TW465093B - Manufacturing method of vertical metal-insulator-metal capacitor - Google Patents

Manufacturing method of vertical metal-insulator-metal capacitor Download PDF

Info

Publication number
TW465093B
TW465093B TW089127244A TW89127244A TW465093B TW 465093 B TW465093 B TW 465093B TW 089127244 A TW089127244 A TW 089127244A TW 89127244 A TW89127244 A TW 89127244A TW 465093 B TW465093 B TW 465093B
Authority
TW
Taiwan
Prior art keywords
layer
patent application
manufacturing
metal
scope
Prior art date
Application number
TW089127244A
Other languages
Chinese (zh)
Inventor
Yeur-Luen Tu
Dah-Cheng Lin
Min-Hwa Chi
Original Assignee
Taiwan Semiconductor Mfg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taiwan Semiconductor Mfg filed Critical Taiwan Semiconductor Mfg
Priority to TW089127244A priority Critical patent/TW465093B/en
Priority claimed from US09/839,964 external-priority patent/US6528366B1/en
Application granted granted Critical
Publication of TW465093B publication Critical patent/TW465093B/en

Links

Abstract

A manufacturing method of vertical metal-insulator-metal (MIM) capacitor is disclosed, which is suitable for the integrated manufacturing of memory devices and logic devices. Since there is a good processing environment during processing the logic circuits for the embedded DRAM process. It can match with the low temperature process (less than 450 DEG C), and reduce the height aspect ratio of the contact in the logic region.

Description

46 50 9 五、發明說明(1) 本發明係有關於一種半導體製造方法,特別是有關於 一種垂直型金屬-絕緣物-金屬(MIM)電容器之製i^方去 在半導體積體電路中所使用之電容器,大客e y定以複曰日 矽-絕緣物-複晶矽之架構所形成之多晶矽電容器;以複a 矽-絕緣物-金屬化複晶矽(或金屬)之架構形成所謂之μ ^ $ 電容器;亦或是以金屬-絕緣物-金屬之架構形成所謂之 ΜΙΜ 電容器(metal-insulator-metal capacitor)。傳統之 ΜI S、或Μ I Μ電容器均係為平面化,以相容於CMOS製程俾使 製程之整合得以簡化。 就MIM電容器而言,亦有具3D形式之MIM電容器[i_2] 已廣被應用於先進1)1^丨1之製造上。此30-«11^1電容器之_般 特徵係為:小尺寸,圓柱狀(cylinder)或冠狀(crown), 使用具高介電常數之介電質(high-k dielectric),以及 使用複雜之DR AM製程製作而得。然而,上述3D-MIM電容 器’大多係形成於第1層金屬内連線(interconnect)之下 方;由於會使前段(front-end)層和後段(back-end)層在 製程條件上之不匹配,因此造成D R A Μ和邏輯電路兩者在製 程整合上之困難。也導致DRAM和邏輯電路兩者會有嚴重之 高度差問題;對接觸(contact)結構而言,會使得其高度-開口比(height aspect ratio)增大。 近來,嵌入式DRAM (亦即將DRAM和邏輯電路合併於同 一晶片上)之研究[3_4],均建議將DRAM之電容器設置於第2 層金屬内連線(metal-2)和第1層金屬内連線(metal-1)之 間。但是,由於在Hi e t a 1 - 1和m e t a 1 - 2兩者間絕緣層之厚度46 50 9 V. Description of the invention (1) The present invention relates to a semiconductor manufacturing method, and more particularly to a vertical metal-insulator-metal (MIM) capacitor manufacturing method used in semiconductor integrated circuits. For the capacitors used, Dakeey will use polysilicon capacitors formed by the structure of polysilicon-insulator-polycrystalline silicon; the structure of polya silicon-insulator-metalized polycrystalline silicon (or metal) will form the so-called μ ^ $ capacitor; or a metal-insulator-metal capacitor is formed by a metal-insulator-metal structure. Conventional MEMS or MEMS capacitors are all planarized to be compatible with the CMOS process, which simplifies the integration of the process. As far as MIM capacitors are concerned, there are also MIM capacitors [i_2] in 3D that have been widely used in advanced 1) 1 ^ 丨 1 manufacturing. The general characteristics of this 30- «11 ^ 1 capacitor are: small size, cylindrical or crown, use of high-k dielectric, and the use of complex Produced by the DR AM process. However, most of the above 3D-MIM capacitors are formed under the first layer of metal interconnects; as the front-end layer and the back-end layer will not match in process conditions Therefore, it is difficult to integrate both the DRA M and the logic circuit in process integration. It also causes serious height difference problems for both DRAM and logic circuits; for a contact structure, its height-to-opening ratio (height aspect ratio) increases. Recently, researches on embedded DRAM (that is, combining DRAM and logic circuits on the same chip) [3_4] have suggested that DRAM capacitors be placed in the second layer metal interconnect (metal-2) and the first layer metal Between the wires (metal-1). However, due to the thickness of the insulating layer between Hi e t a 1-1 and me t a 1-2

0503-5813TWF-3td 第4頁 465093 五、發明說明(2) 無法有太大變化’將使得續製程中所形成電容器之電容值 也因此無法有太大之變化。 第1圖顯示傳統嵌入式DRAM之部分剖面結構示意圖。 圖中’標示Logic者係表示形成有邏輯電路之區域,而標 示Memory者係表示形成有dram記憶體之區域。參照第1 圖’基底1 0上形成有若干記憶體元件(例如Μ1、μ 2)和至若 干邏輯元件(例如LI、L2 ); —第一絕緣層11覆蓋上述記憶 體元件(Ml 'M2)和邏輯元件(LI、L2)。一接觸插栓(piUg) 1 2形成於上述絕緣層1丨中,用以和上述記憶體元件(M1、 M2)形成電性接觸,並作為dRAM貯存電容器之節點接觸 (node contact)。在Memory區域之上述絕緣層11上,通常 亦形成有第一多晶矽層(未圖示)用以構成⑽虓記憶體之内 部連線。第二絕緣層1 3更形成於上述第一絕緣層11及接觸 插栓1 2之上。 上述第二絕緣層1 3中形成有一開口區域(用以定義貯 存電容器),以露出上述接觸插栓丨2。一第一(多晶矽)電 極層1 4形成於上述開口區内;一介電層1 5 (例如為0N0層) 形成於上述第一電極層14之上,接著有一第二(多晶矽)電 極層16形成於上述介電層15之上,如第1圖所示。其中, 上述第一電極層14、介電層15、及第二電極層16,即構成 DRAM之貯存電容器。 由於上述介電層(0N0層)15之形成溫度係大於700 t ; 因此’在Log i c部分之金屬製程部分,必須要在完成貯存 電容器之後才會予以進行。0503-5813TWF-3td Page 4 465093 V. Description of the invention (2) Can not be changed too much 'will make the capacitance value of the capacitor formed in the continuous process not change too much. Figure 1 shows a schematic cross-sectional structure of a conventional embedded DRAM. In the figure, the "Logic" indicates a region where a logic circuit is formed, and the "Memory" indicates a region where a dram memory is formed. Referring to FIG. 1, a plurality of memory elements (for example, M1, μ 2) and a plurality of logic elements (for example, LI, L2) are formed on the substrate 10;-the first insulating layer 11 covers the above-mentioned memory elements (Ml'M2) And logic elements (LI, L2). A contact plug (piUg) 12 is formed in the above-mentioned insulating layer 1 丨 to form electrical contact with the above-mentioned memory elements (M1, M2), and serves as a node contact of the dRAM storage capacitor. A first polycrystalline silicon layer (not shown) is usually formed on the above-mentioned insulating layer 11 in the memory area to constitute the internal connection of the memory. The second insulating layer 13 is further formed on the first insulating layer 11 and the contact plug 12. An opening area (for defining a storage capacitor) is formed in the second insulating layer 13 to expose the contact plug 2. A first (polycrystalline silicon) electrode layer 14 is formed in the above-mentioned opening area; a dielectric layer 15 (for example, a 0N0 layer) is formed on the first electrode layer 14, and then a second (polycrystalline silicon) electrode layer 16 is formed. It is formed on the dielectric layer 15 as shown in FIG. 1. The first electrode layer 14, the dielectric layer 15, and the second electrode layer 16 constitute a storage capacitor for a DRAM. Since the formation temperature of the above-mentioned dielectric layer (0N0 layer) 15 is more than 700 t; therefore, the metal process part of the Log i c part must be performed after the storage capacitor is completed.

