TW490473B - Polyester polymerization catalyst, method for producing polyester and polyester - Google Patents

Abstract

The present invention is to provide a polyester polymerization catalyst, which uses a component except for an antimony compound or a germanium compound as the main component, is excellent in catalyst activity, and can efficiently prohibit heat deterioration during melting processing step without fouling or removing the catalyst, therefore is excellent in heat stability. The present invention also provides a polyester obtained by using said polyester polymerization catalyst, and a method for producing a polyester using said polyester polymerization catalyst. The polyester polymerization catalyst does not comprise antimony or germanium. The activity parameter (AP) of said polyester polymerization catalyst meets AP(min) < 2T(min). The heat stability index (TD) of the polyethylene teraphthalate polymerized by using the catalyst meets TD(%) < 25. In addition, the polyester polymerization catalyst compound component comprising an Ar-O- and/or Ar-Nc unit. The polyester can be used in various moldings such as fibers, films, sheets, hollow moldings.

Description

490473 A7 B7__ V. Description of the invention (f) (Please read the notes on the back before filling out this page) The present invention is related to a polyester polymerization catalyst, the polyester made using it, the method for producing polyester, and the use of polyester Fibers, shaped articles, films, etc., more specifically, a novel polyester polymerization catalyst that does not use germanium and antimony compounds, a method for manufacturing polyesters, polyesters using the same, and polyesters Fiber, molded product, film, etc. The polyester polymer image is a polymer of various compositions exemplified below, and is widely used in various applications in various fields. Polyethylene terephthalate (hereinafter referred to as PET) has excellent mechanical and chemical properties, as well as transparency, heat resistance, and gas barrier properties. It can be used for a variety of purposes, such as fabrics for clothing or industrial materials, Various films or sheets for packaging or magnetic tapes, molded products such as reagent bottles or engineering plastics. PET is industrially produced by the esterification or transesterification of terephthalic acid or dimethyl terephthalate with ethylene glycol, and it is used in It is prepared by polycondensation using a catalyst under high temperature and vacuum. Poly #ethyl elongate has excellent heat resistance, impact resistance, transparency, gas barrier properties, ultraviolet blocking properties, and chemical resistance, so it is used in reagent bottles, films, sheets, and fibers for industrial materials. Polyethylene naphthalate (PEN) printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is manufactured industrially by esterification or transesterification of naphthalenedicarboxylic acid or dimethyl naphthalenedicarboxylic acid with ethylene glycol A molecular weight oligomer is prepared by polycondensing it under a high temperature and a vacuum using a catalyst. Polybutylene terephthalate (PBT) Due to its excellent formability, this paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7 V. Description of the invention (1) Heat resistance, mechanical characteristics, and chemical resistance, so it is widely used as a molding material for automobile parts or electrical and electronic parts. PBT is used in industry to produce low-molecular-weight oligomers by esterification or transesterification of terephthalic acid or dimethyl terephthalate with 1,4-butane diester, which is then used under high temperature and vacuum. The catalyst is prepared by polycondensation. Poly (trimethylene terephthalate) has excellent heat resistance, impact resistance, transparency, chemical resistance, weather resistance, electrical properties, flexibility, etc., so it is used in fibers, films, automotive parts, electrical and electronic parts And so on. Polyethylene terephthalate is produced industrially by low-molecular-weight oligomers by esterification or transesterification of terephthalic acid or dimethyl terephthalate with propylene glycol. It is prepared by polycondensation using a catalyst. Cyclohexanedimethanol-modified polyethylene terephthalate (hereinafter referred to as CHDM-modified PET) has excellent impact resistance, transparency, gas barrier properties, chemical resistance, and recycling properties. Therefore, it is used in various molded articles such as slabs. CHD Μ modified PE Τ 傺 through esterification of terephthalic acid with ethylene glycol and cyclohexanedimethanol, or transesterification of dimethyl terephthalate with ethylene glycol and cyclohexanedimethanol To produce low molecular weight oligomers, which are then polymerized and condensed using a catalyst under high temperature and vacuum. The above polyesters, especially polyester fibers using PET and PEN, are organic fibers with excellent physical properties and cost balance. They are not only used for the clothing of long fibers or short fibers, but also can be widely and widely used in various interior designs. 4- This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) ----------- 1AW -------- Order -------- -(Please read the precautions on the back before filling out this page) Printed clothing 490473 A7 B7_ of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Description of the invention (3) Uses, use of materials such as cotton filling or non-woven fabrics, etc. The polycondensation catalyst which is a polyester polymerization catalyst used for the above-mentioned polyester polycondensation is widely used antimony trioxide. Antimony trioxide is a pseudo-low-priced catalyst with excellent catalyst activity. However, antimony metal crystallizes during polycondensation, which causes problems such as black slag or foreign matter in polyester. Moreover, recently, there have been accusations of the safety of antimony in terms of environment. Therefore, antimony-free polyesters are desired. The foreign matter in the polyester formed by crystallization of metal rhenium in polyester for film is not only the cause of mold contamination during melt extrusion, but also the disadvantage of the film surface. In addition, when used as a raw material for a hollow molded product, the polyester has a high crystallization rate, and it is difficult to obtain a hollow molded product having excellent transparency. Foreign matter in polyester 傺 Foreign matter that reduces strength in the fiber is the cause of mold contamination during yarn making. Among polyester fibers, a polyester polymerization catalyst that does not generate foreign matter is desired in terms of operability. Antimony trioxide was used as a trial polycondensation catalyst, and the generation of black residue or foreign matter in P E T was suppressed. For example, Japanese Patent No. 2 6 6 6 5 ϋ 2 uses a compound of antimony trioxide, bismuth, and selenium as a polycondensation catalyst to suppress the generation of black foreign matter in PET. Furthermore, in Japanese Patent Application Laid-Open No. 9-2 9 1 1 4 1 when antimony trioxide containing sodium and iron oxides is used as a polycondensation catalyst, antimony metal crystals can be suppressed. These polycondensation catalysts cannot achieve the purpose of reducing antimony content. In transparent applications such as PET bottles, methods to solve the problem of antimony catalysts are required, for example, Japanese Patent Laid-Open No. 6-2 7 9 5 7 9 shows that by specifying the amount of antimony compound and phosphorus compound used The paper size of this paper with improved transparency is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------ installation -------- order ----- ---- (Please read the precautions on the back before filling this page) 490473 A7 B7__ 5. Description of the invention (4) Method. However, the polyester hollow molded product obtained by this method has insufficient transparency. (Please read the precautions on the back before filling out this page.) Furthermore, Japanese Patent Application Laid-Open No. 1- 3 6 4 9 5 shows that using antimony trioxide, phosphoric acid, and sulfonic acid compounds can continuously produce polymers with excellent transparency. Ester method. However, the thermal stability of the polyester obtained by this method is not good, and the hollow molded product obtained has a high acetaldehyde content. In addition to antimony compounds, polyester catalysts with excellent catalyst activity and excellent thermal stability can be practically used with germanium compounds. However, the catalyst is very expensive, and it is easy to distill out from the reaction strip during polymerization. The catalyst concentration is prone to change and it is not easy to control the polymerization. Therefore, a polymerization catalyst other than an antimony compound and a germanium compound requires a polymerization catalyst having excellent catalyst activity and hardly causing thermal degradation during melt molding to obtain a polyester with excellent thermal stability. In addition to antimony compounds and germanium compounds, polymerization catalysts with excellent catalyst activity have been proposed. Tetraalkoxyphthalates are typical titanium compounds or tin compounds. Polyesters produced using these are easily heated during melt molding. Degraded, and the polyester was significantly colored. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. In addition, polyester fibers prepared using tetraalkoxyphthalate as a typical titanium compound or tin compound are prone to thermal degradation during melt molding and have significant # Color problem. Polyesters that are polymerized using a titanium compound as a catalyst attempt to control thermal degradation during melt molding. For example, Japanese Patent Application Laid-Open No. 10-2 5 9 2 9 6 shows that a titanium compound is used as a catalyst to polymerize the polyester. , Method of adding phosphorus compounds. A typical example of this technology is by adding such as phosphorus strip compound-6- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 Printed by A7 B7__5 2. Description of the invention (r) Stabilizers to deactivate the catalyst, it is determined that the thermal stability of the polyester can be improved, but effectively adding additives to the polymerized polyester is technically extremely difficult and costly. Cannot be put to practical use. In addition, the use of additives has the problem of raising costs, such as not being an enterprise. In addition, a method for suppressing thermal degradation of the polyester during melt molding is, for example, a method of removing a catalyst from the polyester. As a method for removing the catalyst from the polyester, for example, Japanese Patent Laid-Open No. 1 G-2 5 1 3 9 4 discloses a method of contacting a polyester resin with an extractant of a supercritical fluid in the presence of an acidic substance. However, this method of using a supercritical fluid is technically extremely difficult, and the cost will not be increased. An object of the present invention is to provide a component other than an antimony compound or a germanium compound as a main component, which has excellent catalyst activity, does not deactivate or remove the catalyst, can effectively suppress thermal degradation during melt processing, and can have excellent properties. A polyester polymerization catalyst for a thermally stable polyester using the polyester obtained by the above-mentioned polyester polymerization catalyst and a method for producing a polyester using the above-mentioned polyester polymerization catalyst. In addition, another object of the present invention is to provide a PET, PBT, PEN, CHDM-modified PET, poly (trimethylene terephthalate) obtained by using the polyester polymerization catalyst, and a method for producing the same. In addition, another object of the present invention is to provide a molded article, a film, a fiber, a fiber for industrial materials, a modified fiber, and a flame-resistant fiber using a polyester on the top. In order to solve the above-mentioned problems, the inventors repeatedly researched and found that by making the first component and the second component not sufficiently aggregate (please read the precautions on the back before filling this page). n ϋ ϋ one by one ^ n ϋ ϋ emmem / The paper size of the test paper is in accordance with the Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7B7 Five / ^ / V The statement will be realized. It is clear and hairy, the nature of survival is high, and then it is, compared with the sex to live, the existence of the common use of the active agent with a sufficient amount of active agent to catalyze the condensation and polycondensation and], 1 ± 9 Dissatisfaction with the antimony content can be counted as a special feature. Participant tongue νΛ yyi is a mixture of polyesters and polybenzyl esters. Polymerization is described above.

P A Refers to thermally stable esters of ethyl acetate, methylenediphenyl, C, p-mono-poly [2.

D T

ρ A

ID η η • 1 m / IV τ 2 is determined as the degree of HU Zhanyue 黍 so that there is a finger under the false ΑΡdegree ί press d agent in V 5 7 ο

Ethylene Methylbenzene P-Polymer S Reduced d Poly or Ester 1T B

Oxygen is needed three times a day. In the case of the acid of AP m, the dimethyl benzene catalyzes the antimony for the polymerization to form the biochemical oxygen. The amount of the three series is used to add the antimony. Middle Ester% Ear Mo 5 ο (Please read the note on the back? Matters before filling out this page)

5 2 &lt; \) /% / (\ D T

In the DT, the finger ο is at 3 ° C and is fixed to § d 6 when the time is 2 ii. Dry and dry under true ° C tube b test. ¾ body glass glass ring in the gas T3 nitrogen EP, S / ο ο 3

T

When the degree of stickiness is solid, the small 2 state is melted.

D T is better than% 2 2 &lt; D T% 8 if

% / tv S · Shao 烕 5 for D% 5 2 It is necessary to use a low-temperature drop-shaped end to achieve extreme melting and melt strength, and the film thinner such as ester-convergence or chemical fiber should be used. As a result, the inferior chemical agent of the chemical industry is produced by the Intellectual Property Bureau of the Ministry of Economic Affairs, and printed by the consumer cooperative of the Ministry of Economic Affairs. It is 0 or antimony containing no optional I type 1X. With or without agent can {chemically disperse the catalyst into the material that is contained in the gold that is contained in the material, and the material is golden or active, and the component is combined into a compounding machine and 8 paper standards are applicable to China Standard (CNS) A4 specification (210 X 297 mm)

490473 A7 B7 V. Description of the invention (?) In essence, even if it has catalyst activity, its activity is not sufficient). In the above-mentioned invention, it is preferable that the constituents of the above-mentioned organic compounds are one or more compounds selected from the group consisting of compounds containing the general formula (Formula 1) and / or the general formula (Formula 2). (Formula 1) A r-0-(Formula 2) A r ~ N &lt; (wherein Ar 傺 represents an aryl group), and the polyester polymerization catalyst of the present invention is characterized in that at least one kind of 傺 is selected from the group consisting of It is composed of a metal-containing component of a metal and / or metal compound containing antimony or germanium, and an organic compound component, and the above-mentioned organic compound component 傺 is one or more selected from the group consisting of general formulae (Formula 1) and / or (Formula 2) A group of compounds. (Formula 1) A r-0 (Formula 2) A r-N &lt; (where A r 傺 represents an aryl group) Further, the organic compound of the present invention is pseudo-equipped with a general formula (Formula 1), (Formula 2) For example, a compound or a derivative thereof in which both N and 0 are bonded to an aromatic ring such as an aminophenol. The polyester polymerization catalyst of the present invention is subject to the requirement that it is not substantially -9- This paper size is applicable to China National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back before filling this page ) -------- Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed 490473 A7 B7__ V. Description of Invention ($) Catalyst Those having at least two components, such as an active first component and a second component having substantially no catalyst activity, which are substantially catalytically active. It is preferable that at least the first component is a gold-containing tincture component, and at least the second component is an organic compound component. The present invention also relates to a polymerization method of polyester. The emblem of the polymerization method is to simultaneously or separately add the first component or the second component to the raw material for forming the polyester. [The best form for carrying out the invention] One or two or more suitable metal-containing components as the first component of the present invention are selected from the group consisting of alkali metals, earth metals, 5 A metals, 6 A metals, 7 A Golden hurricane, Group 8 metal, Group 1B metal, Group 2B metal, Group 3B metal, lead, bismuth, tellurium, silicon, boron, junction, thorium,%, ruthenium, lanthanum gold thorium, or a compound of these compounds However, there are no particular restrictions. The metal compounds of the above include, for example, saturated aliphatic carboxylic acid salts such as formic acid, acetic acid, propionic acid, butyric acid, and oxalic acid, unsaturated fatty carboxylic acid salts such as acrylic acid and methacrylic acid, and aromatic carbonyl acids such as benzoic acid. Salt; halogen-containing carboxylic acid salts such as trichloroacetic acid; hydroxycarboxylic acid salts of lactic acid, citric acid, salicylic acid, sulfonic acid, sulfuric acid, nitric acid, phosphoric acid, phosphonic acid, hydrogen sulfonate, hydrogen phosphate, hydrogen sulfide , Inorganic acid salts of sulfurous acid, sulfuric acid, hydrochloric acid, hydrobromic acid, chloric acid, bromic acid, etc., organic sulfonates such as 1-propanesulfonic acid, pentanesulfonic acid, naphthalenesulfonic acid, and laurylsulfuric acid Organic sulfates, alkoxides such as methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, and 3-butoxy; and acetamyl acetate. Chelates, oxides, hydrides, etc .; among these, saturated aliphatic carboxylic acid salts are preferred, and acetate is more preferred. Moreover, for alkali metals, alkaline earth gold hurricanes, -10- This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) ------------ installed ----- --- Order ------ (Please read the precautions on the back before filling out this page). 490473 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (Today) 5A Group Metals, 6A Group metal, Group 78 metal, Group 8 metal, Group 1B metal, Group 2 B metal, Group 3B metal, lead, bismuth, tellurium, silicon, boron, germanium, rhenium, osmium, ruthenium, lanthanum metal, or the like Among the compounds, Li, Na, K, R b N Cs, Be, Mg, Ca Λ S rx Ba, A1, G a N Tl, P bx Bi,

Cr Λ NU Mo, Tc, Re, Sc, Ύ, Iv, Hf, V, Rux Rh, Pd, I rx Pt, Cu, A g N Au, C dx Hg, La N Ce, S nu E u NG d , M n, C ο, Z η, I n, F e, N b, Ta, W, Si or these compounds are more preferred. In the present invention, at least one compound having substantially no polyester polymerization activity is preferably a metal or a compound thereof. Moreover, it is preferable that at least one other compound having substantially no polyester polymerization activity is an organic compound. The metal or compound thereof of the present invention that does not substantially have catalyst activity for polyester polymerization is Na, K, Rb, Cs, Be, Ca, Sr, Si, V, Ci \ Ru, Rh , Pb, Te, Cu and other metals or compounds thereof, preferably Na, K, Rb, Cs, Be, Si, Cu, or these compounds. These metal compounds are not particularly limited, and examples thereof include saturated aliphatic carboxylic acid salts such as formic acid, acetic acid, propionic acid, butyric acid, and oxalic acid, unsaturated fatty carboxylic acid salts such as acrylic acid and methacrylic acid, and benzoic acid. Aromatic carbonyl acid salts; halogen-containing carboxylic acid salts such as trichloroacetic acid; hydroxy carboxylic acid salts such as lactic acid, citric acid, salicylic acid, etc., primary acid, sulfuric acid, nitric acid, phosphoric acid, phosphonic acid, hydrogen sulfonate, Inorganic acid salts such as hydrogen phosphate, hydrogen sulfide, sulfurous acid, sulfuric acid, hydrochloric acid, hydrobromic acid, chloric acid, bromic acid, etc., organic sulfonic acids such as 1-propanesulfonic acid, 1-pentanesulfonic acid, naphthalenesulfonic acid, etc. Acid salts, organic sulfates such as lauryl sulfate, alkoxylates such as methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, and 3-butoxy, and acetamidine Base-11- This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) ----------- Installation -------- Order ------- -(Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 _B7_ V. Description of the Invention (,.) B Chelates, oxides, hydroxides, and the like of acid esters; among these, saturated aliphatic carboxylic acid salts are preferred, and acetate is more preferred. Moreover, Yu metal, earth test metal, Group 5A gold hurricane, Group 6A metal, Group 7A metal, Group 8 metal, Group 1B metal, Group 2B gold metal, Group 3B metal, lead, bismuth, tellurium, silicon, boron, The amount of chromium, hydrogen, H, ruthenium, lanthanum bar metal, or these compounds used is 1X1 for the molar number of all constituent units of the carboxylic acid component such as the dicarboxylic acid or polycarboxylic acid of the obtained polyester. (Γ6 ~ 0.1 Mol is more preferred, and more preferably 5X1 "6 ~ G.05 Mol. The organic compound component of the present invention which does not substantially have polyester polymerization catalyst activity is pseudo-selected from the general formula (Formula 1) and It is preferred that the compounds of the compound of the structure of (Formula 2) be grouped. In the polyester polymerization catalyst of the present invention, the above-mentioned general formulae (Formula 1) and / or (Formula 2) used as an additive, that is, containing Ar-O- and / or Ar-N <structured compounds, specifically, compounds grouped with one or more compounds selected from compounds containing the following general formula (Formula 3) and / or (Formula 4) (Formula 3) Ar-0-χ 1 (Formula 4) X2 /

Ar-N \ X3 (where X1, X 2. X3 傺 are each independent hydrogen, hydrocarbyl, fluorenyl, sulfofluorenyl-containing group (such as sulfonic acid group or sulfonate group), phosphorus-containing fluorenyl group (such as Phosphate group or phosphate ester group), or hydrocarbon group with ether bond; Ar image represents the following aryl groups (formula 5) to (formula 12), etc. -1 2-This paper size applies Chinese national standard (CNS ) A4 size (210 X 297 mm) ------------ install -------- order --------- (Please read the precautions on the back first (Fill in this page) 490473 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (η) (Formula 5) (Formula 6) (Formula 7) (Formula 8) (Formula 9) (Formula 10) ( Equation 1 1) σ

0

〇 0

0

This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -13- -------------------- Order ------- -(Please read the notes on the back before filling this page) 〇

490473 A7 _B7 V. Description of the invention 0 &gt;) (Eq. 12)

Ar contains Ar-0-χ1 and / or represented by the general formula (Formula 5)

Ar-N (-X2) -X3 structure compounds include, for example, linear phenol compounds, linear aniline compounds, and derivatives thereof represented by the following general formulae (Formula 13) and (Formula 14), and the following general formula Branched linear phenol compounds, branched linear aniline compounds, and derivatives thereof represented by (Formula 15) and (Formula 16), or a ring represented by the following general formulae (Formula 17) and (Formula 18) Phenol compounds, aniline compounds, and their derivatives; among these, linear phenol compounds, linear aniline compounds, or cyclic phenol compounds, cyclic aniline compounds, and these derivatives are preferred . In addition, among linear phenol compounds or cyclic phenol compounds and their derivatives, 2,2′-bisphenol represented by the following formula (Formula 45), and 2 represented by the following formula (Formula 46) -Aminobiphenyl, 2,2'-dihydroxydiphenyl ether represented by the following formula (Formula 47), 2,2'-thiobis (4-th 3-octyl) represented by the following formula (Formula 48) Phenol), 2,2'-methylenebis (6-th-butyl-p-cresol) represented by the following formula (Formula 49), and methylene represented by the following formula (Formula 50) Radical cross-linked linear phenol compound (mixture of 2 to 100 polymers), methylene cross-linked linear p-th-butylphenol compound (2 to 100 polymers) represented by the following formula (Formula 51) Mixture), carbamic acid [4] arene represented by the following formula (formula 52), carbamic acid [6] arene represented by the following formula (formula 53), and- 14- The size of this paper applies to China National Standard (CNS) A4 (210 X 297 mm) ----------- installation -------- order -------- -^^ 1 (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7

V. Description of the invention (Formula A is described below, and the following 0 arene J aryl 8 f 1J acid [4 ear acid Carle formula is shown to the opposite 5) All LO \) / formula 6 5 is shown to the following. The better 7 more 5-physical formulae below equal or this, and a ^ 11 0 0 aryl]] 6 8 Γ—L Γ-L ----------- Equipment -------- Order ------ (Please read the precautions on the back before filling out this page) Employees ’Cooperatives of the Intellectual Property Bureau of the Ministry of Luxury and Economic Affairs The paper size for printing is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 V. Description of invention (w) (Formula 1 3)

_R2 (Eq. 14)

(Eq. 1 5)

----------- Equipment -------- Order --------- (Please read the precautions on the back before filling this page) Printed by the cooperative (Eq. 16) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm)

R2 -16- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7 V. Description of Invention (^) (Formula 1 7)

(Eq. 1 8)

(Wherein each R1 is a hydrocarbon group of the same or different Ci to C20, a hydroxyl group or a halogen group to a C20 hydrocarbon group, a halogen group, a carboxyl group or an ester thereof, a methyl group, a fluorenyl group, a (fluorenyl) -0 group Amine groups, amine groups, mono- or dialkylamino groups, fluorenylamino groups or their substitutes, hydroxyl groups, alkanoyl groups, alkylthio groups, sulfonyl groups, phosphoryl groups, nitro groups, Cyano and thiocyano; R2 is like the same or different fluorene, Ci ~ C20 hydrocarbyl, Ci ~ C20 hydrocarbyl with hydroxy or halogen group, halogen group, carboxyl group or ester thereof, formamyl group, fluorenyl group, (醯A base, an amine group, a mono- or dialkylamino group, a fluorenylamino group or a substitute thereof, a hydroxyl group, an alkoxy group, an alkylthio group, a sulfofluorenyl group-containing group, a phosphofluorenyl group-containing group, nitrate Base, cyano, thiocyano; X pseudo is each phase-1 7- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------ t -------- Order --------- (Please read the notes on the back before filling this page) 490473 A7 _B7_ V. Description of the invention (4) Same or different hydrogen, Ci ~ C20 Hydrocarbon group, Ci ~ C2Q hydrocarbon group with hydroxyl or halogen group, fluorenyl group, containing The acyl group, the phosphorus-containing acyl group, or hydrocarbon group having an ether bond of; the Y lines are each the same or different, a direct bond,

Ci ～ C20 susceptible group,-(diluted group) -〇-,-(susceptible group) -S_, -0-, -S-, -S02-, -CO-, -C00-; η is false to 1 ~ 100 Integer; a and c are like integers from 1 to 3, · b and d 傺 are integers from 0 or 1 to 3, but lSa + bS5, 1 ^ c + d ^ 4; the hydrocarbon group 此处 here means an alkyl group Or aryl, etc., and the molecular chain may also contain substituents such as hydroxyl or halogen groups) ------------- φ Equipment ---- (Please read the precautions on the back before filling (This page) — — — — — — Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -18- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7

V. Description of the invention (W (Formula 4 5)

OH ΗΟ (Formula 4 6) NH2 (Formula 47) (Formula 4 8) (Formula 4 9)

rfrr-butyl -19 «This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------- I--installation -------- order ---- ----- (Please read the notes on the back before filling this page) 490473 A7 B7 V. Description of the invention ((Formula 5 0)

Η (where η is any integer from 1 to 9 9 (Equation 5 1)

(Where η is any integer from 1 to 9 9 (Equation 5 2) (Please read the precautions on the back before filling this page)

ΟΗtcy〇H: 4 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 5 3) (Formula 5 4)

OH

CH2 8 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) • 20 · 490473 A7 B7 V. Description of the invention (π) (Eq. 5 5) (Eq. 5 6) (Eq. 5 7)

(Please read the precautions on the back before filling this page) ---- Order ------ Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs (Ar is Ar-0 with general formula (88) -X1 and / or Ar-N (-X2)-X structure of other examples of compounds, such as the following general formula (Formula 19) and (Formula 20) coumarin derivatives, the following general formula (Formula 21 ) And a chromone derivative represented by the formula (22), a dihydrocoumarin derivative represented by the following general formulae (formula 23) and (formula 24), the following general formulae (formula 25) and (formula 26) Chromone shown by), heterochromone shown by the following general formulae (Formula 27) and (Formula 28), chroman derivatives shown by the following general formulae (Formula 29) and (Formula 30), the following general formula (Formula 2 1-This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 _B7_ V. Description of the invention (&gt; &quot;) 3 1) and (Formula 3 2) Heterocyclic compounds such as heterochroman derivatives; among these, coumarin derivatives, chromone derivatives, or chroman derivatives are preferred. Coumarin derivatives, chromone derivatives, In particular, the following formula (Equation 58) Seven-leaf Pavilion shown, 7-amino-4-methylcoumarin shown by the following formula (Formula 59), boxwood expressed by the following formula (Formula 60), and the following formula (Formula 6 1 ), Flavin, represented by the following formula (Formula 62), 2-amino flavin, represented by the following formula (Formula 63), epicatechol, or the following formula (Formula 64) Epiphenyl benzoate and its derivatives are more preferred. (Formula 1 9)

------------ · Install ---- (Please read the phonetic on the back? Matters before filling out this page) (Formula 2 0) (x2N), (NX2) m (Formula 2 1) II --------- # Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 2 2)

〇

-22- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7

5. Description of the invention (W

_ Identical, unradical, or hydrocarbon in phase of 1 C moieties are the radicals of 傺 β.

20 C? 1 C hydroxymethyl, S, alkoxy or its base Oxycyanane, oxo, nitro, oxo, oxo

X, radicals of the same hydrogen, non-hydrocarbons of the same radical, or 20 pseudophases of the same phase

1 C

C 1 c halogen or fluorenyl phosphoryl hydroxyl group, hydrocarbon group containing 20 ^ ^ 0 containing or ο is pseudo b and • Td ·, ·, ~ 2 of the number of whole hydrocarbons ~ bond 1 ether or With CD or 僳, d d VII ο / pt but 4 VII b

The integer VII m VII dm and (Please read the precautions on the back before filling in this page) Bonding sub-point VII m and the equivalent of alkanes or aryl aromatic hydrocarbons refers to the location of the base hydrocarbon. The basic halogen or hydroxyl group can also be set. 丨 ## Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with China National Standard (CNS) A4 (210 X 297 mm) 473 A7 B7

V. Description of the invention (W (Formula 2 3) (Formula 2 4) (Formula 2 5) (Formula 2 6) (Formula 2 7)

〇

------------ Installation -------- Order ---------. (Please read the precautions on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Employee Consumer Cooperatives (Form 2 8)

* 24— This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm)

490473 A7 B7 V. Description of the invention (3) (wherein each R is a same or different Ci ~ C20 hydrocarbon group, a hydroxyl group or a halogen group Cl ~ C 20 hydrocarbon group, a halogen group, a carboxyl group or an ester thereof, formazan Group, fluorenyl group, amine group, amine group, mono- or dialkylamino group, fluorenylamino group or its substitute, hydroxyl group, alkoxy group, alkylthio group, sulfonyl group-containing group Group, phosphorus-containing fluorenyl group, nitro, fluorenyl, thiocyano; X like the same or different hydrogen, Ci ~ C20 hydrocarbyl, Ci ~ c2 with hydroxyl or halogen group, hydrocarbyl, fluorenyl, containing Sulfofluorenyl group, phosphorus-containing phosphonium group, or hydrocarbon group with ether bond; a is an integer of 1 to 3; b 傺 is an integer of 0 or 1 to 3; P and Q 僳 are 0 or 1 to 2 Integer; only; LSa + b contains 4, (^ p + q contains 2. The hydrocarbon group 此处 refers to an alkyl group or an aryl group, and the molecular chain may also contain a substituent such as a hydroxyl group or a halogen group) ( Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -25- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) DESCRIPTION invention () (Formula 29) (Formula 30) (Formula 31) (Formula 32)

(ox) c ⑻d

(X2N)

------------------- ^ --------- (Please read the notes on the back before filling out this page) Employees ’Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Printing (where each I is pseudo or identical to a Ci ~ c20 hydrocarbon group, Ci-Cso hydrocarbon group having a hydroxyl group or a halogen group, a halogen group, a carboxyl group or an ester thereof, a methyl group, a fluorenyl group, (fluorenyl) -〇-, a amine group, an amine group, a mono- or di-alkyl amine group, a fluorenyl amine group or a substitute thereof, a hydroxyl group, an alkoxy group, an alkylthio group, a sulfonyl group-containing group, a phosphonium-containing group , Nitro, cyano, thiocyano, · X pseudo each is the same or different hydrogen, Ci-Cso hydrocarbon group, Ci ~ c2 with hydroxyl or halogen group, hydrocarbon group, fluorenyl group, sulfonyl group-containing group, containing Phosphonium base-2-6- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7

V. Description of the invention (π group or a hydrocarbon group having an ether bond, · a 傺 is an integer of 1 to 3; b 傺 is an integer of G or 1 to 3; c and d 傺 are integers of 0 or 1 to 3; Iga + bS 4, 0 &lt; c + dg3; The hydrocarbyl group referred to herein represents an alkyl group or an aryl group, and the molecular chain also contains a substituent such as a hydroxyl group or a halogen group) (Formula 5 8) (Formula 5 9) ---------- Installation -------- Order --------- ^ _ w (Please read the notes on the back before filling this page) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Consumer Cooperatives

〇 The size of private paper is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 V. Description of the invention (4 (formula 60) OH 〇 〇

HO (Equation 6 1) OH 0

.OH HO,, 〇 '

OH (Please read the notes on the back before filling this page) (Eq. 6 2) 0, nh2 (Eq. 6 3)

OH

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 6 4)

OH

OH This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -28-

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7_ V. Description of Invention (&gt; 7)

Ar is a compound containing an Ar-0-χ1 and / or A 1-N (-X 2)-X 3 structure represented by general formula (89), and has the following general formulae (Formula 33) and (Formula 34) The naphthalene derivative shown, or a dinaphthyl derivative represented by the following general formulae (Formula 35) and (Formula 36), etc .; among these, 4, 5- Disodium dihydroxynaphthalene-2,7-disulfonic acid, 1,8-diaminofluorene represented by the following formula (Formula 66), Naphthol AS represented by the following formula (Formula 67), and the following formula 1, represented by (Formula 68): T-bis-2-fluorenol, 1,1'-difluorenyl-2, 2 ^ diamine represented by the following formula (Formula 69), and derivatives thereof Among them, 4,5-dihydroxynaphthalene-2,7-disulfonic acid disodium or 1,8-diaminonaphthalene and derivatives thereof are more preferable. (Eq. 3 3)

