TW494275B - Photosensitizer and visible light curable resin composition comprising the same - Google Patents

Abstract

A visible light curable resin composition is herein disclosed in which a dipyrromethene boron complex compound represented by the following formula (1) is used as a photosensitizer, and this composition has a very high sensitivity to a general-purpose visible light laser, so that a high-speed scanning exposure is possible by the laser, and an extremely fine high resolution can be obtained. In addition, the composition can be used for coating or printing under safelight irradiating conditions and under bright circumstantial conditions without any thickening of the composition, and hence the composition can exert excellent noticeable effects in points of safe operativity, operational efficiency, the quality stability of products: wherein rings X1 and X2 are each an optionally substituted pyrrole ring; Y is H, CN, optionally substituted alkyl, aralkyl, aryl, heteroaryl or alkenyl group; and Z1 and Z2 are halogen, optionally substituted alkyl, alkoxy, alkylthio, aralkyl, aralkyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy or heteroarylthio group, provided that at least one of substituents on the pyrrole rings X1 and X2, groups Z1 and Z2 is the alkoxy, aralkyloxy or aryloxy group.

Description

494275 w 5. Description of the invention () Background of the invention 1. Field of the invention The present invention relates to a photosensitizer using a dipyrrometheneboron complex compound having a specific structure, and a photosensitizer containing the aforementioned photosensitivity The light shows a highly sensitive visible light-curable resin composition. Furthermore, the present invention relates to a visible light-curable resin composition, in which the effect of preventing curing by oxygen is improved, and it can exhibit high sensitivity to light in the visible light range. In addition, the present invention relates to a visible light curable resin composition that can be used under the irradiation environment of a specific safety lamp. 2. Description of related techniques In recent years, in the field of information or image recording using photopolymerization, Research is being conducted on a technique for directly inputting and recording a manuscript edited electronically by a computer using a high-power laser, instead of using a conventional recording technique such as a film manuscript using purple light. The latest technology of Shangyu is used Laser direct writing enables the advantages of M to significantly simplify the recording and image formation steps. Printed by the Consumer Bureau of Standards Bureau (please read the notes on the back before filling out this page) Many of the high-power and stable laser sources that are commonly used today have output wavelengths in the visible range. Specifically, the Chlorine lasers with stable oscillation lines at a wavelength of 48 8 millimeters and 5 1.4 nanometers and YAG lasers with a bright line at 5 32 millimeters as the second harmonic. Therefore, it is necessary to Compounds with high sensitivity to these wavelengths, but conventional photosensitive surfaces used in combination with ultraviolet light cannot be used because of their low sensitivity in the visible light range. In addition, the addition of piperane salt or thionine tweezers salt can be improved in Sensitivity in the visible light range, but storage stability of the photosensitive layer containing this compound. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm). A? ΙΓ 5. The description of the invention is poor, which makes its application difficult. It is known that the compound has photosensitivity in the visible light range. For example, 7-diethylamino-3-benzothiazole coumarin ( Common names: Coumarin-6) and bis [3- (7-diethylaminocoumarin)] one (common name: coumarin), but these compounds have a maximum absorption wavelength near 450 milliliters, It is shorter than 488 milliliters of argon laser, so its photosensitivity is insufficient. In addition, the 4-substituted-3-benzothiazole coumazone is described in Japanese Patent Laid-Open Application No. 1 8 088/1 992 The compound has high photosensitivity in 488 milligrams of chlorine laser, but it has almost no absorption at 514 + 5 millimeters of rice and 532 milligrams of rice in the second harmonic of YAG laser. Therefore, this compound Photosensitivity cannot be sufficiently improved. European Patent No. 0, 06 1 9 5 2 0, US Patent No. 0 + 5 4 9 8 6 4 1, Japanese Patent Laid-open Application No. 2 5 8 4 4 4/1 9 9 7, 1 7 9 5 0 4/1 9 9 6, 9 5 2 4 4/1996, 76377/1996, 6245/1996 '225474 / 1995- 219223/1 9 9 5, 5 6 8 5/1 9 9 5 and 2 4 1 3 3 8/1 9 9 3 published bispyrrole compounds, but these compounds were not able to sufficiently improve the sensitivity to frontal laser light and the storage stability of the photosensitive layer. On the other hand, conductor circuits such as printed wiring boards have hitherto been made by exposing and developing a plate coated with a photosensitive anti-corrosion coating, preparing an anti-corrosion coating scheme, and then removing unnecessary portions therefrom by etching. form. Regarding exposure technology, there are a method of exposing a plate through a photomask, and another method of directly drawing an anticorrosive coating by using a laser. In the method of exposing the plate through the photomask, there is a problem that it takes a lot of time to position the photomask, and when the surface of the anti-corrosion coating is sticky, the positioning of the photomask is more difficult. problem. This paper size applies Chinese National Standard (CNS) Α4 specification (210X 297 mm) -R-(Please read the precautions on the back before filling this page)

494275 Λ " Β- V. Description of the invention (exposure to light is often used in the general reason for oxygen), which is due to the law. The sensitivity of the square layer is high, and it needs to prevent the layer from being painted. For thunder, it is usually shorter than β, ητ. Covers such as layers of resistance or 0 0 thin cover-rtu a surface coating to prevent capping activation, oxygen and air in the air Being sensitive will not be able to maintain the basic dimension and can live this cause and production, the broken group of laser radiation will be caused by the cause of M, the fat tree fb 0. The light can be changed and the light can be used. For those who are troubled with numbness before, there is no other way to make the lamp safe and cover it. Painted as the agent, the color of the ambient light is ringed with the color of the fluorescent light, the red light is all dark, and the color tube is red as dark. Various lights are used around this lamp. _ Is used to make it thin, and the color is red. The situation is dark. 丨 It will be turned into a full lamp for the outer lamp group, and it will stay in this state. _ Etc. It is difficult to pick up and pick up, etc. It is difficult to pick up and pick up after the coating. Rewrite the questions and check some of the products that are easy to be fixed under the circumstances such as ring difference work, etc., and the quality of the product is stable, and the quality of the product is as follows: Non-sexuality is used to make the work in the full-specific category. The light and fat exposure of the tree is sensitive to the light, but it is not seen, but the subject is also required to be exposed. The bright photos are brief and clear (please read the notes on the back before filling this page). The printed materials of the fixed light printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs include the light 1 UL \ 1 # mentioned in The gigantic hair of the giant 1 has a pair of 4 and 51, and the line singularity is as stable as that of the Zhuan, the sensitive long light wave of the Rael that stores and stores light is long, and the things surround the fan group light. Zhi Jian tree can be slightly in the wave harmonic second or laser argon. Source photosensitivity, high radiation, high stability, stable lightning, LG and AY, rate 2 m 53 Straight-painted like a shadow mask It can be used for any purpose that shines in the light. It can be used to make the light shine. This paper can be used. The paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm). 6 494275 A7 Βη Sex. The active, sensitive, and high-yield coatings on the upper layer can erode its defenses, and it can be used to shoot live lightning to shoot oxygen from the Zhongjingqi. The Huaming fixed light is particularly sensitive to the cocoa's different and superior supply sensibility. One more, and the other is re-manipulation. The Ming Dynasty issued a photo of the ring, and the result of the current hair was also, Ask this question. The combination of the pre-determined solution of the pre-determined solution of the MU substance research and the research and development of the research and development of the special person has clear instructions, including this package of a knowledge solution can be shadowed into lipids. Make sure that your hair is correct, and that you ca n’t do it because of the static C. The answer to this question is how to apply the technical relationship. The first version of the bright hair is to use only a few kinds of chemical formulas (please read the back first) For the matters needing attention, please fill out the form on this page \ — / TI / ί \ '

0 Combination of Sensitive Light \ y

Z

2 Z Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs is Yf-alkane or oxygen; Aromatic, comprehensive ring, zircyl, and pyridyl halide are alkyl-based aromatic compounds, Take 7.2 alkyl groups, or or Z! Groups of each group, and oxygen groups *, alkyl coco alkenyl groups are or or substitute for each group, the base is X2 groups and cyanopoly X, , Or a ring group, the original aromatic group has its hydrogen, an alkoxy group, an oxo group, a sulfur x2 aryl group, an X-based epoxy aryl group, a sulfonyl group, a radical To limit its heterogeneity, the radicals of sulfanyl, arylthio, and heterooxane are substituted by one or more. One base is less oxygen to aromatic or Z2 radical R oxygen Z1 alkane aryl group, this paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 494275 A7 B " 7 5. Description of the invention () The second of the invention The aspect is based on a visible light-curable resin composition, which includes: (A) a light-curable resin, (B) a photoreaction initiating surface, and (C) a photosensitizer. A third aspect of the present invention is a composition for a visible light curing material, which includes the visible light curing resin composition and a solvent of the present invention. A fourth aspect of the present invention relates to a visible light-curable material, which includes a substrate and a visible light-curable resin composition thereon. In the present invention, the visible light-curable resin composition containing a specific compound as a photosensitive substance is a composition that is extremely useful in practice. So far, in the field of information storage using photo-curing reactions, conventional systems that use lasers to directly output and store originals edited electronically by a computer M have some disadvantages. For example, the stability of the photosensitive layer deteriorates with time * its sensitivity is low, and its solubility and storage stability are insufficient. However, the visible-light-curable resin composition of the present invention is extremely compatible with light-curable resins and photosensitive materials, and it is soluble in general-purpose coating solutions. Therefore, this composition can produce a uniformly coated surface with excellent storage stability over time on a substrate. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). In addition, it can be used as a photosensitizer with a specific structure of the dipyrrolidene complex compound of the present invention. For general-purpose visible light lasers, such as argon lasers with stable oscillation lines at 488 millimeters and 514.5 millimeters and YAG lasers with second harmonics at 5 32 millimeters of bright lines, they have very High sensitivity. Therefore, for a photosensitive material prepared using the visible-light-curable resin composition of the present invention, high-speed scanning exposure can be achieved by using this laser. In addition, when high-speed scanning exposure is used to form an image, it can be obtained with extremely high ffl high paper size applicable to Chinese National Standard (CNS) A4 specifications (210X 297 mm) -8-Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 494275 Λ ? ΪΓ 5. Description of the invention () Resolution image. The visible-light-curable resin composition of the present invention can be used for coating or printing under the light of a safety lamp and under bright environmental conditions, without any thickening of the composition, so the aforementioned resin composition can be produced in safe operability , Operating efficiency, product quality stability and so on. Brief Description of the Drawings Figure] is a diagram showing an example of the spectral distribution of a discharge lamp that can be used in a safety lamp containing sodium as a main component of the present invention. Figure 2 is a graph showing the spectral distribution of a sodium discharge lamp equipped with a dim light. Figure 3 is a graph showing the spectral luminous efficiency. FIG. 4 is a graph showing an absorption curve of the anticorrosive coating film used in Example 1. FIG. Circle 5 shows the spectral distribution of a conventional fluorescent lamp. Detailed description of preferred specific examples The present invention is characterized by using a bipykaleneboron complex compound represented by the aforementioned chemical formula (1) as the photosensitive surface (using the chemical formula U) of two% of the methylene chloride complex The photosensitizer of the compound can absorb light in the visible light range of 400 to 700 millimeters, especially light of 400 to 60 millimeters, so that it is excited, and when this photosensitizer is used in visible light curing In the resin composition, the photosensitizer interacts with the photocurable resin (A) and the photoreaction initiator (B) constituting the composition. The term "interactive reaction" referred to herein includes energy transfer or electron transfer from the excitation photosensitizer (C) used in the present invention to the photocurable resin (A) or photoreactive initiator (B). This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) -9-(Please read the precautions on the back before filling this page) • Jacket. 494275 Λ: Β- V. Description of the invention (The present invention The photosensitivity of human hair using the aforementioned dipyrromethene complex compound represented by M (1 >) is extremely effective, and when present on the dipyrromethene boron complex structure of the compound represented by M formula (1) When at least one of the substituents is an alkoxy group, an aralkyloxy group, or an aryloxy group, it exhibits excellent photosensitivity. In addition, it also occurs when a boron atom has an alkoxy group, an aralkyloxy group, or an aryloxy group as a substituent. At the same time, the photosensitivity can be improved by people. The palladium methylene-boron complex compound represented by the chemical formula (1) is a very effective compound as a photosensitizer, which is effective against light from argon lasers and from YAG lasers. The wavelength of the emitted second harmonic light has a great absorbance, and it is very sensitive to such light and can be applied to a negative photosensitive resin composition using a photocuring resin and a photoreaction initiator. Incidentally, in the present invention, $ For visible light curing materials The composition _ 〃 means, for example, a photosensitive coating composition, a photosensitive ink, a photosensitive adhesive, a photosensitive printing plate material, a photosensitive anticorrosive coating material, or an unexposed material formed therefrom containing the visible light curable resin composition of the present invention. The coating materials will be described in more detail in the following. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, it is represented by chemical formula (1) and has the ring X i and) (2, which may have substituents. The compound of the present invention which has a cyclic ring can be represented by the chemical formula (2): RR □

(2) 10 (Please read the notes on the back before filling out this page) This paper size applies to China National Standard (CNS) Α4 size (210 × 297 mm) 494275 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ? 1Γ 2. Description of the invention (wherein Ri, R2, R3, R5, Re, and R7 are each a hydrogen atom, a hydrogen atom, a cyano group, a hydroxy group, an amine group, and may have one or more substituents. Alkyl, alkoxy or alkylthio groups of 1 to 20 carbon atoms, aryl, aryloxy or arylthio groups having 6 to 20 carbon atoms which may have one or more substituents, may have Aralkyl or aralkyloxy groups having 7 to 20 carbon atoms, one or more substituents, heteroaryl groups having 2 to 20 carbon atoms, which may have one or more substituents, may have one Or an alkenyl group having 2 to 10 carbon atoms or more than one substituent, or a group represented by the chemical formula (3) or (4): 0II —CQ (3) wherein Q is a hydrogen atom, an amine group, and may have Alkyl or alkoxy groups having 1 to 20 carbon atoms with one or more substituents, arylfluorenyl groups having 7 to 20 carbon atoms with one or more substituents Aralkyloxy, aryl having 6 to 20 carbon atoms, which may have one or more substituents, aryloxy or arylamine group, 2 to 10 carbon atoms which may have one or more substituents An oxy group, a haloalkylamino group having 1 to 10 carbon atoms, which may have one or more substituents, a dialkylamino group having 2 to 20 carbon atoms, which may have one or more halo substituents, Or an alkoxyalkoxy group or alkoxycarbonylalkoxy group having 3 to 20 carbon atoms which may have one or more substituents, -N Η-L (4) wherein L is a substituent group which may have one or more substituents Alkylcarbonyl group with 2 to 10 carbon atoms or arylcarbonyl group with 7 to 15 carbon atoms which may have one or more substituents; This paper size applies to China National Standard (CNS) A4 specification (210X 297 mm) ) _ Ι ι _ (Please read the notes on the back before filling this page)-€ ·

、 1T • t 494275 Λ? Η * 7 V. Description of the invention () R 4 is a hydrogen atom, a cyano group, which may have one or more substituents] an alkyl group of 20 to 20 carbon atoms, may have one or more Aryl groups with 7 to 20 carbon atoms per substituent, aryl groups with 6 to 20 carbon atoms that may have one or more substituents, 2 to 20 carbon atoms that may have one or more substituents Heteroaryl groups of carbon atoms, or alkenyl groups having 2 to 10 carbon atoms which may have one or more substituents; Z ^ and Z 2 each are a halogen atom and may have one or more substituents Alkyl, alkoxy or alkylthio groups of 1 to 20 carbon atoms, aralkyl or aralkyloxy groups of 7 to 20 carbon atoms which may have one or more substituents, may have one or Aryl, aryloxy or arylthio having 6 to 20 carbon atoms in a plurality of substituents, heteroaryl, heteroaryloxy having 2 to 20 «carbon atoms which may have one or more substituents, or Heteroarylthio; its limitation is that at least one of Ri, R2, R3, R5, Re, and R7 is alkoxy, aralkoxy, or aryloxy. The compound represented by the formula (M) may also be represented by the formula (5):

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling out this page) where Ri, R2, R3, R5, R6, and R7 are each a hydrogen atom, a halogen atom, Cyano, hydroxy, amine, · alkyl or alkylthio having 1 to 20 carbon atoms which may have one or more substituents, 6 to 20 carbons which may have one or more substituents Atomic aryl or arylthio groups, aryl groups having 7 to 20 carbon atoms, which may have one or more substituents, heteroaromatic groups having 2 to 20 carbon atoms, which may have one or more substituents Basic, can have one or more alternative basic paper sizes Applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) _ ι 2-494275 Λ7 ΙΓ 5. Description of the invention () Group, or a group represented by M chemical formula (3 丨 or U): 0

