TW468237B - Improving method for peeling issue in the integrated circuit processing - Google Patents

Improving method for peeling issue in the integrated circuit processing Download PDF

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TW468237B
TW468237B TW88116566A TW88116566A TW468237B TW 468237 B TW468237 B TW 468237B TW 88116566 A TW88116566 A TW 88116566A TW 88116566 A TW88116566 A TW 88116566A TW 468237 B TW468237 B TW 468237B
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dielectric layer
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scope
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layer
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TW88116566A
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Chinese (zh)
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Tzung-Han Lee
Wen-Yi Tan
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United Microelectronics Corp
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Abstract

A method for forming integrated circuit is disclosed which can improve the peeling issue in the integrated circuit processing. The peeling issue often occurs at the integrated circuit area near the periphery region. The method for forming the integrated circuit first provides: a substrate on which has a high packing density region and a low packing density region and the high packing density region is adjacent to the low packing density region; and, forming a pattern layer on the low packing density region; then, forming a dielectric on the high packing density region and the pattern layer; finally, planarizing the dielectric.

Description

46 823 7 五、發明說明(1) 5-1發明領域: 本發明係有關於一種製作積體電路的方法,特別有關 於因平坦化後曝露出來的電容器多晶矽所引發的剝離現象 5-2發明背景: 一般在積體電路的製程中,包括四個多晶矽層的製程 與一些金屬内連線製程,當然於此之前,必須先完成底材 内之所有元件(devi ces )的製程。 通常所謂第一多晶矽層(poiyq ),最主要為閘極導 電層而言’其為底材内元件形成之後所進行的第一層多晶 石夕層,第二多晶石夕層(P〇ly_2)乃指積體電路令的.位元線 (bit lines) ’其通常形成於第一多晶矽層(poly-1)之 上,且此位元線的延伸方向與閘極垂直β為達到隔絕的效 果’兩多晶石夕層間最少有一層介電層存在。 至於第三多晶矽層’如第一圖所示,最主要係指半導 體 I & aa / 於上奋為之下電極(lower eiectrode ) 1〇2而言,其形成 二多,第二介電層上方之介電層101上,此圖將第一及第 "砂層’及底材1 0 0内部元件省略,只示出相關部分46 823 7 V. Description of the invention (1) 5-1 Field of the invention: The present invention relates to a method for manufacturing integrated circuits, and particularly to the peeling phenomenon caused by capacitor polycrystalline silicon exposed after planarization. 5-2 Invention Background: Generally, the manufacturing process of integrated circuits includes the process of four polycrystalline silicon layers and some metal interconnection processes. Of course, before this, the process of all components in the substrate must be completed. The so-called first polycrystalline silicon layer (poiyq) is mainly the gate conductive layer, which is the first polycrystalline silicon layer and the second polycrystalline silicon layer ( P〇ly_2) refers to the integrated circuit. Bit lines' are usually formed on the first polycrystalline silicon layer (poly-1), and the extension direction of this bit line is perpendicular to the gate β In order to achieve the effect of isolation 'at least one dielectric layer exists between the two polycrystalline stones. As for the third polycrystalline silicon layer, as shown in the first figure, it mainly refers to the semiconductor I & aa / lower eiectrode 102, which forms two poly, the second dielectric On the dielectric layer 101 above the electrical layer, this figure omits the first and the first " sand layer 'and the internal components of the substrate 100, only the relevant parts are shown

