TW473508B - UV curable composition and a non-aqueous solvent-free process for making a UV curable composition - Google Patents

Abstract

The present invention relates to a UV curable composition comprising a monohydroxylated epoxidized polydiene polymer and a photoinitiator selected from the group consisting of diarylhalide salts of the general formula (I): wherein X is a complex metal halide anion or a complex halide anion of a strong protonic acid; wherein R is hydrogen, aryl; alkyl or an alkyl halide; Z is I, Br or Cl; and n is an integer of at least 1. The invention further relates to a process for preparing the UV curable composition in the absence of a non-aqueous solvent, to UV cured compositions and articles containing the UV cured compositions.

Description

473508 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 _______ V. Description of the Invention (1) The present invention relates to a UV curing composition, which comprises a monohydroxylated epoxidized polyfluorene polymer and a photoinitiator. The invention further relates to a method for preparing a UV-curable composition; to a UV-cured composition and to an article containing a UV-cured composition. u V curing composition is used in adhesives, sealants, coatings and other types of thin film 'fibers or thin parts selected from self-epoxidized monohydroxylated polydiene polymers. Mono-hydroxylated polydienes that are epoxidized are described in UV 9 6/11215 in UV curing adhesive and sealant compositions. Combining these polymers with other wounds, such as a tackifying resin, makes them suitable for use as adhesives, sealants and sealants. A photoinitiator is included in the complex to promote U V curing (crosslinking) of the composition. As described in the example of the aforementioned patent application, the components are dispersed in a non-aqueous solvent, usually THF, and then an adhesive film is cast from the solution. A non-aqueous solvent must be used because of difficulties encountered when mixing the photoinitiator (triarylsulfonium hexafluoroantimonate) into the adhesion mixture, as it cannot be quickly compatible and cannot be dissolved or finely dispersed. THF must be obtained to obtain effective UV-curing in the absence of non-aqueous solvents ", for many applications, because of environmental hazards, the cost of non-aqueous solvent removal, and the non-aqueous solvent itself, using non-aqueous solvents A possible method to solve this problem is to use a non-aqueous solvent to mix these components, which requires intensive mixing to disperse the photoinitiator in order to prepare an effective curing adhesive, and seal Agent or other composition. The present invention does not require high-shear equipment to obtain the same results as in the production of films. (Please read the precautions on the back page first} 装-丁 、 τ -4-

A7 B7 V. Description of the Invention (Now surprisingly, it has now been discovered that the UV-curable composition and its non-aqueous solvent-free method, which solves one or more problems related to the prior art. Therefore, the present invention The invention relates to a UV curable composition, which comprises a single radically epoxidized polydiene polymer and a photoinitiator selected from the group consisting of diaryl sulfonium salts having the general formula (I): -Z +-X * -0—Y—Cn Hjn + I ⑴ where X is a composite metal_anion or a strong proton acid complex halide anion; Yes_cr2 —cr7—S—- or —cr2— ((Please read the Matters needing attention 'equipment-genuine) order economy, which Central Standards Bureau employees printed by cooperatives

X wherein R is a hydrogen 'aryl group, a fluorenyl group or an autogenous compound; Z is iodine, bromine or gas; and n is an integer of at least one. In formula (I), Z is preferably iodine. Either or both are preferably hydrogen or hydrogen, typically containing up to 10 carbon atoms, more preferably up to 6 carbon atoms, and more preferably 1 to 4 carbon atoms. Most preferably, both of R are hydrogen.

Y is preferably 〇H -cii2-c-

I Η, in formula (1), Π is preferably an integer in the range of 1 to 25, from 5 to 210X297 mm for this paper size) 473508 A7 B7 5. Invention description (3) 20 is better, since 1 0 to 15 is even better. In a specific embodiment, X is preferably a composite metal self-anion ', wherein the metal is selected from Groups 3 to 15 (new IUPAC notation) in the periodic table, and more preferably Groups 13, 14 or 15 (Including P). The halide is preferably selected from F, Cl, Br or I, and F is more preferred. »Examples of preferred composite metal halides include BF4-, PF6 ', AsF6- and SbF /. A particularly good composite metal paint is SbF6_. -According to another specific embodiment, X is preferably a complex anion of strong protonic acid. Particularly preferred compound halide anions for strong protonic acids include ClO4 ·, CF3S03-? FSO, CC13S03_ and C4F9S03 · 0-A particularly good photoinitiator is diaryliodonium hexafluoroantimonate, commercially available Available from Sartomer, Inc. under the trade name CD-1012. Diaryl iodofluorene hexafluoroantimonate has the formula (11): (Please read the precautions on the back first

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Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs According to the present invention, the photoinitiator present in the composition is typically used in an amount of 0.01 to 10% by weight of the total composition, in a range of 03 to 10% by weight. Preferably, 0.1 to 0.3 wt.% Is more preferred. Typically, the photoinitiator is compatible with the remainder of the composition ', preferably it is soluble in the rest of the composition. Useful photoinitiators include those described in U.S. Patent No. 5,079,3 ^ 8. According to the present invention, the UV curing composition has the advantage that the composition is free of non-aqueous solvents and does not require significant mixing using high shear equipment. Therefore, the present invention relates to UV-curable adhesives, sealants, coatings, or other materials. The silk scale is applicable to China National Standards (cns) Cong Mi (21 Yi Bie A7 __________B7 V. Description of the Invention (4) Composition, 1 A method for preparing these,-, and σ compounds from an epoxidized mono-fluorinated polydiene polymer. The _ _ 埽 polymer is composed of at least two polymerizable rare unsaturated hydrocarbon monomers. (At least one of which is a di & monomer, which produces an unsaturation suitable for cyclization), is used as a binder for the composition. Preferred epoxidized monohydroxylated polymers are at least two conjugated A block copolymer of diene (preferably isoprene and butadiene), and optionally, an ethylamidine (where a hydroxyl gene is attached to the -terminus of the polymer molecule). These polymers can be hydrogenated or unsaturated. The photoinitiator incorporated into this composition is soluble or rapidly dispersible into a mixture (polymer blend) containing the other ingredients of the composition and uses UV light. Shot, very good curing is the result. Polymers can be prepared by copolymerizing one or more olefins, especially dioxins, which are copolymerized by themselves or together with one or more alkenyl aromatic hydrocarbon monomers. Of course, these copolymers may be random, Conical, obstructive segments or combinations of these, as well as linear, star or radial. As a general rule, when using solution anion technology, conjugated di-copolymers, as appropriate, together with acetamidine-based aromatic hydrocarbons Classes are prepared by contacting (or each) monomer to be polymerized <(each) with an anionic polymerization initiator simultaneously or continuously. Such polymerization initiators are, for example, metals of the human group, lithium is preferred, and its alkylate, Ammonium amine, pantenamin, biphenyl or anthracene derivatives. Monohydroxylated poly-associated systems are synthesized via anionic polymerization of conjugated diolefins and these lithium initiators. This method is well known. For example, US patent Case No. 4, 〇39,593 and Re 27,145, etc. Polymerization starts with a single lithium initiator. This paper applies Chinese National Standards (CNS) from Miscellaneous (2ι () χ297). (Please read the back first Precautions &lt; r- 衣 丨 .1 P This page) Order printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 ______B7 V. Description of the invention (5) 'It builds a living polymer backbone at each lithium position. Typically, these polymerizations are performed by using ethylene oxide Termination of the alkane results in the termination of a terminal hydroxyl group. Specific methods for making these polymers are detailed in WO 96/11215. The total cost of anionic polymerization includes 4 to 24 carbon atoms &lt; Those conjugated diesters such as 3, butadiene, isoprene, pentadiene, fluorenyl pentadiene, 2-phenyl_1, 3_ butadiene, 3, 4-dimethyl _1,3_hexadiene and 4,5-diethyl_i, 3-octadifluorene. The preferred conjugated diene (difluorene) is one containing 4 to 12 carbon atoms,-with 4 to 6 carbons Atoms are better. Isoprene and stilbene are the best conjugated difluorene monomers for use in the present invention because of their low cost and immediate availability. -... alkenyl (vinyl) aromatic hydrocarbons that can be copolymerized include ethylenyl aryl compounds such as polyethylene glycol, various phenyl ethyl fluorenyl substituted with alkyl, styrene substituted with fluorenyloxy, vinyl fluorene and Ethylfluorenyl substituted with alkyl. Alkenyl aromatic hydrocarbons are preferably phenethylhydrazone and / or alkyl-substituted styrene, more preferably styrene. : ^ Or alkoxy; the oxy substituent may typically contain 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms. The number of alkyl or alkoxy substituents per molecule (if present) ranges from 1 to 3, with 1 being preferred. The best monohydroxyl polydiene polymer of the present invention has the following structural formula (HO) xA-Sz-B- (0H) y (I) · vt% 2 where A and B are polymer blocks, which may be It is a homopolymer of a conjugated diene monomer & a 'co-light monomer copolymer' block 'or a copolymer block of a dialkylene monomer and a monoalkenyl aromatic hydrocarbon monomer. These polymers can contain up to 60 weights. The paper size is applicable to Chinese National Standards (CNS) A4 specifications (210X: 297 mm) 473508 A7 B7 • Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (6) The amount of at least one vinyl aromatic hydrocarbon, preferably styrene. Generally, the better one is that the latter A section should have a higher concentration of aliphatic double bonds than the latter B section. Therefore, the 'A block has more than two, three, or four substituted unsaturated positions (aliphatic double bonds) at a higher concentration than the B block. This results in a polymer in which the easiest epoxidation occurs in the A block. The A block has a number average molecular weight of 1000 to 6000 g / mole, preferably 500 to 4,000 g / mole, and the most preferred is 1000 to 3,000 g / mole, and B The block has a number average molecular weight of 1,000 to 15,000 g / mole, preferably 2000 to 10,000 g / mole, and most preferably 3QQQ to 60Q0 g / mole. S is a vinyl aromatic hydrocarbon rear stage, which has a number average molecular weight of from 100 to 100,000. x or y is 1, the others are 0. Z is 0 or 1. y is preferably 1. A block or B block can be capped with small blocks (number average molecular weight of 50 to 10,000) of polymers of different compositions to compensate for any initiation due to unfavorable copolymerization rates or capping difficulties Effect, taper. These mono- and poly-diene polymers can be epoxidized so that they contain epoxide functionality of 0.1 to 7_0 meq, preferably 0.5 to 5 per gram of polymer meq epoxide functionality. The diblocks which fall within the above description are preferred. The total average molecular weight of these diblocks may range from 1500 to 150,000 g / mole, and more preferably from 3,000 to 7,000 g / mole. Any of the diblocks-blocks may contain some conventionally polymerized ethylenic aromatic hydrocarbons as described above. For example, 'When I represents isoprene, B represents butadiene, S represents styrene, and the slash (/) represents the case of a posterior copolymer. These two segments can have the following structure:- 9. &lt; Paper Size Appropriate Financial Standards (CNS) A4k (2ΐϋ7mm) (Please read the precautions on the back Qin-Pack-τ page) Order • 1. • — ^ 1 I- -1 SI ------ 473508 A7 B7

