TW465035B - Manufacture method of extremely narrow bit line without sidewall spacer - Google Patents

Manufacture method of extremely narrow bit line without sidewall spacer Download PDF

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Publication number
TW465035B
TW465035B TW89118186A TW89118186A TW465035B TW 465035 B TW465035 B TW 465035B TW 89118186 A TW89118186 A TW 89118186A TW 89118186 A TW89118186 A TW 89118186A TW 465035 B TW465035 B TW 465035B
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Taiwan
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layer
bit line
gate
forming
making
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TW89118186A
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Chinese (zh)
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Hung-Huei Tzeng
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Vanguard Int Semiconduct Corp
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Abstract

This invention provides the manufacture method of extremely narrow bit line without sidewall spacer, which include the formation of gate structure on the substrate. The aforementioned gate structure consists of gate oxide layer, gate and the mask layer on top of the gate. Oxide is formed on the surface of gate using thermal oxidation process to eliminate the need of the formation of sidewall spacer. Then, source and drain are formed adjacent to the gate structure. The first oxide layer is patterned on the gate structure to expose the source. Subsequently, capacitor is formed on the abovementioned structure and is connected to the source. The second oxide layer is then formed and the drain is exposed by etching the second oxide layer, which create opening in the oxide layer. Finally, bit line contact is formed in the contact opening.

