TW503581B - Dual-type thin-film field-effect transistors and method for forming the same - Google Patents

Dual-type thin-film field-effect transistors and method for forming the same Download PDF

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TW503581B
TW503581B TW089109150A TW89109150A TW503581B TW 503581 B TW503581 B TW 503581B TW 089109150 A TW089109150 A TW 089109150A TW 89109150 A TW89109150 A TW 89109150A TW 503581 B TW503581 B TW 503581B
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Thomas Doderer
Wei Huang
Chang C Tsuei
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Ibm
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78696Thin film transistors, i.e. transistors with a channel being at least partly a thin film characterised by the structure of the channel, e.g. multichannel, transverse or longitudinal shape, length or width, doping structure, or the overlap or alignment between the channel and the gate, the source or the drain, or the contacting structure of the channel
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N99/00Subject matter not provided for in other groups of this subclass
    • H10N99/03Devices using Mott metal-insulator transition, e.g. field-effect transistor-like devices

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  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Thin Film Transistor (AREA)

Abstract

A microelectronic device includes a gate layer adapted to receive an input voltage. An insulating layer is formed on the gate layer, and a conductive channel layer is formed on the insulating layer and carries current between a source and a drain. The conductive channel layer is adapted to provide a dual channel. The dual channel includes both a p-channel and an n-channel wherein one of the p-channel and the n-channel are selectively enabled responsive to the input voltage polarity. A method for forming the device and applications are also disclosed and claimed.

Description

503581 發明說明(i) iOL專利申譆案說明 本專利申請案取得申請號60/ 1 24 867,申請曰 1999/03/17的臨時專利φ 士主安a y置*也 ..lL , 發明背景 j甲明案的優先榷,其在此供參考。 L^m範疇 2明大致有關於薄膜微電子元件,而且尤其有關於雙 U膜場效電晶體(TFT),包括陪洛或模特 微電子及光電應用。 7十汉 L前案錄.明 體業是以矽裝置的實施及特性為主,新微電 石夕(Si)以外材料作為開關的研發是新 金礼半(CMOS)技術是微電子業的主要角色,南 種電晶體,一種是11型電晶體(NM0S)而另一種是P型 正=。其主要是使用負擴散(摻雜)石夕(以電子為主)或是 正摻雜石夕(以電洞為主)在石夕中製造。 彭=以,整/Λ薄媒技術製造電晶體,在f用11井cm〇s 製秋中’在η井本身形成p通道(p型)電晶 Α 細通道(η型)。 PUb曰體及在卩基底中形 提供更多種類的半導體,而期望有一種裝置能提供 選擇性通道根據輸入信號而導通,因此需要一 類型薄膜場效電晶體(TFT),以便閘極雷m Μ 1又(P) 闲極電壓的極性發生變 2時,可以在單一裝置中達成n型或卩型傳導通 發明總^ ‘ 因此本發明的目的是提供一種方法及結構,其中單一裝 581 五、發明說明(2) 置執行η型及〇刑值m 置封裝密产 ,其優點為簡化製程及連接,增加裝 .^Η "及開發新的微電子或光電電路應用。 3個終Χ端裝置另:的J提供1方法及對應結構,其中由 晶體(TFT)裝置结構極及〉及極)形成高性能薄膜場效電 3個=!另,目的是提供一種方法及對應結構,其中由 或個3頂及底閘極之終端裝置形成可控以了裝置結 以控制門襤(導通)電壓及通道傳導。 材ί t:D:目的是提供一種方法及製程以實施以陪洛 材科或模特材料為架構之切換裝置。例如 物:YWCMb其“在〇 m之間,U2丸Cu吏〇用二 之„、間,Nd2—xCexCu〇4-5,5在0與1之間,而X在0與1 曰 ’ Bi2Sr2CanCun+1〇“2n,HgBa2CanCun+102n+4, 、 l2Ba2CanCunH06+2n ’(Sri xCax)3Ru2〇 其中乂 &(Sr/Ca)n+1RUn03n+lSr。 之間, 本發明的另一目的是提供一種新的ybc〇(yb 材料以實施雙類型TFT開關裝置。 3 7 k道 本發明的另一目的是提供一種在積聚模式中 型開關裝置。 …呆作之雙類 本發明的另一目的是,雙類型單一襞置提供達移 路應用,如全波整流電路。 、匕, 本發明的另目的疋可以用本發明之單類型TFT#蜜 代習用全波橋式整流器之4個模式。 &置取 本發明的另一目的是提供雙類型裝置,其可適用 於微電 503581 五、發明說明(3) 子及光電子應用如邏輯閘極,多JE記憶格,及顯示器或 LED驅動裝置。 一種微電子裝置包括一閘極層矸接收一輸入電壓,一絕 緣層形成在閘極層上,及傳導通道層形成在絕緣層上,及 承載源極與汲極間之電流。傳導通道層可提供雙通道,雙 通道包括一 p通道及一 η通道,其47遂擇性致能P通道及η通 道之一以回應輸入電壓。 根據本發明之電路包括一薄膜電晶體具有一閘極,一源 極及一汲極。薄膜電晶體包括_闊極層用以形成閘極。閘 極可接收輸入電壓,在閘極層上形成絕緣層,在絕緣層上 形成一傳導通道層用以承載源極與汲極間之電流。傳導通 道層可提供雙通道,而雙通道包栝一 ρ通道及一 η通道,其 中選擇性致能Ρ通道及η通道之一以回應輸入電壓。 在其他實施例中,閘極層包括一凹陷閘極結構,傳導通 道層包括模特絕緣材料,如YBa2CU3〇7_ 5,其中5在〇與1之 間,最好在〇與〇 · 5之間。閘極層包括摻雜鈮之二氧化鈦 錄’而絕緣層包括二氧化鈦鳃。最好形成p通道以回應負 輸入電壓’及最好形成^通道以回應正輸入電壓。p通道最 好包括一電洞積聚層以回應負輸入電壓,而η通道最好包 電子積聚層以回應正輸入電壓。微電子裝置最好包括 一薄膜電晶體’源極或汲極可接到負荷,而其他源極或汲 f可接到交流電壓’俾薄膜電晶體能將負荷上之交流電壓 流。薄膜電晶體可連接及驅動一發光二極體。 種形成雙通道電晶體之方法,包括以下步驟··提供一 503581 發明說明(4) 閘極層用以接收輪入電壓,在閘極層 絕緣層上形成—雙通道層,方法是藉由况積一絕緣層,在 沈積一杯率層及於氧存在時使杯率^回士在絕緣層上磊晶 缺陷之杯率層,俾雙通道包括一 P通道另__以提供—實質無 擇性致能p通道及η通道之一以回應操 —η通道,其中選 及在傳導通道層上形成源極及汲極。功間之輸入電壓, 在其他方法中,提供一閘極層之步 樣以形成一凹陷閘極結構,杯率層括疋閘極層之圖 如YBa2Cu3〇H,其中5在0與1之間,最杯一=特絕緣材料, 提供一氧化閘極層之步驟包括摻,〇. 5之間。 更=成-電洞積聚層以回應負二該方法 Ϊ更包括形成-電子積聚層以回應正輸。該方 火步驟包括維持溫度在約2〇(rc與約5〇〇 ^之乂驟。回 0.2小時與約5小時之間。回火 ,長達約 :率層之氧含量之步驟。回火步回調整 真空及惰性氣體中回火之步驟。 在減/ ¥丨兄包括 由以下實施例的詳細說明及配合附 的這些及其他目的,特徵及優點。 更月了本發明 1圖簡單銳.明 明由較佳實施例的說明並配合附圖即可更明了本發 圖1是習用氧化模特絕緣薄膜電晶體(MTFT)裝置 圖,具有單一P通道; °】面 圖2是根據本發明雙類型TFT的剖面圖;503581 Description of the invention (i) The iOL patent application shows that this patent application has obtained application number 60/1 24 867, and has applied for a temporary patent of 1999/03/17. The Jia Ming case has priority, which is here for reference. L ^ m category 2 is generally about thin film microelectronic components, and especially about dual U film field effect transistors (TFTs), including Piro or model microelectronics and optoelectronic applications. The previous record of Shihan Han L. Ming Sports is mainly based on the implementation and characteristics of silicon devices. The research and development of materials other than new micro calcium carbide (Si) is the key to the development of new CMOS technology. The role, the South type transistor, one is a type 11 transistor (NM0S) and the other is a P-type positive =. It is mainly manufactured in Shixi using negatively-diffused (doped) Shixi (dominated by electrons) or positively doped Shixi (dominated by holes). Peng = manufacturing transistor with thin-film technology, using 11-well cm0s in f in the f 'to form p-channel (p-type) transistor in η itself Α fine channel (n-type). PUb provides a wider variety of semiconductors in the form of ytterbium substrates, and a device is expected to provide selective channels to conduct according to the input signal. Therefore, a type of thin film field-effect transistor (TFT) is required to make the gate Μ 1 and (P) When the polarity of the idler voltage changes 2, the n-type or 卩 -type conduction can be achieved in a single device. Therefore, the object of the present invention is to provide a method and structure in which a single device 2. Description of the invention (2) The implementation of η-type and 〇 penalty value m-packaged dense production, its advantages are to simplify the process and connection, increase installation. ^ Η " and develop new microelectronics or optoelectronic circuit applications. 3 terminal X-end devices In addition: J provides 1 method and corresponding structure, in which high-performance thin film field-effect electricity is formed by the structure of the TFT (TFT) device and 3 =! In addition, the purpose is to provide a method and Corresponding structure, in which three or top and bottom gate terminal devices are formed to control the device junction to control the gate (on) voltage and channel conduction. Material: t: D: The purpose is to provide a method and process to implement a switching device based on the materials or model materials of Luoluo. For example: YWCMb: "Between 0m, U2 pills, Cu, and two," Nd2-xCexCu, 4-5, 5 is between 0 and 1, and X is between 0 and 1, "Bi2Sr2CanCun + 10 "2n, HgBa2CanCun + 102n + 4,, l2Ba2CanCunH06 + 2n '(Sri xCax) 3Ru2〇 where 乂 & (Sr / Ca) n + 1RUn03n + lSr. Another object of the present invention is to provide a new Ybc0 (yb material to implement dual-type TFT switching devices. 37 k channels Another object of the present invention is to provide a medium-type switching device in accumulation mode. ... dumb dual-type Another object of the present invention is dual-type A single device provides up-to-the-road applications, such as full-wave rectifier circuits. Another object of the present invention is to use the single-type TFT # honey of the present invention to replace the four modes of a full-wave bridge rectifier. Another object of the present invention is to provide a dual-type device, which can be applied to microelectronics 503581 V. Description of the Invention (3) Sub-electronics and optoelectronic applications such as logic gates, multiple JE memory cells, and display or LED driving devices. The device includes a gate layer, which receives an input voltage, and an insulating layer is formed on the gate. Layer, and the conductive channel layer is formed on the insulating layer and carries the current between the source and the drain. The conductive channel layer can provide dual channels. The dual channels include a p-channel and an n-channel. 47 is selectively enabled. One of the P channel and the η channel responds to the input voltage. The circuit according to the present invention includes a thin film transistor having a gate, a source, and a drain. The thin film transistor includes a wide electrode layer for forming a gate. The pole can receive input voltage, form an insulating layer on the gate layer, and form a conductive channel layer on the insulating layer to carry the current between the source and the drain. The conductive channel layer can provide dual channels, and the dual channels include one ρ channel and an η channel, wherein one of the P channel and the η channel is selectively enabled in response to an input voltage. In other embodiments, the gate layer includes a recessed gate structure, and the conductive channel layer includes a model insulation material, such as YBa2CU3 〇7_ 5, where 5 is between 0 and 1, preferably between 0 and 0.5. The gate layer includes niobium-doped titanium dioxide and the insulating layer includes titanium dioxide gills. It is best to form a p-channel to respond to negative Input voltage It is better to form a ^ channel to respond to the positive input voltage. The p channel preferably includes a hole accumulation layer to respond to the negative input voltage, and the η channel preferably includes an electron accumulation layer to respond to the positive input voltage. The microelectronic device preferably includes a The thin film transistor 'source or drain can be connected to the load, and other sources or drains can be connected to the AC voltage'. The thin film transistor can flow the AC voltage on the load. The thin film transistor can be connected and driven A method for forming a dual-channel transistor, including the following steps: · Provide a 503581 description of the invention (4) The gate layer is used to receive the wheel-in voltage and is formed on the gate layer insulation layer-a dual-channel layer. The method is: By accumulating an insulating layer, a cup ratio layer that allows the cup ratio to be deposited in the presence of oxygen and a cup ratio layer in the presence of oxygen, the double channel includes a P channel and __ to provide-substance One of the p-channels and the n-channels is selectively enabled to respond to the operation-n-channels, and a source and a drain are selected and formed on the conductive channel layer. The input voltage between work, in other methods, a step pattern of the gate layer is provided to form a recessed gate structure. The cup rate layer includes a graph of the gate layer such as YBa2Cu3〇H, where 5 is between 0 and 1. 5。 The most cup one = special insulation material, the step of providing an oxide gate layer includes doping, between 0.5. More = forming a hole accumulation layer in response to negative two. This method also includes forming an -electron accumulation layer in response to positive input. The tempering step includes a step of maintaining the temperature at about 200 (rc and about 5000). Returning between 0.2 hours and about 5 hours. Tempering, up to about: the oxygen content of the rate layer. Tempering Step back to adjust the steps of vacuum and tempering in an inert gas. The minus / ¥ 丨 brother includes these and other purposes, features and advantages attached by the detailed description of the following embodiments and cooperation. The figure of the present invention is simple and sharp. The present invention will be made clearer by the description of the preferred embodiment and the accompanying drawings. Figure 1 is a diagram of a conventional oxidized model insulating thin film transistor (MTFT) device with a single P channel; Figure 2 is a dual type according to the present invention Sectional view of TFT;