(Formula 34) (wherein each R image is the same or different Cj_ ~ C20 hydrocarbon group, Ci-Cso hydrocarbon group having a hydroxyl group or a halogen group, a halogen group, a carboxyl group or an ester thereof, a methyl group, a fluorenyl group, (醯Group)-0-based group, amine group, mono- or dialkylamino group, fluorenylamino group or its substitute, hydroxyl, alkoxy, alkylthio group, sulfonyl group-containing group, phosphorus-containing fluorenyl group Base, δ poetry, cyano, thiocyano; X 僳 is the same or different hydrogen, Ci ~ C20 hydrocarbon, hydroxyl or halogen -29- This paper applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) ----------- Installation -------- Order --------- (Please read the precautions on the back before filling this page) 490473 A7 _B7_, 28 V. Description of the invention Ci ~ C20 hydrocarbyl group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether group-containing hydrocarbon group; j, b, and d are 0 or 1 An integer of ~ 3; but 0 contains j + b contains 4, 0Sc + d ^ 4, lSj + c contains 6. The hydrocarbon group 傺 referred to here represents an alkyl group or an aryl group; and the molecular chain may also contain a hydroxyl group or _ prime Substituents such as radicals (formula 3 5)

(Formula 3 6) (Please read the Zhuyin on the back? Matters before filling out this page)

Printing of clothing by employees' cooperatives in the Intellectual Property Bureau of the Ministry of Economic Affairs

(Wherein each R 傺 is the same or different Ci ~ C20 hydrocarbon group, Ci ~ c20 hydrocarbon group having hydroxyl group or halogen group, halogen group, carboxyl group or ester thereof, formamyl group, fluorenyl group, (fluorenyl) -0 -Bases, amines, mono- or dialkylamines, amido groups or their substitutes, hydroxyl, alkoxy, alkylthio, sulfofluorenyl-containing groups, phosphorofluorenyl-containing groups, nitrates Cyano, cyano, thiocyano; X -30- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 Hydrogen, Ci ~ C2, hydrocarbon group, Ci ~ c20 hydrocarbon group with hydroxyl group or haloyl group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether bond-containing hydrocarbon group; each of Y 傺 is Same or different direct keys,

Ci ～ C20 dilute base,-(susceptor) -〇-,-(susceptor) -S-, -0-, -S-, -SO 2 -C0-, -COO-; j, b, c, d , E, f, g, and h 傺 are integers of 0 or 1 to 3; only 0 ^ j + bS4, OS c + dS 3, OS e + fg 4, Ogg + h contains 3, l £ j + c + d + e + gS12. The hydrocarbyl group here refers to an alkyl group or an aryl group, and the molecular chain may also contain a substituent such as a hydroxyl group or a halogen group. (Please read the precautions on the back before filling this page.) --- # Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy-3 1- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 V. Description of the invention (^) (Eq. 6 5)

Na03S

OH OH S03Na (Equation 6 6)

(Please read the notes on the back before filling this page) (Eq. 6 8)

(Formula 6 9) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

NH2 nh2 * 32 · This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 V. Description of the invention (3 1

Ar is a compound containing the structure of Alm-0-χ1 and / or Ar-N (-X2) -X3 shown in General Formula Test 90) or Test: 91), for example, the following general formula (Formula 37) and (Formula 38) derivatives shown in the following formulae; among them, deoxyalizarin shown in the following formula (formula 70), and 9, 10 -dimethoxyoxide shown in the following formula (formula 71) Quinones, or 2-amino groups represented by the following formula (formula 72) and derivatives thereof are preferred; among these, deoxyalienin and its derivatives are more preferred. (Eq. 37)

(Eq. 3 8)

----------- Installation -------- Order --------- * 5 ^ 1 ^ (Please read the notes on the back before filling this page) Ministry of Economy Intellectual Property Bureau Employees' Consumer Cooperative printed or halogen-based Ci ~ c20 hydrocarbon groups, halogen groups, carboxyl groups or esters thereof, formamyl groups, fluorenyl groups, (fluorenyl) -0-based groups, amine groups, single or Dialkylamino, fluorenylamino or its substitute, hydroxyl, alkoxy, alkylthio, sulfofluorenyl-containing group, phosphorus-fluorenyl-containing group, nitro, cyano, thiocyano; X 僳Each is the same or different hydrogen, Cl ~ c20 hydrocarbon group, Ci ~ C hydrocarbon group with hydroxyl or halogen group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether bond-containing hydrocarbon group; j, b, e, and f are integers of 0 or 1 ~ 3-3-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 V. Description of the invention (32 P and q 傺Is an integer of 0 or 1 to 2; however, 0 + j + b ^ 4, 0Sp + q ^ 2, (^ θ + 1 includes j + p + eS8; the hydrocarbon group 僳 referred to here means an alkyl group or an aryl group, The molecular chain may also contain a substituent such as a hydroxyl group or a halide group (formula 70)

(Eq. 7 1)

(Eq. 7 2)

----------- Installation -------- Order --------- (Please read the notes on the back before filling this page) Printed by a cooperative

Ar is a compound containing an Ar-0-χ1 and / or Ar-N (-X2) -X3 structure represented by the general formula (92), for example, benzene represented by the following general formulae (Formula 39) and (Formula 40) Alcohol derivatives and the like; Among these, 2,5-dihydroxybenzophenone and its derivatives represented by the following formula (Formula 73) are preferred. -34- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 V. Description of the invention ((Formula 3 9) 3 3 Ο

(Equation 4 0) 〇

(Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

(Wherein each R is the same or different Ci ~ C20 hydrocarbon group, Ci ~ C20 hydrocarbon group having a hydroxyl group or halogen group, halogen group, carboxyl group or ester thereof, formamyl group, fluorenyl group, (fluorenyl) -〇- The indicated group, amine group, mono- or dialkylamino group, fluorenylamino group or its substitute, hydroxyl group, alkane group, alkylthio group, sulfofluorenyl group-containing group, phosphofluorenyl group-containing group, nitro group , Cyano, thiocyano; X pseudo each is the same or different hydrogen, Ci ~ C20 hydrocarbyl, Ci ~ c20 hydrocarbyl with hydroxyl or haloyl group, fluorenyl group, sulfonyl group, phosphoryl group K, 1, P, and q 僳 are integers of 0 or 1 to 2; but 0 contains k + 1 ^ 2, 0 contains p + qg2, 3LSk + pS4. Refers to here The hydrocarbon-based image represents an alkyl group or an aryl group, and the molecular chain may also contain a substituent such as a hydroxyl group or a halogen group. (Formula 7 3) This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7_, 34 V. Description of the invention ()

Ar is a compound containing an Ar-0-χ1 and / or Ar-N (-X2) -X3 structure represented by a general formula (Formula 93) or (Formula 94). For example, the following general formula (Formula 41) and (Formula 42) fluorenone derivative represented by the following formula; among them, 5,8-dihydroxy-1,4-naphthalene represented by the following formula (Formula 74) or the following formula (Formula 75) 2-aminonaphthalene and its derivatives are preferred.

(Equation 4 2) ----------- install ---- (Please read the precautions on the back before filling this page)

Order --- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (wherein each R 傺 is the same or different Ci ~ C20 hydrocarbyl group, Ci ~ C20 hydrocarbyl group with hydroxyl group or halogen group, halogen group, carboxyl group, or Ester, formamyl, fluorenyl, (fluorenyl) -0-, amine, mono- or dialkylamino, fluorenylamino or its substitution, hydroxyl, alkoxy, alkylthio, Sulfofluorene-containing group, phosphorous fluorenyl-containing group, nitro, cyano, and thiocyano; X pseudo each is the same or different hydrogen, Ci ~ C20 hydrocarbon group, Ci ~ C 2Q with hydroxyl or halogen group Hydrocarbyl, fluorenyl, sulfofluorenyl-containing groups (such as sulfonic acid groups or sulfonate groups), phosphorus phosphonium-containing groups (such as phosphate groups or phosphate groups, etc.), or hydrocarbon groups with ether linkages; k and 1 Like an integer of 0 or 1 ~ 2, c and d are -3 6-This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 _ B7 V. Description of invention (nu) 0 or An integer of 1 to 3; only 0 ^ k + lS2, 0 ^ c + d ^ 4, 1 gk + c S5. The hydrocarbon group 傺 referred to here means an alkyl group or an aryl group, and the molecular chain may also contain a hydroxyl group or Substituents such as halo (Formula 74)

(Equation 7 5) (Please read the precautions on the back before filling this page)

Order --- ## Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

Ar is a compound containing an Ar-0-χ1 and / or Ar-N (-X 2) _ X 3 structure represented by a general formula (Formula 95), for example, the following general formulas (Formula 4 3) and (Formula 4) 4) Derivatives and the like shown in the above; among them, alizarin represented by the following formula (Formula 76), alizarin represented by the following formula (Formula 77), and represented by the following formula (78) Alcohol, catechol represented by the following formula (Formula 79), emodin represented by the following formula (Formula 80), and 1,4-diamine group represented by the following formula (Formula 81) _, 1,8-diamino-4, 5-dihydroxylidine represented by the following formula (formula 82), or acid blue 25 represented by the following formula (formula 8 3) and derivatives thereof Among these, quinolizin or 1,4-diamino radical and derivatives thereof are more preferable. -37- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 V. Description of the invention (竓) (Formula 4 3) 〇

(Equation 4 4)

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (wherein each R is pseudo C or C; a hydrocarbon group of 1 to C20, a Ci ~ C20 hydrocarbon group having a hydroxyl group or a halogen group, a halogen group, a carboxyl group or an ester thereof, a beetle Group, fluorenyl group, (fluorenyl) -〇- group, amine group, mono- or dialkylamino group, fluorenylamino group or its substitute, hydroxyl group, alkoxy group, alkylthio group, sulfofluorenyl group Radicals (such as sulfonyl, sulfonate), phosphorus-containing phosphonium (such as phosphate, phosphate), nitro, fluorenyl, and thiofluorenyl; each X is the same or different hydrogen, Cl ~ c20 hydrocarbon group, C with hydroxyl or halogen group: L ~ C2Q hydrocarbon group, fluorenyl group, sulfonyl group (such as sulfonic acid group or sulfonate group), phosphorus phosphonium group (such as phosphate group or Phosphate group), or a hydrocarbon group having an ether bond; j, b, c, and d are like Q or an integer of 1 to 3; but OSj + b 4,4; c + dg4, lSj + cg6. The hydrocarbyl group pseudo-represents an alkyl group or an aryl group, and the molecular chain may also contain a substituent such as a hydroxyl group or a halogen group) -38- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) --- ----- ----------- Order --------- (Please read the notes on the back before filling this page) 490473 A7 B7

V. Invention Description (W (Formula 7 6)

(Equation 7 7) Ο ΟΗ

ΟΗ (Please read the precautions on the back before filling this page) Equipment (Equation 7 8) Ο ΟΗ

(Formula 7 9) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 8 0) Ο ΟΗ

〇Η .39 · The paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 _B7 v 38 V. Description of the invention () (Formula 8 1)

(Equation 8 2) (Equation 8 3)