0503-5813TWF-?td 第5頁 46509ο 五、發明說明⑶ ' * 完成ΜΑΜ部分製程後’接著形成經平坦化之第三絕緣 層17於上述第二絕緣層14和上述第二電極層16之上。若要 針對Logic部分進行插栓及内連線製程,則須在第三絕緣 層1 7 H緣層1 3、及第—絕緣層1 2中,挖出接觸孔洞 (C〇ntaCt)18,如圖中虛線所示區域’則後續之金屬化製 程才能與Logic區域之元件形成電性接觸。但是,如此一 來所形成之接觸孔洞18,難免會具有極大之高度_開口比 (aspect ratio),對於製程之控制而言 而影響 良率。 此外,貯存電容器之深度大小受限於第二絕緣層丨3之 厚度’將會減少貯存電容器之電容值,及其可調整性。 竣物有合鑑::二本發:之目的為提出-種垂直型金屬-絕 二杜夕效人制^ ^之崴造方法,適用於記憶體元件和邏輯 造,使嵌入式DRAM (亦即將DRAM和邏輯電路 上)之製程,能夠在處理邏輯電路時有良 ^ *兄,同時能夠配合較低溫(小於450 t)之制 程,=及減少L〇glc區接觸孔洞之高度_開口比。之衣 絶缘上Λ目的’本發明提出之第-種垂直型金屬 絕緣物-金屬電容器之製造方法,包括如下步驟金屬~0503-5813TWF-? Td Page 5 46509ο 5. Description of the invention ⑶ * * After completion of the MIMO part process', then a flattened third insulating layer 17 is formed on the above-mentioned second insulating layer 14 and the above-mentioned second electrode layer 16 . To perform the plug and interconnection process for the Logic part, the contact hole (ContaCt) 18 must be excavated in the third insulating layer 17 H edge layer 1 3 and the first-insulating layer 12, such as The area 'shown by the dotted line in the figure' can then be used to make electrical contact with the components in the Logic area during subsequent metallization processes. However, the contact holes 18 formed in this way will inevitably have an extremely high aspect ratio, which will affect the yield for the process control. In addition, the depth of the storage capacitor is limited by the thickness of the second insulating layer 3, which will reduce the capacitance of the storage capacitor and its adjustability. The completed article has a synopsis :: two books: the purpose is to propose-a kind of vertical metal-the second Du Xi effect person manufacturing method ^ ^, suitable for memory components and logic manufacturing, embedded DRAM (also That is, on the DRAM and logic circuits) process, it can be good when processing logic circuits. * At the same time, it can cooperate with the lower temperature (less than 450 t) process, and reduce the height of the contact hole in the LOglc area_opening ratio. Clothing Λ Purpose ’The first-type vertical metal insulator-metal capacitor manufacturing method proposed by the present invention includes the following steps metal ~

Ua)提供一半導體基底;其中,上上 少一5己憶體元件和至少-邏輯元件,一第一絕成有至 =憶和邏輯元件,一複合層形成於上地2蓋上 庳之上辻ί :ί 一連接結構形成於上述第-絕緣中〜絕緣 應之上述,己憶體元件構成電性連接 :,與對 連接結構 Η 0503-5813TWF-ptd 第6頁Ua) provides a semiconductor substrate; wherein, a semiconductor device and at least a logic device are on the top, a first semiconductor device and a logic device are formed on top, and a composite layer is formed on the upper ground and the top cover.辻 ί: ί A connection structure is formed in the above-insulative ~ the insulation should be the above, the memory element constitutes an electrical connection: and the connection structure Η 0503-5813TWF-ptd page 6

4650、 五'發明說明(4) 形成於上述複合層和第一絕緣層中’盥對應之 件構成電性連接,並露出於上述複合層之;j:;处邏輯元 Π b)形成第二絕緣層於上述複合層之上; (1 c)疋義蝕刻上述第二絕緣層,以露出上述— 結構上方之複合層; 運接 (ld) 以上述第二絕緣層為第一遮罩,蝕刻上述 區到露出上述第一連接結構’並在上述複合層中形成:二 (le) 形成第一金屬層於上述第一連接結構、上 區之側壁、及上述第二絕緣層之上; 幵 (1〇去除形成於上述第二絕緣層上、及上述 側壁上端部分之第一金屬層;其t,留存於上述; 壁上之上述第一金屬層與上述複合層之表面 ^貝 隔; 特疋間 (ig)形成介電層於上述第一金屬層、及上 側壁上端部分之上; < 间口&之 (lh)形成第二金屬層於上述介電層之上,並 述開口區;其中,形成於上述開口區中之上述第 屬 層、上述介電層、及上述第一金属層構& 之垂直型MIM電容器。 ^-己隐體凡件 為達成上述目的,本發明提出之第二種垂 絕緣物-金屬電容器之製造方法,包括如下步驟直金屬 (2a)提供一半導體基底;其中,上述基 · 少-記憶體元件和至少一邏輯元件’一第一絕緣層覆^4650, Five 'invention description (4) The corresponding parts formed in the above-mentioned composite layer and the first insulation layer constitute an electrical connection and are exposed at the above-mentioned composite layer; j :; the logical element Π b) forming the second The insulating layer is on the composite layer; (1 c) the second insulating layer is etched to expose the composite layer above the structure; the operation is to use the second insulating layer as a first mask to etch The above region exposes the first connection structure ′ and is formed in the composite layer: (2) forming a first metal layer on the first connection structure, a sidewall of the upper region, and the second insulation layer; 幵 ( 10 removing the first metal layer formed on the second insulating layer and the upper end portion of the side wall; t, remaining in the above; the surface of the first metal layer on the wall and the surface of the composite layer are separated; (Ig) forming a dielectric layer on the first metal layer and the upper end portion of the upper side wall; < (lh) forming a second metal layer on the dielectric layer, and describing the opening area ; Wherein the above-mentioned subordinate layer formed on the above-mentioned opening region, The dielectric layer and the vertical MIM capacitor of the above-mentioned first metal layer structure. ^ -Hidden body To achieve the above-mentioned object, the second method for manufacturing a vertical insulator-metal capacitor proposed by the present invention includes the following: Step Straight metal (2a) provides a semiconductor substrate; wherein the base-less-memory element and at least one logic element 'a first insulating layer cover ^

(2g)形成介電層於上述第一金屬層、及上述開口區之 側壁上端部分之上; (2h)形成第一金屬層於上述介電層之上,並且填滿上 述開口區;其中,形成於上述開口區中之上述第二金屬 層、上述介電層、及上述第一金屬層構成上述記憶體元件 之垂直型MIM電容器。(2g) forming a dielectric layer on the upper end portion of the first metal layer and the sidewall of the opening region; (2h) forming a first metal layer on the dielectric layer and filling the opening region; wherein, The second metal layer, the dielectric layer, and the first metal layer formed in the opening region constitute a vertical MIM capacitor of the memory element.