V. Description of the invention (I-B-OH B / I-B / S-OH I-S / EB-OH

I-B / S-OH B-B / S-OH I / S-EB-OH

I / S-B-OH I-EB-OH HO-I-S / B

II / B-OH or I-EB / S-OH or HO-IS / EB Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, where EB is hydrogenated butadiene, ·: £] 5 / 8_〇 11 means attaching a hydroxyl source to a phenethyl # repeating unit, and _s / EB_OH represents: attaching a hydroxyl source to a hydrogenated succinic acid repeating unit. In the latter case, -s / E B _ 〇η needs to use a small EB block to block the S / EB "random copolymer" block to compensate for the taper tendency of styrene before blocking with ethylene oxide. These diblocks are advantageous because they show lower viscosity and are easier to manufacture than the corresponding triblock polymers. It is preferable that the hydroxyl group be attached to the succinic acid block, because isoepisofluorene is used for the j-epoxidation, and the functionalities on the polymer are separated. However, if necessary, the radical may be attached to the isoprene difluorene block. This approach produces more surfactant-like molecules with a smaller loading capacity. Isoamidine can also be hydrogenated. It is also desirable that certain services be shared for use herein. Generally, these three segments include a stilbene block or randomly copolymerized styrene to increase the polymer's glass transition temperature, compatibility with polar materials, strength, and viscosity at room temperature. These triblocks include specific configurations in the τ row: I-EB / S-EB-OH IB / SB-OH IS-EB-OH ISB-OH or II / SI-OH ISI-OH BSB-OH BB / SB-OH Or IB / SI-OH I-EB / SI-OH or IBS-OH I-EB-S-OH HO-I-EB-S The paragraph is external) is expressed by the following formula:-• 10- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back first; € this page)