503581 五、發明說明(5) "~' 〜...........................— 圖3是根據本發明圖2 TFT的上視圖; 圖4是根據本發明雙類型TFT的閘極層剖面圖,以 構的基底及顯示圖樣以形成各自的凹陷閉極· ^ ^… 圖5是根據本發明雙類型TFT的上視圖i以顯 以形成一凹陷閘極及TFT裝置區域; ’ 罩圖樣 圖6是根據本發明圖4 TFT的剖面圖,s 在閘極層/基底上; .·、、員不薄絕緣層沈積 顯示杯率材料的磊 上; 顯示杯率材料的磊 上,使用化學機械503581 V. Description of the invention (5) " ~ '~ ................... Figure 3 is a TFT according to the present invention Figure 2 4 is a cross-sectional view of a gate layer of a dual-type TFT according to the present invention, and a structured substrate and a display pattern are formed to form respective recessed closed electrodes. FIG. 5 is a top view of the dual-type TFT according to the present invention. i to form a recessed gate and TFT device region; 'mask pattern Figure 6 is a cross-sectional view of the TFT according to Figure 4 of the present invention, s on the gate layer / substrate; Leakage of cup rate material; Leakage of cup rate material, using chemical machinery

顯不沈積在杯率表 圖7是根據本發明圖6 TFT的剖面圖, 曰曰正,以形成一傳導通道薄板在絕緣層 圖8疋根據本發明圖4 τ F T的剖面圖, 晶正,以形成一傳導通道薄板在絕緣層 研磨法以使絕緣層極化; 圖9是根據本發明圖7 TFT的剖面圖 面的電極以形成源極及汲極; 圖10是根據本發明圖8 TFT6〇剖面_,顯示形成在平坦 杯率表面的電極以形成源極及汲極; 圖11是根據本發明圖9 TFT的剖面圖,顯示電極上的薄 絕緣層及傳導層,以形成上閘極作為TFT裝置的第四端;Apparently deposited on the cup rate table. Figure 7 is a cross-sectional view of the TFT according to Figure 6 of the present invention, which is called positive to form a conductive channel sheet in the insulating layer. Figure 8 疋 Cross-sectional view of Figure 4 τ FT according to the present invention. In order to form a conductive channel sheet, the insulating layer is polished to polarize the insulating layer. FIG. 9 is a cross-sectional view of the electrode of the TFT according to the present invention to form a source and a drain according to the present invention. FIG. 10 is a TFT 6 according to the present invention. 〇 cross section_, showing electrodes formed on a flat cup surface to form a source and a drain; FIG. 11 is a cross-sectional view of the TFT according to FIG. 9 of the present invention, showing a thin insulating layer and a conductive layer on the electrode to form an upper gate electrode As the fourth end of the TFT device;

圖12是根據本發明圖丨〇 TFT的剖面圖,顯示電極上的薄 絕緣層及傳a導層以形成上閑極作aTFT裝置的第四端; 圖13a-c是根據本發明模特絕緣材料的能量帶 圖的例子,以說明區域晶隙狀態的存在; 圖14疋根據本發明特徵的結構的能量帶圖的示意 例’以說明η通道以正電壓施加在閘極·,12 is a cross-sectional view of a TFT according to the present invention, showing a thin insulating layer on the electrode and a conductive layer to form the upper end of the aTFT device as a fourth end; FIGS. 13a-c are insulating materials for models according to the present invention An example of an energy band diagram to illustrate the existence of the state of the intergranular gap; Figure 14 疋 A schematic example of an energy band diagram of a structure according to the features of the present invention 'to illustrate that the n channel is applied to the gate with a positive voltage,

五、發明說明(6) 圖1 5是根據本發明的一 的示意例,以說明卩通 特徵的mt結構的能量帶劇 以 圖16是根據本發明特科/電壓施加在間極; 說明n通道以正電壓施加4 結構的電荷分布例, 圖17是根據本發明另—# 例,以說明p通道以負t ’徵的M+M t結構的電荷分♦ 形成的線性f :二 中雙類型TFT的剖面圖,以顯示 訂y珉的綠f生區域(低沒極區域); 圖1 9是根據本發明操作中雔 一V. Description of the invention (6) FIG. 15 is a schematic example according to the first of the present invention, to illustrate the energy band performance of the mt structure with a through feature. FIG. 16 is a special section / voltage applied to the pole according to the present invention; An example of the charge distribution of a channel with a positive voltage applied to a 4 structure, FIG. 17 is another example of ## according to the present invention to illustrate the charge distribution of the p channel with a negative t 'sign of the M + M t structure. A cross-sectional view of a type TFT to show the green region (low dead zone); Figure 19 is a first view of the operation in accordance with the present invention.