(Please read the phonetic on the back? Matters before filling out this page) Decoration ϋ an I-one dJ 1 ϋ · ϋ ϋ The amount of this additive is based on the mole number of the coexisting metal containing fi) 0 / 0 1 ~ 1 0 0 Mor is better, more preferably 0. 5 ~ 50 0 Mor. The manufacturing method of the polyester of this invention can be performed by a conventional method. For example, the polymerization method of PET includes a method of polycondensing terephthalic acid and ethylene glycol, or transesterifying an alkyl ester of terephthalic acid such as dimethyl benzoate with ethylene glycol. Post-polycondensation method. Moreover, the polymerization device may be a segmented type or a continuous type. The catalyst of the present invention has catalyst activity not only for polycondensation reaction but also for esterification reaction and transesterification reaction. For example, dimethyl terephthalate-40- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) # Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7 V. Description of the invention (39 Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, before the appointment, this report did not add any equivalents or esters. PPΦ refers to the application of germanium and the application of the needle, and the accumulation of 501π with this material. Melt the anti-addition agent ~ Additions add up to a total of ^ 20. The combination can be combined to form the addition of β-upon neutron Fofni below, too, shrinking the final shape is a titanium alloy of different components When the former is stored, only the powder that is only agglomerated is differentiated into gold, and the ilnl MBJ original m is stored. If the agent is not alive, it should be dissolved in PP, and the germanium PP is borrowed from the co-agent to reverse. Cocoa or Cocoa can be added to 30U as a 10-type catalyst. In addition, the mixture is also added to Tianhua and added the word U as the alcohol replacement catalyst. The antimony period is first. The amount of the added M. When the amount of words is urged, sometimes the ester should be added to the ester when the preform is prepared, and the added ester is added or reversed. It is a combination of additives and additives, such as polysaccharides, U, esters, alcohols, and other ingredients. The additives should be mixed with the additives, and the metabolized person f is the polyglyceride. Contains the best catalyst to promote the production of good or bad, polymer additives, etc., so as to make more homogeneous products, so it is more compatible with and liquefied esters in the alcohol and does not shrink when combined. cfflff. Soluble with the esterifying agent. The catalyst in the second step is the same or agglomeration, Jujia PP, Hejiayuan titaniumized c or ester can be combined with B and C, the heterogeneity is different from 50. The catalysts that are used for polymerization are also reduced and the system can be cohesived. The amount of its physical material is equal to or equal to the amount of acid M. It is only for polymerization, and the limit is also added to increase the spot and add money. This reminder of the system, and so on, there should be things, and the amount of chemical additives should be combined with black, instead of solid method hair should be added in addition to anti-combine antimony antimony, and the combination of biochemical equality and Fangben is the way to take the tincture and add the germanium and hypoglycerol polybutadiene polybutadiene to be added after the combination. Add germanium to the middle (please read the precautions on the back before filling this page) ) This paper size applies Chinese National Standard (CN S) A4 specification (210 X 297 mm) 490473 A7 _B7__ v 4 0 V. Description of the invention () When the added amount is greater than 20ppm, it is not beneficial to the cost, so it is not a requirement. (Please read the precautions on the back before filling this Page) Suitable compounds of antimony compounds that can be added are antimony trioxide and antimony pentoxide, especially antimony trioxide is preferred ^, and germanium compounds include germanium dioxide and germanium tetrachloride, especially germanium dioxide is preferred In addition, other polymerization catalysts such as titanium compounds, tin compounds, and cobalt compounds include tetra-n-propyl phthalate, tetraisopropyl phthalate, tetra-n-butyl phthalate, tetra-isobutyl phthalate, and phthalic acid. Tetra-n-butyl acid, tetrahexyl phthalate, tetraphenyl phthalate, tetraphenyl methyl phthalate, etc., especially tetrabutyl phthalate is preferred. Examples of the tin compounds include dibutyltin oxide, methylphenyltin oxide, tetraethyltin, hexaethylditin oxide, triethyltin argon gas, monobutylhydroxytin oxide, and triisocyanate. Butyl, tin acetate, diphenyltin dilaurate, monobutyltin trichloride, dibutyltin sulfide, dibutyltintin oxide, methylmethanone acid, ethylmethanone acid, etc., especially The use of monobutyltintin oxide is preferred. The polyester of the present invention refers to one or two or more polycarboxylic acids selected from the group consisting of dicarboxylic acids and ester-forming derivatives thereof and one or two or more polyvalent alcohols selected from the group consisting of alcohols. Or by hydroxycarboxylic acids and their ester-forming derivatives, or by cyclic esters. Dicarboxylic acids printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs include oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, and decane Dicarboxylic acid, dodecanedicarboxylic acid, tetradecanedicarboxylic acid, hexadecanedicarboxylic acid, 3-cyclobutanedicarboxylic acid, 1,3-cyclopentanedicarboxylic acid, 1,2-cyclo Saturated aliphatic dicarboxylic acids such as hexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,4-pentanehexanedicarboxylic acid, 2,5-ortho-cyclohexanedicarboxylic acid, and dimer acids Or these ester-forming properties -42- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7___, 4 1 V. Description of the invention () (Please read the notes on the back first (Fill in this page again) Biology, unsaturated fatty dicarboxylic acids such as fumaric acid, maleic acid, itaconic acid or their ester-forming derivatives, orthobenzoic acid, isobenzoic acid, p-benzoic acid, 5 -(Alkali metal) sulfoisobenzoic acid, diphenylindenoic acid, 1,3-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 1,5-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid Acid, 2,7-naphthalenedicarboxylic acid, 4,4 pyrene dicarboxylic acid, 4 Aromatic aromatic compounds such as 4,4'-biphenyl coded dicarboxylic acid, 4,4 biphenyl ether dicarboxylic acid, 1,2-bis (phenoxy) ethane-ρ, ρ ^ dicarboxylic acid, and dicarboxylic acid Group dicarboxylic acids or these ester-forming derivatives. Polycarboxylic acids other than these dicarboxylic acids are, for example, ethanetricarboxylic acid, propanetricarboxylic acid, butanetricarboxylic acid, pyromellitic acid, trimellitic acid, pyromellitic acid, 3,43 3 *, 4'-biphenyltetracarboxylic acid, and ester-forming derivatives thereof. Examples of alcohols produced by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs are ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, diethylene glycol, triethylene glycol, 1,2-butanediol, 1, 3-butanediol, 2, 3-butanediol, 1,4-butanediol, 1,5-pentanediol, neopentyl alcohol, 1,6-hexanediol, 1,2-cyclohexanediol , 1,3-Hexanediol, 1,4-Hexanediol, 1,2-cyclohexanedimethanol, 1,3-cyclohexanedimethanol, 1,4-cyclohexanedimethanol, 1 , 10-decamethylene glycol, 1,12-dodecanediol, polymethylene glycol, polytrimethylene glycol, polytetramethylene glycol and other aliphatic alcohols, hydroquinone, 4,4 · -dihydroxy Bisphenol, 1,4-bis (/?-Hydroxyethyloxy) benzene, 1,4-bis (&gt; ff-hydroxyethoxyphenyl) fluorene, bis (p-hydroxyphenyl) ether, bis ( P-hydroxyphenyl) code, bis (p-hydroxyphenyl) methane, 1,2-bis (p-hydroxyphenyl) ethane, bisphenol A, bisphenol C, 2,5-tridiol, this To other alcohols, aromatic alcohols such as ethylene oxide alcohols are added. -43- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 _B7__ 4 2 V. Description of the invention () Polyols other than these alcohols, such as trimethylolmethane, trimethylol Ethane, trimethylolpropane, pentaerythritol, glycerol, hexanetriol and the like. (Please read the precautions on the back before filling this page.) Examples of hydroxycarboxylic acids are lactic acid, citric acid, malic acid, tartaric acid, glycolic acid, 3-hydroxybutyric acid, p-hydroxybenzoic acid, and p- (2-hydroxyethoxylate). Group) benzoic acid, 4-hydroxycyclohexanecarboxylic acid, or these ester-forming derivatives. Examples of the cyclic ester include ε-caprolactone, 0-propiolactone, ^ -methyl-ban-propiolactone, valerolactone, glycolide, and lactide. Examples of the ester-forming derivatives of polycarboxylic acids and hydroxycarboxylic acids include alkyl esters, acid chlorides, and acid anhydrides. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Moreover, the polyester of the present invention may contain a conventional phosphorus compound as a copolymerization component. Phosphate stripe compounds are preferably pseudofunctional, such as dimethyl phenyl phosphate, phenyl diphenyl phosphate, (2-carboxyethyl) methylphosphinic acid, (2-carboxyethyl) benzene Hypophosphorous acid, (2-methoxycarboxyethyl) phenyl hypophosphite, (4-methoxycarbonylphenyl) phenyl hypophosphite, hydroxyethoxycarbonyl) ethyl] methylphosphite Ethylene glycol ester of phosphoric acid, (1,2-dicarboxyethyl) dimethylphosphine oxide, 9, 10-dihydro-10-oxo- (2,3-carboxypropyl) -10-phenanthrene- 10-Gas and so on. The use of such phosphorus strip compounds as a copolymerization component can improve the flame retardancy and the like of the obtained polyester. The polyesters of the present invention are especially polyethylene terephthalate, polybutylene terephthalate (PBT), polybutylene terephthalate, and poly (terephthalate \ 1,4-cyclohexane Alkylene dimethylene) (CHDM-modified PET), polyvinyl naphthalate (PEN), polybutylnaphthyl naphthalate, and copolymers of these are more preferred, such as _ 4 4-This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7___ 5. In the description of the invention (43), polyethylene terephthalate is the best. The polyethylene terephthalate referred to in the present invention is like a polyester formed mainly by repeating the unit of terephthalate, and is formed by containing terephthalic acid or its ester for all acid components. Polyesters with a total amount of 70 mol% or more are preferred, more preferred are polyesters containing 80 mol% or more, and most preferred are polyesters containing 90 mol% or more. The main alcohol component is ethylene glycol. For all alcohol components, it is better to use a polymer with a total ethylene glycol content of 70 mol% or more. The more preferred is a polyester containing 80 mol% or more. The best is Polyester containing 90 mol% or more. In the polyethylene naphthalate referred to in the present invention, the main acid component of fluorene is naphthalenedicarboxylic acid or an ester-forming derivative thereof, and the main alcohol component is a polyester of ethylene glycol. Polyesters whose main acid component is naphthalenedicarboxylic acid or its ester-forming derivative. Compared with polyesters which contain a total of 70 mol% of naphthalenedicarboxylic acid or its ester-forming derivative for all acid components, It is better, more preferred is polycool containing 80 mol% or more, and most preferred is polyester containing 90 mol% or more. Polyesters whose main alcohol component is ethylene glycol, polyesters containing more than 70 mol% ethylene glycol are preferred for all alcohol components, and more preferably polyesters containing 80 mol% or more The best is polyester containing 9Q Mohr J: or more. As the naphthalenedicarboxylic acid or its ester-forming derivative used for the original polyethylene naphthalate, 1,3-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, and 1,5-naphthalenedicarboxylic acid Carboxylic acids, 2,6-fluorenedicarboxylic acid, 2,7-naphthalenedicarboxylic acid, or these cool-forming derivatives are preferred. Among these, 2,6-naphthalenedicarboxylic acid or an ester-forming derivative thereof is more preferable. -4 5-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------ | ^^ Cloth -------- Order-- ------- (Please read the note on the back? Matters before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7__ 4 4 V. Description of the invention () PET 傺 is the main acid component. Terephthalic acid or an ester-forming derivative thereof. The polyester whose main alcohol component is 1,4-butanediol. Polyesters whose main acid component is terephthalic acid or its ester-forming derivative. Compared with polyesters containing naphthalenedicarboxylic acid or its ester-forming derivative, the total acid content is 70 mol% or more. It is better, more preferred is a polyester containing 80 mol% or more, and most preferred is a polyester containing 90 mol% or more. The main alcohol component is ethylene glycol. A polyester containing 70 mol% or more of ethylene glycol is preferred for the total alcohol component, and a polyester containing 80 mol% or more is more preferred. Polyester containing 90 mol or more. In addition, when the catalyst of the present invention is used as a polymerization catalyst for PET, the by-product of tetrahydrofuran can be effectively suppressed. The poly (trimethylene terephthalate) referred to in the present invention is a polyester whose main acid component is terephthalic acid or an ester-forming derivative thereof and whose main alcohol component is 1,3-propanediol. Polyesters whose main acid component is naphthalenedicarboxylic acid or its ester-forming derivative. Compared with polyesters which contain a total of 70 mol% or more of naphthalenedicarboxylic acid or its ester-forming derivative, Better, more preferred is a polyester containing 80 moles 3! Or more, and most preferred is a polyester containing 90 moles or more. Polyesters whose main alcohol component is ethylene glycol, polyesters containing more than 70 mol% ethylene glycol in terms of gold alcohol content are preferred, and polyesters containing more than 80 mol% are more preferred The best is a polyester containing more than 90 mol%. The copolyester (CHD Μ-Ρ Ε) of cyclohexanedimethanol referred to in the present invention is mainly composed of terephthalic acid or an ester-forming derivative thereof, and is composed of ethylene glycol or cyclohexane. Alkyl dimethanol is a polyester whose main alcohol component is. Main -46- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------ Installation -------- Order --- (Please Read the phonetic on the back? Matters and then fill out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7_ V. Description of the invention (4Γ) The acid component is copolymerization of terephthalic acid or its ester-forming derivative The ester is a polyester containing terephthalic acid or an ester-forming derivative thereof having a total content of 9 Q mole% or more of the gold acid component. The main alcohol component is a copolyester of ethylene glycol or cyclohexanedimethanol, which means that the alcohol component of the copolyester contains 90 ~ 5 mole% ethylene glycol and 10 ~ 95 mole% cyclohexane Copolyesters containing methanol and alcohols other than ethylene glycol and cyclohexanedimethanol with a content of 10 mol% or less. The cyclohexanedimethanol used in the present invention is preferably 1,2-cyclohexanedimethanol, 1,3-fluorenehexanedimethanol, or 1,4-cyclohexanedimethanol. Among these, 1,4-cyclohexanedimethanol is more preferable. Polyethylene terephthalate, polybutylene terephthalate (PBT), polytrimethylene terephthalate, poly (1,4-pentanehexanedimethylene terephthalate) (CHD Μ modified PET), polyvinyl acetate (PEN), polybutylene naphthalate, in addition to the acid component and alcohol component of its main component, can also be copolymerized according to its needs. Suitable components of the polycarboxylic acid, polyhydric alcohol and the like mentioned above. The polymerization of the polyester used in the polymerization catalyst used in the production of the polyester of the present invention can be carried out by a conventional method. In other words, taking PE ET as an example, terephthalic acid and its ethylene glycol with twice the molar amount were placed in a bath autoclave with a stirrer and added at 2.5 kg / C Μ 2 The resulting water was distilled off at a pressure of 2 4 5 ° C, and the esterification reaction was performed to obtain bis (2-hydroxyethyl) terephthalate. Calculated from the amount of distilled water, the pressure was released at an esterification rate of 95%. The catalyst was added thereto, and the mixture was stirred in a nitrogen atmosphere at a pressure of 2 4 5 ° C for more than 10 minutes. Then, at 50-4 7-this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----------- installation -------- order- -------- (Please read the note S on the back before filling out this page) 490473 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7__ 5. Description of the invention (you) The temperature rises to 2 7 5 in minutes ° C, and slowly reduce the pressure of the reaction strip to 0.1 Torr, and at 275 ° C, 0.1 Torr, stirring at a certain speed, and a polycondensation reaction to polymerize polyethylene terephthalate. The time required for the polycondensation reaction is referred to as the polymerization time. The AP of the present invention uses the method described above to polymerize poly (ethylene terephthalate) with an intrinsic viscosity of 0.5 dl / g (min). For the determination of T, antimony trioxide is used as a commercially available antimony trioxide, such as Antimony (m) oxidl made by ALDRIC, with a purity of 99.999%, and stirred at 150 ° C for about 1 hour to dissolve into a concentration in the ethylene glycol solution. To the solution of about 10 g / L, antimony trioxide having an antimony atom of 0.05 mol for the acid component in the produced polyethylene terephthalate was added. The compounds referred to in the present invention that do not substantially have catalyst activity for polyester polymerization are assumed to have a critical activity parameter (LP) that can satisfy LP (mi η) &gt; 2 T (mi η), where LP 傺 is obtained by The time (min) required for the above method to polymerize polyethylene terephthalate with an intrinsic viscosity of 0.3 dl / g. Second, compounds that do not have substantially the catalyst activity of polyester polymerization are assumed to satisfy AP (min) &lt; 2T (min). Better AP (min) &lt; 1.5T (min), better AP (min) &lt; T (min). The polyester of the present invention may contain stabilizers such as phosphorus bars, sulfur bars, and amine bars, or antioxidants such as phenol bars and aromatic amine bars. By containing one or more of these, the thermal stability of the polyester can be further improved. Phosphate stabilizers include phosphoric acid esters such as phosphoric acid and trimethyl phosphate, phosphorous acid, triphenyl phosphide, ginseng (2,4-di-th-butylphenyl) phosphide, and (2, 4-Di-third-butylphenyl) 4,48'-diphenylene diphosphide, etc. -48- (Please read the notes on the back before filling this page) Binding --- # This paper size Applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 490473 A7 B7_ V. Description of the invention (V)) Phosphite, methylphosphonic acid, phenylphosphonic acid One of the phosphonic acids and phosphonic acids or dialkyl esters. Examples of phenolic bar antioxidants include methyl- [methyl-3-(3 ', 5'-di-th-butyl-4-hydroxyphenyl) propanoic acid] methyl ester, and 4,4'-sulfinyl bis -(3-methyl-6-th-butylphenol) and the like. After the polyester is polymerized by the method of the present invention, the catalyst is removed from the polyester, or the catalyst is deactivated by adding a phosphorus compound or the like to further improve the thermal stability of the polyester. The polyester of the present invention may contain a blue compound such as a cobalt compound, toners for organic strips, inorganic strips, and organometallic strips, and fluorescent brighteners. By containing one or two or more of these, Etc., can inhibit the yellowing of polyester and other colors. In addition, it may contain other optional polymers or stabilizers, antioxidants, electric generators, defoamers, dyeability improvers, dyes, pigments, anti-glare agents, fluorescent whitening agents, and other additives. When the polyesters such as PBT and poly (trimethylene terephthalate) of the present invention are used in molded parts such as automobile parts or electrical and electronic parts, the reinforcing materials such as glass fiber can be filled, and the inorganic concrete filling materials can be used to improve the molding. Product size stability, strength, rigidity. The polyester of the present invention can be obtained by a conventional method (for example, an extrusion method, a calender method, etc.). After being melted and extruded, it is cooled to an unstretched film, and then sequentially stretched in two axes, simultaneously stretched in two axes, and vertically in one axis. Stretching, transverse uniaxial stretching, or a combination of these are stretched to obtain a stretched film. In biaxial stretching, sequential biaxial stretching is particularly effective, and the order of these vertical and horizontal directions may be either. The stretching ratio varies depending on the application, and the aspect ratio is preferably 2 to 7 times. The biaxially stretched film obtained by biaxial stretching can be used for various purposes, but especially -4 9 ~ This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------ ------ Installation -------- Order ----- (Please read the precautions on the back before filling this page) 490473 A7 _B7___ v 48 5. Description of the invention () Tape is best. (Please read the precautions on the back before filling in this page) Moreover, 1 direction is 2. 5 ~ 7.0 (preferably 3.0 ~ 6.0) to be stretched, and the direction perpendicular to the direction is 1.0 ~ 2. Q 倍 Q (Preferably 1.1 to 1.8 times) It is stretched to obtain a film having excellent heat shrinkability. At this time, the stretching in the initial direction is mainly to obtain high heat shrinkability, and the stretching at right angles to the initial direction can solve the impact resistance or crack resistance of the film stretched in the first direction. Problem. The heat-shrinkable film obtained in this way can be used for packaging purposes, especially food and beverages, pharmaceuticals, and other various commodities. The contents of the package can be displayed or the raw materials of the product can be sold, and the label can be prevented when the product is packaged. Or foreign matter is mixed in the product at the sealed mouth of the container to prevent the product from deteriorating. Safe packaging to prevent contamination during the display or packaging materials when bundling the product. There is no particular limitation on the stretching method, and examples thereof include reed stretching, long-gap stretching, tenter stretching, and tubular stretching. In addition, hot pressing may be performed depending on the purpose during stretching. The thickness of the film is preferably 1 ~ 3G0AH1. In the polyester film using the catalyst of the present invention, foreign substances are rarely generated by the polymerization catalyst, and there is no thermal deterioration during melt molding. As a result, mold contamination rarely occurs during melt extrusion, and the surface of the film has few defects and coloring. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The polyester of the raw material of the polyester film of the present invention may be added as a smoothing agent to impart slippery properties as required. As the smoothing agent, for example, silicon dioxide, aluminum oxide, cobalt silicate, Ba S 0 4, Ca S 0 4 and the like can be used. The polyester 傺 of the present invention is suitable for molded products, especially hollow molded products such as pellet bottles, which is called hollow molded products of pellet bottles. 傺 Use PE Μ-50.-This paper size applies to Chinese national standards (CNS ) A4 size (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7__ 5. Description of the invention () 4 9 or PET is preferred, PET is preferred. The intrinsic viscosity of polyester for hollow molded articles such as pellet bottles is Q · 5 7 to 0.90 dl / g, preferably 0.58 to Q. 88 dl / g, and more preferably 0.60 to 0.85 dl / g. When it is less than 0.57 dl / g, the mechanical properties of the obtained hollow molded product and the like are not good. When it is greater than 0.9 Gdl / g, the temperature of the resin is increased during melting by a molding machine or the like, which causes intense thermal decomposition, affects the fragrance retention, increases the number of free low-molecular-weight compounds, and the hollow molded product is colored yellow. The problem arises. In addition, PET for the hollow molded product is used as the diethylene glycol of the alcohol component, and 1.5 to 5.0 mol% of the alcohol component is preferably used, and 1.6 to 4.5 mol% is more preferable, More preferred is 1.7 to 4.0 mole%. When the amount of diethylene glycol is less than 1.5 mol%, the transparency of the obtained hollow molded product is not good. When the amount of diethylene glycol is greater than 0.5 mol S :, the glass transition point of the polyester resin will be reduced, and the heat resistance of the obtained hollow molded product will be reduced. Due to poor thermal stability, acetaldehyde is formed during molding. The increase of the content greatly increases, which affects the fragrance retention. The polyester for hollow molded articles such as pellet bottles preferably has an acetaldehyde content of 1 Qppm or less, more preferably 8 ppm or less, and even more preferably 5 ppm or less. If the content of acetaldehyde is more than 10 PPra, the flavor or odor of the contents of the container or the like formed from the polyester is not good. The acetaldehyde content in the raw polyester can be reduced by solid phase polymerization. In the polyester for hollow molded products, the content of the cyclic terpolymer is preferably 0.35% by weight or less, more preferably G. 33% by weight or less, and most preferably 0.32% by weight or less. Molded by the polyester of the present invention -5 1-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----------------- --- Order --------- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7 V. Description of the invention (5fl) The heat treatment is performed in the heating mold, but when the content of the oligomeric terpolymer is greater than 0.35% by weight, the oligomer attached to the surface of the heating mold will increase sharply, and the transparency of the obtained hollow molded product will be increased. Extremely poor. The hollow molded article using the polyester of the present invention can be formed by a melt molding method generally used, that is, a method such as a jet blow method, a direct blow method, and a stretch blow method. When producing a stretched hollow molded product, a transparent hollow molded product having excellent heat resistance is produced from the polyester of the present invention by a method such as the conventional hot milk 1 method. When the polyester of the present invention is used to manufacture a hollow molded article, the preform is formed by injection molding, and then stretched and blown into a bottle shape. The injection molding is generally performed at an injection temperature of about 265 to 300 °, and an injection pressure of about 30 to 70 kg / cm2, and the preliminary formed body is formed. The bottle mouth portion of the preliminary formed body is heat-treated and crystallized. The preform thus obtained was stretch blow-molded in a blow mold at about 12G ~ 2 at 10 ° C, and then heat-treated for about ΰβ5 ~ 30 seconds. The stretching ratio is usually 1.3 to 3.5 times in the longitudinal direction and 2 to 6 times in the peripheral direction. The polyester of the present invention can also be used for multilayer hollow molded products. The polyester of the present invention is suitable for use in fibers. The polyester constituting the fiber is particularly preferably 80 mols of its repeating unit X: the above are particularly preferred for ethylene terephthalate units or ethyl acetate. In addition, the polyester fiber of the present invention can be manufactured using conventional spinning conditions, but the spinning speed is preferably 7 flG ~ / min, and more preferably 2000 ~ 50 0 0π / min. When the spinning speed is less than 700mα / min, the productivity is low and the cost is increased by -5 2 ~ This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ---------- ---------- Order --------- (Please read the note on the back? Matters before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 _B7_ V. Invention Explanation (51) is high, so it is not practical. When spinning at SDDin / min or higher, it is pseudo-preferred in terms of theoretical productivity, but the problem of increased flow velocity accompanying spinning must be solved during spinning, and the spinning device must be modified. Otherwise, the yarn spinning situation will occur. , I do not seek. Once the spun yarn drawn in this way is taken up, it is still good even after the drawing process, without being taken up, and then drawn, it is still good to use as the drawn yarn. There is no other limitation on the thickness of the yarn, but it can be extremely fine from ldpf to 100 dp f or more. Depending on the application, it can be false twisted and crimped, and the cross section of the fiber can be round, triangular, hollow, etc. Moreover, it can be combined with other raw materials to form composite spinning. In either case, sufficient strength cannot be obtained with a draw ratio of 1.3 times or less. In general, it is difficult to stretch more than 3.5 times in a stable stretching process. In addition, when the polyester of the present invention is used in polyester fiber for industrial materials, it is better to have a breaking strength of 6 g / d or more and a breaking elongation of 12% or more, and the breaking strength is more preferably 7 g / d or more. It is preferable that the component constituting the polyester for the fiber is a copolymer of a compound having a metal sulfonate group. Polyethylene terephthalate fiber has insufficient dyeing properties, and the dyes that can be used are limited to disperse dyes, so it has disadvantages such as lack of sharpness. Methods for improving the dyeability: A method of copolymerizing an isobenzoic acid compound containing a metal sulfonate group in the main chain of polyethylene terephthalate can improve the dyeability of a basic dye. However, the conventional metal sulfonate-containing polyester is pseudo-monoisomeric metal sulfonate-containing isobenzene in the polymer-53- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----------- Φ Packing -------- Order ---------- (Please read the notes on the back before filling this page) Economy Printed by the Consumer Cooperative of the Ministry of Intellectual Property Bureau 490473 A7 _B7 V. Description of the invention (U) Formic acid compounds are prone to produce insoluble foreign matter, especially when the back pressure of the nozzle increases sharply during melt spinning, so yarn spinning performance is significantly reduced. With the above structure, the present invention can approximately suppress the generation of insoluble foreign matter which is a particular problem in modified polyester fibers containing metal sulfonate groups, and can also suppress the back pressure of the nozzle during melt spinning, and the yarn making property is good. Polyester fibers with good dyeability and a wide range of available cocoa dyes. There are no particular restrictions on the metal sulfonate-containing compound used in the copolymerization of the monomer, such as 5-sodium sulfoisobenzoic acid, 2-sodium sulfoterephthalic acid, and 5-lithium sulfoisobenzene Formic acid, 2-lithium sulfoterephthalic acid, 5-potassium sulfoisobenzoic acid, 2-potassium sulfoterephthalic acid, or these lower alkyl ester derivatives and the like. In the present invention, 5-sodium isobenzoic acid or an ester-forming derivative thereof is particularly preferred. The copolymerization amount of the metal sulfonate group-containing compound is preferably 0.3 to 10.0 mole%, and more preferably 0.8 to 5.0 mole% for the acid component constituting the polyester. If the copolymerization amount is too small, the dyeability of the basic dye is not good, and if it is too large, the yarn-making property is poor and sufficient strength cannot be obtained due to the thickening phenomenon. Moreover, when the compound containing a metal sulfonate group is copolymerized at 2.0 mol% or more, the resulting modified polyester fiber can be dyed under normal pressure. In addition, the amount of metal sulfonate-containing compound can be appropriately reduced by selecting an appropriate dyeable monomer. The dyeable monomer is not particularly limited, and examples thereof include long chain alcohol compounds of polyethylene glycol and polytetramethylene glycol, and aliphatic dicarboxylic acids of adipic acid, sebacic acid, and azelaic acid. In addition, as long as the polyester is a compound capable of imparting plasticizer properties, almost all of them have a function as a dyeable monomer. -54- The paper size obtained from these dyeable monomers is applicable to China National Standard (CNS) A4 (210 X 297 mm) ----------- Package ---- ---- Order --------- (Please read the notes on the back before filling out this page) 490473 A7 B7___ v 5 3 V. Description of the invention () For modified polyester, 0.5 ~ 7. Q% by weight is preferred. (Please read the precautions on the back before filling out this page) The metal sulfonate group-containing polyester fiber of the present invention can be subjected to alkali reduction processing similarly to the conventional metal sulfonate group-containing polyester fiber. The present invention can be applied to composite fibers having a core-sheath structure or a dorsal-ventral structure. In this case, the modified polyester can be used as a fiber to which a core-sheath component or a dorsal-belly-type component is blended. The polyester fiber of the present invention preferably contains a phosphorus compound. By containing a phosphorus compound, the cellulose fiber can be made flame-resistant. Methods for making polyester fibers flame retardant include, for example, a method of copolymerizing or mixing a flame retardant during the production of a polymer, a method of mixing a flame retardant during the production, and post-processing and making the surface of the fiber flame retardant. method. Among them, the method of adding flame retardance to the tool is quite rough, and the flame retarder falls off due to washing and friction, which reduces performance. In addition, the method of mixing the flame retardant is likely to cause pollution and exudation of the flame retardant during the manufacturing process of the formed article, which is a cause of the problem. In this regard, a method of copolymerizing a flame retardant in the production of a polymer is a method with a higher industrial value because it can overcome the above-mentioned disadvantages. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. However, the flame retardant polyester fiber copolymerized with a phosphorus compound as a flame retardant has the disadvantage of poor yarn making properties. These disadvantages are due to the antimony trioxide compound of antimony trioxide used as a catalyst for the polycondensation. When the phosphorus compound coexists, the reduction effect is increased, the antimony crystals of the metal are promoted, and the yarn spinning property is reduced. According to the present invention, the flame-retardant polyester fiber having low cost, good thermal stability, and good yarn-making property can be produced by the above-mentioned constitution. -55- This paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 490473 A7 _B7__ 5 4 5. Description of the invention () As a copolymerized monomer in the flame-retardant polyester fiber of the present invention The phosphorus compound used in the product is not particularly limited, and there are phosphate esters and derivatives thereof, phosphoric acid and derivatives thereof, phosphine and compounds thereof, and these may be used singly or in combination of two or more kinds. Phosphates and their derivatives include trimethyl phosphate and triethyl phosphate. Phosphoric acid and its derivatives phenyl phosphate, dimethyl phosphoric acid, diethyl phosphoric acid, etc. Phosphonic acid and its derivatives include (2-carboxyethyl) methylphosphonic acid, (2-carboxyethyl) ethylphosphonic acid (2-methylaminocarbonylethyl) methylphosphonic acid, (2-hydroxyethoxycarbonyl) methylphosphonic acid methyl ester, (2-carboxyethyl) phenylphosphonic acid, 9,10-di Hydrogen-9-oxyl-1 Q-phenanthrene-1 hydrazone-oxide maleic acid adduct or itaconic acid adduct. Moreover, it is not necessary that the phosphorus compound is copolymerized with the polyester. The addition amount of the phosphorus compound must be 0.2 to 3.0% by weight based on the phosphorus atom for the entire fiber. The content of the phosphorus atom is preferably 0.3 to 2.0 parts by weight, and more preferably 0.30 to 1.Q parts by weight. When the amount of the phosphorus compound is too small, the flame retardancy is insufficient, and if it is too large, the yarn-making property is reduced. A polyester in which a metal sulfonate group and a phosphorus compound coexist is also suitable. At this time, the phosphorus compound is preferably 0.2 to 3.0% by weight based on the phosphorus atoms of the entire fiber, and the metal sulfonate group-containing ester-forming component is 0.3 to all the carboxylic acid components constituting the polyester. 10 mole% is preferred. [Examples] The present invention will be described by examples in the following, but the present invention is not limited by these examples. In addition, the physical property values IV and TD of the polyesters in the respective examples and comparative examples were measured as follows. -56- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back? Matters before filling out this page)-Installation — — — — — — Intellectual Property Bureau of the Ministry of Economic Affairs Printed by an employee consumer cooperative. Printed by the Intellectual Property Bureau of the Ministry of Economy. Printed by an employee consumer cooperative. 490473 A7 B7 V. Description of the invention (β) Intrinsic viscosity (IV): Use of p-chlorophenol / 1,1,2,2-tetrachloroethane 6/4 mixed solvent (weight ratio), measured at a temperature of 3 Q ° C. Thermal stability index (TD): Put PET with lg IV of G.6dl / g in a glass test tube, s under vacuum drying at 1 3 ϋ ° C for 1 2 hours, and then under nitrogen atmosphere gas, 3 GG ° C Reduction rate (%) of IV for 2 hours under melting. The components of the organic compound used in the present invention and their symbols are as follows. (A): alizarin (B): alizarin (C): emodin (D): 1,4-diaminoquinol (£): 1,8-diamino-4,5-di Hydroxylhydrazone (F): 5,8-dihydroxy-1,4- # hydrazone (G): 2,5-dihydroxyphenylhydrazone (Η): deoxyalienin (I): 4,5-dihydroxy Naphthalene-2,7-disulfonic acid disodium (J): esculetine (K): flavin (L): epirubyl ficusate (M): methylene cross-linked linear phenol compound ( Mixture of 1 to 100 polymers) (N): Methylene cross-linked linear p-third-butylphenol compound (mixture of 1 to 100 polymers) (〇): Carmic acid [8 ] Arene-57- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----------- installation -------- order ----- ---- (Please read the precautions on the back before filling this page) 490473 A7 B7__ V. Description of the invention (5 6) (P): p-3-Butylcarboxic acid [8] aromatic hydrocarbon (Q): 2, 2 '-bisphenol (R): 2,2 夂 dihydroxydiphenyl ether (S): 2,2' -thiobis (4-th-octylphenol) (T) ·· 1,1 ' -Di-2 -naphthol (U): Acid Blue-2 5 (V): 2-aminonaphthalene (^ 〇: 1,1'-dinaphthyl-2,2'-diamine U) ·· Epicatechol (Y): 2-amino Benzene (Z) · 1,8-diaminonaphthalene (AA): 2-aminochromone (BB): 7-amino-4-methylcoumarin (CC) · · anthrafenol [Example 1] (Example 1 -1) For 8900 parts by weight of bis (2-hydroxyethyl) terephthalate, 0.23 parts by volume of a 5 g / L ethylene glycol ethylene glycol solution was added, and then For the acid component in the polyester, (A) alizarin is 0.1 mol%. Stir for 10 minutes at normal pressure at 2 45 ° C. Then, the temperature was raised to 275 ° C in 50 minutes, and the pressure of the reaction was gradually reduced to (KlTorr, and the polycondensation reaction was performed at the same temperature and pressure for 180 minutes. The physical properties of the obtained polymer (IV) As shown in Table 1-1. (Examples 1-2 to 1-18) -58- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the Please fill in this page for the matters needing attention) ---- Order ------ Tested by the Intellectual Property Bureau of the Ministry of Economic Affairs to print 490473 A7 B7_ V. Invention Description (^ 7) (Please read the notes on the back before filling in (In this page) The polyester is polymerized in the same manner as in the example except that the alizarin is changed to other organic compound components. The physical properties of the obtained polymer are shown in Table 1 to 1. The organic compound components used are (A ) Alizarin, (B) alizarin, (C) emodin, (D) 1,4-diamino radical, (E) 1,8-diamino-4,5-dihydroxy radical , (F) 5, 8-dihydroxy-1,4-naphthalene, (G) 2,5-dihydroxyphenylhydrazone, (H) deoxyalienin, (I) 4,5-dihydroxynaphthalene_2 , Disodium 7-disulfonate, (J) Aescin, (K) Morin, (L) Epiphenylene acid, (M) methylene crosslinked linear phenol compound (mixture of 1 to 100 polymers), (N) methylene crosslinked linear p-third-butylphenol Compound (1 to 10 G polymer mixture), (0) carbamic acid [8] arene, (P) p-3-butyl carbamic acid [8] arene, (Q) 2,2'- Bisphenol, (R) 2,2'-thiobis (4-third-octylphenyl ether), as indicated by the symbols in the table. (Comparative Examples 1-1) Except for the addition of cymbalariin, the same as the examples 1-1 polymerized polyester in the same way. The physical properties (IV) of the obtained polymer are shown in Table 1-1. (Comparative Example 1 _ 2) Except for the ethylene glycol solution without adding lithium acetate, it is the same as Example 1 Polyester was polymerized in the same way. The physical properties of the obtained polymer are shown in Tables 1-1. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Examples 1-19). To 8900 parts by weight of bis (2-hydroxyethyl) ) For terephthalate, add 0.29 parts by volume of a 5 g / L sodium acetate ethylene glycol solution, and then add 0.1 mole% of the acid component in the polyester. (A) Alizarin , Stir for 10 minutes at atmospheric pressure at 2 4 5 ° C. Raise again in 50 minutes To 2 7 5 ° C, slowly reduce the pressure of the reaction strip to 0.1 T 〇r r>, and at the same temperature and pressure -59- This paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7__ 5 8 V. Description of the invention () The polycondensation reaction is performed for 180 minutes. The physical properties of the obtained polymer are shown in Tables 1-2. (Examples 1-2 0 to 1-3 6) A polyester was polymerized in the same manner as in Example 19 except that iridium was changed to other organic compound components. The physical properties of the obtained polymer are shown in Table 1-2. (Comparative Examples 1 to 3) A polyester was polymerized in the same manner as in Examples 1 to 19, except that no alizarin was added. The physical properties of the obtained polymer are shown in Table 2. (Example 1_3 7) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added 0.34 volume parts of a 5 g / L concentration potassium glycol ethylene glycol solution, and then added to The acid content in the polyester is 0.1 mole% (A) madridin. Stir for 10 minutes at 2 45 ° C under normal pressure. The temperature was raised to 275 ° C in 50 minutes, and the pressure of the reaction bar was slowly reduced to 0.1 T 〇 r r, and then the polycondensation reaction was performed at the same temperature and pressure for 180 minutes. The physical properties of the obtained polymer are shown in Tables 1-3. (Examples 1-3 8 to 1-5 4) A polyester was polymerized in the same manner as in Examples 1-3 7 except that the alizarin was changed to another organic compound. The physical properties of the obtained polymer are shown in Tables 1-3. (Comparative Examples 1 to 4) A polyester was polymerized in the same manner as in Examples 1 to 7 except that KM was not added. The physical properties of the obtained polymer are shown in Tables 1-3. (Example 1 _ 5 5) -60- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ------------------- Order --------- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 _B7____ v 5 9 V. Description of the invention () For 89 00 parts by weight double For (2-hydroxyethyl) terephthalate, add 0.36 volume parts of a 10 g / L beryllium acetate ethylene glycol solution, and add 0.1 mol% for the acid component in the polyester (A) Irisin, stirred at normal pressure at 2 4 5 ° C for 10 minutes. The temperature was raised to 275 ° C in 5 Q minutes, and the pressure of the reaction strip was slowly reduced to 0.1 Torr, and then the polycondensation reaction was performed at the same temperature and pressure for 180 minutes. The physical properties (UV) of the obtained polymer are shown in Tables 1-4. (Example 5 5 ~ 1-7 2) A polyester was polymerized in the same manner as in Example 1-55, except that alizarin was changed to another organic compound component. The physical properties of the obtained polymer are shown in Table 1-4. The organic compound components used are the same as those used in Examples 1-2 to 1-18. (Comparative Examples 1 to 5) A polyester was polymerized in the same manner as in Examples 1 to 5 except that azalea was not added. The physical properties of the obtained polymer are shown in Tables 1-4. (Example 7 3) For 8900 parts by weight of bis (2-hydroxyethyl) terephthalate, 0. 19 parts by volume of an ethylene glycol solution of magnesium acetate at a concentration of 10 g / L was added, and The acid content is 0.1 mol% (A) cyperidin, and it is stirred for 10 minutes at 25 ° C under normal pressure. The temperature was raised to 275 ° C in 50 minutes, and the pressure of the reaction strip was gradually reduced to 0.1 Torr, and then the polycondensation was performed at the same temperature and pressure for 180 minutes. The physical properties of the obtained polymer are shown in Table 1-5 ΛΚ〇 (Examples 74 ~ 1-90)-6 1-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) --- --------- Equipment -------- Order --------- (Please read the precautions on the back before filling this page) Preparation 490473 A7 B7_ V. Description of the invention U)) Polyester was polymerized in the same manner as in Example 73 except that the alizarin was changed to other organic compound components. The physical properties of the obtained polymer are shown in Table 5. (Comparative Examples 1 to 6) A polyester was polymerized in the same manner as in Example 73 except that azalea was not added. The physical properties of the obtained polymer are shown in Tables 1-5. (Examples 1-9 1) To 89GG parts by weight of bis (2-hydroxyethyl) terephthalate, 0.23 parts by volume of 5 g / L · concentration of lithium acetate in ethylene glycol solution (lithium acetate The Li atom is 0.05 mol%), and then 0.1 mol% quinocridin is added for the acid component in the polyester, and the mixture is stirred for 10 minutes under a nitrogen ambient gas, normal pressure at 245 ° C. The temperature was raised to 275 ° C within 50 minutes, and the pressure of the reaction strip was gradually lowered to 0.1 T 〇 r r, and then the polycondensation reaction was performed at 2 75 ° C and 0 · 1 T 〇 r r. The polymerization time required until the IV of PET reached 0.5 dl / g is shown in Tables 1-6. Then, P E T having an I V of 0.6 d 1 / g was polymerized in the manner described above, and a thermal stability index (T D) was obtained. The values of I V and T D after the melting test are shown in Tables 1-6⑴. (Examples 1 to 9 2 to 1 to 1 1 8 and Comparative Examples 1 to 7 to 1 to 9) The same operations as in Examples 1 to 9 were performed except that the catalyst was changed. The catalyst composition used and the polymerization time required for the IV of PET to reach 0.5 dl / g, and IV and TD values after the melting test are shown in Tables 1-6, VII, and 1-8. The amount of addition 傺 is a value for the acid component in P E T. The amount of metal catalyst added is the amount of metal atoms added. (Comparative Examples 1-1〇, Comparative Examples 1-2 4) -62- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----------- pack- ------- Order --------- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7_ 6 1 5. Description of the invention ( ) PET was polymerized in the same manner as in Examples 1 to 9 except that _Alizarin was not added. When the polycondensation reaction was allowed to proceed for 180 minutes, the I V value could not reach 0.5 d 1 / g, so the polymerization was terminated. The addition amount of lithium acetate was increased to G. 3 mol%, and the result was still the same. (Comparative Examples 1-1 1 and Comparative Examples 1-2 5) PET was polymerized in the same manner as in Example 91 except that the ethylene glycol solution of lithium acetate was not added. When the polycondensation reaction was carried out for 180 minutes, the IV value could not reach ϋ .5 d 1 / g, so the polymerization was terminated. The amount of awakening alizarin was increased to 0.2 mol%, but the result was still the same. (Examples 1-1 1 9 to 1-1 3 4) The same operations were performed as in Comparative Examples 1 to 9 1 except that the catalyst was changed. The catalyst composition used and the I V of P E T are 0.5 dl / g, the polymerization time required, and the IV and TD values after the melting test are shown in Tables 1-7 and VII. Among them, the amount of addition 僳 is a value for the acid component in P E T. The amount of metal catalyst added is the amount of metal atoms added. (Comparative Examples 1 to 12) Polyethylene terephthalate was polymerized in the same manner as in Examples 1-1Q0 except that quinolizin was not added. The polymerization time required when the IV of poly (ethylene terephthalate) reaches 0.3 dl / g is shown in Table 1-8. (Comparative Examples 1 to 1) Polyethylene terephthalate was polymerized in the same manner as in Examples 1 to 1 except that sodium acetate was not added. The polymerization time required when the IV of poly (ethylene terephthalate) reaches 0.3 dl / g is shown in Table 1-8. (Comparative Examples 1-1 4 to 1-2 3)-63 One paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----------- installed --- ----- Order --------- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7_ 62 V. Description of Invention () Except for changes Except for the catalyst and its addition amount, polyethylene terephthalate was polymerized in the same manner as in Examples 1 to 91. The composition of the catalyst used and the polymerization time required from IV to 0.33 Ι / g of polyethylene terephthalate are shown in Table 1-8. Among them, the value of the added measuring bar is for the acid component in the P E T. The amount of metal catalyst added is the amount of metal atoms added. (Comparative Example 2 6) The same operations as in Examples 1 to 91 were performed except that the catalyst was changed to tri-gasified antimony. The amount of antimony trioxide added is 0.05 mole% of the antimony atom for the acid component in P E T. The polymerization time required for the IV of PET to reach 0.5 dl / g, the IV and TD values after the melting test are shown in Table 1-8. [Example 2] (Example 2-1) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added 0.71 volume parts of a 5 g / L aluminum acetate ethylene glycol solution, Then, for the acid component in the polyester, Q · 1 mol% (S) 2,2 夂 thiobis (4-th-octylphenol) was added, and the mixture was stirred at normal pressure and 245 ° C for 10 minutes. The temperature was raised to 275 ° C in 50 minutes, and the pressure of the reaction strip was slowly reduced to 0 · 1 T 〇 r r, and then the polycondensation was performed at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 2-1. (Examples 2-2 to 2-1 9) The same as Example 2-1 except that 2,2'-thiobis (4-th-octylphenol) (S) was changed to other organic compound components Geopolymerized polyester. The physical properties of the obtained polymer are shown in 2-1. (Comparative Example 2-1) -64 A paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) • ------------------- Order ---- I ---- · (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 _ B7 V. Description of the invention (0) Except not adding 2, 2 The polyester was polymerized in the same manner as in Example 2-1 except for sulfide (4-th-octylphenol) (S). The physical properties of the obtained polymer are shown in Table 2-1. (Comparative Example 2-2) A polyester was polymerized in the same manner as in Baoshi Examples 2 to 1 except that an ethylene glycol solution of aluminum acetate was not added. The physical properties of the obtained polymer are shown in Table 2-1. (Examples 2-20) For 89G0 parts by weight of bis (2-hydroxyethyl) terephthalate, 1.28 parts by volume of a 5 g / L ethylene glycol solution of gallium acetoacetate was added, and then For the acid component in the polyester, it is G. 1 mole (S) 2,2'-thiobis (4- 3-octylphenol), and it is stirred at normal pressure and 245 ° C for 1Q minutes. The temperature was raised to 275 ° C in 50 minutes, and the pressure of the reaction was gradually reduced to 0.1 T 〇, and then the polycondensation was performed at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 2-2. (Example 2-2 1 ~ 2-3 8) The same as in Example 2-2 G, except that 2,2 ^ thiobis (4- 3rd-octylphenol) (S) was changed to other organic compound components. Polyester was polymerized identically. The physical properties of the obtained polymer are shown in Table 2-2. (Comparative Examples 2 to 3) A polyester was polymerized in the same manner as in Examples 2 to 20, except that 2,2 ^ thiobis (4- 3rd-octylphenol) (S) was not added. The physical properties of the obtained polymer are shown in Table 2-2. (Example 2-3 9) For 8 9 0 0 parts by weight of bis (2-hydroxyethyl) terephthalate, -65- This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the notes on the back before filling this page)

