TW471136B - Manufacturing method for MOS transistor of embedded memory - Google Patents

Manufacturing method for MOS transistor of embedded memory Download PDF

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Publication number
TW471136B
TW471136B TW90101311A TW90101311A TW471136B TW 471136 B TW471136 B TW 471136B TW 90101311 A TW90101311 A TW 90101311A TW 90101311 A TW90101311 A TW 90101311A TW 471136 B TW471136 B TW 471136B
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Taiwan
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layer
peripheral circuit
semiconductor wafer
memory array
silicon
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TW90101311A
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Chinese (zh)
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Sun-Chieh Chien
Chien-Li Kuo
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United Microelectronics Corp
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Abstract

The present invention provides a manufacturing method for MOS transistor of embedded memory, which includes the following steps: sequentially forming a first dielectric layer and an undoped polysilicon layer on the surface of the semiconductor chip with a memory area region and a periphery circuit region defined; then, doping the undoped polysilicon layer on the memory array region and forming a passivation layer on the surface of the semiconductor chip; conducting a first photolithography and etching process (PEP) to etch the passivation layer and the doped polysilicon layer on the memory array region for forming a plurality of gates; forming the lightly doped drain (LDD) around each of the gates; forming a silicon nitride layer and a second dielectric layer on the surface of the semiconductor chip; removing the second dielectric layer, the silicon nitride layer and the passivation layer on the periphery circuit region; finally, conducting a second PEP to etch the undoped polysilicon layer on the periphery circuit region for forming a plurality of gates; then, forming the LDD, the spacer, and the source/drain (S/D) of each of the MOS transistors in the periphery circuit region.

Description

471136 五、發明說明(1) 發明之領域 本發明提供一種嵌入式記憶體之MOS電晶體的製作方 法。 背景說明 隨著製程積集度的不斷提昇,現今製作半導體積體電 路的趨勢是將記憶元陣列(m e m 〇 r y c e 1 1 a r r a y )與高速邏 輯電路元件(high- speed logic circuit elements)進行 整合,同時製作在一個晶片(chip)上,形成一種同時結合 了記憶體陣列以及邏輯電路(1 〇 g i c c i r c u i t s )的德:入式記 憶體,以大幅節省面積並加快訊號的處理速度。 請參閱圖一至圖八,圖一至圖八為習知於一半導體晶 片1 0上製作嵌入式記憶體之M0S電晶體的方法示意圖。半 導體晶片10包含有一石夕基底(silicon substrate)16,且 矽基底1 6的表面上已經預先定義出一記憶陣列區1 2以及一 週邊電路區1 4。其中記憶陣列區1 2中另包含一單胞井 (cell-well)18,而週邊電路區14中亦分別包含有一 P型井 (P-wel 1 )20以及一 N型井(N-wel 1 )22,且各區域以複數個 淺溝隔離11加以分隔。 如圖一所示,習知製作嵌入式記憶體之M0S電晶體的471136 V. Description of the invention (1) Field of the invention The present invention provides a method for manufacturing a MOS transistor with embedded memory. Background Description With the continuous increase of process integration, the current trend of making semiconductor integrated circuits is to integrate memory cell arrays (mem ryce 1 1 array) and high-speed logic circuit elements. It is fabricated on a chip to form a kind of German-type memory that combines a memory array and logic circuits (10giccircuits) at the same time, so as to greatly save area and speed up signal processing. Please refer to FIG. 1 to FIG. 8. FIG. 1 to FIG. 8 are schematic diagrams of a conventional method for fabricating a MOS transistor of an embedded memory on a semiconductor wafer 10. The semiconductor wafer 10 includes a silicon substrate 16, and a memory array region 12 and a peripheral circuit region 14 have been previously defined on the surface of the silicon substrate 16. The memory array area 12 further includes a cell-well 18, and the peripheral circuit area 14 also includes a P-well 1 and an N-wel 1 ) 22, and each area is separated by a plurality of shallow trench isolations 11. As shown in Figure 1, it is known to make M0S transistors of embedded memory.

471136 五、發明說明(2) 方法是先以熱氧化法於該矽基底1 6表面形成一矽氧層,用 來當作各MOS電晶體的閘極氧化層24,接著於閘極氧化層 2 4表面依序形成一未摻雜多晶石夕(undoped polysilicon) 層2 6以及一絕緣(i n s u 1 a t i ο η )層2 8。然後如圖二所示,於 週邊電路區14上方形成一光阻層30當作罩幕(hard mask),並利用一黃光暨蝕刻製程(PEP)來蝕刻記憶陣列區 1 2上方之絕緣層2 8以及未摻雜多晶矽層2 6,直至閘極氧化 層2 4的表面。 在完全去除掉光阻層3 0之後,接著如圖三所示,於半 導體晶片1 0表面依序形成一摻雜多晶矽層3 2、一金屬矽化 物層3 4、一絕緣層3 6以及一氮化石夕層3 8。如圖四所示,然 後於半導體晶片1 0表面形成一光阻層4 0,並於記憶陣列區 1 2上方之光阻層4 0中定義出複數個閘極4 1圖案,隨後利用 各閘極4 1圖案作為罩幕,蝕刻記憶陣列區1 2之氮化矽層 3 8、絕緣層3 6、金屬矽化物層3 4以及摻雜多晶矽層3 2,直 至矽基底1 6之閘極氧化層2 4表面,以於記憶陣列區1 2上形 成各M0S電晶體之閘極4 1。然後進行一離子佈值製程,形 成記憶陣列區12中之各M0S電晶體之輕摻雜汲極(LDD) 42° 在完全去除掉光阻層4 0以及未被各閘極4 1所覆蓋的閘 極氧化層2 4之後,如圖五所示,先於半導體晶片1 0表面形 成一絕緣層44,且絕緣層4 4的厚度大於週邊電路區14中各471136 V. Description of the invention (2) The method is to first form a silicon oxide layer on the surface of the silicon substrate 16 by a thermal oxidation method, which is used as the gate oxide layer 24 of each MOS transistor, and then on the gate oxide layer 2 An undoped polysilicon layer 26 and an insu 1 ati η layer 8 are sequentially formed on the 4 surface. Then, as shown in FIG. 2, a photoresist layer 30 is formed as a hard mask over the peripheral circuit area 14, and a yellow light and etching process (PEP) is used to etch the insulation layer over the memory array area 12. 28 and the undoped polycrystalline silicon layer 26 to the surface of the gate oxide layer 24. After the photoresist layer 30 has been completely removed, as shown in FIG. 3, a doped polycrystalline silicon layer 3 2, a metal silicide layer 3 4, an insulating layer 36, and Nitride stone evening layer 38. As shown in FIG. 4, a photoresist layer 40 is then formed on the surface of the semiconductor wafer 10, and a plurality of gate 41 patterns are defined in the photoresist layer 40 above the memory array area 12. Then, each gate is used. The electrode 4 1 pattern is used as a mask, and the silicon nitride layer 3 8, the insulating layer 3 6, the metal silicide layer 3 4, and the doped polycrystalline silicon layer 32 are etched in the memory array region 12 until the gate of the silicon substrate 16 is oxidized. On the surface of the layer 24, a gate 41 of each MOS transistor is formed on the memory array region 12. Then, an ion layout process is performed to form the lightly doped drain (LDD) of each M0S transistor in the memory array region 42 °. The photoresist layer 40 and the gate electrode 41 are not covered completely. After the gate oxide layer 24, as shown in FIG. 5, an insulating layer 44 is formed before the surface of the semiconductor wafer 10, and the thickness of the insulating layer 44 is greater than that of each of the peripheral circuit regions 14.