-Binding and ordering 473508 A7 P7 V. Description of the invention (8 (HO) xABS- (〇H) v Ί (II) where A, B, S, x and y are all as above. People and towns don't care about these people gathering; 5 The other two funnels are used to introduce the block with the degree of elongation of the locust locust to the mono-A polymer, which is particularly advantageous in many positions. Epoxidation of the basic polymer The effect can be carried out by reacting with an organic peracid (which can be preformed or formed in situ). Suitable preformed peracids include peracetic acid, performic acid, and perbenzoic acid. Zhou Jiu Fighter said that in situ formation can be used by Hydrogen peroxide and a low-molecular-weight fatty acid such as formic acid are implemented. These and other methods are described in more detail in the U.S. Patent. Another method can perform tungsten-catalyzed phase transfer epoxidation, such as JV Crivello and B. Yang Described in the Journal of Polymer Science, pt A, 33, ΐ88ι (1995). The amount of epoxidation of these polydifluorene polymers ranges from about 0.1 to about 7 milligrams per gram of polymer I. Equivalent epoxy gene (ethylene oxide oxygen). Low content to avoid over curing Above 7 meq / g, rigidity, cross-link density 'cost' difficulty in manufacturing, and the polarity of the epoxidation is such that the polymer does not provide any benefit. The preferred amount of epoxidation is about 0.5 to about 5 meq / g, and the optimal amount of epoxidation is about 10 to 3 meq / g. The optimal amount provides the best balance of UV curing rate against the excessive curing of the inch and the best maintenance and various formulation ingredients (generally together with Polydifluorene-based adhesives are used.) Compatibility. Before coupling, the unassembled linear fragments of linear polymers or polymers. For example, mono-, di-, tri-block, etc., star polymerization The molecular weight of the material arm is conveniently measured by gel permeation chromatography (GPC). In this case, the GPC system is properly calibrated. Regarding anionic polymerized linear polymers, the 11-this paper size is applicable to the Chinese National Standard ( CNS) A4 Specification Ul0X297 mm)-Packing-(Please read the note on the back page first) Order Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 473508 A7 B7 V. Description of the Invention (9 Polymer is basically monodisperse (Weight average molecular weight / Number average molecular weight ratio is close to unity), and it is convenient and fully illustrates the "peak peak" molecular weight of the narrow molecular weight distribution observed. Usually, the peak peak is between number average and weight average. The peak peak molecular weight is The molecular weight of the most abundant species shown on the chromatograph. Polydisperse polymers' number-average and weight-average molecular weights should be differentiated from the chromatograph and used. For materials to be used in GPC columns, phenethyl is usually used Associated with a basic gel or rare gel to produce excellent molecular weight selective fruit. Tetrahydrofuran is an excellent non-aqueous solvent suitable for the type of polymer described herein. A refractive index detector can be used. With regard to anionic polymers, it is often convenient to determine the number average molecular weight via end group analysis using NMR. If desired, these block copolymers can be partially hydrogenated. Hydrogenation can be selectively performed, as disclosed in U.S. Patent Reissue No. 27,145. Hydrogenation of these polymers and polymers can be performed by a variety of well-established methods including catalysts such as Raney Nickel, precious metals such as Platinum, etc.), a soluble transition metal catalyst and a catalyst as described in Qian Patent No. 5, No. 2). These polymers can have different diblocks and can selectively hydrogenate these diblocks, as described in U.S. Patent 5,229,4 =. Partially wood-saturated, basicized polymers are useful for printing by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs = "b-effect" and cause the epoxidized polymer family of the present invention to be more suitable for Epoxidation ❽.1 to 7-q 的 佳: For compounds. It should be understood that in this specific embodiment, the better is suitable for epoxidation ^ left on the polymer. In addition, ， In particular, the aliphatic double bond method of U to 3.0% has lower than what should be understood: if you want to use-an epoxidation method, the rate, the better total amount of aliphatic double bonds. ^ Paper size applies China-12- χ 297 mm) Α7 Β7 _ Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (the best amount of soil oxidized before the oxidation. Before the epoxidation, the difficult is : Hydrogenation of all remaining Moon Group A double bonds. Two IL-modified adhesives (viscosity, extremely advantageous is the inclusion of a low molecular weight poly "0 ηη Γ" in the composition. These monoalcohols have 2,000 to 2,000 Poly mol number average molecular weight and preferably used-one terminal 0H, 4% hydrogen Polybutadiene or polyisoλ is preferred (Early alcohol includes those having 2, GGG to 1 G, GGG g / mole range-^ amount, polydiene is typically from the number of 4 to 24 carbon atoms Derived from an ene monomer. It is preferably 4 to 2 carbon atoms, more preferably 4 to 6 carbon atoms, especially isoprene or butadiene. Regarding the coating composition, including- This kind of low molecular weight polydiene diol can be extremely advantageous in this group of mouth. This type: alcohols typically have a number average molecular weight within the same range as shown above with respect to the amount of knife-St-monohydric alcohol. The average number of several genes per molecule is typical, ranging from 16 to 24, preferably 1.8 to 2, 2 and more preferably 19 to 20. The composition of the present invention is typically purely irradiated with ultraviolet light or electrons. Ionization using various electromagnetic-wavelength radiation curing can also be performed with ionization # for example, x-rays and high-energy electricity: electrons_ such as ultraviolet light 'visible light' infrared light, microwave and radio frequency. ^ He can implement this The full description of exposure is contained in Lamex 5,229,464 as described in the examples of WO 96/11215, in order to provide effective Cured composition 'can combine a light side with a polymer and a post: -13- This paper is suitable for size_miscellaneous (210X297mm), — (Please read the precautions on the back page first) * 1Tm .-- -.II 1- «The resin is dispersed in a non-aqueous solvent. The method of the present invention achieves this without using a non-aqueous solvent. 'No solvent is needed because the photoinitiator is extremely compatible with the polymer blend and is exceptionally compatible. Soluble or spontaneous can be dispersed into polymer blends. According to the present invention, excellent cured films can be made without difficulty and without the cost of special processing techniques. Radiation-induced cationic curing can also be combined with free The substrate is cured. Free radical curing can be further enhanced by adding additional free radical photoinitiators and photosensitizers. The materials of the method of the present invention can be used for pressure-sensitive adhesives, sealants (including packaging adhesives, contact adhesives, laminating adhesives, weather-resistant adhesive tapes, adhesives for transferring and installing adhesive tape structures, automotive adhesives, And combined adhesives), coatings, inks, labels, and printed boards and films. In order to obtain a product with a suitable combination of properties (such as adhesion, cohesion, durability, low cost, etc.) suitable for a particular application, the formulator may have to combine various ingredients with the polymer of the present invention. In most of these applications. On the other hand, suitable formulations may also contain various resins, plasticizers, fillers, pigments, reactive diluents, oligomers, and polymers, non-aqueous surfactants' stabilizers, and other ingredients such as asphalt. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economics. The general application method is to add a resin that is compatible with the polymer to promote adhesion or tackiness, usually its amount is from 20 to 400 parts per hundred parts of polymer. A common tackifying resin is about 95%. (: Softening point of dipentadiene and 2-methyl_2-butene diene / fluorene copolymerization. This resin is commercially available 'its commercial name is Wingtaek 95, and its preparation is a cationic polymerization Mixture, which contains about 60% pentamethylene diamine, -14- This paper ruler Jiancai @ 国) A7 V. Description of invention (l2) Isoprene printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs' 5 〇 / 〇 Cyclopentadiene '15% 2-fluorenyl-2-butene and about 10% dimer, as described in US Patent No. 3,577,398. Other tackifying resins may be used, in which the resinous copolymer contains 20-80% by weight of pentadiene and 80-20% by weight of 2-methyl-2_butene. These tackifying resins typically have a ring and ball softening point of about 20 m5 (TC), as measured by ASTM (American Society for Testing and Materials) Method E28. Hydrogenated hydrocarbon resins are particularly useful. These hydrogenated resins Resins include those supplied by Hercules-various resins such as Regalrez 1018, 1085, 1094, U26 * ii39 & Regahte 91, 101, 125 and T140, Arkkawa P 70 supplied by Arakawa , P90, P115, P125 and similar other resins such as ES (i0rez resin series supplied by Εχχ〇η company. Wingtack, Han ^, ^, Arkon and Escorez are registered trademarks. Aromatic resins can also be used for adhesion Resin, but prerequisites are compatible with the formulation and the particular polymer used. Useful == tannin-indene resin, polystyrene resin, ethylfluorene toluene / α methylstyrene copolymer, and polyindene resin. ^ The optional components of the present invention are various stabilizers, which inhibit or retard thermal degradation, oxidation, surface layer formation and color formation. In order to protect the polymer from heat during the preparation, use and high-temperature storage of the composition Degradation and oxidation Type, adding stabilizers to commercially available compounds. Adhesives' 纟 ^ ¥ 疋 A thin layer of tackifying composition for use in a protected environment (with two substrates attached together). Therefore, the unsaturated epoxidized polyc »can have sufficient stability when it is in order to select the resin type and concentration for the most stomach-adhesive, and not care about oxidation or light stability, usually _ -15- The Zhang scale is applicable to the Chinese National Standard (cns) Jing ^ (2⑴X Tear (please read the precautions on the back first. Installation-^ this page) &lt; 11 Quan A7 Invention Description (13) B7 The Consumer Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs has strict printing and uses pigments. However, for high-performance adhesives, hydrogenated polymers can be used, often in combination with hydrogenated tackifying resins. , Tu Feng M 封 gap filler. So 'use it in a very thick layer to fill: the space between the materials. Because the two substrates often move between each other, so ^ ^ ^ sealant is able to resist this movement Low modulus composition. Because seals are often exposed to the weather The hydrogenated epoxidized polymer is usually used to provide sufficient stability to the environment. Resin chelating agents can be selected to more support low modulus and minimize "sticking" of dirt. Fillers and Produces appropriate durability and color. Since the sealant is applied to a fairly dry <layer ', its non-aqueous solvent content should be as low as possible to minimize shrinkage. • In the examples, several adhesion tests were used to show Properties of the test formulations using the method and composition of the present invention. The degree of covalent curing obtained with each adhesive sample was obtained by using a polymer developed by JR Eriksson (Erick called Radiation Curing Adhesives). The gel content test was measured. It was first described in June 1985. The footnote in the TAPPI 1985 Hot Melt Symposium was also "Experimental Thermoplastic Rubber for Strengthening Radiation Crosslinking Hot Melt PSA, s". Because the method used in the examples of the present invention is basically the same as the published method, except for the method of the first edition, except for a few small improvements and corrections. Self-polished stainless steel on 180. Peeling was measured using the pressure sensitive tape association method NO · i. Before performing the peel, a 30 or 60 minute residence time is used to ensure good wetting. When 'a piece of test tape was peeled from the substrate, the large number of puppets showed high strength. Coil viscosity (LT) is using TLMi coils. -16- Good paper size is applicable to Zhongguanjia Standard (CNS) Eight Butterfly ^ 7 ^ 21 ()) &lt; 297)) (Please read the notes on the back first

Installation-"write this page" Order spring 473508 A7 ------ B7 V. Description of the invention (14)

I &quot; born 4 &amp; machine to determine. Polken probbe Tack (PPT) is measured by ASTM D2979. The high numbers of lt and PPT show considerable stickiness.