‘46 82 3 7 五 '發明說明(2) -- :上述多晶矽之下電極1〇2乃與底材1〇〇相接觸,且為了能 增加表面積及電荷儲存量,此下電極部分已發展出各種形 狀’例如圓柱形、中空圓筒形等。待此第三介電層〗.〇2形 成完畢後,再於其上形成一介電層1〇3此介電層極為電容 中分隔兩電極之用,接著形成一第四多晶矽層(p〇ly_4) 1 0 4於此介電層1 0 3上作為上電極,以上所述之步驟乃一般 傳統積體電路中製作電容器電極的主要步驟。 在形成多重内連線(_11;卜1”611111:61_(:〇111^(:1;3)之 金屬之則,先於上電極之上形成一介電層丨5以絕緣( isolating),再將此介電層1〇5經傳統製程加以平坦化( planarizing ),如此可降低多重内連線製程的困難度。 參見第二圖,在施以化學機械研磨(chemical mechanical polishing, CMP)將介電層 1〇5 平坦化之後, 於切割道(periphery region)邊的積體電路區域中,常 會因研磨過度而導致電容器電極之多晶矽層(1 〇2或ι〇4)外 露的情況。於接下來的金屬製程中,其作為黏著層(giue layer)用的鈦(Ti )材料將附箸於此外露的多晶矽上, 此不但造成多重内連部分與電容器短路的情形;又由於g 著於多晶矽上的鈦材料容易產生剝,且剝離 的鈦顆粒容易造成後讀製程的困擾,即位於切叫道( periphery region)邊緣的金屬層容易產生缺陷(defects )°'46 82 3 7 5 'Invention Description (2)-: The above-mentioned polycrystalline silicon lower electrode 10 is in contact with the substrate 100, and in order to increase the surface area and charge storage capacity, the lower electrode portion has been developed Various shapes' such as a cylindrical shape, a hollow cylindrical shape, and the like. After the third dielectric layer is formed, a dielectric layer is formed thereon. This dielectric layer is used to separate two electrodes in a capacitor, and then a fourth polycrystalline silicon layer is formed ( p〇ly_4) 104 is used as an upper electrode on this dielectric layer 103. The above steps are the main steps for making capacitor electrodes in a conventional integrated circuit. In the case of forming multiple interconnects (_11; Bu 1 "611111: 61_ (: 〇111 ^ (: 1; 3)), a dielectric layer 5 is formed above the upper electrode to isolate it. Then, the dielectric layer 105 is planarized by a conventional process, so that the difficulty of the multiple interconnect process can be reduced. Referring to the second figure, when chemical mechanical polishing (CMP) is applied, After the dielectric layer 105 is planarized, the polycrystalline silicon layer (102 or ι04) of the capacitor electrode is often exposed due to excessive grinding in the integrated circuit area beside the peripheral region. In the next metal process, the titanium (Ti) material used as a glue layer will be attached to the exposed polycrystalline silicon, which will not only cause the short circuit of multiple interconnected parts and capacitors; The titanium material on polycrystalline silicon is prone to peeling, and the peeled titanium particles easily cause troubles in the post-reading process, that is, the metal layer at the edge of the peripheral region is prone to defects. °

d6B237 五,發明說明(3) 由於上述原因’為了避免剝離問題(peeling issue) ’必須發展一種形成積體電路的方法,來提昇半導體產品 的品質。 5 - 3發明目的及概述: 雲於上述之發明背景中,傳統的積體電路製程中所產 生的諸多缺點’本發明的目的在改善平坦化製程後所產生 之電容器外露現象。 本發明之另一目的在防止金屬化製程時所產生的剝離 問題。d6B237 V. Explanation of the invention (3) For the above reasons, ‘in order to avoid peeling issues’, it is necessary to develop a method for forming integrated circuits to improve the quality of semiconductor products. 5-3 Purpose and Summary of the Invention: In the above background of the invention, there are many shortcomings in the traditional integrated circuit manufacturing process. The purpose of the present invention is to improve the capacitor exposing phenomenon after the planarization process. Another object of the present invention is to prevent the problem of peeling during the metallization process.