I I I I I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7_ 6 4 V. Description of Invention () 1.  35 capacity parts 5g / L concentration of bismuth acetate in ethylene glycol solution, and then added to the acid component of the polyester is 0. 1 mol% (S) 2, 2 sulfanylbis (4-octylphenol), and stirred at 24.5 ° C for 10 minutes at normal pressure. Increase the temperature to 275 ° C in 50 minutes and slowly reduce the pressure of the reaction strip to 0.  1 T 〇 r, and then polycondensation at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Tables 2-3. (Examples 2-4 0 to 2-5 7) The same as Examples 2-3 9 except that 2,2'-thiobis (4- 3rd-octylphenol) was changed to other organic compound components. Polymer polyester. The physical properties of the obtained polymer are shown in Table 2-3. The organic compound components used are (Q) 2,2 ^ bisphenol, (M) methylene cross-linked linear phenol compound (mixture of 1 to 1 Q polymer), (N) methylene cross-linked linear P-3-butylphenol compound (mixture of 1 to 100 polymers), (0) carbamic acid [8] arene, (P) p-3-butyl carbamic acid [8] arene, ( J) Aescin, (K) Morin, (L) Epibenzyl gallate, (I) 4, 5-dihydroxynaphthalene-2, 7-disulfonic acid disodium, (1) 1, 1 夂 bis-2-_phenol, (11) deoxyalienin, (6) 2,5-dihydroxyphenylhydrazone, (F) 5,8-dihydroxy-1,4-naphthalene_, (A) 酲Alizarin, (B) Alizarin, (C) Emodin, (D) 1,4-diaminoanthracene, (E) 1,8-diamino-4, 5-dihydroxylidine. (Comparative Examples 2 to 4) A polyester was polymerized in the same manner as in Examples 2 to 3, except that 2,2'-thiobis (4-th-octylphenol) was not added. The physical properties of the obtained polymer are shown in Table 2-3. -66- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------ Installation -------- Order ------ ---.  (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7__ V. Description of the Invention (65) [Example 3] (Example 3-1) Double to 89G0 parts by weight (2-hydroxyethyl) terephthalate is added at 0. 60 capacity parts of 5g / L concentration of chromium acetate in ethylene glycol solution, and then added to the acid component of the polyester is 0. 1 mol% (A) TIM, and stirred at normal pressure at 25 ° C for 10 minutes. Increase the temperature to 2 7 5 ° C in 50 minutes, and slowly reduce the pressure of the reaction strip to O. lTorr, polycondensation was performed at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 3-1. (Examples 3-2 to 3-1 9) A polyester was polymerized in the same manner as in Example 3-1 except that the alizarin was changed to another organic compound component. The physical properties of the obtained polymer are shown in Table 3-1. The components of the organic compounds used are (B) alizarin, (C) emodin, (D) 1,4-diaminopyridine, (E) 1 , 8-diamino-4,5-dihydroxyamidine, (U) Acid Blue 25, (V) 2-aminonaphthalene_, (H) deoxyalienin, (W) 1,1'-di Naphthyl-2,2'-diamine, (1) 4,5-dihydroxycae-2,7-disulfonic acid disodium, (J) horse chestnut, (K) moraxanthin, (X) Catechol, (M) methylene cross-linked linear phenol compound (mixture of 1 to 100 polymers), (N) methylene cross-linked linear p-3-butylphenol compound (1 to 100 polymer Mixture of substances), (0) carbamic acid [8] arene, (P) p-3-butyl carbamic acid [8] arene, (Y) 2-aminobiphenyl, (S) 2,2 '-Sulbis (4-th-octylphenol) (S). (Comparative Example 3-1) -67- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). --I --- I ---- · I--I --- Order 1111111! (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7_ V. DESCRIPTION OF THE INVENTION (From) A polyester was polymerized in the same manner as in Example 3-1 except that no alizarin was added. The physical properties of the obtained polymer are shown in Table 3-1. (Comparative Example 3-2) A polyester was polymerized in the same manner as in Example 3-1 except that an ethylene glycol solution of chromium acetate was not added. The physical properties of the obtained polymer are shown in Table 3-1. (Examples 3-2 0) For 8 900 parts by weight of bis (2-hydroxyethyl) terephthalate was added 0. 62 volume parts 5g / L concentration of nickel acetate in ethylene glycol solution, and then added to the acid component of the polyester is 0. 1 mole% (A) cyperidin, stirred at normal pressure at 25 ° C for 10 minutes. Increase the temperature to 2 7 5 ° C in 50 minutes, and slowly reduce the pressure of the reaction strip to O. lTorr, polycondensation was performed at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 3-2. (Examples 3-2 1 to 3-3 8) Polyester was polymerized in the same manner as in Examples 3 to 20 except that the alizarin was changed to other organic compound components. The physical properties of the obtained polymer are shown in Table 3-2. The organic compound components used are the same as those in Examples 3-2 to 3-19. (Comparative Example 3_3) A polyester was polymerized in the same manner as in Example 3-2 G, except that no alizarin was added. The physical properties of the obtained polymer are shown in Table 3-2. [Example 4] (Example 4-1) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added 0.  68 volume parts of 5g / L yttrium chloride ethylene glycol solution, and then add to a 68 paper size to apply Chinese National Standard (CNS) A4 specifications (210 X 297 mm) -------- ---- Equipment -------- Order ---------_ (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 _B7_ Heart 6 7 V. Description of the invention () The acid content of polyester is (K 1 mole% (S) 2, 2 thiobis (4-th-octylphenol), at atmospheric pressure, 245 ° C Stir for 10 minutes. Then raise the temperature to 275 ° C in 50 minutes, slowly reduce the pressure of the reaction strip to (K 1 T 〇rr), and then perform polycondensation under the same temperature and pressure for 18 Q minutes. The physical properties (IV) of the polymer are shown in Table 4-1. (Examples 4-2 to 4-1 9) Except changing 2,2 thiobis (4-th-octylphenol) to other organic Except for the compound components, polyester was polymerized in the same manner as in Example 4-1. The physical properties of the obtained polymer are shown in Table 4-1. The organic compound components used were (Q) 2,2'-bisphenol, ( Μ) methylene cross-linked linear phenol compound (1 ~ 1 Mixture of 0 polymer), (N) methylene cross-linked linear p-3-butylphenol compound (mixture of 1 to 10 0 polymer), (0) carbamic acid [8] aromatic hydrocarbon, ( (P) p-3-Butylcarboxic acid [8] arene, (J) Aescin, (K) Morin, (L) Epiphenylate, (I) 4, 5-Di Hydroxynaphthalene-2, 7-disulfonic acid disodium, (T) 1,1 · -di-2-naphthol, (Η) deoxyalienin, (G) 2,5-dihydroxybenzophenone, (F ) 5,8-dihydroxy-1,4-naphthoquinone, (A) quinoidalin, (B) alizarin, (C) emodin, (D) 1,4-diamine (E) 1, 8-Diamino-4,5-dihydroxy group, (ϋ) Acid Blue 25. (Comparative Example 4-1) Except that 2,2 thiobis (4-third to octylphenol) was not added, The polyester was polymerized in the same manner as in Example 4-1. The physical properties of the obtained polymer are shown in Table 4 _ 1 (Comparative Examples 4-2) -6 9- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the notes on the back before filling out this page) ϋ H ϋ ϋ One: Va— II —Mi ϋ ϋ 印 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 490473 A7 B7__ 685. Description of the invention () Except for the ethylene glycol solution without adding yttrium chloride, the polyester was polymerized in the same manner as in Example 4-1. The physical properties of the obtained polymer are shown in Table 4-1. (Example 4-2 0) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added 0. 13 volume parts of 5Qg / L concentration of n-butoxy chromium n-butanol solution, and then added to the acid component of the polyester is 0.  1 mole% (S) 2,2 ^ sulfur bis (4--3-octylphenol), and stirred at 245 ° C for 10 minutes at normal pressure. The temperature was raised to 275 ° C in 50 minutes, and the pressure of the reaction strip was slowly reduced to (K 1 T rr, and then polycondensed at the same temperature and pressure for 180 minutes. Physical properties of the obtained polymer The value (IV) is shown in Table 4-2. (Examples 4-21 to 4-38) Except for changing 2,2'-thiobis (4- 3rd-octylphenol) to other organic compound components Polyester was polymerized in the same manner as in Example 4-2. The physical properties of the obtained polymer are shown in Table 4-2. The organic compound component used was the same as that used in Example 4-2 to 4-19. (Comparative Examples 4-3) Polyester was polymerized in the same manner as in Example 4-2 except that 2,2'-thiobis (4-octylphenol) was not added. Physical properties of the obtained polymer As shown in Table 4-2 (Example 4-39) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added 1.  12 parts by volume of 5 g / L concentration of chlorinated ethylene glycol solution, and then added to the acid component of the polyester is 0.  1 mol% (S) 2,2 · -thiobis (4-third-octylphenol) was stirred at normal pressure and 245 ° C for 10 minutes. 50 minutes-7 0-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) Packing — — — — — — 490473 A7 B7_ Heart 6 9 V. Description of the invention () (Please read the precautions on the back before filling in this page) The temperature in the clock is raised to 2 7 5 ° C, and the pressure of the reaction strip is slowly reduced to 0 · 1 T 〇rr, and then Polycondensation was performed at the same temperature and pressure for 18 G minutes. The physical properties (I V) of the obtained polymer are shown in Table 4-3. (Examples 4-4 G to 4-5 7) Polymerization was carried out in the same manner as in Examples 4-3 9 except that 2,2 thiobis (4-th-octylphenol) was changed to other organic compound components. ester. The physical properties of the obtained polymer are shown in 4-3. The organic compound component 傺 used was the same as that used in Examples 4-2 to 4-19. (Comparative Examples 4 to 4) A polyester was polymerized in the same manner as in Examples 4 to 3 except that 2,2'-thiobis (4-th-octylphenol) was not added. The physical properties of the obtained polymer are as shown in 4-3 〇 [Example 5] (Example 5-1) To 8 9 Q 0 parts by weight of bis (2-hydroxyethyl) terephthalate 1 .  39 9 parts of ethylene glycol solution of 5 g / L concentration of ethyl acetate, and then add G for the acid component of polyester.  1 mol% (A) 酲 Alizarin, printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Stir for 10 minutes at 25 ° C under normal pressure. Increase the temperature to 275 ° C in 50 minutes, and slowly reduce the pressure of the reaction strip to 0.  1 T 〇 r r, and then polycondensation at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 5-1. (Examples 5-2 to 5-1 8) A polyester was polymerized in the same manner as in Example 5-1 except that the (A) cyperidin was changed to another organic compound component. The physical properties of the obtained polymer are shown in Table 5-1 -7 1- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7_ Heart 7 0 5. The description of the invention (). The components of the organic compounds used are (B) alizarin, (C) emodin, (D) 1, diaminoamino «酲, (E) 1,8-diamino-4,5-dihydroxyanthanol , (U) acid basket 25, (V) 2-aminonaphthalene hydrazone, (H) decloxacin, (¥) 1,1'-dinaphthyl-2,2'-diamine, (1) 4 , 5-Dihydroxynaphthalene-2, 7-disulfonic acid disodium, (J) Aescin, (K) Morin, (X) epicatechin, (M) methylene cross-linked linear phenol Compound (mixture of 1 to 100 polymers), (N) methylene cross-linked linear pair · "3rd to butylphenol compound (mixture of 1 to 100 polymers), (0) carbs Acid [8] arene, (P) p-3-Butyl Carboxylic Acid [8] arene, (ii) 2-aminobiphenyl, (S) 2, 2 ^ sulfibis (4-three-octyl) Phenol) (S). (Comparative Example 5_1) A polyester was polymerized in the same manner as in Example 5-1 except that no alizarin was added. The physical properties of the obtained polymer are shown in Table 5-1. (Comparative Example 5-2) A polyester was polymerized in the same manner as in Example 5-1, except that ethylene glycol solution of yttrium acetate was not added to yttrium. The physical properties of the obtained polymer are shown in Table 5-1. (Examples 5 to 19) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added.  79 parts by volume of 5g / L concentration of palladium acetate in ethylene glycol solution, and then added to the acid component of the polyester is 0. 1 mol% (A) Bandarizin, stirred at normal pressure at 25 ° C for 10 minutes. Increase the temperature to 275 ° C in 50 minutes, and slowly reduce the pressure of the reaction strip to 0.  1 T 〇 r r, and then polycondensation at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 5-2. -12 — This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -------- Order ------ --- Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed 490473 A7 B7_ V. Description of the Invention (71) (Examples 5 ~ 2 G ~ 5-3 6 ) Polyester was polymerized in the same manner as in Examples 5 to 19 except that the alizarin was changed to other organic compound components. The physical properties of the obtained polymer are shown in Table 5-2. The organic compound component 傺 used is the same as in Examples 5-2 to 5 -8. (Comparative Example 5_3) A polyester was polymerized in the same manner as in Examples 5 to 19, except that no alizarin was added. The physical properties of the obtained polymer are shown in Table 5-2. [Example 6] (Example 6_1) To 89G0 parts by weight of bis (2-hydroxyethyl) terephthalate was added 0.  64 parts by volume of a 5 g / L solution of copper acetate in ethylene glycol, added to the polyester component in an amount of 0.1 mol% (S) 2, 2 sulfanthion (4-three-octyl) Phenol), and stirred at 2 4 5 ° C at normal pressure for 1 G minutes. Increase the temperature to 275 ° C in 50 minutes and slowly reduce the pressure of the reaction strip to 0.  1 T 〇 r r, and then polycondensation under the same temperature and pressure for 18 Q minutes. The physical properties (I V) of the obtained polymer are shown in Table 6-1. (Examples 6-2 to 6-1 9) The same as Example 6-1 except that 2, 2 ^ thiobis (4-octylphenol) (S) was changed to other organic compound components Polymer polyester. The physical properties of the obtained polymer are shown in Table 6-1. The organic compound components used are (Y) 2 -aminobiphenyl, (M) methylene crosslinked linear phenol compound (mixture of 1 to 100 polymers), (N) methylene crosslinked linear P-third-butylphenol compound (mixture of 1 to 100 polymers), (0) carbamic acid [8] arene, (P) p-3-butyl carbamic acid [8] arene, (J) Hachiba-73- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------ • Installation ---- (Please read the back first Please pay attention to this page and fill in this page) Order --------- Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 _B7_ V. Description of the Invention (&gt;) Kiosk, (K) Morinin, (L ) Epicylphenyl gallate, (I) Disodium 4,5-dihydroxynaphthalene-2,7-disulfonic acid, (11) 1, Plant-di-2-naphthol, (10 deoxycaline) (G) 2,5-dihydroxybenzophenone, (F) 5,8-dihydroxy-1,4-fluorenone, (A) arsonin, (B) alizarin, (C) emodin (D) 1,4-diaminoquinone, (E) 1, 8-diamino-4,5-dihydroxyfluorenol. (Comparative Example 6-1) Except that 2,2'-sulfur was not added Bis (4- 3rd-octylphenol) Polyester was polymerized in the same manner as in Example 6-1. The physical properties of the obtained polymer are shown in Table 6-1. (Comparative Example 6-2) Except for the ethylene glycol solution without adding ketone acetate, it was the same as in Example. 6-1 Polyester was polymerized in the same way. The physical properties of the obtained polymer are shown in Table 6-1. (Example 6-20) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate In terms of adding 0.  5 8 volume parts 5 g / L concentration of silver acetate in ethylene glycol solution, and then added to the acid component of the polyester is 0. 1 mol% (S) 2,2 sulfanylbis (4-octylphenol) was stirred at 245 ° C for 10 minutes at normal pressure. The temperature was raised to 275 ° C within 50 minutes, and the pressure of the reaction strip was gradually reduced to 0 · 1 T 〇 r, and then the polycondensation was performed at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 6-2. (Examples 6-21 to 6-38) The same as Example 6-2 except that (S) 2, 2 ^ thiobis (4-th-octylphenol) was changed to other organic compound components Polymer polyester. The physical properties of the obtained polymer are shown in Table 6-2. Ingredients of organic compounds used 7 4 ~ This paper size applies to China National Standard (CNS) A4 specifications (210 x 297 mm) ------------- packing -------- Order --------- (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7_ 7 3 V. Description of the invention () and Examples 6-2 ~ 6-9 are the same. (Comparative Example 6-3) A polyester was polymerized in the same manner as in Examples 6-20 except that 2,2'-thiobis (4-octylphenol) (S) was not added. The physical properties of the obtained polymer are shown in Table 6-2. [Example 7] (Example 7-1) To 89Q0 parts by weight of bis (2-hydroxyethyl) terephthalate was added 5. 5 parts by weight of lanthanum acetate, and then added to the acid component of the polyester is 0. 1 mole% (A) quinacridin, stirred at 245 ° C at normal pressure for 10 minutes. Increase the temperature to 275 ° C in 50 minutes and slowly reduce the pressure of the reaction strip to 0.  ITorr, polycondensation was performed at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 7-1. (Examples 7-2 to 7-1 8) A polyester was polymerized in the same manner as in Example 7-1 except that the alizarin was changed to another organic compound component. The physical properties of the obtained polymer are as shown in 7-1. The organic compound components used are (B) alizarin, (C) emodin, (D) 1,4-diamino group M, and (E) 1, 8-diamino-4,5-dihydroxy awakening, (U) Acid Blue 25, (F) 5,8-dihydroxy-1,4-fluorene, (Η) deoxyalienin, (I) Disodium 4,5 -dihydroxynaphthalene-2,7-disulfonic acid, (T) 1,1'-bis-2-resorcinol, (J) aescin, (κ) flavin, (L) Epidallocatechin Cate, (M) methylene cross-linked linear phenol compound (mixture of 1 to 100 polymers), (N) methylene cross-linked linear p-th-butylbenzene -75- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----------- installation -------- order ------- -(Please read the notes on the back before filling out this page) 490473 A7 B7 V. Description of the Invention (桠), Hydrocarbons ¾) Aromatics 1 V 8 and t Mixed acid ears carbaryl 00 but 1 I 3 1- The first pair of compounds} bp / 1 (0 / hydrocarbon 4-arylbis81 sulfur_- · I acid 2 ear 2 card} polymer polymerization in the same phase. 1 shows 7- Example 1 Shi 7- real table and as the value l ·,. . r 〇 性 性 素素 物) (Alien's phenol) 醍 Benzene I Into the base J7 addition polymerization example Xin M 3 3 b divided to get the ((t example is the same phase as the soil. 1 shows 7 example 1 application 7- The actual value is, for example, the value of ΓΓ, lysine, alcohol, diethylene glycol, lanthanum, and so on. The addition of esters to the polymer does not include the addition of polymer. Right \) / ethyl ethyl hydroxy-2 / V double-weight re-pairing and adding re-acid vinegar weight %% Momo pressure is usually in susalol ο then 0 minutes and divided into 10 mixed with sour acid Middle P Borrow 15 (Please read the phonetic on the back? Matters and then fill out this page) The minutes are gathered together to the strength of the clock. The minutes should be ο. Anti 18 Low-heavy and slow-down gatherings. Press 5 1 7 Same as 2 —a V to ι? (IS ^ liter? S property and content table as shown --------- order --------- · Shi 2 Shi 7-, age LrL4t, the property of the property, the combination of the polymerization machine, the best of the others. Its esters, the polymer, the polymer, the polymer, the 0, and the division 19, the staff of the Intellectual Property Bureau of the Ministry of Economic Affairs The cooperative example printed by Fei Cooperative Society is used in combination with the compounding machine. The examples are compared with the actual value and sex, and the extraneous substance Alizarin is added. The purpose is to implement. This paper size is in accordance with the Chinese National Standard (CNS) A4 (210 X 297 mm) in-phase polymerization and in-phase. Full display 490473 A7 _ B7_ V. Description of the invention (β) For 89 00 parts by weight of bis (2-hydroxyl) Ethyl) terephthalate is added 5.  7 parts by weight of osmium acetate, and then added to the acid component of the polyester is 0.  1 mol% (Α) valenicin, stirred at normal pressure and 245 ° C for 10 minutes. Increase the temperature to 275 ° C in 50 minutes and slowly reduce the pressure of the reaction strip to 0.  1 T 〇 r r, and then polycondensation at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 7-3. (Examples 7-3 8 to 7-5 4) A polyester was polymerized in the same manner as in Examples 7-3 except that the alizarin was changed to another organic compound component. The physical properties of the obtained polymer are shown in Table 7-3. The organic compound components used are the same as those in Examples 7-2 to 7-18. (Comparative Examples 7-4) Polyester was polymerized in exactly the same manner as in Examples 7 to 3, except that alizarin was not added. The physical properties of the obtained polymer are shown in Table 7-3. (Examples 7-5 5) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added 5.  8 parts by weight of osmium acetate, and then added 0% mole% (A) oxalaridin to the acid component in the polyester, and stirred at normal pressure and 245 ° C for 10 minutes. Increase the temperature to 275 ° C in 50 minutes and slowly reduce the pressure of the reaction strip to 0.  1 T 〇 r r, and then polycondensation at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 4. (Examples 7-5 6 to 7-7 2) A polyester was polymerized in the same manner as in Examples 7-5 except that the alizarin was changed to another organic compound component. The physical properties of the obtained polymer are shown in Table 7-4. The organic compound components used are the same as those in Examples 7-2 to 7-18. -77- This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back before filling this page) Binding --------- ^-· Ministry of Economic Affairs Printed by the Intellectual Property Bureau employee consumer cooperative printed by the Ministry of Economy Intellectual Property Bureau employee consumer cooperative printed by 490473 A7 B7_ V. Description of the invention (%) (Comparative Example 5) Except for the absence of Akane Ksu, it is exactly the same as in Examples 7-5 5 Geopolymerized polyester. The physical properties of the obtained polymer are shown in Table 7-4. (Examples 7-7 3) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added 5.  9 parts by weight of yttrium acetate, and then added to the acid component of the polyester is 0.  1 mole% (A) awake alizarin, stirred at normal pressure and 245 ° C for 10 minutes. Increase the temperature to 275 ° C in 50 minutes and slowly reduce the pressure of the reaction to 0.  1 T 〇 r r, and then polycondensation under the same temperature and pressure for 18 G minutes. The physical properties (I V) of the obtained polymer are shown in Table 7-5. (Examples 7 to 7 4 to 7 to 9 0) A polyester was polymerized in the same manner as in Examples 7 to 7 except that the quinolizin was changed to another organic compound component. The physical properties of the obtained polymer are shown in Table 7-5. The organic compound components used are the same as those in Examples 7-2 to 7-18. (Comparative Examples 7 to 6) A polyester was polymerized in exactly the same manner as in Example 73 except that alizarin was not added. The physical properties of the obtained polymer are shown in Table 7-5. [Example 8] (Example 8-1) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added zinc acetate at a concentration of 5 g / L at 5 g / L. (II) ethylene glycol solution of hydrate, and then added to the acid component of the polyester is 0.  1 mol% (A) oxyalizarin, stirred at normal pressure at 25 ° C for 10 minutes. Raise the temperature to 2 7 5 ° C in 50 minutes, and slowly reduce the pressure of the reaction strip to 0. 1 Tor r, at the same temperature and pressure -78- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------------- installation ---- ---- Order ------ (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7_ 7 7 V. Condensation of the invention () 8 G minutes, polyester was obtained. (Examples 8-2 to 8-1 8) A polyester was polymerized in the same manner as in Example 8-1 except that the alizarin was changed to another organic compound component. The organic compounds used are (B) alizarin, (D) 1,4-diamino radical, (E) 1,8-diamino-4,5-dihydroxy radical, (U) acid basket 25, (F) 5,8-dihydroxy-1,4-naphthalene, (H) desalination, (Z) 1,8-diaminonaphthalene, (T) 1,1 丨 -di-2 -Naphthol, (W) 1,1 丨 -naphthyl-2,2 fluorenediamine, (L) epicatechin gallate, (K) flavin, (AA) 2-aminochromone, ( J) Aesculetin, (BB) 7-amino-4-methylcoumarin, (0) carbamic acid [8] arene, (P) p-3-butyl carbamic acid [8] arene . (Comparative Example 8-1) A polyester was polymerized in the same manner as in Example 8-1, except that (A) alizarin was not added. (Comparative Example 8-2) A polyester was polymerized in the same manner as in Example 8-1, except that an ethylene glycol solution of zinc (II) acetate hydrate was not added. Table 8-1 shows the measurement results of the specific viscosity of the polyesters obtained in Examples 8-1 to 8-18 and Comparative Examples 8-1 and 8-2. (Example 8-19) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added.  18 parts by volume of an ethylene glycol solution of manganese acetate (Π) 4 hydrate at a concentration of 10 g / L, and then added to the acid component of the polyester.  1 mol% (A) -79- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------------ installation ----------- Order ------ (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7__, 78 V. Description of the invention () Alizarin, at atmospheric pressure, 245 Stir at ° C for 10 minutes. Increase the temperature to 275 ° C in 5Q minutes and slowly reduce the pressure of the reaction strip to 0.  1 T 〇 r r, and then polycondensation at the same temperature and pressure for 180 minutes to obtain a polyester. (Examples 8-20 to 8-3) Polyester was polymerized in the same manner as in Examples 8 to 19 except that _Alizarin was changed to other organic compound components. The organic compound components used are the same as those in Examples 8-2 to 8-18. (Comparative Example 8-3) A polyester was polymerized in the same manner as in Examples 8-19 except that (A) alizarin was not added. Table 8-2 shows the measurement results of the intrinsic viscosity of the polyesters obtained in Examples 8-19 to 8-3 and Comparative Examples 8-3. (Examples 8 to 37) For 89 (30 parts by weight of bis (2-hydroxyethyl) terephthalate, 0.08 volume parts of 20 g / L of cobalt acetate (Π) tetrahydrate was added. Ethylene glycol solution, and then add 0% mole% (A) oxyalizarin to the acid content of the polyester, and stir for 1 Q minutes at 2 45 ° C at normal pressure. Within 50 minutes Increase the temperature to 2 7 5 ° C and slowly reduce the pressure of the reaction strip to 0.  1 T ο η, and then polycondensation under the same temperature and pressure for 180 minutes, to obtain a polyester. (Examples 8-38 to 8-54) A polyester was polymerized in the same manner as in Examples 8 to 19 except that the alizarin was changed to another organic compound component. The organic compound components used are the same as those in Examples 8-2 to 8-18. (Comparative Examples 8-4) ~ 8 0-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----— — — — — — — — — — — — II ^ · 11 ------ · (Please read the note on the back? Matters before filling out this page) 490473 A7 B7__ 7 9 V. Description of the invention () Except not adding (A) alizarin, and Example 8- 3 7 polyester was prepared exactly the same. (Please read the precautions on the back before filling out this page.) Table 8-3 shows the results of measuring the elastic viscosity of polyesters obtained in Examples 8-3 7 to 8-5 4 and Comparative Examples 8-4. [Example 9] (Example 9-1) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added 0. 46 parts by volume of a 5 g / L solution of rhenium acetate in ethylene glycol, and then added to the acid component of the polyester is 0.  1 mol% (W) 1,1'-dinaphthyl-2, 2'-diamine 5 was stirred at normal pressure and 245 ° C for 10 minutes. Increase the temperature to 2 7 5 ° C in 50 minutes, and slowly reduce the pressure of the reaction strip to O. lTorr (mmHg), and then polycondensation at the same temperature and pressure for 180 minutes to obtain a polyester. (Examples 9-2 to 9-1 8) Except (T) 1,1,2-di-2-phenol, (BB) 7-Amino-4-methylcoumarin, (K) Moraxanthin , (AA) 2-aminochromone, (L) epigallocatechin gallate, (X) epicatechol, (〇) carbamic acid [8] arene, (P) p-th-3-butyl Carboxylic acid [8] arene, (B) alizarin, (CC) catechol, (C) emodin, (D) 1,4-diamine anthracene, (E) 1,8-diamine -4, 5-Dihydroxyanthracene _, (『) 5,8-dihydroxy-1,4-naphthyl alcohol, (11) deoxyalizarin, (I) 4, printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A polyester was prepared in the same manner as in Example 9-1 except for disodium 5-dihydroxynaphthalene-2, 7-disulfonic acid and (Z) 1,8-diaminonaphthalene. (Comparative Example 9-1) A polyester was obtained in the same manner as in Example 9-1 except that 1,1 ^ diaphthyl-2,2'-diamine was not added. -81- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7 V. Description of the invention (deduction) (Comparative Example 9-2) Except A polyester was prepared in the same manner as in Example 9-1 except that the ethylene glycol solution of rhenium acetate was not added. Table 9-1 shows the measurement results of the specific viscosity of the polyesters obtained in Examples 9-1 to 9-18 and Comparative Examples 9-1 and 9-2. [Example 1 Q] (Example 1 Q-1) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate was added 1.  4 parts by weight of sodium acetate as a catalyst and Q for acid content in polyester. Q5 Molar% 醍 Alizarin, stirred at normal pressure, 245 ° C for 10 minutes. Increase the temperature to 275 ° C in 50 minutes and slowly reduce the pressure of the reaction strip to 0.  1 T 〇 it, and then polycondensation at the same temperature and pressure for 180 minutes. The physical properties (IV) of the obtained polymer are shown in Table 10-1. (Examples 10-2 to 1 0-8 and Comparative Examples 10-1 to 1 0-1 1) A polyester was polymerized in the same manner as in Example 1 0-1 except that the catalyst was changed. The physical properties (I V) of the obtained polymer are shown in Table 1 0-2. (Comparative Examples 10-13 (Reference Example)) To 8900 parts by weight of bis (2-hydroxyethyl) terephthalate, a 5 g / L ethylene glycol solution of antimony trioxide was added to the polyester The acid content is 0.  0.5 mol%, and stir for 10 minutes at 25 ° C under normal pressure. The temperature was raised to 275 ° C within 50 minutes, and the pressure of the reaction strip was slowly reduced to below 1 mmHg, and then the polycondensation was performed at the same temperature and pressure for 180 minutes. The physical properties (I V) of the obtained polymer are shown in Table 1 G-2. [Example 1 1] -82- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----------- installation -------- order- -------- (Please read the precautions on the back before filling in this page) 490473 A7 B7__ V. Description of the invention (81) (Example 11-1) p-100 parts by weight of diethyl terephthalate For esters and 70 parts by weight of 1,4-butanediol, 0.  1 part by weight of manganese acetate tetrahydrate as a transesterification catalyst was stirred at 150 ° C under normal pressure to raise the temperature to 210 ° C, and the by-produced methanol was distilled off. After 180 minutes, add 0.  7 parts by weight of trimethylphosphoric acid to terminate the transesterification reaction. Then, a polycondensation catalyst having the same composition as that of the user in Example 92 was added, and the mixture was stirred at 220 ° C for 10 minutes under a nitrogen ambient gas, and then the temperature was changed from 220 ° to 40 ° C in 40 minutes. C rose to 250 ° C, slowly reduce the pressure of the reaction bar to O. lTorr, and at 2 50 ° C, O. Polycondensation at lTorr for 40 minutes. The physical properties of the obtained polybutylene terephthalate are shown in Table 11. (Please read the note on the back? Matters before filling out this page.) Example implementation-2 N \ l / 1X I 1i Operation, in-phase composition agent evolution 11 he I urge 11 0 Compared with esters, butyl and extruded, acid 6 i 2 formazan-catalyzed di-L-phenylene polycondensation is modified and divided by the need for polymerization. Example implementation ix 1X Ester-but-but-equivalent value} 2 acid 1-methyl 1 dimerization gains in a timely manner ○ Indications of the Institute of Intellectual Property Bureau of the Ministry of Economic Affairs Employee Consumption Cooperative printed acid 1 A Example 2 The amount of benzene added is increased. Ο In 10 tanks, the inverse amount of E 3 5 9 should be in the same phase as the catalyst for polycondensation and polycondensation. The alcohol is fed into the furan hydrogen and water. Under 50 c 1 0 ° should be 2 reverse, the pressure ester is often used to make the internal minutes by temperature ο 4 afterwards ο minutes 分 ° c to the pressure of the bar should be slowly lowered P ο 5 2 to rise to The result of the rendezvous ο Zhong ο vr g min / ο _ —_ 5 d should be 93 against Also under the said Γ b Γ S To butoxy. 1 οο Acid V 0 ° Two 25 Benzene paper sizes are applicable to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7___ v 8 2 V. Description of the invention ( ) (Comparative Example 1 1 _ 2) Polybutylene terephthalate was polymerized in the same manner as in Example 11-1 except that alizarin was not added. Table 11 shows the polycondensation time and the physical properties of the obtained polyethylene terephthalate. (Comparative Examples 1 to 3) Polybutylene terephthalate was polymerized in the same manner as in Example 1 to 1 except that an ethylene glycol solution of lithium acetate was not added. Table 11 shows the polycondensation time and the physical properties of the obtained polybutylene terephthalate. [Example 1 2] (Example 1 2-1) Q was added to 100 parts by weight of dimethyl 2,6-naphthalenedicarboxylic acid and 56 parts by weight of ethylene glycol.  0 3 parts by weight of manganese acetate tetrahydrate as a transesterification reaction catalyst, stirring was started at 150 ° C under normal pressure to raise the temperature to 2 2 (TC, distill off byproduct methanol. At 1 2 0 After minutes, add 0.  0 2 1 part by weight of trimethylphosphoric acid to terminate the transesterification reaction. Then, a polycondensation catalyst having the same composition as that of the user in Examples 1 to 92 was added, and the mixture was stirred at 2 3 5 ° C for 10 minutes under a nitrogen ambient gas, and the temperature was changed from 2 3 to 50 minutes. 5 ° C to 285 ° C, slowly reduce the pressure of the reaction bar to O. lTorr, another at 2 8 5 ° C, O. Polycondensation at lTorr for 40 minutes. The physical properties of the obtained polyethylene naphthalate are shown in Table 12. (Examples 1 2-2 to 1 2-2 6 and Comparative Example 1 2-1) Except changing the polycondensation catalyst, the same operations as in Example 1 2-1 were performed. The composition of the catalyst used, the polycondensation time required for the polymerization of poly (ethylene naphthalate), and the physical properties of the poly (butylene terephthalate) obtained are shown in Table 1 2 -84- This paper applies Chinese national standards (CNS) A4 size (210 X 297 mm) ------------- install ---- (Please read the precautions on the back before filling this page) Order --------- Printed clothing by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7 5. The invention description (port) is shown. (Example 1 2-2 7) 100 parts by weight of 2,6-naphthalenedicarboxylic acid and 63 parts by weight of ethylene glycol were placed in a reaction tank under a pressure of 2.5 kg / cm 2 and 2 5 Stir at 0 ° C and distill off by-product water. After 240 minutes, release the pressure when the water generation is substantially stopped. Then, the polycondensation catalyst was added in exactly the same manner as in Example 1-2, and the mixture was stirred at 235 ° C under a nitrogen atmosphere for 10 minutes, and then the temperature was increased from 235 ° C to 285 ° C within 50 minutes. Slowly reduce the pressure of the reaction strip to 0.1 Torr, and then perform a polycondensation reaction at 28.5 ° C and 0.1 Torr for 37 minutes. The IV of the obtained polyethylene naphthalate was 0.  6 3 d 1 / g. (fcb Comparative Example 1 2-2) Polyethylene terephthalate was polymerized in the same manner as in Example 1 2-1 except that alizarin was not added. When the polycondensation reaction was allowed to proceed for 180 minutes, I V could not reach 0.  5 d 1 / g, so the polymerization was terminated. In addition, poly (ethyl acetate) was polymerized in the same manner as in Example 1-2. Table 12 shows the polycondensation time and the physical properties of the obtained polyethylene naphthalate. (Comparative Example 1 2-3) Except that ethylene glycol solution of lithium acetate was not added, poly (ethyl acetate) was polymerized in the same manner as in Example 1 2-1. Table 12 shows the polycondensation time and the physical properties of the obtained poly (vinyl acetate). [Example 1 3] (Example 1 3-1) For 100 parts by weight of diethyl terephthalate and 78 parts by weight of 1,3-propanediol, 0 J 3 and 8 parts by weight were added as a transesterification reaction catalyst. Acetic acid 85-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----------------- (Please read the precautions on the back before filling (This page) 490473 A7 B7 V. Description of the invention (84); acid in M phosphorus sif, residues-methyl AP, dihydrate, 4 parts of manganese to 2 liters of heavy manganese, and the temperature should be increased to make the mixture start to ° C ο 8 7 2 2 ο and ο add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, add, 50, $ 1, exchange, S, cross, &gt; , 3 of the 2 use, make the pressure constant 2 9 minutes after the application of gas, ο 1X stir under ° c 璟 gas nitrogen in the internal minutes ο 3 2 by the temperature

Γ Γ ο T to rise at P and other ° c ο 6 2 oc ο 6 2 Propanecarboxylic acid 2 2 3- 1X benzene

Ο 分 分 ο 8 Examples of esters that are slower than 1T under polycondensation are shown in the table. 3 li shows the value to make the time 0. Cooperative polycondensation. ^ PJjr.nJ Examples of esters that are in the same phase as propylene, 7 and 13 acids. Dimethylbenzene, paraben, polyisocyanate, and chemical composition of the catalyst group were changed to eliminate the use case. Ο ο 1X will be shown as 3, 1, the amount of sexual esters of 92 propyl, acetic acid methyl Methyldiphenylbenzene p-parameter} 27 parts of CQ is regained 1 as shown in 3 diethyl alcohol (please read the notes on the back before filling this page) Binding --- in the middle tank should be de-distilled and Stir down P ο 3 2 Press and add 2 m C / β k when the agent is used to stop, stop, stop, and grow together. The water is the same as above, 7 and 13. After the example, Shi Zhongshi divides. Ο Add 21 to add, 〇After the water, the pressure of 0% pressure is released, and the ambient air is nitrogen. The pressure is usually in the next minute. 1 ± Stir down V ο 3 Slowly decrease V ο 6 2 to rise V ο 3 2 It is printed by Du Wenshi inside the minute 5 4 It is printed at the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs to the minute pressure of 75 Shito anti-d

Example S is compared with polycondensation 1. ο = lower f Γ r b is 0 s τ -ϊ 1 propyl ο ethanene, acid methylbenzene is obtained by polycondensation.