Holding Power (HP) is at a fixed temperature, at 2. Under a standard load for resistance to peeling (pressure sensitive tape association method No. 7), from a standard test surface, the standard area of the tape (2.54 cm x 2.54 cm (1 ', χ1). Time required. Long time Shows high adhesion and cohesive strength. Except for the temperature at which the "break" occurred, the shear adhesion failure test (s Α ρ τ) is similar to -HP, and the S AF T is performed in an oven. The rate is 2.2 (40T) for 2 hours. The high temperature number shows high cohesion and adhesion strength. The polymer 1 used in the first example is a linear monohydroxydiene polymerization having a number average molecular weight of 550,000-% oxidation. The polymer is a dioxin polymer, in which the first block is composed of tritiated epoxidized polyisoprene, and the second block is hydrogenated polybutadiene. The block has a first hydroxyl end group. The number average molecular weight ratio between the second block and the first block is 2/1. The polymer has an epoxide functionality per gram of K 4 meq and 0.17 meq per gram. The polymer 2 has a number average molecular weight of 395.0 and a molecular weight of 0.25 meq / g. Linear monohydroxy diene polymer with functional group. Monool has a first hydroxyl end group. Use the compatibility discussed above to print the hair extension agent by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. It is attached to a CnH25 alkyl diaryliodonium hexafluoroantimonate. Adhesive is Regalrez 1085, a hydrogenated tackifier resin made by Hercules, including conventional amounts of the antioxidant Irgan. x 1010 °

Comparative Example A Unless previously mixed with tetrahydrofuran (THF), the previous adhesive, its 17- CNS) A4 size (210X297 mm) 473508 Μ B7 5. Description of the invention (15 series of polydioxane containing epoxidation Alcohol polymer, polybifluorene monoalcohol polymer, Regalrez 1085 tackifier resin and photoinitiator UVI-6974 (triarylphosphafluoroantimonate) will not be UV cured. Without THF, a fairly dense photoinitiator It may be phase separated in the adhesive and fall into the bottom of the container, where it can be easily seen by the naked eye. It is an insoluble bead-like material. Without effective u V curing, it is clearly visible through the lack of adhesive cohesion. Basically The adhesive is still a goo, and when attempting a finger adhesion test, the adhesive may simply be transferred to the finger. After UV exposure, this property is completely unacceptable. THF's comprehensible task It is a photoinitiator that dissolves the photoinitiator and evaporates after the application of the adhesive film, thereby leaving the light-dispersing agent finely dispersed in the dry adhesive film. Therefore, the film can be successfully UV cured. Alternatively, in the absence of non-aqueous solvents In the presence of this, the photoinitiator can be dispersed directly into the adhesive by using extremely high-shear mixing or sonication and then successfully cured. Example 1 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs according to the present invention υν Curable compositions, especially the pressure-sensitive adhesive (p SA) formulations shown in Table 丨 8, do not require non-aqueous solvents, and use simple low-shear mixing equipment to prepare thicknesses of 5 and 20 mm. PSA was identified at two film temperatures during the irradiation period and the solubility was measured at 93 ° C: (200 τ) T '96 hours. These identification treatments are described in Table 丨 B. Treatment A is the other three treatments of the control and It compares. -18-The standard for this paper (') Baenen (210X297 male 473508) Table 1 B-Processing Overview Processing AB ____----- 1 C ^ --- D _____ Film thickness, mm 5 20 --- ----- 5 5 _____— ^ During the irradiation, the film temperature, c 12 1 12 1 —----- 93 121 ______ 9 6 hours melting aging temperature, c 23 23 ______ 23 _ 93 L-- ^ A7 _________B7 V. Description of Invention (16) Table 1 AP SA Formula

Ingredients ~~ ----- 1% by weight .— Polymer 1 24.4 Polymer 2 25.4 Regalrez 1085 (Hercules) ___________ 49.8 ___ CD-1 〇1 2 (Sartomer) 0.25 ___ Irganox 1 0 1 0 (Ciba) ---------------- 〇) 5__J According to the formula in Table IA, use the following procedure to prepare the adhesive (400 g batch) 'Remove photoinitiator , CD-1.02, add all ingredients to a stainless steel beaker, and heat the calendar in a 1 3 5 Ό oven! hour. Remove the beaker and place on a hot and cold plate and mix the ingredients at a moderate rate using a 4-fin stirrer until the mixture is reduced to 93. Add a photoinitiator and use a hot plate. Continue mixing for 30 minutes while maintaining the temperature at 9 3 Ό. When examined under a microscope at a magnification of 500 ', p s a appears transparent in a bright field. Divide the hot PSA into two whole points. The first aliquot consists of 100 grams of 200 ml, high-form Pyrex glass beakers. The beaker was covered with a drop cap and placed in an air oven at 93 ° C for 96 hours. The rest of the steel beaker was covered with a lid and kept at room temperature for 96 hours. After 96 hours of aging, each full minute viscosity profile was obtained using a Bolin rheometer. -19- This paper size applies the Zhongguanjia Standard (CNS) A4 specification (21GX297). ~~-(Please read the precautions on the back page first) Ding-11 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 --------- B7 V. Invention Description (17) Using 93 C application temperature and a hand-controlled applicator, part of the room temperature and 93 C After the aging of the psa is divided into parts, it is casted into a Ø millimeter polyester film to produce an adhesive of about 5 or 20 millimeters. Two cast films were created for each of the four treatments (A-D). The test film was placed in a 93 ° C or ^ 丨 ^ oven for 2 minutes, removed and immediately irradiated using a Fusson laboratory coater operated with a &quot; H &quot; bulb. The irradiation is performed so that the adhesive faces incident light. The conveyor speed was selected (43 meters per minute) to produce a dose of 125 mJ / cm2, as measured on a Lightbug-radiometer. -With the exception of Treatment B, all samples are instantaneously cured to the touch. With the exception of the gel on B, all tests were started in the dark after the irradiated test film was aged at room temperature for about 24 hours: the gel content test on B was started about 48 hours after irradiation. The test specimens were removed from both castings to allow the test to be repeated. The actual cured film thickness was measured using a micrometer (for each—piece). All films were transparent before and after curing. Table ic shows the average radon obtained from each experiment. For average 〇 there is 95%. Confidence limit. The 95% confidence limit associated with mean radon is calculated using experimental errors associated with available test observations. -20- This paper size applies to Chinese national standards (CNS> A4 specifications (21 ×: 297 thin)

(Please read the Precautions on the back I-Install II ▼ Write this page) Order-i. Quan 473508 A7 B7 V. Invention Description (is) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs • 〇1 heart r? (J1 1 J g 〇hj- Μ U3 ω S 'Mob 〇J, h ^ &gt; s * cn 〇One: ¾ 彐 ^ ^ K) h • »_ &gt;-, + (_n 〇 〇 &lt; 〇23 ° C Holding power to steel, 6.45 cm2 (1 in ^) * 2 kg, hour from steel on 180. Peel., Nm (pli) TLMI loop Tack, N / m (oz / in) Polyken Probe Tack, kg 1 Adhesive cm polymer gel content% ^ j Thickness of adhesive film measured by curing test, mm. Treatment V &gt; 71 &gt; 143 ί &gt; 648 1 βδ3 (3.90) 780 (71.2.) Η- »UJ M (T \ CO CO o through curing &lt; Cn 〇 &gt; 1 I 1 1 1 1 1 (Ti 〇U1 cold gin surface curing H- *-«J OJ &gt; 71 &gt; 130 &gt; 648 # 1 77S (4.45 ) 905 (82.7) 〇KD Ln LO CO cr »〇〇 through curing. 〇〇 &gt; 71 &gt; 157 # J &gt; 648 # 1 1 753 (4.30) i 905 j (82.7) 1 i- * C〇. t »1 VN; CO 〇CO cn 〇through curing 〇1 D ro L0 MK) CO CD Cn ΓΟ Μ + 1 number of repetitions 1 H- 〇1 + heart t + 〇〇CO c.) 12.1) 1+ 〇N) 00 1+ 〇t M 〇H- t-1 cn 1 ι-ί ο Ν) Μ to the average 値 950 thickness only limit 诹 IC -PSA ^ &quot;, ^^ 很 _ (Please read the notes on the back first