第6頁 471136 五、發明說明(3) 層的總厚度’接著以週邊電路區1 4之氮化石夕層3 8作為停止 層’進行一化學機械研磨製程(chemicaliechanical ρ ο 1 i s h i n g,簡稱為C Μ P ) ’以使記憶陣列區1 2上方之絕緣 層4 4與週邊電路區1 4之氮化矽層3 8約略形成一水平面。 隨後如圖六所示,蝕刻週邊電路區1 4之氮化矽層3 8、 絕緣層36、金屬矽化物層34、摻雜多晶矽層32以及絕緣層 2 8 ’直至未摻雜多晶石夕層2 6表面。接著於半導體晶片1 〇表 面形成一光阻層46’並進行一黃光製程,以於週邊電路區 1 4上方之光阻層4 6中定義複數個Ρ Μ 0 S與Ν Μ 0 S的閘極4 7圖 案,然後利用光阻層46中的閘極47圖案作為硬罩幕,同時 亦利用d fe陣列區1 2上方之絕緣層4 4作為罩幕來保護記憶 陣列區1 2上的各閘極4 1結構,來飯刻週邊電路區1 4之未摻 雜多晶矽層2 6 ’直至閘極氧化層2 4表面,形成ρ μ 〇 S與N Μ 0 S 的閘極4 7。之後再利用一離子佈值製程來形成各ρ μ 〇 s與 Ν Μ 0 S的輕摻雜汲極(l D D ) 4 2。 如圖七所示’接著於半導體晶片1 〇表面形成一氦^碎層 (未顯示)’並進行一非等向性(a n丨s 0 t r 〇 p i c >|虫刻製程, 以於週邊電路區1 4中之各閘極4 7周圍形成一側壁子 (spacer) 48。然後再分別利用兩次的黃光製程來進行兩次 不同佈植區域的離子佈植製程,以於週邊電路區1 4之p型 井2 0以及N型井22上方分別形成NMOS以及PMOS電晶體的源 極5 0與汲極5 2。Page 6 471136 V. Description of the invention (3) The total thickness of the layer 'is followed by a chemical mechanical polishing process (chemicaliechanical ρ ο 1 ishing, abbreviated as C) using the nitrided layer 3 8 of the peripheral circuit area 14 as the stop layer' MP) so that the insulating layer 44 above the memory array region 12 and the silicon nitride layer 38 of the peripheral circuit region 14 approximately form a horizontal plane. Subsequently, as shown in FIG. 6, the silicon nitride layer 38, the insulating layer 36, the metal silicide layer 34, the doped polycrystalline silicon layer 32, and the insulating layer 2 8 ′ of the peripheral circuit region 14 are etched until the undoped polycrystalline silicon is exposed Layer 2 6 surface. Next, a photoresist layer 46 'is formed on the surface of the semiconductor wafer 10 and a yellow light process is performed to define a plurality of gates of PM0S and NM0S in the photoresist layer 46 above the peripheral circuit area 14. 4 47 patterns, and then use the gate 47 pattern in the photoresist layer 46 as a hard mask, and also use the insulating layer 4 4 above the d fe array region 12 as a mask to protect each of the memory array regions 12 The gate 41 structure is formed by engraving the undoped polycrystalline silicon layer 2 6 ′ of the peripheral circuit region 14 to the surface of the gate oxide layer 24 to form a gate 47 of ρ μOS and N M 0 S. A lightly doped drain (1 D D) 4 2 of each ρ μ s and N M 0 S is then formed using an ion-distribution process. As shown in FIG. 7, 'Next, a helium ^ chip (not shown) is formed on the surface of the semiconductor wafer 10 and an anisotropic (an 丨 s 0 tr 〇pic > | A spacer 48 is formed around each of the gates 4 7 in the area 1 4. Then, two yellow light processes are used to perform two ion implantation processes in different implantation areas to the peripheral circuit area 1. A source 50 and a drain 52 of NMOS and PMOS transistors are respectively formed above p-type well 20 and N-type well 22 of 4.

第7頁 471136 說明(4) 最後如圖八所示,於半導體晶片1 0表面減:鐘 (s p u 11 e r )—由钦(T i )金屬所構成金屬層(未顯示),然後 進行一溫度範圍為5 0 0°C〜7 0 (TC且加熱時間約為3 0秒的第 一快速熱處理(RTP)製程,以使該金屬層中的鈦(Ti )原子 得以擴散進入週邊電路區1 4中各源極5 0、汲極5 2以及閘極 4 7表面。隨後進行一濕蝕刻,以去除於半導體晶片1 0表面 未反應之該金屬層。最後進行一溫度範圍為7 0 0°C〜9 0 0°C 且加熱時間約為30秒的第二快速熱處理(RTP)製程,以於 週邊電路區1 4上之各源極5 0、汲極5 2以及閘極4 7表面形成 一自行對準金屬石夕化物層5 4。 由於記憶陣列區1 2的閘極4 1需要一頂保護層(c a p 1 a y e r ) 3 8,以利後續之自行對準接觸(s e 1 f - a 1 i g n e d contact,簡稱SAC)製程的順利進行,而週邊電路區1 4中 則為了進行後續的自行對準金屬矽化物(sal icide)製程, 以降低各源極50、汲極52以及閘極47表面的片電阻(sheet r e s i s t a n c e,簡稱R s ),因此閘極4 7頂部不可以形成一保 護層。是以在習知製作嵌入式記憶體之M0S電晶體的方法 中,必須反覆進行多次黃光與蝕刻製程,以整合記憶陣列 區與週邊電路區中的閘極製作,進而提高了製程的複雜度 與生產成本,降低產能(throughput)。 發明概述Page 7 471136 Explanation (4) Finally, as shown in FIG. 8, the surface of the semiconductor wafer 10 is reduced by: clock (spu 11 er)-a metal layer (not shown) made of metal (T i), and then a temperature The first rapid thermal processing (RTP) process with a range of 50 ° C ~ 7 0 (TC and heating time of about 30 seconds), so that titanium (Ti) atoms in the metal layer can diffuse into the peripheral circuit area 1 4 The surface of each of the source 50, the drain 52, and the gate 47. A wet etching is then performed to remove the unreacted metal layer on the surface of the semiconductor wafer 10. Finally, a temperature range of 700 ° C is performed. A second rapid thermal processing (RTP) process at ~ 90 ° C and a heating time of about 30 seconds to form a surface of each of the source 50, the drain 5 2 and the gate 4 7 on the peripheral circuit area 14 Align the metal oxide layer 5 4 by itself. Because the gate 4 1 of the memory array area 12 needs a cap 1 ayer 3 8 to facilitate subsequent self-aligned contacts (se 1 f-a 1 igned contact (SAC for short) process, and in the peripheral circuit area 14 for subsequent self-aligned metal silicidation (Salicide process) to reduce the sheet resistance (R s) on the surface of each source 50, drain 52, and gate 47, so a protective layer cannot be formed on the top of gates 4 and 7. In the conventional method of manufacturing M0S transistors of embedded memory, multiple yellow light and etching processes must be performed repeatedly to integrate gate fabrication in the memory array region and peripheral circuit regions, thereby increasing the complexity and production of the process. Cost and reduce throughput. Summary of Invention