Description

465035 五、發明說明(1) 發明領域: 本發明與半導髅-, 準接觸窗之形成方法A件之製二有關,特別是-種自行對 隨機存取記憶體製程中須:作側壁間隙於動態 甲裊作極乍位兀線接觸之方法。 發明背景: 積體電 的密度 寸,可 尺寸的 的挑戰 後,造 於半導 角色也 越小, 態隨機 在電容 重大之 有顯著 種趨勢 電路的 路在製 記憶體 少而導 度不斷 自對準 來越難 ,由於 要維持 隨機存 &增加 小電子 。隨著 不斷出 元尺寸 性上的 以製程 差容忍 同之狀 元件之 荷健存 §己憶胞 路(1C)在 也已儼然 以增加半 縮小化後 。例如, 成了儲存 體晶圓上 益形重要 使得製程 存取έ己憶 尺度縮小 挑戰。通 技術上已 變成為一 導體積體 ’積體電 動態隨機 容量的減 的晶片密 。特別是 之挑戰越 體中發生 情形下仍 常,動態 的提昇, 。經由縮 整合密度 造過程中 (dram )單 致在可靠 提高’所 製程之誤 矩。而相 不斷提升 相當之電 取記憶體 電子元件 元件的尺 電子元件 現許多新 的縮小 缺失。基 所扮演之 度也越來 況也在動 積集度, 量亦是一 之陣列利 用埋式位元線(b u r i e d i 11 i n e)或非埋式位元線結構。以 非埋式位元線結構而言’一般必須蚀刻一垂直之深穿孔於 絕緣層中’直通到切換電晶體。而此非埋式位元線結構又 可以分為位元線下電容結構(capacitor_under~bit line 46 50 3 5 五'發明說明(2) ’ CUB)以及位元線上電容結構(capacit〇r-over — bitiine ;COB)兩種。 而先前技術製作自行對準接觸(self_aligI1 contact; SAC)為半導體製程中重要之一環,但是也同樣面臨到困 境°其主要步驟包含於半導體基板上形成場氧化區以定義 主動區域,接著沈積閘極氧化層以及複晶矽層於場氧化區 與基板上方’在此複晶矽層上方接著沈積二氧化矽層或氮 化石夕層。定義光阻蝕刻上述之閘極氧化層、複晶矽層與氮 化,層形成具有遮蓋層(cap layer)之閘極結構。上述之 遮蓋層(cap layer)是為防止後續沈積之膜層與閘極做電 性接觸而造成短路。下一步驟’沈積一層介電層後,利用 餘刻製程餘刻該介電層以形成側壁間隙於閘極結構之側壁 之上。元成側壁間隙之製作後進行源極、沒極之摻雜。在 上述結構之表面沈積一層介電層,一般為利用氧化矽,並 =省介電層之上定義一光阻圖案。以該光阻圖案做為罩 ’利用姓刻技術蝕刻上述之介電層以製作接觸窗,最後 除光阻,完成接觸窗之製作。一般,側壁間隙為利用氮 石夕作為材質,SAC触刻過程中時易造成側壁間隙之流 失’造成閘極之短路。 美國專利 United States Patent Νο·6,〇57, 187 發明 人J e η等人揭露一種應用於動態隨機存取記憶體中之位元 線接觸製程。題目為"DRAM structure with multiple465035 V. Description of the invention (1) Field of the invention: The present invention relates to the second method of the semi-conductive skeleton, the method of forming the quasi-contact window A, and in particular, the process of the self-access random access memory system must: Dynamic armor is used as a method for extremely sharp contact. Background of the Invention: After the density of integrated electricity and the challenge of size, the smaller the role of the semiconductor, the more random the state is, the larger the capacitance is. There is a significant tendency for the circuit. It will be more and more difficult due to the need to maintain random storage & increase small electrons. With the continuous development of the dimensional tolerance of the same components of the same process, the health of the same components § Ji Yi cell (1C) has also been reduced to increase by half. For example, the importance of becoming a shape on a storage wafer has made the process of accessing and recalling the scale down the challenge. Through technology, it has become a chip with a reduced volume and a random capacitance. In particular, the challenges that occur in the body are still common, dynamic improvement. By shrinking the density, the manufacturing process (dram) has been able to reliably increase the error of the process. While the phase continues to increase, the equivalent of electronic memory, electronic components, rulers, electronic components, and many new shrinkages are missing. The degree played by the base is also more and more dynamic, and the quantity is also an array using a buried bit line (b u r e d i 11 i n e) or a non-buried bit line structure. In the case of a non-buried bit line structure, generally, a vertical deep perforation must be etched into the insulating layer 'to go straight to the switching transistor. And this non-buried bit line structure can be further divided into the bit line capacitor structure (capacitor_under ~ bit line 46 50 3 5 5 'Invention Description (2)' CUB) and the bit line capacitor structure (capacitor-over — Bitiine; COB). In the prior art, making self-aligI1 contact (SAC) is an important part of the semiconductor process, but it also faces difficulties. The main steps include forming a field oxide region on the semiconductor substrate to define the active region, and then depositing the gate. An oxide layer and a polycrystalline silicon layer are above the field oxidation region and the substrate. Then, a silicon dioxide layer or a nitride nitride layer is deposited on the polycrystalline silicon layer. Definition The photoresist etches the above-mentioned gate oxide layer, polycrystalline silicon layer, and nitride to form a gate structure with a cap layer. The above cap layer is to prevent the subsequent deposited film layer from making electrical contact with the gate to cause a short circuit. In the next step ', after depositing a dielectric layer, the dielectric layer is etched by a etch process to form a sidewall gap over the sidewall of the gate structure. After fabrication of the Yuancheng sidewall gap, source and non-doping are performed. A dielectric layer is deposited on the surface of the above structure. Generally, a silicon oxide is used, and a photoresist pattern is defined on the dielectric layer. The photoresist pattern is used as a cover. The above-mentioned dielectric layer is etched using the last engraving technique to make a contact window. Finally, the photoresist is removed to complete the fabrication of the contact window. Generally, the side wall gap is made of nitrogen stone as the material. During the SAC etch process, it is easy to cause the loss of the side wall gap 'and cause the gate to short-circuit. United States Patent No. 6, 〇57, 187 The inventor J e η and others disclosed a bit line contact process applied to dynamic random access memory. Title: " DRAM structure with multiple