(I 形成的飽和區域; *類1TFT的剖面圖,以顯不 =20疋本發明根據m〇材料的雙類型的裝置結構的 剖®圃, 圖21是根據本發明雙類型TFT的汲極電流與汲極電壓的 實驗數,圖,其中閘極電壓32)在_2()至〇伏之間變化; 圖22是根據本發明單一裝置的雙類型傳導的汲極電流與 閘極電壓的實驗數據圖; 圖23是根據本發明在p通道模式中的^丁,在數個不同閘 極電壓下汲極電流與汲極電壓的實驗數據圖; 圖24是根據本發明在^通道模式中的TFT,在數個不同閘 極電壓下汲極電流與汲極電壓的實驗數據圖; 圖25的圖形顯示根據本發明雙類型TFT的高on/〇f f電流 比; 圖26是根據本發明雙類sTFT在數個不同閘極電壓下汲 極電流與汲極電壓的實驗數據圖,以顯示p通道模式的電(Saturation region formed by I; * Cross-section view of class 1 TFT to show == 20 疋 Cross-section of a dual-type device structure according to the invention according to m0 material; FIG. 21 is a sink current of a dual-type TFT according to the present invention The number of experiments with the drain voltage, the graph, in which the gate voltage 32) varies between _2 () and 0 volts; FIG. 22 is an experiment of the dual-type conducted drain current and gate voltage according to a single device of the present invention Data diagram; FIG. 23 is an experimental data diagram of the drain current and the drain voltage under a plurality of different gate voltages in the p-channel mode according to the present invention; FIG. 24 is a graph in the ^ -channel mode according to the present invention TFT, experimental data graphs of drain current and drain voltage under several different gate voltages; FIG. 25 is a graph showing a high on / 0ff current ratio of a dual-type TFT according to the present invention; FIG. 26 is a dual-type TFT according to the present invention Experimental data graphs of sTFT's drain current and drain voltage under several different gate voltages to show

第10頁 503581 五、發明說明(7) 流與電壓特徵; 圖27是習用全波二極體橋式整流電路的示竟圖; 圖28a是輸入電壓與時間(表示輸入信號)的圖形; 圖28b是圖27電路中輸出電壓與時間的圖形·, 圖29是根據本發明雙類型TFT整流電路的示意圖; 圖30是圖29電路中輸出電壓與時間的圖形; 圖31是根據本發明另一傳導TFT整流電路的示意圖; 圖32是圖31電路中輸出電壓與時間的圖形;及 圖33是根據本發明雙類型TFT驅動的有機LE〇示意圖。 這些附圖只是說明本發明,不必因此而限制後附申請專 利範圍。 盤佳實施例之詳細說明 本發明有關於微電子裝置,且尤其是有關於薄膜電晶 (TF;f據本發而揭不一種雙(n/P)類型薄膜場效電晶體 U 知類型裝置的通道材料最好包括模特絕 緣材料如YBa2CU3O7_δ-(YBCO),其中(5在約0盥1之間,齡 =的在0與0.5之間’本發明也使用其他化合物,這此化人 物,括:U2-xSrxCu〇4,x在_ 之間,Nd2xCexCu〇4J ^與1之間,而X在0與1之間,Bi2Sr2CanCUn+i〇㈣,Page 10 503581 V. Description of the invention (7) Current and voltage characteristics; Figure 27 is a diagram of a conventional full-wave diode bridge rectifier circuit; Figure 28a is a graph of input voltage and time (representing the input signal); 28b is a graph of output voltage and time in the circuit of FIG. 27, FIG. 29 is a schematic diagram of a dual type TFT rectifier circuit according to the present invention, FIG. 30 is a graph of output voltage and time in the circuit of FIG. 29, and FIG. 31 is another graph according to the present invention A schematic diagram of a conductive TFT rectifier circuit; FIG. 32 is a graph of output voltage and time in the circuit of FIG. 31; and FIG. 33 is a schematic diagram of an organic LE driven by a dual type TFT according to the present invention. These drawings are only illustrative of the present invention and do not necessarily limit the scope of the attached patents. Detailed description of Panjia embodiment The present invention relates to microelectronic devices, and more particularly to thin film transistors (TF; f) According to the present disclosure, a dual (n / P) type thin film field effect transistor U-type device is known. The channel material preferably includes a model insulation material such as YBa2CU3O7_δ- (YBCO), where (5 is between about 0 and 1 and age = between 0 and 0.5 '. The present invention also uses other compounds, including these characters, including : U2-xSrxCu〇4, x is between _, Nd2xCexCu〇4J ^ and 1, and X is between 0 and 1, Bi2Sr2CanCUn + i〇㈣,

HsBa2CanCun+10 2nr4 ’ Tl2Ba2CanCun+106t2n, (SlVxCax)3Ru2 07 ’其中x 在〇 與1 之間,及(Sr/Ca) R 。本發明包括新的裝置結構及製程步驟,為二Un 3, Sr 而使用數個後沈積熱或雷射回火步驟以改變氧含^,最佳 極電壓的極性而決定是否在相同單一裝置中達二里型二】HsBa2CanCun + 10 2nr4 ′ Tl2Ba2CanCun + 106t2n, (SlVxCax) 3Ru2 07 ′ where x is between 0 and 1, and (Sr / Ca) R. The invention includes a new device structure and process steps. For the two Un 3, Sr, several post-deposition heat or laser tempering steps are used to change the oxygen content, and the polarity of the optimal pole voltage to determine whether it is in the same single device. Da Erli

503581503581

有多項類比/數位或數位/數位 整流器’邏輯閘,多正記憶格 裝置最好是TFT裝置,雖然本 本發明的電晶體是指雙類型 傳導通道。此新類型裝置具 電路應用,如單一裝置全波 及顯示驅動裝置。該新類型 發明也可包括電晶體結構, TFT,雙類型MTFT 或MTFET。 現在參考附圖,其中相同數字表示相同或類似元件,首 先參考圖1,其中顯不一習用模特轉移場效電晶體aTFET) 2,關於 MTFET 可參考 D.M· Newns 等人的”Mott transiti〇n field effect transistor\ Applied Physics Letters,There are multiple analog / digital or digital / digital rectifier 'logic gates, and the multi-positive memory cell device is preferably a TFT device, although the transistor of the present invention refers to a dual type conduction channel. This new type of device has circuit applications such as a single device full wave and a display drive device. This new type of invention can also include a transistor structure, TFT, dual type MTFT or MTFET. Referring now to the drawings, in which the same numerals represent the same or similar elements, first refer to FIG. 1, which shows a conventional model transfer field-effect transistor (aTFET) 2. For MTFETs, refer to "Mott transitioon field" by DM · Newns et al. effect transistor \ Applied Physics Letters,

Vol· 73· No· 6, pp· 780-782, Aug· 1998 °MTFET 是- 種FET型裝置,其中通道丨8是由一種能執行模特金屬絕緣 體轉移的材料(也稱為模特絕緣體),這種通道材料的傳輸 基本上會發生電性遷移,以及當閘極電壓改變時載子數會 改變。在通道材料的絕緣狀態中,電性遷移及載子濃度較 低’在通道材料的金屬狀態中,電性遷移及載子濃度較 高’因而使通道導通。圖1顯示習用的p型⑽”丁裝置,形 成結構中基底的閘極(G)l〇是由傳導n型SrTi03(ST0)含有 1%重量銳(Nb)的(1 〇〇)方向晶體組成。純ST0的40 0nm絕緣 層12蠢晶沈積在閘極丨〇的—_^〇上,又一磊晶正14是由 υ〇·5Ργ0 5Ba2Cu3〇7 ^ybco)組成,其中 5 在約〇 與0· 5 之間, 該蠢晶正14沈積在絕緣層12表面上,磊晶正14形成MTFET 的模特絕緣傳導通道18,接著鉑(pt)電極16,20使用雕空 光罩而沈積在杯率表面,形成源極(S)20及汲極(D)。最 後,由雷射絕緣凹渠22完成該裝置。通道長度24是5微Vol · 73 · No · 6, pp · 780-782, Aug · 1998 ° MTFET is a FET-type device, in which channel 丨 8 is made of a material that can perform the transfer of a model metal insulator (also called a model insulator), which The transfer of this channel material basically occurs electrical migration, and the number of carriers changes when the gate voltage changes. In the insulating state of the channel material, the electrical migration and the carrier concentration are relatively low ', and in the metallic state of the channel material, the electrical migration and the carrier concentration are relatively high', thereby conducting the channel. FIG. 1 shows a conventional p-type silicon device. The gate (G) 10 forming the substrate in the structure is composed of a conductive (n-type) SrTi03 (ST0) crystal containing 1% by weight (Nb) (100) direction crystals. Pure 40 nm nm insulating layer 12 stupid crystals are deposited on the gate electrode __, and another epitaxial positive electrode 14 is composed of υ〇 · 5Ργ0 5Ba2Cu3〇7 ^ ybco), where 5 is about 〇 and Between 0.5, the stupid crystal 14 is deposited on the surface of the insulating layer 12, and the epitaxial crystal 14 forms the MTFET's model insulation conduction channel 18, and then the platinum (pt) electrodes 16, 20 are deposited on the cup using a hollow mask. Rate surface, forming the source (S) 20 and the drain (D). Finally, the device is completed by a laser insulated trench 22. The channel length 24 is 5 micrometers

503581503581

’經由習用電晶體的閘極 操作。這種裝置2的通道 閘極動作時即形成單一通 米,這種裝置是p型或P通道较置 場感應的模特金屬絕緣體轉移而 包括與CMOS操作類似的操作各 道(P通道)。 YBa2CM7.5,其中。'在 ^緣^=^Cu3〇7(YBCO)或 結構,優點是單—裝置可二之二):=mtfET裝置及 之,它能形成η通道❹通Ϊ供ί f(n/p)操作,換言 砵新H通道,由閘極場的電極控制。'Operate via the gate of a conventional transistor. The channel of this device 2 forms a single channel when the gate is actuated. This device is a p-type or p-channel that is transferred to a field-inductive model metal insulator and includes operating channels (P-channel) similar to CMOS operation. YBa2CM7.5, among them. 'At 缘 缘 ^ = ^ Cu3〇7 (YBCO) or structure, the advantage is that the single-device can be two or two): = mtfET device and it can form η channel, which can be used for f (n / p) operation In other words, the new H channel is controlled by the electrodes of the gate field.