第8頁Page 8

47113G 五、發明說明(5) — 本發明之主要目的在於提供一種嵌入式記憶體 (embedded memory)之MOS電晶體的製作方法,^整合記憶 陣列區與周邊電路區中的閘極製程,並達到簡化^ ^的^ 的。 本發明之方法是先於一定義有記憶陣列區(memQ;ry array area)以及週邊電路區(periphery circuits region)之半導體晶片表面依序形成一第一介電層與一未 摻雜(undoped)多晶矽層,接著摻雜該記憶陣列區上方之 該未摻雜多晶矽層,並於該半導體晶片表面形成一保護 層。隨後進行一第一黃光暨蝕刻製程(PEP ),蝕刻該記"^意 陣列區上之該保護層與該摻雜多晶矽層,形成複數個閘μ 極,然後於各該閘極周圍形成輕摻雜汲極(LDD)。接著於 该半導體晶片表面形成一氮石夕層與一第二介電層,然後去 除該週邊電路區上之該第二介電層、該氮矽層以及該保護 層,最後進行一第二PEP,蝕刻該週邊電路區上方之該未 接雜多晶矽層以形成複數個閘極,然後形成該週邊電路區 中之各該Μ 0 S電晶體的L D D、側壁子(s p a c e r )以及源極/没 極(S/D)。 利用本發明嵌入式記憶體之M0S電晶體的製作方法, 可以整合記憶陣列區與週邊電路區中的閘極製程,同時減 少自動對準金屬矽化物製程之熱預算(thermal budget),47113G V. Description of the invention (5) — The main purpose of the present invention is to provide a method for manufacturing MOS transistors with embedded memory, which integrates the gate process in the memory array area and the peripheral circuit area, and achieves Simplify ^ of ^. In the method of the present invention, a first dielectric layer and an undoped surface are sequentially formed on a surface of a semiconductor wafer having a memory array area (memQ; ry array area) and peripheral circuits area defined. The polycrystalline silicon layer is then doped with the undoped polycrystalline silicon layer above the memory array region, and a protective layer is formed on the surface of the semiconductor wafer. Subsequently, a first yellow light and etching process (PEP) is performed, and the protective layer and the doped polycrystalline silicon layer on the array region are etched to form a plurality of gate μ electrodes, and then formed around each of the gate electrodes. Lightly doped drain (LDD). Next, a nitrogen stone layer and a second dielectric layer are formed on the surface of the semiconductor wafer, and then the second dielectric layer, the nitrogen silicon layer, and the protective layer on the peripheral circuit area are removed, and finally a second PEP is performed. , Etching the non-doped polycrystalline silicon layer above the peripheral circuit region to form a plurality of gates, and then forming the LDD, the spacer, and the source / impulse of each M 0 S transistor in the peripheral circuit region (S / D). By using the manufacturing method of the MOS transistor of the embedded memory of the present invention, the gate process in the memory array region and the peripheral circuit region can be integrated, and the thermal budget of the automatic metal silicide process can be reduced.

第9頁 471136 五、發明說明(6) 以降低製程的複雜度與生產成本。 發明之詳細說明 請參考圖九至圖十六,圖九至圖十六為本發明於一半 導體晶片6 0上製作嵌入式記憶體之MOS電晶體的方法示意 圖。半導體晶片60包含有一矽基底66,且矽基底66的表面 上已定義有一記憶陣列區6 2以及一週邊電路區6 4,且記憶 陣列區62中包含有至少一單胞井68,而週邊電路區6 4中包 含有至少一 P型井7 0以及至少一 N型井7 2,且各區域以複數 個淺溝隔離6 1加以分隔。 如圖九所示,本發明方法是先於半導體晶片6 0表面依 序形成一介電層7 4以及一未摻雜多晶矽層7 6。其中介電層 74係由二氧化矽(Si〇2)所構成,用來作為各MOS電晶體的 閘極氧化層。然後利用一黃光(1 i thography )製程來對記 憶陣列區6 2上方之未摻雜多晶矽層7 6進行一離子佈植製 程,以使記憶陣列區6 2上方之未摻雜多晶矽層7 6形成為一 摻雜多晶矽層7 7。 接著如圖十所示,於半導體晶片6 0表面依序形成一保 護層7 8以及一光阻層8 0,其中保護層7 8係由一氮矽化合物 所構成,且保護層7 8與未摻雜多晶矽層7 6之間另包含有一 氮氧化矽(S i 0 XN y)層(未顯示),用來做為一抗反射層Page 9 471136 V. Description of the invention (6) To reduce the complexity and production cost of the process. Detailed description of the invention Please refer to FIG. 9 to FIG. 16, which are schematic diagrams of a method for fabricating an embedded memory MOS transistor on a semi-conductor wafer 60 according to the present invention. The semiconductor chip 60 includes a silicon substrate 66, and a memory array region 62 and a peripheral circuit region 64 have been defined on the surface of the silicon substrate 66. The memory array region 62 includes at least one cell well 68 and peripheral circuits. The area 64 includes at least one P-type well 70 and at least one N-type well 72, and each area is separated by a plurality of shallow trench isolations 61. As shown in FIG. 9, in the method of the present invention, a dielectric layer 74 and an undoped polycrystalline silicon layer 76 are sequentially formed before the surface of the semiconductor wafer 60. The dielectric layer 74 is composed of silicon dioxide (SiO2) and is used as a gate oxide layer of each MOS transistor. Then, a yellow light (Ithography) process is used to perform an ion implantation process on the undoped polycrystalline silicon layer 7 6 above the memory array region 62 to make the undoped polycrystalline silicon layer 7 6 above the memory array region 62. Formed as a doped polycrystalline silicon layer 7 7. Next, as shown in FIG. 10, a protective layer 78 and a photoresist layer 80 are sequentially formed on the surface of the semiconductor wafer 60. The protective layer 78 is composed of a nitrogen silicon compound, and the protective layer 78 and A silicon nitride oxide (S i 0 XN y) layer (not shown) is further included between the doped polycrystalline silicon layers 7 and 6 as an anti-reflection layer.