465035 五、發明說明(3) memory cells sharing the same bit-line contact and fabrication method thereof"。另外一先前技術為美國 專利 United States Patent No.5, 858,829,,題目為 "Method for fabricating dynamic random access memory (DRAM) cells with mi n i in u m active cell areas using side wall spacer bit lines11’ 其中亦提出利用 側壁間隙做為位元線之結構e再者,美國專利U n丨t e d States Patent No. 6, 0 8 3, 8 3 1提出一種製作接觸穿孔 (contact hole)之方法。此方法包含在電容極板之位置上 形成絕緣介電材質,然後在極板位置上方之絕 中蝕刻形成一開孔(open i ng)。然後沈積一膜層沿述 被鞋刻之介電層表面’之後利用非等向性蚀刻㈣上述之 膜層以利於製作側壁間隙於上述開孔之側壁之上。上述之 側壁間隙將有助於形成接觸穿孔n :Ϊ= 以雜。此外,傳統㈣ 寸程中,上述閘極側之側壁間隙寬度將限制 發明目的及概述: 種製作具有位元線接觸之 本發明之主要目的為提供一 積體電路。465035 V. Description of the invention (3) memory cells sharing the same bit-line contact and fabrication method thereof ". Another previous technology is United States Patent No. 5, 858,829, entitled " Method for fabricating dynamic random access memory (DRAM) cells with mi ni in um active cell areas using side wall spacer bit lines11 'which is also proposed The sidewall gap is used as the structure of the bit line. Furthermore, U.S. Patent States No. 6, 0 8 3, 8 31 proposes a method for making a contact hole. This method includes forming an insulating dielectric material at the position of the capacitor plate, and then etching to form an opening (open i ng) in the insulation above the position of the plate. Then, a film layer is deposited along the surface of the dielectric layer engraved by the shoe, and then the film layer is anisotropically etched to facilitate the fabrication of the side wall gap on the side wall of the opening. The above-mentioned side wall gap will help to form the contact hole n: Ϊ = impurity. In addition, in the traditional 寸 -inch range, the width of the side wall gap on the gate side will be limited. Purpose and summary of the invention: The main purpose of the present invention is to provide an integrated circuit with bit line contact.

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五、發明說明(4) 本發明之再一目的為提供一種無須製作側壁間隙於動 態隨機存取記憶體製程中製作極窄位元線接觸之方法 本發明揭露無須製作側壁間隙之製作位元線接觸方 法,包含:形成閘極氧化層於基板之上、形成複晶矽於閘 極氧化層之上以及形成氮化矽層於複晶矽層之上。其中上 述之氮化矽層厚度約為5 0 0 - 2 0 0 0埃之間。之後,蝕刻氮化 矽層、複晶矽層以及閘極化層以形成閘極結構。以熱氧化 法形成氧化物環繞於閘極之表面,用以省卻線前製作側壁 間隙步驟。之後形成汲極與源極鄰接閘極結構。然後,圖 案化第一氧化矽層於閘極結構之上,暴露出源極,氧化矽 層厚度約為1 0 0 0 - 2 0 0 0埃之間。接著電容形成於上述結構 之上且與源極連接。第二氧化矽層之後形成,氧化矽層厚 度約為3 0 0 0 - 1 0 0 0 0埃之間。然後蝕刻上述之氧化矽層以暴 露出汲極,因而形成接觸穿孔於氧化矽層之中。最後形成 位元線接觸於接觸穿孔之中。 發明詳細說明: 如圖一所示,以一晶面為< 1 0 0>之單晶半導體為基 板,如P型或N型單晶之矽基板2 ^接著,製作做為元件間 隔離之絕緣區域4,通常可以使用場氧化製作技術或是溝 渠式隔離技術。以一實施例而言,利用傳統之L 0 C 0 S製程 製作一厚的場氧化區4作為主動區域之絕緣物,此場氧化V. Description of the invention (4) Another object of the present invention is to provide a method for making extremely narrow bit line contacts without making side wall gaps in a dynamic random access memory system. The present invention discloses making bit lines without making side wall gaps. The contact method includes forming a gate oxide layer on the substrate, forming a polycrystalline silicon layer on the gate oxide layer, and forming a silicon nitride layer on the polycrystalline silicon layer. The thickness of the above-mentioned silicon nitride layer is about 500-200 Angstroms. After that, the silicon nitride layer, the polycrystalline silicon layer, and the gate polarization layer are etched to form a gate structure. An oxide is formed on the surface of the gate electrode by thermal oxidation to avoid the step of making a sidewall gap before the wire. A drain and source gate structure is formed next. Then, the first silicon oxide layer is patterned on the gate structure to expose the source electrode, and the thickness of the silicon oxide layer is between about 100 and 2000 angstroms. A capacitor is then formed on the above structure and connected to the source. A second silicon oxide layer is formed later, and the thickness of the silicon oxide layer is between about 300 and 100 angstroms. Then, the silicon oxide layer is etched to expose the drain electrode, thereby forming a contact hole in the silicon oxide layer. Finally, the bit lines are formed in contact with the contact holes. Detailed description of the invention: As shown in FIG. 1, a single crystal semiconductor with a crystal plane of < 1 0 0 > is used as a substrate, such as a P-type or N-type single-crystal silicon substrate 2 ^ Next, it is fabricated as an isolation device The insulating region 4 can generally use field oxidation fabrication technology or trench isolation technology. According to an embodiment, a conventional L 0 C 0 S process is used to fabricate a thick field oxide region 4 as an insulator of the active region, and the field oxide is oxidized.