I —C-Q (3) where Q is a hydrogen atom, an amine group, an alkyl or alkoxy group having 1 to 20 carbon atoms, which may have one or more substituents, Aralkyl or aralkyloxy groups having 7 to 20 carbon atoms, aryl groups having 6 to 20 carbon atoms that may have one or more substituents, aryloxy or arylamine groups, may have one or Alkenyloxy groups having 2 to 10 carbon atoms of multiple substituents, monoalkylamino groups having 1 to 10 carbon atoms that may have one or more substituents, those having one or more substituents A dialkylamino group of 2 to 20 carbon atoms, or an alkoxyalkoxy group or alkoxycarbonylalkoxy group having 3 to 20 carbon atoms which may have one or more substituents, -NH-L (4 ) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling out this page) where L is an alkanecarbonyl group with 2 to 10 carbon atoms which may have one or more fluorene substituents or may have An arylcarbonyl group having 7 to 15 carbon atoms of one or more substituents; R4 is a hydrogen atom, a cyano group, and 1 to 20 carbon atoms which may have one or more substituents An alkyl group, which may have one or more substituents, having 7 to 2C; an aralkyl group which may have one or more substituents, an aryl group having 6 to 20 carbon atoms, which may have one or more substituents, may have one or more Heteroaryl groups with 2 to 20 carbon atoms with multiple substituents, or alkenyl groups with 2 to 10 carbon atoms that may have one or more substituents; This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) _ ι 3-494275 Λ7 h1 V. Description of the invention (there is a radical with a base or a codon with a proton tooth of ΓΓϋ S, each of 2 Z and the son of an alkane have a radical with a carbon .ο py 2 generations up to one or more of the original carbon with one or more radicals There are alternatives, poly- or sulphur, aromatic radicals or radicals, oxygen radicals, radicals, radicals, radicals, carbon radicals, 2 radicals or radicals, aryl radicals, aryl radicals, 2 radicals or radicals. Heterozygous earth or base ζ2 oxygen and aromatic zea The base is aromatic. Hetero-limited radicals have radicals with oxygen radicals. ^ Polymorphic or chemical conversions have radicals with radicals that include oxygen radicals. The radicals with radical radicals have better carbon than 2 radicals. The supreme I-cyclopyridine, the son of the oxyalkoxy aromatic fragrant, the original original carbon carbon number 20 2 to Sf7 6 have a basic group substituted K1 Ήππ many or or one by one with cocoa And the VI base of the basic code is taken from the framework of the substituted formazanylpyrrole, and the radical of the alkyl radical is substituted by a more or | The cyano, alkenyl and primordial hydrogen aromatic inclusions are substituted by the aryl group. The aryl group is replaced by the obvious Λ ,,, and square band compounds (please read the precautions on the back before filling this page) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, Cooperative Alkali, Aromatics, Aromatics, Oxygen, Oxygen, Aromatic Aromatics, Haloalkylated / IV Included Formulas, Science Ilkylated alkanes are in the base, zeolite, zeolite, zeolite, alkane, sulfide, aryl, and aryl, and oxy-based, aryl, and aryl. The aromatic group and the thio group of the exemplified base are better than those of the original carbon. Substitute the oxy group with a radical for it and take the son of a multi-base or oxo-alkane or a cyclic one and have a son and daughter, a branch, a radical, a radical, and a alkoxy alkane Sub-original carbon carbon 7 to this paper size Applicable to Chinese National Standard (CNS) A4 specifications (210X 297 mm) 14 494275 A? ΙΓ 5. Description of the invention (II) in the present invention's M chemical formula (2) or (5) Among the compounds represented by, typical examples of R 1 Λ R 2, R 3 R5 Re, and R? Include a hydrogen atom Λ cyano, a hydroxyl group, and a halogen atom such as a fluorine atom, a chlorine atom, and a bromine atom 0 Μ R 1, Λ Examples of the alkyl group having 20 lower carbon atoms which may be represented by r3, R5, Rg, and Rv include a straight chain having 1 to 20 carbon atoms, a branch bond, and a ring M group such as Methyl ethyl, n-propyl, isopropyl, n-butyl isobutyl, butylbutyl Λ second butyl n-pentyl, isopentyl Λ Pentyl, second pentyl, cyclopentyl Λ n-hexyl 1-methylpentyl Λ 2- methylpentyl 3- methylpentyl, 4-methylpentyl Λ 1, 1-dimethylbutane Group, 1,2-dimethylbutyl Λ 1, 〇_dimethyl-yl 2, 3--1 methylbutyl Λ 1, 1, 2-dimethylpropyl 1, 2, 2-di Methylpropyl 1-ethylbutyl 2-ethylbutyl 1-ethyl-2 -methylpropyl, cyclohexyl '' methylcyclopentyl n-heptyl 1-methylhexyl 2-methylhexyl Λ 3-methylhexyl 4-• methylhexyl Λ 5-methylhexyl 1, 1-dimethylpentyl > 1, 2-dimethylpentyl ·, 1, 3- — ▲ methylpentyl 1, 4-, dimethylpentyl 2, 2-methylpentyl Λ 2, 3-dimethylpentyl 2, 4-dimethylpentyl, 3, 3-dimethylpentyl, 3, 4-methylpentyl 1-ethylpentyl 2-ethylpentyl Λ g monoethylpentyl 1, 1, 2- methylbutyl Λ 1, 1, 3-dimethylbutyl, 1, twenty three - Methylbutyl 1, 2, 2-dimethylbutyl, 1, 3, 3- • dimethylbutyl Λ 2, 3, 3--dimethylbutyl 1-• ethyl-1-methyl Butyl, 1-ethyl-2-methyl-r-based 1- • ethyl-3 丨 -methyl "] ', 2: -ethyl-1-methylbutyl, 2-ethyl Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs-3-methylbutyl, 1-n-propylbutyl, 1-isopropylbutyl, 1-isopropyl-2-methylpropyl, methyl Cyclohexyl, n-octyl, 1-methylheptyl, 2-methylheptyl, 3-methylheptyl, 4-methylheptyl, 5-methylheptyl, 6-methyl15 (please first Read the notes on the reverse side and fill out this page) This paper size applies the Chinese National Standard (CNS) Α4 size (210 × 297 mm) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 494275 Λ7 B * 7 5. Description of the invention () Group, 1,]-dimethylhexyl,], 2-dimethylhexyl, 1,3-dimethylhexyl, 1,4-dimethylhexyl, 1,5-dimethylhexyl, 2,2 -Dimethylhexyl, 2 s 3 -dimethylhexyl, 2,4-dimethylhexyl, 2, 5 -Dimethylhexyl, 3,3-dimethylhexyl, 3,4-dimethylhexyl, 3,5-dimethylhexyl, 4,4-dimethylhexyl, 4,5-dimethylhexyl , 1-ethylhexyl, 2-ethylhexyl, 3-ethylhexyl, 4-ethylhexyl, 1-n-propylpentyl, 2-n-propylpentyl, 1-isopropylpentyl, 2 -Isopropylpentyl, 1-ethyl-1-methylpentyl, 1-ethyl-2-methylpentyl, 1-ethyl-3-methylpentyl, 1-ethyl-4- Methylpentyl, 2-ethyl-methylpentyl, 2-ethyl-2-methylpentyl, 2-ethyl-3-methylpentyl, 2-ethyl-4-methylpentyl, 3-ethyl-p-methylpentyl, 3-ethyl-2-methylpentyl, 3-ethyl-3-methylpentyl, 3-ethyl-4-methylpentyl, 1,1,2 -Trimethylpentyl, 1,1,3-trimethylpentyl, 1,1,4-trimethylpentyl, 1,2,2-trimethylpentyl, 1,2,3 -tri Methylpentyl, 1,2,4-trimethylpentyl, 1,3,4-trimethylpentyl, 2,2,3-trimethylpentyl, 2, 2, 4-trimethyl Amyl, 2, 3, 4-trimethylpentyl, 1, 3, 3-dimethylpentyl, 2, 3, 3-dimethylpentyl, 3, 3, 4-dimethylpentyl , 1, 4, 4-trimethylpentyl, 2, 4, 4-trimethylpentyl, 3, 4, 4-trimethylpentyl, 1-n-butylbutyl, 1-isobutylbutyl, 1- Second butylbutyl, 1-third butylbutyl, 2-third butylbutyl, 1-n-propyl-1-methylbutyl, 1-n-propyl-2-methylbutyl , 1-n-propyl-3-methylbutyl, isopropyl-1-methylbutyl, 1-isopropyl-2-methylbutyl, 1-isopropyl-3-methylbutyl Group, 1,1-diethylbutyl, 1,2-diethylbutyl, 1-ethyl-1, 2-dimethylbutyl, 1-ethyl-1, 3-dimethylbutyl Base, 1-ethyl-2,3-dimethylbutyl, 2-ethyl-1,1-dimethylbutyl, 2-ethyl This paper size is applicable to China National Standard (CNS) A4 specification (210X297) Li) —] β — (Please read the notes on the back before filling out this page)

, 1T printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 494275 Λ? Η * 7 V. Description of the invention () 1,2-dimethylbutyl, 2-ethyl-1,3-dimethylbutyl, 2-ethyl-2,3-dimethylbutyl, 1,2-dimethylcyclohexyl, 1,3-dimethylcyclohexyl, 1,4-dimethylcyclohexyl, ethylcyclohexyl, N-nonyl, 3,5,5-trimethylhexyl, n-decyl, n-undecyl, n-dodecyl, n-pentadecyl, decyl, adamantyl, eicosyl, and 4-tert-butyl Cyclohexyldecyl; alkyl substituted with hydroxy having 1 to 10 carbon atoms such as methylol, hydroxyethyl, hydroxypropyl, and hydroxydecyl; substituted with one or more halogen atoms and having 1 to 20 Alkyl groups such as chloromethyl, dichloromethyl, fluoromethyl, trifluoromethyl, pentafluoroethyl, Ll, l, 3,3,3-hexafluoro-2-propyl, nonafluoro Butyl, perfluorodecyl and perfluoroicosyl; alkyl substituted with alkoxy and having 2 to 20 carbon atoms such as methoxymethyl, methoxyethyl, ethoxyethyl, n-propoxyethyl Base, isopropoxyethyl, n-butoxyethyl, isobutoxyethyl, third butoxyethyl, Butoxyethyl, n-pentoxyethyl, isopentoxyethyl, third pentoxyethyl, second pentoxyethyl, cyclopentyloxyethyl, n-hexyloxyethyl, ethylcyclohexyloxyethyl, N-nonoxyethyl, 3,5,5-trimethylhexyloxyethyl, n-decyloxyethyl, n-undecyloxyethyl, n-dodecyloxyethyl, n-heptadecanyloxyethyl, Octadecyloxyethyl, 3-methoxypropyl, 3-ethoxypropyl, 3- (n-propoxy) propyl, 2-isopropyloxypropyl, 2-methoxybutyl, 2-ethoxy Butyl, 2- (n-propoxy) butyl, 4-isopropoxybutyl, decoxyethyl, and gold alkoxyethyl;. Substituted with alkoxyalkoxy and having 3 to 20 carbon atoms Alkyl groups such as methoxymethoxymethyl, methoxyethoxyethyl, ethoxyethoxyethyl, propoxyethoxyethyl, isobutoxypropoxyethyl and 4- (4-decylcyclohexyloxy) ) Butyl; This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) -1 7-(Please read the notes on the back before filling in this tribute)

1T 494275 A? ΗΊ 5. Description of the invention () Alkyl groups substituted with aryloxy and having 7 to 20 涸 carbon atoms such as phenoxymethyl, phenoxyethyl, (3-methylphenoxy) ethyl and 4- (1_Ceoxy) butyl; alkyl substituted with arsenyloxy and having 8 to 20 pseudo carbon atoms such as benzyloxymethyl, amidoxyethyl, phenethoxyethyl, and 9-pentyl Methoxyhexyl; alkyl substituted with alkylthio and having 2 to 20 carbon atoms such as 2-methylthioethyl, 2-ethylthioethyl, 2-n-propylthioethyl, 2-isopropylthioethyl Methyl, 2-n-butylthioethyl, 2-isobutylthioethyl, and octadecylthioethyl; M and an alkyl group substituted with a dialkylamino group and having 3 to 20 carbon atoms such as 2-dimethylamine Methyl, 2-dimethylaminoethyl, 4-dimethylaminobutyl, 1-dimethylaminopropan-2-yl, 3-dimethylaminopropyl, 2-diisopropylaminoethyl , 2-di-n-butylaminoethyl, N-hexahydropyridineethyl and 4- (di-n-octylamino) butyl. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page) MR i, R 2, R 3 _, R 5, R 6 and R 7 are indicated, and can have one or more Examples of the fluorenyloxy group having 1 to 20 carbon atoms of the substituent include a fluorenyl group having 1 to 20 carbon atoms, a branched fluorene group and a cycloalkylene group such as a methoxy group, an ethoxy group, an n-propoxy group, an isopropyl group, Propoxy, n-butoxy, isobutoxy, third butoxy, second butoxy ..., n-pentyloxy, isopentyloxy, third pentoxy, second pentoxy, Cyclopentyloxy, n-hexyloxy, 1-methylpentyloxy, 2-methylpentyloxy, 3-methylpentyloxy, 4-methylpentyloxy, 1,1-dimethylbutoxy Group, 1,2-dimethylbutoxy, 1,3-dimethylbutoxy, 2,3-dimethylbutoxy, 1,1,2-trimethylpropoxy, 1, 2,2-trimethylpropoxy, 1-ethylbutoxy, 2-ethylbutoxy, 1-ethyl-2-methylpropoxy, cyclohexyloxy, methylcyclopentyloxy Methyl, n-heptyloxy, 1-methylhexyloxy, 2-methylhexyloxy, 3-methylhexyloxy, 4-methylhexyloxy, 5-methyl Hexyloxy, 1, 1-dimethylpentyloxy, 1, 2-dimethylpentyloxy, 1, 3_dimethylpentyl This paper is sized for China National Standard (CNS) A4 (210X297 mm) ) -Ig _ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 494275 Λ? ΙΓ V. Description of the invention () oxy, 1, 4-dimethylpentyloxy, 2, 2-dimethylpentyloxy, 2 , 3-dimethylpentyloxy, 2, 4-dimethylpentyloxy, 3, 3-dimethylpentyloxy, 3, 4-dimethylpentyloxy, ethyl ethylpentyloxy , 2-ethylpentyloxy, 3-ethylpentyloxy, 1,1,2-trimethylbutoxy, 1,1,3-trimethylbutoxy, 1,2,3-trimethylbutoxy Methylbutoxy, 1,2,2-trimethylbutoxy, 1,3,3-trimethylbutoxy, 2,3,3-trimethylbutoxy, 1-ethyl- 1-methylbutoxy, 1-ethyl-2-methylbutoxy, 1-ethyl-3-methylbutoxy, 2-ethyl-1-methylbutoxy, 2-ethyl Methyl-3-methylbutoxy, 1-n-propylbutoxy, 1-isopropylbutoxy, 1-isopropyl-2-methylpropoxy, methylcyclohexyloxy, n- Octyloxy, 1-methylheptyloxy, 2-methylheptyloxy , 3-methylheptyloxy, 4-methylheptyloxy, 5-methylheptyloxy, 6-methylheptyloxy, 1,1-dimethylhexyloxy, 1,2-dimethyl Hexyloxy, 1,3-diΦhexyloxy, 1,4-dimethylhexyloxy, 1,5-dimethylhexyloxy, 2,2-dimethylhexyloxy, 2 , 3-dimethylhexyloxy, 2, 4-dimethylhexyloxy, 2, 5-dimethylhexyloxy, 3, 3-dimethylhexyloxy, 3, 4-dimethyl Hexyloxy, 3,5-dimethylhexyloxy, 4,4-dimethylhexyloxy, 4,5-dimethylhexyloxy, 1-ethylhexyloxy, 2-ethylhexyl Oxy, 3-ethylhexyloxy, 4-ethylhexyloxy, 1-n-propylpentyloxy, 2-n-propylpentyloxy, 1-isopropylpentyloxy, 2-isopropyl Pentyloxy, 1-ethyl-1 -methylpentyloxy, 1 -ethyl-2-methylpentoxy, 1-ethyl-3-methylpentoxy, 1-ethyl-4 _Methylpentyloxy, 2-ethyl-1-methylpentyloxy, 2-ethyl-2-methylpentyloxy, 2-ethyl-3-methylpentoxy, 2-ethyl 4-methylpentyloxy, 3-ethyl_1-methylpentyloxy, 3-ethyl-2-methylpentyloxy, 3-ethyl-3-methylpentyloxy, 3- Ethyl-4-methylpentane Yl, 1,1,2 - trimethyl pentyl group, this applies scale paper China National Standard (CNS) Α4 Specification (210X 297 mm) _ i g - (Read Notes on the back and then fill the page) 4