(Install-horse page)

、 1T • i. This paper size is applicable to Chinese National Standard (CNS) A4 (2 丨 OX W7mm) 473508 • Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (19) Remarks: * This The confidence interval does not apply to process B. The cured layer on the film is floating on the uncured liquid layer ', making the micrometer measurement unreliable. ** The number of gels shown with respect to B represents the average value obtained from a surface layer including a cured surface and an uncured bottom layer. Because the uncured liquid adhesive 'treatment B film on the polyester interface uses the standard p S a performance test, it cannot be tested. 0 # One of the duplicates is a statistical isolate and is omitted. The mean confidence limit for a F T for processing D is ± 5 6. Obviously, treatment B is very different from the other three treatments. CD_1〇12 photoinitiator; too much or too low UV light intensity can not fully cure the 17.7 mm film. The top layer of the film is cured while the bottom layer remains uncured liquid. Because the solidified foot layer is "floating" on the liquid layer, no quantitative test should be performed except for the polymer gel content. The 60.5% gel content seen showed that the cured surface layer was approximately 12 mm thick 48 hours after the irradiation. The PSA formulation (Treatment 8) tested under control conditions produced excellent performance results. It has excellent gel formation, active adhesion, peeling, and honing powed SAFT. Had D has slightly better ball adhesion, treatment d (simulated at 93 ° C, only-kept in the box for 96 hours) also produced similarly excellent results. The viscosity profile shows that maintaining the uncured adhesive at 93 1%% hours causes a very small foot-induced thermal reaction because the 'viscosity only increases by about 50% compared to the adhesive maintained at room temperature. The data presented in this example show that: the mono-dimeric di- / di-dihydric alcohol of epoxidation induced by UV curing using CD_ i 〇i 2 light is ^ • 22- Please read the notes on the back of this book first.) Dingquan 473508 A7 B7 5. Description of the invention (20) In the adhesive, excellent PSA properties can be obtained. The CD_1〇12 photoinitiator is easy to be incorporated into the formulation. Gu easy to cure 5mm film, but it is difficult to cure thicker film. During irradiation, curing at a film temperature of 93 ° C results in the same performance as that caused by higher temperatures. It is expected that lower film temperatures will also work well. The melt stability at ‘93 ° C is good, indicating that there is no problem with the pot life of the adhesive in the storage tank of the production unit operating at this temperature. Curing and film properties are not affected by this treatment. Xianxin 931 is more commercially used-it is required. For high temperature. If the adhesive is at 40. It can be applied at a temperature within 80 ° C using a commercial coater. If necessary, the film temperature can be raised to 93 ° F by standing it before irradiation even if it is passed through a heat roller. Alternatively, heating may be achieved by other methods', such as by using an infrared heater. Example 2 PSA's £, F'G, Η and 1 (Table 2A) are examples of the present invention. They were also prepared using a simple stirrer. : PSA's J, K, and L are not examples of the present invention and were prepared using a B r an s ο η 4 50 sonic generator. Except for its number average molecular weight of 6070 and its epoxide functionality of 1.6 meq per gram, Polymer 3 (in Table 2A) was the same as Hair Compound 1. Except for its number average molecular weight of 3900, polymer 4 (in Table 2A) was the same as polymer 2. (Please read the note on the back page first) • Packing. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs -23- This paper size applies to the Chinese National Standard (CMS) A4 specification (210X297 mm) 0853 A7B7 Central Ministry of Economic Affairs Printed by Standards Bureau's Consumer Cooperative

21) UVI-697 4 outside 50% fi &gt; cv &gt; if‘a-50% ^ life ^ 50% off the smoke # 3cognition 4 '&gt; &amp; 糸

Μ Ο C0 Art &gt; 匁 L &lt; 卬 t-_. Ω Φ 0) Li) lQ Μ ㈡ o vQ &gt; pj PJ 〇 tX3 o pj 〇0 »f 〇 Ui rt M a M _sai oct U) Φ H · # vlo X Μ ON Φ ft (X) η i'j K〇fD ϋ Ln 〇〇q \ eo M 匁 κ »&lt; η LH CO 〇VD-, /-&gt;. 〇 Μ 1 〇μ -»O 00 Cn H * Book 3 〇Α KD Μ -J Lengyi VD W Ο 1 l · -1 1 1 1 CO KD (T \ 〇-J vl ^ k '&gt; -Q V-1 \ D KO 〇 I Η1 1 1 CO 1 KD VD CTt 〇-J Heart vt ^ \ D VD KO 〇1 1 GO 1 1 \ D VD 〇Ί 〇 ~] Heart i-1 VD U) VD 〇1 00 1 i 1 VD, D CT »Ο, heart νί ^ H-1 KO ID 〇σ \ 1 〇CO 1 1 1» V 1 ΚΏ heart KΩ heart it \ D VD \ D 〇Μ I 1 i I 1 CO VD KO σ »〇-J heart heart t- * VD VD VD 〇 &lt; Ti Ν) 〇1 1 1 1 03 -J 1 VD heart \ D heart l ·-*-VJD 〇Ν) 1 00 1 1 I 1 VD L— σ »〇-J -24- This paper size applies to China National Standard (CNS) A4 (210X297 mm) • li 1 i« 1 1 --- · (Please read the notes on the back first ^ 2A- ^ ^^^ ° ^^ --Equipment-- .Item K) -n -Order ...... 1 11 I ·. M 473508 A7 B7 .Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (22) Except for the CD-1 〇12 photoinitiator, weigh all components of the adhesives E, F, G, Η and I into a quartz jar, and heat each jar in an oven at 149 ° C for about 1 hour. Remove each jar, stir by hand, and return to the oven for another 1/2 hour. Immediately after the last removal from the oven, each part of the formulation was mixed using a laboratory stirrer equipped with impeller blades until the temperature was cooled to about 93 ° F. This mixing step transforms the crude polymer / tackifier resin mixture into a liquid 'homogeneous mixture. Add half of the required CD-120, and slowly stir each wound formulation for approximately 5 minutes until Cd-120 is dissolved. Add the remaining required CD-1012 and stir the complete formulation for another 30 minutes while maintaining the temperature at 88. 〇 and 99t. Four hundred grams were cooled in batches to room temperature 'and covered with a lid and used within one week. To prepare 400 g, batches of adhesives j, κ and L, the following steps were followed. 50 grams of polymer 4, 5 WT% UVI-6974 photoinitiator precursor mixture, prepared by weighing 2.5 grams of UVI-6974 and 47.5 grams of polymer 4 into a bottle only, in an oven at 121 ° C Heat for 30 minutes, mix by hand, and finally use the Branson 450 ultrasonic generator for ultrasonic processing for one minute between the two factories. "A cooling time of about 2 minutes is attached between each period. Weigh adhesives J, K, and L, less photoinitiator and some polymer 4 into a quartz jar, and heat each jar in a 149 «C oven for about 1 hour. Each jar was then removed, stirred by hand and returned to the oven for another 1/2 hour. After the final removal in the self-baking, each part of the formulation was mixed using a laboratory stirrer equipped with impeller blades until the temperature was cooled to about 93. 〇. Then 40 grams of the photoinitiator precursor mixture was added, and stirring was continued for another 30 minutes while maintaining the batch temperature at 88 ° F and 104 °. (: Between. When the mixing is completed, apply -25- this paper size to the Chinese National Standard (CNS) A4 specifications (210X2975 ^ -------- (Please read the precautions on the back of Thai-Pack-P this first) page)