體Ατ)、,通道鉍可配置成三端或四端薄膜場效電晶 緣材料,、言此U ”料是根據杯率材料,陪洛或類似模特絕 Ν 二料包括· La2-xSrxCu04,X 在〇 與!之間,Body Ατ), channel bismuth can be configured as a three-terminal or four-terminal thin film field-effect crystal edge material, said U ”material is based on cup rate materials, Perot or similar models must include two materials La2-xSrxCu04, X is between 〇 and!,

Nd2~xCexCu〇4i' ’ 5在〇與1之間而X在〇與1之間,Nd2 ~ xCexCu〇4i '′ 5 is between 0 and 1 and X is between 0 and 1.

Bi2Sr CaCun 〇6,n ^HgBa2CanCun+102η+4 Ί l2Ba2CanCunH 06f2n ^ w卜xiax)3Ku207,其中x在之間,及/或 \SF/Ca)nTlRUn〇3_Sr*。也可使用這些材料的合併,以下附圖 將說明本發明的裝置結構及其製造方法,裝置操作原理及 應用。 參考圖2,其顯示高性能MTFET TFT(MTFT)結構或雙類型 MTFT ’裝置的結構特徵及其製造在其成功操作上佔有重要 地位’為了得到最佳MTFT性能,最好磊晶的成長一通道 f 108 ’包括一基底1〇2,基底1〇2最好是金屬基底及使用鈮 摻雜的SrTi03(ST0)含有1 · 5%重量的鈮(Nb),也可用其他 摻雜劑(如Mn,Pb,Fe,Ti等)來摻雜基底1〇2,基底102可以 一 用镱(Y)穩定錘(Zr)(YSZ),鋁化鑭,二氧化鈦,鎵化鈥來Bi2Sr CaCun 〇6, n ^ HgBa2CanCun + 102η + 4 Ί l2Ba2CanCunH 06f2n ^ xiax) 3Ku207, where x is between, and / or \ SF / Ca) nTlRUn〇3_Sr *. A combination of these materials can also be used. The following drawings will illustrate the device structure and its manufacturing method, device operation principle and application of the present invention. Referring to Figure 2, it shows a high-performance MTFET TFT (MTFT) structure or a dual-type MTFT. "The structural characteristics of the device and its manufacturing play an important role in its successful operation." In order to obtain the best MTFT performance, it is best to grow one channel of epitaxy. f 108 'includes a substrate 102, which is preferably a metal substrate and niobium-doped SrTi03 (ST0) containing 1.5% by weight of niobium (Nb). Other dopants such as Mn may also be used. , Pb, Fe, Ti, etc.) to dope the substrate 102, the substrate 102 can be doped with ytterbium (Y) stabilized hammer (Zr) (YSZ), lanthanum alumina, titanium dioxide, gallium.

第13頁 川3581Page 13 Chuan 3581

五、發明說明no) 製造,這些基底材料也可以摻雜以改良性能,基底1 0 2也 可作為閘極及包括凹陷閉極1 〇 1以具有高性能傳導通道 1 08,詳如以下所述,凹陷開極丨〇 1提供本發明的改良性 能。 一高介電穩定的閘絕緣體1 0 5最好磊晶成長在基底1 0 2 上,閘絕緣體1 0 5最好包括STO,雖然也可使用與基底1 〇 2 相容的其他絕緣體。沈積通道材料1 20如YBC0,最好在氧 氣下以雷射消除理想配比目標以沈積閘絕緣體1 〇 5及通道 材料1 2 G,沈積源極1 〇 4及汲極1 〇 6,源極1 〇 4及汲極1 〇 6最 好包括鉑(P t ),及經由矽雕空光罩用電子束蒸發法來沈 積。用雷射消除凹渠1 1 2可以使晶片或裝置1 〇 〇上的各裝置 或是裝置100互相隔離。 參考圖3,其顯示根據本發明的另一 MTFT裝置的上視 圖’裝置1 0 0包括以下尺寸,這些尺寸只是說明性,不應 視為一種限制。通道長度11 7(L)包括約5微米的長度,及 約90微米的寬度11 1,裝置1〇〇的凹陷閘極丨〇1接到整體字 線109,源極l〇4a及汲極106a的寬度約為50微米,間絕緣 體105的厚度約為200-300nm而通道厚度(深入頁)約為 5Onm 〇 以下是三端或四端YBaJi^O7 (YBC0或模特絕緣材料)薄膜 場效電晶體(TFT)的各別及整合的詳細製程步驟。 、 參考圖4,TFT製程的第一步驟是使用結構的基底1〇2以 形成裝置的閘極,將基底1 〇 2定圖樣以形成各別凹陷間極 101,結構的基底102最好用Nb-STO(IOO)切除晶體製造以V. Description of the invention no) Manufacturing, these base materials can also be doped for improved performance. The base 102 can also be used as a gate electrode and include a recessed closed electrode 1001 to have a high-performance conductive channel 108, as described in detail below. The recessed open electrode provides improved performance of the present invention. A highly dielectrically stable gate insulator 105 is preferably epitaxially grown on the substrate 102, and the gate insulator 105 preferably includes STO, although other insulators compatible with the substrate 102 may be used. Deposition of channel material 1 20 such as YBC0, it is best to use laser to eliminate the ideal ratio target under oxygen to deposit gate insulator 1 05 and channel material 1 2 G, deposition source 1 104 and drain 1 06, source The 104 and the drain 106 are preferably composed of platinum (P t), and are deposited by an electron beam evaporation method through a silicon mask. Using laser to eliminate the dimples 1 12 can isolate each device on the chip or the device 100 or the device 100 from each other. Reference is made to Fig. 3, which shows a top view of another MTFT device according to the present invention. The device 100 includes the following dimensions, these dimensions are only illustrative and should not be considered as a limitation. The channel length 11 7 (L) includes a length of about 5 micrometers and a width of about 90 micrometers 11. The recessed gate of the device 100 is connected to the overall word line 109, the source 104a, and the drain 106a. The width is about 50 microns, the thickness of the inter-insulator 105 is about 200-300nm and the channel thickness (in-depth page) is about 5nm. The following is a three-terminal or four-terminal YBaJi ^ O7 (YBC0 or model insulation material) thin film field effect transistor (TFT) detailed and integrated process steps. 4. Referring to FIG. 4, the first step of the TFT process is to use a structured substrate 102 to form the gate of the device, and pattern the substrate 102 to form the respective recessed interstitial electrodes 101. The structured substrate 102 is preferably made of Nb. -STO (IOO) excision crystal

五、發明說明(Η) 作為閘極。最好以適當 極定圓樣以形成凹陷二t 光學或電·子束微影術將開 光罩圖樣在MTFT裝置區…H參考圖5的上視圖’其顯示 凹陷問極丨(Π的例子。域(具有寬度in及長度117)中形成 參考圖6,沈積薄的絕 的Nb-STO表面上的ST(3,^層I05,層105最好包括基底102 積層105,或者,用抑用好使用脈衝雷射消除製程以沈 表面平坦以提供平的自表而的,學機械研磨(CMP)法使層1 的2個結構,這些實施例卜圖7 ’8表示本發明 示,這些數字包括一字舟 5_或類似元件用相同數字表 參考圖7,沈積杯率材H表/不同的實施例。 層l〇5a上形成傳導通道拉的站晶層102a(如YBC0)以便在 長出的層1 02a最好含有高:f7 了得到良好裝置性能,成 缺陷。處理參數包括低雷射:::以確保膜中極小的格子 在製程期間提供氧氣環产射'尤積率(如2Hz的雷射脈衝), 基底102可維持在二心到匕約3—加的氧氣分壓。 阻通道而使用數個後回火牛驟5〇c。為了製造本質高電 佳方法中,後回火包括維^以使場效回應最佳化。在較 長達約0. 2小時及約5小時持=f在約20〇。〇至約5〇〇 °C之間 或其他惰性氣體或是直Λ。在減少大氣環境中,如氬 電阻以監控製程及破佯;晉^製程期間可測量裝置通道的 間最好執行氧回火以調ί = 錢回火之後或是期 參考圖8的另—實施二傳/通道層的氧含量。 層12心沈積而在平〇5b、(=杯率材料(如ECO)的蟲晶 -曰5b(如上所述用化學機械研磨法5. Description of the invention (i) As the gate. It is better to form a concave circle with appropriate polar patterns. Optical or electrical beam beam lithography is used to open the mask pattern in the MTFT device area ... H Refer to the upper view of FIG. 5 ', which shows an example of the concave electrode Π (Π). In the field (with a width of in and a length of 117), referring to FIG. 6, the ST (3, ^ layer I05, layer 105 on the surface of the thin, absolutely insulated Nb-STO is deposited, and the layer 105 preferably includes the substrate 102 and the layer 105. The pulsed laser elimination process is used to flatten the surface to provide a flat, self-explanatory, mechanical polishing (CMP) method to make the two structures of layer 1. These examples are illustrated in Figures 7'8 and 7. I-boat 5_ or similar components refer to Figure 7 with the same number table, deposition cup rate table H / different embodiment. A layer 102a (such as YBC0) of conductive channel pull is formed on layer 105a to grow in The layer 1 02a should preferably contain high: f7 to obtain good device performance and become defective. Processing parameters include low laser ::: to ensure that the very small grid in the film provides an oxygen ring emission during the process (such as 2Hz) Laser pulses), the substrate 102 can be maintained at about 3 to the added oxygen partial pressure 2Hours and approx. 2 hours and approx. 2 hours and approx. 5 hours hold = f between about 20.0 to about 500 ° C or other inert gas or straight Λ. In reducing the atmospheric environment, such as argon resistance to monitor the process and break down; during the Jin process It is best to perform oxygen tempering between the channels of the measuring device to adjust the oxygen content after the tempering or referring to Figure 8 for another pass-through / channel layer. The layer 12 is deposited and the flat layer is in the flat 05b, (= Worm crystals of cup material (such as ECO)-5b (as described above by chemical mechanical grinding