0503-5813TVF-pta 第8頁 46 50 ^ 五、發明說明(6) 圖式之簡單說明: 為讓本發明之上述目的、特徵、和優點能更明顯易懂,下 文特舉較佳實施例,並配合所附圖式,做詳細說明如下: 第1圖係顯示嵌入式DRAM之部分剖面結構示意圖; 第2a圖至第2g圖係顯示本發明方法第一實施例之流程剖面 圖;以及 第3 a圖至第3 g圖係顯示本發明方法第二實施例之流程剖面 圖。 符號說明: 1 0〜基底;Μ1 -M2〜記憶體元件;U -L 2〜邏輯元件; 11〜第一絕緣層;1 2〜接觸插栓;1 3〜第二絕緣層; 14〜第一電極層;15〜介電層;16〜第二電極層; 1 7 ~第三絕緣層;1 8〜接觸孔洞;2 0〜半導體基底; MIM-MD2〜記憶體元件;LD卜LD2邏輯元件; 2 1〜第一絕緣層;2 2 ~複合層;2 2 a•〜第一中間絕緣層; 22b〜第二中間絕緣層;23〜第一連接結構; 24〜第二連接結構;2.4a〜第一接觸插栓; 24b〜第二接觸插栓;25〜第二絕緣層;26〜第一金屬 層; 27〜光阻;28〜介電層;29〜第二金屬層;0P〜開口區; 30〜半導體基底;3卜第一絕緣層;32~複合層; 32a〜第一中間絕緣層;32b〜第二中間絕緣層;0503-5813TVF-pta Page 8 46 50 ^ V. Description of the invention (6) Brief description of the drawings: In order to make the above-mentioned objects, features, and advantages of the present invention more comprehensible, the following describes preferred embodiments, In conjunction with the accompanying drawings, detailed descriptions are as follows: FIG. 1 is a schematic diagram showing a partial cross-sectional structure of an embedded DRAM; FIGs. 2a to 2g are cross-sectional views showing a flow of a first embodiment of the method of the present invention; and FIG. Figures a to 3g are cross-sectional views showing the flow of the second embodiment of the method of the present invention. Explanation of symbols: 10 ~ substrate; M1-M2 ~ memory element; U-L2 ~ logic element; 11 ~ first insulating layer; 12 ~ contact plug; 13 ~ second insulating layer; 14 ~ first Electrode layer; 15 to dielectric layer; 16 to second electrode layer; 17 to third insulating layer; 18 to contact hole; 20 to semiconductor substrate; MIM-MD2 to memory element; LD and LD2 logic element; 2 1 ~ first insulation layer; 2 2 ~ composite layer; 2 2a • ~ first intermediate insulation layer; 22b ~ second intermediate insulation layer; 23 ~ first connection structure; 24 ~ second connection structure; 2.4a ~ First contact plug; 24b to second contact plug; 25 to second insulating layer; 26 to first metal layer; 27 to photoresist; 28 to dielectric layer; 29 to second metal layer; 0P to open area 30 ~ semiconductor substrate; 3 first insulation layer; 32 ~ composite layer; 32a ~ first intermediate insulation layer; 32b ~ second intermediate insulation layer;

8503-551 3117·:,;!! 第9頁 4650g3 五、發明說明(7) ---- 3 3-¾ 币〜連接結構:33丨〜第一部分;3 32〜第一部分; 2-a~3\—導電性插栓;34〜第二連接結構; 3 4 3 \ 楚 弟一接觸插栓;34b〜第二接觸插栓; 3 5 \ 乐二絕緣層;36〜第一金屬層;37〜光阻: 38〜介電層;39〜第二金屬層。 實施例: 第2a圖至第2g圖係顯示本發明方法第一實施例之流程 剖面圖°圖中’標示Logic者係表示形成有邏輯電路之區 域(例如由若干M0S電晶體所構成)’而標示Memory者係 表示形成有DRAM記憶體之區域。 耳先參照第2a圖,提供一半導體基底20 ;上述基底2〇 上形成有至少一記憶體元件MD1和至少一邏輯元件LD1 ;— 第—絕緣廣21覆蓋上述記憶體元件MD 1和邏輯元件LD1 ; — 複合層22形成於上述第一絕緣層上21。其中,上述複合層 22係由包含一至多層之絕緣物(例如,te〇S、IMD等)所構 成;在此實施例中,上述複合層2 2係由第一中間絕緣層 22a和第二中間絕緣層22b所構成之雙層結構。 至少一第一連接結構23,形成於上述第一絕緣21中, 而與對應之上述記憶體元件MD1構成電性連接在此實施例 中’係為2個具導電性之接觸插栓(contact plug)。 至少一第二連接結構24形成於上述複合層22和第一絕 緣層21之中’與對應之上述邏輯元件LD1構成電性連接, 並露出於上述複合層22之外。其中,上述第二連接結構8503-551 3117 ·:, !! Page 9 4650g3 V. Description of the invention (7) ---- 3 3-¾ Coin ~ Connection structure: 33 丨 ~ Part 1; 3 32 ~ Part 1; 2-a ~ 3 \ —conductive plug; 34 ~ second connection structure; 3 4 3 \ Chudi first contact plug; 34b ~ second contact plug; 3 5 \ Le Er insulation layer; 36 ~ first metal layer; 37 ~ Photoresist: 38 ~ dielectric layer; 39 ~ second metal layer. Example: Figures 2a to 2g are cross-sectional views showing the flow of the first embodiment of the method of the present invention. In the figure, the "labeled Logic means the area where the logic circuit is formed (for example, composed of several MOS transistors)". Those who indicate Memory indicate the area where the DRAM memory is formed. First, referring to FIG. 2a, a semiconductor substrate 20 is provided; at least one memory element MD1 and at least one logic element LD1 are formed on the above-mentioned substrate 20;-the first-insulator 21 covers the memory element MD1 and the logic element LD1 — The composite layer 22 is formed on the first insulating layer 21 described above. Wherein, the composite layer 22 is composed of one to multiple layers of insulators (for example, teOS, IMD, etc.); in this embodiment, the composite layer 22 is composed of the first intermediate insulating layer 22a and the second intermediate layer. A two-layer structure composed of an insulating layer 22b. At least one first connection structure 23 is formed in the first insulation 21 and forms an electrical connection with the corresponding memory element MD1. In this embodiment, it is two contact plugs with conductivity (contact plug ). At least one second connection structure 24 is formed in the composite layer 22 and the first insulating layer 21 'and is electrically connected to the corresponding logic element LD1, and is exposed outside the composite layer 22. Wherein, the above-mentioned second connection structure

0503_5B13TWFpid 第ίο頁 465093 五、發明說明(8) 24 ’包含一第一接觸插栓24a形成於上述第一絕緣層以 中;一第一金屬連線層metal-1形成上述第一接觸^栓24a 及上述第一絕緣層21之上:一第二接觸插栓24b形成於上 述第一中間絕緣層22a中;一第二金屬連線層metM_2形成 上述第一接觸插栓24b及上述第一中間絕緣層22a之上;以0503_5B13TWFpid Page 465093 V. Description of the Invention (8) 24 'Contains a first contact plug 24a formed in the above-mentioned first insulating layer; a first metal wiring layer metal-1 forms the above-mentioned first contact plug 24a And above the first insulation layer 21: a second contact plug 24b is formed in the first intermediate insulation layer 22a; a second metal wiring layer metM_2 forms the first contact plug 24b and the first intermediate insulation Layer 22a;

及,一第二接觸插栓2 4 c形成於上述第二中間絕緣層2 2 b 中 G 之後’先形成第二絕緣層25於上述複合層22之上。其 中’上述第二絕緣層2 5例如為薄氧化層,厚度為2 〇 〇〜 50 0 A。 接著’以微影製程定義蝕刻上述第二絕緣層2 5及複合 層22 ’直到露出上述第一連接結構,而在上述複合層“ 中形成開α區〇p ;如第η圖所示。 去除光阻層PR後’結果如第2c圖所示。所形成之上述 開口區0P ’係為了定義DRAM記憶體元件MD1所需之貯存電 容器。 形成第一金屬層26於上述第一連接結構23、上述開口 區0P之側壁、及上述第二絕緣層25之上;結果如第2d圖所 不。其中,上述第一金屬層26係選擇自:Ti、TiN 、 Ti/TiN、TaN、w、WN 其中之一,厚度為200 〜500 A,例 如使用化學氣相沈積法、或濺鍍法在溫度小於4 5 0 t之條 件下而形成。 接著’先將旋塗式(spin-on)光阻27塗佈於上述第一 金屬層26之上’亦或是形成底部防反光層(BARC)於上述第And, a second contact plug 2 4 c is formed after G in the second intermediate insulating layer 2 2 b ′, and a second insulating layer 25 is formed on the composite layer 22 first. Among them, the above-mentioned second insulating layer 25 is, for example, a thin oxide layer having a thickness of 2000 to 500 A. Next, 'etch the above-mentioned second insulating layer 25 and the composite layer 22 with a lithographic process definition until the above-mentioned first connection structure is exposed, and an open α region oop is formed in the above-mentioned composite layer'; as shown in FIG. Η. Remove The result of the photoresist layer after PR is shown in FIG. 2c. The above-mentioned opening area 0P is formed to define a storage capacitor required for the DRAM memory element MD1. A first metal layer 26 is formed on the first connection structure 23, The side wall of the above-mentioned opening region 0P and the above-mentioned second insulating layer 25; the result is not shown in Fig. 2d. Among them, the first metal layer 26 is selected from: Ti, TiN, Ti / TiN, TaN, w, WN One of them has a thickness of 200 to 500 A, and is formed, for example, by using a chemical vapor deposition method or a sputtering method at a temperature of less than 450 ° T. Next, a spin-on photoresist is first formed. 27 is coated on the first metal layer 26 'or a bottom anti-reflective layer (BARC) is formed on the first