Γ Γ ο T Yu ° c ο 6 6 8 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 8 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperative 490473 A7 _B7_ 85 V. Invention Explanation () Polyethylene terephthalate was polymerized in the same manner as in Example 1-3, except that no alizarin was added. When the polycondensation reaction was allowed to proceed for 180 minutes, the IV value could not reach G. 5 d 1 / g, so the polymerization was terminated. Further, poly (trimethylene terephthalate) was polymerized in the same manner as in Example 1-3. Table 13 shows the polycondensation time and the physical properties of the obtained poly (trimethylene terephthalate). (Comparative Example 1 3-3) Polypropylene terephthalate was polymerized in the same manner as in Example 1 3-1 except that the ethylene glycol solution of lithium acetate was not added. Table 13 shows the polycondensation time and the physical properties of the obtained poly (trimethylene terephthalate). [Example 1 4] (Example 1 4 -1) 100 parts by weight of diethyl terephthalate, 54 parts by weight of ethylene glycol, 2 3 parts by weight of 1,4-cyclohexanedimethanol, and Add 0.88 parts by weight of manganese acetate tetrahydrate as a transesterification reaction catalyst, start stirring at normal temperature at 190 ° C, raise the temperature to 220 ° C, and distill off byproducts Methanol. After 12 G minutes, 0.026 parts by weight of trimethylphosphoric acid was added to stop the ester exchange reaction. Then, the polycondensation catalyst having the same composition as that of the users in Examples 1 to 92 was added, and the mixture was stirred at 2 0 0 ° C for 15 minutes under a nitrogen atmosphere, and then the temperature was changed from 2 4 to 15 minutes. The temperature was raised from 0 ° C to 27.5 ° C, and the pressure of the reaction strip was gradually reduced to 0.1 T 〇rr, and the polycondensation was further performed at 70 rpm and 0. 1 T 〇r r for 70 minutes. The physical properties of the obtained copolyester of cyclohexanedimethanol are shown in Table 14. (Examples 1 4-2 to 1 4 _ 2 6 and Comparative Example 1 4-1) The same operations as in Examples 1 4 to 1 were performed except that the catalyst was changed. Make -87 a paper size applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----------- installed -------- ordered ------ --- (Please read the notes on the back before filling this page) 490473 A7 B7___, 86, V. Description of the invention () (Please read the notes on the back before filling this page) The polycondensation time required for the polymerization of the copolyester of methanol, and the physical properties of the obtained copolyester of cyclohexanedimethanol are shown in Table 14. (Example 1 4-2 7) 100 parts by weight of terephthalic acid, 52 parts by weight of ethylene glycol, 32 parts by weight of 1,4-cyclohexanedimethanol were placed in a reaction tank at 2. Pressurized at 5 kg / cm 2, stirred at 2 4 G ° C, and distilled off the by-produced water. After 5 minutes at 1 G, the pressure on the side effects of dehydration on the actual water was released. Then, the same polycondensation catalyst as that of Example 1 4-1 was added, and the mixture was stirred for 15 minutes under a nitrogen atmosphere at a normal pressure of 240 ° C, and then the temperature was adjusted to 240 ° C within 7 5 minutes. The temperature was raised to 275 ° C, and the pressure of the reaction bar was gradually reduced to 0.1 T rr, and the polycondensation reaction was performed at 27.5 ° C and 0 · ITorr. The reduced viscosity of the obtained copolyester of cyclohexanedimethanol was G. 7 7 d 1 / g. (Comparative Example 14-2) Except that alizarin was not added, cyclohexanedimethanol copolyester was polymerized in the same manner as in Example 14-1. The physical properties of the copolyester of the polycondensation time and the obtained cyclohexanedimethanol are shown in Table 14. (Comparative Example 1 4-3) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, except that a glycol solution of lithium acetate was not added, and a copolyester of cyclohexanedimethanol was polymerized in the same manner as in Example 1 4-1. Table 14 shows the physical properties of the polycondensation time and the obtained copolyester of cyclohexanedimethanol. [Example 15] (Example for film application) Evaluation method of foreign matter generated in film: The foreign matter was evaluated by the following method. -88- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7__ v 8 7 V. Description of the invention () The amount of foreign matter in the film: The film was sandwiched between glass coverslips and melted, and was observed at 2 Q 0 times in a dark field by an optical microscope, and the number of bright spots of 10 cm 2 was evaluated. If there are less than 40 foreign objects, there will be no other problems, but if there are more than 6 Q, there will be practical problems. (Example 1 5 _ 1) The catalyst used in Examples 1-92 was used, and PET was polymerized by the same method as in Example 1. When the IV of the polymer was 0.63, the polymer was made by a conventional method. Tablet. After the polymer was dried, it was melted in a 1-axis extruder, and the mold from the exit of the extruder was extruded on a cooling mold barrel to form an unstretched film. Then, the unstretched film was longitudinally stretched 3.3 times at 9 G ° C, and then stretched 3.6 times at 110 ° C, and heat-treated at 190 ° C to obtain a polyester film. The film was almost completely free of foreign matter, and the surface of the film was defective. The measurement results of the amount of foreign matter in the film of this polymer are shown in Table 15 (Examples 1 2 to 5 to 15-2 6 and Comparative Example 1 5 to 1 to 1 5-3) except for changing the catalyst, PET was polymerized in the same manner as in Example 15-1. The amount of foreign matter in the obtained P E T film was measured, and the catalyst composition used is shown in Table 15. In Comparative Examples 1 to 5, the polymerization rate was slow and could not be put into practical use. In Comparative Examples 15-2, 15-3, satisfactory polymers could not be obtained, so the amount of foreign matter was not measured. (Comparative Examples 1 to 5-4) P E T was polymerized in the same manner as in Examples 1 to 5 except that antimony trioxide was used as a catalyst. The amount of antimony trioxide added was 0 · ϋ 5 mol% for the acid component in P E T (Comparative Example 26, equivalent catalyst). -8 9-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------- Installation -------- Order ---- ----- (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7___ ν 88 5. Description of the invention () The amount of foreign matter in the PET film obtained, and The catalyst composition used is shown in Table 15. In the sample of Comparative Example 15-4, although the polymerization rate was practical, the amount of foreign matter in the polymer was particularly high. [Example 16] Hollow molded product The measurement method of the main characteristic values of the hollow molded product is as follows. (Diethylene glycol content (hereinafter referred to as [DEG content]). The polyester is decomposed by methanol, and the amount of DEG is quantified by gas chromatography, and the ratio is for all alcohol components (%) Content. (Acetaldehyde content (hereinafter referred to as [AA content]) The resin pellet sample / distilled water = lg / 2ml was placed in a glass tube replaced with nitrogen, and the upper part was sealed at 160 ° C. Extraction and extraction treatment for 2 hours, after cooling, the high-sensitivity gas chromatography analysis was used to measure the acetaldehyde and acetaldehyde concentration in the extracted solution in ppm. (Cyclic 3 polymer content of polyester) Hexafluoroisopropanol / chloroform mixture was diluted by adding chloroform. After adding methanol to precipitate the polymer, it was filtered. The filtrate was evaporated to dryness and quantified by dimethylformamide. Layer analysis method was used to quantify the cyclic terpolymer of polyester. (Haze)% The cuts taken from the carcass of the following shaped body were measured using a Nippon Denshoku (Hakage) haze tester. (Forming of the molded body) The dried polyester was manufactured by Meiki Seisakusho M_ 1 0 0 injection molding machine, in the cylinder-temperature 2 0 0 ° C, with a flat mold to cool down to 1 G ° C. -90 a paper size applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------ Equipment -------- Order ------ (Please read the precautions on the back before filling this page) Manufacturing 490473 A7 B7____ Heart 89 V. Description of the invention () It is formed to produce a segment-attached shaped body. The segment-attached shaped body is formed by a thickness of 2, 3, 4, 5, 6, 7, 8, 9, 10, llinni. A forming plate having an angle of about 3cmx and a corner of about 5cm is provided with a stage shape, and one piece weighs about 146g. A 5mm-thick forming plate is measured for Haze (%). (Examples 16-1) Using Examples 1-9 2 The catalyst used was a polyester polymerization catalyst, and was polymerized in the same manner as in the polymerization of PET in Example 1. The PET resin was cut into flakes when the IV of the resin was 0 · 60, and then cut into a nitrogen atmosphere. Solid phase polymerization was performed at 5 T. The IV of the obtained PET was 0.75, the [DEG content] was 2.6 mole%, the [AA content] was 3. 3ρριη, and the content of the cyclic 3 polymer was 0.3 Q parts by weight The haze of the obtained 5 mm thick formed plate formed by the above method of PE ET by the above method is 4. 7¾ 傺. (Example 1 6-2 to 1 6-2 6 and Comparative Example 1 6-1 to 1 6-3) Except changing the catalyst, perform the same operation as in Example 16-1. The composition of the used catalyst and the degree of haze of the formed plate after solid-phase polymerization are shown in Table 16. Comparative Examples 16-1 to 1 6-3 have the disadvantage that the polycondensation time is long. In addition, the [D E G content] of the obtained P E T was all 1.7 to 3.5 mol%, the [AA content] was 5 ρρηι or less, and the cyclic terpolymer content was 0.31% by weight or less. (Comparative Example 16-4) The same operation was performed as in Example 16-1 except that the catalyst was changed to antimony trioxide. The amount of antimony trioxide added to the acid component of P E T is an antimony atom of 0 · D 5 mole% (Comparative catalysts 1 to 2 6). The haze of the formed plate obtained after solid-state polymerization is shown in Table 16. The obtained -9 1 paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----—— — — — — — 1111-I Order I ------- (Please Read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7___ v 9 0 V. Description of the invention () Polymer has excellent thermal stability, but transparency is particularly poor. The [PET content] of the obtained PET was 2.5 moles, the [AA content] was 5 ppm, and the content of the cyclic terpolymer was 0.31% by weight. [Example 17] (Example of use of fiber for industrial materials) A method for measuring the amount of foreign substances contained in polyester used for fibers for industrial materials is as follows. Amount of foreign matter: The polyester film was formed into a biaxially stretched film of 0.1 mm, and the amount of foreign matter was visually observed and expressed as a gage number equivalent to 1 g. (Example 17-1) For bis (2-hydroxyethyl) terephthalate, 5 g / L of lithium acetate as a polycondensation catalyst was added in a solution of ethylene glycol in a nitrogen atmosphere, Stir at atmospheric pressure at 2 4 5 ° C for 10 minutes. The catalyst composition was the same as in Examples 1-9 2. Then, the temperature was raised to 275 ° C within 50 minutes, and the pressure of the reaction strip was gradually lowered to 0 · 1 T 〇rr, and the polycondensation was performed at 2 75 ° C and 0 · 1 T 〇rr. reaction. When the IV of the polymer is 0.63, the polymer is tableted in a conventional manner, and solid-state polymerization is performed under a vacuum of 230 ° C and Q. 1 T rr to obtain a polyester with an IV of 1.0. sheet. When it is spun at a spinning temperature of 3 1Q ° C, the mold is almost completely free of contamination and the yarn making property is also good. Foreign matter was 0 pieces / g. (Examples 17-2 to 1 7-2 6 and Comparative Example 1 7-1) The same operations as in Example 1 were performed except that the catalyst was changed. When the IV of the polymer is 0.63, the polymer is tableted in a conventional manner, and solid-state polymerization is performed under a vacuum of 230 ° C and 0.01 Torr to obtain a polyester sheet with an IV of 1.3. When pre-spun at a spinning temperature of 3 1 Q ° C, the mold is almost completely free from contamination and the yarn-making property is also good. The identified foreign matter is shown in Table 17. Comparative Example 1 7-1 -92- This paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ------------- installation ---- (Please read the precautions on the back before filling this page) Order --- ------ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7. B7__ v 9 1 V. Description of the invention () Has the disadvantage of long polycondensation time. (Comparative Examples 1 7-2 and 1 7-3 ) Except for changing to a catalyst, the same operation as in Example 17-1 was performed. The results are shown in Table 5. The polymerization was performed for 180 minutes or more, and the IV could not reach 0 · 50 (Comparative Example 17) -4) The same operation was performed as in Example 17-1 except that the catalyst was changed to antimony trioxide. The amount of antimony trioxide added to the acid component in PET was 0.5 0.5 mol. % (Comparative example 2 6 equivalent catalyst). When the IV of the polymer is 0.63, the polymer is tableted in a conventional manner, and solid phase polymerization is performed at 230 ° C, 0.01 Tor &r; r $ to obtain IV as 1.0 polyester sheet. When it is spun at a spinning temperature of 3 0 ° C, the mold is quite contaminated and the yarn making property is not good. In addition, the resin is black and foreign matter is quite large. [Example 1 8] (Example as a fiber application) (Example 1)

In a stainless steel autoclave, add 1700 parts of terephthalic acid, 1 160 parts of ethylene glycol, 4.0 parts of triethylamine, at 230 ° C, and a valve pressure of 2.5 kg / The generated water was removed under cm 2 and an esterification reaction was performed for 2 hours. Then, a 5 g / L concentration of lithium acetate in ethylene glycol solution was added as a polycondensation catalyst, the lithium atom was G. 3 mole% for the acid component, and the alizarin was (K 2 mo for the acid component). Ear%, the temperature in the bar was raised to 275 ° C within 1 hour, and the pressure in the bar was gradually reduced to 0.1 T 〇r 1, during which the polycondensation reaction was performed under these conditions. The catalyst composition is the same as that of Examples 1 to 92. The polymer is pelletized in a conventional manner so that the spinning temperature is 290 ° C -9 3-This paper applies Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) (Please read the notes on the back before filling out this page) —Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 B7__ 9 2 V. Invention Note: When spinning in the conventional method, the mold is almost completely free from contamination and the yarn making property is good. The time required for polymerization and the IV of the polyester obtained are shown in Table 18. (Example 1 8-2 ~ 1 8-2 6 and Comparative Example 1 8-1) Polyethylene terephthalate was polymerized in the same manner as in Example 1 8-1. The polycondensation time and IV are shown in Table 1 8 The composition of the catalyst used is also shown in the table. The yarn-making property of any polyester is good. V (Comparative Example 18-2) The same as Example 18-1 except that alizarin is not added. Polyethylene terephthalate was polymerized. When the polycondensation reaction was performed for 180 minutes, the IV could not reach 0.5 dl / g, so the polymerization was terminated. In addition, poly (ethylene terephthalate) was polymerized in the same manner as in Example 18-1. At that time, polymerization was not possible as shown in Table 18. (Comparative Example 18-3) Except that a lithium ethylene glycol solution was not added, polyethylene terephthalate was polymerized in the same manner as in Example 18-1. When the polycondensation reaction was 18Q minutes, IV could not reach G. 5 d 1 / g, so the polymerization was terminated. In addition, when poly (ethylene terephthalate) was polymerized in the same manner as in Example 18-1, as shown in Table 18 (Comparative Examples 18-4) Polyethylene terephthalate was polymerized in the same manner as in Example 18-1 except that the catalyst was changed to antimony trioxide. The amount of antimony trioxide added to the polyester In terms of the acid component, the antimony atom is 0.05 mol% (equivalent catalysts of Comparative Examples 1 to 26). The polycondensation time and IV are shown in Table 18 The amount of metal catalyst added is used as the amount of metal atoms. Yarn-making properties are poor and the yarn is easy to break. -9 4 A paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm)- --------- Equipment -------- Order --------- (Please read the precautions on the back before filling this page) Preparation 490473 A7 B7__, 93 V. Description of the invention (Example 1 9) Example of fiber containing metal sulfonate group The dyeability of the fiber was measured by measuring the dye adsorption rate as described below. (Dye Adsorption Rate) Machine: Mini color dyeing machine Dye: Nichiron Black KB2Q (U (cationic dye: manufactured by Nissin Kasei Co., Ltd.) Concentration: 4. Q% Auxiliary: 1 (U acetic acid (2 in 1 / L) 10% sodium acetate (2ml / L) Temperature: 130 ° C Time: 4 5 minutes Bath ratio: 1: 50 (Example 1 9-1) Put 1,000 parts by weight in a stainless steel autoclave Phthalic acid, 787 parts by weight of ethylene glycol, 19 parts by weight of 22% by weight titanium oxide in ethylene glycol dispersion, 3 parts by weight of triethylamine, after nitrogen substitution, pressurized to a valve pressure of 2.5 kg / cm2, at The distilled water was continuously removed by a distillation column at 245 ° C, and an esterification reaction was performed. After the reaction started, the pressure was released after 11 minutes, and an oligomer having an esterification rate of 95% was prepared. The polymer was transferred to a polycondensation reactor, and 2 1.6 parts by weight of 5-sodium sulfoisobenzoic acid dihydroxyethyl ester, 12.5 parts by weight of polyethylene glycol with a molecular weight of 1,000, and 0.5 were added. 6 parts by weight of Irgang X 1 3 3 0 (manufactured by Chiba Machine Maple Co., Ltd.) as an antioxidant and a polycondensation catalyst of the same composition used in Examples 1 to 92, at 60 minutes The internal temperature rises to 2 7 5 ° C, so that the pressure of the reaction strip slowly drops to 0.3 Torr, -95- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm)- ---------- · Installation -------- Order --------- (Please read the precautions on the back before filling this page) 490473 A7 B7 V. Description of the invention () 9 4 S undergoes a polycondensation reaction at the same temperature and pressure. When the obtained polymer is pelletized by a conventional method, and it is spun at a spinning temperature of 290 ° C, the mold is almost completely unaffected. Pollution and good yarn-making properties. The time required for polymerization and the IV of the polyester obtained are shown in Table 2. The dye absorption of the drawn yarn of 50 denier and 24 single yarns was 97.7%, and was good. Example 1 9-2 ~ 1 9-2 6 and Comparative Example 1 9-1) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, in addition to changing the polycondensation catalyst, and working to modify the metal sulfonate group The IV is shown in Table 19. The amount of the metal catalyst added. The yarn making good adhesion rate of any example is above 95% and the pseudo-goodness is good. (Examples 1 9-2 7) In addition to 5 ~ sodium sulfoisobenzene Dihydroxy formate The IV of the polyester obtained in Example 1 9-1 was 0.40 d 1 / g, which was low, and the adsorption rate was 9 G%. It can be known that the pressure is normal (Comparative Example 1 9-2). It was polymerized with ethyl acetate in the example. The polycondensation reaction was 0.5 dl / g, so the polymerization was terminated. Further, the modified polyester of the metal sulfonate group was polymerized (Comparative Examples 19 to 3). The same operation was carried out in Examples 19-1 to polymerize the polyester. The polycondensation time and the amount of addition are good as metal atoms. In addition, the same operation was performed when the amount of the dye-absorbing ethyl ester was 90 weight polyester. The dyeability of the above dyes was observed at 100 ° C. In addition, the yarn making property 1 was the same, so that the polytetraphthalic acid did not reach IV in the same manner as in Example 1 at 180 minutes, and was not polymerized as shown in Table 19. Except for the ethylene glycol solution without adding lithium acetate, Polyethylene terephthalate was polymerized in the same manner as in Example 1. Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) when the polycondensation reaction is 180 paper size (please read the precautions on the back before filling this page) 490473 A7 _B7__ V. Description of the invention f5) (Please first Read the phonetic on the back? Matters need to fill in this page again) The IV cannot reach 0.5 d 1 / g in minutes, so the polymerization is terminated. Further, the modified polyester having a metal sulfonate group was polymerized in the same manner as in Example 1. As shown in Table 19, the polymer could not be polymerized. (Comparative Example 19-4) A metal sulfonate group-modified polyester was polymerized in the same manner as in Example 19-1 except that the catalyst was changed to antimony trioxide. The amount of antimony trioxide added to the acid component in the polyester is 0.55 mole% antimony (comparative catalyst of Comparative Example 26). The polycondensation time and I V are shown in Table 19. The amount of metal catalyst added is the amount of metal atoms added. The dyeability is 96% good, but the yarn making property is not good, the back pressure rises and the yarn breaks easily. [Example 2 0] Example of flame retardant fiber The evaluation method of flame retardant characteristics of flame retardant polyester fiber was performed as follows: Flame retardant: Evaluated according to J I S L-1 Q 9 1 D. In other words, the number of knitting trials of 5 G denier 2 4 single yarns obtained by spinning and stretching was measured. Those who received more than 3 times of inflammation were qualified. (Example 2 G-1) Printed by a consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, put 401 parts of terephthalic acid and 45 parts of a phosphorus compound having the following formula (formula 84) in a stainless steel autoclave, 300 parts of ethylene glycol was added, and 1 · 7 parts of triethylamine was added. The generated water was removed at 230 ° C and a valve pressure of 2.5 kg / cm 2, and an esterification reaction was performed for 2 hours. As a polycondensation catalyst, an ethylene glycol solution of 5 g / L lithium acetate with a concentration of 0.3 mol% of lithium atoms as the acid component and 0.2 mol% of caustic acid as the acid component were added. The temperature of the strip can be raised to 2 7 5 ° C within 1 hour, and the pressure in the strip can be increased to -9 7 in the meantime.-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm). Printed by the Consumer Affairs Cooperative of the Property Bureau 490473 A7 B7___ v 9 6 V. Description of Invention () Slowly reduced to 0.1 τ 0 rr. A polycondensation reaction is performed under these conditions. The polymer is pelletized in a conventional manner, and the polymer is spun at a spinning temperature of 290 ° C. The mold is completely free from contamination and has good yarn making properties. The time required for polymerization and the I V of the obtained polyester are shown in Table 20. The flame resistance is 5 times the number of times of inflammation, which is a qualified level. (Eq. 84)

CH2

I HOch2 ch2c o—c-c-c—c-och2 ch2oh

II H h2 II 〇〇 (Examples 20-2 to 2 G-2 6 and Comparative Example 20-1) Except changing the polycondensation catalyst, the same operation as in Example 2 0-1 was performed to make the polymerization pair Ethyl phthalate is polymerized. The polycondensation time and I V are shown in Table 20. In either case, the yarn making property was good. In addition, the flame resistance of any case was 5 times the number of times of inflammation. (Comparative Example 20-2) Except that alizarin was not added, polymerized polyethylene terephthalate was polymerized in the same manner as in Example 20-1. When the polycondensation reaction was 180 minutes, I V could not reach G. 5 d 1 / g, so the polymerization was terminated. In addition, the copolymers of the phosphorus-containing compound copolymerized polyester were polymerized in the same manner as in Examples 2 to 1, and as shown in Table 2G, the polymerization was impossible. (Comparative Examples 2 0-3)-98- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A7 _B7___ Heart 97 V. Description of the invention () Except for the ethylene glycol solution without adding lithium acetate, poly (ethylene terephthalate) was polymerized in the same manner as in Example 2 ϋ-1 Ester polymerization. When the polycondensation reaction was 180 minutes, the IV value could not reach 0.5 dl / g, and the polymerization was terminated. In addition, a phosphorus compound copolymer polyester was polymerized in the same manner as in Example 20-1, but it was not polymerized as shown in Table 20. (Comparative Examples 20 to 4) A phosphorous compound copolymerized polyester was polymerized in the same manner as in Example 2 G-1 except that the catalyst was changed to antimony trioxide. The amount of antimony trioxide added was 0.05 mol% for the acid component in the polyester (Comparative Example 26 is a comparable catalyst). The polycondensation time and IV are shown in Table 20. The flame resistance is 5 times of inflammation, which is a false standard, but the yarn is not good and it is easy to break. [Utilization field in industry] The present invention relates to a polyester having excellent thermal stability using a polymerization catalyst other than an antimony compound and a germanium compound, a polyester polymerization catalyst for manufacturing the polyester, and polymerization using the polyester Catalyst for making polyester. Specific examples of the above-mentioned polyesters include polyethylene terephthalate, polybutylene terephthalate, polybutylene terephthalate, and cyclohexanedimethanol-modified polybutylene terephthalate. Ester, polyethyl acetate. The polyesters mentioned above can be used for clothing applications with excellent thermal stability and yarn-making properties, interior design applications, polyester fibers most suitable for materials such as cotton and nonwovens, and polyester fibers suitable for industrial materials (such as tire coatings). Polyester fiber for industrial materials such as rubber reinforcement for V-belts or V-belts). In addition, the above-mentioned polyesters can be used for hollow molded articles, films, sheets, and the like, such as bottles having excellent transparency. In addition, the above-mentioned polyesters can be widely used in automobile parts, electrical and electronic parts, molded articles for various other purposes, and coatings or adhesives. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order ------ (Please read first Note on the back, please fill in this page again) 490473 A7 B7 V. Description of the invention (9 8 [Table 1-1 Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Example 1-1 Example 1-2 Example 3 Example 3 1- 4 Example 1-5 Example 1-6 Example 1-7 Example 1-8 Example 1-9 Example 20 Example 1 1-11 Example 1-12 Example 1-13 Example 1 -14 Examples 1 to 15 Examples 1-16 Examples 1-17 Examples 1-18 Comparative Example 1-1 Comparative Example 1-2 Metal compound lithium acetate additive IV (dl / g) (A) 0.58 (B) 0.61 (C) 0.62 (D) 0 · 56 (E) 0.60 (F) 0.58 (G) 0.57 (H) 0.62 (I) 0.61 (J) 0.57 (K) 0.65 (L) 0.57 (M) 0.62 (N) 0.58 (〇) 0.63 (P) 0.60 (Q) 0.57 (R) 0.57 —- 0.31 (A) 0.25 ------------- install -------- order --- ------ ^^ 1 · (Please read the precautions on the back before filling this page) Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 490473 A7 _B7 9 9 V. Description of invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 1 ~ 2] Metal Compound Additive IV (dl / g) Examples 1-1 9 (A) 0.60 Examples 1 _ 2 0 (B) 0.58 Examples 1 _ 2 1 (C) 0.55 Examples 1 _ 2 2 (D) 0.61 Examples 1 _ 2 3 (E ) 0.61 Examples 1-2 4 (F) 0.58 Examples 1 _ 2 5 (G) 0.57 Examples 1 _ 2 6 (H) 0.61 Examples 1-2 7 Sodium acetate (I) 0.59 Examples 1-2 8 (J) 0.56 Examples 1-2 9 (K) 0.63 Examples 1-3 0 (L) 0.55 Examples 1-3 1 (M) 0.60 Examples 1-3 2 (N) 0.61 Examples 1-3 3 (〇) 0.60 Examples 1-3 4 (P) 0.58 Examples 1-3 5 (Q) 0.54 Examples 1-3 6 (R) 0.55 Comparative Examples 1-3 — 0.27-1 0 1----- --------- Loading ---- (Please read the precautions on the back before filling in this page) Order --------- This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) 490473 A7 B7 10 0 V. Description of invention () Printed by the cooperative [Table 1-3] Metal compound additive IV (dl / g) Examples 1-3 7 (A) 0.56 Examples 1-3 8 (B) 0.60 Examples 1-3 9 (C) 0.57 Examples 1-4 0 (D) 0.59 Example 1-4 1 (E) 0.60 Example 1-4 2 (F) 0.55 Example 1 _ 4 3 (G) 0.56 Example 1-4 4 (H) 0.58 Example 1-4 5 Potassium (I) 0.59 Example 1-4 6 (J) 0.58 Example 1-4 7 (K) 0.61 Example 1-4 8 (L) 0.59 Example 1-4 9 (M) 0.61 Examples 1-5 0 (N) 0.60 Examples 1-5 1 (〇) 0.59 Examples 1-5 2 (P) 0.57 Examples 1-5 3 (Q) 0.57 Examples 1-5 4 (R) 0.58 Comparative example 1-4 — 0.27 -10 2- ------------- install -------- order --------- (Please read the note on the back first Please fill in this page again for this matter) This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 490473 A7 B7 v 10 1 V. Description of invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 1 -4]

-10 3- ------------- install ---- (Please read the precautions on the back before filling this page) Order --------- This paper size is applicable to China National Standard (CNS) A4 Specification (210 X 297 mm) 490473 A7 _B7, 10 2 V. Description of Invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 1-5]

-10 4- ------------ Installation -------- Order --------- (Please read the precautions on the back before filling this page) This paper Standards are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) 490473 A7 — —_ B7 ττ w 1 〇 5. Description of Invention () [Table 1-6⑴] Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

------------- Pack ------- Order --------- (Please read the note on the back? Matters before filling out this page) 490473 PET polymerization catalyst Adding amount (moU) Time (rain) IV (dl / g) Catalyst composition after melting test Example 1-118 Acetic acid 2,2'-dihydroxydiphenyl ether 112 1.47 Example 1-117 109 1.46 Example 1- 115 Example 116 116 Potassium Chloride Ethanol Flavonol Acetate Epicatechinate 77 77 1.47 1.47 Example 1-112 Sodium Deoxychlorin Example 1-113 Lithium Acetate 4,5-Dihydroxynaphthalene -2,7-Disulfonic acid disodium 78 Example 1-114 Potassium acetate esculetine, 48 Example 1-111 Aluminum acetate Carboxic acid [8] Aromatic example 1-110 115 0.46 Example 1-109 Sodium acetate 5,8_Dihydroxy-1,4-naphthalene Example 1-108 铷 acetate 0.05 1,8-diamino-4,5-dihydroxy group _ 0.2 1.49 A7 B7 i. Description of the invention (10 4 [Table 1-6 (2)] Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

