 苯,過 對側通 聚輪膜 以輥薄 ,花酯 1 r^'I51JT 壓二 二餘合的二壓 苯,層刷笨的 對外的印對成 _聚層著加聚而 U於刷壓施的輪 I#設印熱予刷輥 -1接面加未印膠 直全之之加橡 &夂層色U膜施氧 r刷著Μ薄已矽 -f印有1SI面聚卜案設員一一 S早及 U圖上與丁此輪 U紋其JO酸使輥 的彳π I* 49^ 雙 之505562 V. Description of the invention (ίο) _ Make the same method as in Example 1 ;, nw Butyl diformate resin unstretched film of / :: 1 same polyparaphenylene and heating and pressing The purpose of the film is opposite, the surface of the butyl phthalate film is embossed / bull, and the transparent poly pair and the embossing made by the silicone rubber roller are made transparent by the embossing roller. Poly terephthalic acid τ 2: 3 ^ and pre-pressed, a decorative resin laminate for printing board laminate film. Namely, ^ has an embossed recess on the surface, and the gravure roll is coated with a two-liquid hardening amine ester :: Ze: Ershen 30 / ζ m, manufactured by Zhaozhang Ink Co., Ltd. 81) Here is a paint for Mende week finishing (The embossed surface of the Showa film is used to make a thin film for external printing and private use. The polyurethane adhesive is made of 50 g / m2 of ^ 'budan yanna film. Next, the plywood is heated at 16 ° C. € f wood with thickness 6_, pressing time: under 15 seconds, e plus bonding // m00 printed resin film, to obtain a decorative board .... Quoting the use case of decorative board lamination in thin film For Ding Shi I ’s acid elongation, make the acid lacquer and apply C / »on the noodles. For example, apply the SI and the film two to the same order of the grease to make the same phase except the printed strips. Through the opposite side, the polymer wheel film is thinly rolled, and the flower ester 1 r ^ 'I51JT is pressed into the two diisocyanate benzene. The wheel I # set the printing heat to the brush roller -1 interface plus unprinted glue plus the rubber & 夂 layer color U film oxygen application brushing the M thin silicon-f printed with 1SI surface Member one one S early and U picture The upper part of the wheel is U-shaped and its JO acid makes the roller 彳 π I * 49 ^ both
I 11— I I— I i —tf— I Lk II 11— I I— I i —tf— I Lk I
第15頁 505562 酸 甲二 苯 對 聚 出 作 製 間 \ly (11之 明輪 說輥 明 發用 五著 上 面 單 之 膜 薄 匕曰 刷花 印壓 用之 合膜 層薄 板脂 飾樹 裝刷 之印 部用 凸合 凹層 花板 壓飾 有裝 上此 面於 單, 外者 另再 5 ο 層膜 刷薄 印脂 有樹 出 作 製 料 塗 用 整 周 澤 色 布涂Ό έ膜 、、/薄 同卩 2飾 例裝 施的 實越 與優, 上計 面設 工觀 加外 以 次 其 上 板 膏 石 之 之加 2 /m在 塗 熱 度 厚 於 劑: 著力 妾壓 系著 酯接 胺, 聚°c 布80 塗:1 量度 布溫 飾 裝 述 前 著 壓 熱 加 下。 件板 條飾 之裝 秒得 20而 間膜 時薄 著脂 壓樹 ,刷 ap PH ο用 ο合 o y 1層 147板 估 評 性 特 之 膜 薄 脂 樹 例 施 實 估 評 特 的 述 下 就 板 飾 裝 的 作 製 所 3 及 性 染 污 耐 0^一 S3 油 筆 異 奇 性 油 色 culn 以 隹 例 施 實 於 繪 描 置油 靜筆 並異 上奇 面察 膜觀 i專艮 岭、、^PMM 脂肉 樹, 的拭 層擦 表塊 上布 最之 之醇 板乙 飾有 裝潰 的浸 作以 製, 已後 之時 3 及1 異 奇 。 的 估 微 評 些 行 極 進 之 準 度 基。程 述墨題 下油問 以筆無 ,異上 度奇用 程有實 之現著 面發存 膜被殘 薄未現 脂全發 樹完被 於··: 存◎〇 殘 油 筆 異 奇 的 微 些 之 題 問 為 成 上 用 實 著 存 殘 現 發 被 Ο · · 墨△ 油 筆 墨Page 15 505562 Methyl p-diphenyl parapolymer production system \ ly (11's Minglun said that the roller Mingfa uses five sheets of thin film and daggers, brushes, embossing, thin film grease, decorative tree, and brushes. The printed part is embossed with a convex concave concave flower plate, and the other side is mounted on the sheet, and the other is 5 ο layer film brush thin printing grease has a tree out as a material coating with a whole week color cloth coated with a film ,, / The application of the thin Tongji 2 decoration example is more practical and superior. The upper surface is designed with a working concept plus the second stone