、 1T 494275 Λ-? ΗΊ 5. Description of the invention () Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) 1,1,3 -trimethylpentyloxy, 1 , 1,4-trimethylpentoxy, 1,2,2-trimethylpentoxy, 1,2,3-trimethylpentoxy, 1,2,4-trimethylpentoxy , 1,3,4-trimethylpentyloxy, 2,2,3-trimethylpentyloxy, 2,2,4-trimethylpentyloxy, 2,3,4-trimethylpentyl Oxy, 1,3,3-trimethylpentyloxy, 2,3,3-trimethylpentyloxy, 3, 3, 4-trimethylpentyloxy, 1,4,4-trimethyl Pentyloxy, 2,4,4-trimethylpentoxy, 3,4,4-trimethylpentoxy, 1-n-butylbutoxy, 1-isobutylbutoxy, 1 -Second butylbutoxy, 1-third butylbutoxy, 2-third butylbutoxy, 1-n-propyl-1 -methylbutoxy, 1-n-propyl-2 -Methylbutoxy, 1-n-propyl-3-methylbutoxy, 1-isopropyl-1-methylbutoxy, 1-isopropyl-2-methylbutoxy, 1 -Isopropyl-3 -methylbutoxy, 1, 1 -diethylbutoxy, 1, 2-diethylbutoxy, 1 -ethyl-1,2-di Methylbutoxy, 1-ethyl-1, 3-dimethylbutoxy, 1-ethyl_2, 3-dimethylbutoxy, 2-ethyl-1, 1-dimethyl Butoxy, 2-ethyl-1,2-dimethylbutoxy, 2-ethyl-1,3-dimethylbutoxy, 2-ethyl-2,3-dimethylbutoxy , 1,2-dimethylcyclohexyloxy, 1,3-dimethylcyclohexyloxy, 1,4-dimethylcyclohexyloxy, ethylcyclohexyloxy, n-nonyloxy, 3,5,5-trimethylhexyloxy, n-decyloxy, n-undecyloxy, n-dodecyloxy, 1-goldalkoxy, n-pentadecanyloxy, eicosane Oxy and 1 0- (4-tert-butylcyclohexyl) decoxy; alkoxy substituted with alkoxy and having 2 to 20 carbon atoms such as methoxymethoxy, ethoxyethoxy , Ethoxyethoxy, n-propoxyethoxy, isopropoxyethoxy, n-butoxyethoxy, isobutoxyethoxy, third butoxyethoxy, second butoxyethoxy , N-pentyloxyethoxy, isopentyloxyethoxy, third-pentyloxyethoxy, second-pentyloxyethoxy, cyclopentyloxyethoxy, n-hexyloxy This paper is applicable to Chinese National Standards (CNS) Α4 specifications (210X 297 mm) -2 0-494275 Η " 7 V. Description of the invention (Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China 10 ~ 3 ~ iso_.1 Propoxypropoxymethoxy, butoxymethoxypropoxy , III.iE, 2- ^ u Η, KJ oxypropoxy f ethoxy, propoxy KJ oxypropoxy 5-, radical., Propane; ΙΛ subunit, methoxybutoxyethoxy, ethoxyethyl Oxypropoxy 5, phenyloxy (JF & Λoxy, butoxymethoxy ethoxy, methoxypropoxy butyl 3, oxyethoxy 2-: »bond methoxy ·, propoxyethoxyethoxy , Butoxybutoxy gold straight-L., Ethoxypropane, · mono / oxymethoxy, ethoxyethoxyethoxy, propoxymethyloxane 1} yl 1 / h methoxymethoxy, methyl Propoxypropoxy, ethoxylate 8S oxygen α α oxyethoxymethoxy, butoxybutoxypropoxy, methyl ethyl ten! * Butoxy M ethoxyethoxy methoxy, propoxymethyl Oxypropoxy, oxygen ten, propoxy gz, life, methoxypropoxyethoxy, ethoxymethoxypropoxy non-n-yl (1Fethyl_0 # yl, butoxybutoxyethoxy, methoxyethyl Hyproxen, 3-2-oxin, 2oxy, propoxymethoxyethoxy., Butoxypropoxypropane, ethyl,,-& g t; 3-methoxy, ethoxymethoxyethoxy, propoxybutoxyoxyoxy group U aeromethoxy, methoxyethoxyethoxy, ethoxybutoxyethaneoxy Γ « With methoxymethoxy, butoxypropoxyethoxy_, φoxyethoxypentapropane, and oxymethoxymethoxy, propoxybutoxypropoxy, butoxydecadecaoxy ^ Oxymethoxy, ethoxybutoxypropoxy, hexamethylene-n-methylpropane, such as butoxypropoxymethoxy, & oxymethoxypropoxy ring, 3-2--P-based, propane Oxybutoxyethoxy, butoxyethoxypropoxy, 4oxy, ethoxybutoxyethoxy, propoxypropoxypropethoxyoxy, alkoxyoxy, methoxy Methoxyethoxy, ethoxypropoxy, ethoxyethoxy ^ δoxanemethoxy, butyloxyethoxyethoxy, methoxybutyloxypropoxypropyl Oxypropoxyethoxy, butoxyoxyhexaneoxyoxy »J group is methoxymethoxy, ethoxypropoxypropoxy, propylethyldimethylpropyloxy ethoxyethoxymethoxy, methyl Oxybutoxypropoxy., (Please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) 21 494275 Λ? ΙΓ 5. Description of the invention () Ethoxymethoxybutoxy, propoxymethoxybutoxy, butoxymethoxybutoxy, methoxy Ethoxybutoxy, ethoxyethoxybutoxy, propoxyethoxybutoxy, butoxyethoxybutoxy, methoxypropoxybutoxy, ethoxypropoxybutoxy, propoxypropoxy Butoxy, butoxypropoxybutoxy, methoxybutoxybutoxy, ethoxybutoxybutoxy, propoxybutoxybutoxy, butoxybutoxybutoxy, 4-ethylcyclohexyl Oxyethoxyethoxy, (2-ethyl-buhyloxy) ethoxypropoxy, 4- (3,5,5-trimethylhexyloxy) butoxyethoxy and 6- {2 -(2-decoxy) butoxy} n-hexyloxy; alkoxy substituted with an alkylthio group and having 2 to 20 carbon atoms such as methylthiomethoxy, 2-methylthioethoxy, 2- Ethylthioethoxy, 2-n-propylthioethoxy, 2-isopropylthioethoxy, 2-n-butylthioethoxy, 2-isobutylthioethoxy and decylthiodecyloxy; Alkylamino substituted alkoxy groups having 3 to 20 carbon atoms such as dimethylaminomethoxy, 2-dimethylaminoethoxy, 4-di Aminobutoxy, printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes and notices on the back before filling out this page) 1-dimethylaminopropyl-2-yloxy, 3-dimethylamine Methylpropoxy, 2-dimethylamino-2-methylpropoxy, 2-diethylaminoethoxy, 3-diethylaminopropoxy, 1-diethylaminopropoxy, 2-diisopropylaminoethoxy, 2- (di-n-butylamino) ethoxy, 2-hexahydropyridineethoxy and 4- (di-n-octylamino) butoxy; M and An alkoxy group substituted with a dialkylaminoalkoxy group and having 4 to 20 carbon atoms such as dimethylaminomethoxymethoxy, dimethylaminoethoxyethoxy, dimethylaminoethoxypropoxy , Diethylaminoethoxypropoxy, 2- (2-dimethylaminoethoxy) ethoxy, 2- (2-diethylaminoethoxy) ethoxy and 4- (f-di Isobutylaminocyclohexyloxy) cyclohexyloxy. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -22-494275 A7 Η * 7 V. Description of the invention () MR!, R 2, R 3, R 5, Re and R 7 indicate, Examples of the aralkyl group having 7 to 20 carbon atoms which may have a substituent include benzyl, phenethyl, 3-phenylpropyl, 1-naphthylmethyl, 2-naphthylmethyl, 2-naphthylethyl , _Benzyl, 2-_ggmethyl, 4-ethylbenzyl, 4-cumyl, 4-tert-butylbenzyl, 4-tricumylethyl, tert-butylphenethyl Base, 4-tert-butylphenethyl, tolylmethyl, tolylethyl, 2,3-xylylmethyl, 2,4-xylylmethyl, printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please first (Please read the notes on the back and fill in this page.) 2, 5-Xylylmethyl, 2,6-Xylylmethyl, 2, 4,6-Trimethylol, 2-chlorobenzyl, 3-chlorobenzene Methyl, 4-chlorobenzyl, 2-bromobenzyl, 3-bromobenzyl, 4-bromobenzyl, 2-fluorobenzyl, 3-fluorobenzyl, 4-fluorobenzyl Methyl, 2-methoxybenzyl, 3-methoxybenzyl, 4-methoxybenzyl, 2-ethoxybenzyl, 3-ethoxybenzyl, 4-ethoxybenzene Methyl, 2-n-propoxybenzyl, 3-n-propoxybenzyl, 4-n-propoxybenzyl, 2-isopropoxybenzyl, 3-isopropoxybenzyl, 4-isopropyl Propoxybenzyl, 2-n-butoxybenzyl, 3-n-butoxybenzyl, 4-n-butoxybenzyl, 2-isobutoxybenzyl, 3-isobutoxybenzyl , 4-isobutoxybenzyl methyl, 2-third butoxybenzyl, 3-third butoxybenzyl, 4-third butoxybenzyl, 2,3-dimethylphenethyl , 2,4-dimethylphenethyl, 2,5-dimethylphenethyl, 2,6-dimethylphenethyl, 2,4,6-trimethylphenethyl, 2-chloro Phenethyl, 3-chlorophenethyl, 4-chlorophenethyl, 2-bromophenethyl, 3-bromophenethyl, 4-bromophenethyl, 2-fluorophenethyl, 3-fluorobenzene Ethyl, 4-fluorophenethyl, 2-methoxyphenethyl, 3-methoxyphenethyl, 4-methoxyphenethyl, 2-ethoxyphenethyl, 3-ethoxyphenethyl, 4-ethoxyphenethyl, 2-n-propoxyphenethyl, 3-n-propoxyphenethyl, 4-n-propoxyphenethyl, 2-isopropoxyphenethyl, 3-isopropoxybenzene Ethyl, 4-isopropoxyphenethyl, 2-n-butoxyphenethyl, 3-n-butoxyphenethyl National Standard (CNS) A4 specification (210X 297 mm) _ 23-494275 Λ? ΙΓ V. Description of the invention () 4-n-butoxyphenethyl, 2-isobutoxyphenethyl, 3-isobutoxybenzene Ethyl, 4-isobutoxyphenethyl, 2-tert-butoxyphenethyl, 3-tert-butoxyphenethyl, 4-tert-butoxyphenethyl, # -9-yl, 9- Methyl-9-yl, 9-ethyl-9-yl, 9-propyl-9-yl, and 9-butyl-9-yl. WR i, R 2, R 3, R 5, R s, and R 7 represent, and examples of the aralkyloxy group having 7 to 20 carbon atoms which may have a substituent include benzyloxy, phenethyloxy, 3-phenylpropoxy, 1-methoxy, 2-methoxy, 1-I: ethoxy, 2-ethoxy, benzophenoxy, 2-Mquinonemethoxy, 4 -Ethyl phenoxy, 4-cumene methoxy, 4-tert-butyl phenoxy, 4-cumene ethoxy, tertiary butyl phenoxy, 4-tertiary butyl phenoxy Oxygen, toluenemethoxy, tolueneethoxy, 2,3-xylylmethoxy, 2,4-xylylmethoxy, printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the note on the back first) Please fill in this page again for details) 2,5-xylylmethoxy, 2,6-xylylmethoxy, 2, 4, 6-xylylmethoxy, 2-chlorobenzyloxy, 3-chlorobenzene Methoxy, 4-chlorobenzyloxy, 2-bromobenzylmethoxy, 3-bromobenzyloxy, 4-bromobenzyloxy, 2-fluorobenzyloxy, 3-fluorobenzyloxy Methyl, 4-fluorobenzyloxy, 2-methoxybenzyloxy, 3-methoxybenzyloxy, 4-methoxybenzyloxy, 2-ethoxybenzyloxy, 3-ethoxyl Benzyloxy, 4- Ethoxybenzyloxy, 2-n-propoxybenzyloxy, 3-n-propoxybenzyloxy, 4-n-propoxybenzyloxy, 2-isopropoxybenzyloxy, 3-iso Propoxybenzyloxy, 4-isopropoxybenzyloxy, 2-n-butoxybenzyloxy, 3-n-butoxybenzyloxy, 4-n-butoxybenzyloxy, 2-iso Butoxybenzyloxy, 3-isobutoxybenzyloxy, 4-isobutoxybenzyloxy, 2-thirdbutoxybenzyloxy, 3-thirdbutoxybenzyloxy, 4 -Third butoxyphenoxy, 2,3-dimethylphenethoxy, 2,4-dimethylphenethoxy, 2,5-dimethylphenethoxy, 2, 6- Dimethylphenethoxy, 2,4, 6-trimethylphenethyl This paper is sized according to the Chinese National Standard (CNS) A4 (210X297 mm) -24-Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 494275 Β " 7 V. Description of the invention () oxy, 2-chlorophenethoxy, 3-chlorophenethoxy, 4-chlorophenethoxy, 2-bromophenethoxy, 3-bromophenethoxy Methyl, 4-bromophenethoxy, 2-fluorophenethoxy, 3-fluorophenethoxy, 4-fluorophenethoxy, 2-methoxyphenethoxy, 3-methoxyphenethoxy Base, 4-methoxyphenethyl Ethoxy, 2-ethoxyphenethoxy, 3-ethoxyphenethoxy, 4-ethoxyphenethoxy, 2-n-propoxyphenethoxy, 3-main network Yuben ethoxylate, 4-it oxybenzylacetam, Z-isoendoxybenzyl stilbene, 3-isopropoxyphenethoxy, 4-isopropoxyphenethoxy, 2-n-butoxyphenethoxy , 3-n-butoxyphenethoxy, 4-n-butoxyphenethoxy, 2-isobutoxyphenethoxy, 3-isobutoxyphenethoxy, 4-isobutoxyphenethoxy , 2-Third-butoxyphenethoxy, 3-tert-butoxyphenethoxy, 4-tert-butoxyphenethoxy ·, manganese-9-yloxy, 9-methylmanganese-9 -Alkyloxy, 9-Ethyl-9-yloxy, 9-Propyl-9-yloxy, 9-Butyl_-9-yloxy, 4-Nitrofluorenyloxy, 4 -Cyano 1i? Oxy, 4-ethyl ethyl ethoxy, 2,4-dimethyl ethoxy, 2,3-dimethyl ethoxy, 2,5-dimethylbenzyloxy, 2,6-dimethylfluorenyloxy, 3,5-dimethylbenzyloxy, and 2,4,6-trimethylbenzyloxy. MR i, R 2, R 3, R 5, R s and 17 indicate that examples of the alkylthio group which may have one or more substituents include straight fluorene, branched chain and ring having 1 to 20 carbon atoms Unsubstituted alkylthio groups such as methylthio, ethylthio, n-propylthio, isopropylthio, n-butylthio, isobutylthio, second butylthio, third butylthio, n-pentyl Thio, isoamylthio, 1,2-dimethylpropylthio, 1,1.-dimethylpropylthio, cyclohexylthio, eicosylthio, and 4- (third butyl ring) Hexyl) decylthio; alkylthio substituted with alkoxy and having 2 to 20 carbon atoms such as methoxymethylthio, methoxyethylthio, ethoxyethyl and 10- (2-decahydrofluorene Oxygen) This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) -25- (Please read the precautions on the back before filling this page) .1. Order 494275 Λ? Η * 7 V. Description of the invention () C7VC- * r ·· ^ · -t = 5-, ^ mi *; Alkylthio groups substituted with alkylthio groups and having 2 to 20 carbon atoms such as methylthiomethylthio, methylthioethylthio, Ethylthio ethylthio and 10-2 -decahydrosulfanyl) decylthio; M and be Amine-substituted alkylthio groups having 3 to 20 carbon atoms such as 2-dimethylaminoethylthio, 4-dimethylaminobutylthio, 2- (di-n-butylamino) ethylthio, 2-Hexahydromethylthio and 4- (di-n-octylamino) butylthio. MR i, R 2, R 3, R 5, R e, and R 7 represent, and examples of an aryl group having 6 to 20 carbon atoms which may have one or more substituents include an unsubstituted aryl group such as benzene Base, naphthyl, onionyl, radical, 1-based, furylmethylpentenyl (per ί I 1 eny 1), triphenyl, and phenanthryl ^ Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Or more alkyl-substituted aryl groups having 7 to 20 carbon atoms such as 2-tolyl, 3-tolyl, 4-methylbenzyl, 2, 3-xylyl, 2, 4-xylyl , 2,5-xylyl, 2,6-xylyl, 3,4-xylyl, 3,5-xylyl, 3, 6-xylyl, 2, 3, 4-trixyl , 2, 3, 5-trisyl, 2, 3, 6-trisyl, 2, 4, 5-trisyl, 2, 4, 6-trisyl, 3, 4, 5-trisyl , 2-ethylphenyl, propylphenyl, butylphenyl, hexylphenyl, cyclohexylphenyl, octylphenyl, 2-methyl-1 -naphthyl, 3-methyl-1 -fluorenyl, 4- Methyl-1 -naphthyl, 5-methyl-1 -naphthyl, 6 -methyl-1 -naphthyl, 7 -methyl-1 -naphthyl, 8 -methyl-1 -naphthyl, 1- Methyl-2-naphthyl, 3-methyl-2- 4-methyl-2-naphthyl, 5-methyl-2-naphthyl, 6-methyl-2-naphthyl, 7-methyl-2-naphthyl, 8-methyl-2-naphthyl Aryl, 2-ethyl-1-naphthyl and n-decaphalyl; aryl groups substituted with one or more alkoxy groups and having 7 to 20 carbon atoms (please read the notes on the back before filling (This page) The paper size applies to the Chinese National Standard (CNS) A4 specification (210X 297 mm) 494275 Η * 7 V. Description of the invention (such as 3-methoxyphenyl, 4-methoxyphenyl, 2, 3- Dimethoxyphenyl, 2,4-dimethoxyphenyl, 2,5-dimethoxyphenyl, 2,6-dimethoxyphenyl, 3,4-dimethoxyphenyl, 3,5- Dimethoxyphenyl, 3,6-dimethoxyphenyl, 2,3,4-trimethoxyphenyl, 2,3,5-trimethoxyphenyl, 2, 3,6-trimethoxyphenyl, 2 , 4, 5-trimethoxyphenyl, 2, 4, 6-trimethoxyphenyl, 3, 4, 5-trimethoxyphenyl, 2-ethoxyphenyl, propoxyphenyl, butoxyphenyl, hexane Oxyphenyl, cyclohexyloxyphenyl, octyloxyphenyl, 2-methoxy-1-fluorenyl, 3-methoxy-1-naphthyl, 4-methoxy-1-forbidden, 5- Methoxy-naphthyl, 6-methoxy-1 -naphthyl, 7-methoxy 1-1-naphthyl, 8-methoxy-1-naphthyl, 1-methoxy-2-naphthyl, 3-methoxy-2- »yl, 4-methoxy-2-naphthyl , 5-methoxy-2-naphthyl, 6-methoxy-2-fluorenyl, 7-methoxy-2-naphthyl, 8-methoxy-2-naphthyl, 2-ethoxy -1 -naphthyl and decahydrozeolyl; aryl substituted with one or more S atoms and having 6 to 20 carbon atoms such as chlorophenyl, dichlorophenyl, trichlorophenyl, bromobenzene ·, Dibromophenyl, iodophenyl, fluorobenzyl, difluorophenyl, trifluorophenyl, tetrafluorophenyl, pentafluorophenyl, trifluorotolyl, and 6- (perfluorodecyl) naphthalene Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Replaced by N-monoalkyl- or N_monoarylamino groups with 7 to 20 carbon atoms Aryl groups such as N-methylaminophenyl, N-ethylaminophenyl, N-decaphalyl, N-anilinephenyl and N-toluidinephenyl; N, N-dialkylamino, N, N- Diarylamino or N-arylalkylamino substituted aryl groups having 8 to 20 carbon atoms such as N, N-dimethylaminephenyl, N, N-diethylaminephenyl, N-phenyl -N- 甲Phenyl, N-tolylethylaminephenyl, N-chlorophenyl-M-cyclohexylaminephenyl, and N, N-xylylaminophenyl; substituted with alkylthio and having 7 to 20 carbon atoms Aryl groups such as methylthiobenzene The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) -27-494275 Λ? Η * 7 5. Description of the invention (), ethylthiophenyl, methylthiophene And decylthionaphthyl; M and aryl substituted with arylthio and having 12 to 20 carbon atoms such as phenylthiophenyl and naphthylthionaphthyl. MR !, R2, R3, R5, Re and R7, and examples of the aryloxy group having 6 to 20 carbon atoms which may have one or more fluorene substituents include 6 to 20 fluorene carbon atoms Unsubstituted aryloxy groups such as phenoxy, naphthyloxy, onionoxy,? > oxy, & oxy, furylmethylpentenyloxy, biphenyloxyl, and phenanthryloxy; printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling in (This page) Aryloxy substituted with one or more alkyl groups and having 7 to 20 carbon atoms such as 2-tolyloxy, 3-tolyloxy, 4-tolyloxy, 2, 3-xylyloxy Group, 2,4-xyloxy, 2,5-xyloxy, 2,6-xyloxy, 3, 4-xyloxy, 3, 5-xyloxy, 3,6 -Xyloxy, 2, 3, 4-trimethyloxy, 2,3,5-trimethylbenzyloxy, 2, 3, 6-trimethyloxy, 2, 4,5-trimethyloxy, 2 , 4,6-trimethyloxy, 3,4,5-trimethyloxy, 2-ethylbenzyloxy, propylphenoxy, butylphenoxy, hexphenoxy, cyclohexylphenoxy, octyl Phenoxy, 2-methyl-1-naphthyloxy, 3-methyl-1-naphthyloxy, 4-methyl-1-naphthyloxy, 5-methyl-1-naphthoxy, 6- Methyl-1-naphthyloxy, 7-methyl-1-naphthyloxy, 8-methyl-1-naphthyloxy, 1-methyl-2-naphthyloxy, 3-methyl-2- _Oxy, 4-methyl-2- «oxy, 5-methyl-2-fluorenyloxy, 6- Methyl_2-naphthyloxy, 7-methyl-2-naphthyloxy, 8-methyl-2-_oxy and 2-ethyl-1-naphthyloxy; one or more alkoxy Substituted aryloxy groups having 7 to 20 carbon atoms such as 3-methoxyphenoxy, 4-methoxyphenoxy, 2,3-dimethoxyphenoxy, 2, 4-dimethoxyphenoxy Base, 2,5-dimethoxyphenoxy, 2, 6-dimethoxyphenoxy This paper is sized for China National Standard (CNS) A4 (210X297 mm) -2 8-494275 Λ? B * 7 5 Description of the invention () group, 3,4-dimethoxyphenoxy, 3,5-dimethoxyphenoxy, 3,6-dimethoxyphenoxy, 2, 3,4-trimethoxyphenoxy Radical, 2, 3, 5-trimethoxyphenoxy, 2, 3, 6-trimethoxyphenoxy, 2, 4, 5-trimethoxyphenoxy, 2, 4, 6-trimethoxyphenoxy, 3,4,5-trimethoxyphenoxy, 2-ethoxyphenoxy, propoxyphenoxy, butoxyphenoxy, hexyloxybenzyloxy, cyclohexyloxyphenoxy, octyloxyphenoxy , 2-methoxy-butoxy, 3-methoxy-buttoxy, 4-methoxy-naphthyloxy, 5-methoxy-l-oxyl, 6-methoxy -1 ... naphthyloxy, 7-φoxy-bnaphthyloxy, 8-methoxy -1-naphthyloxy, 2-naphthyloxy, 3-methoxy-2naphthyloxy, 4-methoxy-2-naphthyloxy, 5-methoxy-2 -naphthyloxy Group, 6-methoxy-2-«oxy group, 7-methoxy-2 -fluorenyl group, 8-methoxy-2-tyloxy group and 2-ethoxy-bnaphthyloxy group; Aryloxy substituted with one or more halogen atoms and having 6 to 20 carbon atoms such as chlorophenoxy, dichlorophenoxy, trichlorophenoxy, bromophenoxy, dibromophenoxy, iodobenzene Oxy, fluorophenoxy, difluorophenoxy, trifluorophenoxy, tetrafluorophenoxy, pentafluorophenoxy, trifluorotolyloxy and 6- (perfluorodecyloxy) naphthyloxy; Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before writing this page) Aromatic oxygen substituted with N-monoalkyl- or N-monoarylamino group and having 7 to 20 carbon atoms Groups such as N-methylaminephenoxy, N-ethylaminephenoxy, N-deconaphthyloxy, N-anilinephenoxy and N-toluidinephenoxy; and N, N-dialkylamino, N, N-diarylamino or N-aryl-N-alkylamino substituted aryloxy groups having 8 to 20 carbon atoms such as N, N-dimethylaminephenoxy Ν, M-diethylaminephenoxy, N-phenyl-N-methylaminephenoxy, N-tolyl-N-ethylaminephenoxy, N-chlorophenyl-N-cyclohexylaminephenoxy And Ν, Ν-xylylamine phenoxy; this paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) -2 9-494275 Λ? ΒΊ Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 、 Explanation of the invention () 1 1 is substituted by mm group and M has aryloxy group with 75 i 2 0 carbon atoms such as methylthio 1 1 phenoxy Λ one: household 51 phenoxy, methylthionaphthyloxy and decyl sulfur Naphthyloxy groups M and 1 1 are substituted with arylthio groups and have an aryloxy group with 12 to 20 carbon atoms, such as phenylsulfide. * Ν Please read 1 1 phenoxy group and M thionaphthyloxy group. Read 1 I Back 1 M R 1 Λ r2 Λ r3, r5 Λ RG and R7 means that 5 deniers may have -1 or more arylthio groups having 6 to 20 carbon atoms in the 1 I group. Examples include phenylthio, i. Ί Item I 2-Tolylthio, 4-tolyl 51yl, 4-second butylphenylthio, 2-methoxydeca-tenbenzyl Re · Fill in the f 1 group • S 4-Second butylphenylthio and M " Thio. Pages K R 1, r 2 r 3 R 5 Re and R 7 represent 9 and may have one or more aryl groups having 2 to 20 carbon atoms. Examples include heteroaryl groups having 2 to 20 carbon atoms, including Pyrrolyl, 1 I Ν-methylpyrrolyl, 11-ethylpylamyl, N-propylpyrrolyl Λ N-butylpyryl 1 1 Retardant Λ Ν-iso-ylpyryl, N-iso Pentyl η 咯 rolyl, N-octylrolyl1, N-methoxymethylpyrrolyl, N-methoxyethylpyryl, N-ethoxymethylpyryl 1 < N-ethyl Oxyethyl m rolyl Λ H- methoxy methyl methyl pyrimyl Λ Ν- methyl 1 1 oxycarbonyl ethyl rolyl, Ν-ethoxy methyl methyl ηΆ rolyl Λ N- ethoxycarbonyl-m Ethylrolyl, N-ylrolyl, N-phenylrolyl, N-formyl Phenylpyridine 1 ϋ 基 m m m 喵 咯 m-m propyl methyrolyl, Ν-butyl pylyl yl-, N-pentamyl py lyl 1 1 yl, Ν-deca-JU, ylpyro yl yl Furylpyridyl., Fluorenyl 1 1 isofluorenyl, oxazolyl, isofazolyl, W4 azolylthiadiazolyl, 1 | mazolyl, benzo_azolylazobenzyl, benzo m azolyl Λ benzofuran 1 I ranyl and 丨 ° * -3 丨 -group 丨 1 1 Κ R 1, r2 r3 丨., R 5 丨, R 6 and R 7, represents 9 and may have one or Examples of a plurality of radicals having 2 to 10 carbon atoms of a 1 1 generation group include vinyl, 1-1 1 propimyl 2-propenyl, 1-butenyl 1 -pentenyl , 〇 一 .pentenyl, 3 1-1 1 This paper size applies to Chinese National Standards (CNS) A4 specifications (210X 297 mm) -30-494275 Β * 7 5. Description of the invention 7MQ group in carbamoyl and alkenyl chloride di I 2

