TW505562B - Print resin film for decorative sheet lamination and the decorative sheet laminated with the said resin film - Google Patents

Abstract

It is an object of this invention to provide a print resin film for the decorative sheet lamination and the decorative sheet laminated with the said resin film. The said print resin film has excellent grain and pattern in appearance design better than that of the convention polyvinyl chloride resin film and excellent in the surface characteristics such as stain resistance, solvent resistance. Therefore, the printing layer which is composed of grain and pattern printing layer and wholly printed printing layer, then surface protection layer being selectively embossed was laminated onto the wholly printed printing layer, then gloss adjusting layer being selectively applied onto the surface protection layer in the order from the bottom to upper on the substrate resin layer of printing substrate to form the print resin film for the decorative sheet lamination. The said print resin film for the decorative sheet lamination can be adhered onto the substrate such as wood board, metal sheet, inorganic board to form a decorative sheet.

Description

505562 V. Description of the invention α) TECHNICAL FIELD The present invention relates to a printed resin film laminated on a decorative board used for various furniture or building interior decoration materials, and a decorative board laminated with the printed resin film. The background of the technical skills has been decorated with decorative materials, such as decorative materials β, inside the building or the like ¢ -81. Each effect makes the base of the layered resinous tree become the common method of printing and adding spells. The universal tree picker is called S amine resin alcohol amine. It has ¾ mouth ^ back. The surface of the film is decorated with a thin layer of brush. The protective layer of the printing is covered with a quilt. 'After the film is thinned, the second layer is printed, the second layer is printed, and the force of the layer is intended to be fattened, and the method is applied to the tree, and the method is used for daily mining 2 in 3 / IV > / (layer Back thin

D

Wait, F library F decorative or mounting of the film, thin plate Hikaoka S heteropolyzinc drawing and drawing on the shaft double layer or agent film with a thin film of ethylene chloride, thin transparent decoration of the poly film The upper layer base is installed on the thin film decoration of the plate decoration X) / 1-1 / 1 \ Said on the upper layer to cut and then cut "and so on 7"-Cut 纟 工 V 加加 又 U Bao, Baokou ^ Cut in the crack Vi, when the turtle is full, it will apply the film to the thin and strong decoration. When the film is thin, the thin work is decorated with questions, and the equal volume is filled with ink. From V- 分 β, Ji of CU The buccal layer has been used in the field, and it is easy to use. 2) The ease of the material} (3 sides are more isothermal than the superficial layer. The soft lines of the agent are soluble in flowers, resistant to flowers ,, Compared with film, compressibility and soft dyeing are soft and difficult to resist. Although the surface is thin, the surface plus plate lacks the flower decoration and the pressure is applied. In addition, the thinner, the better the decoration.

Page 6 505562 The polluted place is resistant to abandonment and waste, and the film is fed into the thin burned olefin and then burned in the gas, and the polymer is used. The film is dissolved and resistant to the surface. It is said that the poisoning furnace of the dyeing gas containing I and P is burned in the body due to injury and the poisonous burning of the interstitial gas is burned in the body. The practical use of physical, harmful and social gatherings is resolved with the use of customary solutions. The problematic issue of the question is to consider the more and more superior the quality of the flower dress, the better the surface properties, the surface and the surface of the surface, such as the top-up agent, the solvent resistance, the plate decoration dyeing resistance Membrane for thin lipid extraction with tree, vinyl case B Figure chlorine pattern for plate decoration. Membrane thin film helium = mouth laminated layer and membrane thin palm tree for printing and printing. 0 board title decoration lesson I | Ming Send a tree brush printing with laminated board decoration item 11 Di Wei Li specially asked Shen Zhiming to send this layer of tree protection material in front of the surface description table, set the printing system layer on the layer, and brush the printing layer to connect the front material. The film pair is thinner than the special layer decorated on the bag, and the sequence film is brushed by the second layer to cover Fan Yinli. Specializing in the application, please indicate the full characteristics of the application on the application. The film of the thin layer of the film is decorated with a decorative plate, and the tree is printed with the order of the protective surface and the surface. Let's use the Lidi system for painting. The surrounding layer is brushed and printed with special descriptions, please complete the front surface, the back of the surface is thin, and the hair decoration layer is protected. Figure # 化 纹 述. The front layer of the flower is layered and printed on the lower surface of the full layer. The front layer is printed on the tree surface. The front side is characterized by the special color of the material. The base film is masked by the thin layer and the printed layer. Of