第11頁 50 9 3 五、發明說明(9) -金屬層26之上(兩者均填滿上述開口區〇p)。接著 =蝕上述光阻27、或底部反光層,使得上述開口區〇p内, 殘留有:阻層27、或底部反光層。其中,採用旋塗式光阻 可對塗佈之光阻27先進行部分曝光之後再顯影, j衫後則於上述開口區0P内之殘留有部分之光阻”。在此 汽施例中係採用旋塗式光阻2 7。 然後,以殘留之光阻27作為第二遮罩’對上述 屬層26進行触刻,以去除形成於上述第二絕緣層25上、及 述開:區0P之側壁上端部分之第一金屬層⑼,結果如第 e圖所不。其中,殘留於上述開口區OP側壁上之上述第一 金屬層26與上述^二絕緣層25之表面相距—特‘ (約為20 00 ~ 3000 A )。 ^ 去除上述第二遮罩後,接著形成介電層28於上述 金屬層26、及上述開口區〇{>之側壁上端部分之上。 上述介電層28係由具有高有介電常數之材料所形成: 如,厚度為60〜150 A之Ta2 05。由於形成Ta2a層之、、e声 i'於=,二以不會影響前述步驟之各個金屬層(如:ΐ 第一連接結構)。 再形成第二金屬層29於上述介電層28之上,並且垃、$ 層 29 係選擇自:Ti、TiN 、Ti/TiN、TaN、w、_ 其;之屬 —,厚度為2 0 0〜5 0 0 A,例如使用化學氣相沈積法、 濺鑛法在溫度小於4 5 0 ec之條件下而形成。 需注意的是:上述記憶體元件〇1之貯電容器係由,①形Page 11 50 9 3 V. Description of the invention (9)-Above the metal layer 26 (both fill the above-mentioned opening area oop). Then, the photoresist 27 or the bottom reflective layer is etched, so that the resist layer 27 or the bottom reflective layer remains in the opening area oop. Among them, the spin-coated photoresist can be used to partially expose the coated photoresist 27 and then develop it. After the j-shirt, there is a part of the photoresist remaining in the above-mentioned opening area 0P. " Spin coating type photoresist 27 is used. Then, using the remaining photoresist 27 as a second mask, the above-mentioned metal layer 26 is etched to remove the second insulating layer 25 formed thereon, and the area is 0P The first metal layer ⑼ at the upper end portion of the side wall is as shown in FIG. E. Among them, the first metal layer 26 remaining on the side wall of the opening area OP is spaced from the surface of the second insulating layer 25—specially ( (Approximately 20 00 to 3000 A). ^ After removing the second mask, a dielectric layer 28 is formed on the metal layer 26 and the upper end portion of the sidewall of the opening region 0 {>. The dielectric layer 28 It is formed of a material with a high dielectric constant: for example, Ta2 05 with a thickness of 60 to 150 A. Because the Ta2a layer is formed, the sound is not equal to =, and the two metal layers will not affect the foregoing steps. (Eg: ΐ first connection structure). A second metal layer 29 is further formed on the dielectric layer 28, Moreover, the layer 29 is selected from: Ti, TiN, Ti / TiN, TaN, w, _, which is the genus, and the thickness is 2 0 ~ 5 0 0 A, for example, using chemical vapor deposition method, sputtering The method is formed at a temperature of less than 4 50 ec. It should be noted that the storage capacitor of the above-mentioned memory element 01 is formed by ①

第12頁 46509: 五 '發明說明(ίο) ^於上述開口區OP中之上述第二金屬層29 (作為貯存電容 斋之上電極層1;(^-616(;1;1'〇{16)、0上述介電層28、及0上 述開口區0P内之第一金屬層26 (作為貯存電容器之下電極 層 bottom-electrode),三者所構成。 此外’在形成上述第二金屬層2 9後,更使用化學機械 研磨法(CMP)進行平坦化’去除位於上述開口區〇p以外之 上述第二金屬層29、介電層28、及第二絕緣層25 ’以露出 上述第二連接結構24。再進行金屬化製程,依應用之所需 形成必要之第三金屬連線層metah3 ;結果如第2§圖所 示。 實施例二: 第3a圖至第3 f圖係顯示本發明方法第二實施例之流程 剖面圖。圖中’標示L〇gic者係表示形成有邏輯電路之區 域(例如’由若干M0S電晶體所構成),而標示Memory者係 表示形成有DRAM記憶體之區域。 參照第3a圖’首先提供一半導體基底3〇 ;上述基底3〇上形 成有至少—記憶體元件MD2和至少一邏輯元件LD2 :—第一 絕一緣層31覆蓋上述記憶體元件MD2和邏輯元件lD2 ; —複合 層32形成於上述第一絕緣層上31。其中,上述複合層32係 由包含—至多層之絕緣物(例如,TE0S、IMD等)所構成; 在此實施例中,上述複合層32係由第一中間絕緣層32a和 第二中間絕緣層3 2b所構成之雙層結構。 至少一第一連接結構33,具有第一部分33和第二部分Page 12 46509: Five 'invention description (ίο) ^ The above-mentioned second metal layer 29 in the above-mentioned opening area OP (as the electrode layer 1 above the storage capacitor; (^ -616 (; 1; 1'〇 {16 ), 0 of the above-mentioned dielectric layer 28, and 0 of the first metal layer 26 (as the bottom-electrode layer bottom-electrode of the storage capacitor) within the above-mentioned opening area 0P. In addition, 'the above-mentioned second metal layer 2 is formed 2 After 9th, chemical mechanical polishing (CMP) is used for planarization. 'The second metal layer 29, the dielectric layer 28, and the second insulating layer 25' located outside the opening area oop are removed to expose the second connection. Structure 24. A metallization process is performed to form the necessary third metal connection layer metah3 according to the application requirements; the result is shown in Figure 2§. Second embodiment: Figures 3a to 3f show the present invention Sectional flow chart of the second embodiment of the method. In the figure, 'Locic' indicates the area where the logic circuit is formed (for example, 'formed by a number of MOS transistors), and memory' indicates the area where the DRAM memory is formed. Area. Referring to FIG. 3a ', a semiconductor substrate 30 is first provided; The substrate 30 is formed with at least-a memory element MD2 and at least one logic element LD2:-a first insulating edge layer 31 covers the above-mentioned memory element MD2 and the logic element 1D2;-a composite layer 32 is formed on the above-mentioned first insulating layer The above 31. Among them, the above-mentioned composite layer 32 is composed of-to multiple layers of insulation (for example, TEOS, IMD, etc.); in this embodiment, the above-mentioned composite layer 32 is composed of the first intermediate insulation layer 32a and the second A double-layer structure composed of an intermediate insulating layer 3 2b. At least one first connection structure 33 has a first portion 33 and a second portion

D533-5B13TWF-1T 第13頁 4b 93 五、發明說明(11) 3 32 ’分別形成於上述第一絕緣層3 1和上述複合層3 2中, 而與對應之上述記憶體元件M D 2構成電性連接。在此實施 例中,上述第一部分3 3! ’係為2個具導電性之接觸插栓 (contact plug)。而上述第二部分’係由至少一導電 連線層及導電性插栓依序交錯地形成於上述第一部分3 3, 之上而構成;在此實施例中’上述第二部分332包含2個金 屬連線層(metal-1、metal-2)和2個導電性插栓(339 a、 3 32 b),如第3a圖所示。 至少一第二連接結構34形成於上述複合層32和第一絕 緣31之中,與對應之上述邏輯元件LD2構成電性連接,並 露出於上述複合層32之外。其中,上述第二連接結構34, 包含一第一接觸插栓34a形成於上述第一絕緣層31中;一 第一金屬連線層roe tal-1形成上述第一接觸插栓3 4a及上述 第二絕緣層3 1之上;一第二接觸插栓34b形成於上述第一D533-5B13TWF-1T Page 13 4b 93 V. Description of the invention (11) 3 32 'are formed in the above-mentioned first insulating layer 31 and the above-mentioned composite layer 32, respectively, and form electrical connection with the corresponding memory element MD 2 Sexual connection. In this embodiment, the first part 3 3! ′ Is two contact plugs with conductivity. The above-mentioned second portion ′ is composed of at least one conductive connection layer and conductive plugs which are sequentially and staggeredly formed on the above-mentioned first portion 3 3 ,; in this embodiment, the above-mentioned second portion 332 includes two Metal wiring layers (metal-1, metal-2) and two conductive plugs (339 a, 3 32 b), as shown in Figure 3a. At least one second connection structure 34 is formed in the composite layer 32 and the first insulation 31, and is electrically connected to the corresponding logic element LD2, and is exposed outside the composite layer 32. The second connection structure 34 includes a first contact plug 34a formed in the first insulating layer 31, and a first metal connection layer roe tal-1 forms the first contact plug 34a and the first contact plug 34a. Over two insulating layers 31; a second contact plug 34b is formed on the first