paste plus 2 / m. The coating heat is thicker than the agent: focus on the pressure with the ester amine , Poly ° C Cloth 80 Coating: 1 Measure cloth temperature decoration before pressing and heating. The lath decoration is 20 seconds, and the thin film is pressed against the fat tree, brush ap PH ο use ο 合 oy 1 The evaluation of the characteristics of the thin film of the thin layer 147 board is based on the practical evaluation of the evaluation. The following is a description of the work of the board decoration 3 and the sexual stain resistance 0 ^ -S3 oil pen bizarre oil color culin. It is true that the oil static pen is set and the strange surface is inspected. The view of the film is specially designed. The rubbing layer on the surface of the table is decorated with the most mellow alcohol plate B, which is decorated with the immersion immersion to make it. The time is 3 and 1. The evaluation is based on the accuracy of these advances. The oil question is nothing, the strangeness is different, the process is real, the face is stored, the film is thin and the fat is not fully displayed, and the tree is finished.... The actual use of the remaining quilt 〇 · · ink △ oil pen ink
墨 油 筆 異 奇 之 度 程 當 相 著 存 殘 現 發 被 XThe degree of strangeness of ink pen
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第16頁 505562 五、發明說明(12) (耐溶劑性) 將浸潰有甲乙基S同之海棉置放於實施例1、2及3製作 的裝飾板之最上表層的樹脂薄膜面上2 4小時後,肉眼觀察 薄膜表面發生變色及膨潤之程度,以下述基準進行評估二 ◎:樹脂薄膜上完全未發現有變色及膨潤之發生 〇:被發現實用上無問題程度之極些微的變^及膨 之發生。 △ •被舍現貝用上有問題転度之些微的變色及膨潤之 發生。 被發現有相當程度之變色及膨潤 X : (耐水劣化性) 先假定使本發明之裝飾板在高溫多渴, 長期間的情形(例如:用作一體成形浴室 …步 的情形等)’以杜邦衝擊試驗法評估長2 樹脂薄膜之耐水劣化性。 I、水接觸時的 將貫施例1、2及3製作的裝飾板層人 層合於厚度0· 5韻之鍍鋅鋼I飾^& ^印^树脂薄膜 切成60mm x60麗之大小,綱萬扳乍為/片。將此試片裁 離子水中一個月後’;官ΐ二二狐,保持在38 ± 2 t之去 HS K5400^ ^ ,Η ^ ; I; : ;h ^ ^ 洛下南度50cm),於以施加衝擊,以·^央=、重量1Kg、 的樹脂薄膜之狀態,艮硯①施加衝擊後 ◎:樹脂薄膜上j f m t進行評估。交 、上凡全未被發現裂縫。P.16 505562 V. Description of the invention (12) (Solvent resistance) Sponge impregnated with methyl ethyl S and the same is placed on the resin film surface of the uppermost surface of the decorative plate produced in Examples 1, 2 and 3. 2 After 4 hours, the degree of discoloration and swelling on the surface of the film was visually observed, and evaluated according to the following criteria: ◎: No discoloration and swelling occurred on the resin film at all. And swelling occurs. △ • Slight discoloration and swelling of the problematic scale used by the shellfish occurred. It was found that there was a considerable degree of discoloration and swelling X: (water resistance) First assume that the decorative panel of the present invention is thirsty at high temperatures for a long period of time (for example, used as an integrated bathroom ... steps, etc.) The impact test method evaluates the water resistance of the long 2 resin film. I. When the water is in contact, the decorative slabs produced in Examples 1, 2 and 3 are laminated on a galvanized steel with a thickness of 0.5 and 5 rhombuses. I > ^ Print ^ resin film is cut into a size of 60mm x 60 li , Gang Wan pulls for the first time. After cutting this test piece for one month in ion water '; the official two foxes, kept at 38 ± 2 t away from HS K5400 ^^, Η ^; I;:; h ^ ^ South below 50cm), Yu Yi When an impact is applied, the state of the resin film with a weight of 1 kg and 1 kg, that is, ① after the impact is applied ◎: The resin film is evaluated by jfmt. No cracks were found in Jiao and Shangfan.