Page 7 V. Description of the invention (3) The aforementioned equipment is preferably composed of a poly-S tree, the aforementioned equipment, a pair of stupid Dijia, and the aforementioned equipment is preferably provided with an embossing layer. The aforementioned device is made of a polyphenylene diene film of at least one side of the present invention. The aforementioned device is preferably a decorative board laminated with the aforementioned device. The veneer lamination grease becomes suitable for veneer lamination using butyric acid tree veneer laminating and processing, and the veneer laminating with butyl formate for decorative board, 'the veneer has been laminated before the printing. Resin veneer is based on the substrate, and then the resin veneer layer is set. Printing resin film, 0 printing resin film, preferably grease. Printing resin film, resin on the surface protection layer is better. It is characterized in that the decorative film is laminated and the adhesive layer is laminated between the 4 films, and the galvanized steel sheet is used, or the example 2 is shown in the chart. Ding Ben ^ Ming's print of decorative board lamination printing other Γ is cut out to show the surface of the present invention, "Board laminating printing other ί3" is cut out to show the surface of the decorative board lamination printing protective layer resin system of the present invention Adjust the color of the surface protective layer ^ Resin-based substrates with printed tree decorative films or inorganic 'films' films 505562 5 4 / ί ν 发 发 发 发 明 发 发Figure 4 5 for the first

The examples of the examples are shown in the figure, and the quality of the resin is based on the brush base and the film with full selectivity. The quality can be 0. The example shows that the design is also superior in terms of design. Contents of the invention. Fig. 1 is a cross-sectional view showing a printed tree for laminated veneer lamination according to the present invention. Figures 2 and 3 show the best form of the polyvinyl chloride resin film of the present invention, and there is a concern that the environment may be polluted due to harmful substances during incineration. Resin films that can be laminated and printed with decorative patterns that can replace polyvinyl chloride and have a good design appearance, and that are superior in stain resistance and solvent resistance on the physical surface are discussed. As a result, a polybutylene terephthalate film can be used as the base resin layer of the printing material. A printed layer formed by forming a pattern printed layer and a lower layer of an ash surface printed layer is added, and a surface protection layer with selective embossing processing is laminated in sequence from the bottom, and a decorative board is formed thereon. Resin film. On the attack, Yongte will use polybutylene terephthalate on the surface protection layer plus a printing layer formed by brushing with the substrate, omitting the base village ^: thin down, and knowing the layer, and the above Resin films are laminated on metal plates, decorative plates, etc. The above-mentioned superior inorganic materials with resin films are also found to be damaged in appearance and design. From the 'special film' fat film to the decorative plate laminate printing Shuyuezhi

505562 V. Description of the invention (5) Sectional views of other examples of films. Fig. 4 and Fig. 5 are diagrams showing the aunt of the present invention. In the figure, 1 is an example of a decorative plate for decorative board lamination. The cross-section is an adhesive layer, 4 is a base resin layer, 5 is a diisocyanate film, 2 is a substrate, a -3 pattern print layer, and 6 is a surface protection layer. Layers ", King face / 卩 brush layer, 5 b is the flower adjustment layer, 9 is the decorative board. 9 for the coating recessed part '8 for the color-^ ϊ ί # i 1 «^ Printed from the pattern printing layer 5b J ^ 王 $ Printing layer 5a, pattern, protective layer 6, shown as 7Λ5, can also be Adopted J :::! Resin film 1 'As shown in Figure 2, the printed resin gastric membrane 1 is closed on a single layer of the table = ίί6 #, such as 3f 5b ^ ^ ^; V / 5a ○ ^ ^;:? r The base resin layer 4 with a color "heart" is provided on the upper layer, although it has inherent 505562