、 1T -1. B7 V. Description of the invention (23) Each batch is placed in an 121 C oven to keep the materials extremely flowing. One by one, pour 3 grams each into bottles, ultrasonically process them for 15 hours, and then transfer them to a clean tank that collects all the whole points for that particular batch. Ultrasonic processing was performed using a Brans On 45 sonic generator operating in continuous mode. So that the energy density is about 2.8 watts per milliliter of the binder, use a laboratory mixer to stir the collected material for another minute. The batches were cooled to room temperature, covered with a lid and used within one week. Glue wjE-L was applied to a Akrosil SBL80c suOx Η · thermoset release 砚 using a chem Instruments HLCL-1000 埶 melt coater and gluer to a thickness of 5 mm. The required application temperature is 49 ° C. Each film sample was warmed in a preheated oven for 2 minutes, then taken out, and then simultaneously used by heat-with the work unit 2 carried by Eye UV PL_1T curing unit 2 for immediate curing. Excluding psA, the UV dose is 180 mJ / cm, which requires a dose of 400 mJ / cm2. The dose was calibrated to :: 疋 by using a hand-held dosimeter supplied from £ 1, $ 1, $ 1, $ 1, $ 1, $ 1, and $ 1, which was supplied by 、 糸 外 光 &amp; 3 households. After curing ', the adhesive was laminated to Pilcher H-2 untreated polyacetate film and allowed to age at room temperature for 5 to 15 days before testing. Test Book-Inventive Adhesives E, F, G, compared with the Ministry of Adhesive Economy t Standard: Ά X Consumer News Agency Printing: K and L (j 〖and B need ultrasonic treatment to disperse photo-induced M) 'Two Solvent-based acrylic adhesive and two commercial transfer tapes. Commercial transfer tapes are two-layer acid tapes made by self-winding on a release liner. These tapes are made of solvent-based acrylic coatings, dried and cured. In order to test commercial tapes, the grades are laminated to 2 mm untreated. -26 473508 A7 B7 This paper is a national standard. V. Description of the invention (24) The test results shown in Table 2B show that: Adhesives E, F, G, Gadolinium, and I produce properties as good as those produced by ultrasonic processing methods, or propionic acid-based adhesives, or commercial transfer tape adhesives. (Please read the caution page on the back first) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs -27- This paper is again applicable to China National Standard (CNS) Α4 specifications (210 × 297 mm) 473508

7 7 AB V. Description of the invention (25) 23 ° C for stainless steel printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Holding power ι 6.45 cm2 (1 in2) * 2 kg, hourly peeled from high-density polyethylene, 180 ° peeled 180 ° peel from polycarbonate 180 ° peel from glass 180 ° peel from glass 180 ° peel from stainless steel 180 ° peel Tack, kg Loop tack, N / m (pli) polymer gel content. / 〇 Film temperature during irradiation. c PSA &gt; 112 μ σ \ σ, σ \ cn M a \ I 1085 (6.2) y〇cn Ln &gt; 112 '1 Μ ch Office eo VD 〇1 · -1 .c ^ N) • 94 5 (5.4 ) κο OJ VO U) Q &gt; 112 Κ) Μ 〇ι Ui v £ ^ M CO l ·-· 'Office U) 910 Ϊ5.2) CO must CO o &gt; 100 〇Μ &lt; _π 00 Η1 〇L 〇N) o `` X) 630, (3.6) CO CO a OJ f-* c \ CO υι cn l ·-· σ »heart 473 (2.7) KO Ca M &gt; 112 K) (J1 vt» ·. fc. j- »N &gt; | 1155 i (6.6) VD u &gt; CO 1 &gt; 112 丨 M CO ο M ^ ch 1015 (5.8) ① CO &gt; 112 OJ M 〇u &gt; 〇l .fc»-· » CO v K) -J 4 33 (2.5) VD \ .D GO L— &gt; 113 Ξ σ \ Μ cn -J H- * 00 M o \ 788 (4,5) 1 1 Acrylic 1 &gt; 113 1 o (Tϊ U) c_n K) IP M OJ 1 998 (5.7) 1 1 Acrylic 2 &gt; 112 o (Jl Office ho Ui CO l ·-»〇Cn 2) I 1 Com, tape 1 丨 &gt; 112 1 1 o ro (_Π Office σ \ cn (_n 〇M U &gt; CO 368. (2.1) 1 r Com. tape 2 -28- r 清 s 之; i intend to write this page)

-I. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 473508

A

7 B V. Description of the invention (26 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs • S3 Μ * &lt; 1 §5 π 牦 i 桊. K) Ξ · v〇 '.: 〇 -§ σ-1: + 3. co CTQ \ ^ ^ 〇 V to .〇V Ι- * ο ο V κ &gt; ο heart V Μ 〇〇〇 * V Κ) ο heart V Μ .〇〇 ro 2 V Μ Ο 〇 — 〇Κ) 1 V [\ &gt; ο Office V Μ Ο Ο V (Ό ο Office V Η ~ * Ο * Ο 1 1 U) AV Μ Ο Ο Μ Office υ »U) V Ν) Ο .r ^ 1 V ro ο Office V -SV h〇ο V »-* 〇. 洳 2BS) (Please read the note on the back to write this page first),-= '° * | —HI— n ^ — · -29- This paper size applies to Chinese national standards (CNS) A4 specification (210X 297 mm) 473508 A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (27) Example 3 A simple coating formulation prepared by warming 〇〇〇〇〇 Mixture of polymer 3 and 0.2 5 g of CD-1 0 1 2 photoinitiator and at about 9 3 ° F, using a medium-speed laboratory: the mixer is mixed for 30 minutes. Pour a portion of the coating into a petri dish to produce a 20 mm film. The film was warmed back to 93 C, and then immediately irradiated with a dose of 250 m J / cm 2 output from a bulb via a Fusi ο η laboratory processor, within 5 minutes. The film was detected using thin wood strips and found to be completely cured to produce a solid coating film. The other part of the coating was poured into another petrol m to produce a liquid coating of 50 cm. It was heated and irradiated with a dose of 500 mJ / cm2. It is also fully cured immediately to produce a solid coating or thin layer. '' Example 4 A simple coating, printing plate or fiber formulation prepared by warming 60.2 grams of polymer 3; 39.8 grams of polymer 5 and 0.25 grams of CD-1012 photoinitiator at about 93 ° C , Using a medium speed laboratory mixer for 30 minutes. Polymer 5 is a hydrogenated polybutadiene diol polymer having a number average molecular weight of 3,530 and a laminar functionality of 0.53 meq per gram. The hydroxyl group is first, and the terminal is positioned at each terminal of the polymer. A portion of the coating was poured into a petri dish to produce a 20 mm film. The membrane was returned to 93 ° C and then immediately irradiated with a dose of 250 mJ / cm2 of the output of a single ΜΗM bulb via a Fusion laboratory processor. Within 5 minutes, the film was probed with a thin strip of wood. It was found that it was completely cured to produce a solid coating film. Pour the other part of the paint into another accompany to produce a 50 cm liquid paint. It was heated and irradiated with a dose of 500 mJ / cm2. -30- The size of this paper is applicable to Chinese National Standard (CNS) A4 (210X297mm) (Please read the precautions on the back first &lt; ▼ Loading-write this page)

* 1T Ί. 473508 A7 B7 V. Description of the invention (28) It will also be completely solidified immediately to produce a solid material. Example 5 The pressure-sensitive adhesives shown in Table 5A were prepared via simple & early mixing according to Example &amp; These adhesives use epoxidized polymer monoalcohol polymer 4 with different relative ratios, and use several kinds of adhesives.