第10頁 471136 五、發明說明(7) (ARC)。如圖十一所示,隨後進行一微影 (photolithography)、曝光(exposure)以及顯影 (development)製程,以於記憶陣列區62之單胞井68上方 的光阻層8 0中定義出複數個閘極8丨的圖案。接著利用光阻 層8 0的圖案當作硬罩幕,以蝕刻記憶陣列區6 2上方之保護 層7 8以及摻雜多晶;ς夕層7 7,直至介電層7 4表面。隨後進行 一離子佈植製程,形成記憶陣列區6 2中之各M0S電晶體的 輕摻雜汲極(LDD) 82。 在完全去除掉光阻層8 0以及未被各閘極8 1所覆蓋的閘 極氧化層7 4之’後,如圖十二所示,接著便於半導體晶片6 〇 表面依序形成一氮矽層8 4以及一介電層8 6,並覆蓋於記憶 陣列區6 2上之各閘極8 1表面。隨後如圖十三所示,於記憶 陣列區6 2上方形成一光阻層8 8當作罩幕,以去除週邊電路 巴6 4上之介電層86、氮石夕層84以及保護層78。 如圖十四所示’然後於半導體晶片6 〇表面形成一光阻 層9〇。其中’在形成光阻層90之前,另可先於半導體晶片 6〇表面形成一氮氧化矽(Si〇xNy)層(未顯示)當作抗反射層 (ARC)。接著進行一黃光製程,以於週邊電路區64之N型井 7 2以及p型井7 〇上方的光阻層9 〇中,定義出複數個閘極9 1 $圖案。然後利用光阻層9 0的圖案當作硬罩幕,|虫刻週邊 電路區64上方之未摻雜多晶矽層76,直至介電層74表面, 以於週邊電路區64上形成各M0S電晶體之閘極91。接著進Page 10 471136 V. Description of Invention (7) (ARC). As shown in FIG. 11, a photolithography, exposure, and development process is subsequently performed to define a plurality of photoresist layers 80 in the photoresist layer 80 above the cell well 68 in the memory array region 62. Pattern of gate 8 丨. The pattern of the photoresist layer 80 is then used as a hard mask to etch the protective layer 78 and the doped polycrystalline silicon over the memory array region 62; the layer 7 7 to the surface of the dielectric layer 74. Then, an ion implantation process is performed to form a lightly doped drain (LDD) 82 of each MOS transistor in the memory array region 62. After the photoresist layer 80 and the gate oxide layer 7 4 not covered by the gates 81 are completely removed, as shown in FIG. 12, it is then convenient to sequentially form a silicon silicon nitride on the surface of the semiconductor wafer 60. The layer 84 and a dielectric layer 86 cover the surfaces of the gates 81 on the memory array region 62. Subsequently, as shown in FIG. 13, a photoresist layer 8 8 is formed as a mask over the memory array area 62 to remove the dielectric layer 86, the nitrogen oxide layer 84 and the protective layer 78 on the peripheral circuit bar 64. . As shown in FIG. 14 ', a photoresist layer 90 is then formed on the surface of the semiconductor wafer 60. Among them, before the photoresist layer 90 is formed, a silicon nitride oxide (SiOxNy) layer (not shown) may be formed as an anti-reflection layer (ARC) before the surface of the semiconductor wafer 60. Next, a yellow light process is performed to define a plurality of gate electrodes 9 1 $ patterns in the photoresist layer 9 0 above the N-type well 72 and the p-type well 70 in the peripheral circuit area 64. The pattern of the photoresist layer 90 is then used as a hard mask, and the undoped polycrystalline silicon layer 76 above the peripheral circuit area 64 is etched to the surface of the dielectric layer 74 to form each MOS transistor on the peripheral circuit area 64. Of the gate 91. Go on

第11頁 471136 五、發明說明(8) 行一離子佈植製程,形成週邊電路區64中 之輕摻雜汲極(LDD) 82。 StPage 11 471136 V. Description of the invention (8) An ion implantation process is performed to form a lightly doped drain (LDD) 82 in the peripheral circuit region 64. St

曰B 體 隨後去除光阻層9 0以及形成於光阻層9 〇下方之氣氣化 石夕層(未顯示)。如圖十五所示,於半導體晶片6 〇表面形成 氮石夕層(未顯示),並覆蓋於週邊電路區64上之各閘極91 表面。接著利用兩次黃光暨蝕刻(PEP )製程來分別對pM〇s 電晶體以及N Μ 0 S電晶體進行後續之製程,亦即先進行第一 次PEP,以蝕刻週邊電路區64之Ρ型井70上方之各閘極91周 圍的氮矽層’形成一側壁子9 2,並進行一離子佈植製程, 以於P型井7 0中形成NMOS電晶體的源極94與汲極96。然後 進行第二次PEP,以蝕刻週邊電路區64之N型井7 2上方之各 閘極9 1周圍的氮矽層,形成一側壁子9 2,並再進行一離子 佈植製程,以於N型井7 2中形成PMOS電晶體的源極94與汲 極9 6。其中上述兩次離子佈植製程會分別對ρ型井了 〇以及% 型井7 2上方之各閘極9 1中之未摻雜多晶矽層7 6進行摻雜。 如圖十六所示,在製備完週邊電路區6 4上之各MOS電 晶體的源極9 4與汲極9 6之後,先去除未被各閘極9 1所覆蓋 的閘極氧化層7 4,接著於半導體晶面6 0表面沉積一由鈷 (Co)所構成金屬層(未顯示),且金屬層覆蓋於週邊電路區 6 4上之各源極9 4、汲極9 6以及閘極9 1表面之上。然後進行 一溫度範圍為4 0 (TC〜6 0 0°C且加熱時間為1 0〜5 0秒的第一 快速熱處理(RTP)製程,以使金屬層中的鈷(Co)原子得以The B-body is then removed from the photoresist layer 90 and the gasification layer (not shown) formed below the photoresist layer 90. As shown in FIG. 15, a nitrogen stone layer (not shown) is formed on the surface of the semiconductor wafer 60, and covers the surface of each gate 91 on the peripheral circuit area 64. Then, two yellow light and etching (PEP) processes are used to perform subsequent processes on the pM0s transistor and N M 0 S transistor, that is, the first PEP is performed first to etch the P-type of the peripheral circuit area 64. The nitrogen-silicon layer 'around each gate 91 above the well 70 forms a sidewall 92 and performs an ion implantation process to form the source 94 and the drain 96 of the NMOS transistor in the P-well 70. Then a second PEP is performed to etch the nitrogen-silicon layer around each gate 9 1 above the N-type well 72 in the peripheral circuit area 64 to form a sidewall 92, and then perform an ion implantation process to A source 94 and a drain 96 of a PMOS transistor are formed in the N-type well 72. The above two ion implantation processes will dope the undoped polycrystalline silicon layer 76 in each gate 91 above the p-type well 0 and the% -well 72, respectively. As shown in FIG. 16, after the source 9 4 and the drain 9 6 of each MOS transistor on the peripheral circuit area 64 are prepared, the gate oxide layer 7 not covered by the gates 9 1 is removed first. 4. Next, a metal layer (not shown) made of cobalt (Co) is deposited on the surface of the semiconductor crystal plane 60, and the metal layer covers each of the source electrodes 9 4, the drain electrodes 96, and the gates on the peripheral circuit area 64. Pole 9 1 above the surface. Then, a first rapid heat treatment (RTP) process is performed at a temperature range of 40 (TC ~ 600 ° C and a heating time of 10 ~ 50 seconds), so that the cobalt (Co) atoms in the metal layer can be

