經濟部智慧財產局員工消費合作社印制衣 46 9 1 6 9 A7 公—告本-2Z_ 五、發听1 ) ί.技術領域丨 本發明關於使用氣化钛粒子之食品容器，詳細的説即不 易弄髒，卽使弄髒也容易洗淨的容器。而且，如果是玻 璃製的食品容器時可以增加其機槭性強度，提供一種可 以長期保存的食品容器.在此所諝的食品也包括啤酒等 飲料 本由請專利是以日本國内的待許專利（恃願平1 〇 - 3 5 0 4 0 6 號及特願平1〗-2 86 114號>為基礎，本詳細説明書的部分 内容採甲該日本申請專利的記載内容„ (技術背景1 啤酒、果汁、牛奶等飲料及液體食物，搬蓮或儲存時 使用的捅.槽或槽車使用的大型槽等食品容器，可以因 應用途而使用玻璃、塑_、金颶等質材。其中金屬製的 容器因為耐久件較佳所以廣泛被使用，尤其不綉銷製的 容器不易生㈣更常使用。，另外，玻璃製的容器因具形狀 的自由性及低成本等特性也被重視。 以搬運或儲存為目的的食品容器，因重複使用而且多 在室外使用所以容器的外倒及瓶口等地方容易髒，希望 能容易洗淨.而a金屬製容器比不锈鋼製品脆弱，必須 增加厚度導致較重，因此希望能輕童化 為了讓食品容器不易髒，可進行氣處理例如利用氟糸 列樹脂包覆在容器表面等，加大與水的接觸角，亦即增 加撥水性等表面處理的方法。 但是在食品容器表面包覆氣系樹脂等表面處理方法， -3 - 本紙張尺度適用中國國家標準（CNS)A4規格（210x 297公釐） 〈請先閱讀背面之注意事項再填寫本頁) 裝-------訂---------線 469169 A7 _B7五、發明說明（2 ) 經濟部智慧財產局員工消費合作社印製 要法 量 清的度 容 以 器材厚 儲飲 h 品玻 向方 輕 易製強 的 所容的其 、等車食用 一理。器 容璃性 子 越性器少 蓮奶槽· 使 對處題容 .也玻械 粒 ，，優屬容減 搬牛及儲常 -面問使度 了是機 鈦洗性金品可 的 、以 、通 色表的了強髒別持 化清明等食以 料汁器蓮。 顔的落為性使特維 氧易透鋼。所 飲果容搬制 的想剝，械即，.能 有容的㈣器度 或' 等了限 器理及時機髒器也 含也膜不容強 品酒槽為的 容是損璃的弄容時 面了钛為的性 食啤 、質別 品不磨玻璃易品同 表髒ft若感械 於運桶材待 食，有是玻不食的 種使氣如潔機 用搬 '的無 繼言會質低種的度 一即為例清其 ，是如瓶器他 影而層材降一續厚 偽且因 ，及加 1 明器例的容其 會器覆的會供持璃 ，而 > 觀澤增 態發容 ..用些用 色容包器後提期玻 器 ，同外光為。型本品制使這適 顔品其容薄是長少容髒不的屬因瓶佳明食限 ， 需 之食用品變的可減一 品弄劑來金，的最説的的時等面 劑的使食度目果在之7^]食易覆本有時量的地用別物槽生 覆感期果厚的效，的®.Γ的不包器具璃輕明細使持食型衛 包潔長如璃明此器目 明此脂容為玻為發詳明無體大面 的清Η-玻發Η容為 Λ 發因樹有成為成施下發並液的金 用有而¾將本 ，品亦 Μ 本。和保可若而實以本等或闬安 使求、 化 冼食 .ί?器 可 ，質度 ί 藏料使在 ；-------1 I ------—訂·--—----- <請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 經濟部智慧財產局員工消費合作杜印製 469163 A7 _B7_ 五、發明說明（3 ) 璃、塑讓、金驅等，因為要搬蓮、反覆使用所以耐久性 沣的金騸及玻擒較理想，而金画中又以不易生锈的不i秀 鋼較理想。 這類的食品容器多使用於室外，例如，瓶口複雜的凹 凸形狀而容易餺不易洗淨的不銹鋼製啤酒桶，或由蘇打 石灰玻璃、硼矽玻璃形成的可回收性玻璃瓶等。 本發明使用的氣化钛粒子具有利用紫外線將有機物等 分解的光觸媒機能，對分解食品污垢的有機物、殺®、 防ih發落等效果佳。而且氣化鈦粒子的親水性高可以防 Ih食品的油成分等有機物或粉塵、泥砂等無機物附箸。 又，在玻璃容器中使用氣化鈦粒子時因為會增加其機械 件強度.所以可將玻璃厚度變薄而達到輕量化，5 這類氣化鈦粒子的結晶構造並無限制，通常使用正方 晶条中，低溫型的銳鈦礦型、高溫形的金紅石型、斜方 晶集的板鈦礦型之氧化鈦粒子，其中以板鈦礦型氧化鈦 粒子較理想含有板鈦礦型結晶的氣化鈦粒子可以只含 有板鈦礦型結晶fe可以同時含有金紅石型或銳鈦礦型的 氧化鈦粒子c·同時含有金紅石型或銳鈦礦型的氧化鈦粒 子時，其中板鈦礦聖氣化鈦粒子佔的比例並無特別限制， 通常在總重的1〜1 0 0 範圍以1 0〜1 0 0 %為佳，又以5 0〜 1 0 0 %較理想，:，這是因為板钛礦型氧化钛的光觸媒性能比 金紅石型或銳鈦礦型氧化钛的光觸媒性能優越。 含有板鈦礦型結晶氣化鈦粒子的製法有氣態和液態二 種：，氣態的製法是將銳鈦礦型氣化鈦粒子熱處理後得到 - 5 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1! I 1.1---I I*---ί — 訂----I--1線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作杜印製 4 6 9* 69 A7 _B7_ 五、發明說明（4 ) 含有板鈦礦型結晶的氣化鈦粒子；液態的製法是將四氣 化鈦、三氣化钛、烷氣鈦、硫酸鈦等钛化合物的溶液經 過中和、加水分解後得到有氧化鈦粒子分散其中的氧化 钛溶_ -. 這些製造方法R要能得到含有板钛礦型結晶的氧化鈦 粒平即可並無特别限制，若考慮所得物質的光觸媒性能 、使用方便性、形成氣化鈦薄膜時的透明性、密合性、 膜硬度等，以本發明的實例所示之方法較理想。也就是 在7 5〜1 0 0 D的熱水中加λ四氨化鈦，於7 5 t1以上溶液 的沸點以下之溫度，邊控制氣離子的濃度邊將四氨化钛 加水分解.得到含有板鈦型結晶氣化鈦粒子的氧化鈦溶 _ -或在7 5〜1 0 0 °C的熱水中加入四氣化鈦，硝酸離子 及磷酸離子單獨存在或同時存在的情況下，於7 5 t以上 溶液的沸點以下之溫度，邊控制氨離子、硝酸離子及磷 酸離子的總濃度邊將四氮化鈦加水分解，得到含有板鈦 型結晶氣化鈦粒子的氧化钛溶膠等方法，： 氧化鈦粒子的大小沒有持別的限制，通常苹均粒徑為 0 . 0 0 5〜0 . 1 μ m :因為大於0 . 1 u ra其光觸媒性能差，容 易髒Μ弄髒時不易將有機物分解也不易洗淨，另外氣化 鈦粒子的透明性也會降低，食品容器的表面含有這類氧 化钛粒子時，氣化钛粒子顔色會影饗食品容器的顔色並 不滴合.若氧化鈦粒子小於0 . 0 0 5 « m ,在製造工程中不 易處理。又，氣化鈦粒子的表面積比通常在2 0 m 2 / s以上 將從上述方法得到的氣化鈦粒子固定在食品容器表面 -6 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ----------I I^.1------訂·--------- (請先閲讀背面之注意事項再填寫本頁) /569169 A7 _B7五、發明說明（5 ) 經濟部智慧財產局員工消費合作杜印製 品器上氧 金解 的 、刷即 熱鈦 。處的劑又 品酸、 食容器將 等電 別法、亦 '化等的器合髒 食磷矽 在在容接 鋼、 持層法， 燥氣物層容接易 用如化 塗箸品直ίι換 有塗層量 乾在驅内品或不 使例氣 膠附食劑 不交 沒動塗抹 過以前成食劑有 因酸如 溶會在合 蝕子 法流輪塗 經可劑形和肋保 類特例 的子塗接 腐離 方 、滾的 ，，合行子結能 種斯用 子粒合用 會、 的法、_h時接進粒燒仍 的巴使 粒後混以 能析 上層法溶 器上 、劑鈦的間 物布可 欽結等可 可透 。器塗層子 容面劑合化類時 驅用劑 化燒料tt1 電想容轉塗粒fno品表合接氣這長 前使合 氣 '塗 於 、理品旋軸鈦 y 食器接塗加加過 劑可接 將理和法上低淨較食的 '化00茌容或上增添經 合劑 。 是處子方器若洗上在用法氧-1塗在劑面可由， 接肋酸 種熱粒等容PH濾以塗採層 ，.01_ 著肋表劑經落 '結羧 一 、鈦理品的過 1膠遍塗等 ο 溶附結器合，剝 劑燒機 ，煥化處食顧以在溶普霧法為的子燒容接度易 ，合 ，有 種乾氣熱在溶 ，制子用噴潰約子粒加品或硬不果接異等 二過將 '定子器控粒使 '浸常粒後添食劑膜子效或而酸 有經或燥固粒容PH鈦以法 、通鈦結中在肋及粒的爾質醋 法 ， '乾子鈦品將化可層法度化燒_先結度鈦洗肋材¾ 行上 h. 過粒化食法氣 ，塗翳厚氧 .'溶以燒強化清結的酸 的器面铧鈦氯製方將制染塗的將理子可。合氣易燒器鹽 上容表再化 屬等 限浸子膜 處粒也理接 ，容 容 、 ----r--------I --------訂·--------線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 4 S 9 I 6 9 A7 _B7_五、發明說明（6 ) 氣化鈦、氧化鋁、氣化鈷、氧化鈣、氧化錳等金颶氣化 經濟部智慧財產局員工消費合作社印製 強結基劑氧 箸化器要有容璃矽 氣概這易 上加00 膜燒氣合烷。藉氧容只面若玻基 的大及不 以添00 及是乙接的.劑，或品現表。是氣 成時鈦又 種 C-1 性別四 '的合蓋物食發為強若乙 形酸化佳 二擇 m 合特、酯等接覆驅與且因性，四 物礎氧度 或選PP 接，烷酸矽成基前別而器合酸、 驅用、強 用由10 加想矽乙基形羥其分，容接磷烷 前使結膜 使自為 增理基的氣而或及劑合品的用矽 劑，化 > 獨以常 可較氣鈦乙烷氣硅合結食劑使基 合料氧上 單可通 等質甲 、四氣被化接力的合好氣 接材 、以 種例鈦 物物四物.矽會氧或強製接最甲 、的矽6H一比化 氣類的氧矽聚中的劑成屬與劑四 劑器化度 以的氧 院這物烷基機氣合肋形金以肋的 合容氧硬 可合於 的用驅的氣有空結結合。所結物 接饗用筆 劑混對 颶使前鈦甲、在醇燒縮力，燒驅 或影使鉛 合時相 金以劑 -四烷面烷使面合在時前 劑會 ，為 接用量 哇物合物。氣表矽可表接存鋼劑，肋度上槪 或使加 這 _ 接氣等矽的成，的的層銹合物結硬以大 劑合添 有前或烷物聚子形物子越物不接氧燒其4H時 肋混其 含劑酸矽合成粒可驅粒優化是用烷類 ，度物 結 ，時 為合链的螯合鈦酸前鈦有氣質使矽這糢硬驅 燒用劑 因接的等的縮化锘其化就的材奸的用薄筆前。呰使肋 , ，劑烷钛 .氣用及氣量屬的最等使鈦鉛的落這合結 物度肋矽中物 使鈦及少金器時烷 化為些剝 混燒 ------^--------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用令國國家標準（CNS)A4規格（210 X 297公釐） A7 469169 B7_ 五、發明說明（7 ) P P m ,劣於1 0 0 0 0 p p m必須將燒結溫度設高，延長燒結時 間較不理想，低於1 0 P P in燒結效果差：，添加接合劑、接 合劑前驅物時的添加量，若將這些以氣化物換算通常為 氣化钛重最的5〜5 0 %。多於重量的5 0 % ,因為埋在接 合薄ί中之氣化钛粒子的比例增加使塗膜的光觸媒活性降 低，少於重量的5%，接合劑的效果差不理想。 添加燒結叻劑或接合劑、接合劑前驅物的方法没有特 別的限制，可以先添加在氧化钛溶膠中再塗在食品容器 上；或當氣化鈦溶Ρ以噴霧塗層法塗抹時，燒結肋劑或 接合劑、接合劑前驅物以別的噴霧器塗抹C· 氧化鈦粒子的溶讀塗在食品容器後，乾燥時為了加快 乾燥速度可以添加適當溶媒，通常當氧化钛溶_分散在 水中時使用乙醇等有機溶媒。， 又、氣化鈦粒子的溶瞟塗在食品容器前，為了防止食 品容器因氣化鈦而劣化，可以使用含有矽膠、氟樹脂等 的溶液塗在食品容器的表面，乾燥後形成保護膜。 將氣化钛粒子的溶_塗在食品容器後，進行乾燥、熱 處理使氣化鈦粒子固定在表面上。進行乾燥、熱處理的 環境沒有限制，可在大氣中、真空中、惰性氣體中，通 常在大氣中進行：其溫度視食品容器的材質或使用燒結 肋劑、接合劑、接合劑前驅物的種類而異，通常在2 0〜 80 0'Γ ,若使用燒結叻劑、接合劑、接合劑前驅物則在 2 0〜4 5 0 °C ,,乾燥、熱處理的時間通常為5分鐘〜2 4小 時，以〗5分鐘〜1 2小時較理想。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -------------^-------- 訂----J I---. (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 A7 /69169 ____B7____ 五、發明說明（8 ) 例如，t品容器的材質是不锈鋼或玻擒時，使闬磷酸 當燒結肋割在1 0 0〜4 5 Ο ΐ:下處理.又以氣化矽或其前驅 物的四甲氯基矽烷、四乙氣基矽烷、鈦的烷氧物、螯合 物、乙酸_等作為接合劑、接合劑前驅物，在20〜450f 處理後可增加氣化鈦粒子形成暌的硬度較理想，.此時熱 琮理的時間通常為5分鐘〜2 4小時，以1 5分鐘〜1 2小時 較理想 使用燒結肋劑或接合劑、接合劑前驅物可在2 0〜4 5 0 t 的低溫下將氣化鈦粒子固定在容器的表面上，所以可以 降低熱處理的能量成本。而且食品容器的材質是玻璃時 ，不需加熱到玻璃的軟化溫度將氣化鈦粒子融著，在低 於破璃的軟化溫度下就可將氣化鈦粒子固定在容器表面 ，因此可防止玻璃變形。玻璃的軟化溫度通常在500 1 以上。 如此得到表面含有氧化鈦粒子的食品容器其薄膜的厚 度通常為0.005〜10y is，以0.03〜0.5u is較理想。比 0.005^ !«薄光觸媒活性或親水性不足，比1〇/^11!厚則光 觸媒反應只在氣化鈦薄暌表面的附近進行，導致不進行 光觸媒反應的氣化鈦增加造成浪費，薄膜也容易與食品 容器剝離，而且降低氧化鈦薄膜的透明性較不理想 如此表而含有氣化鈦粒子的食品容器，籍由氧化鈦粒 子的光觸媒機能將附著的污垢分解，&可殺傷接觸的微 生物抑制其增殖。另外，因為氧化鈦粒子的親水性佳， 與水的接觸角在2 0度以下，所以在室外使用的容器其外 -1 0 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ^--------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 /16 9 1 6 9 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（9 ) 側及瓶Π處不易有污垢附箸，即使弄髒也容易洗淨。