連接結構33之第二部分3 32,而於上 口區0? ’並露出上述第一連接結構33 3c圖所示。形成上述開口區0P,係The second part 3 32 of the connection structure 33 is shown in the above-mentioned first connection structure 33 3c in the mouth area 0? '. Form the above-mentioned open area 0P,

第14頁 46 SO 93 五、發明說明(12) 為了定義DRAM記憶體元件jjD2所需之貯存電容器。 其中’去除上述第一連接結構33之第二部分3 32 ’係 採用札〇2溶液,並配合使用成分為CH3COOH/HN〇3/H3p〇4/M 之混合液而完成。H2〇2溶液係用以去除上述第二部分33s中 之導電性插栓33a a和3 3211 (兩者例如由鎢金屬w所構成)° 而CH3COOH./HN03/H3P〇4/h2〇之混合比,例如為5 : 5 : 85 : 5則係用以去除上述第二部分3(32中之金屬連線層 (metai-1、meta卜2) 〇 接著’形成第一金屬層36於上述第—連接結構33之第 一部分33!、上述開口區〇p之側壁 '第二中間絕緣層32b、 及上述第二絕緣層35之上:結果如第3d圖所示。其中,上 述第一金屬層36係選擇自:Ti、Ti N 、Ti/TiN、TaN、W、 ft N其中之一,厚度為2 〇 〇〜5 〇 〇人’例如使用化學氣相沈 積法、或滴:鐘法在溫度小於45〇。(:之條件下而形成。 接著’先將旋塗式(Spin_on)光阻37塗佈於上述第一 金屬層36之上,亦或是形成底部防反光層(BARC)於上述第 一金屬層3 6之上(兩者均填滿上述開口區〇p)。接著, 回蝕上述光阻37、或底部反光層,使得上述開口區〇p 殘留有光阻層37、或底部防反光層。其中,採用旋朵 阻3m,亦可對塗佈之光阻37先進行部分曝光之:光 影,顯影後則於上述開口區0P内之殘留有部分之 ^ 在此實施例中係採用旋塗式光阻3 7。 ° 然後’以殘留之光阻37作為遮罩,對上述第— 36進行蝕刻,以去除形成於上述第二絕緣層25上、笛層Page 14 46 SO 93 V. Description of the invention (12) In order to define the storage capacitor required for DRAM memory element jjD2. Among them, the “removing the second part 3 32” of the first connecting structure 33 is completed by using a ZA 02 solution and using a mixed solution of CH3COOH / HNO3 / H3po4 / M. The H2O2 solution is used to remove the conductive plugs 33a a and 3 3211 in the second part 33s (both are composed of tungsten metal w, for example). ° The mixture of CH3COOH./HN03/H3P〇4/h2〇 The ratio, for example, 5: 5: 85: 5 is used to remove the second part 3 (the metal connection layer (metai-1, meta 2) in 32). Then, the first metal layer 36 is formed on the first -The first portion 33! Of the connection structure 33, the side wall 'second intermediate insulating layer 32b of the above-mentioned open area oop, and the above-mentioned second insulating layer 35: the result is shown in Fig. 3d. Among them, the above-mentioned first metal layer The 36 series is selected from: Ti, Ti N, Ti / TiN, TaN, W, ft N, and the thickness is 2,000 to 5,000 people. For example, using a chemical vapor deposition method, or a drop: bell method at temperature Less than 45 °. (: Formed under the conditions. Then, 'Spin_on' photoresist 37 is first coated on the first metal layer 36, or a bottom anti-reflective layer (BARC) is formed on the above Above the first metal layer 36 (both fill the above-mentioned opening area 0p). Then, the photoresist 37 or the bottom reflective layer is etched back to make the above-mentioned opening area. p Residual photoresist layer 37 or anti-reflection layer at the bottom is left. Among them, the use of a spin resistance of 3m can also partially expose the coated photoresist 37: light and shadow, and remain in the open area 0P after development. Some ^ In this embodiment, a spin-coating photoresist 37 is used. ° Then, using the remaining photoresist 37 as a mask, the above -36th is etched to remove the second insulating layer 25 formed above. Upper and lower layers

第15頁 4 6 5 Ο 9 3 五、發明說明(13) 間絕緣層32b、及上述開口區OP之側壁上端部分 屬層36,結杲如第3e圖所示。其中,逄f °刀之第—金 茂d於上述開口 惻壁上之上述第一金屬層36與上述複合居u 特定間隔d2 (約為200 0〜3000 A )。 & ~~ 在去除上述遮罩後’接著形成介電層38於上 — 屬層36、及上述開口區0P之側壁上端部分之上。其金 述介電層38係由具有高有介電常數之材料所形成了中’上 厚度為60 - 150 A之TagO5或BST。由於形成丁32〇5層 度小於450 t ’所以不會影響前述步驟之各個金屬層。之溫 再形成第二金屬層39於上述介電層38之上,並曰 上述開口區0P,結果如第3f圖所示。其中,μ、+.姑 填滿 層 39 係選擇自:Ti、TiN 、Ti/TiN、TaN、W、WN 其;屬 一’厚度為2 0 0〜5 0 0入,例如使用化學氣相沈積法之 濺鍍法在溫度小於450 r之條件下而形成。 '或 需注意的是:上述記憶體元件MD2之貯電容器係由 ①形成於上述開口區0P中之上述第二金屬層39 (作為^ 電容器之上電極層top-electrode)、②上述介電層38 了存 ③上述開口區0P内之第一金屬層36 (作為貯存電容3|之及 電極層bottom-electrode),三者所構成。 下 此外’在形成上述第二金屬層39後,更使用化學 研磨法(CMP)進行平坦化,去除位於上述開口區〇p以外、、 上述第二金屬層39、介電層38、及第二絕緣層35,以露 上述第二連接結構34。再進行金屬化製程,依應用 匕出 形成必要之第三金屬連線層meta卜3 ;結果如第3g圖所Page 15 4 6 5 Ο 9 3 V. Description of the invention (13) The interlayer insulating layer 32b and the upper end part of the side wall of the above-mentioned open area OP belong to the layer 36, and the result is shown in Fig. 3e. Among them, the first metal layer 36 of the 逄 f ° blade on the wall of the opening 与 and the composite space u have a specific interval d2 (about 200 0 to 3000 A). & ~~ After the above mask is removed ', a dielectric layer 38 is then formed on the upper-general layer 36 and the upper end portion of the sidewall of the above-mentioned open area OP. The metal dielectric layer 38 is formed of TagO5 or BST with a thickness of 60 to 150 A on the middle 'layer formed of a material having a high dielectric constant. Since the formation of D 3205 layer is less than 450 t ′, each metal layer of the foregoing step is not affected. At this temperature, a second metal layer 39 is further formed on the dielectric layer 38, and the above-mentioned opening area OP is formed. The result is shown in Fig. 3f. Among them, the μ, +. Filling layer 39 is selected from: Ti, TiN, Ti / TiN, TaN, W, WN, which is a thickness of 2 0 ~ 5 0, such as using chemical vapor deposition The sputtering method is formed at a temperature of less than 450 r. 'Or note that the storage capacitor of the memory element MD2 is composed of ① the second metal layer 39 (as the top-electrode of the capacitor above the capacitor layer) formed in the opening area 0P, and ② the dielectric layer. The first metal layer 36 (as the storage capacitor 3 | and the electrode layer bottom-electrode) in the above-mentioned opening area OP is composed of three. After the formation of the second metal layer 39, planarization is further performed using a chemical polishing method (CMP) to remove the second metal layer 39, the dielectric layer 38, and the second metal layer located outside the opening region oop. The insulating layer 35 exposes the second connection structure 34. The metallization process is then performed, and the necessary third metal connection layer meta 3 is formed according to the application; the result is as shown in Figure 3g.