V. Description of the invention (6) Poly (butylene terephthalate) film with a viscosity (IV value) of 1 · 0 ～ 2 · 0 is suitable, but the inherent viscosity is below 1.5 from the aspect of film formation. In terms of timeliness (resistance to water deterioration), it is preferably 1 or 2 or more. When the base resin layer 4 is formed into a film using an extruder, the colored pigment may be kneaded into a colored resin layer. The printing layer 5 is a pattern printing layer 5 b and a substrate resin layer 4 covering the entire surface of the pattern printing layer 5 b which has shown patterns such as wood grain, stone grain, surface pattern of natural leather, cloth pattern, abstract painting, etc. The layer 5b is printed with the color of the base material, and simultaneously imparts the thermal adhesiveness of the base resin layer 4 and the surface protective layer 6 to the full-print layer 5a that has been applied to the entire surface of the base resin layer 4 '. Although the ink vehicle (V ehic 1 e) of the layer 5 can be a known cellulose derivative such as nitrocellulose or cellulose acetate, or a polyesteramine S resin, it is known for its adhesion and thermal adhesiveness. The two viewpoints are preferably a nitrocellulose alkyd resin ink. To use with a membrane. This resin is all made by lining to the following group of soft chain-like alkylene diacids, which is printed on the surface of the original polymer, and the bottom is brushed. It is an alcohol-based binary protective layer. Viscosity 1. Resin thin The characteristic brush layer 5 a coating method is suitable for this copolymerization or poly-ε acid, etc., preferably a polyester resin film, of which a polybutylene terephthalate resin of 0 to 2 · 0 is more suitable. The film is made of plasticizer and polyester without South element. Further, a printed layer 5 made of the upper and pattern printed layer 5b is provided on the surface protective layer 6, and the base resin layer 4 described above may be omitted. As an example of the material of the ester resin, a polyester resin or the like is preferably used. That is, as for the softness of the resin, polyoxyl-caprolactone, azelaic acid, sebacic acid, and n-dodecane such as polyethylene glycol and polytetramethylene glycol are used. H00C- [CH] -C00H Molecularly structured fat

505562 V. Description of the invention (7) Aliphatic aliphatic polyester formic acid bicyclo; a carboxylic acid, a hard segment of adipose and / or dibenzyl fgf tree, and ^ f courtyard di-tau cyclohexene 7 2, terephthalic acid cyclohexyl benzene 1; 3 aromatic y or cycloaliphatic butyl 2,6 dicarboxylic acid: ^,;:, f ΐ; It can be made as follows: The printing resin surface for the lamination of the y-parts can be laminated to the substrate resin 1 as follows: That is, the surface protection layer 6 is below, the layer 4 and the surface protection are above 4: of, The upper φ of the brush layer 5 passes through a pair of Γ ί f ίί ㈣ in the state of Bao J: and 挟 掊 Η 挟 掊 Η—combined with heat: ί f laminated and laminated by heat to make and produce the base The printing surface sounds 5 and jf of the resin layer 4 are dazzled from the f surface protective layer 6 to the resin film i. Brush the surface layer 5 and make-a piece of decorative plate for embossing for printing, embossing of the second substrate resin layer 4 and the surface protection layer 6... On the surface of the surface protection layer, the surface protection layer 6 can be obtained on the surface of the surface protection layer 6 ^ consistent lamination and embossing plus j shows the printed resin thin film for lamination board lamination 1 2 layer 4 can be made into a printed pattern due to its excellent scale stability, and it can be made into a printed pattern]: embossed decorative film with two designs caused by tensile force or heat, The same color j ^ mouth operation or embossing processing page 12 5. The invention finds ^ the search step-t operation. Then go to I: the same polyvinyl chloride resin film is used for the same stop 8ze adjustment; 8 'as the first As shown in Figure 3 *, eP Z can be used in combination with f protection on the surface protection and core layer. It can also be used to make design resins. The decorative board layer of the light n's f #Adjusting layer 8 is to adjust the decorative board layer regardless of whether it is colorless or transparent? Ester resin, 璟 a 舛 ί color agent, phenolic resin, unsaturated ^ taken usually to make = ii ί 、, i ΐ to form the color adjustment layer 8, the material can be used mica, dioxy ^ J Yaί and the expected gloss, but eliminate Shi Xisha, Shi Xi hollow ball and so on. S j Ming 'carbonic acid word, Shi Xi algae earth, phase gravure coating, self-coating, ϊ t i ί f coating method, can be used according to the use of the above; j 3 3 f cloth method. Lipid film 1, through the adhesive layer 3, two inhibitions 2 = 2 printed board for lamination of decorative panels 5 decorative panel 9 shown in the figure. As for the ^ cylinder mouth soil plate 2 can be obtained in Figure 4 or the wood plywood, particle board, MDF, 箄 i i 4 ', for example, a wood veneer, a plate, or a galvanized steel plate can be used. Steel plates, aluminum alloy plates, calcium plates, asbestos rock plates and other inorganic ^ J 4 metal plates, or gypsum plates, silicic acid. For the gp test of decorative board lamination. Brush the adhesive 丨 know the film 1 and the substrate 2 bonding olefin resin resin type, ethylene-acetic acid Γ Kazakh-like adhesives, such as ethylene acetate S purpose resin, urea resin, amine