由 氣化钛粒子形成的膜其透明性佳不會影響食品容器的顔 色、而目氣化钛薄膜會使玻璃製食品容器的機械性強度 增加 使用掩合劑及/或燒結肋劑將氣化钛粒了·固定在食品容 器表而上，使粒子與表面有強力的接合因此膜硬度佳、 不易剝落、經過長時間仍能保有上述效果。而且將氣化 钛粒子固定在食品容器表面的溫度在20〜450 °C的低溫 ,可以降低熱處理的能量成本同時若為玻璃製食品容器 時還可防lh因高溫産生的變形。 像這樣的食品容器不僅在室内使用也使用於室外，特 别適用在瓶口有複雜凹凸形狀、大小有複雜曲線，容易 弄髒但不易洗淨的不誘銷製啤酒桶、玻璃製啤酒瓶等。 啤酒的成分，水佔電匮的9 1〜9 3 ίϋ、乙醇為3 . 3 - 3 . 9 %、 萃取液為3 .〗〜4 , 0% ,二氧化硪為0 , 4 2〜0 . 5 5 5S t其中 不揮發件有機物的萃取液含有由糊精等全糖形成的碳水 化合物約75〜80% ，因此啤酒成分中的萃取液為污染 之ΐ因 含有板鈦礦型結晶的氣化鈦粒子之光觸媒機能，可以 分解因糊精等有機物造成的污染，具有不易污染及即使 弄髒容易清洗之特性 菁例 以下，舉實例具體説明本發明。 宵例1 -1 1 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝--------訂---------線 經濟部智慧財產局員工消費合作杜印製 A7 _B7_ 五、發明說明（1G) 在内容量1L附有回流冷卻器的玻璃反應槽内裝入954isL 的蒸餾水，並在9510下加溫。接箸以大約200rpm的速度 it拌反應槽，槽内液溫維持在9 5 t並將4 6 a L的四氯化鈦 溶液以大約2m L/ rain的速度滴入反應槽，如此可得四氣 化鈦濃度為0 . 2 5 m 〇 ! / !,(氣化鈦的重量濃度為2 % )的溶液 。四氣化鈦溶液滴完後加熱至沸點1 0 4 °C左右並維持在 此溫度下達60分鐘，可加水分解四氰化鈦。並冷卻濃縮 眈溶隱，利闬旭化成工業（股）製的電透析G 3型装置以電 透析的方法去除加水分解生成的氣，得到pH4.0(氣離子 濃度約4 Ο 0 p p m )的水分散氣化鈦粒子溶膠，並以穿透型 電子顯徹鏡觀察溶隱中粒子的粒徑為0.01〜0.03W ns。 為了觀察溶瞜中所含氣化鈦粒子的結晶構造將此溶膠 置於60t的真空乾燥器中乾燥，再利用理學電機（股）製 的X線繞射裝置（RAD-B rotor flex)以X線繞射分析氣 化鈦粒子，此裝置的管球為銅製品。結果顯示在2Θ =30,8 檢出板鈦礦型結晶（1 2 1 )面繞射的波峰，金紅石型及 鋭钛礦型没有被檢出。為了將上述所得含板鈦礦型結晶 的水分散氣化鈦溶賴塗在容器上，添加矽膠条接合劑的 四甲氣基矽烷當接合劑前驅物及可加快乾燥速度的乙醇， 調製成表1所示組成份的塗料。 以刷子塗層法將所得塗料塗抹在不銹網製啤酒桶（1 0 L ) ，在大氣中，501下乾燥I小時後再經過20〇υ、2小 時熱處理，可得表面含有厚為0 . 4 u m氧化鈦薄膜的啤酒 桶。 -12- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） --------：-----^--------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 469169 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（11 ) 以噴霧器將1 L的啤酒噴在此啤酒桶的上面及側面，放 在宰外：？値月後觀察啤酒桶的外觀。待別是在有複雜凹 凸形狀的瓶口部分污垢強，並評估其不易污染的程度.3 之後以1 0 U 2 0 f的水冲淋在啤酒桶，觀察並評估洗淨 污垢的容易度，，结果如表2所示。 表1 1 曹例 酸化氩化鈦 四甲氣基矽烷 乙醇 號數 (T i 0 2 )[重量 ％ ] S i 0 2換算[重量％ ] [重量％ ] 菁例1 2.5 0.5 75 奮例2 2 . 5 響 75 曹例3 5.0 1.0 75 啻例4 2.5 0.5 75 啻例5 2,5 0.5 75 菁例B 2.5 - 75 -13- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） . ^--------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 46 9 ? 6 9 A7 B7 五、發明說明（1 2 )Printed clothing for consumer cooperatives of employees of the Intellectual Property Bureau of the Ministry of Economic Affairs 46 9 1 6 9 A7 Announcement-2Z_ Fifth, Announcement 1) Technical Field The present invention relates to food containers using vaporized titanium particles. A container that is not easily soiled, making it easy to clean when soiled. In addition, if it is a glass food container, it can increase its mechanical strength and provide a food container that can be stored for a long time. The food here also includes beer and other beverages. Based on patents (恃 Wing Hei 1 0-3 0 5 4 0 6 and 愿 Wing Hei 1-2 86 114) > part of the contents of this detailed description is based on the contents of the Japanese patent application „(technology Background 1 Beverages such as beer, fruit juice, milk, and liquid foods, and food containers such as large tanks used in lotus transportation or storage tanks for storage of lotuses or tank cars can be made of glass, plastic, or golden hurricane depending on the application. Among them, metal containers are widely used because of their durable parts. Especially non-embroidered containers are not easy to be used more often. In addition, glass containers are also valued for their freedom of shape and low cost. Food containers used for transportation or storage are reused and used outdoors. Therefore, the container is easy to be dirty when it is poured out and the mouth of the bottle is easy to clean. A metal container is better than stainless steel. It is fragile and must be thickened to cause heavy weight. Therefore, we hope to make it lighter. In order to prevent food containers from getting dirty, you can perform gas treatment, such as coating the surface of the container with fluororesin resin, etc., to increase the contact angle with water, that is, increase Surface treatment methods such as water repellency. However, the surface of food containers is covered with surface treatment methods such as gas-based resin. -3-This paper size is applicable to China National Standard (CNS) A4 (210x 297 mm). <Please read the back Note: Please fill in this page again.) Install ------- Order --------- line 469169 A7 _B7 V. Description of Invention (2) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs The degree of capacity is based on the thick storage of the drink. The glass is easy to make it strong, and it can be eaten by the car. The device contains glass, the sex, the sex, and the Shaolian milk trough. It ’s better to move cattle and store the food, and to save it, it ’s organic titanium washable gold. It ’s clean, strong, dirty, clean, clear, and so on. It ’s a juicer. The nature makes Tevi oxygen easy to penetrate steel. If you want to peel the fruit, you can peel it off. .Can contain the degree of organs or 'wait for the limiter and timely machine organs also contain membranes that are not tolerated. The capacity of the wine tasting tank is a loss of glass, and the face is made of titanium for beer and quality products. If the glass is not ground, the product is the same as the surface. If the machine is ready to be eaten, there is a kind of glass that is inedible, so that the air is clean, and the quality is low. It is because the bottle is different and the layer material is still thick and false, and because it is added with a container, it will be used for holding glass, and > Guanze increases the capacity .. use some After the color container, the lifting glass is the same as the external light. This type of product makes this suitable product the thinness of the product is the length of the bottle and the viscera. It is due to the bottle's food limit, and the required food can be reduced by one product. Get the gold, the most said is the instant noodles to make the appetite and fruit 7 ^] food easy to cover the amount of the effect of using a different material tank to cover the thick effect of the sensation period, ®.