〇503-5313TW?-p:d 第16頁 ^65093 五、發明說明(14) 示 實施例可知,應用本發明方法之優 由上述第一、第 點有: 在嵌。入式DRAM中形成垂直型MIM電容器’係採用低溫 (小於450 C )製程。因此,形成電容器時之熱製程循環 (thermal cycle),對於先前所形成邏輯元件中之接觸插 栓、金屬連線層、及電晶體…等,不會造成不良之影響故 可提昇良率。 由於邏輯元件中之接觸插栓、金屬連線層係先於MU1 電谷器形成,因此接觸孔洞不會具有極大之高度—開口 比。 MIM! 了存電容器之深度大小,不是限定於和 metal-2兩個層面之間,故其電容器之電容值,可藉由變 化複合層之層數、厚度而進行調整。 雖然本發明已以兩個較佳實施例揭露如上,然其並非 用以限定本發明,任何熟悉本項技藝者,在不脫離本發明 之精神和範圍内,當可做些許之更動和潤飾,因此本發明 之保護範圍當視後附之申請專利範圍所界定者為準。 參考資料: [1] S.Kamiyama, J. Drynan, Y.Takaishi, and K.Koyama, M Highly reliable MIM capacitor technology using low pressure CVD-WN cylinder〇503-5313TW? -P: d p. 16 ^ 65093 5. Description of the invention (14) It can be seen from the examples that the advantages of applying the method of the present invention include the following points: The formation of vertical MIM capacitors in the in-line DRAM is a low temperature (less than 450 C) process. Therefore, the thermal cycle when the capacitor is formed does not cause adverse effects on the contact plugs, metal connection layers, transistors, etc. in the previously formed logic elements, which can improve the yield. Because the contact plugs and metal connection layers in the logic components are formed before the MU1 valley trough, the contact holes will not have a great height-to-opening ratio. MIM! The depth of the storage capacitor is not limited to the two layers of metal-2, so the capacitance of the capacitor can be adjusted by changing the number and thickness of the composite layers. Although the present invention has been disclosed as above with two preferred embodiments, it is not intended to limit the present invention. Anyone skilled in the art can make some modifications and retouching without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention shall be determined by the scope of the appended patent application. References: [1] S.Kamiyama, J. Drynan, Y.Takaishi, and K.Koyama, M Highly reliable MIM capacitor technology using low pressure CVD-WN cylinder

0503-5813TWF.ptd 第17頁 465093 五、發明説明(15) storage-node for 0.12 um-scale embedded DRAM", Symposium on VLSI Technology, paper#4A-4, p. 39-40, 1999.0503-5813TWF.ptd page 17 465093 V. Description of the invention (15) storage-node for 0.12 um-scale embedded DRAM ", Symposium on VLSI Technology, paper # 4A-4, p. 39-40, 1999.

[2] K.Kim, et. a 1. , "A DRAM technology using MIM BST capacitor for 0.15 DRAM generation and beyond", Symposium on VLS ί Technology, paper#4A-1, p. 33-34, 1 999.[2] K. Kim, et. A 1., " A DRAM technology using MIM BST capacitor for 0.15 DRAM generation and beyond ", Symposium on VLS ί Technology, paper # 4A-1, p. 33-34, 1 999 .

[3] P.W.Diodato, et al, "Merged DRAM-LOGIC in the Year 2001", IEEE Transaction (1998).[3] P.W. Diodato, et al, " Merged DRAM-LOGIC in the Year 2001 ", IEEE Transaction (1998).

[4] C.Y. Sun, et al, "Low Temperature Fully Planarized Capacitor-After-Metal-1-Process (CAMP) for Manufacturable Gigabit Scale Embedded DRAM Technologies”.[4] C.Y. Sun, et al, " Low Temperature Fully Planarized Capacitor-After-Metal-1-Process (CAMP) for Manufacturable Gigabit Scale Embedded DRAM Technologies ".

C5〇3-5S13T¥f 第18頁C5〇3-5S13T ¥ f p.18

Claims (1)