503581 五、發明說明(12) 形成)上傳導通道層,層1 2 〇 b最好用雷射消除室中的原地 目標變化而沈積在已平坦層l〇5b的(100)表面上,層 120b(120a)形成TFT的MOS絕緣體雙類型傳導通道。 參考圖9,沈積電極i〇4a,106a作為層120a上的傳導材 料(如鉑)正。使用雕空光罩以形成源極l〇4a,l〇6a。 參考圖10,使用雕空光罩以便在層120b的平坦表面上形 成(最好是鉑)的源極1 〇 4 b,1 0 6 b。用圖樣製程而形成源極 1 〇4b及汲極1 〇6b。 藉由形成雷射隔離凹渠112a,112b(圖9,10)即可完成503581 V. Description of the invention (12) Formation) On the conductive channel layer, the layer 12b is preferably deposited on the (100) surface of the flat layer 105b with the in-situ target change in the laser elimination chamber. 120b (120a) forms a MOS insulator dual type conduction channel of the TFT. Referring to Fig. 9, the electrodes 104a, 106a are deposited as a conductive material (such as platinum) on the layer 120a. A carved mask is used to form the source electrodes 104a, 106a. Referring to Fig. 10, an engraved photomask is used to form (preferably platinum) source electrodes 10b, 10b on the flat surface of layer 120b. The pattern process is used to form source 104b and drain 106b. This can be done by forming laser-isolated dimples 112a, 112b (Figures 9, 10).

雙類型TFT裝置結構,最後的各別三端TFT裝置結構也在圖 2顯示。 為了強化傳導通道載子濃度及控制門檻(導通)電壓,可 以將另外的頂閘極130c及130d加入(圖11或圖12)以完成四 端TFT裝置。這些步驟包括沈積絕緣材料的另一層丨18c及 118d,接著沈積一金屬層130c及130(1以及將其定圖樣以形 成另一閘極。圖11說明TFT製程以沈積另一薄絕緣材料層 180c(如STO)在電極(104C,106C)上,方法是最好沈積 Nb-STO傳導層130c以形成頂閘極,作為TFT裝置的第四The structure of the dual-type TFT device and the final structure of the respective three-terminal TFT device are also shown in FIG. 2. In order to strengthen the carrier concentration of the conduction channel and control the threshold (on) voltage, additional top gates 130c and 130d can be added (Figure 11 or 12) to complete the four-terminal TFT device. These steps include depositing another layer of insulating material 18c and 118d, and then depositing a metal layer 130c and 130 (1 and patterning it to form another gate. Figure 11 illustrates the TFT process to deposit another thin layer of insulating material 180c (Such as STO) on the electrodes (104C, 106C), the method is best to deposit the Nb-STO conductive layer 130c to form a top gate, as the fourth TFT device

圖12說明TFT製程中的另一步驟,以沈積另一薄絕緣材 料層180d在平電極(104d,106d)上,其最好是由鉑形成, 且接著沈積一傳導層,最好是Nb-ST0,以形成頂閘極 130d,作為TFT裝置的第四端。 裝置操作原理FIG. 12 illustrates another step in the TFT process to deposit another thin insulating material layer 180d on the flat electrodes (104d, 106d), which is preferably formed of platinum, and then deposits a conductive layer, preferably Nb- ST0 to form the top gate electrode 130d as the fourth terminal of the TFT device. Device operating principle

第16頁 刈3581 五、發明說明(13) 通道材料層120最好包括Ba2Cu3〇?(YBCO),YBCO薄膜材料 般不具有長範圍晶體次序,這些類材料也稱為模特絕緣 材料’參考圖1 3 a,這些類材料的能帶結構2 〇 1,2 〇 3與非 晶體能帶結構極類似。通常YBCO材料包括區域化狀態以便 ^電荷集中狀態引入能帶間隙(參考圖丨3b)。本文的這些 區域化間隙狀態(包括似受子狀態2丨3及似施子狀態2丨5 )在 材料中是均勻分布的(參考圖13c的曲線2〇6),未摻雜材料 中的費米級EF(圖13a的數字235 ) —般在中間隙2〇7附近。 圖1 3a-c說明場效金屬絕緣體模特絕緣材料結構(也可參考 圖16 ’17,其中Nb - STO 270是金屬,STO280是絕緣體而 YBC0290是模特絕緣體)或^^卜以電容器的能帶圖,其中模 特絕緣材料是具有區域密度Nt(圖13c的2〇8)的薄正了 、 一為了簡化而假設在〇閘極偏壓(、=Q )下都是平帶情況, 當區域密度較高時,當費米級235在中間隙2〇7之中時,即 可在模特絕緣材料中得到電荷中性。 ”,考圖1 4的Μ - I - M t結構的能帶圖例子,圖中說明施加正 電$到閘極時形成的n通道,小正閘極電壓的施加開始使 能帶向下彎曲,當能帶在STO正2 05表面向下彎曲時,中間 I^:2 0 7a之上的部分區域狀態即填充著電子。因為這些是似 文^狀態,所以這些狀態中的負電荷A 2〇8即使閘極的正 電荷平衡,至少在小閘極電壓下,傳導帶(Ec)不會與費米 級很接近。結果,傳導帶中的電子很少,在圖丨4中,以& 2 08表示負電荷,在大閘極電壓下(Vg>〇)235a(圖14),費 米級2 0 7a與傳導帶2〇ia接近,而大量電子t 204即形成在Page 16 刈 3581 V. Description of the invention (13) The channel material layer 120 preferably includes Ba2Cu3? (YBCO). YBCO thin film materials do not have a long-range crystal order. These types of materials are also called model insulation materials. Refer to Figure 1 3a. The band structure of these materials is very similar to the amorphous band structure. Generally, YBCO materials include a regionalized state so that the charge concentration state is introduced into the band gap (refer to Figure 3b). These regionalized gap states (including acceptor-like states 2 丨 3 and donor-like states 2 丨 5) in this paper are uniformly distributed in the material (refer to curve 20 of Figure 13c), and the cost in the undoped material Meter-level EF (number 235 in Fig. 13a) is generally around the middle gap 207. Figure 1 3a-c illustrates the structure of the field effect metal insulator model insulation material (also refer to Figure 16 '17, where Nb-STO 270 is a metal, STO280 is an insulator and YBC0290 is a model insulator) or a band diagram of a capacitor Where the model insulation material is thin and has a regional density Nt (208 in Fig. 13c). For the sake of simplicity, it is assumed that the flat band is the case at 0 gate bias (, = Q). When the regional density is relatively When it is high, when the Fermi level 235 is in the middle gap 207, the charge neutrality can be obtained in the model insulation material. "Consider the example of the band diagram of the M-I-M t structure in Fig. 14. The figure illustrates the n-channel formed when a positive voltage $ is applied to the gate. The application of a small positive gate voltage starts to bend the energy band downward. When the energy band is bent downward on the positive surface of STO 2 05, the state of a part of the region above the middle I ^: 2 0 7a is filled with electrons. Because these are text-like states, the negative charge A 2 in these states 〇8 Even if the positive charge of the gate is balanced, at least at the small gate voltage, the conduction band (Ec) will not be very close to the Fermi level. As a result, there are very few electrons in the conduction band. 2 08 indicates negative charge. Under the large gate voltage (Vg > 0) 235a (Figure 14), the Fermi level 207a is close to the conduction band 20ia, and a large number of electrons t 204 are formed at