根據以上所述之目的,本發明提供了一種製作積體電 路的方法,於此方法中,首先提供一底材,其上有—第— 部分與—第二部分;再形成一第一介電層於第一部分上與 第二部分上β然後,定義一第一導體層於第一部分之第二 介電層上,作為此積體電路之電容器下電極;形成一第二 介電層於第一導體層上;再形成一第二.導體層於第二介f 層上,作為積體電路之電容器上電極。接下來,形 二介電層於第二導體層上及第二部分之第—介電屉 成一第四介電層於第三介電層上;再形成—光阻^於第jAccording to the above-mentioned object, the present invention provides a method for fabricating an integrated circuit. In this method, a substrate is first provided with -part- and -second parts thereon; and a first dielectric is formed. Layer on the first part and β on the second part Then, define a first conductor layer on the second dielectric layer of the first part as the capacitor lower electrode of this integrated circuit; form a second dielectric layer on the first On the conductor layer; a second conductor layer is formed on the second dielectric layer to serve as the capacitor upper electrode of the integrated circuit. Next, a second dielectric layer is formed on the second conductor layer and the first-dielectric drawer of the second part is formed into a fourth dielectric layer on the third dielectric layer; and then a photoresist is formed on the j-th layer.

46 8237 五、發明說明(4) 介電層上,此光阻層中已形成一圊案區於第二部分上方; 然後蝕刻第二部分上方之第三與第四介電層,隨後移除光 阻層。形成一第五介電層於第四介電層上,最後,移除第 五介電層直至第四介電層曝露出來為止。 5-4圖式簡單說明: 第一圖係表示傳統積體電路中邊緣區之電容器與相鄰 之切割道結面圖。 第二圖係表示傳統積體電路之平坦化製程後所產生之 電容器外露的截面圖。 第三圖至第七圖係表示本發明所提出之積體電路製程 流程截面圖。 主要部分之代表符號: 10 底 材 11 介 電 層 12 導 體 層 13 介 電 層 14 導 體 層 15 介 電 層 16 介 電 層 17 光 阻 層46 8237 5. Description of the invention (4) On the dielectric layer, a patterned area has been formed in the photoresist layer above the second part; then the third and fourth dielectric layers above the second part are etched and then removed Photoresist layer. A fifth dielectric layer is formed on the fourth dielectric layer. Finally, the fifth dielectric layer is removed until the fourth dielectric layer is exposed. 5-4 Schematic description: The first diagram shows the junction surface of the capacitor in the edge area and the adjacent scribe line in the traditional integrated circuit. The second figure is a cross-sectional view showing the exposed capacitors after the planarization process of the conventional integrated circuit. The third to seventh figures are cross-sectional views showing the process flow of the integrated circuit proposed by the present invention. Representative symbols of the main parts: 10 substrates 11 dielectric layer 12 conductor layer 13 dielectric layer 14 conductor layer 15 dielectric layer 16 dielectric layer 17 photoresist layer

第7頁 46 823 7 五、發明說明(5) 18 介電層 100 101 102 103 104 105 底材 介電層 導體層 介電層 導體層 介電層 5-5發明詳細說明: 於下列所舉之一實施例,可改善積體電路製程中之剝 離問題。 參見第 元件已事先 之元件如閘 的部分,亦 形成一介電 及非專向性 器之接觸窗 之頂面延伸 其與下方之 三圖,首先提供一底 形成,但於此不予贅 極、位元線、介電層 予省略。因此,接下 層11 ’如氧化物;然 蚀刻(anisotropic 洞(contact holes ) 至底#10頂面,且上 其他元件之用》 材10,其中所有之半導體 述,其他形成於半導體上 等不與本發明有直接相關 來之步驟乃於底材10上方 後以微影(1 i thography) etch)等程序型成一電容 ,此接觸窗洞由介電層11 述之介電層11乃用於隔離Page 7 46 823 7 V. Description of the invention (5) 18 Dielectric layer 100 101 102 103 104 105 Substrate dielectric layer conductor layer dielectric layer conductor layer dielectric layer 5-5 Detailed description of the invention: An embodiment can improve the peeling problem in the integrated circuit manufacturing process. Refer to the components of the element, such as the gate, in advance. It also forms the top surface of the contact window of the dielectric and non-specific device, which extends from the bottom three. First, a bottom formation is provided, but it will not be redundant here. Bit lines and dielectric layers are omitted. Therefore, connect the lower layer 11 'such as an oxide; then etch (anisotropic hole (contact holes) to the top surface of the bottom # 10, and use other components on the top 10), all of which are described in semiconductors, others are formed on semiconductors and so on. The step directly related to the present invention is to form a capacitor by using a program such as lithography (etch) on the substrate 10, and the dielectric layer 11 described by the dielectric layer 11 for the contact window hole is used for isolation.