第12頁 471136 五、發明說明(9) 擴散進入各源極9 4、汲極9 6以及閘極9 1表面。隨後再進行 一濕蝕刻,以去除於半導體晶片6 0表面未反應之金屬層。 最後進行一溫度範圍為6 0 0°C〜8 0 0°C且加熱時間為1 0〜5 0 秒的第二快速熱處理(RTP)製程,以於週邊電路區64上之 各源極9 4、汲極9 6以及閘極9 1表面形成一自行對準矽化物 層98。其中,金屬層可以鈦(Ti)、鎳(Ni)或鉬(Mo)等金屬 取代。 綜合上述說明,本發明之製作一嵌入式記憶體之M0S 電晶體的方法,是先於半導體晶片6 0表面形成一閘極氧化 層7 4、一未摻雜多晶矽層7 6以及一保護層7 8,接著於記憶 陣列區62中形成各M0S電晶體之閘極81結構,隨後再於半 導體晶片6 0表面依序形成一氮石夕層8 4以及一介電層8 6,然 後去除週邊電路區6 4上方之介電層86、氮碎層8 4以及保護 層78,並於週邊電路區64中形成各M0S電晶體之閘極91結 構。 相較於習知製作嵌入式記憶體之M0S電晶體的方法, 本發明在製作M0S電晶體的製程中,是以一多晶矽層同時 作為週邊電路區以及記憶陣列區之導電層,因此減少許多 化學沉積以及蝕刻程序,降低製程的複雜度與生產成本。 以上所述僅本發明之較佳實施例,凡依本發明申請專 利範圍所做之均等變化與修飾,皆應屬本發明專利之涵蓋Page 12 471136 V. Description of the invention (9) Diffusion into the surface of each source 9 4, drain 9 6 and gate 9 1. Then, a wet etching is performed to remove the unreacted metal layer on the surface of the semiconductor wafer 60. Finally, a second rapid thermal processing (RTP) process is performed in a temperature range of 600 ° C to 80 ° C and a heating time of 10 to 50 seconds, so that each source 9 4 on the peripheral circuit area 64 A self-aligned silicide layer 98 is formed on the surfaces of the drain electrode 96 and the gate electrode 91. The metal layer may be replaced by a metal such as titanium (Ti), nickel (Ni), or molybdenum (Mo). To sum up the above description, the method for manufacturing an M0S transistor of an embedded memory of the present invention is to form a gate oxide layer 7 4, an undoped polycrystalline silicon layer 76 and a protective layer 7 before the surface of the semiconductor wafer 60. 8. Next, a gate 81 structure of each MOS transistor is formed in the memory array region 62, and then a nitrogen oxide layer 84 and a dielectric layer 86 are sequentially formed on the surface of the semiconductor wafer 60, and then the peripheral circuits are removed. The dielectric layer 86, the nitrogen fragmentation layer 84, and the protective layer 78 above the region 64 are formed in the peripheral circuit region 64 to form a gate 91 structure of each MOS transistor. Compared with the conventional method for making M0S transistors in embedded memory, the present invention uses a polycrystalline silicon layer as a conductive layer in the peripheral circuit area and the memory array area in the manufacturing process of the M0S transistor, thus reducing many chemistry Deposition and etching procedures reduce process complexity and production costs. The above are only the preferred embodiments of the present invention. Any equivalent changes and modifications made in accordance with the scope of the patent application for the present invention shall be covered by the patent of the present invention.

第13頁 471136 五、發明說明(ίο) 範圍。Page 13 471136 V. Description of the Invention (ίο) Scope.

Hi 第14頁 471136 圖式簡單說明 圖示之簡單說明 圖一至圖八為習知製作一嵌入式記憶體之MOS電晶體 的方法示意圖 圖九至圖十六為本發明製作一嵌入式記憶體之MOS電 晶體的方法示意圖 圖示之符號說明 10 半 導 體 晶 片 11 淺 溝 隔 離 12 1己 憶 陣 列 區 14 週 邊 電 路 區 16 矽 基 底 18 單 胞 井 20 P型井 22 N型井 24 閘 極 氧 化 層 26 未 摻 雜 多 晶 矽層 28^ 36^ 44 絕 緣 層 30、 40、 46 光 阻 層 32 摻 雜 多 晶 矽 層 34 金 屬 矽 化 物 層 38 氮 化 矽 層 41、 47 閘 極 42 輕 摻 雜 汲 極 48 側 壁 子 50 源 極 52 汲 極 54 白 動 對 準 金 屬 矽化物層 60 半 導 體 晶 片 61 淺 溝 隔 離 62 記 憶 電 路 區Hi Page 14 471136 Simple illustration of the diagrams Simple illustrations of the diagrams Figures 1 to 8 are schematic diagrams of a conventional method for making a MOS transistor of an embedded memory. Figures 9 to 16 show the methods of making an embedded memory according to the present invention. MOS transistor method schematic diagram Symbol description 10 Semiconductor wafer 11 Shallow trench isolation 12 1 Memory array area 14 Peripheral circuit area 16 Silicon substrate 18 Cell well 20 P-type well 22 N-type well 24 Gate oxide layer 26 Doped polycrystalline silicon layer 28 ^ 36 ^ 44 insulating layer 30, 40, 46 photoresist layer 32 doped polycrystalline silicon layer 34 metal silicide layer 38 silicon nitride layer 41, 47 gate 42 lightly doped drain 48 side wall 50 source Pole 52 Drain 54 White-aligned metal silicide layer 60 Semiconductor wafer 61 Shallow trench isolation 62 Memory circuit area