505562

V. Description of the invention (9) Emulsion-type adhesives such as ester resins are safe to the fire and gas system, have no odor and are inexpensive, so they are more suitable for use. Examples Hereinafter, the present invention will be described in detail using examples. Example 1

A single side of an unstretched film with a degree of 100 # m of a commercially available polybutylene terephthalate resin (manufactured by P0yplasties Co., Ltd., Duranex 8 0FP) was produced using an extrusion film forming machine. On the other hand, a nitrocellulose-based ink (manufactured by Showa Ink Co., Ltd., SAM) was used, and gravure printing was used to print and print a full-scale printing pattern on the layer. , + Next, a transparent biaxially stretched polyethylene terephthalate film (manufactured by a Teijin company) with a thickness of 2 5 // m and a polyethylene terephthalate film with the above printing applied. The pattern of the pattern is printed on the surface of the film, and the rollers for pressing are used: Degree · 2 0 (^ C 'Resin film conveying speed: 20 m / min, pressure ^, nip Pressure: 245 1 Under the condition of 6 6 2 Pa, apply two π and use two layers of nr. A adhesive agent to apply 5g / m2 coating to households.

4V for decorative board lamination. Heating and pressing the foregoing embodiment 2

505562 V. Description of the invention (ίο) _ Make the same method as in Example 1 ;, nw Butyl diformate resin unstretched film of / :: 1 same polyparaphenylene and heating and pressing The purpose of the film is opposite, the surface of the butyl phthalate film is embossed / bull, and the transparent poly pair and the embossing made by the silicone rubber roller are made transparent by the embossing roller. Poly terephthalic acid τ 2: 3 ^ and pre-pressed, a decorative resin laminate for printing board laminate film. Namely, ^ has an embossed recess on the surface, and the gravure roll is coated with a two-liquid hardening amine ester :: Ze: Ershen 30 / ζ m, manufactured by Zhaozhang Ink Co., Ltd. 81) Here is a paint for Mende week finishing (The embossed surface of the Showa film is used to make a thin film for external printing and private use. The polyurethane adhesive is made of 50 g / m2 of ^ 'budan yanna film. Next, the plywood is heated at 16 ° C. € f wood with thickness 6_, pressing time: under 15 seconds, e plus bonding // m00 printed resin film, to obtain a decorative board .... Quoting the use case of decorative board lamination in thin film For Ding Shi I ’s acid elongation, make the acid lacquer and apply C / »on the noodles. For example, apply the SI and the film two to the same order of the grease to make the same phase except the printed strips. Through the opposite side, the polymer wheel film is thinly rolled, and the flower ester 1 r ^ 'I51JT is pressed into the two diisocyanate benzene. The wheel I # set the printing heat to the brush roller -1 interface plus unprinted glue plus the rubber & 夂 layer color U film oxygen application brushing the M thin silicon-f printed with 1SI surface Member one one S early and U picture The upper part of the wheel is U-shaped and its JO acid makes the roller 彳 π I * 49 ^ both