465093465093 丄. 方法,適 提供 記憶體元 憶體元件 上;至少 之上述記 成於上述 構成電性 形成 和邏輯元件, 一第一連接結 憶體元 複合層 連接,並露出 弟二絕緣層於 種垂直型金屬-絕緣物-金 用於記憶體元件和邏輯元 一半導體基底:其中,上 件和至少一邏輯元件,一 一複合層形 構形成於上 件構成電性連接; 和第一絕緣層中, 於上述複合 上述複合層 屬(MIM)電容器之製造 件之整合製造,包括: 述基底上形成有至少__ 第一絕緣層覆蓋上迷言己 成於上述第一絕緣層 述第一絕緣中,與對應 至·^ 一第·一連接結構形 與對應之上述邏輯元件 層之外; 之上; … 定義餘刻上述第二絕緣層和上述複合層,直到露出上 述第一連接結構’並在上述複合層中形成開口區; 形成第一金屬層於上述第一連接結構、上述開口區之 側壁、及上述第二絕緣層之上; -去除形成於上述第二絕緣層上、及上述開口區之側壁 上端部分之第一金屬層;其中’留存於上述開口區側壁上 之上述第一金屬層與上述複合層之表面相距一特定間隔; 形成介電層於上述第一金屬層、及上述開口區之側壁 上端部分之上; 形成第二金屬層於上述介電層之上,並且填滿上述開 口區;其中’形成於上述開口區内之上述第二金屬層、上 述介電層、及上述第一金屬層構成上述記愧體元件之垂直 型MIM電容器。 2.如申請專利範圍第1項所述之製造方法,其中,上方法. Method, suitable for providing memory element memory element; at least the above is recorded in the above-mentioned constituent electrical formation and logic element, a first connection junction memory element composite layer is connected, and the second insulation layer is exposed to the vertical Type metal-insulator-gold is used for memory element and logic element-semiconductor substrate: wherein the upper part and at least one logic element, a one-to-one composite layer structure is formed on the upper part to form an electrical connection; and in the first insulating layer The integrated manufacturing of the above-mentioned composite MIM capacitor manufacturing component includes: forming at least __ a first insulating layer covered on the substrate and a mystery formed in the first insulating layer and the first insulating layer, And corresponding to the first and first connection structure shapes and corresponding to the above-mentioned logic element layer; above;… define the second insulation layer and the composite layer above until the first connection structure is exposed and the above Forming an opening region in the composite layer; forming a first metal layer on the first connection structure, a side wall of the opening region, and the second insulating layer; A first metal layer on the second insulating layer and an upper end portion of the side wall of the opening area; wherein the first metal layer remaining on the side wall of the opening area and the surface of the composite layer are at a specific distance; An electric layer is formed on the first metal layer and the upper end portion of the sidewall of the opening region; a second metal layer is formed on the dielectric layer and fills the opening region; wherein the above is formed in the opening region The second metal layer, the dielectric layer, and the first metal layer constitute the vertical MIM capacitor of the shame body element. 2. The manufacturing method described in item 1 of the scope of patent application, wherein the above 465093 六、申請專利範園 述第二絕緣層係為厚度2 0 0〜5 0 〇 A之薄氧化層。 3.如申請專利範圍第1項所述之製造方法,其中,上 述第一、第二金屬層所使用之金屬’均係可在溫度小於 4 5 0 °C之條件下形成。 4 ·如申請專利範圍第1項所述之製造方法,其中,上 述第一、二金屬層係選擇自:Ti、TiN 、Ti/TiN ' TaN ' W、WN其中之一’厚度為2 0 0 ~ 500 A。 5.如申請專利範圍第1項所述之製造方法,其中,上 述第一、二金屬層’係使用化學氣相沈積法 '或賤鍍法而 形成。 6.如申請專利範圍第1項所述之製造方法,其中,去 除部分上述第一金屬層,包括下列步驟: 在上述開口區内之上述第一金屬層上形成第二遮, 而露出形成於上述第二絕緣層上 '及上述開口區之辟 端部分之第一金屬層; 上 去除露出於上述第二遮罩外之上述第一金.、 去除上述第二遮罩^ ’以及 7_如申請專利範圍第項所述之製造方法,兑 述第二遮罩層之形成係先形成光阻層、或底部防、’上 上述第一金屬層上,並填滿匕述開口區;再 光層於 阻層、或底部反光層,而在上述開口區 j上述光 罩。 战述第二遮 作上述第 h导利範圍第6項所述之製造方法,复 遮罩’係先形成光阻層於上述第”中’ 货屬層上465093 VI. Patent Application Park The second insulating layer is a thin oxide layer with a thickness of 200 ~ 500 A. 3. The manufacturing method as described in item 1 of the scope of patent application, wherein the metals' used in the first and second metal layers are all formed at a temperature of less than 450 ° C. 4 · The manufacturing method as described in item 1 of the scope of patent application, wherein the first and second metal layers are selected from: Ti, TiN, Ti / TiN 'TaN' W, WN 'and the thickness is 2 0 0 ~ 500 A. 5. The manufacturing method according to item 1 of the scope of patent application, wherein the first and second metal layers are formed using a chemical vapor deposition method or a base plating method. 6. The manufacturing method according to item 1 of the scope of patent application, wherein removing part of the first metal layer includes the following steps: forming a second mask on the first metal layer in the opening area, and exposing the second mask on the first metal layer; On the second insulating layer and on the first metal layer of the open end of the opening region; removing the first gold exposed from the second mask; removing the second mask ^ 'and 7_ 如For the manufacturing method described in the scope of the patent application, the formation of the second masking layer is to first form a photoresist layer, or a bottom protection layer, on the above first metal layer, and fill the opening area; Layer on the resist layer or the bottom reflective layer, and the photomask in the opening area j. The second cover of the war is the manufacturing method described in item 6 of the h-lead range above, and the complex cover is first formed with a photoresist layer on the above-mentioned "medium" cargo layer. 4 6 5〇4 6 5〇 申請專利範圍 並填 V·、4· 接、上述開口區;再對上述光阻層進行部分曝光,_影 而在μ na ' 上-4開口區内形成上述第二遮罩。 9.如申請專利範圍第1項所述之製造方法, 疋間隔為2000〜3000 A。 地公10 ·如申請專利範圍第1項所述之製造方法 電層係由具有高有介電常數之材料所形成 上11 ‘如申請專利範圍第1 0項所述之製造方法 "電層係為T a2 05 ’厚度為6 0 ~ 1 5 0 A。 形成H、如申请專利範圍第1項所述之製造方法’其中’在 化 过"第一金屬層後’更使用化學機械研磨法進行平坦 層i去除位於上述開口區以外之上述第二金屬層、介電 及第二絕緣層’以露出上述第二連接結構。 1 ^13.如申請專利範圍第1項所述之製造方法 义琅合層係由包含一至多層之絕緣物所構成。 14,如申請專利範圍第1項所述之製造方法 处第一連接結構係為導電性插栓。 15. —種垂直型金屬-絕緣物„金屬(MIM)電容器之製造 去’適用於記憶體元件和邏輯元件之整合製造,包括: ^提供一半導體基底;其中,上述基底上形成有至少一 =愫體元件和至少一邏輯元件,一第一絕緣層 憶體元件和邏輯元件’―複合層形成於上述第一絕二 ^,以及,至少一第—連接結構具有第一、和第二部^ ’ /刀別形成於上述第一絕緣層和上述複合層中,與 述記憶體元件構成電性連接;至少一第二連接結構以 其中 其中 上 上 其中 其中,上 其中,上Scope of the patent application and fill in V ·, 4 ·, and the above-mentioned opening area; and then partially expose the photoresist layer to form the above-mentioned second mask in the -na opening area on μna '. 9. The manufacturing method as described in item 1 of the scope of patent application, with a 疋 interval of 2000 ~ 3000 A. Digong 10 · The manufacturing method described in item 1 of the scope of patent application, the electric layer is formed of a material with a high dielectric constant. The manufacturing method described in item 10 of the scope of patent application " electric layer The system is T a2 05 'and the thickness is 60 ~ 150 A. Form H, the manufacturing method described in item 1 of the scope of the patent application 'wherein' after the " first metal layer " is further flattened by chemical mechanical polishing method i to remove the second metal located outside the opening area Layer, dielectric and second insulation layer 'to expose the second connection structure. 1 ^ 13. The manufacturing method described in item 1 of the scope of patent application Yilang composite layer is composed of one to multiple layers of insulation. 14. The manufacturing method described in item 1 of the scope of patent application where the first connection structure is a conductive plug. 15. —The manufacture of a vertical metal-insulator „metal (MIM) capacitor is suitable for the integrated manufacturing of memory elements and logic elements, including: ^ providing a semiconductor substrate; wherein at least one of the above substrates is formed = The body element and at least one logic element, a first insulating layer, the body element and the logic element'-composite layer are formed on the first insulation element ^, and the at least one first-connection structure has first and second portions ^ / / The knife is formed in the first insulating layer and the composite layer to form an electrical connection with the memory element; at least one second connection structure has one of the upper, the upper, the upper, and the upper. 0503-5813IWF ptd 第21頁 465093 六、申請專利範圍 上述複合層和第〜絕緣層中,與對應之上述邏輯元件構成 電性連接’並露出於上述複合層之外; 形成第二絕緣層於上述複合層之上; 疋義敍刻上迷第二絕緣層,以咸出上述第一連接結構 之第二部分; 去除上述第一連接結構之第二部分,而於上述複合層 中形成開口區’並露出上述第〆連接結構之第一部分; 形成第一金屬層於上述第〆連接結構之第一部分、上 述開口區之側壁、及上述第二絕緣層之上; 去除形成於上述第二絕緣廣上、及上述開口區之側壁 上端部分之第一金屬層;其中,留存於上述開口區側壁上 之上述第一金屬層與上述複合層之表面相距一特定間隔; 形成介電層於上述第一金屬層' 及上述開口區之側壁 上端部分之上; 形成第一金屬層於上述介電廣之上’並且填滿上述開 口區;其中,形成於上述開口區内之上述第二金屬層、上 述介電層、及上述第一金屬層構成上述記憶體元件之垂直 型MIM電容器。 I6.如申請專利範圍第b項所述之。製造一方产,其中, 上述第二絕緣層係為厚度20〇 ~ 5〇〇 A之溥氧化層。 1 7.如申請專利範圍第丨5項所述之氣泣方其中’ 上述第一、第二金屬層所使用之金屬"’、’皿义,、於 之製造方法,其中, 4 5 0 °C之條件下形成。 1 8.如申請專利範圍第丨5項所述0503-5813IWF ptd Page 21 465093 VI. Patent application scope In the above composite layer and the first ~ insulating layer, an electrical connection is formed with the corresponding logic element and exposed outside the above composite layer; forming a second insulating layer on the above On the composite layer; the second insulating layer is engraved to describe the second part of the first connection structure; the second part of the first connection structure is removed, and an open area is formed in the composite layer; The first part of the first connection structure is exposed; a first metal layer is formed on the first part of the first connection structure, a side wall of the opening region, and the second insulation layer; and the first insulation layer is removed from the second insulation structure. And the first metal layer on the upper end portion of the side wall of the opening region; wherein the first metal layer remaining on the side wall of the opening region and the surface of the composite layer are at a specific distance; forming a dielectric layer on the first metal Layer 'and the upper end portion of the side wall of the above-mentioned opening area; forming a first metal layer on the above-mentioned dielectric layer' and filling the above-mentioned opening area; , The second metal layer is formed on the region of the opening on said dielectric layer, and said first metal layer above the MIM capacitor vertical type of memory device. I6. As described in item b of the scope of patent application. The product is manufactured by one manufacturer, wherein the second insulating layer is a samarium oxide layer having a thickness of 20 to 500 A. 1 7. The manufacturing method of Qiqifang described in Item 5 of the scope of patent application, wherein the metal used in the first and second metal layers ", " Formed at ° C. 1 8.As described in item 5 of the scope of patent application 05 03-5ei3TWF-ptii 第22賓 ^650^ - 六、申請專利範圍 Ti/TiN 上述第一、二金屬層係選擇自:Ti、TiN TaN、w、其中之一,厚度為200〜500 a。 1 9 _如申請專利範圍第1 5項所述之製造方法,其中, 上述第一、二金屬層,係使用化學氣相沈積法、或濺鍍法 而形成。 2 0 ·如申請專利範圍第1 5項所述之製造方法,其中, 去除部分上述第一金屬層,包括下列步驟: 、 在上述開口區内之上述第一金屬層上形成遮罩,而露 出形成於上述第二絕緣層上、及上述開口區之側壁上端部 分之第一金屬層; 去除露出於上述遮罩外之上述第一金屬層;以及 去除上述遮罩。 21.如申請專利範圍第2〇項所述之製造方法,其中, 上述遮罩層之形成係先形成光阻層、或底部防反光層於上 述第一金屬層上’並填滿上述開口區;再回蝕刻上述光阻 層、或底部防反光層,而在上述開口區内形成上述遮罩。 2 2,如申請專利範圍第2〇項所述之製造方法,其中, 製作上述遮罩’係先形成光阻層於上述第一金屬層上,並 填滿上述開口區;再對上述光阻層進行部分曝光,顯影後 而在上述開口區内形成上述遮罩。 2 3.如申凊專利範圍第1 5項所述之製造方法’其中, 上述特定間隔為2000〜3000 A。 24·如申請專利範圍第15項所述之製造方法,其中, 上述介電層係由具有高有介電常數之材料所形成。05 03-5ei3TWF-ptii No. 22 guest ^ 650 ^-6. Scope of patent application Ti / TiN The above-mentioned first and second metal layer systems are selected from: Ti, TiN TaN, w, one of which has a thickness of 200 ~ 500 a. 19_ The manufacturing method according to item 15 of the scope of patent application, wherein the first and second metal layers are formed using a chemical vapor deposition method or a sputtering method. 20 · The manufacturing method according to item 15 of the scope of patent application, wherein removing a part of the first metal layer includes the following steps: forming a mask on the first metal layer in the opening area and exposing it A first metal layer formed on the second insulating layer and an upper end portion of a side wall of the opening region; removing the first metal layer exposed outside the mask; and removing the mask. 21. The manufacturing method according to item 20 of the scope of the patent application, wherein the formation of the masking layer is to first form a photoresist layer or a bottom anti-reflective layer on the first metal layer and fill the opening area. ; Etch back the photoresist layer or the bottom anti-reflective layer, and form the mask in the opening area. 2 2. The manufacturing method as described in item 20 of the scope of the patent application, wherein the above-mentioned mask is produced by forming a photoresist layer on the first metal layer and filling the opening area; The layer is partially exposed, and the mask is formed in the opening area after development. 2 3. The manufacturing method according to item 15 of the scope of the patent application, wherein the specific interval is 2000 to 3000 A. 24. The manufacturing method according to item 15 of the scope of patent application, wherein the dielectric layer is formed of a material having a high dielectric constant. 0503-5813TW?ptd 第23頁 4 6 5 00503-5813TW? Ptd Page 23 4 6 5 0 六、申請專利範圍 2 5 *如申請專利範圍第2 4項所述之製造方法,其中 上述介電層係為Ta2〇5,厚度為60 ~ 150 A。 , 2 6.如申請專利範圍第1 5項所述之製造方法,其中/ 在形成上述第二金屬層後,更使用化學機械研磨法進行平 坦化’去除位於上述開口區以外之上述第二金屬層、介電 |層 '及第—絕緣層,以露出上述第一連接結構。 2 7.如申請專利範圍第1 5項所述之製造方法,其中, 上述複合層係由包含一至多層之絕緣物所構成。 2 8.如申請專利範圍第1 5項所述之製造方法,其中, 上述第一連接結構之第一部分係為導電性插栓。 29.如申請專利範圍第15項所述之製造方法,其中, 上述第一連接結構之第二部分,係由至少一導電層及導電 性插栓依序交錯地形成於上述第一連接結構之第一部分上 而構成。 3 0.如申請專利範圍第2 9項所述之製造方法,其中, 去除上述第一連接結構之第二部分’係採用h2〇2溶液,並 配合使用成分為CICOOH/HNOs/HsPO〆1120之混合液而完成。6. Scope of patent application 2 5 * The manufacturing method described in item 24 of the scope of patent application, wherein the dielectric layer is Ta205 and the thickness is 60 to 150 A. 2 6. The manufacturing method as described in item 15 of the scope of the patent application, wherein / after the formation of the second metal layer, a chemical mechanical polishing method is used for planarization to remove the second metal located outside the opening area Layer, dielectric | layer 'and first insulating layer to expose the above-mentioned first connection structure. 2 7. The manufacturing method according to item 15 of the scope of the patent application, wherein the composite layer is composed of one to multiple layers of insulators. 2 8. The manufacturing method according to item 15 of the scope of patent application, wherein the first part of the first connection structure is a conductive plug. 29. The manufacturing method according to item 15 of the scope of patent application, wherein the second part of the first connection structure is formed by at least one conductive layer and conductive plugs in a staggered order in the first connection structure. Constituted on the first part. 30. The manufacturing method as described in item 29 of the scope of the patent application, wherein removing the second part of the first connection structure is using an H2O2 solution, and the composition is used in combination with CICOOH / HNOs / HsPO〆1120. Complete with liquid. 0503-58I3T^^ptd 第24頁0503-58I3T ^^ ptd Page 24
TW089127244A 2000-12-19 2000-12-19 Manufacturing method of vertical metal-insulator-metal capacitor TW465093B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
TW089127244A TW465093B (en) 2000-12-19 2000-12-19 Manufacturing method of vertical metal-insulator-metal capacitor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW089127244A TW465093B (en) 2000-12-19 2000-12-19 Manufacturing method of vertical metal-insulator-metal capacitor
US09/839,964 US6528366B1 (en) 2001-03-01 2001-04-23 Fabrication methods of vertical metal-insulator-metal (MIM) capacitor for advanced embedded DRAM applications