Regalite 91. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

B7 V. Description of Invention (29) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

Irganox 1010 SarCat CD-1012 Regalite 91 polymer 4. i polymer 3 〇f- »〇, 〇r \) U) kD 03 core U) 〇Cn Μ N3 '-J RR1 wt. 〇h-1 Cn 〇M Cn CO 〇U) 〇CO 00 〆00 VO [Ό RR2 〇M Ln o K) cn 〇l \ D cn M heart 〇f-1 σι heart RR3: 〇l · -1 Cji 〇K) cn U) KD CO M U3 00 00 K) KD CO CO RR4 o Bu J 0.25, 'j 〇i -j t- *' VO KD K) M KO M RR5 〇 «M CH 〇N3 cn U) VO CO ΓΌ K) -J u &gt; 〇Cn I RR6 〇cn 〇K) cn VD 00 f-1 CO VO K) CO 〇00 00 RR7 〇H-1 〇1 o CO Ln (J1 KD (Tt Cn h- * K) -0 RR8- . ------------ Equipment ------ Order {Please read the notes on the back first to write this page) _

This paper size applies to China National Standard (CNS) A4 specification (210X297). 473508 A7 —_________ B7____ V. Description of the invention (30) Apply the adhesive RR-1 to a Chem Instruments HLCL-1000 hot melt coating Applicators and gluers were coated on Akr0Sil SBL80SC Silox FIU / 0 heat-curing release liners to a thickness of 5 mm. The required application temperature is 49 ° C. Samples of each film were warmed in an oven at 50-C for 2 minutes, and then UV-cured immediately using a benchtop UV curing unit pl-1 made by Eye UV. The UV dose was 1 80 mJ / cm2. The dose was determined by calibration using the EIT-U VIM AP handheld dosimeter supplied by Eye Ultraviolet. After curing, each adhesive was laminated to Pilcher Hamilton 2 mm untreated polyester film and allowed to age at room temperature for 5 to 15 days before testing. _______ All adhesives show excellent curing and PSA properties as shown in Tables 5B and 5C. (Please read the precautions on the back of the page i ▼ Install-| Write this page) Order -i- Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-33- This paper size applies to Chinese National Standard (CNS) A4 specifications (210X297 (Mm) 473508 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China 5/3 Λ 3 / — \ 明明 发 6.45 c1 -'- h1-) + 500%, &quot; 0t ^^ 绿 医 ~ 95dhoiding power, 6.4 ^ 032 (ΜΗ · 32) * 500 g, 2 4 ^ 3 ^-^ 23dholding. Power? 6.45 cmM (1-1Η · 32) * Μ kg, a,. 7 7. £ 3-¾ ^ ¾¾ ^ ¾¾¾¾ AB -H--I ------ Wins 舯 啩 蛑 翔 pberry_L1S0. -# tl 鲜 宋 &quot; l °° p &quot;# iJq ^-. L ISO. -#

Probelrfl0, cx, lyrg

Loop tzacx, M / m (pii) (Please read the notes on the back-r this page)

1 2〇4 192 15 9: V 2〇4 153 &gt; 2〇4 &gt; 2〇4

&gt; 2CM &gt; 16〇 V 114

3.6 2 · 9 3.5 PS6 823 (4.7) FIR1 &gt; 16〇 47.7

31 12〇8 (6.9) 9〇 ρ '&quot; 2 orders &gt; 16〇 96 · 6

i 9 Ί, -6 1.61 1663 (9.5: 82

Pil3 ΪΊ. V 16〇 V 114

〇 7 4 735 (4,2) 92 V 160 &gt; 16〇 &gt; 160 &gt; 16〇 114 &gt; 15〇 &gt; 16〇 &gt; 16〇

-34- This paper size is in accordance with Chinese National Standard (CNS) A4 (21 × 297 mm) 2 · 6, 2.6 2.5 4.6 4: 5 1 62 133〇 (7.6) 95

Rs 〇 62 6S (3.9)

Ril6 1.33 1103 (6.3) 96 1. 58 5 ^ 5 (3.4) c 98

Fms 473508

A

7 B 2 3 / __ \ Explanation of five sounds ^ 杂 1-^^^^^^^^? 6 _ 45 cmMi 1 ir-) * 50〇ί5, -h; 摩 ^ 漆 1- ^ 95dholding power '' 6.45 c1-inM) * 500 gram, 2 'special motorcycle lacquer 1 ^-23 dholding power, 6 · 45 c- (l i1-) ★ 2 .. kg, two, Zhong Miao 蝌 ^ ^ berry &quot; 1 °° 0. -Fei | J 郑 粦 髁 -l · ISO. | _ 一 檗 Ban Zheng-19 ^ and Berry Hot &&;-ISO. -# probertacx, kg

Loop &quot; tack, N / m (PI1 ') V 2C4 V 112 V 118 〇 · 1.4 3 · .〇2.2 〇.77 525 (3_〇) 83 &gt; · 2〇4 20〇 &gt; 112 &gt; 112 V 118 1 · 3 4 · 2 3, 0,79 S75 (5.0) 87 &gt; 118 3.1 6.3 ο 6.5 ο 6.4 o • 1 c • 13 1138 (6,5) 71

Rs is jealous of 5C-1.5! -Life check〆 PSA + i ^ (Please read the notes on the back to write this page) &gt; 204 &gt; 16〇V 118 2 · 3 2.2 2.3 P51 438 (2.5) 84 RR.4 &gt; 2C4 &gt; 16〇 V 114 1 · 〇6 · S ο 2.1c 6.1 P76 245 (1.4) 87 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs &gt; 204 &gt; 2〇4 V 2〇4 &gt; 16〇 &gt; 114 〇 · 1 • 2 2 · 3 • 6 2.1

Ob 5〇8 -.9) 95 R.H6 V 16〇 V 16〇 &gt; 114 1 · 〇 3 · 3. 3.5

P5S 893 (5.1) 87 &gt; 114 57

94 This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) 473508 A7B7 V. Description of the invention (33 Example 6 The preparation of the pressure-sensitive adhesive shown in Table 6A is based on the example method 'Simply mix. These adhesives use epoxidized polymers.' The different relative ratios of Monool Polymer 4 and the use of several levels of tackifier resin

Arkon P90-Table 6 A Pressure Sensing Load: Adhesive (Please read the precautions on the back ▲: -I 1---· ΛP1 wt.% AP2 polymer 3, 22.71 18.92 polymer 4 37.05 33.08 Aukοη Γ90 39.84 ^ 9.00 SarCat: CD-1012 0.25 0.25 Irganox 1010 0.15 0.15 ΛΡ3 15 14 2Ί 70 59 76 0 25 ϋ 15 4 2 ^ 2 n ΛΡ5 ΑΓΰ ΑΡ7 ΛΡ8 19.92 37.05 30.88 24.70 19.92 22.7 丄 18.92 15.14 59.76 39.04 49.8 59.76 0.25 0.25 0.25 0 0.15 0.15 0.15 0.15 Packing 丨 | ^ This K) is printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs * i 36- This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 473508 A7 ___B7 Description of the invention (34) The adhesive API to APM is coated with a Chein Instruments hLCL_ 丨 000 hot melt applicator and gluer on the milk from SBL 80SC SiloxFIU / O heat-curing release liner up to 5 mm thickness. The required application temperature is 4 9 ° C. Samples of each film were placed at 50 ° C. 〇The next oven was heated for 2 minutes at medium temperature, and then a p l _! Portable benchtop UV curing unit made by Ey e UV Co. was used for immediate UV curing. The UV dose was 180 mJ / cm2. After curing, each adhesive was laminated to a Pilcher-Hamilton 2 mm untreated polyester film and allowed to age at room temperature for 5 to 15 days before testing. All the adhesives showed excellent curing and PSA properties as shown in Table 6B. (Please read the note on the back to win the installation first-this page) Order the printed mouth of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs i 37 This paper size applies to the Chinese National Standard (CNS) A4 specification UI0X297 mm) _---- -Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 8ο 5 3 A7B7 V. Description of Invention (35