第8頁 468237 五、發明說明(6) 沉積一導體層1 2如多晶矽於介電層11上且填滿接觸窗 洞;再以微影及截刻或其他傳統程序將導體層1 2定義成電 容器之圓枉形下電極12 ’且其上也形成半球粒石夕( hemi-spherical grain silicon,HSG silicon)結構,位 於切割道(periphery region)之部分導體層12亦被蝕刻 而移除;再將一薄的介電層1 3如氧化物(ox i de)或氮化矽( si licon ni tride)沉積於導體層12上;接下來沉積另—導 體層1 4如多晶矽之後,此積體電路中的電容器則完成,其 中此導體層1 4係用以作電容器之上電極。 以上主要描述半導體製程中製作積體電路之電容器的 主要步驟’其所有程序皆為傳統且標準的積體電路程序, 且上述之電容器尚度比切割道(periphery regi〇n)或其 他較低積極度的表面高出許多,大約為5〇〇至5〇〇〇埃( angstroms)左右’再此高度落差較大之處,要形成—單一 南度的介電層的確是不可能的事,且即使平坦化後容易導 致與發明背景中所述之缺點。所以本發明提供了一模型層 (dummy layer)的結構形成於切割道(periphery regi〇n )或低積極度區’此模型層(dummy layer)之高度與電容 器之尚度相差不多,以致於形成一介電層時,高積極度區 與低積極度區的高度差相差不大,以化學機械研磨法平坦 化時,能夠有較好的效果,且可避免後續製程易發生的剝 離問題(peeling issue )。至於較詳盡的内容描述如下。Page 8 468237 V. Description of the invention (6) Deposit a conductive layer 12 such as polycrystalline silicon on the dielectric layer 11 and fill the contact window hole; then define the conductive layer 12 as a capacitor by lithography and truncation or other traditional procedures The round-shaped lower electrode 12 ′ and a hemi-spherical grain silicon (HSG silicon) structure are also formed thereon, and a part of the conductor layer 12 located in the peripheral region is also etched and removed; then A thin dielectric layer 13 such as an oxide or silicon nitride is deposited on the conductive layer 12; then another conductive layer 14 such as polycrystalline silicon is deposited, and the integrated circuit The capacitor is completed, in which the conductor layer 14 is used as an electrode on the capacitor. The above mainly describes the main steps in the fabrication of capacitors for integrated circuits in the semiconductor process. All the procedures are traditional and standard integrated circuit procedures, and the capacitors described above are less active than the peripheral regiron or other The surface is much higher, about 5,000 to 5,000 angstroms, and where there is a large difference in height, a single south-level dielectric layer is really impossible, and Even after flattening, it easily leads to the disadvantages described in the background of the invention. Therefore, the present invention provides a dummy layer structure formed in a peripheral regio or low active area. The height of this dummy layer is similar to that of a capacitor, so that it is formed. When a dielectric layer is used, the height difference between the high-positivity area and the low-positivity area is not much different. When planarized by the chemical mechanical polishing method, it can have a good effect, and can avoid the peeling problem that is easy to occur in subsequent processes. issue). The more detailed content is described below.