490473 A7 B7, 10 5 V. Description of the invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [表 卜 7⑴] PET polymerization 1 Polymerization test TD Catalyst composition Catalyst time IV 验 Addition amount (min) (dl / g) (mol%) Example 1-119 osmium acetate 0.03 85 0.48 20 1,8_diamino-4,5-dihydroxylidine 0.1 Example 1-120 cobalt acetate 0.01 80 0.46 23 cyprotin 0.05 Example 1-121 Zinc acetate 0.008 85 0.47 22 1,4-Diamino group 基 0.01 Example 1-122 Manganese acetate 0.02 50 0.50 17 Carboxic acid [8] aromatic hydrocarbon 0.08 Example 1-123 Iron acetoacetate ( Π1) 0.02 77 0.47 22 5,8-dihydroxynaphthalene fluorene 0.05 Example 1-124 Nickel acetate deoxyalizarin 0.1 0.1 85 0.47 22 Example 1-125 Acetyl ruthenium acetate 0.05 86 0.47 22 Seven leaves Pavilion 0.2 Implementation Example 1-126 Rhenium Acetyl Acetate 0.05 87 0.47 22 Alizarin 0.1 Example 1-127 Bismuth Acetate 0.2 74 0.46 23 4,5-Dihydroxynaphthalene-2,7-disulfonic acid disodium 0.1 Example 1- 128 acetic acid 0.5 62 0.46 23 emodin 0.5 -10 7- ----------- load -------- order -------- -(Please read the notes on the back before filling out this page) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 v 10 6 V. Description of Invention () Intellectual Property Bureau, Ministry of Economic Affairs Printed by employee consumer cooperatives [Table 1-7⑵] Catalyst composition PET polymerization catalyst addition amount (mol%) Polymerization time (min) IV (dl / g) TD (%) after melt test Example 1-129 Silver acetate 0.1 79 0.46 23 Deoxyalizarin 0.3 Example 1-130 Tetrabutyric oxide 0.05 50 0.49 18 p-3-Butylcarboxic acid [8] arene 0.1 Example 1-131 Chlorination gives 0.07 61 0.46 23 Quinaziridin 0.15 Example 1-132 Rhenium acetate 0.05 115 0.47 22 2,2-Dihydroxyphenyl ether 0.4 Example 133 Lanthanum acetate 0.05 94 0.47 22 Quinaziridin 0.05 Example 1-134 Tetraethoxide 0.1 65 0.46 23 Morin 0.2 (Please read the precautions on the back before filling out this page) The paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) Bamboo U473 A7 B7 V. Description of the invention () 10 7 [Table 1 -8 ] Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Agent composition PET polymerization catalyst addition amount (mol%) Polymerization time (min) IV (dl / g) TD (%) after melt test Comparative Example 1-7 Tetrabutoxyphthalate 0.003 54 0.42 30 Comparative Example 1-8 Lithium Acetate 0.005 0.01 166 0.52 13 Comparative Example 1- 9 Magnesium Acetate 2,2 · -bisphenol 0.5 0.5 59 0.38 37 Comparative Example 1-10 Lithium Acetate 0.05 &gt; 180 — — j Comparative Example 1-11 Element 0,1 &gt; 180 — — Comparative Example 1-12 Sodium Acetate 0.1 144 — — Comparative Example 1-13 Quinoalysin 0.2 162 — — Comparative Example 1-14 Potassium Acetate 0.05 168 — — Comparative Example 1-15 Rhenium Acetate 0.05 175 — — Comparative Example 1-16 Acetic acid planing 0.1 180 — — Comparative Examples 1-17 Acetic acid wave 0.08 152 — — Comparative Example 1-18 Tetrabutoxysilane 0.1 163 — — Comparative Example 1-19 Calcium acetate 0.05 147 — — Comparative Example 1-20 Rhenium Acetate 0.2 191 — — Comparative Example 1-21 Ruthenium Acetyl Acetate 0.05 159 — — Comparative Example 1-22 Rhenium Acetyl Acetate 0.05 170 — — Comparative Example 1-23 Palladium Acetate 0.5 158 — — Comparative Example 1-24 Lithium Acetate 0.3 &gt; 180 One Comparative Example 1-25 Alizarin 0.2 &gt; 180 One — Comparative Example 1-26 Trioxane Antimony 0.05 66 0.46 23 ------------ 1 ^ 11 ^ · !!! Order ·!! Line ϋρ. (Please read Note 3 on the back before filling out this page) 10 9 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, 108 V. Description of Invention () [Table 2-1]

-110- (Please read the precautions on the back before filling in this page) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 _B7 v 10 9 V. Description of Invention () Wisdom of the Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Property Bureau [Table 2-2]

-111- -------------------- Order --------- line (Please read the precautions on the back before filling this page) This paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 490473 A7 B7 v 1 1 05. Description of invention () [Table 2-3] Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

-112- -------------------- Order --------- line (Please read the precautions on the back before filling this page) This paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 490473 A7 _B7 v 111 V. Description of invention () [Table 3-1] Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

-1 1 3-(Please read the precautions on the back before filling this page) -¾ ----- Order --------- The size of a single paper is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 • A7 _B7 v 112 V. Description of the invention () Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 3-2]

-114- (Please read the precautions on the back before filling in this page)-囔 ----- Order --------- Line 1 Paper Size Applies to Chinese National Standard (CNS) A4 Specification (210 X 297 mm) 490473 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs v 113 V. Description of Invention () [Table 4-1]

-115- -------------------- Order --------- Line (Please read the precautions on the back before filling this page) This paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 490473 A7 _B7 114 V. Description of the invention () Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs [Table 4-2]

-116- (Please read the precautions on the back before filling this page) -------- Order --------- Line j This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 490473 A7 B7, 115 V. Description of the invention () Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 4-3] Metal compound additive iv (dl / g) Example 4 _ 3 9 (S) 0.54 Examples 4-4 0 (Q) 0.55 Examples 4-4 1 (M) 0.57 Examples 4 _ 4 2 (N) 0.60 Examples 4-4 3 (〇) 0.56 Examples 4-4 4 (P) 0.61 Examples 4-4 5 ⑴ 0.55 Examples 4-4 6 (K) 0.61 Examples 4-4 7 (X) 0.58 Examples 4-4 8 Chromium (I) chloride 0.57 Examples 4-4 9 (T ) 0.54 Example 4-5 0 (H) 0.61 Example 4-5 1 (F) 0.56 Example 4-5 2 (A) 0.60 Example 4-5 3 (B) 0.59 Example 4 _ 5 4 (C ) 0.55 Example 4-5 5 (D) 0.56 Example 4-5 6 (E) 0.59 Example 4-5 7 (U) 0.60 Comparative Example 4-4 — ~ 0.26 -117- (Please read the note on the back first ? Please fill out this page again) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 PCT) 490473 A7 B7 v 116 Fifth, the invention is described in () Ministry of Economic Affairs Intellectual Property Office employees consumer cooperatives printed [Table 5-1]

-118- -------------------- Order --------- Line (Please read the precautions on the back before filling this page) This paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 490473 A7 _B7 v 117 V. Description of the invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 5-2]

-1 1 9--------------------- Order --------- line || p · (Please read the notes on the back before filling (This page) This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1 18 V. Description of the invention () [Table 6-1]

-12 0- ---------------- (Please read the notes on the back before filling this page) Order --------- line; This paper size is applicable to China National Standard (CNS) A4 Specification (210 X 297 mm) 490473 A7 _B7 v 119 V. Description of Invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 6-2]

-12 1- --------- Order --------- Line U (Please read the precautions on the back before filling this page) Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 v 12 0 V. Description of invention () im 7-i] Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

-12 2- -------------------- Order --------- line ^ (Please read the precautions on the back before filling this page) Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7, 12 1 V. Description of Invention () Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 7-2]

-123- -------------------- Order --------- line up (Please read the precautions on the back before filling this page) This paper Standards are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) 490473 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, 12 2 V. Description of invention () [Table 7_3]

1 1 4-(Please read the notes on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 12 3 V. Description of the invention () Ministry of Economy Printed by the Intellectual Property Bureau Staff Consumer Cooperatives [Table 7-4]

-125- --------------------- Order --------- Line Thai (Please read the precautions on the back before filling this page) Paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 490473 A7 B7 12 4 V. Description of invention () [Table 7-5] Printed Metal Compound Additive IV by Employee Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs ( dl / g) Examples 7-7 3 (A) 0.54 Examples 7-7 4 (B) 0.55 Examples 7-7 5 (C) 0.58 Examples 7-7 6 (D) 0.59 Examples 7 _ 7 7 (E) 0.54 Examples 7-7 8 (U) 0.57 Examples 7-7 9 (F) 0.56 Examples 7-8 0 (H) 0.60 Example 8 1 (I) 0.56 Examples 7-8 2 Acetic acid 1 (T) 0.52 Examples 7-8 3 (J) 0.55 Examples 7-8 4 (K) 0.54 Examples 7 _ 8 5 (L) 0.54 Examples 7-8 6 (M) 0.52 Examples 7-8 7 (N) 0.58 Examples 7-8 8 (〇) 0.57 Examples 7-8 9 (P) 0.55 Examples 7-9 0 (S) 0.57 Comparative Examples 7-6 ---- 0.27 -126- ---- ---------------- Order --------- Line (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 Regulation (210 X 297 mm) 490473 A7 B7 12 5 V. invention is described in () Ministry of Economic Affairs Intellectual Property Office employees consumer cooperatives printed clothing [Table 8-1]

-12 7- ---------------- (Please read the notes on the back before filling this page)

Order --------- Line I This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 12 6 V. Description of the invention () [Table 8-2]

-128- (Please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 Printed by the Employees ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 12 7 V. Description of the invention () [Table 8-3]

-12 9- (Please read the notes on the back before filling this page)

This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 _B7 v 128 V. Description of the invention () Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 9- 1]

-1 3 0-(Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 _B7 12 9 V. Description of Invention () Ministry of Economic Affairs Made by Intellectual Property Bureau employee consumption cooperation [Table 10-1] Catalyst composition PET polymerization catalyst added amount (mol%) IV (dl / g) Example 1 〇-1 Sodium acetate 0.05 0.51 Xantaridin 0.05 Example 1 0 -2 Potassium acetate 0.05 0.48 Alizarin 0.05 Example 1 0-3 Acetyl acetate 0.05 0.45 Deoxyalizarin 0.05 Example 1 0-4 Acetic acid 0.05 0.052 Carboxylic acid [8] Aromatic hydrocarbons 0.05 Example 1 0-5 Acetyl acetate 0.05 0.47 Moringain 0.05 Example 1 0 ~ 6 Silicon acetate 0.05 0.51 Moringain 0.05 Example 1 0-7 Copper acetate 0.05 0.60 Carboxic acid [8] Aromatic hydrocarbon 0.05 Example 1 0-8 Acetic acid Sodium 0.05 0.56 Carboxic acid [8] arene 0.05 (Please read the note on the back? Matters before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 v 13 0 V. Description of Invention () Printed by the Bureau ’s Consumer Cooperatives [Table 10-2] Catalyst composition PET polymerization catalyst added amount (mo 1%) IV (dl / g) Comparative Example 10-1 Acetic acid pin 0.05 0. 27 Comparative Example 10-2 Potassium acetate 0 .05 0. 27 Comparative Example 10- 3 Samarium Acetate 0.05 0. 29 Comparative Example 10_ 4 Acetic Acid Plane 0.05 0.29 Comparative Example 10-5 5 Acetyl Acrylic Acid 0.05 0. 27 Comparative Example 10-6 Silicon Acetate 0.05 0. 26 Comparative Example 10-7 Copper Acetate 0. 05 0. 26 Comparative Example 10-8 8-Alizarin (A) 0.05 0.25 Comparative Example 1Q ~ 9 Deoxyalizarin (H) 0.05 0. 26 Comparative Example 1 〇 -1 〇 Morphanthin U) 0.05 0.25 Comparative Example 1 〇- 11 Carboxylic acid [8] arene 0.05 0.27 Comparative Example 10-12 —— 0.25 Comparative Example 10-13 Antimony trioxide (reference example) 0.05 0.57 -13 2- -------------------- Order --------- Line m- (Please read the precautions on the back before filling this page) This paper Standards apply to China National Standard (CNS) A4 specifications (210 X 297 mm) 490473 A7 _B7, 13 1 V. Description of the invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 11] Catalyst polyterephthalic acid extension Butyl ester polymerization time (min) Original viscosity (dl / g) 11- 1 Example 1- 92 40 0.92 11- 2 Example 100 50 1.01 11- 3 Example 1- 94 45 0.95 11- 4 Example 1-119 50 0.94 11- 5 Implementation Example 1-101 50 0.91 11- 6 Example 1-106 55 1.02 11- 7 Example 1-107 45 0.93 11- 8 Example 1- 97 45 0.96 11- 9 Example 99 40 0.98 Example 11-10 Implementation Example 1-120 45 0.95 11-11 Example 121 50 0.91 11-12 Example 1-122 40 0.97 Example 11-13 Example 1-123 50 0.96 11-14 Example 1-124 55 1.02 11-15 Implementation Example 1-125 50 0.87 Example 11-16 Example 1-126 50 0.92 11-17 Example 1-127 55 0.95 11-18 Example 1-128 50 1.03 11-19 Example 1-129 45 0.97 11-20 Example 1_130 40 1.01 11-21 Example 131 50 0.96 11-22 Example 1-116 55 1.00 11-23 Example 1-108 55 0.94 11-24 Example 1-132 65 0.86 11-25 Example 1-133 50 0.92 11-26 Example 1-134 55 0.90 Than 11-1 Comparative Example 1- 8 90 0.75 Than 11-2 Comparative Example 1- 24 90 〇-43 Example 11- 3 Comparative Example 25 90 0.38 -133-- ------------------- Order --------- line (please read first Note on the back, please fill in this page again) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7, 13 2 V. Description of Invention () Printed by the Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs [Table 12] Polymerization time of catalyst polyethylene naphthalate (min) IV (dl / g) 12-1 Example 1-92 40 0.57 12-2 Example 1-100 45 0.58 12-3 Example 1-94 40 0.57 12-4 Example 1-119 45 0.56 12-5 Example 1-101 45 0.54 12-6 Example 1-106 45 0.56 12-7 Example 1-107 45 0.57 12-8 Example 1-97 45 0.55 12- 9 Example 1- 99 40 0.60 Actual 12-10 Example 1-120 45 0.56 12-11 Example 1-121 45 0.53 12-12 Example 1-122 40 0.60 Example 12-13 Example 1 -123 50 0.51 12-14 Example 124 45 0.58 12-15 Example 1-125 55 0.50 Example 12-16 Example 1-126 55 0.52 12 -17 Example 1-127 50 0.57 12-18 Example 1 -128 40 0.58 12-19 Example 1-129 45 0.58 12-20 Example 1-130 40 0.62 12-21 Example 1-131 45 0.55 12-22 Example 1-116 45 0.55 12-23 Example 1_10845 0.56 12-24 Example 1-132 60 0.50 12-25 Example 1-133 55 0.53 12-26 Example 134 45 0.59 than 12-1 Comparative Example 1-8 120 0.56 Compared to 12-2 Comparative Example 24 120 0.36 Example 12- 3 Comparative Example 1- 25 120 0.32 -13 4- -------------------- Order --------- Line 1 ^ · (Please read the Zhuyin on the back? Please fill in this page again for this matter) This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 490473 A7 B7 13 3 V. Description of the invention () Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 13] Catalyst poly (trimethylene terephthalate) polymerization time (min) IV (dl / g) 13-1 Example 1- 92 80 0.75 13-2 Example 1-100 75 0.68 13-3 Example 1- 94 80 0.70 13-4 Example 1-119 75 0.77 13-5 Example 1-101 75 0.72 13-6 Example 106 85 0.81 13- 7 Example 1-107 80 0.73 13- 8 Example 1- 97 80 0.75 13 -9 Example 1- 99 75 0.81 Example 13-10 Example 1-120 80 0.74 13-11 Example 1-121 80 0.73 13-12 Example 1-122 75 0.82 Example 13 -13 Example 1-123 80 0.80 13-14 Example 1-124 75 0.72 13 -15 Example 1-125 80 0.74 Example 13-16 Example 126 80 0.73 13-17 Example 1-127 80 0.81 13-18 Example 1-128 85 0.82 13-19 Example 1-129 75 0.78 13-20 Example 130 130 0.8 0.84 13-21 Example 1-131 75 0.76 13-22 Example 1-116 80 0.81 13-23 Example 1-108 80 0.75 13 -24 Example 132 85 0.67 13-25 Example 1-133 80 0.71 13-26 Example 1-134 85 0.73 Ratio 13-1 Comparative Example 1-8 150 0 58 Compared with 13-2 Comparative Example 1-24 180 0.31 Example 13-3 Comparative Example 25 180 0.25 -13 5- -------------------- Order --------- Line Up · (Please Please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 v 134 5. Description of the invention () [Table 14] Catalyst CHDM copolymerization polyester polymerization time (min) reduced viscosity (dl / g) 14-1 Example 1-92 70 0.84 14-2 Example 1-100 65 0.78 14-3 Example 1- 94 70 0.75 14- 4 Example 1-119 70 0.82 14-5 Example 1-101 70 0.76 14-6 Example 1-106 75 0.85 14-7 Example 1-107 75 0.82 14-8 Example 1- 97 70 0.73 14-9 Example 1-99 60 0.81 Example 14-10 Example 1-120 65 0.78 14 -11 Example 1-121 65 0.75 14-12 Example 122 60 0.83 Example 14-13 Example 123 65 0.81 14-14 Example 1-124 60 0.77 1 4-15 Example 1-125 65 0.72 Example 14-16 Example 1-126 65 0.74 14-17 Example 1-127 60 0.78 14-18 Example 1-128 65 0.84 14-19 Example 1-129 60 0.77 14-20 Example 1-130 60 0.85 14-21 Example 1-131 65 0.81 14-22 Example 1-116 65 0.73 14-23 Example 1-108 65 0.77 14-24 Example 1-132 75 0.68 14-25 Example 1-133 70 0.76 14-26 Example 1-134 75 0.75 to 14-1 Comparative Example 1 to 8 140 0.66 to 14-2 Comparative Example 1 to 24 150 0.32 Example 14-3 Comparative Example 1 -25 150 0.29 -136- -------------------- Order --------- line (Please read the precautions on the back before filling this page ) This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7 v 135 V. Description of the invention () [Table 15] Printed on the catalyst PET film used by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Foreign matter (pieces / g) 1 5-1 Example 1-9 2 2 1 1 5-2 Example 1-1 0 0 2 5 15- 3 Example 1-9 4 12 1 5-4 Example 1-1 1 9 3 15- 5 Examples 1-1 〇1 24 1 5-6 Examples 1-1 0 6 3 5 1 5-7 Example 1-1 0 7 2 3 1 5- 8 Example 1-9 7 10 1 5-9 Example 1-9 9 15 Example 15-10 Example 1-1 2 0 5 15-11 Example 1- 1 2 1 4 15-12 Example 1-1 2 2 8 Application 15-13 Example 1-1 2 3 10 15-14 Example 1-1 2 4 7 15-15 Example 1-1 2 5 5 Example 15-16 Example 1-1 2 6 4 15-17 Example 1-1 2 7 2 5 15-18 Example 1-1 2 8 2 4 15-19 Example 1-1 2 9 15 15-20 Implementation Example 1-1 3 0 19 15-21 Example 1-1 3 1 12 15-22 Example 1 1 6 14 15-23 Example 1-1 0 8 10 15-24 Example 1-1 3 2 6 15-25 Example 1 1 3 3 3 15-26 Example 1-1 3 4 12 Ratio 1 5-1 Comparative Example 1 _ 8 5 Less than 15-2 Comparative Example 1-2 4-Example 1 5- 3 Comparative Example 1-2 5 Fortune 1 5-4 Comparative Example 1-2 6 6 5-1 3 7-(Please read the notes on the back before filling this page) -------- Order ------ --- line; This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 __B7 v 13 6 V. Description of Invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 1 6 ] Use reminder Chemical agent PET forming board blur value (%) 1 6-1 Example 1-9 2 4. 7 16- 2 Example 1-1 0 0 3. 5 16- 3 Example 1-9 4 4. 3 16- 4 Examples 1-1 1 9 3. 2 16- 5 Examples 1-1 0 1 3. 3 1 6-6 Examples 1 _ 1 0 6 4. 5 1 6-7 Examples 1-1 〇 7 5 3 16- 8 Examples 1-9 7 3. 7 16- 9 Examples 1-9 9 3. 1 Examples 16-10 Examples 1-1 2 0 3. 3 16-11 Examples 1-1 2 1 2. 8 16-12 Example 1-1 2 2 2. 7 Application 16-13 Example 1-1 2 3 3. 6 16-14 Example 1-1 2 4 4. 1 16-15 Example 1- 1 2 5 3. 8 Example 16-16 Example 1-1 2 6 4. 5 16-17 Example 1-1 2 7 4. 6 16-18 Example 1-1 2 8 6. 9 16-19 Implementation Example 1-1 2 9 4. 4 16-20 Example 1 1 3 0 3. 2 16-21 Example 1 1 1 1 4. 0 16-22 Example 1 1 6 3. 7 16-23 Example 1-1 0 8 4. 5 16-24 Example 1-1 3 2 5. 7 16-25 Example 1-1 3 3 3. 8 16-26 Example 1-1 3 4 4.4 Ratio 1 6-1 Comparative Example 1-8 2. 7 Compared with 16-2 Comparative Example 1-2 4 Example 1 6-3 Comparative Example 1-2 5-1 6- 4 Comparative Example 1-2 6 2 4.5 -138- ------------- Sacrifice · II (Please read the notes on the back before filling this page) Order ------ --- line; This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7, 13 7 V. Description of the invention () Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 17] Foreign matter in the PET fiber using the catalyst (a / g) 1 7-1 Example 1-9 2 0 17- 2 Example 1-1 0 0 0 1 7 ~ 3 Example 1-9 4 1 1 7-4 Implementation Example 1-1 1 9 1 17- 5 Spring Example 1 〇1 0 1 7-6 Example 1 10 6 1 1 7-7 Example 1-1 0 7 1 1 7-8 贲 Example 1- 9 7 1 1 7-9 Examples 1-9 9 0 Examples 17-10 Examples 1-1 2 0 0 17-11 Examples 1-1 2 1 0 17-12 Examples 1-122 0 Examples 17-13 Example 1-1 2 3 1 17-14 Example 1-1 2 4 0 17-15 Spring Example 1-1 2 5 0 Example 17-16 Example 1-1 2 6 0 17-17 Example 1- 1 2 7 1 17-18 Examples 1-1 2 8 0 17-19 Examples 1-1 2 9 0 17-20 Examples 1 3 0 1 17-21 Examples 1-1 3 1 0 17-22 Examples 1-1 1 6 0 17-23 Examples 1-1 0 8 0 17-24 Examples 1-1 3 2 2 17-25 Examples 1-1 3 3 0 17-26 Examples 1-1 3 4 0 to 1 7 -1 Comparative Example 1-8 0 Compared with 1 7-2 Comparative Example 1-2 4 Tower Example 17- 3 Comparative Example 1-2 5-17- 4 Comparative Example 1-2 6 15 1 139------- --------------- Order ---------- (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) 490473 A7 B7 v 13 8 V. Description of the invention () Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs [Table 18] Polymerization time of PET for catalyst fibers (min) IV (dl / g) 18 -1 Example 92 74 0.63 18- 2 Example 100 80 0.61 18-3 Example 1- 94 78 0.61 18-4 Example 1-119 104 0.62 18-5 Example 1-101 87 0.62 18-6 Example 1-106 80 0.63 18- 7 Example 1-107 81 0.61 18-8 Example 1- 97 94 0.61 18-9 Example 1- 99 71 0.62 Example 18-10 Example 1-120 99 0.62 18- 11 Example 1-121 105 0.61 18-12 Example 1-122 70 0.61 Example 18 -13 Example 1_123 95 0.61 18 -14 Example 1-124 102 0.63 18-15 Example 1-125 104 0.62 Example 18-16 Example 1-126 108 0.62 18 -17 Example 1-127 93 0.61 18-18 Example 1-128 84 0.61 18- 19 Example 1-129 102 0.61 18-20 Example 1-130 69 0.62 18-21 Example 1-131 79 0.62 18-22 Example 1-116 96 0.61 18-23 Example 1-108 90 0.61 18- 24 Example 132 132 141 0.61 18-25 Example 1-133 120 0.61 18-26 Example 1-134 87 0.62 Ratio 18-1 Comparative Example 1-8 205 0.60 Ratio 18-2 Comparative Example 1-24--Example 18-3 Comparative Example 1- 25-18- 4 Comparative Example 1- 26 88 0.63 -14 0- -------------------- Order ------ --- Line (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 A7 B7, 13 9, V. Invention Description () Economy Printed by the Consumer Cooperatives of the Ministry of Intellectual Property Bureau [Table 19] Polymerization time of catalyst modified PET (min) IV (dl / g) 19-1 Example 1-92 80 0.55 19-2 Example 1-100 90 0.56 19- 3 Example 1- 94 90 0.57 19- 4 Example 1-119 120 0.55 19-5 Example 1-101 100 0.58 19-6 Example 1-106 90 0.58 19-7 Example 1-107 90 0.56 19-8 Example 1-97 105 0.56 19-9 Example 99 99 0.58 Actual 19-10 Example 1-120 115 0.56 19-11 Example 121 120 0.59 19-12 Example 1-122 80 0.57 Example 19-13 Example 123 110 0.60 19-14 Example 1-124 115 0.58 19-15 Implementation Example 1-125 115 0.57 Example 19-16 Example 1-126 125 * 0.57 19 -17 Example 1-127 105 0.59 19-18 Example 1-128 95 0.57 19-19 Example 1-129 115 0.58 19- 20 Example 1-130 80 0.58 19-21 Example 1-131 90 0.57 19-22 Example 1-116 105 0.56 19-23 Example 1-108 100 0.56 19-24 Example 1-132 160 0.55 19- 25 Example 1-133 135 0.57 19-26 Example 1-134 100 0.56 Compared to 19-1 Comparative Example 1- 8 200 0.55 Compared to 19- 2 Comparative Example 1- 24 \ One- Example 19- 3 Comparative Example 1- 25 --19- 4 Comparative Example 1- 26 95 0.57 -14 1- -------------------- Order --------- Line «(Please (Please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 490473 -1 0 5 -A7 B7, 14 0 V. Description of the invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 20] Polymerization time of catalyst flame retardant PET (min) IV (dl / g) 20-1 Example 1- 92 80 0.62 20- 2 Example 1-100 95 0.63 20- 3 Example 1- 94 85 0.62 20- 4 Example 1-119 110 0.65 20-5 Example 1-101 95 0.64 20-6 Example 1-106 85 0.61 20-7 Example 1-107 85 0.61 20-8 Example 1- 97 105 0.64 20-9 Example 1-99 80 0.64 Example 20 115 Example 120 115 0.63 20-11 Example 1-121 120 0.63 20-12 Example 1-122 80 0.65 Application 20-13 Example 1-123 115 0.63 20-14 Example 1-124 125 0.65 20-15 Example 1-125 120 0.64 Example 20-16 Example 1-126 125 0.63 20 -17 Example 1-127 110 0.64 20-18 Example 1-128 90 0.63 20 -19 Example 1-129 115 0.65 20-20 Example 1-130 80 0.65 20-21 Examples 1-131 90 0.64 20-22 Examples 1-116 100 0.63 20-23 Examples 1-108 105 0.63 20-24 Examples 1-132 150 0.61 20-25 Examples 1-133 130 0.62 20-2 6 Example 1-134 100 0.62 Ratio 20- 1 Comparative Example 1- 8 195 0.62 20-2 Comparative Example 24--Example 20_ 3 Comparative Example 1-25-20-4 Comparative Example 1-26 95 0.63 -14 2 --------------------- Order --------- Line (Please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm)

Claims (1)