第7頁 λ r η ^ 5 _ 五、發明說明(5) ---—- 區域之形成是在有氧蒸氣之環境下熱氧化,溫产在 85Η贼間產生二氧切,厚度為4_ —=埃在 接Page 7 λ r η ^ 5 _ V. Description of the invention (5) ------ The area is formed by thermal oxidation in an aerobic vapor environment. Warm production produces a dioxygen cut between 85 thieves and has a thickness of 4_ — = Egypt is picking up

著’在基板2之上形迠一 ρ』托a Q 法 之 遮 嗖赭禎曰矽屏fm葚3極氧化層6 ’再利用化學氣相 沈檟複日日石7層8覆蓋閘極氮几a > 間。於上述之複晶二8= ’厚度為1000至2_埃 甚厝1 〇,u ^,曰8表以化學氣相法沈積 遮蓋層,f蓋於複晶…之;“匕氮“夕材質做為上述 之間。接著n = iV;’^度範圍為5酿20 00埃 ^ ^ . 阻圖案於氮化矽層1 0之上,以蝕刻 ΐ 1G'複晶梦層8以及閉極氧化層 搞壯:备木#蝕刻去除未被光阻覆蓋之區域,形成 閉極結構,氮化石夕層10做為閘極結構之遮蓋層,主要作用 為,止複晶矽層8與後續之導電膜層之間形成短路現象。 均等功能之材質也可以取代氮化矽做為遮蓋層。上述之氮 化石夕層1 0可以利用化學氣相沈積法开)成例如低壓化學氣 相沈積法,一般可以於反應室中利用S i Η 4、 NH 3、N 2、N 2〇 或其他適合之反應物,於溫度攝氏3〇〇至8 〇 〇度之下形成氮 化石夕層。由圖中可知,製作閘極之蝕刻過程中,也同時製 作字語線於絕緣結構4之上。 接著,一氧化物1 2形成於複晶矽閘極8之表面,如圖二所 示。厚度約為5 0 - 2 0 0埃。此氧化物1 2之功用如同遮蓋層1 〇 之作用疋做為触刻的阻障(b a r r i e r),為防止複晶石夕層8與 後續之導電結構形成短路現象。以一較佳實施例而言,可With 'formed a ρ on the substrate 2', the cover of the Q method is called the silicon screen fm 葚 3 pole oxide layer 6 'recycling chemical vapor deposition daylight stone 7 layer 8 covering the gate nitrogen a > In the above-mentioned polycrystalline silicon 8 = 'thickness is 1000 to 2 _ Angstrom 1 〇, u ^, said Table 8 is a chemical vapor deposition covering layer, f is covered with polycrystalline silicon ... of "Dagger nitrogen" material As between the above. Then n = iV; '^ degree range is 5 to 20 00 angstroms ^ ^. The resist pattern is on the silicon nitride layer 10 to etch ΐ 1G' polycrystalline dream layer 8 and closed electrode oxide layer to strengthen: prepare wood #Etching removes areas not covered by photoresist to form a closed electrode structure. The nitride layer 10 is used as a cover layer for the gate structure. Its main function is to prevent a short circuit between the polycrystalline silicon layer 8 and subsequent conductive film phenomenon. Equal function materials can also replace silicon nitride as a cover layer. The above nitrided layer 10 can be formed by chemical vapor deposition method, for example, low pressure chemical vapor deposition method. Generally, Si Η 4, NH 3, N 2, N 2 0 or other suitable materials can be used in the reaction chamber. The reactant forms a nitrided layer at a temperature of 300 to 800 degrees Celsius. As can be seen from the figure, during the etching process of making the gate electrode, the word line is also formed on the insulating structure 4 at the same time. Next, an oxide 12 is formed on the surface of the polycrystalline silicon gate electrode 8 as shown in FIG. The thickness is about 5 0-2 0 0 Angstroms. The function of this oxide 12 is similar to that of the covering layer 10, which acts as a barrier (b a r r e e r) for the etching, in order to prevent the polycrystalline stone layer 8 from forming a short circuit with the subsequent conductive structure. In a preferred embodiment,