Shown in Table 7 R and B ηκ 5 Dft 3 R 2 R ο Ethylene 3 cyanotriene in acetylene-learning 2,1b 2, sub-example Q ί Proton hydrogen including oxybutene I 2 and oxypropylene such as All radicals; radicals; radicals; radicals, radicals, radicals, 1 radicals, alkyl radicals, alkyl radicals, alkane, aryl aryl, aryl ^ 1, 2- 逑 逑 逑 逑逑 逑 There are 10 items before and after! IT — (Please read the notes on the back # .Fill in this page)

1, 1T-based Ministry of Economic Affairs, Central Standards Bureau, Consumer Cooperatives, printed amines, such as amines, substituted by the original carbon ο 1-f to *, a * -I group has an amine group Amine amine hexyl cyclohexyl Λ methyltriamine 5-hex 5 n 3, and the base 1K BaMM butylhexyl Λ ethyl

There are radicals and amines which take hydroxyl 2 hydroxyls, which are radically connected to WHO 2 radicals amines hexyl methyl ethyl hydroxy, such as the original carbons of allylamine alkyls. Substitute oxygen to take methyl, oxyalkylamine by methoxymethyl D ¢-all C-- based on the original carbon of BP alkane mono ο 1 to amine methoxyethylamine ethoxyethoxypropane paper size applicable to China National Standard (CNS) A4 specification (210X 297 mm) 3 1 494275 A. V. Description of the invention () Ethylamino and 2- (2f-ethylhexyloxy) ethylamino; with 2 to 20 carbon atoms Unsubstituted dialkylamino groups such as dimethylamino, diethylamino, di-n-butylamino, di-n-hexylamino, di-n-octylamino, di-n-decylamino, N-isoamyl -N-methylamino and H-hexahydropyridyl; hydroxy-substituted dialkylamino groups having 2 to 20 carbon atoms such as bis (hydroxyethyl) amino, bis (2-hydroxypropyl) Amino, bis (3-hydroxypropyl) amino and bis (1 0-hydroxydecyl) amino groups; alkoxy-substituted dialkylamino groups having 4 to 20 carbon atoms such as di (methyl Methyl) amino, bis (methoxyethyl) amino, bis (ethoxymethyl) amine, bis (ethoxyethyl) amine, dipropyloxyethyl) amine, bis (butoxy) Ethyl) amino and bis [2- (2 # -ethylhexyloxy) ethyl] amino; arylamines having 6 to 10 carbon atoms such as benzyl, 4-tolylamino, 2-methyl Oxyanilide, 4-n-propenylbenzyl and 4-tert-butoxyaniline; alkoxycarbonylalkoxy groups having 3 to 10 carbon atoms such as methoxycarbonylmethoxy, ethoxycarbonyl , N-propoxycarbonylmethoxy, isopropoxycarbonylmethoxy, and 4 5 -ethylcyclohexyloxymethoxy; printed by the Consumer Cooperatives of Employees and Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs- 丨 尔 衣 — 丨 (Please Please read the notes on the back * before filling out this page) Alkylcarbonylalkoxy groups with 3 to 10 carbon atoms such as methylcarbonylmethoxy, ethoxycarbonyl, and octylcarbonylmethoxy. Typical example of the substituent L in the chemical formula (4) represented by MR i, R 2, R 3, R 5, R s, and R 7 -N Η-L ί 4) includes a hydrogen atom; has 2 to 10 carbons Atoms of unsubstituted alkylcarbonyl such as ethyl alcohol, ethyl carbonyl: isobutyl carbonyl, cyclohexyl carbonyl and 3, 5, 5-trimethylhexyl carbonyl; this paper size applies Chinese National Standard (CNS) A4 specifications (210 × 297 mm) _ -32-494275 A. B " V. Description of the invention (Decafluoride and radical have ethyl and fluorinated tris, 2 tris, 2 subs, 2 originals, 2 halogens, 1 bases, or ethyl chloride. The original carbons of the children of the various carbonyls are 1 ο to 1-ί and the radicals have _ and _ are substituted for oxymethoxy, and the alkyl is ethoxylated, such as the original carbons of the children of various carbonyls. Τ—-i to And M carbonyl hexamethylene oxide tritriene carbonyl benzene, such as the children of carbonyl aryl, 5 1 to 7 have carbonyl phenyl phenyl carbonyl fluorenyl carbonyl phenyl phenyl isopropyl phenoxymethyl 4 ο R-based carbonyl naphthalene is oxygenated butyl compound 3 and the carbonyl group is not benzene-epoxy 5} / i \ benzene 7 or CO). 2 Λ ί Basic carbonyl aniline M methamine Ⅱ Ben? Λ ·, / Ν square, Guanyl cyano protohydrogen including the inclusion group of the alkyl group, the type of the alkyl逑 前 and M: 基 aryl fragrant or 前 r front or 2 formulas it ο Μ 明明 _ This II is issued at the front gate (please read the precautions on the back before filling this page) Central Standards of the Ministry of Economic Affairs Bureau's Consumer Cooperative Co., Ltd. Printing Example of Primitive Halane Codes & Description 2, 1u > -yzrr and the Substituted Hydrogenated Bun Group Substitute Table 5) Cyano Group The description of the pre-precursor group of oxy-arane; oxy .; The description of the pre-precursor oxyaryl of thioalkyl arane. January This paper size applies Chinese National Standard (CNS) A4 (210X 297 mm) 3 C0 494275 A? I ”V. Description of the invention () Arylthio group of the former fluorene; Heteroaryl group of the former fluorene; Heteroaryloxy group having 2 to 20 carbon atoms such as pyrrolyloxy , N-methyl-2, 3-dimethylpyrrolyl-4-oxy, N-butyl-2,3-dimethylpyrrolyl-4-oxy, Alkoxy, bisoxy, alkoxy and 1,2,3-oxadiazol-4-oxy; M and heteroarylthio groups having 2 to 20 carbon atoms such as pyrrolylthio, 1- Methyl_azolyl-2-thio, l-fluorenyl_azolyl-2-thio, thiazylthio, oxanthio, oxazolylthio, and thiazolylthio. Table 1 shows a typical example of the oholo methylene boron complex compound represented by the chemical formula (1), but the scope of the present invention should not be limited to these compounds alone. (Please read the note on the back _Impacts before filling out this page) The paper size printed by the Employees' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs applies the Chinese National Standard (CNS) Α4 size (210X 297 mm) -34-494275 Λ7 ΙΓ 5 Description of the invention (printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

(Please read the note on the back *-Matter # -Fill this page first) This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 35 494275

A Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

(Please read the note r on the back before filling this page), 1T This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 3 6 494275 A7 B1 V. Description of the invention Printed by a cooperative

• vj αι ω t ro rn ^ JL to —k rr aj; > ir 工 〇b 6 § c? 1 ο ο Μό ^ > = 〇 ° 5 CO 6 Ο c? 6 ro ^ ΟΙ ci L Oz J3 ό c? 6 c? rP c? 6 c? ό c? ό c? s ω 6 § | S ΓΟ 工 6 r〇io ro P c? ό c? CP 6 ①worker ω c? workmanship P_X 6工 II 〇c? ZLO Φ O J3 ό Worker 6 c? 6 c? 6 c? 6 c? II 〇 ro Worker 6 c? Ό c? 6 CO Worker 6 ό c? S ω c? C? 6 v 〇〇ό c? Ό 〇r > F 工 6 ο c? II 〇 V〇4 / ω 〇ό Workers / 〇o Workers Φ M <: ① 6 ο c? Ο7 Ύ 1 〇-rV \ 〇TO _N 8 c? / 〇6 1 3 Ρ 〇 / 6 oc? 8 CO 工 i 工 o M0 roN 谢 一 (Ila ------! -I (Please read the note on the back t- 事 # -Fill this page first )

、 1T This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 494275 A7 Βη V. Description of invention (printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs? —T ώ _k ω ω —i. GO CD z 00 Br n {> 6 ①work 6 c? 〇 work II 〇 work 0 work 1 ro ΤΙ I work 〇 〇ο 6 work II s N > ° b \ ZI ° b O 〇z work, o ro 6 work CO 6 § 1 N) H 1 / o Worker 6 N > Ol oc? Workers c? 〇 工 〇 一 Η ro 工 ϋΐ lO- ri ° 丨 Workers 1 ro 6 Workers ω 6; c? C? Workers工 〇-b ° b 6 工 II spc? 工 ό Ⅱ S ro 1 J3 6 c? 工 t〇r ① 6 CO worker 6; c? 6 c? 6 c? 6 CO worker c? 6 c? 6 2: \ 6 c? 6 c? Τι 6 Worker II Ο Worker 0 Worker 1 ro 6 c? Vo Worker z ό 6 c? 6 c? 6 c? 6 c? Ό c? Ό c? X 6 s > Q | oc? J3 $ 〇 person 1 1 〇 work ό < 0r① 1 〇 work ο ① i work o M0 c / fy / ^ CD ff CD work 6 ID 6 ω · / 〇JSJ 8 rg r? ro 1 〇工 ό = ro I ^ 0 " I 〇 工 ό Μ0 ο t ~ Qr CD oc? 6 oc? 6 oc? 6 1 〒 6 ω · / 〇roN Zhejiang 1 (difficult) (Please read the note on the back first Matters need to be re-filled_) This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 × 297 mm) 38 494275 A7 B1 V. Description of invention (printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs—L 〇1 -Jl 1 έ h _L 厶 o _L rf ·· • ir 6 c? 6 ro αι 6 c? 6 c? 工 6 c? 6 ro Ol 6 c? rP ό c? 6 cn ό c? 工 6 c? 6 c? rP c? · J3 工 工 r? 6 c? ό c? 6 c? ό c? 6 co 工 6 c? 工 6 c? c? 工 II Ο 孑! 6 c? ό 工 ό 〇ώ〇ό 工 ό c ό C0 工 ό CO 工 ό c? ό c? ό c? 工 ⑺ 工 6 c? c? 工 工 工 rP c? P c? 6 ro ^ cn 工 6 ro αι 6 r > ^ αι ό c? ό c? ό c? 6 co 工 6 co 工 ό c? 6 c? W 6 2 J) χό Μό &. 工 〇 / ό 6 ro ° c? 6 oc? ό P, 〇 工 cS Μό 〇ώ〇〇 JN ΊΠ o? Ro on ό 1 13 cP 6 I ro ^ 工 P c? Ro ^ 6 S co or〇N 浙 1. (_ ---------- • 衣 -I (Please read the back first Note * -Item # _Fill in this page) This paper size is applicable to China National Standard (CNS) A4 (210X 297mm) 3 494275 Λ7 B * 7 V. Description of Invention (Employment Printed by Cooperative

Λ Please read the note at the back 'and then _ fill in this page f. The paper size of the book is applicable to the Chinese National Standard (CNS) A4 (210X 297 mm) 4 0 494275 V. Description of the invention # 1 S σ > 1 s ^ JL deg 1 s ^ -JL άά 〇 t CD *-^ N ur 3]; > Mod. R 6 P c? 〇 / 1 ό ρ cF I 〇b \ 〇 (〇 〈I 6 P 工 II 〇6 〇ο c? § 〇 ① 工 6 c? 6 〇c? 6 〇. 工 CO $ 、 〇 \ 工 ό Ο c? 6 P cF 6 ο c? 6 ο c? R 6 c? 6 〇c? 工 c? 6 c? Ό c? 6 P c? Ό c? 6 2 工 c? 1 3 P j: 6 工 11 Ο 6 ZO ro ό β Workers c? Workers II Ο ό 工 6 z J3 6 c? 6 c? Ό 8 7 1 ό c? CO Ο c? 工 c? 6 c? Ό c? 工 Ο Ρ c? 1 1 8 c? Ό c? Ό ο cf c? 6 工 II Ο / Ον ro; δ Φ 6 c? cP 6 c? 6 c? ό 6 c? cf 6 〇. 工 o 〇 工 CO oc? ό ό ό " / CO ω _N 6 〇 c? 工 〇 / —yo ωΙ CO oc? 6 ο c? η ό 6 ο c? " Π roN 谢 1 ((藤) (Please read the note t ~ Matters # on the back first to complete this page)

This paper size applies to the Chinese National Standard (CNS) Α4 specification (210 × 297 mm) 41 494275 Λ7 Βη V. Description of invention

—L 'νΙ ΟΊ —L 1 —L * ^ 1 ω _L • ^ ι ro —L one —L 〇—L σ > CD CT ^ nj > 6 Engineering II 2 ro ZO 〇 ό 1 Engineering ο 〇ο ω " 6 〇ζ 1 ο ro Ο 〇Z 1 ho 工 〇 〇3 6 〇z oc? 工 rP 6 c? 6 c? 工 ό Ο c? RP ό c? 工 工 Ρ cF ό c? Ό c? Ν rx ό 〇ζ 1% 〇 /) 〇1 6 fo · cn ό ω * c? ό 6 ζ 工 6 工 II s ω ΙΟ 工 工 工 工 6 〇ω1 ό ο c? 6 ο c? 6 ο c? ό ο C0 工 ό 工 6 c? 6 ο c? Ό c? Ό c? Ό c? Ο CO 工 工 W 工 ό oc? 6 ο c? 8 ό ό c? Ό c? Ό c? / 8 〇 \ Έ 6 h 8 Μ \ 6 CO 工 ο 〇ζ 工 ο · 工 \ 〇 < ω Έ / 〇FV; S ω ω / ω Μ1 / ° -2 ^ ι ό k 〇1 (ζ ί \ 0) < ζ 1 ro 1] P j: \ ω < ω φ ~ Π JN \ 〇 〈ω ί 6 ο c? η 〇Η L ζ τι 1 13 P jz \ ω < 0) S φ " Π roN (Please read first Note on the back *-Matter 1 Fill out this page) This paper size applies to Chinese National Standard (CNS) Α4 specification (210 × 297 mm) 4 2 494275

A] V 5. Description of the invention (printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs § 1 S _L CO 00 5 _JL k —JL 1 s 1 2 -Λ. Ό 1 ω 1 FREE 1 Ο Ι Αι CD ΕΡ 'π > 6 ① 工 c? 6 c? Ό c? 6 c? 6 c? 6 ωω 6 c? Ό c? Ό c? 6 c? Ό II Ο 孑 ρ 6: 工 c cF 6 c? 6 rP c? 6 I ω W 6 ο c? ⑺ 工 工 ό ro spiritσι ο 8 ό r? η c? 6 c? 6 oc? 6 co workers 6 c? 6 c? ⑺ 工 1 令 1 1 1 Ο ω ό c? \ 〇 <, 〇① 6 ζ 工 6 ο ω 工 c? 工 工 工 ό 工 工 工 ό 工 工 工 J3 ac? 6 c? Ό ο c? 6 c? 6 c? 6 oc? Ro 6 Ρ αι 6 Ο c? 6 ο ic? \ 〇 < ο ή ① 6 Ρ Ι 6 ο c? c? P ό c? ό cF ό c? 6 c? 6 c? 6 rP cF 6 c? 6 oc? 6 c? 6 o co: 6 c? ό Ρ ΟΙ 工 ό Ρ W 6 c? ό c? ό c? ό c? ό Ic? 6 c? ο Ρ 工 6 c? 6 c? c? J3 1 8 δ 6 ο c? T | 1 8 Φ 1 o δ ό ό \ ω 〈〇ο / 〇 \ 〇 < 〇 < ζ ro \ ο < ζ β ro ω ο c? \ 〇 < 〇 < 〇i / ω _Ν 1 8 δ ό T | 1 8 Φ 1 8 δ 1 〇ό Λ ω 〈〇ο 〇F 〇 / * η \ ο < ζ ί ro ω ο 〇F \ 〇 < 〇 < 〇 I ΊΠ 涵 11 ^^ 衣-(Please read the note on the back t-- matter before filling in this page)

、 1T This paper size is applicable to China National Standard (CNS) A4 specification (210 乂 297 mm) 4 3 494275

Λ · \ V V. Description of the invention Table \ — / · 5 Or, as in the examples, the material can be combined into a chemical code φ, and the wrong boron statement is replaced by Asia 0. ¾ Prepare the second system step. Table 5 Μ can be learned by using The chemical compound M is combined with the compound M, and the compound H is compounded by the formula H or the compound of the compound H2.

Learning or

Physicochemical oxygen or air, using ridine, should be reversed, such as R7 and acid R vinegar, fluorine R5 three, or R3 acid, bromine r2 hydrogen, such as the acid in R1 Combined, the thing Kuiji /: 9 trans' {chemical oxygen quinone chloride M if available, the agent should react to produce b / Ί oxygen to continue to connect the boron halide and (Please read the precautions on the back first (Fill in this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs

⑼ The original RV bromine needs to be reached or depending on the ηκ daughter, the most common chlorine and the most protofluorine in the former, such as the original protohalogen are A and YD, as shown in the table above, and the »-* rj. Bonding Substitute This paper size applies Chinese National Standard (CNS) Α4 specification (210X 297 mm) 4 4

Η 494275 ί \! W V. Description of the invention () Furthermore, wake up to the present invention with the chemical formula < 2) or < 5), in which R 4 is a hydrogen atom two acetomethylene boron complex compound, but It is easily prepared according to another method, which comprises reacting the compound represented by the aforementioned chemical formula (7) with the chemical formula of M (1 0 丨): (10) wherein R i, R 2 and R 3 are as M As defined above, or the compound represented by Chemical Formula Π. 1) and Chemical Formula (1 2): (Please read the precautions on the back before filling this page)

c〇〇c2h5 (11) h5c2〇oc

FU

Η R〇

(12)

Ri Boron halide printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

Where R · 1, R2, R3, R5, Rg, and R7] are reacted in the presence of an acid such as hydrobromic acid, as described in M, and the reaction product is reacted with the following formula to obtain M 3) Compound represented by: R

(13) wherein R i, R 2, R 3, R 5, R S, and R 7 are as defined in M, such as a fluorine atom, a chlorine atom, or a bromine atom, and then, if necessary, a halogen atom bonded to a boron atom. 4 5 This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 494275 Λ? Β * 7 5. Description of the invention (

SU

Ji? I'J Xin Sr-type lysozyme, M _ use alcohol to dissolve alcohols, such as _ surface soluble amines in free or via _ soluble hydrocarbons to take Group II II, said hydrocarbon-soluble fragrant aromatics Shown in Table 4: ri is the base of M and Y. As in Z, its children are in the original Yuan, D $ Zhuziyuan and magnesium chloride 1 or magnesium bromide one: as shown in the original compound or Table 5 5 protons (1 original lithium or chemical protons or protons or \\\ 5 5 il is Μ and the meaning of the above, as in the 2 z, the gold source is like the virgin or the United States Λ0 ib bromine is the virgin or the proton Lithium or Jinziyuan original potassium potassium chloride and magnesium chloride (Please read the precautions on the back before filling in this page) and so on See the if the surface can be produced by the hair, the alkali, the hair, the answer should be the original or glossy

B, Health) U acid-producing fatty light trees, chemical agents, solid hair, Λ bow, including polymer base, composed of groups from lipid light trees, such as rfy asm picture 0

The structure of arropyridine is unique and has the characteristics of making S _ RP RP ’s temple free of ΛΕ A / 1 _ tree, and the bright and light hair of the "11 c MU / ir agent" can be used in combination to make it wrong. The Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs printed a basic and a light-to-light unit with a light-emitting package, and as a rule, the light-emitting shoots have the following characteristics: The only thing that is solid is the combination of light and light, such as chemical species, and so on. This is a small amount of oligomerization. Ο The tree-like matter mystery includes pre-co-encapsulation, its daughters and examples, and other things. # 之 合 混 脂 化 的 树 之 ， 知 鐽 物 习 双 聚 化 和 三 固 满 和 光 不 物 " Family poly _ _ Polyphenols of dimer tree, containing polyester packets, trees or fatty tallow oxygen , Aldehyde cyclolipids, tree melt lipids, ethanoic acid esters, chloroacetic acid, methyl, aliphatic fatty resins, amines, polyethoxylates, acid esters, and resins 、 Oxygen Polyester Silicon Paper Standard Applies to Chinese National Standards (CNS) Specification A4 (210X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 494275 Λ7 B * 7 V. Description of the invention () The wax composition of these resins on M and its photopolymerizable unsaturated group Compounds containing modified resins containing two of these resins on M. Examples of photopolymerizable unsaturated groups B include acryl, methacryl, vinyl, styryl, propyl, Cinnamon, cassia and azide.