Γ The light details are not included to make the food-holding toilet bag clean and long. The device is clear. The fat is clear and the body is clear. The glass is clear. The glass is Λ. The gold used to release and liquid is ¾ will be the book, the product is also Μ 本. Hebao can use the original or the security to make a request and change the food. Ί? The device can be, the quality is ί The collection of materials is used; ------- 1 I -------- order -------- < Please read the notes on the back before filling out this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) Printed 469163 A7 _B7_ V. Description of the invention (3) Glass, plastic transfer, gold drive, etc., because of the need to move the lotus and use it repeatedly, the durable gold tincture and glass trap are ideal, and the gold painting is not easy to rust Xiu Steel is more ideal. This type of food container is mostly used outdoors. For example, stainless steel beer kegs with complicated concave and convex shapes and easy to clean, or recyclable glass bottles made of soda lime glass and borosilicate glass. The vaporized titanium particles used in the present invention have a photocatalyst function that decomposes organic matter and the like by ultraviolet rays, and has good effects on decomposing organic matter of food dirt, sterilization, and prevention of ih fall. In addition, the vaporized titanium particles have high hydrophilicity, and can prevent organic matter such as oil component of Ih food or inorganic matter such as dust and mud. In addition, the use of vaporized titanium particles in glass containers increases the strength of the mechanical parts. Therefore, the thickness of the glass can be reduced to reduce the weight. 5 The crystal structure of such vaporized titanium particles is not limited, and tetragonal crystals are usually used. Among the strips, low-temperature anatase-type, high-temperature rutile-type, orthorhombic-set brookite-type titanium oxide particles, among which brookite-type titanium oxide particles preferably contain brookite-type crystals. Vaporized titanium particles may contain only brookite-type crystals, fe may contain both rutile-type or anatase-type titanium oxide particles, and c. Rutile-type or anatase-type titanium oxide particles, There is no particular limitation on the proportion of Saint-Gas titanium particles, usually in the range of 1 to 100% of the total weight is preferably 10 to 100%, and more preferably 50 to 100%. It is because the photocatalyst performance of brookite-type titanium oxide is superior to that of rutile-type or anatase-type titanium oxide. There are two methods of preparing gas phase titanium particles containing brookite-type crystalline gasification: gaseous method is obtained by heat-treating anatase-type gasification titanium particles-5-This paper size applies Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) 1! I 1.1 --- II * --- ί — Order ---- Line I--1 (Please read the notes on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs Consumption cooperation by employees 4 6 9 * 69 A7 _B7_ V. Description of the invention (4) Vaporized titanium particles containing brookite type crystals; the liquid method is to produce titanium tetraoxide, titanium trioxide, alkane titanium Solutions of titanium compounds such as titanium sulfate, titanium sulfate, etc. are neutralized and hydrolyzed to obtain titanium oxide solution in which titanium oxide particles are dispersed.-These production methods R are necessary to obtain titanium oxide particles containing brookite type crystals. There is no particular limitation, if the photocatalyst performance, convenience of use, transparency, adhesion, film hardness, etc. of the vaporized titanium thin film obtained are considered, the method shown in the examples of the present invention is ideal. That is to say, λ tetraammine titanium is added to hot water at 75 to 100 D, and the titanium tetraammine is decomposed into water while controlling the concentration of gas ions at a temperature above the boiling point of the solution above 7 5 t1. Titanium oxide dissolved in plate titanium-type crystallized titanium particles-or add titanium tetraoxide to hot water at 7 5 to 100 ° C. Nitrate ions and phosphate ions are present separately or simultaneously. At a temperature below the boiling point of a solution of more than 5 t, the titanium tetranitride is hydrolyzed while controlling the total concentration of ammonia ions, nitrate ions and phosphate ions to obtain a titanium oxide sol containing plate titanium type crystallized titanium particles, and other methods: There are no other restrictions on the size of titanium oxide particles. Generally, the average particle diameter is 0. 0 5 to 0. 1 μm: Because it is larger than 0.1 u ra, its photocatalytic performance is poor, and it is not easy to stain organic matter when it is dirty and soiled. Decomposition is not easy to clean, in addition, the transparency of the vaporized titanium particles will be reduced. When the surface of food containers contains such titanium oxide particles, the color of the vaporized titanium particles will affect the color of the food container and will not drip. Particles smaller than 0. 0 0 5 «m in manufacturing engineering Not easy to handle. In addition, the surface area ratio of the vaporized titanium particles is usually more than 20 m 2 / s, and the vaporized titanium particles obtained from the above method are fixed on the surface of a food container.