第15頁Page 15

47113G 圖式簡單說明47113G Schematic description

64 週 邊 電 路 區 66 矽 基底 68 單 胞 井 70 P型井 72 N型丼 74、 86 介 電 層 76 未 摻 雜 多 晶 矽 層 77 換 雜多 晶 矽 78 保 護 層 80、 88> 90 光 阻 層 81、 91 閘 極 82 輕 摻雜 汲 極 84 氮 矽 層 92 側 壁子 94 源 極 96 汲 極 98 商 動 對 準 金 屬 矽 化物層 第16頁64 Peripheral circuit area 66 Silicon substrate 68 Cell well 70 P-type well 72 N-type 丼 74, 86 Dielectric layer 76 Undoped polycrystalline silicon layer 77 Doped polycrystalline silicon 78 Protective layer 80, 88> 90 Photoresistive layer 81, 91 Gate Electrode 82 lightly doped drain electrode 84 silicon nitride layer 92 side wall 94 source electrode 96 drain electrode 98 commercial alignment metal silicide layer page 16

Claims (1)

471136 六、申請專利範圍 1· 一種嵌入式記憶體(embedded memory)之金屬氧化物 半導體(metal oxide semiconductor, M0S)電晶體的製作 方法,該製作方法包含有下列步驟: 提供一半導體晶片,且該半導體晶片之石夕基底 (silicon substrate)表面已定義有一記憶陣列區(mem〇ry array area)以及一週邊電路區(periphery circuits region); 於該半導體晶片表面依序形成一第一介電層以及一未 摻雜多晶矽(undoped polysi 1 icon)層; 對該記憶陣列區上方之該未摻雜多晶矽層進行一第一 離子佈植製程(i ο n i m p 1 a n t a t i ο η),以使該記憶陣列區上 方之該未摻雜多晶矽層形成為一摻雜多晶矽層; 於該半導體晶片表面依序形成一保護層以及一第一光 阻層; 進行一第一黃光製程,以於該記憶陣列區上方之該第 一光阻層中定義出複數個問極(gai:e)的圖案(pattern); 利用該第一光阻層的圖案當作硬罩幕(hard mask), 以餘刻該記憶陣列區上方之該保護層以及該摻雜多晶矽 層,直至該第一介電層表面; 進行一第一離子佈植製程,形成該記憶陣列區中之各 該M0S電晶體之輕摻雜汲梳〆彳_ w t ^ ,. * 叉馇(lightly doped drain, LDD); 去除該第一光阻層;471136 VI. Application Patent Scope 1. A method for manufacturing a metal oxide semiconductor (MOS) transistor with embedded memory, the method includes the following steps: providing a semiconductor wafer, and A memory array area and a peripheral circuits region have been defined on the surface of the silicon substrate of the semiconductor wafer; a first dielectric layer is sequentially formed on the surface of the semiconductor wafer and An undoped polysilicon (unoped polysi 1 icon) layer; performing a first ion implantation process (i ο nimp 1 antati ο η) on the undoped polysilicon layer above the memory array region to make the memory array region The undoped polycrystalline silicon layer above is formed as a doped polycrystalline silicon layer; a protective layer and a first photoresist layer are sequentially formed on the surface of the semiconductor wafer; a first yellow light process is performed to over the memory array region A pattern of a plurality of interrogation electrodes (gai: e) is defined in the first photoresist layer; using the first photoresist layer The pattern is used as a hard mask to etch the protective layer and the doped polycrystalline silicon layer over the memory array area until the surface of the first dielectric layer is performed; a first ion implantation process is performed to form Lightly doped drain (LDD) of each of the MOS transistors in the memory array region; lightly doped drain (LDD); removing the first photoresist layer; 第17頁 471136 六、申請專利範圍 二介電層,並覆蓋於該記憶陣列區上之各該閘極表面; 去除該週邊電路區上之該第二介電層、該第一氮矽層 以及該保護層; 於該半導體晶片表面形成一第二光阻層; 進行一第二黃光製程,以於該週邊電路區上方之該第 二光阻層中定義出複數個閘極的圖案; 利用該第二光阻層的圖案當作硬罩幕,蝕刻該週邊電 路區上方之該未摻雜多晶矽層直至該第一介電層表面,以 於該週邊電路區上形成各該MOS電晶體之間極; 進行一第三離子佈植製程,形成該週邊電路區中之各 該Μ 0 S電晶體之輕摻雜汲極(L D D ); 去除該第二光阻層; 於該半導體晶片表面形成一第二氮矽層,並覆蓋於該 週邊電路區上之各該閘極表面: 利用一蝕刻製程來去除該週邊電路區中之部份的該第 二氮矽層,以於該週邊電路區中之各該閘極周圍形成一側 壁子(spacer);以及 進行一第四離子佈植製程,以形成該週邊電路區上之 各該Μ 0 S電晶體的源極(s 〇 u r c e )與没極(d r a i η )。 2 . 如申請專利範圍第1項之方法,其中該第一介電層係 由二氧化石夕(silicon dioxide, SiO 2)所構成,用來作為 各該M0S電晶體的閘極氧化層。Page 17 471136 VI. Patent application scope Two dielectric layers covering each gate surface on the memory array area; removing the second dielectric layer, the first silicon nitride layer and the first silicon nitride layer on the peripheral circuit area; The protective layer; forming a second photoresist layer on the surface of the semiconductor wafer; performing a second yellow light process to define a plurality of gate patterns in the second photoresist layer above the peripheral circuit area; using The pattern of the second photoresist layer is used as a hard mask, and the undoped polycrystalline silicon layer above the peripheral circuit area is etched up to the surface of the first dielectric layer to form the MOS transistors on the peripheral circuit area. An intermediate electrode; performing a third ion implantation process to form a lightly doped drain (LDD) of each of the M 0 S transistors in the peripheral circuit region; removing the second photoresist layer; forming on the surface of the semiconductor wafer A second silicon nitride layer and covering each gate surface on the peripheral circuit area: an etching process is used to remove a part of the second silicon nitride layer in the peripheral circuit area to the peripheral circuit area Formed around each of the gates Side wall sub (spacer); and performing a fourth ion implantation process to form each of the of the peripheral circuit region of the Μ source 0 S transistor pole (s square u r c e) and without pole (d r a i η). 2. The method according to item 1 of the scope of patent application, wherein the first dielectric layer is composed of silicon dioxide (SiO 2) and is used as a gate oxide layer of each MOS transistor. 第18頁 471136 六、申請專利範圍 3. 如申請專利範圍第1項之方法,其中該保護層係由一 氮矽化合物所構成,且該保護層與該未摻雜多晶矽層之間 另包含有一第一氤氧化矽(silicon-oxy-nitride, SiOxNy) 層,用來做為一抗反射層(anti-reflection coating, ARC)。 