surface

第17頁 503581 五、發明說明(14) 傳導帶2 Ola之中。因此形成η型傳導通道,傳導通道會在 電子積聚層中動作,正閘極電壓會吸引半導體中的負電 荷’以η型半導體為例,會在接近氧化YBC0介面處包括增 強的電子濃度(積聚)。 參考圖1 5的Μ - I - M t結構的能帶圖例子,圖中說明施加負 電壓到閘極時形成的p通道,小負閘極電壓的施加開始使 能帶向上彎曲,能帶2〇lb,203b在正205b表面向上彎曲, 結果,中間隙下面的部分區域狀態即填充著電洞。因為這 些是似施子狀態,所以這些狀態中的正電荷即使閘極的負 電荷平衡,至少在小閘極電壓下,傳導帶(Ev)不會與費米 級很接近。結果,原子值帶中的電洞很少,在圖1 5中,以 Qt 2 09表示正電荷,在大閘極電壓下(Vg<〇)23 5b(圖15), 費米級207b與原子值帶2〇3b接近,而大量電洞Qp 20 5即形 成在原子值帶20 3b之中。因此形成p型傳導通道,傳導通 道會在電洞積聚層中動作,負閘極電壓會吸引傳導通道中 的正電荷,以p型半導體為例,會在接近氧化YBC〇介面處 包括增強的電洞濃度(積聚)。 參考圖16 ’其中顯示μ-I-Mt中電荷分布的例子(包括 Nb STO 270,STO 280及YBC0 29 0),以說明以正電壓施加 到閘極時n通道的形成,以裝置的電荷中性為例,它要求 Qg Qn + Qt ’其中Qg 2 3 1表示閘極上每單位區域的正電 壓,Qn 20 4η表示傳導帶中的傳導電子,而a 2〇8n表示中 間隙之上的區域電荷狀態其中填充有電子。在一電子積聚 情況下的電荷分布與能帶圖有關(參考圖14)。 503581 五、發明說明(15) 參考圖17,其中顯示- Mt (270 - 280 - 290)結構中電荷 分布的例子,以說明以負電壓施加到閘極時p通道的形 成。類似的以裝置的電荷中性為例,它要求1 = Qp + Qt ,其中Qg 233表示閘極上每單位區域的負電壓,209p表 示原子值帶中的傳導電洞,而Qt 2〇8p表示中間隙下面的 區域電荷狀態其中填充有電洞。在一電洞積聚情況下的電 荷分布與能帶圖有關(參考圖1 5 )。Page 17 503581 V. Description of the invention (14) In the conduction band 2 Ola. Therefore, an n-type conduction channel is formed, and the conduction channel will act in the electron accumulation layer. The positive gate voltage will attract the negative charge in the semiconductor. Taking the n-type semiconductor as an example, it will include an enhanced electron concentration (accumulation) near the oxidized YBC0 interface. ). Referring to FIG. 15 for an example of an energy band diagram of the M-I-M t structure, the figure illustrates the p-channel formed when a negative voltage is applied to the gate. The application of a small negative gate voltage starts to bend the energy band upward, and the energy band 2 〇lb, 203b is bent upward on the surface of positive 205b. As a result, the state of a part of the area under the middle gap is filled with holes. Because these are donor-like states, the positive charge in these states, even if the negative charge of the gate is balanced, at least at a small gate voltage, the conduction band (Ev) will not be very close to the Fermi level. As a result, there are very few holes in the atomic value band. In FIG. 15, Qt 2 09 represents a positive charge. Under the large gate voltage (Vg < 〇) 23 5b (Fig. 15), the Fermi level 207b and the atom The value band 203b is close, and a large number of holes Qp 20 5 are formed in the atomic value band 20 3b. Therefore, a p-type conduction channel is formed, and the conduction channel will act in the hole accumulation layer. The negative gate voltage will attract the positive charge in the conduction channel. Taking a p-type semiconductor as an example, it will include enhanced electricity near the oxidized YBC0 interface Hole concentration (accumulation). Referring to FIG. 16 ', which shows an example of the charge distribution in μ-I-Mt (including Nb STO 270, STO 280, and YBC0 29 0) to illustrate the formation of n-channels when a positive voltage is applied to the gate, the charge in the device For example, it requires Qg Qn + Qt 'where Qg 2 3 1 represents the positive voltage per unit area on the gate, Qn 20 4η represents the conduction electrons in the conduction band, and a 2〇8n represents the area charge above the mid-gap. The state is filled with electrons. The charge distribution in the case of one electron accumulation is related to the energy band diagram (refer to FIG. 14). 503581 V. Description of the invention (15) Referring to FIG. 17, an example of the charge distribution in the -Mt (270-280-290) structure is shown to illustrate the formation of the p-channel when a negative voltage is applied to the gate. Similarly, taking the device's charge neutrality as an example, it requires 1 = Qp + Qt, where Qg 233 represents the negative voltage per unit area on the gate, 209p represents the conduction hole in the atomic band, and Qt 208p represents medium The state of charge in the area below the gap is filled with holes. The charge distribution in the case of a hole accumulation is related to the energy band diagram (refer to Figure 15).

參考圖18,其中顯示線性區域(低汲極區域)中的MTFT操 作’大的正電壓\ > Vt (Vt是門檻電壓)施加在閘極 (G) 10 2ί,而使電子在YBC0 12〇f表面積聚,若施加小汲 極電壓,則電流會從源極(S) 104f經由傳導通道1〇8f而流 到汲極(D ) 1 0 6 f,因此通道作為電阻,而汲極電流與汲極 電壓成正比,這是線性區域。 參考圖19,其中顯示飽和區域中的⑽”操作例子,當汲 極電壓增加時,汲極電壓最後會到達一點,即通道1〇仏在 沒極106h的深度會減為〇。這稱為載止點,在截止點以 外,汲極電流仍維持相同,這是飽和區域。 了:類型m的數學公式’雙類型fet的門檻電壓 士 πτ:,門檻電壓(Vt)與區域間隙狀態極為有關,Referring to FIG. 18, it is shown that the MTFT in the linear region (low drain region) operates' large positive voltage> Vt (Vt is the threshold voltage) is applied to the gate (G) 10 2ί, and the electrons are at YBC0 12. The f surface area is concentrated. If a small drain voltage is applied, the current will flow from the source (S) 104f to the drain (D) 1 0 6f through the conductive channel 108f. Therefore, the channel acts as a resistor, and the drain current and The drain voltage is directly proportional to the linear region. Referring to FIG. 19, an example of “⑽” operation in a saturated region is shown. When the drain voltage increases, the drain voltage will finally reach a point, that is, the depth of channel 10 仏 at 106h will be reduced to 0. This is called loading. The dead point, beyond the cut-off point, the drain current remains the same, which is the saturation region.: The mathematical formula of type m 'threshold voltage of double type fet πτ :, the threshold voltage (Vt) is extremely related to the region gap state,

而且”矽FET裝置完全不同,惟,汲極電流與汲極電壓 (ι-ν)的關係仍然與方形律近似中碎fet得到的公式相同。 503581 五、發明說明(16) 表1 :雙類型TFT的重要公式 門檻電壓(ν〇 η型 vg>0, Vt>0, Vd>0 VpqN^frEpJts/Q^ Qr〒Qt時 P型 Vg<0, vt<0, vd<0 |Or=Q 時 ―_- Ι-V線性區域 Qn=Qg-Qt Id=C〇x(W/L) β neff [(V^Vd-Vo2^] Qp=Qg-Qt Id=C〇x(W/L) β pcff [IVrVJVD-VD2/2] 一 Ι-V飽_區域 Id=Cox(W/L) " ncff (V.-VO2 IId丨=C〇X(W/2L) " peff (V.-VO2 飽和馳 vD^=vrvt 參考圖20 ’其中顯示根據其他製造步驟的TFT式γβ⑶材 料的裝置結構,圖中的金屬基底1〇2e包括Nb摻雜ST〇,基 底102e也可作為閘極(G),閘極絕緣體ST〇 ^“接著在基 底1〇2e上蠢晶的成長。接著沈積通道材料YBCO 120e,源 及5極106e(Pt)接著經由雕空光罩而以電子束蒸發 圄:傳導通道1〇8e接著形成在YBC0材料10。的底面, 圖中顯不汲極電壓V ,0 此夂數W本- D閘極電壓、及汲極電流ID,使用這 二2以表不以下各圖的實驗結果。 參考圖21 ,置中顧千滇权 ^ ^ ^305 ^ t ^ ,; ,^303 «BCO „ 置’閘極電壓、是_2〇, _16, 3兒月”本發明形成的裝 參考圖22,1由廉-、,1 , 8,一4及0V。 型傳導時的另二實驗極電流323與閘極電壓325在雙類 的WVg特徵,部分32G包括^示雙類型爪的近似對稱 電流,於Vg等於〇伏時變換。電、洞電流而部分330包括電子Moreover, the "silicon FET" device is completely different, but the relationship between the drain current and the drain voltage (ι-ν) is still the same as the formula obtained from the broken fet in the square law approximation. 503581 V. Description of the invention (16) Table 1: Double type Important formula threshold voltage of TFT (ν〇η-type vg > 0, Vt > 0, Vd > 0 VpqN ^ frEpJts / Q ^ Qr〒Qt P-type Vg < 0, vt < 0, vd < 0 | Or = Q ―_- Ι-V linear region Qn = Qg-Qt Id = C〇x (W / L) β neff [(V ^ Vd-Vo2 ^] Qp = Qg-Qt Id = C〇x (W / L) β pcff [IVrVJVD-VD2 / 2] I-V saturated_area Id = Cox (W / L) " ncff (V.-VO2 IId 丨 = C〇X (W / 2L) " peff (V.-VO2 Saturation vD ^ = vrvt Refer to FIG. 20 'It shows the device structure of the TFT-type γβ⑶ material according to other manufacturing steps. The metal substrate 102e in the figure includes Nb-doped ST0, and the substrate 102e can also serve as the gate (G). The gate insulator ST〇 ^ "followed by the growth of stupid crystals on the substrate 102e. Then the channel material YBCO 120e, the source and the 5-pole 106e (Pt) were deposited by an electron beam through an engraved photomask: conduction channel 108e is then formed on the bottom surface of YBC0 material 10. The figure shows no drain voltage V, 0 For the number of W-D gate voltage and drain current ID, use these two to show the experimental results in the following figures. Referring to Figure 21, center Gu Qiandianquan ^ ^ ^ 305 ^ t ^,;, ^ 303 «BCO„ Setting the gate voltage, it is _2〇, _16, 3 months "The device formed by the present invention is referred to FIG. 22, 1 by Lian- ,, 1, 8, 4 and 0V. In the other two experiments, the pole current 323 and the gate voltage 325 have dual WVg characteristics. Part 32G includes the approximately symmetrical currents of the two types of claws, which are transformed when Vg is equal to 0 volts. The electric and hole currents and the part 330 include electrons.