-This paper is in accordance with the Chinese National Standard (CNS) A4 standard (210 X 297 mm) ---------- II ^ .1 ------ Order · --------- (Please read the precautions on the back before filling this page) / 569169 A7 _B7 V. Description of the invention (5) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs have co-operated with the printed materials of Du printed products, and they are hot titanium. The product is acidic, and the food container will be used for isoelectric method, and it is also used to contain dirty food phosphorus silicon in the receiving steel, holding layer method, and the dry layer is easy to use, such as chemical coating. I changed the coating amount to dry in the drive product or to keep the aerosol adhesive and food additives intact. I have previously applied the food additives. If the acid is soluble, they will be applied on the flow wheel of the Synthetic Oxide Method. In the special case of protection, the coating is rotten away from the square, rolled, and the combination of seeds and seeds can be used in combination with the method. When _h is used, the granules are still mixed, and the granules are mixed with the upper layer method. The top and bottom titanium interstitial cloth cochin knot and other cocoa transparent. Device coating, surface coating agent, compounding agent, driving agent, sintering material, tt1, electric capacity, transfer coating, fno, surface, and gas Adding the agent can be used to combine the low net clean food and chemical formula or add Jingjing. If you wash it on the square, you can use the oxygen-1 to apply it on the surface of the agent. The acid volume of hot-grained isotonic PH filter is used to coat the layer. After 1 glue spreading and coating, etc., dissolving and attaching the device, dissolving the burner, and refining the food, the solvent is easy to melt and melt, and there is a kind of dry gas heat dissolving. Use the blaster to add seeds or add fruit or not, and then change the 'stator device to control the granules' to soak the regular granules, then add the film of the food agent, or the acidity or dryness. The quality and vinegar method of ribs and grains in titanium knots, 'Dried Titanium products will be burned by the layer method _ first knot degree titanium wash ribs ¾ line h. Granulated food gas, coated with thick oxygen. 'Solve the surface of the acid to strengthen the scorched acid. Titanium Chloride will make the dyed and coated Ryoko. Aqueous easy-burner salt on the surface of the surface re-chemical genus and other limiting immersion sub-membrane particles are also connected, the capacity, ---- r -------- I -------- order · -------- Line (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 4 S 9 I 6 9 A7 _B7_ V. Description of the invention (6) Titanium gasification, alumina, cobalt gasification, calcium oxide, manganese oxide and other gold hurricane gasification Ministry of Intellectual Property Bureau Employees' Consumer Cooperatives printed a strong binder base oxygenator to print glass Silica gas is easy to add 00 film burning gas alkane. The oxygen capacity can only be used if the glass base is large and does not add 00. It is an adhesive, or the product is on display. It is a titanium and a C-1 sex of the four's cover when the gas is formed. The food and hair are strong if the acidity of the sigmoid is good. The combination of ethoxylate and ester is driven by the nature. Before the silicon alkanoate is formed into a base, it is necessary to combine the acid, drive, and strong use by adding 10 to the silyl-type hydroxyl group. Before receiving the phosphane, the conjunctiva is made into a gas that is a conditioner or the combination The product uses silicon agent, which can be used to make the base material oxygen on the single material, which can pass the quality of nails, and the four gas is relayed. For example, titanium materials, four materials, silicon can be oxygen or forcedly connected to the most silicon, silicon, 6H, and other oxygen compounds in the silicon polymerization. Rib-shaped gold is combined with ribbed oxygen-capacity and air-to-air junctions. The resultant is then mixed with a pen to the titanium alloy before the hurricane, when the alcohol shrinks, burns out, or affects the lead, the phase of the metal is mixed with the agent-tetradecane and the surface is mixed with the agent. Dosage Wow. Gas surface silicon can be stored with steel agent, the ribs can be increased, or the layer of rust can be hardened by adding silicon and other silicon. When the material is not oxygen-burned, the ribs are mixed with the agent containing silicon acid. The synthetic particles can be driven by particles. The optimization is to use alkanes, which are bonded together. When the chain is chelated, the titanate has a temperament, which makes the silicon hard to burn. Use a thin pen before using the thinner because of the shrinkage of the agent.呰 make ribs, titanium agents. The best use of gas and gas volume is to make titanium and lead come together. The content of ribs in silicon makes alkylation of titanium and few gold vessels to some peeling and mixing .-- -^ -------- Order --------- Line (Please read the precautions on the back before filling this page) This paper size is applicable to the national standard (CNS) A4 specification (210 X 297 mm) A7 469169 B7_ V. Description of the invention (7) PP m, inferior to 1 0 0 0 0 ppm must set the sintering temperature high, prolonging the sintering time is not ideal, and the sintering effect is lower than 10 PP in: When adding a bonding agent and a bonding agent precursor, these are usually 5 to 50% by weight of the vaporized titanium when converted into a gaseous substance. More than 50% by weight, because the proportion of titanium dioxide particles buried in the thin film increases, which reduces the photocatalytic activity of the coating film, less than 5% by weight, and the effect of the bonding agent is not ideal. The method of adding a sintering agent or a bonding agent or a precursor of the bonding agent is not particularly limited. It can be added to a titanium oxide sol and then coated on a food container; or when the vaporized titanium solution P is applied by a spray coating method, sintering Ribs, adhesives, and adhesive precursors are coated with C. titanium oxide particles using another sprayer. After coating on food containers, a suitable solvent can be added to speed up the drying process. Usually when titanium oxide is dissolved in water Use an organic solvent such as ethanol. In addition, before the solution of the vaporized titanium particles is coated on the food container, in order to prevent the food container from being deteriorated by the titanium vaporization, a solution containing silicone, fluororesin, etc. can be used to coat the surface of the food container and form a protective film after drying. After dissolving the vaporized titanium particles on a food container, drying and heat treatment are performed to fix the vaporized titanium particles to the surface. The environment for drying and heat treatment is not limited. It can be performed in the atmosphere, vacuum, or inert gas, usually in the atmosphere: its temperature depends on the material of the food container or the type of sintered rib, bonding agent, and bonding agent precursor. Different, usually at 20 ~ 80 0'Γ, if using sintering agent, bonding agent, binder precursor at 20 ~ 4 50 ° C, drying, heat treatment time is usually 5 minutes to 24 hours It is ideal to use 5 minutes to 12 hours. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------------- ^ -------- Order ---- J I-- -. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 / 69169 ____B7____ V. Description of the invention (8) For example, when the material of the t-product container is stainless steel or glass, The phosphoric acid is cut when the sintering rib is at 100 ~ 4 5 〇 ΐ: and then treated with tetramethylchlorosilane, tetraethylsilylsilane, titanium alkoxide, and chelate gasified silicon or its precursor. As a bonding agent, a precursor of the bonding agent such as acetic acid, etc., it is ideal to increase the hardness of the titanium oxide particles to form hafnium after 20 ~ 450f treatment. At this time, the heat curing time is usually 5 minutes to 24 hours. It is ideal to use sintered ribbing agent or bonding agent or bonding agent precursor for 15 minutes to 12 hours. The titanium oxide particles can be fixed on the surface of the container at a low temperature of 20 to 450 tons, so the heat treatment can be reduced. Energy costs. Moreover, when the material of the food container is glass, it is not necessary to heat the glass to the softening temperature of the glass to melt the vaporized titanium particles, and the vaporized titanium particles can be fixed on the surface of the container at a temperature lower than the softening temperature of the broken glass, which can prevent the glass Deformation. The softening temperature of glass is usually above 500 1. In this way, the thickness of the film of the food container containing titanium oxide particles on the surface is usually 0.005 to 10 μs, and preferably 0.03 to 0.5 μs. Less than 0.005 ^! «Thin photocatalyst is insufficient in activity or hydrophilicity, thicker than 10 / ^ 11 !, the photocatalyst reaction is only carried out near the surface of the thin titanium oxide thin film, which results in the increase of waste of titanium oxide without the photocatalyst reaction, and the thin film It is also easy to peel off from food containers, and it is less desirable to reduce the transparency of titanium oxide films. Food containers containing vaporized titanium particles, as shown in the table, can decompose attached dirt by the photocatalyst function of titanium oxide particles. Microorganisms inhibit their proliferation. In addition, because titanium oxide particles have good hydrophilicity, and the contact angle with water is below 20 degrees, the outside of the container used outside-1 0-This paper size applies to China National Standard (CNS) A4 (210 X 297) Mm) ^ -------- Order --------- line (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs / 16 9 1 6 9 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (9) The side and the bottle are not easy to be stained with dirt, and it is easy to wash even if it is soiled. Films made of vaporized titanium particles have good transparency and will not affect the color of food containers, and the gasified titanium film will increase the mechanical strength of glass food containers. Use masking agents and / or sintering ribs to vaporize titanium. The granules are fixed on the surface of the food container, so that the particles are strongly bonded to the surface, so the film has good hardness, is not easy to peel off, and can maintain the above effects over a long period of time. In addition, the temperature at which the vaporized titanium particles are fixed on the surface of the food container is a low temperature of 20 to 450 ° C, which can reduce the energy cost of heat treatment, and prevent glass from being deformed by high temperature if it is a glass food container. Such food containers are not only used indoors but also outdoors, and are especially suitable for non-seductive beer kegs and glass beer bottles that have complicated concave and convex shapes on the mouth of the bottle, have complex curves in size, and are easy to stain but not easy to clean. The composition of beer, water accounts for 9 1 ~ 9 3 ϋ, ethanol is 3.3-3.9%, the extract is 3. 0 ~ 4, 0%, osmium dioxide is 0, 4 2 ~ 0. 5 5 5S t The extraction liquid of non-volatile organic matter contains about 75 ~ 80% of carbohydrates formed from whole sugars such as dextrin, so the extraction liquid in beer ingredients is contaminated due to gasification containing brookite type crystals The photocatalyst function of titanium particles can decompose pollution caused by organic substances such as dextrin, and has the characteristics of being difficult to contaminate and easy to clean even if soiled. The following are examples of the present invention. Example 1 -1 1-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -------- Consumption cooperation between employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, Du printed A7 _B7_ V. Description of the invention (1G) Put 954isL of distilled water in a 1L glass reaction tank with a reflux cooler, and Warm at 9510. Then, stir the reaction tank at a speed of about 200 rpm. The liquid temperature in the tank is maintained at 9 5 t and 4 6 a L of titanium tetrachloride solution is dropped into the reaction tank at a speed of about 2 m L / rain. A solution having a vaporized titanium concentration of 0.25 m 0 //, (2% by weight of the vaporized titanium). After the tetra-titanium solution is dripped, it can be heated to a boiling point of about 104 ° C and maintained at this temperature for 60 minutes. The titanium tetracyanide can be decomposed by adding water. It was cooled and concentrated