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Claims (1)

系是吾 % 正 __ 六、申請專利範圍 1一種無須製作側壁間隙之製作位元線接觸之方法,該方 法包含: 形成間極氧化層於基板之上; 形成複晶矽於該閘極氧化層之上; 形成第一介電層於該複晶矽層之上做為遮蓋層; 蝕刻該第一介電層、該複晶矽層以及該閘極化層以形成閘 極結構*該閘極結構包含閘極氧化層、閘極以及遮蓋層; 以熱氧化法形成氧化物環繞於該閘極之表面; 形成汲極與源極鄰接該閘極結構; 圖案化一第二介電層於該閘極結構之上,暴露出該源極; 形成第三介電層於上述之結果表面; 蝕刻上述之第三介電層以暴露出該汲極,因而形成接觸穿 孔於該第三介電層之中;以及 形成位元線接觸於該接觸穿孔之中。 2如申請專利範圍第1項之無須製作側壁間隙之製作位元線 接觸方法,其中在圖案化該第二介電層之後,更包含形成 一電容。 3如申請專利範圍第1項之無須製作側壁間隙之製作位元線 接觸方法,其中上述之第一介電層包含氮化矽。 4如申請專利範圍第1項之無須製作側壁間隙之製作位元線 接觸方法,其中上述之第一介電層厚度約為500-200 0埃之This is my% positive __ VI. Patent application scope 1 A method for making bit line contact without making sidewall gap, the method includes: forming an interlayer oxide layer on a substrate; forming polycrystalline silicon on the gate oxide Layer; forming a first dielectric layer on the polycrystalline silicon layer as a cover layer; etching the first dielectric layer, the polycrystalline silicon layer, and the gate polarization layer to form a gate structure * the gate The electrode structure includes a gate oxide layer, a gate electrode, and a cover layer; an oxide is formed around the surface of the gate electrode by a thermal oxidation method; a drain electrode and a source electrode are formed adjacent to the gate electrode structure; and a second dielectric layer is patterned on Above the gate structure, the source electrode is exposed; a third dielectric layer is formed on the above-mentioned result surface; the third dielectric layer is etched to expose the drain electrode, and thus a contact hole is formed in the third dielectric Layers; and forming bit lines into contact with the contact holes. 2. The method of making a bit line without the need to make a side wall gap according to the first patent application scope, wherein after patterning the second dielectric layer, it further comprises forming a capacitor. 3. The method for making a bit line contact without the need to make a side wall gap according to item 1 of the scope of the patent application, wherein the above-mentioned first dielectric layer includes silicon nitride. 4 If the method of making a bit line without making a side wall gap is required in the first scope of the patent application, wherein the thickness of the first dielectric layer is about 500-200 Angstroms. 第12頁 4. 6 5 0 b 六、申請專利範圍 間。 5如申請專利範圍第1項之無須製作側壁間隙之製作位元線 接觸方法,其中上述之第二介電層包含氧化矽。 6如申請專利範圍第1項之無須製作側壁間隙之製作位元線 接觸方法,其中上述之第二介電層厚度約為1 0 0 0 - 2 0 0 0埃 之間。 7如申請專利範圍第1項之無須製作側壁間隙之製作位元線 接觸方法,其中上述之第三介電層包含氧化矽。 8如申請專利範圍第1項之無須製作側壁間隙之製作位元線 接觸方法,其中上述之第三介電層厚度約為3 0 0 0 - 1 0 0 0 0埃 之間。 9如申請專利範圍第1項之無須製作側壁間隙之製作位元線 接觸方法,其中在形成該第三介電層之後,更包含平坦化 該第三介電層。 1 0—種無須製作側壁間隙之製作位元線接觸之方法,該方 法包含: 形成閘極氧化層於基板之上; 形成複晶矽於該閘極氧化層之上;Page 12 4. 6 5 0 b 6. Between patent applications. 5. The method for making a bit line without the need to make a side wall gap according to item 1 of the scope of the patent application, wherein the above-mentioned second dielectric layer includes silicon oxide. 6. The method of making a bit line contact without the need to make a side wall gap according to item 1 of the scope of the patent application, wherein the thickness of the second dielectric layer is about 100-200 Angstroms. 