苐20頁 503581 五、發明說明(π) 參考圖23,其中是根據本發明而顯示汲極電流353與汲 極電壓3 5 5在ρ通道的數個不同閘極電壓下的實驗圖形,結 果顯示雙類型TFT I-V特徵。 參考圖24,其中顯示汲極電流373與汲極電壓375在η通 道雙類型TFT的數個不同閘極電壓下的實驗圖形。 圖26顯示雙類型TFT的高〇n/off電流比的另一實驗圖 形’圖中顯示汲極電流4 1 3與閘極電壓4 1 1 (從-1 〇 V到2 0 V ) 的關係,圖27顯示p通道TFT電流電壓特徵的另一實驗圖 形,其中顯示汲極電流5 13與含有YBC0通道材料的汲極電 壓515圖形,閘極電壓Vg是一 25,_20,_15, —1〇,—5及〇 V。 應用 熟於此技術者可瞭解提供雙類型(n/p)操作的單一裝置 會產生许多新的應用’其中的一例是應用在電源電路。 參考圖27, 28a及2 8b,其中顯示習用的全波二極體整流 電路600及電壓輸入輸出與時間(t)的關係圖形,圖中在圖 28a的輸入周期的正部分612期間,當變壓器6〇5的極性如 圖所示時,二極體D!及〇3即導通,而電流從負荷心的正端 >’il向負知。導通路徑如虛線迴路6Q7所示,在次一負半周 期613中,變壓器6 0 5使其極性相反,而二極體d2及^導° 通’而電流依照與先刖正半周期61 2相同的方向流入負荷 Rl ’輸出如圖28b所示。 ' 參考圖28a及29到32,根據本發明,用雙類型γρτ裝置 710替代4個二極體D1,D2,D3及D4(圖27),分別參考圖29及页 Page 20, 503581 V. Description of the invention (π) Refer to FIG. 23, which shows the experimental graphs of the drain current 353 and the drain voltage 3 5 5 under several different gate voltages of the ρ channel according to the present invention. The results show Features of dual type TFT IV. Referring to FIG. 24, an experimental pattern of a drain current 373 and a drain voltage 375 at several different gate voltages of an n-channel dual-type TFT is shown. FIG. 26 shows another experimental pattern of the high ON / OFF current ratio of the dual-type TFT. The relationship between the drain current 4 1 3 and the gate voltage 4 1 1 (from −10 volts to 20 volts) is shown in the figure. FIG. 27 shows another experimental pattern of p-channel TFT current and voltage characteristics, in which the drain current 5 13 and the drain voltage 515 graph including the YBC0 channel material are shown. The gate voltage Vg is 25, _20, _15, -10. —5 and 0V. Applications Those skilled in the art will understand that a single device providing dual-type (n / p) operation will create many new applications. One example is in power supply circuits. Referring to Figs. 27, 28a and 28b, which shows a conventional full-wave diode rectifier circuit 600 and the relationship between voltage input and output and time (t). In the figure, during the positive part 612 of the input cycle of Fig. 28a, when the transformer When the polarity of 6〇5 is shown in the figure, the diodes D0 and 03 are turned on, and the current is negatively known from the positive end of the load center> 'il. The conduction path is shown by the dotted line 6Q7. In the next negative half cycle 613, the transformer 605 has its polarity reversed, and the diode d2 and ^ are turned on, and the current is the same as the first positive half cycle 61 2 The direction of the inflow load Rl 'is shown in Figure 28b. '' Referring to FIGS. 28a and 29 to 32, according to the present invention, the four diodes D1, D2, D3, and D4 are replaced by a dual-type γρτ device 710 (FIG. 27), referring to FIGS. 29 and 29, respectively.

503581 五、發明說明(18) 3 1。在輸入周期的正部分6 1 2期間,當負閘極電壓施加在 T F T的閘極7 1 2時’即形成p通道,而電流從負荷的正流到 負(圖2 9的RL 7 1 5或圖3 1的KL 7 1 4 &CL 7 1 6 ),在輸入周期 的負部分6 1 3期間,正閉極電·壓施加在τ F T 7 1 0的閘極7 1 2 因而形成η通道,接著通過負荷1 715(或& 714及Q 716) 的電流方向與先前正半周期6 1 3期間的相同,如圖3 〇及3 2 所示。 參考圖33,其中顯示本發明的 雙類型MTFT 81 0 (最好包括YBC0) (LED) 820,從電壓供給器814調 到電壓供給8 1 6,光的輸出與LED YBCO TFT的整合對於未來智慧型 上述實施例只是範例,其中使 明僅限於此,熟於此技術者可瞭 實施例多而且廣,也是重要的是 夤及特徵的其他材料及尺寸來替 寸。本發明的優點是提供一種更 路的間單解決方法。 本發明的部分優點包括: ^裝置大小可改變,如設為10 換時間約為0.1皮秒;及 3.雙類型(n/p)特徵。 已說明雙_刑μ ^ , 頭型缚膜場效電晶體 僅為說明性而非 非限制性),注意 另一應用,根據本發明由 驅動有機發光二極體 節閘極電壓,LED 820接 電流成正比,有機LED與 顯示器有極大利益。 用本發明但不應視為本發 解本發明的應用遠比上述 注意,可以用具有類似性 代或是改變上述材料及尺 省空間,低功率及習用電 nm通道長及更大; 及應用的較佳實施例(其 1熟於此技術者可由上述503581 V. Description of the invention (18) 3 1. During the positive part 6 1 2 of the input cycle, when a negative gate voltage is applied to the gate 7 1 2 of the TFT, a p-channel is formed, and the current flows from the positive to negative of the load (RL 7 1 5 in Figure 2 9 Or KL 7 1 4 & CL 7 1 6) of FIG. 3), during the negative part 6 1 3 of the input cycle, the positive closed-electrode voltage is applied to the gate 7 1 2 of τ FT 7 1 0, thus forming η The current direction of the channel and then through the load 1 715 (or & 714 and Q 716) is the same as that of the previous positive half cycle 6 1 3, as shown in Figures 3 0 and 32. Referring to FIG. 33, there is shown a dual-type MTFT 81 0 (preferably including YBC0) (LED) 820 of the present invention, which is adjusted from a voltage supply 814 to a voltage supply 8 1 6. The integration of light output and LED YBCO TFT is for future wisdom The above-mentioned embodiments are merely examples, and the description is limited to this. Those skilled in the art can have many and extensive embodiments. It is also important that other materials and dimensions are used instead. The advantage of the present invention is to provide a more alternate solution. Some of the advantages of the present invention include: ^ The device size can be changed, for example, it is set to 10, and the change time is about 0.1 picoseconds; and 3. The dual type (n / p) feature. It has been described that the double-sided penalty μ ^, the head-shaped film field-effect transistor is merely illustrative and not limitative. Note another application. According to the present invention, the gate voltage of the organic light-emitting diode is driven by the LED 820. The current is proportional to the organic LED and the display is of great interest. The application of the present invention should not be regarded as the solution of the present invention. The application of the present invention is far more than the above-mentioned attention. It is possible to use similar materials to replace or change the above materials and feet to save space, low power and conventional electrical nm channel length and larger; and A preferred embodiment of the application (one skilled in the art can use the above

第22頁 503581 五、發明說明(19) 教示作各種改良及變化,因此要瞭解只要在後附申請專利 範圍所述的本發明範圍及精神之内,可以對揭示的本發明 特別實施例作改變。因此已詳細說明本發明且符合專利 法,而欲保護的申請專利範圍詳如以下: « ❿Page 22 503581 V. Description of the invention (19) The teachings are various improvements and changes, so it is necessary to understand that as long as the scope and spirit of the present invention described in the scope of the attached patent application can be changed, the disclosed special embodiments of the present invention can be changed. . Therefore, the present invention has been described in detail and is in compliance with patent law. The scope of patent applications to be protected is as follows: «❿

第23頁Page 23

Claims (1)