to dissolve the condensate. The electrodialysis G 3 type device manufactured by Asahi Kasei Kasei Kogyo Co., Ltd. used electrodialysis to remove the gas generated by hydrolysis and obtain water with a pH of 4.0 (the gas ion concentration is about 4 0 0 ppm). The vaporized titanium particle sol was dispersed, and the particle size of the particles in the dissolution was observed with a transmission electron microscope to be 0.01 to 0.03 W ns. In order to observe the crystal structure of the vaporized titanium particles contained in the solution, this sol was dried in a 60t vacuum dryer, and then an X-ray diffraction device (RAD-B rotor flex) made by Rigaku Electric Co., Ltd. was used to X Wire diffraction analysis of vaporized titanium particles. The tube of this device is a copper product. The results show that the peaks diffracted from the brookite type crystal (1 2 1) plane are detected at 2Θ = 30,8, but the rutile type and brookite type are not detected. In order to dissolve the water-dispersed and vaporized titanium containing brookite-type crystals obtained above onto a container, tetramethylsilyl silane, which is a silicone strip bonding agent, was added as a precursor of the bonding agent and ethanol capable of accelerating the drying speed to prepare a table. The coating of the composition shown at 1. The resulting coating was applied to a stainless steel beer keg (1 0 L) by a brush coating method, and dried in the air at 501 for 1 hour and then heat-treated for 20 hours and 2 hours to obtain a surface with a thickness of 0. Beer barrel with 4 um titanium oxide film. -12- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) --------: ----- ^ -------- Order ---- ----- line (please read the precautions on the back before filling this page) 469169 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (11) Spray 1 L of beer on this beer with a sprayer The top and sides of the barrel are placed outside the slaughter:? After the next month, observe the appearance of the beer barrel. Wait until the bottle mouth with a complicated uneven shape is strong in dirt and evaluate the degree of non-pollution. 3 After that, rinse the beer barrel with 10 U 2 0 f water, observe and evaluate the ease of cleaning the dirt, The results are shown in Table 2. Table 1 1 Example of Cao acid acidified titanium argon tetramethylsilyl alcohol (T i 0 2) [wt%] S i 0 2 conversion [wt%] [wt%] cyanide example 1 2.5 0.5 75 fen example 2 2 5 Rings 75 Cao Case 3 5.0 1.0 75 Case 4 2.5 0.5 75 Case 5 2,5 0.5 75 Case B 2.5-75 -13- This paper size applies to China National Standard (CNS) A4 (210 X 297) ^). ^ -------- Order --------- line (Please read the notes on the back before filling this page) 46 9? 6 9 A7 B7 V. Description of the invention (1 2 )
1 奮例號數 不易污染程度 洗淨容易洗淨程度 菁例1 ◎ ◎ 窨例2 ◎ ◎ 實例3 〇 〇 W例4 .〇 〇 富例5 ◎ ❹ 實例6 ◎ ◎ 比較例1 X X 比較例2 X X -----.11---^--------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 表2中所示符號分別表示以下内容 1 .不易污染程度 ◎......幾乎没有污垢 〇......少許污垢 X......很多污垢 -14' 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 4 6 9 1 6 9 A7 _B7五、發明說明（13 ) 經濟部智慧財產局員工消費合作社印製 應將60驟中 構及銳別 、的 化但鈦值 反驟約步嘐 晶峰胄判Itl晶下 氣，鋭d 入步子同溶 結皮l·,法 J 結以 的峰和在的 加同離相察 的 無¾^型由 晶波型型5 式相氣做觀 子彳 以ί&礦可 结射礦礦重 y-JH 35^ 形做91地 粒燒峰所㈣鈦率 型繞钛鈦是 的11.例同 钛面皮螢面銳有 石線板板蜂 3 例為實相 化丨έί重丨、含 红 X是而波 Ρ0實ΡΗ與1 氣21Ϊ峰04晶約 金的別52傾 以與的夕.伊 e 含^~燒波_~^結晶 、示特 33 淨 酸外®m實"所晶1·主晶型結 晶所，、這 洗 磷之溶Π!)和03中結 > 的結礦些 結^)多51上 淨易淨 前此得PP並 ο 膠型10型型鈦這 犁 π 很3 質 洗不洗 之除所00溶礦(1礦礦板’ 礦PD分為事 易後難 液，使 wlgol察钛蜂鈦鈦為物 钛JC部別 , 容稍很 溶pm。 t 溶 ο 觀板波板鋭 _ 合 銳自的分峰 度染垢垢 水0P解T,'鈦為地示主與示溶混 、錄 #值波 程污污污 钛20分 化徑同顯的峰顯的的 晶摘重 d 一 淨)一〕 化為水 氣粒相出犁波出得晶 結3(知的另 洗一 一 _ 氣成加酸散其1檢石主檢所結，型表可峰有 易· · ‘ 四度敎 ett 分，伊果紅的PT知型出礦有俏波ft 容 ©CX2 入濃化 水子啻結金型是可石算钛別 άΐϋ 2 例滴使氣 m 到粒和 ◊示礙佝此紅法板分其型47 菁 槽四PP得的 造顯钛 ，由金方 钛由確 3 --------------^------1— 訂-------I 1-^ (請先閱讀背面之法意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 46 9 1 6 9 A7 B7_五、發明說明（14 ) 如ί比，_法求得板鈦礦型和銳鈦礦型主波蜂的強度比 ，所以改用沒有和鋭鈦礦型波峰重β的板鈦礦型U 2 1 ) 而的波峻，求此波峰和上述3假重叠波峰的強度比即（板 鈦礦犁丨1 2 1 )而的波峰強度）/ (3痼重壘的波蜂強度）， 再由此求得板钛確型和銳鈦礦型氣化钛的含量.另外， 顯示金紅石型主波蜂（11 0丨面繞射的波峰和上述3摑重 壘波峰的強度比即 < 金紅石型主波峰強度）/( 3値重疊的 波峰強度 >,由此可求得含量。 結果，（板鈦礦型Π 2 1 )面的波蜂強度）/( 3個重叠的波 峰強度）=0 . 3 8 .、（金红石型主波峰強度> / ( 3痼重叠的波 峰強度）=0 . 0 5 ,可知板鈦礦型結晶的含量約為重量的7 0 ，金紅石型結晶約1 . 2 $，銳鈦礦型結晶約2 8 . 8 %。 由上述方法所得含有板鈦礦型氣化钛（含磷酸）的水分 散氣化鈦溶_ ,為了加快乾燥速度可添加乙醇，並調製 成如表一所示Μ成份的塗料。 除了使用由此得到的塗料以外均和實例1相同步驟， 可得表而含有氧化钛粒子的啤酒桶並做同樣的評估，結 果如表2所示，、 ----------- ^ --------訂---------"5^ . (請先閱請背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印制农 -16- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 9 6 A7B7 經濟邹智慧財產局員工消費合作社印製 五、發明說明（15) 表3 板鈦礦犁（29-1360) 銳鈦礦型（21-1272) 金紅石型（29-1276) <)值 結晶面 強度比 d值 結晶面 強度比 d值 結晶面 強度比 3.51 120 100 3.52 101 100 3.25 110 100 2.90 121 90 1.89 200 35 1.69 221 60 3.47 111 80 2.38 004 20 2.49 101 50 實例3 在不含板鈦礦型結晶只由銳鈦礦型結品構成的水分散 氣化钛溶廖（比表面積約為270m2 /g)中，添加矽膠条接 合劑的四甲氣基矽烷作為接合劑前驅物及可加快乾燥速度 的乙醇，並調製成如表1所示組成份的塗料。 除了使用由此得到的塗料以外均和實例1相同步驟， 可得表面含有氣化鈦粒子的啤酒桶並做同樣的評估，結 果如表2所示。 實例4 在不含板鈦礦型結晶只由金紅石型結晶構成的水分散 氣化鈦溶膠（比表面積為5 0 m 2 / s )中，添加矽隱条接合 _的四甲氣基矽烷作為接合劑前驅物及可加快乾燥速度 的乙醇，並調製成如表1所示組成份的塗料。 -17- 本紙張尺度適用中國國家標準（CNS)A4規格（2]0 χ 297公釐） -------------- ^--------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 469169 A7 _B7_ 五、發明說明（16 ) 除了使用由此得到的塗料以外均和實例1相同步驟， 可得表面含有氧化钛粒子的哗酒桶並做同樣的評估，結 果如表2所示。 窨例5 除了以玻璃製的啤酒瓶（大瓶：5 3 5 κι Γ)取代不锈鋼製的 Pg酒桶以外均和啻例1相同步驟，可得表面含有氧化鈦 粒平的啤酒桶並做同樣的評估，結果如表2所示。 並目對此破璃製啤酒瓶進行強度試驗.測定強度的簡 易方法是使用大小為5cnix 5cbiX 1.2mm,與構成玻璃瓶 的破璃相同成份之玻璃板。.將此玻璃板放在平滑的台上 ，使首徑1 0 m m的不綉鋼球從上面自由落下。此時將不_ 鋇球自由落下的高度逐漸升高，測定玻璃板會發生裂痕 時的高度當作産生破壞時的高度，結果如表4所示，顯 示高度越高其機械性強度越佳，，並測定5次取其中最高 m , 表 4 窗例號數 發生裂痕高度 [cm3 奮例 5 30 實例（3 30 比較例2 20 本紙張尺度適用中國國家標準（CNS)A4規格C21U X 297公釐） -------J------^-------f 訂--------- {請先閱讀背面之注意事項再填寫本頁) 4 6 9 16 9 A7 _B7五、發明說明（17) 瓶 瓶 酒 啤 的 製 璃 砘 以 β 了 例除 奮 製 銷 锈 不 代 取 化 氣 」 有示 含所 面 2 表表 得如 可果 ,結 驟 r 步估 同評 相的 2 榜 例同 實做 和並 均捅 外酒 wof 桶的 酒子 啤粒 的钛 驗 試 度 強 行 進 瓶 酒 製 璃 玻 此 對 同 。 相一不 5 所 传 4 賓表 和如 ΠΓ 果 # 結 其 容 .-- 0 桶示 酒所 啤 2 製表 鋼如 _ 果 不結 的 -理估 處評 未的 卽同 子相 粒 1 鈦例 化實 氧和 有 一1 ΓΤ- -,'ΐ- 1 没進 例商I,) 較表10 比 最 瓶 瓶 酒 啤 製 璃 玻 的 rrtl·- 理 0 未 Β'Λ 子 粒 鈦 化 氣 有 2 沒 例而 較表 ±. 驗 試 表度 如強 果行 結進 ，瓶 估酒 評啤 的製 同璃 相披 1 此 例對 實同 和相 行 5 進例 1)菁 0 口 5 £, 3 1.3 曰 示 所 並 結 其 瓶 酒 啤 桶 酒 啤 的 子 粒 鈦 化 氣 有 含 面 表 c 般 示一不 所所 4 2 表表 如如 果 多如 較外 具另 有 0 含佳 面更 表果 是效 Hu 待桶 .