4 . 如申請專利範圍第1項之方法,其中在該半導體晶片 表面形成該第二光阻層之前,另可先於該半導體晶片表面 形成一第二氮氧化矽(Si 0xNy)層當作抗反射層(ARC)。 5. 如申請專利範圍第4項之方法,其中在去除該第二光 阻層之後,亦須去除形成於該第二光阻層下方之該第二氮 氧化石夕層。 6. 如申請專利範圍第1項之方法,其中在形成完該週邊 電路區上之各該M0S電晶體的源極與汲極之後,該方法另 包含有下列步驟: 於該半導體晶片表面形成一金屬層,且该金屬層覆蓋於遠 週邊電路區上之各該源極、汲極以及閘極表面之上; 進行一第一快速熱處理(rapid thermal process, RTP)製 程; 進行一濕蝕刻(wet etch),去除於該半導體晶片表面未反 應之該金屬層;以及 進行一第二快速熱處理(RTP)製程。Page 18 471136 VI. Application for Patent Scope 3. For the method of applying for the scope of patent application item 1, wherein the protective layer is composed of a nitrogen silicon compound, and the protective layer and the undoped polycrystalline silicon layer further include a The first silicon-oxy-nitride (SiOxNy) layer is used as an anti-reflection coating (ARC). 4. The method according to item 1 of the patent application, wherein before the second photoresist layer is formed on the surface of the semiconductor wafer, a second silicon oxynitride (Si 0xNy) layer may be formed on the surface of the semiconductor wafer as an anti-resistance. Reflective layer (ARC). 5. If the method of claim 4 is applied, after the second photoresist layer is removed, the second oxynitride layer formed under the second photoresist layer must also be removed. 6. The method of claim 1, wherein after forming the source and drain of each of the MOS transistors on the peripheral circuit area, the method further includes the following steps: forming a semiconductor wafer surface A metal layer covering the source, drain, and gate surfaces on the far peripheral circuit area; performing a first rapid thermal process (RTP) process; and performing a wet etch etch), removing the unreacted metal layer on the surface of the semiconductor wafer; and performing a second rapid thermal processing (RTP) process. 第19頁 471136 六、申請專利範圍 7. 如申請專利範圍第6項之方法,其中該金屬層係由鈷 (cobalt, Co)、鈦(titanium, Ti)、錄(nickel, Ni)或鉬 (molybdenum,Mo)所構成。 8. 如申請專利範圍第6項之方法,其中該第一快速熱處 理(RTP )製程的溫度範圍為4 0 (TC〜6 0 0°C ,加熱時間為1 0 〜50秒,而第二快速熱處理(RTP)製程的溫度範圍為6 0 0°C 〜8 0 (TC,加熱時間為1 0〜5 0秒。 9. 一種嵌入式記憶體之金屬氧化物半導體(M0S)電晶體 的製作方法,該製作方法包含有下列步驟: 提供一半導體晶片,該半導體晶片之矽基底表面已定 義有一記憶陣列區以及一週邊電路區,且該記憶陣列區中 包含有至少一單胞井(cell-well),而該週邊電路區中包 含有至少一 N型井(N-well)以及至少一 P型井(P-well); 於該半導體晶片表面依序形成一第一介電層以及一未 摻雜多晶矽層; 對該記憶陣列區上方之該未摻雜多晶矽層進行一第一 離子佈植製程,以使該記憶陣列區上方之該未摻雜多晶矽 層形成為一捧雜多晶石夕層, 於該半導體晶片表面依序形成一保護層以及一第一光 阻層; 進行一第一黃光製程,以於該記憶陣列區之單胞井上Page 19, 471136 6. Application for Patent Scope 7. The method of claim 6 for patent application, wherein the metal layer is made of cobalt (Co), titanium (Ti), titanium (nickel, Ni) or molybdenum ( molybdenum, Mo). 8. The method according to item 6 of the patent application, wherein the temperature range of the first rapid heat treatment (RTP) process is 40 (TC ~ 60 0 ° C, the heating time is 10 ~ 50 seconds, and the second fast The temperature range of the heat treatment (RTP) process is 600 ° C to 80 (TC, and the heating time is 10 to 50 seconds.) 9. A method for manufacturing a metal oxide semiconductor (M0S) transistor with embedded memory The manufacturing method includes the following steps: A semiconductor wafer is provided. A silicon array surface of the semiconductor wafer has a memory array region and a peripheral circuit region defined thereon, and the memory array region includes at least one cell-well. ), And the peripheral circuit region includes at least one N-well and at least one P-well; a first dielectric layer and an undoped layer are sequentially formed on the surface of the semiconductor wafer; Heteropolycrystalline silicon layer; performing a first ion implantation process on the undoped polycrystalline silicon layer above the memory array region, so that the undoped polycrystalline silicon layer above the memory array region is formed into a pile of heteropolycrystalline silicon layer Sequentially shaped on the surface of the semiconductor wafer A first protective layer and a light-blocking layer; performing a first photolithography process, the memory cell array in a single zone to Inoue 第20頁 471136 六、申請專利範圍 方的該第一光阻層中定義出複數個閘極的圖案; 利用該第一光阻層的圖案當作硬罩幕,以蝕刻該記憶 陣列區上方之該保護層以及該摻雜多晶矽層,直至該第一 介電層表面; 去除該第一光阻層; 進行一第二離子佈植製程,形成該記憶陣列區中之各 該MOS電晶體的輕摻雜汲極(LDD); 於該半導體晶片表面依序形成一第一氮矽層以及一第 二介電層,並覆蓋於該記憶陣列區上之各該閘極表面; 去除該週邊電路區上之該第二介電層、該第一氮矽層 以及該保護層; 於該半導體晶片表面形成一第二光阻層; 進行一第二黃光製程,以於該週邊電路區之N型井以 及P型井上方的該第二光阻層中,定義出複數個閘極的圖 案; 利用該第二光阻層的圖案當作硬罩幕,蝕刻該週邊電 路區上方之該未摻雜多晶石夕層直至該第一介電層表面,以 於該週邊電路區上形成各該Μ 0 S電晶體之閘極; 去除該第二光阻層; 進行一第三離子佈植製程,形成該週邊電路區中之各 該MOS電晶體之輕摻雜汲極(LDD); 於該半導體晶片表面形成一第二氮矽層,並覆蓋於該 週邊電路區上之各該閘極表面; I虫刻該週邊電路區之Ρ型井上方之各該間極周圍的該Page 20 471136 6. The pattern of the plurality of gates is defined in the first photoresist layer in the patent application range; the pattern of the first photoresist layer is used as a hard mask to etch the upper part of the memory array area. The protective layer and the doped polycrystalline silicon layer up to the surface of the first dielectric layer; removing the first photoresist layer; performing a second ion implantation process to form a light weight of each of the MOS transistors in the memory array region Doped drain (LDD); sequentially forming a first silicon nitride layer and a