503581 _案號89109150_fV年7月丨〇日 修正 _ 六、申請專利範圍 1 . 一種場效電晶體裝置,包括: 一閘極層可接收一輸入電壓; 一絕緣層形成在閘極層上; 一傳導通道層形成在絕緣層上用以承載一源極與一汲 極間之電流;及 傳導通道層可提供一雙通道,雙通道包括一Ρ通道及 一 η通道,其中選擇性致能ρ通道及η通道之一以回應輸入 電壓。 2 .如申請專利範圍第1項之裝置,其中閘極層包括一凹 陷閘極結構。 3. 如申請專利範圍第1項之裝置,其中傳導通道層包括 一模特絕緣材料。 4. 如申請專利範圍第1項之裝置,其中傳導通道包括 YBa2Cu307_5 ,其中5在約0與約1之間。 5. 如申請專利範圍第1項之裝置,其中閘極層包括摻雜 銳之二氧化欽銘。 6. 如申請專利範圍第1項之裝置,其中絕緣層包括二氧 化鈦錄。 7. 如申請專利範圍第1項之裝置,其申形成ρ通道以回應 一負輸入電壓,及形成η通道以回應一正輸入電壓。 8. 如申請專利範圍第1項之裝置,其中ρ通道包括一電洞 積聚層以回應一負輸入電壓。 9. 如申請專利範圍第1項之裝置,其中η通道包括一電子 積聚層以回應一正輸入電壓。503581 _Case No. 89109150_Amended on July 丨 0 of FV_ VI. Patent application scope 1. A field effect transistor device includes: a gate layer can receive an input voltage; an insulation layer is formed on the gate layer; The conductive channel layer is formed on the insulating layer to carry a current between a source and a drain; and the conductive channel layer can provide a dual channel, the dual channel includes a P channel and an n channel, of which the p channel is selectively enabled And one of the n channels in response to the input voltage. 2. The device according to item 1 of the patent application, wherein the gate layer comprises a recessed gate structure. 3. The device according to item 1 of the patent application, wherein the conductive channel layer includes a model insulation material. 4. The device according to item 1 of the patent application range, wherein the conductive channel includes YBa2Cu307_5, where 5 is between about 0 and about 1. 5. The device as claimed in item 1 of the patent application, wherein the gate layer comprises a doped sharp oxidized TiO 2. 6. The device as claimed in claim 1, wherein the insulating layer comprises titanium dioxide. 7. As for the device in the scope of patent application, it is applied to form a ρ channel to respond to a negative input voltage, and form an η channel to respond to a positive input voltage. 8. The device according to item 1 of the patent application, wherein the ρ channel includes a hole accumulation layer in response to a negative input voltage. 9. The device according to item 1 of the patent application, wherein the η channel includes an electron accumulation layer in response to a positive input voltage. G:\64\64157-9107i0.ptc 第25頁 503581 _案號89109150_<7/年7月α曰_魅_ 六、申請專利範圍 1 0 .如申請專利範圍第1項之裝置,其中場效電晶體裝置 包括一薄膜電晶體。 1 1 . 一種場效電晶體電路’包括· 一薄膜電晶體具有一閘極,一源極及一汲極; 薄膜電晶體包括一閘極層用以形成閘極,閘極可接收 一輸入電壓; 在閘極層上形成一絕緣層; 在絕緣層上形成一傳導通道層用以承載源極與汲極間 之電流;及 傳導通道層可提供一雙通道,雙通道包括一 p通道及 一η通道,其中選擇性致能ρ通道及η通道之一以回應輸入 電壓。 1 2 .如申請專利範圍第1 1項之電路,其中閘極包括一凹 陷閘極結構。 13. 如申請專利範圍第11項之電路,其中源極及沒極之 一接到一負荷,而源極及沒極之另一者接到一交流電壓, 俾薄膜電晶體將負載上之交流電壓整流。 14. 如申請專利範圍第11項之電路,其中傳導通道層包 括一模特絕緣材料。 15. 如申請專利範圍第11項之電路,其中傳導通道包括 YBagCi^iVs ,其中5在約0與約1之間。 1 6.如申請專利範圍第1 1項之電路,其中閘極層包括摻 雜鈮之二氧化鈦勰。 1 7.如申請專利範圍第1 1項之電路,其中絕緣層包括二G: \ 64 \ 64157-9107i0.ptc Page 25 503581 _Case No. 89109150_ &7; July / Year α_Charm_ VI. Application for patent scope 1 0. For the device of the scope of patent application No. 1, which has field effect The transistor device includes a thin film transistor. 1 1. A field effect transistor circuit includes: a thin film transistor having a gate, a source and a drain; the thin film transistor includes a gate layer for forming a gate, and the gate can receive an input voltage Forming an insulating layer on the gate layer; forming a conductive channel layer on the insulating layer to carry the current between the source and the drain; and the conductive channel layer can provide a dual channel, which includes a p channel and a η channel, wherein one of the ρ channel and the η channel is selectively enabled in response to an input voltage. 12. The circuit according to item 11 of the patent application, wherein the gate includes a recessed gate structure. 13. If the circuit in the scope of patent application No. 11 is applied, one of the source and the pole is connected to a load, and the other of the source and the pole is connected to an AC voltage. Voltage rectification. 14. The circuit of claim 11 in which the conductive channel layer includes a model insulation material. 15. The circuit of claim 11 in which the conductive channel includes YBagCi ^ iVs, where 5 is between about 0 and about 1. 16. The circuit according to item 11 of the patent application scope, wherein the gate layer comprises niobium-doped titanium dioxide hafnium. 1 7. The circuit according to item 11 of the scope of patent application, wherein the insulating layer includes two O:\64\64157-9107i0.ptc 第26頁 503581 修正 案號 89109150 六、申請專利範圍 氧化鈦链。 1 8.如申請專利範圍第1 1項之電路,其中形成ρ通道以回 應一負輸入電壓,及形成η通道以回應一正輸入電壓。 1 9.如申請專利範圍第1 1項之電路,其中ρ通道包括一電 洞積聚層以回應一負輸入電壓。 其中η通道包括一電 其中薄膜電晶體與 包括以下步驟·· 2 0 .如申請專利範圍第1 1項之電路 子積聚層以回應一正輸入電壓。 2 1 .如申請專利範圍第1 1項之電路 一發光二極體連接且將其驅動。 2 2. —種形成雙通道電晶體之方法 提供一閘極層用以接收輸入電壓; 在閘極層上沈積一絕緣層; 在絕緣層上形成一雙通道層,係藉由: 在絕緣層上磊晶沈積一杯率層;及 在一減少環境中使杯率層回火以提供一實質無缺陷 之杯率層,俾雙通道包括一 ρ通道及一 η通道,其中選擇性 致能Ρ通道及η通道之一以回應操作期間之輸入電壓;及 在傳導通道層上形成源極及汲極。 2 3.如申請專利範圍第2 2項之方法,其中提供一閘極層 之步驟包括定閘極層之圖樣以形成一凹陷閘極結構。 2 4.如申請專利範圍第2 2項之方法,其中杯率負包括一 模特絕緣材料。 2 5.如申請專利範圍第2 2項之方法,其中杯率層之步驟 包括YBa2Cu3 07_d ,其中5在約0與約1之間。O: \ 64 \ 64157-9107i0.ptc Page 26 503581 Amendment No. 89109150 6. Scope of patent application Titanium oxide chain. 1 8. The circuit according to item 11 of the scope of patent application, wherein the ρ channel is formed to respond to a negative input voltage, and the η channel is formed to respond to a positive input voltage. 19. The circuit of item 11 in the scope of patent application, wherein the ρ channel includes a hole accumulation layer in response to a negative input voltage. The η channel includes an electric film, and the thin film transistor includes the following steps: 20. As in the circuit of the patent application No. 11 sub-accumulation layer in response to a positive input voltage. 2 1. The circuit of item 11 in the scope of patent application. A light-emitting diode is connected and driven. 2 2. A method of forming a dual-channel transistor provides a gate layer for receiving an input voltage; deposits an insulating layer on the gate layer; and forms a dual-channel layer on the insulating layer by: on the insulating layer The epitope deposits a cup rate layer; and tempers the cup rate layer in a reduced environment to provide a substantially defect-free cup rate layer. The dual channels include a ρ channel and an η channel, of which the P channel is selectively enabled. And one of the n channels in response to the input voltage during operation; and forming a source and a drain on the conductive channel layer. 2 3. The method according to item 22 of the scope of patent application, wherein the step of providing a gate layer includes fixing the pattern of the gate layer to form a recessed gate structure. 2 4. The method according to item 22 of the scope of patent application, wherein the negative cup ratio includes a model insulation material. 2 5. The method according to item 22 of the scope of patent application, wherein the step of the cup layer includes YBa2Cu3 07_d, where 5 is between about 0 and about 1. O:\64\64157-910710.ptc 第27頁 503581 修正 案號 89109150 六、申請專利範圍 2 6.如申請專利範圍第2 2項之方法,其中提供一閘極層 之步驟包括摻雜閘極層之步驟。 2 7.如申請專利範圍第2 2項之方法,更包括形成一電洞 積聚層以回應一負輸入電壓之步驟。 2 8.如申請專利範圍第2 2項之方法,更包括形成一電子 積聚層以回應一正輸入電壓之步驟。 2 9.如申請專利範圍第2 2項之方法,其中回火步驟包括 維持一溫度在約2 0 0 °C與約5 0 0 °C之間,長達約0 · 2小時與 約5小時之間。 3 0 .如申請專利範圍第2 2項之方法,其中回火步驟包括 在氧中回火以調整杯率層之氧含量之步驟。 3 1 .如申請專利範圍第2 2項之方法,其中回火步驟包括 在包括一真空及一惰性氣體之一之減少環境中回火之步 驟0O: \ 64 \ 64157-910710.ptc Page 27 503581 Amendment No. 89109150 VI. Application for Patent Scope 2 6. The method for applying for Patent Scope No. 22, wherein the step of providing a gate layer includes doping the gate Layer of steps. 2 7. The method according to item 22 of the scope of patent application, further comprising the step of forming a hole accumulation layer in response to a negative input voltage. 2 8. The method according to item 22 of the patent application scope further comprises the step of forming an electron accumulation layer in response to a positive input voltage. 29. The method according to item 22 of the patent application range, wherein the tempering step includes maintaining a temperature between about 200 ° C and about 500 ° C for up to about 0.2 hours and about 5 hours. between. 30. The method of claim 22, wherein the tempering step includes a step of tempering in oxygen to adjust the oxygen content of the cup layer. 31. The method of claim 22, wherein the tempering step includes the step of tempering in a reduced environment including one of a vacuum and an inert gas. O:\64\64157-910710.ptc 第28頁O: \ 64 \ 64157-910710.ptc Page 28
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