46 8237 五、發明說明(7) 程前述之製程’接下來的步驟為將電容器隔絕,使之 無法影響多重内連線(multi-]_evei erconnects )的金 屬製程。如第四圖所示,沉積一介電層1 5如氧化物於導體 層1 4上與切割道之介電層11上,此介電層丨5將作為—模型 層(dummy layer )之用;再沉積另一介電層16於介電層15 上,此介電層16玎選用氮化矽(Silic〇n nitride)或任何 高選擇比的材質;接著形成一光阻層1 7於此介電層丨6上, 其中已形成一種類似電容器下電極的圖案(pattern )於切 割道或低積集區之上方丨相對的,此光阻層1 7位於電容器 區或高積集區的部分’將無任何圖案,且完全覆蓋此區^ 介電層15與介電層16被蝕刻後,即移除此光阻層17, 則所得結構如第五圖所示,其中所有之電容器將被此介- 層1 5隔絕;另一方面,此介電層1 5位於切割道上方之二1 ,被蝕刻成許多的圓柱模型(cylindrical dummies } #分 狀似電容器之下電極。由於此模型層,切割道 ’ ^ . 、辦相鄰的雷 谷器區之南度差減y 了許多’甚至沒有高度差。 7 /又左。而且,ΐΏ· 積於介電層15上的介電層16,具有一較薄的原疮 ^ 儿 下述之平坦化程序(planarization process ) ώ从μ ? β 6 J中的終止層 參見第六圖,沉積一介電層18如氡化物於介電層j 且填滿上述模型層1 5上之各模型之間的空隙。 θ 上46 8237 V. Description of the invention (7) The aforementioned process ’The next step is to isolate the capacitor so that it cannot affect the metal process of multi-] _ evei erconnects. As shown in the fourth figure, a dielectric layer 15 such as an oxide is deposited on the conductive layer 14 and the dielectric layer 11 of the scribe line. This dielectric layer 5 will be used as a dummy layer; Deposit another dielectric layer 16 on the dielectric layer 15. This dielectric layer 16 is made of silicon nitride or any material with a high selectivity ratio; then a photoresist layer 17 is formed on the dielectric. On the layer 6, a pattern similar to the lower electrode of the capacitor has been formed above the scribe line or the low accumulation area. Opposite to this, the photoresist layer 17 is located in the part of the capacitor area or the high accumulation area. Without any pattern, and completely covering this area ^ After the dielectric layer 15 and the dielectric layer 16 are etched, the photoresist layer 17 is removed, and the resulting structure is shown in the fifth figure, in which all capacitors will be -Layer 15 is isolated; on the other hand, this dielectric layer 15 is located above the cutting path bis 1 and is etched into many cylindrical models (cylindrical dummies) # fractal like capacitors below the electrode. Because of this model layer, cutting Road '^., The south degree difference of the adjacent Leiguqi area has been reduced by y', and it is not even high Degree difference. 7 / again left. Also, the dielectric layer 16 that is deposited on the dielectric layer 15 has a thin protothema ^ The planarization process described below is from μ? Β 6 The termination layer in J is shown in the sixth figure, and a dielectric layer 18 such as a halide is deposited on the dielectric layer j and fills the gap between the models on the model layer 15 above. Θ on

46 823 7 五、發明說明(8) 參見第七圖,用化學機械研磨法(chemical mechanical p〇liShing,CMP)將介電層18施以平坦化( planarizing),直至該具有高選擇比的介電層16曝露出來 為止,此介電層16係作為此CMP程序的終止層(stop layer ),且其厚度約為200至3000埃左右。 以上所述僅為本發明之較佳實施例而已’並非用以限 定本發明之申請專利範圍;凡其它未脫離本發明所揭示之 精神下所完成之等效改變或修飾,均應包含在下述之申請 專利範圍内。46 823 7 V. Description of the invention (8) Referring to the seventh figure, the dielectric layer 18 is planarized by chemical mechanical polishing (CMP) until the dielectric having a high selection ratio is planarized. Until the electrical layer 16 is exposed, the dielectric layer 16 serves as a stop layer for the CMP process, and has a thickness of about 200 to 3000 angstroms. The above are merely preferred embodiments of the present invention and are not intended to limit the scope of patent application for the present invention; all other equivalent changes or modifications made without departing from the spirit disclosed by the present invention shall be included in the following Within the scope of patent application.