second dielectric layer on the surface of the semiconductor wafer and covering each gate surface on the memory array region; removing the peripheral circuit region Forming the second dielectric layer, the first silicon nitride layer, and the protective layer; forming a second photoresist layer on the surface of the semiconductor wafer; performing a second yellow light process for the N-type of the peripheral circuit area Wells and the second photoresist layer above the P-type well, define a plurality of gate patterns; use the pattern of the second photoresist layer as a hard mask to etch the undoped layer over the peripheral circuit area Polycrystalline stone layer up to the surface of the first dielectric layer To form a gate electrode of each M 0S transistor on the peripheral circuit region; remove the second photoresist layer; perform a third ion implantation process to form each of the MOS transistors in the peripheral circuit region Lightly doped drain (LDD); forming a second silicon nitride layer on the surface of the semiconductor wafer and covering each gate surface on the peripheral circuit area; I etched the P-well above the peripheral circuit area Decisive 第21頁 471136 六、申請專利範圍 第二氮矽層,形成第一側壁子,並進行一第四離子佈植製 程,以於該P型井中形成NMOS電晶體的源極與汲極;以及 蝕刻該週邊電路區之N型井上方之各該閘極周圍的該第二 氮矽層,形成第二側壁子,並進行一第五離子佈植製程, 以於該N型井中形成PMOS電晶體的源極與汲極。 1 0.如申請專利範圍第9項之方法,其中該第一介電層係 由二氧化矽(Si 02)所構成,用來作為各該MOS電晶體的閘 極氧化層。 1 1.如申請專利範圍第9項之方法,其中該保護層係由一 氮矽化合物所構成,且該保護層與該未摻雜多晶矽層之間 另包含有一第一氣氧化石夕(S i 0 XN y)層,用來做為一抗反射 層(ARC )。 1 2.如申請專利範圍第9項之方法,其中在該半導體晶片 表面形成該第二光阻層之前,另可先於該半導體晶片表面 形成一第二氮氧化矽(Si OxNy)層當作抗反射層(ARC)。 1 3 .如申請專利範圍第1 2項之方法,其中在去除該第二光 阻層之後,亦須去除形成於該第二光阻層下方之該第二氮 氧化矽層。 1 4.如申請專利範圍第9項之方法,其中該第四以及第五Page 21 471136 VI. Patent application scope Second nitrogen silicon layer, forming a first sidewall, and performing a fourth ion implantation process to form a source and a drain of an NMOS transistor in the P-type well; and etching The second silicon nitride layer around each of the gate electrodes above the N-type well in the peripheral circuit area forms a second sidewall, and a fifth ion implantation process is performed to form a PMOS transistor in the N-type well. Source and drain. 10. The method according to item 9 of the scope of patent application, wherein the first dielectric layer is composed of silicon dioxide (Si 02) and is used as a gate oxide layer of each MOS transistor. 1 1. The method according to item 9 of the scope of patent application, wherein the protective layer is composed of a silicon nitrogen compound, and a first alumina oxide is further included between the protective layer and the undoped polycrystalline silicon layer (S i 0 XN y) layer is used as an anti-reflection layer (ARC). 1 2. The method according to item 9 of the patent application, wherein before the second photoresist layer is formed on the surface of the semiconductor wafer, a second silicon oxynitride (Si OxNy) layer may be formed on the surface of the semiconductor wafer as Anti-reflective layer (ARC). 13. The method according to item 12 of the scope of patent application, wherein after the second photoresist layer is removed, the second silicon oxynitride layer formed under the second photoresist layer must also be removed. 1 4. The method according to item 9 of the scope of patent application, wherein the fourth and fifth 第22頁 471136 六、申請專利範圍 離子佈植製程會分別對該P型井以及該N型井上方之各該閘 極中之該未摻雜多晶矽層進行摻雜。 1 5.如申請專利範圍第9項之方法,其中在形成完該週邊 電路區上之各該MOS電晶體的源極與汲極之後,該方法另 包含有下列步驟: 於該半導體晶片表面形成一金屬層,且該金屬層覆蓋於該 週邊電路區上之各該源極、汲極以及閘極表面之上; 進行一第一快速熱處理(RTP)製程; 進行一濕蝕刻,去除於該半導體晶片表面未反應之該金屬 層;以及 進行一第二快速熱處理(RTP)製程。 1 6 .如申請專利範圍第1 5項之方法,其中該金屬層係由鈷 (Co)、鈦(Ti )、鎳(Ni )或鉬(Mo)所構成。 1 7.如申請專利範圍第1 5項之方法,其中該第一快速熱處 理(RTP)製程的溫度範圍為4 0 0T:〜6 0 0°C ,加熱時間為1 0 〜50秒,而第二快速熱處理(RTP)製程的溫度範圍為6 0 0°C 〜8 0 0°C ,加熱時間為1 〇〜5 0秒。Page 22 471136 6. Scope of patent application The ion implantation process will dope the undoped polycrystalline silicon layer in the P-well and the gate above the N-well, respectively. 1 5. The method according to item 9 of the patent application, wherein after forming the source and drain of each of the MOS transistors on the peripheral circuit area, the method further includes the following steps: forming on the surface of the semiconductor wafer A metal layer covering the source, drain and gate surfaces on the peripheral circuit region; performing a first rapid thermal processing (RTP) process; performing a wet etch to remove the semiconductor The metal layer not reacted on the wafer surface; and a second rapid thermal processing (RTP) process is performed. 16. The method according to item 15 of the scope of patent application, wherein the metal layer is composed of cobalt (Co), titanium (Ti), nickel (Ni), or molybdenum (Mo). 1 7. The method according to item 15 of the scope of patent application, wherein the temperature range of the first rapid heat treatment (RTP) process is 400 ° T: ~ 600 ° C, and the heating time is 10-50 seconds, and The temperature range of the second rapid heat treatment (RTP) process is from 600 ° C to 80 ° C, and the heating time is from 10 to 50 seconds. 第23頁Page 23
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