I 11— I I— I i —tf— I Lk I

Page 15 505562 Methyl p-diphenyl parapolymer production system \ ly (11's Minglun said that the roller Mingfa uses five sheets of thin film and daggers, brushes, embossing, thin film grease, decorative tree, and brushes. The printed part is embossed with a convex concave concave flower plate, and the other side is mounted on the sheet, and the other is 5 ο layer film brush thin printing grease has a tree out as a material coating with a whole week color cloth coated with a film ,, / The application of the thin Tongji 2 decoration example is more practical and superior. The upper surface is designed with a working concept plus the second stone paste plus 2 / m. The coating heat is thicker than the agent: focus on the pressure with the ester amine , Poly ° C Cloth 80 Coating: 1 Measure cloth temperature decoration before pressing and heating. The lath decoration is 20 seconds, and the thin film is pressed against the fat tree, brush ap PH ο use ο 合 oy 1 The evaluation of the characteristics of the thin film of the thin layer 147 board is based on the practical evaluation of the evaluation. The following is a description of the work of the board decoration 3 and the sexual stain resistance 0 ^ -S3 oil pen bizarre oil color culin. It is true that the oil static pen is set and the strange surface is inspected. The view of the film is specially designed. The rubbing layer on the surface of the table is decorated with the most mellow alcohol plate B, which is decorated with the immersion immersion to make it. The time is 3 and 1. The evaluation is based on the accuracy of these advances. The oil question is nothing, the strangeness is different, the process is real, the face is stored, the film is thin and the fat is not fully displayed, and the tree is finished.... The actual use of the remaining quilt 〇 · · ink △ oil pen ink

The degree of strangeness of ink pen

ϋ

P.16 505562 V. Description of the invention (12) (Solvent resistance) Sponge impregnated with methyl ethyl S and the same is placed on the resin film surface of the uppermost surface of the decorative plate produced in Examples 1, 2 and 3. 2 After 4 hours, the degree of discoloration and swelling on the surface of the film was visually observed, and evaluated according to the following criteria: ◎: No discoloration and swelling occurred on the resin film at all. And swelling occurs. △ • Slight discoloration and swelling of the problematic scale used by the shellfish occurred. It was found that there was a considerable degree of discoloration and swelling X: (water resistance) First assume that the decorative panel of the present invention is thirsty at high temperatures for a long period of time (for example, used as an integrated bathroom ... steps, etc.) The impact test method evaluates the water resistance of the long 2 resin film. I. When the water is in contact, the decorative slabs produced in Examples 1, 2 and 3 are laminated on a galvanized steel with a thickness of 0.5 and 5 rhombuses. I > ^ Print ^ resin film is cut into a size of 60mm x 60 li , Gang Wan pulls for the first time. After cutting this test piece for one month in ion water '; the official two foxes, kept at 38 ± 2 t away from HS K5400 ^^, Η ^; I;:; h ^ ^ South below 50cm), Yu Yi When an impact is applied, the state of the resin film with a weight of 1 kg and 1 kg, that is, ① after the impact is applied ◎: The resin film is evaluated by jfmt. No cracks were found in Jiao and Shangfan.