Publications (1)

Publication Number Publication Date
TW465093B true TW465093B (en) 2001-11-21

Family

ID=26666943

Family Applications (1)

Application Number Title Priority Date Filing Date
TW089127244A TW465093B (en) 2000-12-19 2000-12-19 Manufacturing method of vertical metal-insulator-metal capacitor

Country Status (1)

Country Link
TW (1) TW465093B (en)

Similar Documents

Publication Publication Date Title
US6528366B1 (en) Fabrication methods of vertical metal-insulator-metal (MIM) capacitor for advanced embedded DRAM applications
US8492818B2 (en) High capacitance trench capacitor
US6259128B1 (en) Metal-insulator-metal capacitor for copper damascene process and method of forming the same
US6620701B2 (en) Method of fabricating a metal-insulator-metal (MIM) capacitor
US7662695B2 (en) Capacitor structure and fabricating method thereof
US20070152258A1 (en) Semiconductor device with a capacitor
US9831171B2 (en) Capacitors with barrier dielectric layers, and methods of formation thereof
US8546915B2 (en) Integrated circuits having place-efficient capacitors and methods for fabricating the same
KR100806034B1 (en) Semiconductor device having metal-insulator-metal capacitor and fabrication method for the same
KR100480641B1 (en) Metal-Insulator-Metal capacitor having high capacitance, integrated circuit chip having the same and method for manufacturing the same
KR100572828B1 (en) Method of manufacturing semiconductor device with MIM capacitor
WO2011103735A1 (en) Fabricating method of copper interconnection structure with mim capacitor and structure fabricated thereby
US6825080B1 (en) Method for forming a MIM capacitor
US6822283B2 (en) Low temperature MIM capacitor for mixed-signal/RF applications
US10566414B2 (en) BEOL capacitor through airgap metallization
US6284619B1 (en) Integration scheme for multilevel metallization structures
EP3627576B1 (en) Capacitor and manufacturing method for same
TW465093B (en) Manufacturing method of vertical metal-insulator-metal capacitor
KR100387265B1 (en) Method of manufacturing a metal wiring and a capacitor in a semiconductor device
KR100816247B1 (en) Mim capacitor and the fabricating method thereof
JP2000208743A (en) Integrated circuit device provided with dual damascene capacitor and related method for manufacture
KR100965215B1 (en) Method of manufacturing Metal- Insulator-Metal capacitor of a semiconductor device
KR100364818B1 (en) method for manufacturing of semiconductor device
CN113517273B (en) Capacitor array structure, method for manufacturing the same and semiconductor memory device
TWI578346B (en) Capacitor structure and method of forming the same

Legal Events

Date Code Title Description
GD4A Issue of patent certificate for granted invention patent
MK4A Expiration of patent term of an invention patent