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Claims (1)

4 6 82 3 7 六、申請專利範圍 1. 一種形成積體電路的方法,至少包含: 該 提供一底材,其上具有一高積集區與一低積集區 高積集區與該低積集區相鄰; 形成一模型層於該低積集區上; 形成一介電層於該高積集區與該模型層上;及 將該介電層平坦化。 2. 如申請專利範圍第1項之方法,其中上述之該高積集區 至少包含電容器,且該電容器位於該高積集區與該低積集 區的邊緣。 3. 如申請專利範圍第1項之方法,其中上述之低積集區包 .括晶圓上的一切割道。 4. 如申請專利範圍第1項之方法,其中上述高積集區之線 路密度比該低積集區的線路密度要高。 5. 如申請專利範圍第1項之方法,其中上述之模型層至少 包含氧化物。 6. 如申請專利範圍第1項之方法,其中上述之模型層至少 包含氮化石夕。 7 ·如申請專利範圍第1項之方法,其中上述之介電層至少4 6 82 3 7 VI. Scope of patent application 1. A method for forming an integrated circuit, including at least: a substrate provided with a high accumulation area and a low accumulation area, and a high accumulation area and the low The accumulation regions are adjacent; a model layer is formed on the low accumulation region; a dielectric layer is formed on the high accumulation region and the model layer; and the dielectric layer is planarized. 2. The method according to item 1 of the patent application range, wherein the above-mentioned high accumulation area includes at least a capacitor, and the capacitor is located at an edge of the high accumulation area and the low accumulation area. 3. The method according to item 1 of the patent application range, wherein the above-mentioned low accumulation area includes a scribe line on the wafer. 4. For the method of the first item in the scope of patent application, wherein the line density of the high accumulation area is higher than the line density of the low accumulation area. 5. The method according to item 1 of the patent application scope, wherein the above model layer contains at least an oxide. 6. The method according to item 1 of the scope of patent application, wherein the model layer mentioned above includes at least nitride nitride. 7 · The method of claim 1 in which the above dielectric layer is at least 第12頁 468237Page 12 468237 第13頁 ^ β 82 3 7 六、申請專利範圍 至少包含多晶矽。 11.如申請專利範圍第9項之方法,其中上述之第二介電層 至少包含氧化物。 1 2.如申請專利範圍第9項之方法,其中上述之第二介電層 至少包含氮化矽。Page 13 ^ β 82 3 7 6. Scope of Patent Application At least polycrystalline silicon is included. 11. The method of claim 9 in which the above-mentioned second dielectric layer contains at least an oxide. 1 2. The method according to item 9 of the scope of patent application, wherein the second dielectric layer includes at least silicon nitride. 1 3.如申請專利範圍第9項之方法,其中上述之第二導電層 至少包含多晶石夕。 1 4.如申請專利範圍第9項之方法,其中上述之第三介電層 至少包含氧化物。 15.如申請專利範圍第9項之方法,其中上述之第四介電層 至少包含氮化矽。1 3. The method according to item 9 of the scope of patent application, wherein the second conductive layer includes at least polycrystalline silicon. 14. The method according to item 9 of the scope of patent application, wherein the third dielectric layer described above includes at least an oxide. 15. The method as claimed in claim 9 wherein the fourth dielectric layer includes at least silicon nitride. 1 6.如申請專利範圍第9項之方法,其中上述之第三介電層 與第四介電層係以非等向性蝕刻法蝕刻。 1 7.如申請專利範圍第9項之方法,其中上述之第五介電層 至少包含氧化物。 1 8,如申請專利範圍第9項之方法,其中上述之第五介電層16. The method according to item 9 of the scope of patent application, wherein the third dielectric layer and the fourth dielectric layer are etched by an anisotropic etching method. 1 7. The method according to item 9 of the scope of patent application, wherein the fifth dielectric layer described above contains at least an oxide. 1 8. The method according to item 9 of the scope of patent application, wherein the fifth dielectric layer described above 第14頁 46823 7 六、申請專利範圍 係以化學機械研磨法(CMP )移除。Page 14 46823 7 VI. Patent application scope It is removed by chemical mechanical polishing (CMP). 第15頁Page 15
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