7. The method for making a bit line without the need to make a side wall gap according to item 1 of the scope of the patent application, wherein the third dielectric layer described above includes silicon oxide. 8. The method for making a bit line contact without the need to make a side wall gap according to item 1 of the scope of the patent application, wherein the thickness of the third dielectric layer is about 300-1000 Angstroms. 9. The method for making a bit line without the need to make a side wall gap according to item 1 of the scope of patent application, wherein after forming the third dielectric layer, the method further includes planarizing the third dielectric layer. 10—A method for making bit line contact without making a sidewall gap, the method includes: forming a gate oxide layer on a substrate; forming polycrystalline silicon on the gate oxide layer; 第13頁 4 6 5 L· — 六、申請專利範圍 形成氮化矽層於該複晶矽層之上做為遮蓋層; 蝕刻該氮化矽層、該複晶矽層以及該閘極化層以形成閘極 結構,該閘極結構包含閘極氧化層、閘極以及遮蓋層; 以熱氧化法形成氧化物環繞於該閘極之表面; 形成汲極與源極鄰接該閘極結構; 圖案化一第一氧化矽層於該閘極結構之上,暴露出該源 極; 形成電容於上述結構之上且與該源極連接; 形成第二氧化矽層於上述之結果表面; 平坦化該第二氧化矽層; 蝕刻上述之第二氧化矽層以暴露出該汲極,因而形成接觸 穿孔於該第二氧化矽層之中;以及 形成位元線接觸於該接觸穿孔之中。 1 1如申請專利範圍第1 0項之無須製作側壁間隙之製作位元 線接觸方法,其中上述之氮化矽層厚度約為5 0 0 - 2 0 0 0埃之 間。 1 2如申請專利範圍第1 0項之無須製作側壁間隙之製作位元 線接觸方法,其中上述之第一氧化矽層厚度約為 1 0 0 0 - 2 0 0 0埃之間。 1 3如申請專利範圍第1 0項之無須製作側壁間隙之製作位元 線接觸方法,其中上述之第二氧化矽層厚度約為Page 13 4 6 5 L ·-VI. Patent application scope: forming a silicon nitride layer on the polycrystalline silicon layer as a cover layer; etching the silicon nitride layer, the polycrystalline silicon layer and the gate polarization layer To form a gate structure, the gate structure including a gate oxide layer, a gate electrode, and a cover layer; forming an oxide to surround the gate electrode surface by a thermal oxidation method; forming a drain electrode and a source electrode adjacent to the gate structure; Forming a first silicon oxide layer on the gate structure to expose the source; forming a capacitor on the above structure and connecting to the source; forming a second silicon oxide layer on the above-mentioned resulting surface; planarizing the A second silicon oxide layer; etching the second silicon oxide layer to expose the drain electrode, thereby forming a contact hole in the second silicon oxide layer; and forming a bit line in contact with the contact hole. 11 According to the method of manufacturing bit line contact which does not need to make a side wall gap according to item 10 of the scope of the patent application, the thickness of the above silicon nitride layer is between about 500 and 2000 angstroms. 1 2 According to the method of manufacturing bit line contact without the need to make a side wall gap in item 10 of the scope of patent application, the thickness of the first silicon oxide layer is about 100-200 Angstroms. 1 3 According to the method of making a bit line contact without making a side wall gap in item 10 of the scope of patent application, wherein the thickness of the second silicon oxide layer is about 第14頁 46503dPage 14 46503d 第15頁Page 15
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