505562 五、 的 的 試 示 微 。細 缝有 裂現 的發 細被 微上 有體 現全 發部 被工 上加 份花 部壓 一之 之上 膜膜 薄薄 匕曰匕曰 樹樹 13)於於 /(\ 明· · · · 說〇△ 明 發 大 較 有 現 發 被 上 體 全 立口 工 加 花 壓 之 上 膜 薄 脂 樹 於 ο 缝X 裂505562 Five, the test of the micro. The cracks appearing in the thin seam are slightly reflected on the whole hair part, and the flower part is pressed on top of the work part. The film is thin and thin. The knife is thin 13) Yu / (\ Ming ····· Speaking △ △ Mingfa is more faint than the existing thin upper body by the upper body of the upper body, and the flower is pressed on the thin film of the tree at the seam X crack
缝. 裂 的 著 顯 有 上 體 整 膜 薄 脂 樹 於 〇 · · 縫X 裂X 此估 ,評 且±1 。特 題之 問膜 無薄 並脂 上樹 用的 使等 在此 〇, 及施 ◎實 以以 , 予 分片 評試 的片 述10。 上對1 對係表 驗於 表1 實施例 評估項目 耐污染性 财溶劑性 耐水劣化性 實施例1 ◎ ◎ ◎ 實施例2 〇 ◎ ◎ 實施例3 〇 ◎ ◎The cracks and cracks are prominent in the upper body, and the whole membrane is thin. The crack X is estimated to be ± 1. The special question is that the film is not thin and the resin used on the tree is used here, and the actual application is given in order to give a piece of evaluation of the film 10. A pair of pairs are shown in Table 1. Examples Evaluation items Pollution resistance Rich solvent resistance Water degradation resistance Example 1 ◎ ◎ ◎ Example 2 ○ ◎ Example 3 ○ ◎ ◎
第18頁 505562 五、發明說明(14) 如表1所示,本發明之裝飾板層合用印刷樹脂薄膜, 係在耐污染性、耐溶劑性、耐水劣化性之任一方面均顯示 出優越的特性。 性 用 利 可 之 上 業 產 以熱 予對 般層 述脂 上樹 如材 係基 膜的 薄成 脂而 樹膜 刷薄 印酯 用二 合丁 層酸 板甲 飾二 裝苯 之對 明聚 發由 本, 成 構 得 可 故 性 定 安 度 尺 的 越 優 有 具物聚 且刷的 ,印用 少的習 動好與 變良在 縮度使 伸精為 之計, 力估又 拉刷 或印 方 造 製 的 榡 同 膜 薄 脂 樹 烯 乙 氣 改表 備可 設的 或樣 備同 設膜 新薄 %又匕日 =口 增樹 需烯 不乙 , 氯 膜聚 薄的 飾用 裝習 得與 製, 下資 件投 條備 造設 製之 及等 法良 的 越 優 性 計 設 觀 外 之 同 格 同 相 紋 花 花 壓 及 紋 花 刷。 印案 在圖 出紋 現花 中污方 脂面性 樹表物 之的面 層起表 護引等 保出性 面滲水 表之耐 或劑、 層塑性 脂可劑 樹於溶 材由耐 基生、 成發性 構未染 在故污 於,耐 由劑在 , 塑 J 者可題 再有問 含等 未染 有 類 氫 化 氯 生 發 未 於 由 際 之 物 棄 廢 燒 焚 在 。者 越再 優又 均 面 越 優 係 亦 上 境 環 護 維 在 且 慮 顧 之 境 環 染 污 無 體 氣 。 毒的Page 18 505562 V. Description of the invention (14) As shown in Table 1, the printed resin film for lamination of the decorative board of the present invention is superior in any of pollution resistance, solvent resistance, and water resistance. characteristic. Sexually useful products are produced by heat-preparing resins, such as a thin base film of a wood-based base film, and a thin film of a resin film. The reason is that the better the structure is, the better the stability scale is. The better the material is, the better it is, and the less it is, the better it is and the better it is. The better the shrinkage is, the better the extension is. Alkali thin film ethylene resin made by the square can be modified or the sample can be prepared with the new thin film% and the thickness of the film is equal to the amount of the tree, and the chlorine film is thin. System, the investment and preparation of the following investment documents and