Regarding the precured resin (A), monofunctional and polyfunctional (meth) propionic acid esters are commonly used, and examples of the photocurable tree include anionic having a (meth) acryl group as a photosensitive group. Light-curing resins, light-curing resins having a cinnamon group as a photosensitive group, and light-curing resins having an allyl group as a charge-sensitive group 5 These are disclosed in Japanese Patent Laid-Open Application No. 2 2 3 7 5 9 / 1 9 9 1 Z The description is given in the paragraph on the bottom right of page 2 on line 6 to the bottom left of page 6 on line 16. The photo-curable resin (A) K is preferably used in combination with any of the photo-radical polymerization initiators mentioned below. These photocurable trees (A) may be used alone or in the form of a mixture thereof. It is also possible to use polyethylene glycol bis (methyl) propionate having a molecular weight of 300 to 100 as a typical example of an ester compound of an aliphatic polyhydroxy compound and an unsaturated carboxylic acid. This unsaturated carboxylic acid The acid is referred to as the ethylenically unsaturated compound of the photocurable resin component (a 2) in the rhenium announcement. Regarding the front-filling curing resin (A), in addition to the front-filling compounds, it can also be used by, for example, polymerization, etherification, pinacol (P inac) recombination, silanol dehydrogenation, intramolecular dehydration condensation, or Hydrolytic condensation reaction is a compound obtained by curing (making insoluble) in the presence of an acid as a catalyst generated from a photoacid generating surface. Examples of these compounds include propylene oxide type epoxy compounds such as bis (A) type diglycidyl ether, (poly) ethylene glycol diglycidyl ether, and this paper applies Chinese National Standard (CNS) A4 specifications ( 210X 297 mm) —47-(Please read the precautions on the back before filling this page).

1T 494275 Λ? B * 7 V. Description of the invention () Trimethylolpropane diglycidyl ether; wax ring epoxy compounds such as 3, 4-epoxycyclohexylmethyl-3,4-epoxycyclohexyl Alkane carboxylate, dicyclopentadiene dioxide, ethylene glycol cyclohexene fluorenate, and ethylene glycol _ and 1, 3-bis [2- {3 (7-acyclobicyclo [4, ls0] heptyl) } Ethyl] tetramethyldisilaxane [see J * Polym. S c 1.? Part A, ο 3 y is. C he in., V o 1 * 2 8, p, 4 7 9, ί 1 9 9 0)]

Ethyl ether compound_such as butanediol divinyl ether, trimethylolpropane di-U-propenyl) methyl ether, trimethylolpropane di- (1-propenyl) butyl ether, three Methylolpropane di- (1-propenyl) octyl ether, trimethylolpropane di- (1-propenyl) phenyl ether, trimethylolpropane di- (1-propenyl) ether acetic acid®, Trimethylolpropane di- (1-propenyl) ether acrylate and trimethylolpropane di- (1-propanyl) -n-butyl carbonate [see J, Polyin, Sci ... Part A, Ρο iym C hem,, V o i., 3 4, p, 2 0 5 1, (1 996)] »'M Printed by the Consumer Cooperatives of the Central Standards Bureau, Ministry of Economic Affairs (Please read the notes on the back before filling out this page ) Oxypropadiene compounds such as dodecylpropadiene (DA), diethylene glycol dipropadiene (DEGA), triethylene glycol dipropadiene (TEGA), 1-tetrahydrofuran methylpropadiene Difficult (THFA, n-hexyloxy-1,2-propadiene (HA), 1,4-di-n-butoxy-1, 2-butadiene (DBB), 1,4-diethoxy-1 , 2-butadiene and n-hexyl lisocaine ether (HPPE) [see J + Polyi Sci ,, Part A, Polyia · Chem., Vol, 33, p * 2493, (1995)]; propylene oxide compounds such as 3-ethyl-3-phenoxymethyl propylene oxide, phenoxymethyl propylene oxide, methoxymethyl propylene oxide, and 3-methyl-3-methoxymethyl propylene oxide [see J, Ρ ο 1 y in * S c ί ♦, P 3 rt A, ρ ο 1 ym * C he in ♦, V ο 1 ♦ 3 3 , p ♦ 1 8 0 7, Π. 9 9 5)]; ene-fluorene I aldehyde compounds such as 2-propylene-4, 5-dimethyl-1,3-dioxolane, 2-propylene 4-methyl-1,3-dioxofluorenyl and 359-dithiapandi-((^ 1 ^ 111 (^! ^)-2,4,8,10-tetra_11 [5 + 5] This paper size applies to China National Standard (CNS) A4 (210X297 mm) _ 48-494275 ΙΓ 5. Description of the invention () Eleven roasts [see Polym * Sci ·, Part A, Polyin * Cfiei »*, V ο 1. 3 4, p, 309 1 U 9 9 6)]; bicyclic proto-substance compounds such as 1-phenyl-4-ethyl-2,6,7-trifluorenebicyclo [2,2 * 2] octyl Alkane [see 夂? 〇] ¥ er ·

Sc ί., Polym, Lett, Ed ,, VOL 23, ρ.359, Π985)]; lactone compounds such as propiolactone, butyrolactone, 7-valerolactone, 7-caprolactone, 7- Caprolactone, 7-laurolactone and coumarin; aromatic vinyl compounds such as methoxy-σ »methylstyrene; heterocyclic vinyl compounds such as vinyl panzole; melamine compounds such as hexamethylol melamine And hexamethoxymelamine; copolymers of p-vinylphenol and p-vinylbenzyl acetate; M and other aromatic compounds such as trimethylolbenzene and tris (acetoxycarbonylmethyl) benzyl. These compounds may have a polymer structure as long as they can be cured with an acid proton. It is also possible to use a polymer that can be cured (insoluble) by polymerization or polycondensation under the catalysis of a base generated from a photobase generator, for example, a compound having at least one functional group such as an epoxy group or a silanol group. Compound. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). Except for the former, it can be cured under the catalysis of the acid or alkali produced by the photoacid generator or photobase generator. In addition to "Combination", conventional resins without unsaturated groups can be blended as needed, and examples of these resins include acrylic acids: resins, ethyl resins, polyester resins, alkyd resins, epoxy resins, Age resin, rubber and urethane resin. Regarding the photoreactive initiator (B) which can be used in the present invention, a photoradical polymerization initiator, a photoacid generator, and a photobase generator can be used. As the photoradical polymerization initiator, a known compound can be used. Examples of these compounds include aromatic carbonyl compounds such as benzophenone and benzoin. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) _ — 494275 5. Description of the invention () Methyl _, benzoin Propyl noodles, benzyl groups, xanthine, sulfur, and onion quinone; acetophenones such as acetocyanine, propylbenzene 11, d-hydroxyisobutylbenzene, α ^ dichloro-4 -Phenoxyphenethyl I, 1-hydroxy-1-cyclohexylacetophenone and diethyl acetophenone; organic peroxides such as benzophenoxide, third butylperoxy-2-ethyl Hexanoate, third butyl hydroperoxide, di-third butyl diperoxybutyl diperoxy isophthalate, and 3,3,4,4 tetrakis (third butyl peroxycarbonyl) ) Dibenzoyl; diphenyl halide || Salts such as diphenyliodobromide and diphenyliodochloride; organic halides such as tetrabromomethane, chloroform and triiodomethane; heterocyclic and polycyclic compounds such as 3 -Phenyl-5 -isohydroxycoumarin and 2,4, 6-ginsyl (trichloromethyl) -1,3,5-Sanka benzo, kao, azo compounds such as 2, 2 coupling Nitrogen (2,4-dimethylvaleronitrile) , 2,2-azobisisobutyronitrile, 1,1 f-azobis (cyclohexane-1-nitrile), and 2,2 ^ azobis (2-methylbutyronitrile); iron-aromatic Hydrocarbon complexes (see European Patent 〇〇, 1 2 5 3 7 7); dicyclopentadiene iron compounds (see printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs of the Japanese Patent Publication Application (please read the precautions on the back first) (Fill in this page again) Application Nl22] 110/1988); bis-azole compounds; N-aryl epoxypropyl compounds; acridine compounds; a combination of aromatic and aromatic amines; See Japanese Patent Laid-Open Application No., 321895/1994 >. Among the former radical photopolymerization initiators, di-peroxy isophthalate di-third butyl ester, 3, 3, 4, 4, 4-( The third butyl peroxycarbonyl) dibenzoate, iron-aromatic hydrocarbon complex, and dicyclopentaerium are preferred because of their high activity for cross-linking or polymerization. Furthermore, photoacids generate The agent is a compound capable of generating an acid through exposure, and using the generated acid as a catalyst M to be compounded before curing. As the photoacid generator, a conventional compound can be used. Examples of acid generation terms The paper size of this paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -50-494275 Λ7 ΙΓ 5. Description of the invention () Iron salts such as 槺 J salt, ammonium salt, osmium salt, please Salts and sulfonium salts, fluorene-aromatic hydrocarbon complexes, delta silanol-gold chelate complexes, tripartite compounds, diazide sulfonium compounds, sulfonates, and sulfonium imines. In addition to the former compounds, the photoacid generators mentioned in Japanese Patent Laid-open Application No. 4 65 5 2/1995 and Japanese Patent Application No. 289218/1997 can also be used. In addition, photo-alkali-producing blue is a compound that can generate a base through exposure, and using the generated base as a catalyst, M cures the compound before curing. As for the photobase generator, conventional compounds can be used. Examples of the photobase generator include a benzylcarbamate compound such as [(o-nitrobenzyl) oxy] carbonylcyclohexylamine [see J * km. Chem. S oc,, V ο ο. 113, No. 11 , ρ. 4 3 0 5 (1 9 9 1)] and photofunctional urethane compounds such as N-[{1-(3, 5 -dimethoxyphenyl) -bumethylethoxy} carbonyl] ring Hexylamine and (3,5-dimethoxyphenyl) -1 -methylethoxy} ore group j η 定 L See J · 0 rg · C he π ·, V ο 1.55, No, 23 , Ρ. 5919, (1 990)] 〇 The blending ratio of the photoreaction initiator printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs is not important, and it can comply with the type of the photoreaction initiator in a wide range. Variety. ——In general, the amount of the photoreactive initiator is in the range of 0.1 to 25 parts by weight relative to 100 parts by weight (solid content) of the photocurable resin, and M0.2 to 10 parts by weight is preferred. If the amount of the photoinitiator is more than 25 parts by weight, the stability of the resulting composition tends to deteriorate. The visible-light-curable resin composition of the present invention includes at least one of the two compounds represented by the chemical formula (1), which is a photosensitizer (C), and may include another conventional photosensitizer. 5 1 (Please read the precautions on the back before filling in this page) The paper size applies the Chinese National Standard (CNS) A4 specification (210 × 29? Mm) 494275 ΙΓ 5. Description of the invention () There is no special for the known photosensitive surface It is limited as long as it is BP usually used, but examples of the photosensitizer include _coumarin, coumarin-6 and coumarin compounds mentioned in Japanese Patent Laid-Open Application No. 18088/1992. In this case, there is no particular limitation on the amount of the dipyrromethene complex compound represented by the chemical formula (1) in the photosensitizer (C), but in order to obtain the desired effect in the present invention, the chemical formula U) represents Second, the content of the pallylene methylene boron complex compound in the photosensitive term (C) is preferably 10% by weight M, more preferably 20% by weight M, and 30% by weight M. Particularly preferred is a photosensitizer containing 50% by weight of the bis-methyleneboron complex compound. The amount of photosensitive surface (C) used depends on the type and quantity of photosensitive (C) and the type of light-curable resin (A) components that can interact with photosensitive surface (C), but in general, photosensitizers The amount of (C) is suitably within a range of 0 "to 10 parts by weight with respect to 100 parts by weight of the photocurable resin (A), and M 0.3 to 5 parts by weight is preferable. If the amount of the presensitizer (C) is less than 0.1 part by weight, the photosensitivity of the resulting coating film tends to deteriorate, and if it is more than 10 parts by weight, it may be difficult to make the composition from the viewpoint of solubility. The tendency to stay in a uniform state. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). If necessary, the visible light-curable resin composition used in the present invention may contain photopolymerizable unsaturated compounds in addition to the aforementioned ingredients ( Resin). Examples of the photopolymerizable unsaturated compound include methyl (meth) acrylate, ethyl (meth) acrylate, butyl (meth) propionate, 2-ethylhexyl (meth) acrylate, and poly Ethylene glycol di (meth) acrylate, (poly) propylene glycol tri (meth) acrylate, trimethylolpropane tri (meth) propionate, glycerol tri (meth) acrylate, .isopentyl Tetraol tetra (meth) acrylate and isopentaerythritol tri (methyl) The paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) -52- 494275 Λ · Η · 5. Description of the invention ( Grouped in a pair of phasor to make it 1b and incomplete. Poly_talene photoacid has a better total weight than the inner range. It is heavier than the inner range. 5 to ο. Hundreds of weight ο 4 Seeing that the defense can be combined with the materials used in D}] h (D Protection _ Conservation basicization can be protected by protection and self-protection can be made, self-required-must be mixed, the material will be made into hair Metamorphosis in the form of fixed light formation The solid layer is based on the base of light, which can be produced by the freely-born, and the photochemical effect can be seen when the light is solidified. _ The thin photo layer is a good and sensitive layer that is prevented by the application of corrosion.}: D 涂 ί ' Under the protection of protector base, in the existing II oxygen, in the system is clearly selected to make the ring of aromatic cocoa carbon to form the base amine amine two methylated N -One Ν, the rarest thing to combine fbib _ group of the acid aromatic phosphine from the original shot by the photo-oxygen by 5 and then, the basic oxygen from the self-existing oxygen such as, as Zhongcheng The material tree should form a counter_ oxygen tree and the 1b base solid from the light can be born in the place of production to live in the land without base from 0 because of the matter-zygote chemical protection oxygen base as the basis for self-reaction Therefore, the other often pass.

Mingfa's receipts Λ:., / 丄 · 'in the deposit D (please read the precautions on the back before filling this page). The self-testing of the former division of the base by oxygen can be inferred from others and should be based on others.

Oxygen will not be sensitive to the high and hold it, the fruit should be able to settle. The object should be in the opposite group. B. JJB. The solidifying layer of the solidified film of the tree can be seen by the coating. _ Alkyl ethanedioic acid, phosphoric acid 0 sub-groups, including esters, two examples of acid-type phosphoric acid, sub-groups, chemical compounds, alkyl alkanoic acid, aryl phosphite, and alkyl prearyl diesters, hexyl ethyl group Fangsanjijiyao (2 bis-bisacid acid phosphite butyl ester 1C diacetate phosphorus phosphite, and ester ester malonate diphosphonic acid phosphine sub-paper) The paper standards are applicable to Chinese national standards ( CNS) A4 size (210X 297 mm) 494275

Λ.) V. V. Description of the invention (, Phosphorus acid trimethyl ester, phenylphosphine tricarboxylic acid, o-ester ethylene, tribasic acid triphosphine triphosphite, trimethoate trimethoate, trimethoate Three such as phosphorous acid subunits of tris; 4 * ~ ί ester ginsenoacetic acid diphosphine i-tr and acyl phosphate decyl isocyanate three esters such as aryl sulfonate di 丨 aromatic acid ginseng phosphorous acid; Phosphorus 丨 Methyl and M-alkyl alkanoyl phosphonates Ethyl chloride ί 2/1% Phosphoric acid Phosphorus and Ethyl fluorotris I 2 Carboxylic acid diaryl N-N, The child is the original ring of the original carbons Aromatic amines form phenyl groups to methyl double bond N groups. N amines include dimers I 9 N mw N, which are preformed amines, anilide phenyl N, bis' methyl, and dienamine N. -Ethylbenzene N, subunit £-·-Φ group 4 7 4 I Η three,, the second amine (N 4-phenylbis, methylaminotolyldiene N- · -ί > 4 methyl N, one 1/4 1 group, Ν 芍) t propyl δ Ta ^ bromobis s 1 1 group 4 6 —, methyl, 2 dibismethylimine phenyl methyl pentamidine, hydrazine, group N π pyridine hru) 2 /.ί. -Base 4 methylamine V benzene N, methyl T m-propyl propyl isoprene N amine phenyl nitrite (Please read the precautions on the back before filling this page) The coating of the ring can be formed by anti-corrosion The bond and bond have T capacity, the basic phase looks at the origin of the second lipid point N-tree view N, and the layered amine coating sensitized phenyl sensitization of the protection of the nail and light two see N-, can N, which (Pair)-the quantum fraction of the original carbon fb family aromatics of the thin film nitrogen thin film ο ο 4 to ο 2 IX with a methylamine dijiajia special printing for the chemical protection of the employees ’cooperatives of the Central Standards Bureau of the Ministry of Physics and Economics Front