490473 Announcement VI. Patent Application No. 88 1 1 8370 "Polyester Polymerization Catalyst, Manufacturing Method of Polyester and Polyester" Patent Case (Amended on March 1, 91) A. Patent Application Scope: 1. A polyester The polymerization catalyst is characterized in that it does not contain antimony and germanium, and the activity parameter (AP) of the catalyst can satisfy the following formula [1]. The thermal stability index of polyethylene terephthalate polymerized using the catalyst ( TD) can satisfy the following formula [2]: [1] AP (min) &lt; 2T (min) (AP means to use a predetermined catalyst and make the intrinsic viscosity at 27 5 ° C and a low pressure of 0.1 Tor r 0.5 dl / g time required for polymerization of polyethylene terephthalate (mi η); T represents AP when antimony trioxide is used as a catalyst; wherein, for the generated polyterephthalic acid In terms of the acid component of ethyl acetate, the amount of antimony trioxide added is 0.05 mol% of antimony atoms. [2] TD (%) &lt; 25 (TD means that the intrinsic viscosity of lg is 0.6 dl / g. PET was placed in a glass test tube and vacuum-dried at 13CTC for 12 hours. Then, it was maintained in a molten state at 300 ° C for 2 hours in a nitrogen atmosphere. There is a viscosity reduction rate (%)); wherein the polyester polymerization catalyst is composed of at least one metal-containing component and an organic compound component selected from metals and / or metal compounds containing no antimony or germanium, and the organic compound component is One or more members selected from compounds containing general formula (Formula 1 and / or general formula (Formula 2): (Formula 1) 490473 6. Application scope of patent A r-0-(Formula 2) Ar -N &lt; A r represents an aryl group, and the metal-containing component is a kind of L々B 巳, on: ¾ white on Li, Na, 'K, Rb Cs ;, Be Mg Ca Sr, Ba, A1 Ga, T1, Pb , Bi, Cr, Νι, Mo, Tc Re, Sc, Y, zr, Hf, V, Ru, Rh, Pd Λ 〇s, Ir, Pt, Cu, Ag Λ Au, Cd, Hg, La, Ce , Sm Λ Eu Gd In, Mn, Co Zn, Fe, Nb, Ta, W, Si, Te, B, and compounds thereof 2. A polyester polymerization catalyst, characterized in that at least one kind is selected from the group consisting of The metal and / or metal compounds of antimony or germanium-containing metal and / or metal compounds are composed of organic compounds and the organic compound is 1 Or more selected from compounds containing general formula (Formula 1) and / or general formula (Formula 2): Ar-0-(Formula 2) Ar -N &lt; wherein Ar is an aryl group, and the metal-containing component is 1 or more. Focus on Li, Na, K, Rb, Cs; N Be, Mg, Ca-Sr, B a, A1, Ga, T1, Pb, Bi Λ Cr, Ni Λ Mo, Tc Re, Sc , Y ', Zi, Hf, V, Ru &gt; Rh Pd Os' Ir Pt, Cu, Ag, Au, Cd, Hg, La Ce, Sm, Eu, Gd, In, Mn, Co, Zn , Fe, Nb, Ta W, Si, T e, B and their compounds O 490473 VI. Patent application scope 3. For polyester polymerization catalysts such as patent application scope item 1 or 2, where the metal component is one The above are selected from T1, pb, Bi and compounds thereof. 4. A polymer polymerization catalyst of item 1 or 2 according to the scope of the patent application, wherein the metal-containing component is one or more selected from Cr, Ni, and a compound thereof. 5. The polyester polymerization catalyst according to item 1 or 2 of the scope of patent application, wherein the metal-containing component is one or more kinds selected from Sc, Y, Zr, Hf &amp; compounds thereof. 6. The polyester polymerization catalyst according to item 1 or 2 of the patent application scope, wherein the metal-containing component is one or more selected from Ru, Pd and compounds thereof. 7. The polyester polymerization catalyst according to item 1 or 2 of the patent application scope, wherein the metal-containing component is one or more selected from Cu, Ag, and compounds thereof. 8. The polyester polymerization catalyst according to item 1 or 2 of the scope of patent application, wherein the metal-containing component is one or more selected from the group consisting of lanthanoid metals and their compounds. 9. The polyester polymerization catalyst according to item 1 or 2 of the patent application scope, wherein the metal-containing component is one or more kinds selected from I η and compounds thereof. 10. The polyester polymerization catalyst according to item 1 or 2 of the patent application scope, wherein the metal-containing component is one or more selected from Fe and its compounds. 1 1. The polyester polymerization catalyst according to item 1 or 2 of the scope of patent application, wherein the compounds containing the structure of the general formula (Formula 1) and / or (Formula 2) each contain the following general formula (Formula 3) and / Or a compound of the structure shown in (Formula 4): 490473 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 A compound showing the structure of the scope of patent application (Formula 3) Ar-0-X (Formula 4) X2 A r — NX: (where A r represents an aryl group; each of X 1, X 2, and X 3 为 is hydrogen, a hydrocarbon group, a fluorenyl group, a sulfofluorenyl group-containing group, a phosphorus fluorenyl group-containing group, or an ether bond (Hydrocarbyl). 12. The polyester polymerization catalyst according to item 11 of the scope of patent application, wherein Ar of the general formulae (Formula 3) and (Formula 4) is pseudo-selected from the general formulae (Formula 5) to (Formula 1 2). By ... (Eq. 5) σ (Eq. 6) (Eq. 7) -4 This paper size applies to China National Standard (CNS) Α4 specification (210 × 297 mm) (Please read the precautions on the back before filling this page) 490473 A8 B8 D8 Patent Application Range (Formula 8) (Eq. 9) 〇 (Please read the notes on the back before filling this page) (Formula 1 0) 〇 (Formula 1 1) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 1 2) 〇 This paper size applies to China National Standard (CNS) A4 specification (210X 297 mm) 490473 A8 B8 C8 D8 VI. Application for patent scope 1 3. As for the polyester polymerization catalyst of item 11 of patent scope, which contains the general The compound having a structure represented by formula (Formula 3) and / or (Formula 4) is selected from the group consisting of linear phenol compounds, linear aniline compounds, and derivatives thereof shown by the following general formulae (Formula 13) and (Formula 14). Groups of compounds ... (Formula 1 3) (X〇WYx ^ / X) c (R1) b, (R1 R2 (Please read the precautions on the back before filling out this page) (Formula 1 4) (X2N ) a \ (R1) d (R ^ b (nx2)》 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of 1T (in (Formula 1 3), (Formula 1 4), each R 1 傜 is the same or different C 丄 ~ C 20 hydrocarbon group, hydroxyl group or halogen group. C i ~ C 20 hydrocarbon group, halogen group, carboxyl group or ester thereof, methylamino group, fluorenyl group, (fluorenyl) -0- group, amine group, mono- or dialkylamino group, fluorenylamino group or Substituents, hydroxy, alkoxy, alkylthio, sulfofluorenyl-containing groups, phosphorofluorenyl-containing groups, nitro, cyano, and thiofluorenyl groups; R 2 傺 is each the same or different hydrogen, C 1 ~ C 20 hydrocarbyl, C 1 ~ C 20 hydrocarbyl, halo, carboxy or its ester, formamyl, fluorenyl, (fluorenyl) -0-a radical, amine, mono or Dialkylamine, amidoamine or its substitution This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297mm) 490473 A8 B8 C8 D8 6. Application scope of patent, hydroxyl, alkoxy, alkanesulfide Group, sulfofluorenyl group-containing group, phosphorofluorenyl group-containing group, nitro, cyano, and thiofluorenyl group; each X 傺 is the same or different hydrogen, C i ~ C 20 hydrocarbon group, C with hydroxyl group or halogen groupi ~ C 20 hydrocarbyl group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether group-containing hydrocarbon group; Y 傺 each is the same or different direct bond, C i ~ C10 Shenyuan group, -(Dilute base) _〇-,-(¾ base) -S-, -0-, -S_, ~ S 0 2 ~ λ -CO-, -COO-; η is an integer from 1 to 100; a and c is an integer of 1 to 3; b and d 傺 are integers of 0 or 1 to 3; but l &lt; a + b contains 5, 1 gc + dg 4; d may be the same or different). 14. The polyester polymerization catalyst according to item 11 of the scope of patent application, which contains a compound having a structure represented by the general formula (Formula 3) and / or (Formula 4), which is pseudo-selected from the following general formula (Formula 15) And compounds composed of linear phenol compounds, branched linear aniline compounds, and derivatives thereof represented by (Formula 16): (Formula 15) (Please read the precautions on the back before filling this page), 1T Ministry of Economic Affairs Printed by the Intellectual Property Bureau Staff Consumer Cooperative This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) 490473 A8 B8 C8 D8 VI. Application for patent scope (Formula 16) (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (in (Equation 1 5), (Equation 16)), each R 1 傜 is the same or different C 的 ~ C 20 hydrocarbyl group, Ci ~ C 20 hydrocarbyl group having a hydroxyl group or a halogen group, a halogen group, a carboxyl group or an ester thereof, a methyl group, a fluorenyl group, a (fluorenyl) -0 group, an amine group, a mono or Dialkylamino, amidino or its substitutes, hydroxyl, alkoxy, alkylthio, sulfofluorenyl-containing group, phosphoramido-containing group, nitro, cyano, thiocyano; R 2傜 Each is the same or different chlorine, c 1 ~ C 20 nicotinyl, C 1 ~ C 2C with warp or halogen group, halo group, halo group, carboxyl group or ester thereof, formamyl group, fluorenyl group, (醯Group)-0-a base, an amine group, a mono- or dialkylamino group, a fluorenylamino group or a substitute thereof, a hydroxyl group, an alkoxy group, an alkylthio group, a sulfonyl group-containing group, a phosphorus-containing fluorenyl group Radicals, nitro, fluorenyl, thiocyano; X is each the same or different hydrogen, c'1 ~ C 20 hydrocarbyl, C i ~ C 20 hydrocarbyl with hydroxy or halogen radical, fluorenyl, sulfonium A base, a base containing a phosphonium group, or Hydrocarbon groups of the chain; Y pseudo each is the same or different direct bond, C 1 ~ C10 Shen Yuanji,-(skeleton) _〇 **, _ (alkenyl) -S- *, -S-, this paper The scale is applicable to China National Standard (CNS) A4 specification (210X297 mm) 490473 ABCD patent application scope -S 0 2-,-C 0-,-C 0 0-; η is an integer from 1 to 1 0 G; c is The same or different integers of 1 to 3, · d is the same or different integers of 0 to 3, but 1 contains c + dg 4). 15. The polyester polymerization catalyst according to item 11 of the scope of patent application, wherein the compound containing a structure represented by the general formula (Formula 3) and / or (Formula 4) is selected from the following general formula (Formula 17) And compounds formed by the cyclic phenol compound, the cyclic aniline compound, and derivatives thereof represented by the formula (Formula 18): (Formula 1 7) Read the winter notes on the back before filling in this page Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 1 8) (In (Formula 1 7) and (Formula 1 8), each R 1 is the same or different; i ~ C 20 hydrocarbon group, C 1 ~ C 20 hydrocarbon group with hydroxyl or halogen group, basic paper size applies to China Standard (CNS) A4 specification (210X297 mm) 490473 ABCD VI. Patent application scope Halo group, carboxyl or its ester, methylamino, fluorenyl, (fluorenyl)-0-base, amine, mono or Dialkylamino, fluorenylamino or its substitute, hydroxyl, alkoxy, alkylthio, sulfofluorenyl-containing group, phosphofluorenyl-containing group, nitro, cyano, thiofluorenyl; X pseudo Each is the same or different hydrogen, ci ~ C 20 hydrocarbyl group, Ci ~ C 20 hydrocarbyl group having hydroxyl or halogen group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether bond-containing hydrocarbon group ; Y pseudo is the same or different direct bonding, C: L ~ C10 alkylene,-(alkenyl) -0-,-(alkenyl) -S-,-0 '-S-,-S 0 2-,-C 0-,-C 0 0-; η 傺 is an integer from 1 to 1 (] 0; C 傺 is an integer from 1 to 3; d 傺 is an integer from 0 or 1 to 3; l £ c + dS4; d can be the same or different) 1 6. As in the 11th scope of the patent application An ester polymerization catalyst containing a compound represented by the general formulae (Formula 3) and / or (Formula 4): a coumarin derivative selected from the following general formulae (Formula 19) and (Formula 20), Or the compounds of the group of chromone derivatives represented by the general formulae (Formula 2 1) and (Formula 2 2): (Please read the precautions on the back before filling out this page) Employee Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Printing -10- This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 VI. Application scope of patent (Formula 1 9) (Eq. 2 0) (Please read the notes on the back before filling this page) (Equation 2 1) 〇 (Formula 2 2) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 〇 This paper size applies to Chinese National Standard (CNS) A4 (210 × 297 mm) 490473 ABCD Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 6. The scope of patent application (in (Equation 1 9) ~ (Equation 2 2) R is a hydrocarbon group of the same or different C 丄 ~ C 20, Ci ~ C2 with a hydroxyl group or a halogen group, a hydrocarbon group, a halogen group, a carboxyl group or an ester thereof, a methyl group, a fluorenyl group, and a (fluorenyl) group. Amine groups, amine groups, mono- or dialkylamino groups, fluorenylamino groups or their substitutes, hydroxyl, alkoxy, alkylthio, sulfofluorenyl-containing groups, phosphofluorenyl-containing groups, nitro, Cyano and thiofluorenyl; X 傺 is each the same or different hydrogen, C 1 ~ C 20 hydrocarbyl, C 1 ~ C 20 hydrocarbyl with hydroxyl or halogen group, fluorenyl, sulfofluorenyl-containing group, phosphorous fluorene Base or hydrocarbon group with ether bond; j and b are pseudo integers of 0 or 1 ~ 3; m and d 傺 are integers of 0 or 1 ~ 2; only 0gj + bg4, 0 &lt; m + d S 2 xj + ηι = 5) 〇1 7. The polyester polymerization catalyst according to item 11 of the patent application scope, which contains a compound having a structure represented by the general formula (Formula 3) and / or (Formula 4): Dihydrocoumarin derivatives represented by general formulae (Formulas 23) and (Formula 24), chromone derivatives represented by the following general formulae (Formulas 2 5) and (Formula 2 6), or the following general formulae Compounds grouped by heterochromone derivatives represented by (Formula 2 7) and (Formula 2 8). (Formula 2 3) (XO) 12 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 490473 A8 B8 C8 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Please read the notes on the back before filling this page) 490473 A8 B8 C8 D8 Patent application scope (in (Formula 23) to (Formula 28), each R 傺 is the same or different C i ~ C 20 hydrocarbon group, C 1 ~ C 20 hydrocarbon group with hydroxyl group or halogen group, Halo group, carboxyl group or ester thereof, methylamidino group, fluorenyl group, (fluorenyl) -0 group, amino group, mono or dialkylamino group, fluorenylamino group or its substitute, hydroxyl group, alkoxy group Group, alkylthio group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, nitro group, fluorenyl group, and thiocyano group; each X 傺 is the same or different hydrogen, Ci ~ C20 hydrocarbon group, hydroxyl group or Ci ~ C20 hydrocarbon group of halogen group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus-containing fluorenyl group, or ether group-containing hydrocarbon group; a is an integer of 1 to 3; b 傺 is 0 or 1 ~ Integers of 3; P and q are 0 or integers of 1 ~ 2; but lSa + bS4, p + q S 2) 〇 1 8. As the polyester polymerization catalyst of the scope of application for the 11th item, which contains the general formula The compound 构造 having a structure represented by (Formula 3) and / or (Formula 4) is selected from a coumarin derivative represented by the following general formulae (Formula 29) and (Formula 30), or the following general formula (Formula 31) ) And a group of isochromone derivatives represented by (Formula 32) Compound: (Formula 29) (Caution Please read the back of this page to fill out) Ministry of Economic Affairs Intellectual Property Office employees consumer cooperatives printed (type 3 0) (XO) a (X2N); (NX2) c-(R) d 14- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 490473 ABCD patent application scope (Formula 3 1) (Formula 3 2) (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Equations 2 9) to (Equation 3 2), each R is pseudo C or C Hydrocarbyl group of 20, Ci ~ C with a hydroxyl group or a halogen group 20 Hydrocarbon group, a halogen group, a carboxyl group or an ester thereof, a methyl group, a fluorenyl group, a (fluorenyl) -0 group, an amino group, a mono or di Alkylamino, amido or its substitute, hydroxyl, alkoxy, alkylthio, sulfofluorenyl-containing group, phosphorofluorenyl-containing group, nitro, cyano, thiocyano; X 傺 each It is the same or different hydrogen, Ci ~ C20 hydrocarbon group, Ci ~ C20 hydroxy group with hydroxyl group or halogen group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether bond-containing hydrocarbon group; a 傺 is an integer of 1 to 3; b is an integer of 0 or 1 to 3; c and d are integers of 0 or 1 to 3; but l ^ a + bg4, 0Sc + d ^ 3) 〇19. If applied The polyester polymerization catalyst according to item 11 of the patent, wherein the compound containing a structure represented by the general formulae (Formula 3) and / or (Formula 4) is selected from the following general formulae (Formula 33) and (Formula 34) The naphthalene derivative shown below, or the following general formula ( 35) and compounds formed by the dinaphthyl derivatives shown in (Formula 36). -15- This paper size applies to China National Standard (CNS) A4 (210X297 mm) 490473 A8 B8 C8 D8 (X〇) i (〇X) c (Equation 3 3) (R) b (R) d (Equation 3 4) (X2N), (NX2) c 33), (Formula 34), each R 傺 is a hydrocarbon group of the same or different Ci to C20, Ci to C2 having a hydroxyl group or a halogen group; a hydrocarbon group, a halogen group, a carboxyl group or an ester thereof, and a methyl group , Fluorenyl, (fluorenyl) -0-a radical, amine, mono- or dialkylamino, fluorenamine or its substitution, hydroxyl, alkoxy, alkylthio, Group, phosphorus-containing fluorenyl group, nitro, cyano, thiocyano; X 傺 is the same or different hydrogen, C.1 ~ C 20 hydrocarbon group, C i ~ C 20 hydrocarbon group with hydroxyl or halogen group, Fluorenyl-group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether group-containing hydrocarbon group; j, b, c, and d are pseudo integers of 0 or 1 to 3; but VII ο VII &lt; -1X VII VII ο VII 6 VH This paper size applies to China Quasi (CNS) A4 size (210X297 mm) 490473 A8 B8 C8 D8 Patent Application range (Formula 3 5) (XO), vvx (R) h Please read the notes on the back before (Equation 3 6) (X2N), (NX2) 〇. (R) d 2) g (in (Equation 3 5), (Equation. 3 6), each , _R is the same or different C 丄 ~ C 20 hydrocarbon group, C i ~ C 20 hydrocarbon group with hydroxyl group or halogen group, halogen group, carboxyl group or ester thereof, formamyl group, fluorenyl group, (fluorenyl) -0 -I subscribe to the base of the printed material printed by the Consumer Cooperative of the Ministry of Economic Affairs and the Intellectual Property Bureau, with the same hydrocarbon linkages, 10 and phosphorus, and 20 ethers, which contains or e with ~ or, the same or C1 base phase C1,, The base of the amine is the bond of each group, the halogen group is connected to the sulfone X, the halogenated straight amine contains ·, or the phosphorus group, the group contains the same 17-alkyl hydroxy, and does not disulfide With a base or or alkane, the same single, base-based phase, cyanocarbon fluorene as the base oxygen, 20 sulfonyl amine alkyl e containing pseudo, S ~ 丄, Y group, 01 group; hydroxy, 醯The base paper, hydrogen, and hydrocarbon paper standards are applicable to the Chinese National Standard (CNS) A4 specifications (210X297 mm) 490473 A8 B8 C8 D8-S '-SO 2, e, f, g, and h. (纟 希基) · ~ 0-、-(《《 Hickey) £, -C0-, -C00-; j, b, c N are integers of 0 or 1 to 3; only 0 S, j + bg 4, 0 gc + d S 3, 0 Yune + fS4 , O ^ g + h contains 3, j + c + e + gg 12) 〇20. For example, the polyester polymerization catalyst for item 11 of the patent application scope, which contains the general formula (Formula 3) and / or (Formula 4) The compounds of the structure shown are pseudo compounds selected from the group consisting of the derivatives shown in the following general formulae (Formula 3 7) and (Formula 3 8): (Please read the precautions on the back before filling this page) ( (3) 7) (〇X) P (〇Χ) β (R) q (Equation 3 8) (In (Formula 37) and (Formula 38), each R 傺 is the same or different Ci ~ C20 hydrocarbon group, Ci ~ C20 hydrocarbon group having a hydroxyl group or a halogen group, a halogen group, a carboxyl group or an ester thereof, a methyl group, Fluorenyl, (fluorenyl) _0-based, amine, mono- or dialkylamine, fluorenylamine or its substitutes-18- This paper size applies to China National Standard (CNS) A4 (210X297) (%) 490473 A8 B8 C8 D8 6. Scope of patent application, hydroxyl group, alkoxy group, alkylthio group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, nitro, fluorenyl group, thiofluorenyl group; X 傺 each Is the same or different hydrogen, ci ~ C 20 hydrocarbyl group, C 1 ~ C 20 hydrocarbyl group having hydroxyl or halogen group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether bond-containing hydrocarbon group; j, b, e, and f 傺 are integers of 0 or 1 to 3; · P and q are integers of 0 or 1 to 2; but 0Sj + bS4, 0Sp + qg2, OSe + f Yun 4, IS j + p + e ^ 8). 2 1. The polyester polymerization catalyst according to item 11 of the scope of patent application, wherein the compound containing the structure represented by the above general formula (Formula 3) and / or (Formula 4) is pseudo selected from the following formula (Formula 39) and Compounds grouped by benzophenone derivatives represented by (Formula 4G): (Formula 3 9) (Please read the precautions on the back before filling this page). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 40) 〇 (In (Formula 3 9) and (Formula 40), each R is pseudo or the same or different C 丄 ~ C 20 hydrocarbon group, C i ~ C 20 hydrocarbon group having a hydroxyl group or halogen group, -19- Applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 6. Application scope of patents Halo group, carboxyl or its ester, formamyl, fluorenyl, (fluorenyl) -0-the base shown , Amine, mono- or dialkylamino, fluorenylamino or its substitutes, hydroxyl, alkoxy, alkylthio, sulfofluorenyl-containing group, phosphorus-fluorenyl-containing group, nitro, fluorenyl, Thioxanyl; X is each the same or different hydrogen, ci ~ C 20 hydrocarbon group, Ci ~ C 20 hydrocarbon group with hydroxyl group or halogen group, fluorenyl group, sulfonyl group-containing group, phosphoryl fluorenyl group-containing group Or a hydrocarbon group having an ether bond; k, 1, P, and q 傺 are integers of G or 1 to 2; but k + 1 contains 2, 0 contains p + qS2, l ^ k + p ^ 4). 2 2. The polyester polymerization catalyst according to item 11 of the scope of patent application, wherein the compound containing the structure represented by the above general formula (Formula 3) and / or (Formula 4) is selected from the following general formula (Formula 4 1 ) And compounds of the _ 醍 derivative shown by (Formula 4 2): (Formula 4 1) (Please read the precautions on the back before filling this page) 〇 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 4 2) 〇 This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 6. Scope of patent application (in (Formula 4 1), (Formula 4 2) In the above, each R 傺 is the same or different C 丄 ~ C20 hydrocarbon group, Ci ~ C20 hydrocarbon group having a hydroxyl group or a halogen group, a halogen group, a carboxyl group or an ester thereof, a methyl group, a fluorenyl group, (fluorenyl) A group represented by _〇-, an amine group, a mono- or dialkylamino group, a fluorenylamino group or a substitute thereof, a hydroxyl group, an alkoxy group, an alkylthio group, a sulfofluorenyl group-containing group, a phosphofluorenyl group-containing group , Nitro, cyano, thiocyano; X 傺 is the same or different hydrogen, Ci ~ C20 hydrocarbon group, Cl ~ C20 hydrocarbon group with hydroxyl or halogen group, fluorenyl group, sulfonyl group-containing group, phosphorus-containing fluorene Group or a hydrocarbon group having an ether bond; k and 1 傺 are integers of G or 1 to 2; c and d 傺 are integers of 0 or 1 to 3; 1 隹 gk + l &lt; 2, 0Sc + dS4, IS k + cg 5) 〇23. The polyester polymerization catalyst according to item 11 of the patent application scope, wherein the compound containing the structure represented by the above general formula (Formula 3) and / or (Formula 4) is pseudo-selected Compounds grouped from anthracene pyrene derivatives represented by the following formulae (Formula 4 3) and (Formula 4 4): (Formula 4 3) (Formula 44) 〇 〇 This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 AB.CD 6. The scope of patent application (in (Formula 4 3), (Formula 4 4), each R is pseudo same or different Ci Hydrocarbon group of ~ C20, Ci ~ C20 hydrocarbon group having a hydroxyl group or halogen group, halogen group, carboxyl group or an ester thereof, formamyl group, fluorenyl group, (fluorenyl) group represented by -0-, amine group, mono or di Alkylamine, amido or its substitute, hydroxyl, alkoxy, alkylthio, sulfofluorenyl-containing group, phosphorylfluorenyl-containing group, nitro, cyano, thiocyano, X pseudo Each is the same or different hydrogen, ci ~ C 2 fluorenyl hydrocarbon group, C i ~ C 20 hydrocarbyl group having hydroxyl or halogen group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether bond-containing hydrocarbon group ; J, b, c, and d are pseudo- [] or integers from 1 to 3; only 0 ^ j + b 4 4 N 0Sc + dS4, IS j + c ^ 6) 〇 2 4. If the scope of patent application 1 1 The polyester polymerization catalyst according to item 2, which contains the compound having the structure represented by the general formula (Formula 3) and / or (Formula 4), and is selected from 2 shown by the following formulas (Formula 4 5) and (Formula 4 6) , 2 bisphenol, or the following formula (Formula 4 6) Compounds of 2-aminobiphenyl and its derivatives as shown: (Formula 4 5) (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs ( (Equation 4 6) -22- This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm)-490473 A8 B8 C8 D8, patent application scope 2 5. If the polyester polymerization catalyst of item 11 of the patent application scope, which contains The compound having the structure represented by the general formula (Formula 3) and / or (Formula 4) is assumed to be selected from 2,2'-dihydroxydiphenyl ether represented by the following formula (Formula 4 7), and the following formula (Formula 4 8) 2,2'-thiobis (4-third octylphenol), or 2,2'-methylenebis (6-third-butyl-p-thyl) represented by the following formula (Formula 49) Compounds grouped by toluene ') and its derivatives: (Formula 47) (Eq. 48) (Please read the notes on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 4 9) tert-buiyl i ^ r / -butyl 26. The polyester polymerization catalyst according to item 11 of the scope of patent application, which contains a compound having a structure represented by the above general formula (Formula 3) and / or (Formula 4) -23- Applicable to China National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 6. The scope of patent application is forged from a methylene cross-linked linear phenol compound represented by the following formula (Formula 50): 2 ~ 1 G 0 polymer mixture), or a methylene cross-linked linear p-3 butylphenol compound (mixture of 2 to 100 polymer) shown by the following formula (Formula 5 1) and its Compounds grouped by derivatives: (Formula 50) (In (Equation 5 0), n 傺 represents any integer from 1 to 9 9); (Equation 5 1) (Please read the precautions on the back before filling this page), 1T Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (in the formula (5 1), η 傺 represents any integer from 1 to 9 9). 27. The polyester polymerization catalyst according to item 11 of the scope of patent application, which contains the structure represented by the above general formula (Formula 3) and / or (Formula 4): Compound 傺 is selected from the following formula (Formula 5 2 C a 1 y X [4] arene, Calyx [6] arene represented by the following formula (Formula 53), Calyx [8] arene represented by the following formula (Formula 54), and the following formula (Formula 5 5) Para 3 butyl C a 1 y X [4] aryl, para 3 butyl Calyx [6] arene shown in the following formula (Formula 56) -24- This paper is applicable to China Standard (CNS) A4 specification (210X297 mm) 490473 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 6. The scope of patent application, or the 3rd butyl C as shown in the following formula (Formula 5 7) Compounds grouped by a 1 y X [8] arene and its derivatives: (Formula 52) (Eq. 5 3) This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) 490473 A8 B8 C8 D8 VI. Patent application scope (Formula 5 4) (Eq. 5 5) (Eq. 5 6) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 5 7) (Please read the notes on the back before filling this page) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 · &gt; Application for patent scope 2 8. For example, the polyester polymerization catalyst for item 11 of the scope of patent application, which contains the above general formula ( The compound 构造 having a structure represented by formula 3) and / or (formula 4) is selected from the group consisting of horse chestnut represented by the following formula (formula 58), or 7-amino group represented by the following formula (formula 5 9)- 4-Methylcoumarin and its derivatives: Compounds of group: (Formula 5 8) (Eq. 5 9) (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 2 9. The polyester polymerization catalyst of item 11 in the scope of patent application, which contains the compound of the structure shown by the above general formula (Formula 3) and / or (Formula 4) The bar is selected from the group consisting of boxwood expressed by the following formula (Formula 60), mulberry yellow shown by the following formula (Formula 61), or 2-amine based color formula shown by the following formula (Formula 6 2) and Compounds grouped by its derivatives: (Formula 60) This paper size applies Chinese National Standard (CNS) A4 specification (2 丨 0X297 mm) 490473 A8 B8 C8 D8 Patent application scope (Formula 6 1) (Formula 6 2) OH (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 30. If the polyester polymerization catalyst for item Π of the patent application scope contains the above general formula (Formula 3) and / Or a compound having a structure represented by the formula (Formula 4) is selected from epicatechin represented by the following formula (Formula 6 3), or epicatechin of the following formula (Formula 6 4), and Compounds grouped by its derivatives: (Formula 6 3) OH 28- This paper size applies to China National Standards (CNS) A4 (210X297). Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A8 B8 C8 D8 6. Scope of Patent Application (Formula 64) OH 3 1. The polyester polymerization catalyst according to item 11 of the scope of patent application, wherein the compound containing a structure represented by the general formula (Formula 3) and / or (Formula 4) is selected from the following formula (Formula 6 5 ), Disodium 4,5-dihydroxynaphthalene-2,7-disulfonic acid, 1,8-diaminonaphthalene represented by the following formula (Formula 66), and formula (Formula 67) Naphthol AS, 1: 1 represented by the following formula (Formula 68): T-bis-2-naphthol, or 1,1'-dinaphthyl-2,2 represented by the following formula (Formula 69) '-Diamine and its group of compounds: This paper size applies the Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) 490473 A8 B8 C8 D8 Patent Application Range (Formula 6 5) S03Na (Equation 6 6) nh3 nh5 (Equation 6 7), OH (Formula 6 8) OJ OH 'OH Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 6 9) OJ, nh2 NH〇 -30 (Please read the precautions on the back before filling this page) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 VI. Application for patent scope 3 2. For the polyester polymerization catalyst of item 11 of patent scope, which contains the above general formula ( The compound 构造 having a structure represented by formula 3) and / or (formula 4) is selected from the group consisting of deoxyalienin represented by the following formula (formula 7 0) and 9,1 0 represented by the following formula (formula 7 1). -Dimethoxy®, or a group of 2-amino groups and their derivatives represented by the following formula (Formula 7 2): (Formula 70) (Equation 7 1) (Please read the precautions on the back before filling this page), 1T (Eq. 7 2) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 490473 A8 B8 C8 D8 6. Scope of Patent Application (Formula 7 3) 〇 3 4. The polyester polymerization catalyst according to item 11 of the scope of patent application, which contains a compound having a structure represented by the above general formula (Formula 3) and / or (Formula 4). It is assumed to be selected from the following formula (Formula 74) Compounds of 5,8-dihydroxy-1,4-fluorene or 2-aminonaphthoquinone and its derivatives represented by the following formula (Formula 7 5): (Formula 74) (Please (Read the notes on the back before filling out this page) Printed by 1T Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs (Formula 7 5). 3 5. The polyester polymerization catalyst according to item 11 of the scope of patent application, which contains the compound of the structure shown in the above general formula (Formula 3) and / or (Formula 4) -32- This paper size applies Chinese National Standard (CNS ) A4 specification (210 × 297 mm) 490473 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 6. The scope of the patent application is selected from the following formula (Formula 76): Alizarin represented by the formula (Formula 77), madder represented by the following formula (Formula 78), anthracene phenol represented by the following formula (Formula 7 9), and Emodin, 1,4-diamino group represented by the following formula (Formula 8 1), 1,8-diamino group 4,5 -dihydroxy represented by the following formula (Formula 8 2) Anthracene, or a group of acid blue 25 and its derivative represented by the following formula (formula 8 3): (, formula 7 6) (Equation 7 7) OH (Equation 7 8) 〇 OH -33- This paper size applies to Chinese National Standard (CNS) A4 (210X297mm) (Please read the precautions on the back before filling this page) 490473 A8 B8 C8 D8 Patent Application Range (Formula 7 9) (Formula 8 0) (Formula 8 1) ΟΗ Ο OH OH (Please read the precautions on the back before filling out this page), 11 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 8 2) (Form 83) 34- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 VI. Application for patent scope 3 6. A kind of polyester, which is produced by using polyester polymerization catalyst, the polyester polymerization catalyst is Does not contain antimony and germanium, and its activity parameter (AP) can satisfy the following formula [1], and the thermal stability index (TD) of polyethylene terephthalate polymerized using the catalyst can satisfy the following formula [2]: [1] AP (mi η) &lt; 2 T (in i η) (AP refers to the use of a predetermined catalyst at a low pressure of 275 t: 0.1 Torr to make the intrinsic viscosity 0.5 dl / g of the time required for the polymerization of polyethylene terephthalate (mi η); T is the AP when antimony trioxide is used as a catalyst; In terms of acid content, the amount of antimony trioxide added is 0.05 mol% of antimony atoms) [2] TD (%) &lt; 2 5 (TD means PET with an inherent viscosity of 0.6 dl / g Placed in a glass test tube and vacuum-dried at 130 ° C for 12 hours. Inherent in a nitrogen atmosphere at 300 t for 2 hours. (%)), Wherein the polyester polymerization catalyst is composed of at least one metal-containing component and an organic compound component selected from metals and / or metal compounds containing no antimony or germanium, and the organic compound component is 1 or more selected from compounds containing general formula (formula 1 and / or general formula (formula 2): (formula 1) A r-0-(formula 2) -35- 490473 Where Ar is an aryl group, and the metal-containing component is one or more selected from L 1, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, A1, Ga, ΤΙ, Pb, Bi , Cr, Ni, Mo, Tc, Re, Sc, Y, Zr, Hf, V, Ru, Rh Pd, 0s, Ir, Pt, Cu, Ag, Au, Cd, Hg, La &gt; Ce Sm , Eu Gd, In, Mn, Co, Zn, Fe, Nb Ta W, si, Te, B and their compounds ..