cn ^ 1/1 溧 〇 invite μ note Η-th · 〇 broken: 〇 ^ ιΏ two X ΧΧ3 life υ, 溆 Wh- 〇 S Β ν〇-ο. Μ = r Η- 2- &amp; ^! 3 ； 0Q 'Ό 屮 Ο name οι ο S di-term * σ \ i ^ · ^ 绿 ο window 3 to ^ υ3 «Λ Ο Μ: τ Η · ° 3 &amp; ΓΟ 3 —-OQ; &quot;Ο; 彳 Ο Κ) Οι 2m, m-3 porphyrin, Berry W-►— * g 1 23h 嵙 W 1— * 00 〇〇3 »·}« &gt; 1 • E &gt; -¾, w &gt; .-¾ acv h-1— »00 .oo m- 綷 ύ κ-* — * g ί Ε &gt; 卜卜 Μ- &gt; g 0 iin) 〇cr a &gt; rt bait 7T t'1 O 〇Ό rt- fu O 2 \ B}-* H- 丨 咿 '〇V • JP V Γ〇 〇V Μ Η- »CO Γν〇 卜 j 1M C0 K &gt; CO core ω 〇〇〇U) 〇CO ΓΌ 1 Λ CO 00 C0 CO &gt; fa M Μ ΓΟ V Μ Μ KD ω ΓΟ --J &lt; f \ Ο 'cn -J Ol 0 &gt; M ω 〇 ^ »-». Heart CO CO Ch &gt; ro Μ ω σ »V Η Μ Κ) V Μ Η CO (J1 ~ Ϊ m CO -〇〇- ^ J K0 Office V h 0, Xin Yi \ D (Jl ^ .Cn Xin n CO cn (j〇V Γ〇 〇V Μ Μ Μ V Μ Η C0 〇- J (Λ ·) ο CO ro Κϊ -〇 fO CO 〇 .— ^ U &lt; τ »00 ΚΌ 心 &gt; ^ T) Μ cn CO V l · -1 Μ ΓΟ V Η \-* 00 f '' 〇-j to -J CO Μ C-Π-, J 〇H * MM CTi &lt; _n 〇VD cn &gt; yv Ln \ V Ν &gt; 〇V Η Μ ΓΟ V Κ * Bu, 00 〇 heart t ho 1 KO Ni σ »Ν) ΓΟ ro (T \ 〇σ \ CTi-» Ό, L · »H 4 00 t- &gt; KD σ \ &gt; &gt; 0 c \ V ΪΌ 〇 Center V Κ &gt; Μ ro V Η * Η C0 κ &gt; M 0J Center σ \ Η1 〇- σ \ '-J N3 KD, J &gt; Ό • o Μ νο 0J V Η Μ Μ Μ .V l ·-* C0 〇Cn cn ώ J -J Ul CJ 〇0J ro -— ^ oo, 0 ω &gt; CO 8 3 (Please read the precautions on the back fc 丨-* item page) Order il 噱! -.......- Rule paper A 'Ns c Standard I Standard-Home Country-Country I Used X Applicable X ο I mm 473508 Table 7-Pressure Sensitive Adhesive Ingredients- -Weight 0Λ Polymer 3 (epoxidized polymer) 19.72 Polymer 5 (mono-alcohol polymer) 25.10 Regalite 91 54.78 SarCat CD-1012 0.2 5 Irganonox 1010 0.15 Put PLI adhesive on the neck and use To cure one with Eye UV: Pack-A7 __B7_ V. Description of the Invention (36) Example 7 PSA formulation PL1 was created using a stirrer method. The company's portable unit 'was continuously coated and UV cured on an experimental applicator line. At 80 ° C, the adhesive was applied to the Akrosil SBL80SSC release profile at a line speed of 9.144 m / min (30 ft / min) and irradiated with a dose of 250 mJ / cm2. A 2 mm corona-treated polyester film was then continuously laminated to the UV cured adhesive, and the laminate was rewinded and stored at room temperature. One part of the adhesive laminate was coated with 5.0 mm of PLI, and the second part was coated with 1.5 mm. One week after coating, various properties of the adhesive were tested. (Please read the note on the back first to write this page), 1r Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs-39- This paper size is applicable to China National Standard (CNS) A4 (2 丨 〇 乂 297 mm) 473508 A7 B7 V. Description of the invention (37 Test: Polymer gel content

Loop tack, N / m (pli) Probe tack, kg Stainless steel stripped to 180 ° on stainless steel 23ϋ_ holding power, 6.45 cm2 (1 kg, hours &gt; 720 to stainless steel 95 ° C'holding power, 6.45 cm2 (1 ❸ 500 g, hour male cut adhesion failure temperature, 6.45 cm2 (1 in2) * _ g, hour one after 4 months of coating 'test 5 millimeters ^: 2: peeling' including the difficulty of bonding thermoplastic polyfluorene. Since The results of this sticky transfer are shown in Table 7C. ^ 7C ~ 18 0 Base material Polymethylmethacrylate Polypropylene Density frame ethylene (Please read the precautions on the back page first} Polycarbonate glass printed by the Consumer Cooperatives of the Ministry of Standards of the People's Republic of China ^ 4 5 (5.4) (5.5) ^ 49 0 (2.8) ^ 63 (5.5) 893 (5.1)

-40- This paper size applies to China National Standard (CNS) A4 (210X297 mm)

Claims (1)

% ii:,; 473508 Patent Application No. 86108M2 Patent Application Amendment (90 years 丨 0 and) A8 B8 C8 VI. Application Scope 丨 Official MrM 1. A uy curing composition comprising a An epoxidized polydipolymer and a photoinitiator based on a radical, the initiator is selected from the group consisting of a diaryl halide salt having the general formula (I):, 〇 ~ Y ~ Cn H2n + 1 Where χ is a complex metal halide anion or a complex proton acid complex halide anion; Y is 〇 I ——CR2—C—— or Wherein R is a hydrogen'aryl group, an alkyl group, or a carbohydrate; z is iodine, bromine, or gas; η is an integer of at least 1; and the monohydroxylated epoxidized polydiene polymer contains at least two A polymerized ethylenically unsaturated hydrocarbon monomer, at least one of which is a difluorene monomer that produces unsaturated bonds suitable for epoxidation, and wherein the polymer contains 0.1 to 7.0 milliequivalents of epoxy groups per gram of polymer . 2. The UV curing composition according to item 1 of the application, wherein Z in the formula (j) is Qi. 3. The UV-curable composition according to item 1 or 2 of the scope of patent application, wherein Υ in formula (I) is? Η -CH2- (j: — 纸张 This paper size is suitable for national standards (CNS) Α4 specifications (21Q χ 297 public love) • The u V curing composition according to claim 1 or claim 2, wherein X in formula (1) is SbF6-. 5 'The UV-curable composition according to item 1 or 2 of the scope of the patent application, wherein η in formula (1) is an integer ranging from 5 to 20. 6. The UV-curable composition according to item 1 of the patent application scope, wherein the mono-epoxidized epoxidized polymer has the following formula (H0) rA-SZ-B- (OH) y or (HO) xABS- (〇H) y where A and B 疋 polymer fungible segments, which can be homopolymer blocks of copolymer monomers, copolymer blocks of conjugated diene monomers or copolymer monomers and A copolymer block of a fluorenyl aromatic hydrocarbon monomer, s is an alkenyl aromatic hydrocarbon block, χ or y is 1, the other is 0, and Z is 0 or 1. 7. The UV curing composition according to item 1 or 2 of the scope of patent application, which is used as a sealant or adhesive composition, and additionally contains a tackifier resin compatible with a photoinitiator. 8. The UV curing composition according to item 7 of the patent application scope, further comprising a polydiol. 9. The curing composition according to item 1 or 2 of the scope of the patent application, which is used as a coating composition, which additionally contains fillers, pigments, and / or stabilizers. A method of curing a composition according to item u, which comprises mixing a photoinitiator of formula (1), a monohydroxylated epoxidized polydimer polymer and any other ingredients in the absence of a non-aqueous solvent. -2- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 473508 8 8 8 8 A Be D 6. Application for patent scope 11. A UV-cured composition borrowed in the presence of UV light source It is obtained by curing from a UV-curable composition according to any one of claims 1 or 2 of the scope of patent application. 12. UV-cured composition according to item 11 of the patent application, which is used in articles. This paper size applies to China National Standard (CNS) A4 (210X 297 mm)