the design of the law and the better the superiority of the design of the same view of the same phase of the same pattern flower pressure and flower brush. Printed in the figure shows the surface of the surface of the soil surface of the surface of the surface of the soil surface of the surface of the tree, the surface of the surface of the tree surface, the surface of the tree, and the surface of the surface, such as surface protection, etc. The hair growth structure is not stained, and the resistant agent is present. Those who have plasticity can ask questions such as containing unstained hydrogen chloride-like hair that has not been generated and burned. Those who are better and better are all better, and the system is also environmentally friendly and environmentally friendly. The environment is contaminated and has no body gas. Poisonous
第19頁Page 19
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP34523198 | 1998-12-04 |
Publications (1)
Publication Number | Publication Date |
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TW505562B true TW505562B (en) | 2002-10-11 |
Family
ID=18375194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW88121233A TW505562B (en) | 1998-12-04 | 1999-12-03 | Print resin film for decorative sheet lamination and the decorative sheet laminated with the said resin film |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP3712617B2 (en) |
AU (1) | AU1413900A (en) |
TW (1) | TW505562B (en) |
WO (1) | WO2000034055A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014117620A1 (en) * | 2013-01-30 | 2014-08-07 | 仙居县德忆装饰材料有限公司 | Elastic plastic floor and manufacturing method thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2547232B (en) * | 2016-02-11 | 2019-04-24 | Innovia Films Ltd | Laminate web |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0811435B2 (en) * | 1991-05-17 | 1996-02-07 | 大日本印刷株式会社 | Cosmetic material |
JPH0592537A (en) * | 1991-09-30 | 1993-04-16 | Toppan Printing Co Ltd | Manufacture of decorative plate |
JP3908308B2 (en) * | 1996-09-18 | 2007-04-25 | 大日本印刷株式会社 | Manufacturing method of cosmetic material |
-
1999
- 1999-12-01 AU AU14139/00A patent/AU1413900A/en not_active Abandoned
- 1999-12-01 JP JP2000586528A patent/JP3712617B2/en not_active Expired - Fee Related
- 1999-12-01 WO PCT/JP1999/006735 patent/WO2000034055A1/en active Application Filing
- 1999-12-03 TW TW88121233A patent/TW505562B/en not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014117620A1 (en) * | 2013-01-30 | 2014-08-07 | 仙居县德忆装饰材料有限公司 | Elastic plastic floor and manufacturing method thereof |
Also Published As
Publication number | Publication date |
---|---|
JP3712617B2 (en) | 2005-11-02 |
WO2000034055A1 (en) | 2000-06-15 |
AU1413900A (en) | 2000-06-26 |
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