505562 Five, the test of the micro. The cracks appearing in the thin seam are slightly reflected on the whole hair part, and the flower part is pressed on top of the work part. The film is thin and thin. The knife is thin 13) Yu / (\ Ming ····· Speaking △ △ Mingfa is more faint than the existing thin upper body by the upper body of the upper body, and the flower is pressed on the thin film of the tree at the seam X crack

The cracks and cracks are prominent in the upper body, and the whole membrane is thin. The crack X is estimated to be ± 1. The special question is that the film is not thin and the resin used on the tree is used here, and the actual application is given in order to give a piece of evaluation of the film 10. A pair of pairs are shown in Table 1. Examples Evaluation items Pollution resistance Rich solvent resistance Water degradation resistance Example 1 ◎ ◎ ◎ Example 2 ○ ◎ Example 3 ○ ◎ ◎

Page 18 505562 V. Description of the invention (14) As shown in Table 1, the printed resin film for lamination of the decorative board of the present invention is superior in any of pollution resistance, solvent resistance, and water resistance. characteristic. Sexually useful products are produced by heat-preparing resins, such as a thin base film of a wood-based base film, and a thin film of a resin film. The reason is that the better the structure is, the better the stability scale is. The better the material is, the better it is, and the less it is, the better it is and the better it is. The better the shrinkage is, the better the extension is. Alkali thin film ethylene resin made by the square can be modified or the sample can be prepared with the new thin film% and the thickness of the film is equal to the amount of the tree, and the chlorine film is thin. System, the investment and preparation of the following investment documents and the design of the law and the better the superiority of the design of the same view of the same phase of the same pattern flower pressure and flower brush. Printed in the figure shows the surface of the surface of the soil surface of the surface of the surface of the soil surface of the surface of the tree, the surface of the surface of the tree surface, the surface of the tree, and the surface of the surface, such as surface protection, etc. The hair growth structure is not stained, and the resistant agent is present. Those who have plasticity can ask questions such as containing unstained hydrogen chloride-like hair that has not been generated and burned. Those who are better and better are all better, and the system is also environmentally friendly and environmentally friendly. The environment is contaminated and has no body gas. Poisonous

Page 19

Claims (1)

88121233 said before printing 3. Thin substrate? +2 board laminated printing resin film, 5 layers of resin resin layer, printing layer, surface protection sound are sequentially laminated with a brush layer set on the aforementioned substrate resin layer Surface: And: On top, the above-mentioned series t are laminated in order from the bottom, so that the Koss printing layer is disposed on a decorative film for a decorative board laminating printing resin film, a brush layer, a surface protection layer, and the surface protection layer. The back is fully formed. : Shen = Decorative plate of item i or item 2 of the range :, where the printing layer is made of a pattern :: the printing base of a patterned printing layer with a printed resin edge of the full-printed layer 4 · If the scope of patent application is 3 The surface protective layer is made of polyimide; using a printed resin film, 5 · If the scope of the patent application is @, where the polyacetate resin is poly-p-phenylene methacrylate: the printing resin for board lamination is thinly exposed. Resin. 6 · If the scope of patent application is 篦 R ^ ^ I νΛ "; ^ " ep " J ^^ 'V2: f Patent Range No. 1, No. 2' No. 4 or No. 6 decorative layer combined printing Resin film with color on top of the surface protection layer: jkjjjoa 881919QQ Amendment VI. Scope of patent application The whole floor. 8. If the first scope of the patent application is applied, the substrate resin layer is made of a printing resin film for lamination of clothing and decorative boards, and a resin of butylene dibenzate. 9 · If item 7 of the scope of the patent application is based on the laminated resin film, the printed resin film for the lamination board lamination, the printed resin film is used in combination with the ":::" lamination of the aforementioned decorative board layer on one side 10. Patent Fan Yuan No. 9 ^ The substrate and the aforementioned split-throw film are used to form a plate :::: printing resin film, which is laminated through an adhesive. Between printed resin films for mouthpieces 11 · The film according to item No. 0 of the patent application scope, in which the substrate is a galvanized steel sheet. g η Printing resin thin Brush resin thin 1 2. The decorative board laminated film according to the scope of application for patent No. 0, wherein the substrate is a wooden board. Thin printed resin 1 3 · The decorative board laminate film according to item 10 of the patent application, wherein the substrate is an inorganic board. 88121233-91009-1483TW.ptc page 23 read.