3X β > spoon & grid 0 without parallel mixing and / or DS strong and -amount 1 and similar '' * spoon 0 t β rc. · --- Bow _ should be a thin reflective layer of anti-corrosion to prevent damage to the place, so Lankou can be used as one. ， Ib system changes i part in 30 pairs to HM ο gl amount, f of the amount) ([) contains _ the combination of solidification of the protection and protection of the basic group from the fat from the tree f ic / ΛΊ on the solid and better brightness Weight ο 11 to acceptable weight S § 0 Some 1 person plus Chinese material into a group of fat tree 1b Fix light and easy to read, can be better than the internal standard of this paper. Chinese national standards apply (CNS) A4 specification (210'〆297 mm) 54 494275 Λ? Β " 7 V. Description of the invention () Add Seoul. Examples of additives include adhesion-improving surfaces, polymerization-inhibiting surfaces such as hydroquinone, 2,6-di-third-butyl-p-cresol or N, N-diphenyl-p-phenylenediamine, rubber, organic resins such as vinyl polymers Or particles of ethylenic polymer with unsaturated groups, pigments such as colored pigments or extenders, metal oxides such as cobalt oxide, plasticizers such as dibutyl phthalate, dioctyl phthalate, tricresyl phosphate _ Esters, polyethylene glycol or polypropylene glycol, shrinkage inhibition_ and fluidity regulators. The front adhesion improving agent is mixed to improve the adhesion of the coating film to the substrate, and examples of the adhesion improving agent include tetrazoles such as tetrazole, 1-phenyltetrazole, 5-aminotetrazole, 5- Amino-p-methyltetrazole, 5-amino-2-phenyltetrazole, 5-fluorenyl-1-phenyltetrazole, 5-weilyl-1-methyltetrazole, 5-methylthiotetrazole And 5-chloro-1-phenyl-1H-tetrazole. The composition of the present invention can be used under the irradiation environment of a safety lamp having a high spectral luminous efficiency and a maximum wavelength selected in the range of 500 to 620 nm. When the composition is used under the safety lamp, the absorbance of the unexposed coating film formed by the composition is 0, 5 Μ within the maximum wavelength of the safety lamp, 30 milliliters of rice. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). For the known safety lights, the red fluorescent lamp has been used, but the emission spectrum of the fluorescent lamp is in the ultraviolet range. A wide range of wavelengths from light to visible light (Figure 5). Therefore, this fluorescent lamp may even cure a part of the visible light-sensitive resin coating film which does not need to be cured, so that it is impossible to form any clear anti-corrosion coating through the development process. This disadvantage can be compensated by reducing the light intensity, but it can cause dark and inconvenient working environments. On the contrary, the present invention uses, for example, a nano lamp with a distinct wavelength as a safety lamp. Therefore, this paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) _ 5 5-494275 Λ7 V. Description of the invention () It can solve the previous problem. In other words, the safety light used in the present invention has visible light of the highest wavelength in the range of 500 to 620 millimeters, preferably with a high spectral luminous efficiency of 5 to 0 to 600 nanometers. This safety lamp can be obtained, for example, by using a discharge lamp, in which light having a maximum wavelength in the range of the former can be emitted by discharging the lamp itself in a gas such as sodium. Among various discharge lamps, sodium lamps have excellent safety properties, working environment properties, and the like. Since the light emitted by the nano lamp is mainly composed of yellow D-rays having a wavelength of 589 milliliters and it is monochromatic light, Therefore, the chromatic aberration of light is low, and thus the object can be clearly displayed. Circle 1 shows the spectral distribution of the low-pressure nanolamp. As shown by the spectral distribution circle of the sodium lamp, in addition to the maximum wavelength of D-rays of the sodium lamp, the safety lamp may have a high-energy ray wavelength component (short wavelength range) to the extent that it does not adversely affect the visible light sensitive resin composition. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). Alternatively, the light emitted by the sodium lamp equipped with a filter can be used as a safety lamp. The high-energy ray wavelength components are cut off. The spectral distribution of a nano-lamp with a high-energy ray wavelength component cut off is shown in FIG. 2. Examples of filters include $ Fantac FD-1081 Scarlet "-" F antac FC-1 4 3 1 S unf 1 ower Y e 1 1 ow 〃 < both are registered trademarks, see by Kansai Pain t Co ,, L t · manufactured), and "L i? itech I, um ί o ο o I film No * 1 905 " (registered trademark, manufactured by Lintech Co * L td · destroyed I 0 In addition, The strong monochromatic light used in the present invention is 589 milligrams of strong monochromatic light, such as light from nano lamps, but can be used in addition to light having a maximum wavelength in the range of 500 to 620 millimeters meter. Contains the paper scales distributed in the UV template. Applicable to China National Standard (CNS) A4 specifications (210X 297 mm) -56-494275 Λ? ΙΓ 5. Description of the invention (), visible light range or infrared light range except for the former range A safety lamp having a wavelength component in a wavelength range. However, when a safety lamp containing a wavelength component distributed in any of these other ranges is used, the wavelength distribution range needs to be such that it does not adversely affect the visible light-sensitive resin composition. (Sensitization effect) Safety lamp range This safe high-energy light wavelength range (low wavelength range) is related to the light distribution energy intensity and the absorbance of the visible light sensitive resin composition within this range. When the light energy intensity is high, a low absorbance can be used Composition, and when the energy intensity of light is low, a composition having a much higher absorbance than the former can be used. In view of the requirements such as ft5, the safety lamp may contain high-energy light to the extent that it does not adversely affect the visible light-sensitive resin composition However, ordinary fluorescent lamps with a maximum wavelength of 500 to 620 millimeters cannot be used as a laser light sensitization for visible light lasers with an oscillation line specifically tied to 488 millimeters or 5 3 2 millimeters. Safety lamps for visible light curable resin compositions, because this type of fluorescent lamp has a high light energy below 500 millimeters, especially between 400 and 499 milliliters. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (Please read the precautions on the back before filling this page.) The formula of the absorbance defined in the present invention is expressed as 5 where I is the penetrating resin that will cure visible light. The composition is coated on the surface of a transparent substrate and then dried (remove the dissolved surface > the light intensity of the coating film formed; and I. is transmitted through the blank [coating sample (photosensitive resin composition) thereon) Transparent substrate (such as polyethylene terephthalate sheet)] light intensity. The degree of brightness that can be perceived by the human eye can be expressed by the M-spectrum luminous efficiency. As defined in JIS ZZ8113-2005, this spectral luminous efficiency can be defined as when the brightness of monochromatic light with a wavelength λ is judged to be equal to the Chinese national standard (CNS) Α4 specification (210 × 297 mm) -5 7-494275 A7 B * 7 V. Description of the invention () When comparing reference light, the reciprocal of the pairing value of the radiant intensity of the monochromatic light with a wavelength of λ, and can usually be defined It is a normalized value such that the maximum value becomes 1 when the wavelength λ is changed. Fig. 3 shows a spectral luminous efficiency curve in the range of 380 to 780 milliliters of liquid length in visible light. In Fig. 3, the ratio of the spectral luminous efficiency is shown assuming that the maximum value of the spectral luminous efficiency on the vertical axis is 100. From this curve, it can be clearly seen that the spectral luminous efficiency is low in the range of 640 to 780 milliliters of the conventional red wavelength range, which is perceived by the eyes as dark, and for example, for the human eye to perceive With the same brightness at a wavelength of 589 nm, the intensity of the irradiated light must be further increased. The maximum value of the luminosity is about 555 milliliters (JIS-Z8113 2008). The maximum wavelength of the unexposed coating film formed from the visible light-curable resin composition of the present invention has a maximum wavelength of a safety lamp selected within the aforementioned range. The maximum wavelength is 30 milliliters (-30 milliliters to +30 milligrams). A maximum wavelength of 20 millimeters of rice (-20 millimeters to +20 millimeters of rice) is preferred, or a maximum wavelength of 10 millimeters of soil (-10 nanometers to +10 millimeters of rice) is better. The degree is (K5M, MCK2M is better, 0.1M is better. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). Made of the visible light curable resin composition of the present invention. The thickness of the formed dry film (excluding the solvent) is set so that the maximum wavelength of the non-sensitized coating film formed by this composition _ selected in front of the maximum wavelength of the safety lamp is within the range of ± 30 millimeters The absorbance in the range can be (). 5 M, but from a practical point of view, it is usually within the range of 0.1 to 50 metric meters, and K1 to 30 mold rice is preferred. Furthermore, the absorbance depends on the Photoreactive initiator (B), photosensitizer (C), etc. in the composition It depends on the type and quantity, and the same paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) _-494275 A7 V. Description of the invention () (Please read the precautions on the back before filling this page In the case of the material, it also depends on the thickness of the coating film. In other words, in the same composition, when the thickness of the coating is increased, the photoreactive initiator (B », photosensitive As the concentration of the agent (C) and the like increases, the absorbance increases. On the other hand, when the thickness of the coating film decreases, the concentration of the plutonium component before being contained in the coating film decreases, so the absorbance decreases. As explained by the previous paragraph It is clear that the absorbance can be adjusted to be within the range of the coating thickness by adjusting the thickness of the coating layer to be formed. The visible light-curable resin composition of the present invention can be used as a known photosensitive material in various applications. Such as coating composition, ink, adhesive, anti-corrosion coating materials, printing plate materials (printing materials for lithography and copiers, and pre-sensitized plates for lithographic printing), information recording materials And materials for imaging the convex plate. Next, a typical anti-corrosion coating material of the visible light-curable resin composition of the present invention (for example, a general negative-curing anti-corrosion coating material and a negative-curing material for power deposition coating) will be described. Anti-corrosion coating material). General negative-cured anti-corrosion coating material 5 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. For example, the visible light-curable resin composition of the present invention is dispersed or dissolved in a solvent (including water) (in In the case of using a pigment as a tinting pigment, the pigment is dispersed by fine mold), and thus a photosensitive solution is prepared, and the photosensitive solution is coated on a substrate using a coating device such as a roller, a roll coater or a spin coater, and then In addition, the surface of the coating film may be covered with a covering coating layer in advance before being cured by exposure to visible light. The purpose of forming this covering coating layer is to cut off oxygen in the air, to prevent the free radicals generated by exposure from being deactivated by oxygen, and to smoothen the coating film through exposure and curing. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -59-Printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 494275 Λ7 B * 7 5. Description of the invention () Covered by M polyester resin such as polyethylene terephthalate, acrylic acid resin, polyethylene resin, polyvinyl chloride resin, etc. (film thickness = about 1 to 70 mold meters) 5 至 The coating film is formed on the surface of the coating; or by applying an aqueous solution prepared by dissolving or dispersing the aqueous tree I in water on the surface of the coated coating film (dry film thickness = about 0.5 to 5 microns), and then dried to form. In this case, examples of the water-based resin include polyvinyl alcohol, a partially saponified compound of polyvinyl acetate, a copolymer of polyvinyl alcohol and vinyl acetate, a partially saponified compound of polyvinyl acetate, and a copolymerization of vinyl acetate Polymers, polyethynylpyrrolidine, water-soluble multi-brew polymers such as starch polymers (P u 1 1 u 1 a η), and acrylic resins containing basic groups, acidic groups or bases, polymers Ester resin, vinyl resin and epoxy resin. This cover coat layer M is preferably removed after the coating film is exposed and before the development process. This coating layer of the water-soluble polymer or water-based resin can be removed, for example, by using a solvent such as water, an acidic aqueous solution or an alkaline aqueous solution which can dissolve or disperse the resin. Examples of solvents that can be used to dissolve or disperse the visible light curable resin composition include noodles (eg, acrylic, methylethyl and methyl isobutyl ether!), Esters (eg, ethyl acetate, butyl acetate, benzene Methyl formate and methyl propionate), ethers (for example, tetrahydrofuran, dioxane, and dimethoxyethane), cellulosic term ί For example, methylcellulose, ethylcellulose, and diethylene glycol _Monomethyl ether), aromatic hydrocarbons (for example, benzene, toluene, xylene, and ethylbenzene), halogenated hydrocarbons (for example, trichloromethane, trichloroethane, and dichloromethane), alcohols (for example, ethanol and benzene) Methanol), other solvents (such as dimethyl methylamine and dimethyl arylene), and the size of this paper is applicable to China National Standard (CNS) A4 specifications (210X 297 mm) 1 _ -------- --- Feng II (Please read the precautions on the back before filling out this page) Order 494275 A " B " V. Description of the invention The share of brush Qiu and sheet metal becomes gold, such as iron and 0 sheet carbon. The 1Q surface and the water-soluble layer of the crystalline alumina sand glass glue liquid solution are water-coated or the erosion-prevention type is divided into negative water. Use light to see when it is possible, make the external rc Jtt, when the object is formed and rK, il 子 化 i i i 光 见 可 The base anion agent will be mixed with i by water soluble water or matter Divided water is formed and the base carboxyl is like the succinyl group. When the fatty group is transformed into the sunlight, it will be used when the nylamine is used to make it at this time. With HU V from time to time, amine isoalcohol diethyl, diamine, diethylamine, diethylamine, diethyl, diphenyl, {女 i · ". Diethyl alcohol, such as triphenylamine, etc. Agent _ and the use of alcohol and alkali in the amine three; and the alcohol alcohol ethyl and sodium amine sodium diacid as the various amines alcoholized alkoxyhydroalkane; belongs to the amine butadiene test diamine and hexylamine ring Amino acids such as succinyl amine, cyclamate, and ο amino acid milk and Potassium acetic acid, acetic acid and methacrylic acid are mixed with their acids or carboxylic acids, such as succinates, monolayers, and so on. The surface is neutralized, etc. (Please read the precautions on the back before filling this page) Economy Department of Central Standards Bureau's consumer co-operative printed tree fats should be used in each of the general-purpose groups of 0-based formula in the 0. Formula group M to the chemical industry It can be used as ο containing 1 pack to 2 into the sexual_flowing portion of the fat tree into the water ο scattered good content or solution of 8 good \ t / step into the positive group, the fatty alcohol tree is propylated and different solid , Light _ See Ethyl Alcohol, Ethyl Alcohol, Ethyl Alcohol, Water Soluble Affinity, Water Soluble Affinity Ding nature, water alcohol pro-B. Oxranylfurfur, Hydrogen Alcohol Tetraethyl and Oxymetholone TN, Oxygen 0, 2nd, 3rd, 1st, and 2nd Dioxin Ding Di Paper Size Applicable to Chinese National Standard (CNS) A4 (210X 297 mm) 6 494275 A7 B7 V. Description of the invention (Xianfen is a regular component of solid fat r * JJ i. The weight is better than M. 0. Zhongcheng _ ffi or the wax of the tree group is only fixed on the light. See the addition of Tu Kejia as the former > ί to 01¾ plus 10 and then Μ solvable :: i, r water and vegetables. 4: 1: II? Water £ · ¾ A Γτυ 5 all surface solvents -{出 石 含 包子 r 的 phenylmethylethyl amidate ο f ο --β ΊΙ and Yu; To 0 strokes Butyrate heavy acid plus ethyl addition and the ester ethyl soluble acid ethyl water such as sparse. II | ¥ .: · A_Phenyl and Butyl_Liί Hexylmethylethyl B and 2 0r Adult solid fat ο Shu Jia's weight under the weight Μ The amount is usually under the normal weight, 'Μ weight (please read the precautions on the back before filling in this (Page) Group line _ Covering the product formula of light coating method And the things of Bei and Qin ± Γ. The Weiwei group used the Li Shu tree to visualize its solidity by light. «U _ Example U. The composition of the mixture of light-sensitive and light-filled components constitutes δ. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs _ 化 发 护 Π.P Paul Yingji from the self-owned and possessed set " and} 3 BV ¢. ≪ α _ 合 0 η νί to ΰ. Lishui will come again _: ~ 丨 ^ S ί 0 The tree needs to dissolve this D ¢-to dilute the dilute solution and use it to enter the water. There is a good formula 1- & From the group of 5 to 儒 儒 霊 15 2 to Zhao, the percentage is 100%. The group of objects A ® is covered by 1.ΪIs coated i is covered by Shen M. Electricity, Shennoi Electricity has a thick tank | 1: The tank Better product than the specific electric points or 100 liters in the overcoating formula H square range a: Μ 3 to 3 volts in the spinal cord to produce the formula system is a thick volume, the guide contains this body, solid Ｍ 上 ί The surface can be expressed in Μ, the inner range of the adjustment range is 11 PIΤ;-ο of 4 slots to -h, 5 έ ^ 1- · —i first in Chengzhi system ^ 15 control temperature change ο trough material will be followed by the material 2 to t 5 0 plus 0 0 in the tank rLΛν / electro-immersion body | At the same time, it is the same as 〇 5 The paper size is better than the Chinese standard (CNS) A4 size (210X 297 mm) 494275 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of invention f) 1 1 When an awesome substance is anion-containing / dual-type, 5 Use it as a JUU anode 5 or m-.C-f VI product coating group 1 1 When the substance is m-ion type, 5 lm Decazone is used as a cathode, and voltage is applied for a long time. Appropriately 1 1 within 10 s 5 minutes B i; /-~, please 1 1 1 I II -A * A. Electrodeposition coating technician 3 can also perform a kind of low glass transfer 3¾ read 1 back 1 m degree—electrodeposition coating composition is applied to the material to be coated 5 MW washed m 9 side 1 or K washed beach Dry after m and then apply another 20 T; cover glass transfer m watts of electricity 9 VI product coating method of η η m (see Japanese Patent Publication Refilling • Green Case No. 20873/1990) 9 Immediate f——Double-coating electrode M * < 71 Product coating method written on this page 1 method 〇1 I The thickness of the coating film obtained Μ The thickness of the dry coating film is usually 1 I 〇 * 1 Within the range of 50 to 50 meters, 'M i to 15 micrometers is preferred. After electrodeposition coating 1 1 will be / * 77? 5 m water washing irrigation m 4 \ W through m coating substrate θ electrodeposition tank After M 1 is dried by hot air and 黾 m film is removed to remove water content 0 1 1 tr.H of usable conductors includes conductive materials such as metal TiJJ m tin 1 | oxide M and the surface via lamination, m plated or similar and fixed cover-txt These conductive materials are plastic Glue and glass 0 J In addition, before using visible light m light and curing 5 can be pre-coated 1 1 The coating is formed on the surface of the mt 1/1 product. ° This example of the coating layer 1 1 includes the front 逑Material 〇 Covering coating layer M Development before electrodeposition coating film 1 | Remove preferably before treatment 0 Covering containing water-soluble polymer or water-based resin 1 I Covering coating layer can be used, for example, soluble or Resin for dispersing use-½ Dissolve 1 1 If the water is acidic or alkaline, remove 1 0 1 1 Visible anti-corrosion coating material is formed on the surface of the conductor in the manner of M 1 4 1 1 5 Electrodeposited visible light anti-corrosion m-layer coating made by electrodeposition coating 1 1 This paper size applies to Chinese National Standard (CNS) A4 specifications (210X297 mm) -63-494275 A7 B7 Employees' Cooperatives of Central Standards Bureau, Ministry of Economic Affairs Printing V. Invention Theory () 1 1 m is exposed to visible light according to the image and cured after m is removed through the development process 1 1 unexposed parts thereby forming an image ° 1 1 II The light used to cure the group m of the visible light-sensitive salty material of the present invention -½ Please use the first visible light source without any special restrictions, as long as it can read the 1 t 1 cured composition ° Examples of light sources that can emit visible light include high pressure 咼 1, high pressure Λ medium pressure Or low-pressure mercury vapor lamp, chemical '1 trillion m. Recovery lamp, £ = zr a lamp matters | Jin Jie m compound lamp and tungsten filament lamp 0 In addition 9 also can use a variety of oscillating lines with refill in the visible range Laser light in which the purple copybook page 1 is exposed through a UV-cut filter The front chirped light source is cut off. In particular, a m laser with an oscillating line at 488 millimeters or a YAG-SHG laser with an oscillating line at 5 32 millimeters may be 1 1 I satisfactory. 0 1 1 Order 1 The development process can be performed by applying LiTTr to the coating layer when the unexposed coating M is anionic, or using an alkaline aqueous solution 5 or 5ΜΓ- > when X is cationic, using an acidic aqueous solution 5 having a pH of 1 I at 5M to coat the Si. Unexposed parts are washed off for 0 1 I. Common examples of alkaline aqueous solutions that can be used include caustic _ ΊΤΐυ m sodium caustic 1 A potassium and ammonia solution. B can neutralize the S contained in the coating by carboxylic acids. Examples of an acidic aqueous solution that can be used to make the coating film ˜P * · m water-soluble include 1 1 m acid formic acid and lactic acid 〇1 I and 5 in the case where the photocurable resin does not have an ionic group, Developer 1 I The washing process is performed by dissolving the unexposed portion with a solvent such as 1, 1, 1-dichloromethyl fee trichloroethylene, methyl ethyl 1 1 _, or methyl chloride. The water-washed beach 1 1 is developed in this way. Μ Hot air is dried to form 1 1 on the conductor into the desired image. 〇Etching can be performed if necessary. AT Remove AT ?? _. Photoelectric conductivity 1 | Part m > »η can remove the anti-corrosion coating film 9 And the preparation of printed circuit boards 0 1 1 This paper size applies to Chinese National Standard (CNS) A4 specifications (210X297 mm) -6 4-494275 A7 B7 V. Description of the invention () In addition to the previous application, for example, The composition for the visible light-sensitive material of the present invention can be coated on a transparent resin film such as polyethylene terephthalate, acrylic resin, polyethylene, polyvinyl chloride, etc. It is formed into a cover film layer by using a roll coater, a blade coater or a curtain coater, and then dried to form a corrosion-resistant coating. Film (thickness of dry thin film = about 0 + 1 to 5 metric meters). Then, a protective film is laminated on the coated belly to obtain a dry noise film anticorrosive coating. The protective film can be removed from the dry_film anti-corrosion coating 5 and then the dry film anti-corrosion coating can be laminated on the carrier. The M-induced dry film anti-contact coating can be contacted with the carrier by means such as thermal compression bonding. Formation of the anti-corrosion coating film. The anti-coating film can be exposed to visible light, cured, and then developed from the image in the same manner as in the case of the previous electrodeposition coating, thereby forming an image. Further, when necessary, a cover coat layer can be formed on the dry film anti-corrosive coating in the same manner as explained. This cover coat layer can be formed by coating it or adhering it to the anticorrosive coating film. This cover coat can be removed before or after the development process. The present invention will be described in more detail based on examples. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). Incidentally, in the examples and comparative examples that will be described below, the number of $ parts refers to parts by weight number〃. Synthesis Example 1 Synthesis of compound 1-1 in Table 1) 24.4 g of 2,4-dimethyl-3-ethyl, 8.4 g of 351 formalin and 500 ml of ethanol in the air After stirring and dissolving, after adding 17 g of 47 »hydrobromic acid dropwise, the reaction was carried out at room temperature for 12 hours. The solvent was concentrated and distilled off, and 500 · ml of water was added to the whole residue, and then 5,000 ml of trichloride paper was applied to the Chinese National Standard (CNS) A4 size (210 × 297 mm) -B 5-494275 A7 _ B7 V. Description of the invention () Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling this page) Methane extraction reaction products. The chloroform phase thus obtained was washed with 1 liter of water, further washed with 200 ml of a saturated saline solution, and then dried over 20 g of sodium sulfate. Insoluble matter was removed by filtration, and 78 g of N-ethyl-N, N-diisopropylamine was added to the obtained filtrate. Next, 85.2 g of boron trifluoride ethyl ether complex was added, and the reaction was carried out at room temperature for 6 hours. After the reaction was completed, 500 ml of water was used to wash the reaction to produce W, and then 200 ml of a saturated saline solution was further washed, and then dried over 20 g of sodium sulfate. Thereafter, the insoluble matter 5 was removed by filtration, and the obtained solution was concentrated, and the residue was processed by silica gel column chromatography (developing solution = chloroform) to collect the main components. After concentrating the collected solution, the components were purified by recrystallization with n-hexane and chloroform, and then dried at 60C to obtain 9, 3 g of 4,4-difluoro-2,6-diethyl. -1, 3, 5, 7-tetramethyl-4-SIS-3 a, 4 a-di 5 Υ-s-indigo 0 Next, 9, 2 grams of the aforementioned _ compound 狻 I is added to the via 3 47 grams of metal sodium was added to a methanol solution of sodium methoxide prepared in 380 ml of methanol, and the reaction was performed at 55 to 60 ° C. for 2 hours. After the reaction was completed, 1 liter of water was added, and the desired compound was extracted with 6,000 ml of chloroform. The chloroform phase was washed with 1.5 liters of water, washed with 200 ml of a saturated saline solution, and then dried over 50 g of sodium sulfate. Next, it was filtered to obtain a clear solution, and then this 8 solution was concentrated, and the remaining solution was processed by silica gel column chromatography [developing solution = chloroform-ethyl acetate mixed solution (1: 1)]. Collect the main ingredients. After the collected solution was concentrated, the components were purified by recrystallization using chloroform, and then dried at 60 ° C to obtain 5.4 g (yield = 171) of 4,4-dimethoxy One 2,6—diethyl-1,3,5,7—tetramethyl one 4 one δ-Peng-3 a 5 4 'a -di BY-s-© _ ° This paper size applies Chinese National Standard (CNS ) A4 specification (2l0x297 mm) -66-494275 A7 B7 V. Description of the invention () The elemental results of the compound obtained are as follows: C (1) H (SH N (1) Calculated value 6 9.5 2 8.90 8, 58 Measured value 69 · 69 8,76 8… 5 0 Example 2 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (Synthesis of Huaheshi 1-8 in Table 1) 57,4 g of ethyl-4 , 5-Dimethyl-3-methoxymethyl-2-carboxylic acid ester, 100 + 4 g of 881 formic acid and 85 + 2 g of 471 hydrobromic acid were mixed, and the mixture was heated to 9510, followed by stirring for 3 hours. After cooling to room temperature, M600 ml of chloroform was used to extract the reaction solution. The chloroform phase was washed with 2 liters of water, then washed with 200 ml of saturated saline solution, and then dried over 20 g of sodium sulfate. The second was discussed A solution was obtained, and 113 g of fluorene-ethyl-N, N-diisopropylamine was added to the filtrate. In addition, 123.5 g of boron trifluoride acetonium complex was added, and then at room temperature The reaction was carried out for 12 hours. After the reaction was completed, firstly, 500 ml of water was used to wash the lovers formed on the beach, and then 200 ml of _ and the aqueous solution were washed «, and then dried on 20 g of sodium sulfate. Then« to obtain _ liquid Then the concentrated solution was concentrated, and the residue was treated with a silica gel column chromatography (developing solution: n-hexane / chloroform: 35/65) to collect the main components. After the collected solution was concentrated, It was purified by recrystallization from n-hexane and chloroform, and then dried at 6 0 " C to obtain 0,6 g (yield = 14¾) of 4,4-difluoro-2,3,5 The elemental analysis results of the compounds prepared by 6,6-tetramethyl-1,7-dimethoxy-4-5penta-3a, 4a-diifamma-s-indene 0 are as follows: Calculated value C (1) HU) N (1 »5 8 + 4 7 ί 6,22 9, 09 This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 6 7 (Please read the precautions on the back before filling this page ) Order 494275 A7 B7 V. Description of the invention (ί Actual value ...__ ί " 58 + 55 Implementation 洌 1 By using 100 parts of polymer as photocuring resin (polymeric adhesive surface), this polymer is methyl methacrylate / Methylpropionate / Methylpropionate / Methylpropionate = 50/20/10/20/20 (parts by weight 丨 mixture, 55 parts trimethylolpropane triacrylate, 1 , 5 parts of compound 1-1 in Table 1 as photosensitizer, and 20 parts of cyclamethylene compound represented by chemical formula (a) of K as photoinitiator:

1ST Γ

(Please read the notes on the back before filling out this page) ⑻ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs and 160 parts of methyl cellosolve as a solvent to prepare a photosensitive solution. Using a textile machine, the photosensitive solution thus prepared was coated on a copper layer having a thickness of 18 mold meters on its surface, a copper surface having a thickness of 2 mm and a size of 3 50 × 460 mm, and an epoxy substrate reinforced with glass fiber. Then, it was dried at 60 ° C for 10 minutes to prepare a substrate of an anticorrosive coating film having a dry thickness of 5 microns. Next, the substrate with the anti-corrosive coating film was irradiated with a xenon lamp (ultraviolet wavelength range is cut off) at an intensity of 5 mJ / cm² and the second harmonic of the YAG laser (5 32 milliliters meter). At that time, it was confirmed that the resin was rapidly cured [the cured resin was not dissolved by immersing the substrate in a 1 »sodium carbonate aqueous solution (developing solution) for 1 minute at 30 υ]. This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) 68-494275 A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () Furthermore, leave 6 at room temperature Months later, M used a xenon lamp (the ultraviolet wavelength range was cut off) and the second harmonic of the YAG laser (532 millimeters >) to irradiate the unexposed substrate in the same way as before. At this time, it was confirmed that the resin quickly fixed ib-Examples 2 to 9 0 The same procedure as in Example 1 was performed except that the compounds 1-2 to 1-9 0 in Table 1 were used as the photosensitizer, so a presensitized solution was prepared. Thereafter, each of these was used Equal to the photosensitive solution, K forms an anti-corrosion coating film on the substrate in the same manner as in Example 1, and then uses a xenon drill (ultraviolet wavelength range is truncated) at an intensity of 5 mJ / cm2 and YAG laser second Harmonics (532 millimeters) illuminate the substrate with the anti-corrosion coating film. At this time, it was confirmed that the resin was quickly painted. [The cured resin was not immersed in a sodium carbonate aqueous solution (developed at 30 ° C) Solution) dissolved in the developing solution for 1 minute]. After standing at room temperature for 6 months, K uses a xenon lamp (truncated ultraviolet wavelength range) with a intensity of 5 mJ / cm² and the second harmonic of YAG laser (5 (32 millimeters) Irradiated the unexposed substrate, at this time, it was confirmed that the resin cured rapidly. Example 9 1 The same procedure as in Example 1 was performed except K 20 parts 3, 3, 4, 4 ^ ( The third butylperoxycarbonyl) dibenzophenazine replaces 20 parts of the dicyclopentadienyl iron compound represented by the chemical formula (a) in Example 1 as a photoreaction initiation surface, and thus is prepared approximately the same as in Example 1. Photosensitive solution. Thereafter, a ribbed photosensitive solution was used to form an anti-corrosion coating film on the substrate in the same manner as in Example 1. Then, a xenon lamp (ultraviolet wavelength range was truncated) was used at 5 millijoules. Standard (CNS) Α4 Specification (210 × 297 mm) -69-(Please read the precautions on the back before filling out this page) I Binding and Ordering Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 494275 A7 B7 V. Description of Invention () / Cm2 and YAG laser Harmonics (532 nm) illuminate the thin-coated substrate with an anti-corrosion coating. At this time, it was confirmed that the resin cured rapidly [the cured resin was not immersed in a 1% sodium carbonate aqueous solution (developing solution at 30)丨 dissolve by 1 minute development treatment]. Furthermore, after standing at room temperature for 6 months, M uses a xenon lamp (5mm Joules square intensities) in the same manner as previously described. The range is truncated) and the second harmonic of YAG laser (532 millimeters meter) is irradiated to the unexposed substrate 5 At this time, it is confirmed that the resin is rapidly cured. Spring Example 9 2 Perform the same steps as Cell Example 1, except that M20 parts of di-peroxyisophthalic acid di-third butyl ester was used in place of 20 parts of the dicyclopentadiene iron compound represented by the chemical formula (a) in Example 1 as a photoreaction initiator, and thus was prepared as in Example 1. Roughly the same photosensitive solution. Thereafter, using this photosensitive solution, the coating film was formed on the substrate in the same manner as in Example 1. Then, a xenon lamp (ultraviolet wavelength range truncated) was used at an intensity of 5 mJ / cm² and YAG. The laser's second harmonic solution (532 milliliters of rice) irradiated this substrate with a thin anti-touch coating. At this time, it was confirmed that the resin cured rapidly [the cured resin was not immersed in the substrate at 30 under 11 Carbonic acid_aqueous solution (developing solution) is decomposed by the development treatment for 1 minute]. Furthermore, after standing at room temperature for 6 months, M used a xenon lamp (truncated ultraviolet wavelength range) with a intensity of 5 mJ / cm² and the second harmonic of YAG laser in the same manner as before. (532 milligrams) was irradiated to the unexposed substrate, and at this time, it was confirmed that the resin cured rapidly. Example 9 3 This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 1-1 ~ 70 ~ 2 (please read the precautions on the back before filling this page) I. · 1T 494275 A7 B7 V. Description of the invention () Perform the same steps as the actual example, except that M] parts of the compound 1-8 8 and 1 part of the compound in the table] -8 9 instead of 1.5 in Example 1 are shown in Table 1. Compound _ 1, and thus a photosensitive solution almost the same as that of the spring example was prepared. Then, using this photosensitive solution? In the same manner as in Example 1, an anti-corrosion coating film was formed on the substrate, and then a xenon lamp (ultraviolet wavelength range truncated) was used at an intensity of 5 mJ / cm² and the second harmonic of YAG laser (532 Millicure m) was irradiated to this substrate with a thin anticorrosive coating. At this time, it was confirmed that the resin cured rapidly [the cured resin was not immersed in the substrate at 30 t] in a 1% sodium carbonate aqueous solution (developing solution) Dissolved in a 1 minute development process]. Furthermore, after standing at room temperature for 6 months, M used a xenon lamp with a intensity of 5 mJ / cm² (truncated outside the wavelength range) and the second YAG laser in the same manner as before. Harmonic slope (52 mm) was irradiated to the unexposed substrate, and at this time, it was confirmed that the resin cured rapidly. Example 9 4 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). Perform the same steps as in Example 1 except for 1 part of Compound 1-43 in Table 1 and 1 part of Compound_1-90 replaces 1,5 parts of compound 1-1 shown in Table 1 in Example 1, and thus a photosensitive solution having a composition substantially the same as that of Example 1 is prepared. Thereafter, using this photosensitive solution, M formed a thin layer of an anti-corrosion coating on the substrate in the same manner as in Example 1. Then, a xenon lamp (ultraviolet length range cut off) was used at an intensity of 5 mJ / cm 2 and The second harmonic of YAG laser (532 millimeters meter) irradiated the substrate with the anti-touch coating film, at this time, it was confirmed that the tree I was quickly cured [the curing resin was not immersed in the substrate at 30 C Cir * ^ JXr * ~ · development solution in a sodium carbonate aqueous solution (developing solution) for 1 minute. " This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) -7 1-494275 A7 B7 V. Description of the invention () Furthermore, after standing for 6 months at room temperature, In the same way, an unexposed substrate was irradiated with an S lamp (truncated ultraviolet wavelength range) with an intensity of 5 mJ / cm² and the second harmonic of YAG laser (532 millimeters meter). At this time, the resin was confirmed Fast curing. Example 9 5 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). Perform the same steps as in Example 1, except that 100 parts of acrylic acid will be used. 100 parts of resin M is added by adding 35 parts of glycidyl methacrylate to 100 parts of methyl acrylate / phenethyl / propionic acid = 60/10/30 (weight ratio of free radical copolymer (acid value) = Approximately 2 3 3) instead of the photo-curable resin (acid value = approximately 70, and the unsaturation = 1,83 mol / kg) obtained by the addition reaction. A photosensitive solution of the same composition in Dalu. Thereafter, using this photosensitive solution, M forms an anti-contact coating film on the substrate in the same manner as in the first embodiment, and then uses a xenon lamp (the ultraviolet wavelength range is cut off) at 5 millijoules. At the intensity of ./cm 2 and the second harmonic of YAG laser (532 nm), the substrate with the anti-corrosion coating film was irradiated. At this time, it was confirmed that the resin cured rapidly. Soluble at 3 0 C for 1 minute in 1 «sodium carbonate aqueous solution (developing solution) [Solution]. Furthermore, after standing at room temperature for 6 months, M used a xenon lamp with a intensity of 5 mJ / cm² (truncated UV liquid length range) and a YAG laser in the same manner as before. The second harmonic, "532 milligrams," irradiated the unclear substrate, at this time, it was confirmed that the resin cured rapidly. Example 96 The same steps as in Example 1 were performed, except that the paper size in Example 1 was 100. The Chinese national standard (CNS) A4 specification (210 × 297 mm) -72- 494275 A7 B7 V. Description of the invention () Parts of acrylic acid: series of resin K 50 part of the propionate-based resin and 50 parts of the mixture of the light-curing tree shrew used in Example 9 5 were replaced, so that the composition having substantially the same composition as in Example 1 was prepared. Photosensitive solution. Thereafter, using this photosensitive solution, a corrosion-resistant coating film was formed on the substrate in the same manner as in Example 1, and then xenon dial (ultraviolet wavelength range was truncated) at an intensity of 5 mJ / cm² and YAG thunder. The second harmonic liquid (532 millimeters meter) was irradiated on the substrate with the anti-corrosion coating film. At this time, it was confirmed that the resin was rapidly cured. [The curing tree was not immersed in the sodium carbonate aqueous solution at 30 υ. (Developing solution in the developing solution for 1 minute). Further, after standing at room temperature for 6 months, M uses a xenon lamp (ultraviolet light with an intensity of 5 mJ / cm²) as described above. The wavelength range is truncated) and the second harmonic of the YAG laser (532 milligrams > irradiates the unexposed substrate, at which point it is confirmed that the resin cures quickly. Example 9 7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (Please read the precautions on the back before filling this page) Perform the same steps as in Example 1, except that 100 parts of propionic acid: based resin and 55 parts of trimethylolpropane tripropyl are used in Example 1. 155 parts of fumarate M were used in Example 95. The curing resin was substituted, and a photosensitive solution having a composition substantially the same as that of Example 1 was prepared. Thereafter, using this photosensitive solution, M was used to form an anticorrosive coating film on the substrate in the same manner as in Example 1. Then, xenon was used. (The ultraviolet wavelength range is truncated.) At the intensity of 5 mJ / cm² and the second harmonic of the YAG laser (5.32 mmol), the substrate with the anti-corrosion coating film is irradiated. It was confirmed that the resin cured rapidly [the cured resin was not dissolved by immersing the substrate in a 1¾ sodium carbonate aqueous solution (developing solution) for 1 minute at 30t]. This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 -73-494275 A7 B7 V. Description of the invention (Furthermore, after standing for 6 months under room temperature, M uses a xenon lamp with an intensity of 5 millijoules per square centimeter in the same manner as before ( Ultraviolet wavelength range ffl was truncated) and the second harmonic of YAG laser (532 millimeters meter) was irradiated to the unexposed substrate. At this time, it was confirmed that the resin was rapidly cured. Example 98 The same step 5 as in the mask example 1 was performed. Except in Example 1, 5 5 parts of trimethylolpropane tripropionate and 20 parts of dicyclopentafluorite compound M A propylene oxide compound represented by the chemical formula (b)

(b) (Please read the notes on the back before filling out this page) and 10 copies of Μ chemical formula

The combination of representation_ 0

M-0-Qi-CF Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs instead of using the photo-acid-generating class ί, and a photosensitive solution having the same composition as that of Example 1 was prepared. Thereafter, using this photolysis solvent, M formed an anticorrosive coating film on the substrate in the same manner as in Example 1. Then, a xenon lamp (ultraviolet wavelength range was cut off) was used at an intensity of 5 mJ / cm² and YAG thunder. The second harmonic liquid (5 3 2 millimeters) was irradiated to the substrate with the anti-corrosion coating film. At this time, it was confirmed that the resin cured rapidly [the cured resin was not immersed in a base at 30] I carbonic acid 1 minute in sodium aqueous solution (developing solution) This paper is in accordance with Chinese National Standard (CNS) A4 specification (210 × 297 mm) 74 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 494275 A7 B7 V. Development Processing Institute Dissolve]. In addition, after standing at room temperature for 6 months, the second method uses a xenon lamp (truncated ultraviolet wavelength range) with a intensity of 5 mJ / cm² and a second harmonic of YAG laser in the same manner as described above. (5 3 2 millimeters) was irradiated to the non-light substrate, at this time 5 confirmed that the resin cured quickly. Example 9 9 100 parts (solid content) of the photosensitive solution prepared in Example 95 and 7 parts Etsu Jun was mixed, and after stirring, the mixture was then dispersed in deionized water to obtain an aqueous resin dispersion (solid content: 1 5 I). Anion electrodeposition coating was performed at 5 μm. In the case where the thus obtained aqueous resin dispersion was used as an electrodeposition coating tank and a laminated copper plate was used as an anode, the thickness of the dried film may be 5 mil. The thin plate was washed with M water, and then dried at 80t for 5 minutes to obtain an electrodeposited photosensitive layer. The light-sensitive layer was irradiated with a gas lamp (ultraviolet range truncated) at an intensity of 5 mJ / cm² and the second harmonic of the YAG laser (532 millimeters meter). At this time, it was confirmed that the resin cured rapidly [The cured resin was not dissolved by immersing the substrate in a developing solution of II carbonic acid aqueous solution at 30 t] for 1 minute]. Furthermore, after standing at room temperature for 6 months, the second harmonic of a YAG laser was used in the same way as before M section, using a xenon lamp with an intensity of 5 mJ / cm² (ultraviolet wavelength range truncated) a < 5 3 2 milli-meters) irradiated the photosensitive layer, at this time, it was confirmed that the tree I was intended to cure quickly. Example 1 100 was added 100 parts by adding 15 parts of propionic acid to 100 parts of propionate. Methyl fluorate / phenethyl paper This paper applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm) —75 ~ II I binding (please read the precautions on the back before filling this page) 494275 A7 B7 V. Invention Explanation () Women's / Propanic Acid_ / Methyl Propionate Glycidyl / Methyl Proposamethylene Dimethyl Ethyl Acetate = 2 0/1 0/2 2 8 3 0/1 8 (weight ratio ) Of the photo-curable resin (amine value == about 56, and the degree of unsaturation of 2, 1, 83 mol / kg) and the 5 compounds of Z compound 1 in Table 1 -1, 5 5 parts of trimethylolpropane tripropionate and 20 parts of the same dicyclopentadienyl iron compound used in Example 1 were mixed to obtain a photosensitive solution. Then, 100 parts (solid content) of this photosensitive solution was mixed with 3 parts of acetic acid, and then the mixture was dispersed in deionized water to obtain an aqueous resin dispersion (solid content = 15¾). When the cationic electrodeposition coating is performed, the thickness of the dried film can be 5 metric meters in the case where the aqueous resin dispersion prepared by Rugao is used as an electrodeposition coating tank and the laminated panel is used as an anode. After that, the plate with the film was washed with water and dried at 80 tt for 5 minutes to obtain an electrodeposited photosensitive S; 3 using a gas lamp (ultraviolet wavelength cutoff) at SYAG laser at an intensity of 5 millijoules per square centimeter. The second harmonic wave (532 millimeters meter) irradiated this photosensitive layer, at this time, it was confirmed that the resin was rapidly cured [the cured resin was not immersed in the substrate at 30 υ in a 2, 3 8 I tetrahydroxide aqueous solution ( Developing solution) dissolved in the developing solution for 1 minute]. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) and then s After standing at room temperature for 6 months, Μ can be used in the same way as described above. A xenon lamp with a Joule / cm2 intensity (the ultraviolet wavelength range is truncated) and the second harmonic of the YAG laser are irradiated to the light-sensitive layer. At this time, it is confirmed that the resin is rapidly cured. Example 1 0 1 The same steps as in Example 1 were performed, except that 3 parts of Ν, Ν-dimethylaniline were added as a radical protecting compound, so it was prepared to have the same paper size as Example 1 in China. Standard (CNS) A4 specification (210X297 mm) -7 6-494275 A7 B7 V. Description of the invention (