酒 淨啤 洗的 易子 容粒 也鈦 了 化 髒氣 使晶 即結 ，0 0 礦 易鈦 不板 (請先閱讀背面之注意事項再填寫本頁) 裝--------訂·-------1^- 經濟部智慧財產局員工消費合作社印製 氧 有 含 上 面 表 為 因 器 容 〇 品 度 食 強 的 性 明 械 發 機 本 其 ， 強性明 增闬説 可利的 瓶的 h 璃 t 以 玻業如 為商 ， 會 又果 效 洗述 易上 容§[; 也子 了粒 髒鈦 使化 即氣 ntt 的 而晶 髒結 弄型 易礦 不敎 以板 所有 子含 粒是 鈦果 化如 性 透 的 膜 薄 鈦 化 氧 同 不 劑 覆 包 旨 ΠΒ 樹 的 般 一 i D ί 好而 ¥ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 4 6 9 f 6 9 A7 _B7_五、發明說明（18) 佳所以可保持容器本來的外觀。例如若為不誘鋼等金屬 性容器，可成為具有金鼷光澤及清潔感的容器。食品容 器的材質若為玻璃時，因為其機械性強度也會增加所以 可減少其厚度而成為輕量的瓶。 又' 為了使氣化鈦粒子緊密接合在食品容器h可以使 用燒結肋劑或接合劑，所以氣化鈦粒子不易剝落.經過 長時間仍能保有不易弄髒而且即使髒了也容易洗淨的特 性。另外，使用燒結助爾或接合劑後不需經過5 Ο Ο υ以 上的高溫熱處理就可將氣化鈦粒子固定在食品容器表面 <請先閱讀背面之注意事項再填寫本頁) 装 — I--I--. I I------ 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）1 The number of examples is not easy to contaminate the degree of cleaning, easy to clean the degree of cyanide Example 1 ◎ ◎ Example 2 ◎ ◎ Example 3 〇W Example 4. 〇 Rich Example 5 ◎ ❹ Example 6 ◎ ◎ Comparative Example 1 XX Comparative Example 2 XX -----. 11 --- ^ -------- Order --------- line (Please read the precautions on the back before filling this page) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs The symbols shown in Table 2 printed by the consumer cooperatives respectively indicate the following: 1. Poor degree of pollution ◎ ... Almost no dirt 0 ... Slight dirt X ... A lot of dirt -14 ' This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 4 6 9 1 6 9 A7 _B7 V. Description of the invention (13) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs should be printed in 60 steps. The sharp and sharp changes in the titanium value are about the opposite step. The crystal peak is judged. Itl crystallizes the gas, 鋭 d enters into the same solution crust l ·, the peak of the method J and the difference between the current phase and the phase. The ^ type is based on the crystal-wave type 5 phase gas, and the ί & ore can be ejected ore weight y-JH 35 ^ to form 91 grain burning peaks ㈣ titanium rate type around titanium titanium is 11. The same titanium surface leather fluorescent surface sharp stone line 3 cases of the wasp are realized, and the red X is contained, and the waves P0 and P1 are combined with 1 gas, 21, peaks, and 04 crystals, and the 52 crystals are related to each other. Yi e contains ^ ~ 烧 波 _ ~ ^ Crystallization, Shite 33 net acid outside the "solid crystal 1 · main crystal form crystallization, the washing of the phosphorus solution ii!) And the crystallization of 03 junctions> more than 51 on the net easy Before the net, we got PP and ο glue type 10 type titanium this plow π very 3 quality washing without washing 00 dissolving ore (1 ore ore board 'ore PD is divided into easy and difficult liquid, so wlgol check titanium bee titanium Titanium is the material of the titanium JC, and its content is slightly soluble in pm. T Solve ο Viewing plate wave plate 鋭 _ He Ruizi's peaking degree staining scale water 0P solution T, 'Titanium is the main indicator and the indicator is mixed, recorded # 值 波 程 dirty and polluted titanium 20 differentiation diameter with the same apparent peak weight of the crystal picking d a net) a) into water and gas phase phase out of the plow wave out of the crystal 3 (known as another wash one by one _ gas Cheng Jia Tuan San's 1 check stone has been checked by the main inspection, and the type table can be easy to reach. · 'Four degrees 敎 ett points, the PT knowing type of ore red has a pretty wave ft capacity © CX2 into concentrated water 啻The gold-bearing type is a stone that can be counted as titanium. 2 cases of dripping gas m to the grain and showing obstacles. This red method is divided into 47 types. Slot four PP made titanium, made of gold, titanium, and titanium 3 -------------- ^ ------ 1— Order ------- I 1- ^ (Please read the legal and legal matters on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 46 9 1 6 9 A7 B7_V. Description of the invention (14) ί ratio, _ method to obtain the intensity ratio of brookite-type and anatase-type main wave bee, so instead use brookite-type brookite type U 2 1) without the peak weight β and The intensity ratio of this peak to the above three pseudo-overlapping peaks is (the peak intensity of the brookite plough 丨 1 2 1) / (wave intensity of the 3 蜂 heavy barrier), and the definite shape and sharpness of the plate titanium are obtained from this The content of titanite-type gasified titanium. In addition, the rutile main wave bee (the intensity ratio of the peaks of the 1 10 丨 plane diffraction and the above-mentioned 3 掴 heavy barrier peak is the < rutile main wave intensity) / (3値 Overlapping peak intensity > As a result, (the intensity of wave bees of the brookite-type Π 2 1) plane) / (the intensity of the three overlapping peaks) = 0. 3 8., (The intensity of the rutile main peak > / / (3 痼 overlapping peak intensity) = 0.05, it can be seen that the content of brookite-type crystals is about 70% by weight, rutile-type crystals are about 1.2 $, and anatase-type crystals are about 28.8%. Mineral-type gasified titanium (containing phosphoric acid) is a water-dispersed gasified titanium solvent. In order to accelerate the drying speed, ethanol can be added to prepare a coating with the composition of M as shown in Table 1. Except for using the coating thus obtained, the examples are uniform. 