-a type of polyester, which is produced using a polyester polymerization catalyst The polymerization catalyst is characterized by at least one metal-containing component selected from the group consisting of a metal containing no antimony or germanium and / or a metal compound. It is composed of organic chemical ingredients, and the organic compound component is one or more types of OBBs. White compounds containing general compounds of formula (formula 1) and / or general formula (formula 2): A r-0-(formula 2 ) Ar-N &lt; where Ar is an aryl group, and the metal-containing component is one or more. It is selected from Li, Na, K, Rb, Cs' Be Mg, Ca, Sr, Ba, A1 Λ Ga, T1, Pb, Bi, Cr, Ni &gt; Mo, Tc, Re, Sc, Y, τr, Hf, V, Ru Λ Rh, Pd, Os Ir, P t, Cu, Ag, Au, Cd, Hg, L a Ce, Sm, Eu Gd, In, Mn, Co, Zn, Fe, Nb, Ta -36- 490473 6. Scope of patent application: W, Si, Te, B and their compounds. 38. The polyester according to item 36 or 37 of the scope of patent application, wherein the metal-containing component is one or more members selected from T1, Pb, B1, and compounds thereof. 39. The polyester polymerization catalyst according to item 36 or 37 of the scope of patent application, wherein the metal-containing component is one or more selected from the group consisting of Cr, N1 and compounds thereof. 40. The polyester of claim 30 or 37, wherein the metal-containing component is one or more selected from the group consisting of Sc, Y, Zr, Hf and compounds thereof. 41. The polyester of claim 36 or 37, wherein the metal-containing component is one or more selected from Ru, Pd, and compounds thereof. 42. The polyester as claimed in claim 36 or 37, wherein the metal-containing component is one or more selected from Cu, Ag and compounds thereof. 43. If the polyester is in the range of 36 or 37, the metal-containing component is one or more selected from lanthanoid metals and their compounds. 44. For example, the polyester in the 36th or 37th of the scope of patent application, wherein the metal-containing component is one or more selected from I η and its compounds. 45. The polyester of claim 36 or 37, wherein the metal-containing component is one or more selected from Fe and its compound. 46 · If the polyester in the scope of patent application No. 36 or 37, the compounds containing the structure of the general formula (Formula 1) and / or (Formula 2) each contain the following general formula (Formula 3) and / or ( Compound of the structure shown by formula 4): -37- 490473 ABCD VI. Patent Application Range (Formula 3) A r-0-X 1 (Formula 4) X2 Ar-N7 \ X3 (where A r represents an aryl group; X1, X2, and X3 are each a hydrogen, a hydrocarbyl group, a fluorenyl group, a sulfofluorenyl group-containing group, a phosphorus fluorenyl group-containing group, or an ether bond-containing hydrocarbon group). 47. The polyester according to item 46 of the scope of patent application, wherein the Ar formula of the general formulae (Formula 3) and (Formula 4) is selected from the group consisting of the general formulae (Formula 5) to (Formula 12): (Formula 5 ) σ -38- This paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm) 490473 A8 B8 Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm). The scope of patent application is A8 B8 C8 D8 48. The polyester in scope of patent application No. 46, which contains the general formula (Formula 3) and / Or the compound having a structure represented by (Formula 4) is formed by selecting a linear phenol compound, a linear aniline compound, and a derivative thereof represented by the following general formula (Formula 1 3) and (Formula 1 4). Group of compounds: (Formula 13) " Y, (〇X) c R2 (Please read the precautions on the back before this page) (Eq. 1 4) R2, \ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (in (Formula 1 3), (Formula i 4), each R i 僳 is the same or different C 1 ~ C 2 0 hydrocarbon group, hydroxyl group or C χ ~ C 20 hydrocarbon group, halogen group, alkyl group, ester group, methyl group, fluorenyl group, fluorenyl group, amine group, mono- or dialkylamino group, fluorene Amine group or its substitute, mesogenic group, mesyl group, alkylthio group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, nitro group, fluorenyl group, and thiocyano group; R2 傺 is the same or different 氲'C i ~ C 20 hydrocarbon group having a hydroxyl group or a halogen group, c 1 ~ C 20 hydrocarbon group, a hydroxyl group, a carboxyl group or an ester thereof, a methyl group, a fluorenyl group, Amine group, mono- or dialkylamine group, amido group or its substitution-40- This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) 490473 A8 B8 C8 D8 , Hydroxyl, alkoxy, alkylthio, sulfofluorenyl-containing group, phosphorofluorenyl-containing group, nitro, cyano, and thiofluorenyl; X 傺 is each the same or different hydrogen, C 1 ~ C 20 Hydrocarbyl, hydroxyl or halogen C 1 ~ C 20 hydrocarbyl group of prime group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether group-containing hydrocarbon group; Y pseudo each is the same or different direct bond, C i ~ C 10 Shenyuanji, _ (dilute base) -〇-,-(ί: Hickey) -S-, -0-, -S-, -S 0 2-,-C 0-,-C 0 0-; η is an integer of 1 to 1 0 0; a and c are integers of 1 to 3; b and d 傺 are integers of 0 or 1 to 3, but 1 contains a + b contains 5, 1 gc + dS 4 d may be each the same or different). 49. The polyester according to item 46 of the patent application scope, wherein the compound containing a structure represented by the general formula (Formula 3) and / or (Formula 4) is selected from Compounds grouped by linear phenol compounds, branched linear aniline compounds, and derivatives thereof represented by the following general formulae (Formula 15) and (Formula 16): (Formula 15) (Please read the note on the back first (Items on this page), 1T Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -41-蝮 丨 1. This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 ^, patent application scope (Formula 16) C 消费 ~ C 20 hydrocarbyl group, C ~~ C 20 hydrocarbyl group, halogen group, carboxyl group or its ester, formamyl group, fluorenyl group, (fluorenyl group) -0-a base, an amine group, a mono- or dialkylamino group, a fluorenylamino group or a substitute thereof, a hydroxyl group, an alkoxy group, an alkylthio group, a sulfofluorenyl group-containing group, a phosphofluorenyl group-containing group , Nitro, fluorenyl, thiocyano; R 2 傺 is each the same or different hydrogen, C 1 ~ C 20 hydrocarbyl, C 1 ~ C 20 hydrocarbyl with hydroxyl or halogen group, halogen group, carboxyl group or ester thereof, Formamyl, fluorenyl, (fluorenyl) -0-a radical, amine, mono- or dialkylamino, fluorenylamino or its substitute, hydroxyl, alkoxy, alkylthio, sulfo Fluorenyl group, phosphorus-containing fluorenyl group, nitro, fluorenyl, and thiofluoro groups; X is the same or different hydrogen, C 1 ~ C 2Q hydrocarbon group, C i ~ C 2 with hydroxyl or halogen group ◦Hydrocarbyl, fluorenyl, sulfofluorenyl-containing, phosphorofluorenyl-containing, or ether-bonded hydrocarbon groups; Y systems are the same or different direct bonds, Ci ~ C10 alkylene,-(ene Group) -〇-,-(alkenyl) -S ~-0- 、-S-、 -42- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 _____D8____ 6. Scope of patent application-S〇2 '-CO' -COO-; η An integer from 1 to 100; c is an integer from 1 to 3 that is the same or different; d is an integer from 1 to 3 that is the same or different; only 1 S c + d 4). 50. The polyester according to item 46 of the patent application scope, wherein the compound containing a structure represented by the general formula (Formula 3) and / or (Formula 4) is selected from the following general formula (Formula 17) And a group of the cyclic phenol compound, the cyclic aniline compound, and a derivative thereof represented by the formula (Formula 18): (Formula 17) (Eq. 1 8) This paper size applies the Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) 490473 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 VI. Patent application scope Halo, carboxy or its ester, methyl , Fluorenyl, (fluorenyl) -0-a radical, amine, mono- or dialkylamino, fluorenamine or its substitution, hydroxyl, alkoxy, alkylthio, Radicals, phosphorus-containing fluorenyl radicals, nitro, aryl, and thiosulfanyl groups; X 傺 is the same or different hydrogen, ci ~ C 20 hydrocarbyl, C i ~ C 20 hydrocarbyl with hydroxyl or sulfonyl, 醯Group, sulfofluorenyl group-containing group, phosphorofluorenyl group-containing group, or hydrocarbon group having ether bond; Y systems are each the same or different direct bond, Ci ~ C10 alkylene group,-(alkenyl) -0 -,-U # $)-s-, -o-, -s-, -so2-, -CO-, -C00-; η 傺 is an integer from 1 to 100; c is an integer from 1 to 3; d傺 is an integer of 0 or 1 ~ 3; but 1 Yun c + dg 4; d can be each the same or different). 5 1. The polyester according to item 46 of the scope of patent application, wherein the compound containing a structure represented by the general formula (Formula 3) and / or (Formula 4) is selected from the following general formula (Formula 19) and (Formula 20) The coumarin derivative shown by), or the compound formed by the chromone derivatives represented by the following general formulae (Formula 21) and (Formula 22): This paper size applies the Chinese National Standard (CNS) A4 specification ( 210X297 mm) 490473 A8 B8 C8 D8 6. Scope of patent application (Formula 1 9) (Eq. 2 0) (Equation 2 1) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 2 2) 〇 -45- This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 490473 A8 B8 C8 D8 The scope of patent application (in (Formula 1 9) ~ (Formula 2 2), each R is the same or Different ci ~ C 20 hydrocarbyl groups, Ci ~ C 20 hydrocarbyl groups with hydroxy or halogen groups, halogen groups, carboxyl groups or esters thereof, methylamidino, fluorenyl, (fluorenyl) -0-the bases and amines shown Group, mono- or dialkylamino group, amidino group or a substitute thereof, a hydroxyl group, an alkoxy group, an alkylthio group, a sulfofluorenyl group-containing group, a phosphorofluorenyl group-containing group, a nitro group, a cyano group, and a thiocyanate X; each is the same or different hydrogen, Ci ~ C20 hydrocarbyl, Ci ~ C20 hydrocarbyl with hydroxyl or halogen group, fluorenyl, sulfofluorenyl-containing group, phosphorofluorenyl-containing group, or Hydrocarbon group with ether bond; j and b are pseudo integers of 0 or 1 ~ 3, · Π1 and d 傺 are integers of Q or 1 ~ 2; but 0 contains j + bS4, OSm + d contains 2, and Ι j + ηι = 5) 〇5 2. The polyester according to item 46 of the patent application scope, which contains a compound having a structure represented by the general formula (Formula 3) and / or (Formula 4) 傜 is selected from the following general formula (Formula 23) And the dihydrocoumarin shown by (formula 24) Derivatives, chromone derivatives represented by the following general formulae (Formula 2 5) and (Formula 2 6), or isochromone derivatives represented by the following general formulae (Formula 2 7) and (Formula 2 8) Groups of compounds:, (Formula 2 3) Please read the notice on the back and write on this page. This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 Patent application scope (Formula 2 4) (X2N) a (NX2) p (R) q (R) b ο ο (Equation 2 5) 〇 (Please read the notes on the back before filling this page) (Eq. 2 6) 〇 Order (Form 2 7) End! Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 2 8) (Χ2Ν) β (Νχ2) ρ γ (R) b This paper size is applicable to Chinese National Standard (CMS) A4 specification (210X297 ^^) -47 490473 A8 B8 C8 D8 Patent application scope (in (Expression 2 3) ~ (Expression 2 8) Each R pseudo is the same or different C χ ~ C 20 hydrocarbon group, C i ~ C 2 with hydroxyl group or halogen group. Hydrocarbyl group, halogen group, carboxyl group or ester thereof, formamyl group, fluorenyl group, (fluorenyl group) -0-a base, an amine group, a mono- or dialkylamino group, a fluorenylamino group or a substitute thereof, a hydroxyl group, an alkoxy group, an alkylthio group, a sulfofluorenyl group-containing group, a phosphofluorenyl group-containing group , Nitro, cyano, thiocyano; X is the same or different hydrogen, C 1 ~ C 20 hydrocarbyl, C i ~ C 20 hydrocarbyl with hydroxyl or halogen group, fluorenyl, sulfonyl group , Phosphonium-containing groups, or hydrocarbon groups with ether linkages; a is an integer of 1 to 3; b is an integer of Q or 1 to 3; p and q are integers of 0 or 1 to 2; only 1 Contains a + b Yun 4, 0 ^ p + q ^ 2) 〇53. The polyester according to item 46 of the patent application scope, which contains a compound having a structure represented by the general formula (Formula 3) and / or (Formula 4). Is selected from the following general formulae (Formula 29) and (Formula 3Q) Coumarin derivatives, or compounds of the group consisting of isochromone derivatives represented by the following general formulae (Formula 31) and (Formula 32): (Formula 2 9) (Please read the precautions on the back before filling in ^ : Page), 17 竦: Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 30) (X〇) a (X2N), (R) b | -p- (R) d &gt; &lt; ^ 0 夕 -48-This paper size applies to China National Standard (CNS) A4 (210X 297 mm) 490473 A8 B8 C8 D8 Patent application scope (Formula 3 1) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (in (Equation 2 3) ~ (Equation 3 2), each R is pseudo-C i ~ C 20 hydrocarbon group, hydroxyl group or halogen-containing C i ~ C 20 hydrocarbon group, halogen group, carboxyl group or ester thereof, methylamino group, fluorenyl group, (fluorenyl) -0 group, amino group, mono or dialkylamino group, fluorenylamino group or its substitute, Hydroxyl, alkoxy, alkylthio, sulfofluorenyl-containing group, phosphorofluorenyl-containing group, nitro, cyano, thiocyano; X pseudo each is the same or different hydrogen, C 1 ~ C 20 hydrocarbon group , C 1 ~ C 20 hydrocarbyl group having hydroxyl or halogen group, fluorenyl group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether group-containing hydrocarbon group; a 傺 is an integer of 1 to 3; b is pseudo Integers of 0 or 1 to 3; c and d are integers of 0 or 1 to 3; only lSa + bg4 and OSc + d are 3). 54. The polyester according to item 46 of the scope of patent application, wherein the compound containing a structure represented by the general formulae (Formula 3) and / or (Formula 4) is selected from the following general formulae (Formula 33) and (Formula 34) The compounds shown in the fluorene derivative, or the dinaphthyl derivatives represented by the following general formulae (Formula 3 5) and (Formula 3 6): -49- The Chinese paper standard (CNS) A4 specification (2 丨 0X297mm) 490473 A8 B8 C8 D8 Patent application scope (X〇) i (〇X) c (Formula 3 3) (R) b (R) d (Formula 3 4) (In (Formula 3 3) and (Formula 3 4), each R 傺 is the same or different C i ~ C 20 hydrocarbon group, C i ~ C 2 having a hydroxyl group or halogen group, a hydrocarbon group, a halogen group, a carboxyl group, or Its ester, methylamidino, fluorenyl, (fluorenyl) -0-based group, amine group, mono- or dialkylamino group, fluorenylamino group or its substitute, hydroxyl group, alkoxy group, alkylthio group Sulfonyl group, phosphoryl group, nitro group, cyano group, thiocyano group; X is the same or different hydrogen, C.1 ~ C 20 hydrocarbon group, C with hydroxyl or halogen group 1 ~ C 20 hydrocarbon group, fluorenyl-group, sulfofluorenyl group-containing group, phosphorus fluorenyl group-containing group, or ether group-containing hydrocarbon group; j, b, c, and d are pseudo-G or integers of 1 to 3; but OSj + b each 4, 1 Yuna + b ^ 5, 0 Yun c + dg4, lgj + c Yun 6); Please read the notice on the back and fill in I · 'Printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -50 This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 Patent application scope (Formula 3 5) (XO), &gt; &lt; vx (Eq. 3 6) Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, Λ-based radicals, radicals, radicals, p-substituted hydrocarbons, hydrocarbons, 10, 0, phosphorus, 20 ether, and 20S), or does it contain ~ C groups? 1 No ~ lla or, the same as 1 or C or (^ base group phase C ,, the same as C1, the base of the amine base phase, the base of the base group, the bond of each group is the base group, the actin group is connected to the element, the group Sulfur X halo R R haloamine containing ·, or phosphorus or fluorenyl group, the group containing the same 51, methyl methyl alkyl hydroxyl, not -5 middle hydroxyl, disulfide or 6 vinegar or vinegar, , The same as -t3, its single, aryl group, U group, or cyanocarbon fluorene, hydrocarbyloxy, 20 sulfonyl each 5) Carboxamido-C containing fluorene-t2L,,, nitrate, Y UC Basic group, 01 group; 1 hydroxyl group, fluorenyl icl halogen, hydrogen, hydrocarbon The paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 ,-(¾ group) -〇-,-(burning group) -3-, -0 ~, -8-, ~ 3〇2_, -C 0-,-C 0 0-; j, b, c, d , E, f, g, and h are integers of 0 or 1 to 3; only 0 gj + b 4 4, 0 gc + dg 3, 0 e e + f ^ 4, 0 &lt; g + h ^ 3 sj + c + e + g ^ 12) 〇5 5 · The polyester according to item 46 of the patent application scope, which contains a structure represented by the general formula (Formula 3) and / or (Formula 4) The compound 傺 is a compound selected from the group consisting of ® derivatives represented by the following general formulae (Formula 3 7) and (Formula 3 8): Read the winter notes on the back (〇χ) β (Formula 3 7 (〇 X) p Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 3 8) Ci ~ C20 hydrocarbyl group, Cl ~ C 20 hydrocarbyl group with hydroxy or halogen group, halogen group, carboxyl group or ester thereof, formamyl group, fluorenyl group, (fluorenyl) -0-based group, amino group, Dialkylamine, amidoamine or its substitute -52- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. A8 B8 C8 D8 6. Scope of patent application, hydroxyl group, alkoxy group, alkylthio group, sulfofluorenyl group-containing group, phosphorofluorenyl group-containing group, nitro, fluorenyl group, and thiofluorenyl group; X 傺 is the same or Different hydrogens, C 1 ~ C 20 nicotinyl, C 1 ~ C 2CJ with a meridian or haloyl group, mesityl, a sulfoamyl group, a phosphorylamyl group, or an ether bond Hydrocarbyl; j, b, e, and f 傺 are integers of 0 or 1 to 3; p and q are integers of 0 or 1 to 2; except Ogj + b contains 4, 0Sp + qS2, 0 contains e + f Yun 4 , J + p + eg 8) 〇56. The polyester according to item 46 of the scope of patent application, wherein the compound containing the structure represented by the above general formula (Formula 3) and / or (Formula 4) is pseudo selected from the following formula Compounds grouped by benzenehydrazone derivatives represented by (Formula 3 9) and (Formula 4 ()): (Formula 3 9) 〇 (x〇) k \ ^ JL ^^ (〇x) P ο (Formula 4 0) (In (Formula 3 9), (Formula 40), each R 傺 is the same or different Ci ~ C20 hydrocarbon group, Ci ~ C20 hydrocarbon group with hydroxyl group or halogen group, -53- This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 490473 ABCD Group, carboxyl group or ester thereof, formamyl group, fluorenyl group, (fluorenyl group) -0-a group represented by amine group, amine group, mono- or dialkylamino group, fluorenylamino group or its substitute, hydroxyl group, alkoxy group , Alkylthio, sulfofluorenyl-containing group, phosphorofluorenyl-containing group, nitro, m group, thiosulfanyl group, X series are each the same or different hydrogen, Ci ~ C20 hydrocarbon group, hydroxyl group or C i ~ C 2 of a halogen group, a hydrocarbyl group, a fluorenyl group, a sulfofluorenyl group-containing group, a phosphorus fluorenyl group-containing group, or an ether bond-containing hydrocarbon group; k, 1, P, and q are pseudo-fluorene or 1 ~ 2 Integer; only 0 ^ k + 1 ^ 2, Ogp + qyun2, k + ρ 4 4). 5 7. For the polyester in the 46th scope of the patent application, which contains the above general formula (Formula 3) and / Or a compound having a structure represented by (Formula 4) is a compound selected from the group consisting of _ alcohol derivatives represented by the following general formula (Formula 4 1) and (Formula 4 2): (Formula 4 1) (please first (Read the notes on the back and fill in the pages) 'IT. 〇 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 4 2) 〇 -54- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 ABCD 々, patent application scope (in (Formula 4 1), (Formula 4 2), each R4 is the same or different C 丄 ~ C 2ϋ hydrocarbon group, C i ~ C 2 with hydroxyl group or halogen group, hydrocarbon group, halogen group, carboxyl group or ester thereof, methyl group, fluorenyl group, (fluorenyl) -0-based group, amine Group, mono- or dialkylamino group, amidino group or a substitute thereof, a hydroxyl group, an alkoxy group, an alkylthio group, a sulfofluorenyl group-containing group, a phosphorofluorenyl group-containing group, a nitro group, a cyano group, and a thiocyanate X 傺 is the same or different hydrogen, ci ~ C 20 hydrocarbyl, C 1 ~ C 20 hydrocarbyl having hydroxyl or halogen group, fluorenyl, sulfofluorenyl-containing group, phosphorus fluorenyl-containing group, or A hydrocarbon group having an ether bond; k and 1 are integers of 0 or 1 to 2; c and d 傺 are integers of Q or 1 to 3; 1 隹 0 contains k + lS2, OSc + d Yun 4, 1 contains k + c contains 5). 58. The polyester according to item 46 of the scope of patent application, wherein the compound containing the structure represented by the general formula (Formula 3) and / or (Formula 4) is pseudo selected from the following formulae (Formula 4 3) and (Formula 4) 4) Compounds in the group of hydrazone derivatives shown: (Formula 4 3) (Please read the notes on the back before filling in the page), printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 44). 〇 This paper size is applicable to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 490473 ABCD 6. Application scope of patent (in C 1,-(&quot; 20 of hydrocarbon group in (Formula 43) (Formula 4 4) \ with hydroxyl halogen Carboxyl group, carboxyl group or ester thereof, methyl group, amine group, C3CJ early or dioxane, hydroxy X alkoxyalkylthio group, nitro group, cyano group, and thionium hydrogen C: L ′ ~ C 20 hydrocarbon group, with Hydroxyl \ fluorenyl, fluorenyl-containing group, hydrocarbyl, b, C, and d 傺 0 S j + b &lt; 4. 0 &lt; C + d ^ 4 X The formula (Formula 3) and the pseudostructure are selected from the following formula (Formula 4 5) \ or the following formula (Formula 4 6): each R is the same or different or a halogen group of C 1 to C 20 hydrocarbon group , Fluorenyl, fluorenyl, (fluorenyl) -0 _ an amino group, fluorenyl group or a substitute thereof, a sulfofluorenyl group, a phosphorus-containing fluorenyl group; each of X pseudo is the same or different group or C 1 ~ C 20 nicotinyl group containing nicotinyl phosphonium group, or integer with 0 or 1 ~ 3: 1 &lt; j + c d 6). The polyester of item 46, wherein / or the compound of the structure shown in (Formula 4) and the 2,2 bisphenol 2-aminobiphenyl shown in (Formula 46) and derivatives thereof Compounds printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs: (Formula 4 5) (Formula 4 6) 56- This paper size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 490473 ABCD Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economy Application for patent scope 60. If the polyester scope of the patent application is 46, it contains the above The compound having the structure represented by the general formula (Formula 3) and / or (Formula 4) is assumed to be selected from 2,2 f -dihydroxydiphenyl ether represented by the following formula (Formula 4 7), and the following formula (Formula 4) 8) 2,2′-thiobis (4-third octylphenol), or 2,2′-methylenebis (6-third butyl) represented by the following formula (Formula 4 9) -Compounds pre-toluene and its derivatives: (Formula 47) (Eq. 48) (Formula 4 9) OH OH un-butyl i ^ r / -butyl 61. The polyester according to item 46 of the patent application scope, which contains the compound of the structure shown by the general formula (Formula 3) and / or (Formula 4) above. Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 6. The scope of the patent application is customary selected from the group consisting of methylene cross-linked linear phenol compounds (mixture of 2 to 10 G polymers) represented by the following formula (formula 50), or chancre. Compounds grouped by methylene cross-linked linear p-butylphenol compounds (mixtures of 2 to 100 polymers) and their derivatives represented by formula (Formula 51): (Formula 50) (In (Formula 5 0), II pseudo-indicates any integer from 1 to 9 9); (Formula 5 1) (Please read the precautions on the back before filling this page), va Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (in the formula (5 1), η represents any integer from 1 to 9 9). 62. The polyester according to item 46 of the scope of patent application, wherein the compound containing the structure represented by the general formula (Formula 3) and / or (Formula 4) is selected from C shown by the following formula (Formula 5 2) a 1 y U 4] aromatic hydrocarbon, C a 1 y X [6] aromatic hydrocarbon represented by the following formula (Formula 5 3), C a 1 y X [8] aromatic hydrocarbon represented by the following formula (Formula 5 4), P-third butyl C a 1 yx [4] aryl represented by formula (formula 5 5), p-third butyl C a 1 yx [6] arene-5 represented by the following formula (formula 5 6) 8-This paper size applies the Chinese National Standard (CNS) A4 specification (210 ×: 297 mm) 490473 A8 B8 C8 D8 6. The scope of patent application, or the 3rd butyl C shown in the following formula (Formula 5 7) Compounds grouped by a 1 y X [8] arene and its derivatives: (Formula 52) (Please read the notes on the back before filling in. Page (Eq. 5 3) , V Yikou finished> Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-59- This paper size applies to Chinese National Standard (CNS) A4 specifications (210X 297 mm) 490473 A8 B8 C8 D8 Patent application scope (Formula 5 4 ) (Eq. 5 5) (Please read the precautions on the back before filling this page), 1T (Eq. 5 6) 印 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 5 7) The size of this paper is applicable to China National Standard (CNS) A4 specification (21〇 ×: 297mm) 490473 ABCD, patent scope 6 3. For the polyester of scope 46 in the patent scope, it contains the above general formula (Formula 3 ) And / or the compound represented by the formula (4) is selected from the group consisting of horse chestnut represented by the following formula (Formula 58) or 7-amino-4-represented by the following formula (Formula 5 9) Compounds grouped by methylcoumarin and its derivatives: (Formula 5 8) (Eq. 5 9) (Please read the precautions on the back before filling this page) Printed by a consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, a compound containing a structure represented by the above general formulae (Formula 3) and / or (Formula 4) is selected from the boxwood flavin represented by the following formula (Formula 6Q), Compounds composed of moraxanthin represented by the following formula (Formula 6 1) or 2-aminotryptone and its derivatives represented by the following formula (Formula 6 2): (Formula 6 0) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 Patent application scope (Formula 6 1) (Formula 6 2) OH (Please read the precautions on the back before filling out this page) 6 5. As for the polyester in the scope of patent application No. 46, which contains the structure shown in the above general formula (formula 3) and / or (formula 4) Compound 傺 is a compound selected from the group consisting of epicatechin shown by the following formula (Formula 6 3), or epicatechin catechin shown by the following formula (Formula 6 4): _ .. (Eq. 6-3), printed by the Consumer Cooperatives of the Intellectual Property Bureau of the 11th Ministry of Economic Affairs OH -62- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 gong) 490473 ABCD Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 6. Scope of Patent Application (Formula 6 4) OH 66. The polyester according to item 46 of the scope of patent application, wherein the compound containing a structure represented by the general formula (Formula 3) and / or (Formula 4) is selected from the group consisting of the following formula (Formula 6 5) 4, 5 -dihydroxynaphthalene-2,7-disulfonic acid disodium, 1,8-diaminonaphthalene represented by the following formula (Formula 6 6), and one represented by the following formula (Formula 6 7) Phenol AS, 1,1'-bis-2 -f # phenol represented by the following formula (Formula 6 8), or 1,1 (-dinaphthyl-2,2) represented by the following formula (Formula 6 9) * -Compounds of diamine and its derivatives: -63- This paper size is applicable to Chinese National Standard (CNS) A4 (210X29 * 7mm) 490473 A8 B8 C8 D8 Patent application scope (Formula 6 5) Na03S SO〇Na (Formula 6 6) (Please read the precautions on the back before filling this page) (Eq. 6 7) .CONH, OH 1T (Equation 6 8) t. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 6 9) νη2 ΝΗο 64- This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 A8 B8 C8 D8 Patent application scope 67. The polyester of the 46th scope of the patent contains a compound having a structure represented by the general formula (Formula 3) and / or (Formula 4), which is conventionally selected from the group consisting of deoxyalienin represented by the following formula (Formula 70), Compounds grouped by 9,10-dimethoxy group represented by the following formula (Formula 7 1), or 2-amino group and its derivatives represented by the following formula (Formula 7 2): ( (Eq. 70) OH (Equation 7 1) Read and read the winter items first, then fill out this page Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 7 2) 68. The polyester according to item 46 of the scope of patent application, wherein the compound containing a structure represented by the general formula (Formula 3) and / or (Formula 4) above is selected from the group consisting of 2, shown by the following formula (Formula 73), Compounds of 5 -dihydroxyphenylhydrazone and its derivatives: -65- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 490473 ABCD 々, patent application scope (formula 7 3) 〇 6 9 · The polyester according to item 46 of the patent application scope, which contains a compound having a structure represented by the general formula (Formula 3) and / or (Formula 4). It is assumed to be selected from the following formula (Formula 7 4) Compounds grouped by 5,8-dihydroxy-1,4-酲 or 2-amino group 酲 shown by the following formula (Formula 7 5) and its derivatives: (Formula 7 4) (Please (Read the notes on the back before filling out this page) , 1T Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Formula 75). 70. The polyester as claimed in item 46 of the patent application scope, which contains the compound of the structure shown in the above general formula (Formula 3) and / or (Formula 4) -66- This paper size applies to China National Standard (CNS) A4 (210X 297 mm) 490473 A8 B8 C8 D8 6. The scope of the patent application is selected from the group consisting of cyperidin represented by the following formula (Formula 7 6), alizarin represented by the following formula (Formula 77), the following Anthracene represented by the formula (Formula 78), anthracene phenol by the following formula (Formula 7 9), emodin represented by the following formula (Formula 80), and the following formula (Formula 8 1) 1,4-diamino group shown in the following formula (formula 8 2) 1,8-diamino group shown in the following formula (formula 8 2), or the following formula (formula 8 3) Compounds grouped as shown in acid basket 25 and its derivatives: (. Formula 7 6) (Equation 7 7) (Please read the precautions on the back before filling in this page) 〇 OH ’Printed by the Consumer Cooperatives of the Intellectual Property Bureau, Ministry of Economic Affairs (Formula 7 8) Ο OH -67- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 490473 A8 B8 C8 D8 Patent Application Scope (Form 7 9) (Form 8 0) (Please read the notes on the back before filling this page) (Eq. 8 1) (Eq. 8 2) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Form 8 3) ° -68- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 490473 VI. Patent application scope 7 1 · A kind of manufacturing method for polyester, which uses the application scope of the patent application as attached to the first to third A polyester polymerization catalyst according to any one of 5 items. 72. The method for producing a polyester according to claim 71, wherein the metal-containing component and the organic compound component are added at the same addition period. 7 3 · The method for manufacturing a polyester according to item 71 of the patent application, wherein the metal-containing component and the organic compound component are added at different addition periods. 74. The method for producing a polyester according to item 71 of the scope of patent application, wherein at least one kind of terephthalic acid and naphthalenedicarboxylic acid are the main components of the dicarboxylic acid component. 75. The method for producing a polyester according to item 71 or 72 of the scope of patent application, wherein at least one kind of ethylene glycol, 1,3-propanediol, 1,4-butanediol, and 1,4-cyclohexanedimethanol are used. It is the main component of the diol component. 76. A method for producing polyethylene naphthalate, characterized in that a polyester polymerization catalyst as described in any one of claims 1 to 35 of the scope of patent application is used. 77. A method for producing polybutylene terephthalate, which is characterized by using a polyester polymerization catalyst according to any one of claims 1 to 35 of the scope of patent application. 78. A method for producing poly (trimethylene terephthalate), which is characterized by using a polyester polymerization catalyst according to any one of claims 1 to 35 of the scope of patent application. 79. A method for producing poly (ethylene terephthalate) copolymerized with cyclohexanedimethanol, which is characterized by using a polyester polymerization catalyst according to any one of claims 1 to 35 in the scope of patent application. -69-