It is called _ rtti, which is slightly similar to the liquid-soluble light-sensitive light, W liquid ruu V, the ffl ruu V does not hide the same phase of the solid square_ anti-forming upper material base is in 舅 Hhu 'W t -'- tv- layered lamp S. a 用度? 7 ί 之 h 防 分 ί V have i ', with ¾ 眈 平-rTJ, dazzling ears} 隹? Million signs p dizzy.) CO Broken i Poor economy Circumstances AB Hua Changbo ir Xi Zidu Harmony No. 2 The thunder material-based film W layer will be non-greased in the material base) «Solid solution bli; ί员] 00 Gud, ground solution, fast-dissolving, fast-water, tree acid, carbon proof II, at the time of dipping, the same phase of the same phase, r D $ K, the next month, 6 ° r 丨 J, the solution room is located in the wet room Ying Yuxian, of whom Zhong Zaifen has useful breaks and truncated styles. In this example, the material is real to purple'-ί, the degree of lamp xenon Λ 3 A strong centimeter flat / ear focus 2 3 5 The second wave of the second harmonic wave is solidified and the speed of the tree is very fast. The steps of 9 to 2 are the same. After the application of 0 lamp gas to the public interest M? Natural liquid, soluble _ thin layer of this coating is used to prevent corrosion is 0 long-based light exposure without exposure to the fiber content of 3 into ο fl, except for the sensitive material to be cut The base of the scriptures in the fan-style Fan Fang _ Wai Zhi Zi (Please read the precautions on the back before filling Page) 顚 之 分 公 方 S Printed W-layer touch-proof protective gear for the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, tt / S ^ 0 ears 丨 Jiaomi Minzheng 2 r, b wave harmonic, 2 o'clock This' Shooter Raki G 1 A

Immersion IIP solution P 30 30 in the material shadow base display will be divided by the clock 11 [tree solution solid solution b [® ji show 0 (ground fluid to dissolve fast water fat _ tree acid carbon reward certificate 11 in 1 -£ _ At 5 Yu You, the user uses the re-benefit method to set the headlights of the same phase of the ear-focus side, such as xenon W, after a strong month and a square flat 0. Long skin \ .yi fr 夕 紫When the material breaks V! At this time 20 ° Λ-15ib Liquid-solid harmonic second-speed fastest fat-shooting tree Lightning AG card base light exposure without exposure Δ., \ T7r The paper standard applies to Chinese national standards (CNS ) A4 size (210X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 494275 A7 B7 V. Description of the invention () Xiao Yi] 9 1 Perform the same steps as in Example 1 except that 5 parts are added. Triethyl acid was used as a radical protecting compound to prepare a photosensitive solution. Thereafter, using this photosensitive solution, M was formed in the same manner as in Example 1 to form a thin anti-corrosion coating on the substrate. Truncated by long range) second at anti-YAG laser at 2 mJ / cm² Harmonics (5 3 2 millimeters) illuminate the substrate with the anti-corrosion coating film. At this time, it was confirmed that the resin was cured rapidly [the cured resin was not immersed in the substrate at 3 〇 ΐ] in 1 $ carbonic acid In the Hannai aqueous solution (developing solution), it is dissolved by the developing treatment in minutes]. Furthermore, after standing at room temperature for 6 months, M used a xenon lamp (truncated ultraviolet wavelength range) with a intensity of 5 mJ / cm² and the second harmonic of YAG laser in the same manner as before. (5 2 2 millimeters) Irradiated the unexposed substrate, and at tt, it was confirmed that the resin cured rapidly. Example 1 2 Using a free radical copolymer (toluene) of 100 parts of methacrylic acid / acetophenone acetic acid methyl ester Sg / methyl methacrylate = 20/1 0/20/50 (weight ratio) Solution), 60 parts of Tetraacetic Acid Dimethylpropionic Acid S, 15 parts of Table 1 as the photosensitizer compound 1-1, 1 part was used in the bicyclo and glutarin of Example 1 An iron compound was used to prepare a photosensitive solution. Using a doctor blade coater, the tt photosensitive solution was coated on a polyester film having a thickness of 25 米 m, and then dried at 1 ο ο π to obtain a visible light-curable tree shrew composition layer having a thickness of 50 征 m. Thereafter, a 35-micron-thick polyethylene film was laminated on the dry-coated film as a protective film to obtain a dry-color anticorrosive coating. The dry _ Yan anti-corrosion coating thus obtained was heat-laminated on a copper-plated multilayer substrate and the protective film was peeled off, and the paper was prepared in accordance with the Chinese National Standard (CNS) A4 specification (210 × 297 mm)- 78-I Binding (Please read the precautions on the back before filling this page) 494275 A7 B7 V. Description of the invention () According to the photosensitive layer of the dry film. Then, the substrate with a photosensitive layer was irradiated with a xenon lamp (ultraviolet cut-off by the UV lamp) at an intensity of 5 mJ / cm 2 and a second harmonic of y A G laser (525 mF). The polyester film is peeled from the surface of the photosensitive layer. The exposed part was not dissolved by the development treatment in which the substrate was immersed in a sodium carbonate aqueous solution (development solution) at 30 to 10 for 1 minute. On the other hand, the unexposed part was washed away by Gu Ying solution. In other words, it was confirmed that the dried film was good. Furthermore, after standing at room temperature for 6 months, the unexposed substrate was evaluated in the same manner as previously described. At this time, it was confirmed that the photosensitivity was not changed. Example 1 9 3-2 8 1. The same procedure as in Example 1 2 was performed except that the compounds 1-2 to 1-9 0 in Table 1 were used as the photosensitive surface, and a photosensitive solution was prepared. It was then printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). Using each of these photosensitive solutions, K was formed on the substrate in the same manner as in Example 9.2. Layer, and then use a xenon lamp (ultraviolet wavelength range is cut off at the intensity of 5 millijoules / square centimeter and the second harmonic of YAG laser (5 3 2 milliliters))-this substrate with photosensitive 11, this At that time, it was confirmed that the dendritic cells solidified quickly [the cured resin was not dissolved by immersing the substrate in a sodium carbonate aqueous solution (developing solution) for 1 minute at 30 ° C.] Furthermore, at room temperature After standing for 6 months, M evaluated the unexposed substrate in the same manner as before, and at this time, it was confirmed that the photosensitivity was not changed. Example 282 In a dark room 3 A doctor blade coater will be used to make the first example The obtained photosensitive solution is coated on a copper-plated epoxy substrate reinforced with glass sickle. The thickness of the film can be 5 metric meters, and it can be dried at 60t for 10 minutes. National Standard (CNS) Α4 Specification (210 × 297 mm) -79-494275 A7 B 7. V. Description of the invention () A substrate with anti-touch coating is prepared. Next, the surface of the substrate with anti-coating thin film thus prepared is at a luminous intensity of 40 lux (MuX). The tt lamp 2 shown in circle 1 is irradiated for 4 hours. Thereafter, the substrate having the thin coating with anti-coating was heated in a dark room at 120 t for 30 minutes, and then immersed in a sodium carbonate aqueous solution of 11 as a developing solution at 30 t for 1 minute. . As a result, the anti-coating film was completely dissolved in the carbonic acid aqueous solution, which means that photo-curing did not occur at all through the sodium lamp inconveniently. Using a scratch-coating process, the front photosensitive solution was applied to a transparent polyethylene terephthalate sheet. The thickness of the M-coated film could be 5 metric meters, and it was then dried at 60 1C. 10 minutes. Next, the light of this coating was measured. The results are shown in circle 4. The ordinate represents the absorbance and the abscissa represents the wavelength (millimeters). Ϋ The liquid length of the safety lamp in Figure 1 and the absorbance curve in Figure 4 confirm that the safety lamp will not adversely affect the photosensitive solution. The spectral luminous efficiency curve also confirms that the safety funeral is on. Example 2 8 3 to 3 7 1 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). In a dark room, use a wiper coater to carry out Examples 2 to 9 The photosensitivity prepared in 0 is coated on a copper-plated epoxy substrate reinforced with glass fiber. The thickness of the M-dried layer can be 5 metric meters, and it can be dried at 60t for 10 minutes to obtain corrosion resistance. Substrate for coating film. Next, the surface of the substrate having the anti-corrosion coating film thus prepared (thickness of the dry anti-contact coating film = 5 zhenm) was irradiated with the lamp shown in FIG. 1 at a light intensity of 40 lux for 4 hours. Thereafter, the paper size with anti-corrosion coating was applied to the Chinese National Standard (CNS) A4 specification (210X297 mm) -80-494275 A7 B7 V. Description of the invention (7θ) Thin-colored substrate in a dark room at 120 under It was heated for 30 minutes, and then immersed in a 1¾ sodium carbonate aqueous solution as a developing solvent for 1 minute under 3ot. As a result, the anti-contact coating film was completely dissolved in the carbonic acid aqueous solution, which means that the light curing did not occur conveniently via the lamp. Comparative Examples 1 to 90 The same procedure as in each of Revelation 282 to 371 was performed, except that the sodium lamp M fluorescent lamp in Examples 282 to 371 was replaced, thereby preparing a substrate having an anticorrosive coating film. In addition, M was immersed in a 1 »sodium carbonate aqueous solution in the same manner as in Example 1. As a result, the anticorrosive coating film was not disadvantageously dissolved in the sodium carbonate aqueous solution. The spectral distributions of the fluorescent light used in Comparative Examples 1 to 90 are shown in (Please read the precautions on the back before filling this page) Printed on the paper standards of the China National Standards Bureau (Consumer Cooperatives) CNS) Α4 specification (210X297 mm)-&S; S-

Claims (1)

Called 4275 ABCD 0¾ ► I, 12 positive 0. repair '. ^ VI. Patent application, etc. 1. A photosensitizer with at least one dipyrrometheneboron complex compound represented by the chemical formula (1): Y 员工 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, where rings X! And χ2 are each a pyrrole ring that may have one or more substituents; Y is a hydrogen atom, a cyano group, or an alkane that may have one or more substituents Aryl, aralkyl, aryl, heteroaryl, or alkenyl; and Zi and Z2 each are a halogen atom, or an oxo, oxo, oxo, or aryl group that may have one or more substituents : Peroxy, aryl, heteroaryl, alkylthio, aryloxy, arylthio, heteroaryloxy or heteroarylthio, the restrictions are the substituents on the pyrrole ring X! And χ2 and At least one of the groups Z! And Z2 is an alkoxy group, an aralkyloxy group or an aryloxy group which may have one or more substituents. 2. The photosensitizer according to item 1 of the scope of patent application, wherein the dipyrrole methylene boron complex compound is a dipyrrole methylene boron complex compound represented by the chemical formula (2): Z2 (2) where R !, R2, R3, R5, R6 and R7 are hydrogen atom and halogen atom, respectively. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the back page first) Note for this page, please fill in this page) Order ---- Line # Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 494275 A8 B8 C8 __ D8 VI. Application scope of patents cyano, hydroxyl, amine, can have one or more Alkyl groups having 1 to 4 carbon atoms, alkoxy groups having 1 to 5 carbon atoms or alkylthio groups having 1 carbon atom, 6 carbon atoms having one or more substituents An aryl group, an aryloxy group having 6 to 10 carbon atoms or a square sulfur group having 0 carbon atoms, a square alkyl group or aralkoxy group having 7 carbon atoms which may have one or more substituents, Heteroaryl groups having 3 to 4 carbon atoms, which may have one or more substituents, which may have 2 carbon atoms, which may have one or more substituents, or a chemical formula (3) or (4) Represented group: 〇II-CQ (3) where Q is a hydrogen atom, an amine group, and a methyl group which may have one or more substituents Or a methoxy group, an aralkoxy group having 7 carbon atoms which may have one or more substituents, an aryloxy group or arylamine group having 6 carbon atoms which may have one or more substituents, may have One or more substituents having 2 carbon atoms, alkenyloxy groups, one or more substituents having 1 to 2 carbon atoms, monoalkylamino groups, and one or more substituents having 2 A dialkylamino group having 4 to 4 carbon atoms, or an alkoxycarbonylalkoxy group having 3 carbon atoms which may have one or more substituents, -NH-L (4) wherein L is a group which may have one or more Ethyl fluorenyl as a substituent or benzamidine phenyl having one or more substituents; R4 is a hydrogen atom, a cyano group, an alkyl group having 1 to 4 carbon atoms which may have one or more substituents, and may have The original paper size with 7 carbons of one or more substituents is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -------------------- Order --------- line (Please read the precautions on the back before filling out this page) 2 494275 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Z2 A8 B8 C8 D8 VI. Patented aralkyl groups, aryl groups with 6 carbon atoms that may have one or more substituents, and 3 to 4 carbons that may have one or more substituents Atom heteroaryl groups, or alkenyl groups having 2 carbon atoms which may have one or more substituents; Z! And Z2 each are a halogen atom, and may have 1 to 4 carbon atoms which may have one or more substituents Atom alkyl, alkoxy having 1 to 5 carbon atoms or alkylthio having 1 carbon atom, aralkyl or aralkoxy having 7 carbon atoms which may have one or more substituents , An aryl group having 6 carbon atoms which may have one or more substituents, an aryloxy group having 6 to 10 carbon atoms or an arylthio group having 10 carbon atoms, which may have one or more substituents Heteroaryl groups with 3 to 4 carbon atoms, heteroaryloxy groups with 4 to 7 carbon atoms or heteroarylthio groups with 3 carbon atoms; the restrictions are R !, R2, R3, R5, R6 And at least one of R7 is an alkoxy group, an aralkyloxy group, or an aryloxy group. 3. The photosensitizer according to item 1 of the scope of patent application, wherein the dipyrrole methylene boron complex compound is a dipyrrole methylene boron complex compound represented by the chemical formula (5): Re wherein R1, R2, R3, R5, R6 and R7 are each a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, an amine group, an alkyl group having 1 to 6 carbon atoms or an alkylthio group having 1 carbon atom, which may have one or more substituents, An aryl group having 6 to 10 carbon atoms, which may have one or more substituents, or an arylthio group having 10 carbon atoms, which may have 7 to 9 carbons, which may have one or more substituents. China National Standard (CNS) A4 Specification (210 X 297 mm) -------------------- Order --------- (Please read the back first Note: Please fill in this page again.) 3 494275 Printed by A8, B8, C8, D8, Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs. 6. Aromatic alkyl groups that have one or more substituents and three carbon atoms that may have one or more substituents. Heteroaryl, alkenyl having 2 to 5 carbon atoms, which may have one or more substituents, or a group represented by chemical formula (3) or (4): 〇 II —CQ (3) wherein Q is a hydrogen atom, an amine group, a methyl group which may have 7 or more substituents or an alkoxy group having 1 to 3 carbon atoms, and may have one or more substituents having 7 Aralkyloxy groups of 10 to 10 carbon atoms, aryl groups of 6 carbon atoms that may have one or more substituents, aryloxy or arylamine groups, 2 carbon atoms that may have one or more substituents Atomic alkenyloxy groups, monoalkylamino groups having 1 to 3 carbon atoms which may have one or more substituents, dialkylamino groups having 2 to 4 carbon atoms which may have one or more substituents, Or alkoxyalkoxy or alkoxycarbonylalkoxy having 3 carbon atoms which may have one or more substituents, -NH-L (4) where L is benzyl which may have one or more substituents Fluorenyl; R4 is a hydrogen atom, a cyano group, an alkyl group having 1 to 5 carbon atoms which may have one or more substituents, an arane group having 7 to 9 carbon atoms which may have one or more substituents An aryl group having 6 to 13 carbon atoms which may have one or more substituents, a heteroaryl group having 4 to 7 carbon atoms which may have one or more substituents, or may have Alkenyl groups having 2 to 4 carbon atoms with one or more substituents; Zι and Z2 are each a halogen atom and may have one or more substituents with 5 paper sizes. The Chinese paper standard (CNS) A4 specification applies. (210 X 297 mm) -------------------- Order --------- line (Please read the precautions on the back before filling this page ) 4 494275 A8 B8 C8 D8 6. Scope of patent application (please read the notes on the back before filling out this page) Alkyl group with carbon atoms, alkoxy group with 1 to 20 carbon atoms, may have one or more Aryloxy groups having 7 to 13 carbon atoms as the substituents, aryl groups having 6 carbon atoms which may have one or more substituents, aryloxy groups having 6 to 7 carbon atoms, which may have one or more A heteroaryloxy group having 10 carbon atoms or a heteroarylthio group having 2 carbon atoms per substituent; the restriction is that at least one of Z! And Z2 is an alkoxy group, an aralkyloxy group, or an aryloxy group base. 4. The photosensitizer according to item 3 of the scope of patent application, wherein at least one of Z! And Z2 is an alkoxy group having 1 to 20 carbon atoms or 7 to 13 having one or more substituents Aryloxy of carbon atom. 5. The photosensitizer according to item 4 of the scope of patent application, wherein Ri, R2, R3, R5, R6 and R7 are each a hydrogen atom, or a group having 1 to 6 carbon atoms which may have one or more substituents. A chain or branched alkyl group; R4 is a hydrogen atom, a methyl group, an ethyl group or an aryl group having 6 to 7 carbon atoms, and at least one of 2! And Z2 is 1 to 2 which may have one or more substituents Linear, branched or cycloalkoxy or benzyloxy with 5 carbon atoms. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs π 6. A visible light curable resin composition containing a photocurable resin (A) having a photosensitive group which can be crosslinked by irradiation with light, selected from photoradical polymerization The photoinitiator (B) and photosensitizer (C) of the initiator, the photoacid generator and the photobase generator are characterized by using the photosensitizer such as any one of claims 1 to 5 as a photosensitizer. (C) The photoreaction initiator (B) is 0.1 to 25 parts by weight and the photosensitizer (C) is 0.1 to 10 parts by weight based on 100 parts by weight of the photocurable resin (A). 7. If the visible light curable resin composition of item 6 of the scope of patent application, the paper size of this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 494275 A8 B8 C8 D8 6. The scope of patent application includes free radicals Protected compound (D). (Please read the precautions on the back before filling this page) 8. If the visible light curing resin composition of item 7 of the patent application scope, wherein the radical protection compound (D) contains a compound selected from phosphite compounds and N, N -At least one free radical protecting compound of a dimethylamine group bonded to an aromatic compound of carbon atoms forming an aromatic ring. 9. The visible light curable resin composition according to item 6 of the patent application, which is used under the irradiation environment of a safety lamp having a high spectral luminous efficiency and a maximum wavelength selected in the range of 500 to 6 20 nm, which consists of The absorbance of the unexposed coating film formed by the object within the range of the maximum wavelength ± 30 nm of the safety lamp is 0.5 or less. 10. The visible light-curable resin composition according to item 6 of the patent application range, wherein the visible light-curable resin composition and a solvent can be used to make an ink for a visible light-curable material. 1 1. The visible light curable resin composition according to item 6 of the patent application scope, wherein the visible light curable resin composition and the substrate can be made into a visible light curable material. Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is sized to the Chinese National Standard (CNS) A4 (210 X 297 mm)