1 The same steps can be used to obtain beer kegs containing titanium oxide particles and do the same evaluation. The results are shown in Table 2. ----------- ^ -------- Order --------- " 5 ^. (Please read the notes on the back before filling out this page) Printed by Agricultural Consumers Cooperatives, Ministry of Economic Affairs and Intellectual Property Bureau-16-This paper size applies Chinese national standards ( CNS) A4 size (210 X 297 mm) 9 6 A7B7 Economy Zou Intellectual Property Bureau Printed by Consumer Consumption Cooperative V. Invention description (15) Table 3 Slab titanium plow (29-1360) Anatase (21-1272) Rutile (29-1276) <) value crystal plane strength ratio d value crystal plane strength ratio d value crystal plane strength ratio 3.51 120 100 3.52 101 100 3.25 110 100 2.90 121 90 1.89 200 35 1.69 221 60 3.47 111 80 2.38 004 20 2.49 101 50 Example 3 In a water-dispersed and vaporized titanium solution (with a specific surface area of about 270 m 2 / g) that does not contain brookite type crystals and consists only of anatase type products, silicone rubber is added. Tetramethylsilane based on the bonding agent is used as a bonding agent precursor and ethanol which can accelerate the drying speed, and is prepared into a coating composition as shown in Table 1. Except that the coating material thus obtained was used in the same procedure as in Example 1, a beer keg containing vaporized titanium particles on the surface was obtained and the same evaluation was performed. The results are shown in Table 2. Example 4 In a water-dispersed gasified titanium sol (with a specific surface area of 50 m 2 / s) containing no brookite-type crystals and consisting only of rutile crystals, tetramethylaerosilane bonded with silicon hidden strips was added as The binder precursor and ethanol which can accelerate the drying speed were prepared into coatings with the composition shown in Table 1. -17- The size of this paper applies to China National Standard (CNS) A4 (2) 0 χ 297 mm) -------------- ^ -------- Order- ------- line (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 469169 A7 _B7_ V. Description of the invention (16) The same procedure as in Example 1 was used to obtain a wine barrel containing titanium oxide particles on the surface and the same evaluation was performed. The results are shown in Table 2. Example 5 Except replacing the stainless steel Pg keg with a glass beer bottle (large bottle: 5 3 5 κι Γ), the same procedure as in Example 1 was performed. A beer keg containing titanium oxide particles on the surface was obtained and made the same. Evaluation, the results are shown in Table 2. The strength test of this broken glass beer bottle is carried out. The simple method for measuring the strength is to use a glass plate with a size of 5cnix 5cbiX 1.2mm and the same composition as the broken glass of the glass bottle. This glass plate is placed on a smooth table so that stainless steel balls with a first diameter of 10 mm can fall freely from above. At this time, the height of the free fall of the barium ball is gradually increased, and the height when the glass plate is cracked is taken as the height when the damage occurs. The results are shown in Table 4. The higher the height, the better the mechanical strength. , And measure the highest m five times. Table 4 Number of window cracks [cm3 Fen example 5 30 Example (3 30 Comparative example 2 20) This paper size applies Chinese National Standard (CNS) A4 specification C21U X 297 mm ) ------- J ------ ^ ------- f Order --------- {Please read the notes on the back before filling this page) 4 6 9 16 9 A7 _B7 V. Description of the invention (17) The glass bottles of the bottles of wine and beer are made with β as an example. They are not used to produce rust, but not to substitute for gas. The two examples of the same appraisal are the same as those of the same example, and the titanium test test of the wine seeds and beer grains of the wof barrels of foreign wine are forced into the bottle of wine. Xiangyi Bu 5 passed 4 guest tables and Ru ΠΓ 果 # Jie Qi Rong.-0 barrels of wine and beer 2 watch steel such as _ fruit does not end-the reason is not evaluated by the same homogeneous phase particles 1 titanium Instantiate real oxygen and have 1 ΓΤ--, 'ΐ- 1 did not enter the quotient I,) than Table 10 than the rrtl ·-0 of the most bottles of wine beer glass glass 0 Β′Λ grain titanium dioxide has 2 It ’s better than the table ±. The test results are as strong as the fruit, and the bottle evaluation of the beer and the beer are made with the glass. 1 This example is the same with the real 5. The example is 1) Jing 0 mouth 5 £, 3 1.3 It is said that the titanium titanium gas of the bottle of beer and barrels of beer and beer has a surface containing c. It shows nothing. 2 2 If it is more than external, there is another 0. It is more effective if it contains better noodles. Hu to be barrels. The Yizi capsules washed with beer and beer have also titaniumized the dirty gas to make the crystals knot. 0 0 mineral titanium is not plated (please read the precautions on the back before filling this page). Loading ----- --- Order · ------- 1 ^-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Qiang Mingzeng said that the glass bottle of Keli's bottle is based on the glass industry, and it will be easy to recap. § [; It also has dirty titanium, which is the gas ntt, and the crystals are dirty. The type of easy-to-mine ore is based on the fact that the grains of the board are titanium fruitification, such as thin film, thin titanium oxide, and oxygen-free coating, which is the same as that of the tree. Π Good and ¥ This paper size applies to Chinese national standards (CNS ) A4 size (210 X 297 mm) 4 6 9 f 6 9 A7 _B7_ V. Description of the invention (18) It is good so it can maintain the original appearance of the container. For example, if a metallic container such as steel is not attracted, it can be a container with a golden tint and a clean feeling. If the food container is made of glass, its mechanical strength will increase, so its thickness can be reduced to make it a lightweight bottle. In addition, in order to tightly bond the vaporized titanium particles to the food container, a sintered rib or a bonding agent can be used, so the vaporized titanium particles are not easy to peel off. After a long time, it can maintain the characteristics of being difficult to stain and easy to clean even if it is dirty. . In addition, the use of sintering aids or bonding agents can be used to fix gasified titanium particles on the surface of food containers without high-temperature heat treatment above 5 Ο Ο υ. <Please read the precautions on the back before filling out this page.) — — I --I--. I I ------ This paper is printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, and the paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm)