TW464508B - Composition for oil-in-water type cosmetic - Google Patents

Abstract

A composition comprises water, wax ester and at least one which is the other component used in cosmetic, which contains C18-34 aliphatic acid-C18-34 higher alcohol ester and amphoteric surfactant, further contains C18-34 higher aliphatic acid. This invention provides an intermediate composition for cosmetic having an excellent in feeling to skin and physical-chemical properties in keeping stably, which is especially effectively used in foundation, lip-stick, eye-shadow etc., and the above-mentioned final product.

Description

46 45 0 8 A7 B7 V. Description of the invention (,) a '...— ------- Ϊ

This invention relates to oil-in-water cosmetic compositions, and more particularly to oil-in-water solid compositions suitable for foundations, eyeshadows, lipsticks, and the like. Back long branch is known as solid cosmetic type. Generally, solid oily type with solidified oil with wax, solid ingot type made by pressing powder or a mixture of powder and oil agent, specific oily coagulant and hydrophobized powder The solid water-in-oil type dehydration formula composed of water, water, and lipophilic surfactants is divided according to the purpose or method of use of the cosmetics, respectively. Among them, the solid oil-in-water emulsification type has good stability and water resistance, and has a feeling of use after wetting. For example, it is known to use a silicone varnish with solid tincture and water, and use polyalkylene oxide to modify organic polysiloxane. Ethane plus kappa emulsifier (Japanese Patent Laid-Open No. 64-79104). However, this type of oil-in-water emulsion type, with an external phase mixed with oil or oil-based coagulant, is inferior to oil-in-water rolling fluids or creams in terms of "softness", "dryness" and "non-stickiness". In addition, examples of the oil-in-water emulsified coagulate in which a higher alcohol or a clay mineral is blended in a large amount are known. However, because of this oil-in-water emulsification type, the older child mixes the aforementioned ingredients, which loses the characteristics of "soft moisturizing," "dry," and "non-sticky" that oil-based emulsions or creams have. Other examples of solid water-in-oil type emulsification are those in which external phase water is coagulated by fatty acid soap (Japanese Patent Application Laid-Open No. 5-178723, Japanese Patent Application Laid-Open No. 7-17828). The former has a lot of soap. * The pH is high, and it has problems with skin irritation and safety. The latter does not have sufficient hardness, and it is not easy to use a sponge. This is the problem. -3- (Please read the precautions on the back before filling this page) The dimensions of this paper are applicable to the Chinese cabinet (CNS) A4, see the grid (210X 297 cm) zj. 5 0 O A 7 '— ‘

B7 ft V. Description of the invention (>) _ You (please read the notes on the back before filling this page) The emulsification technology developed in recent years, it is known to combine the amphoteric surfactant and high-fat fatty acid to form a water-insoluble compound This compound forms an emulsification interface film to ensure the stability of emulsification (Japanese Patent No. 3-166367). There is also a solid emulsification method using this technology, but it is difficult to obtain a "soft and smooth" and "not dry" Sticky. On the other hand, general lotions or creams are from 0¾ to 50t: Fanpu has fluidity, so when it is in the form of a container such as a bottle or tube, it is slightly lacking in portability or ease of use, especially in the case of foundations. Due to this background, there has not been a solid solid composition with good portability or ease of use, and it has all the "soft", "dry" and "non-sticky" feels of emulsions or creams. Therefore, the object of the present invention is to provide a composition that shows the "soft" f dry, "non-sticky" feel of an oil-in-water emulsion or cream, and at the same time can be used as a portability or easy to use. Solid cosmetics are beneficial to use. Mingxi Xi was reported that Yin Xian, the incumbent consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs and the present inventors, etc., in order to achieve the above-mentioned purpose, devoted themselves to the research and development of the use of specific phosphonium esters and amphoteric surfactants, or to combine phospholipids with these two ingredients It can obtain a stable and stable oil-in-water emulsion composition with excellent touch. The composition thus obtained can exhibit the aforementioned excellent physical properties without using, for example, a water-soluble coagulant or a water-soluble adhesive contained in a conventional water-in-oil type cosmetic. Therefore, according to the present invention, a water-in-oil composition according to the present invention, consisting of water, methyl ester, and other cosmetic formula ingredients, is provided. A4C grid U10 X 297 public 嫠) ί-ζ- ------- ^ Α7 Β7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Ⅴ 5. Invention Description (々), the total weight of the M composition is based on the standard, including: U) — The phosphonium ester on species K from 0.1 to 10.0% by weight, and its constituents have C18-C34 higher fatty acid-derived moieties, and ClS-C4i higher fatty alcohol-derived moieties, and (B) — amphoteric on species M The surfactant is 0.5 to 10.0% by weight. Another cosmetic inhibitor is provided. * In addition to the above (A) component and (B) component, it also contains a certain amount of (C) component, which is more than one C6-C34 higher fatty acid. In addition, 遨 can provide solid cosmetics, based on the above (A) and (B) ingredients, or U), (B) and (C) ingredients, and other ingredients used in this technology model, selected from silicon light One or more types of oil, cool oil (or semi-solid stilbene ester), stilbene alcohols, water-soluble polymers, ethylene glycol or glycerol fatty acids, titanium oxide, and spherical powder group, K means the purpose.最佳 Best specific examples of the axillary invention The "solid" or "solid J" as referred to in the present invention refers to its composition or ingredient at a temperature of 50 or less, which does not take into account the fluidity, and is usually used even under misuse and storage conditions. There is no obvious change in the state below. Specifically, it refers to the required amount of components or ingredients in a certain shape, while the rest can maintain the hardness of the original shape. Furthermore, the hardness is specifically at 37T. , Using this technical range _ When the commonly used hardness tester measures t, the hardness (γ) shown in the following formula is above 7 ~ 5-This paper size is generally Chinese National Standard (CNS) Λ4 specification (210X297 mm) (Please read the back first Please pay attention to this page and fill in this page) Order 46 45 0 8 A7 Printed by the Consumers Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs B7 V. Invention Description u) GXL τ (Hardness) =-(dyn / cm 2) 1 xa where G To measure the stress (gr) x 980dyn L is the thickness of the sample (Π1Β> 1 is the compression distance (mn〇a is the cross-sectional area of the needle (cm 2) (Urdu conditions) Load: 2kg Needle diameter: 5-6 Φ Pin insertion speed: 2cm / ain Pin insertion distance: 1 am Degree: 37P For the purpose of the present invention, the composition of the present invention should preferably have proper fluidity at a temperature above 50T, so that its constituent components can be uniformly mild or emulsified. In the description of the present case, the main composition of the present invention For the concept of foundation, the description is added, but the manufacturer's hardness is used as an index, and other combinations can be selected as needed. Therefore, the present invention limits the lower limit and adds the description, but it is not limited to this. The ethyl ester used in the present invention is at room temperature. It is a carboxylic acid derived from -34 higher (or long fluorene) fatty acids, and Clfi higher (or long fluorene) fatty alcohols. The fatty groups of these fatty acids and fatty alcohols can be straight or branched. Both non-saturated and unsaturated aliphatic groups can be used in practical -6-(Please read the notes on the back before filling out this page. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm)

A7 B7 46 45 0 8 The seal of Xiaoxian Cooperative of Employees of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention) 1 1 It is better to use saturated aliphatic bases at the point of view. 1 1 C ΐ 3-3- i higher fatty acids constituting the m ester. Specific examples include C 1S octadecane 1 1 acid (IIB, fatty acid) 1 C20 eicosanoic acid (arachidic acid), C 22 dodecanedioic acid Please i first 1 (Small ¥ acid) C24 Docosaic acid, C26 Hexadecanoic acid (Phenylic acid) > Read II C2B Octacosanoic acid (Yancoic acid), C BO Di + alkanoic acid (bee Flower acid), C 3; 1 back 1 I 1 32 m acid, C34 tetracosanoic acid and other natural waxes choose 4 fi f itself or pay attention to 1 thing · 1 includes the ester form 〇 commonly used in the above brackets Name C Item 1 The above-mentioned even-numbered fatty acids »are generally easy to obtain, but c L 39 Nineteen acids are filled in < Odd-numbered fatty acids such as this I and C 33 triclosanic acid, as long as they are available, do not exclude 1 I except Based on the aforementioned carbon number of fatty acids. In addition, the aliphatic group may be 1 1 m »For example, the fatty acid component of lanolin contains at least -38 kinds of C 38-32 iso fatty acids (even 1 carbon). And C 19-33 anteiso fatty acids, also Included in the fatty acids of the 1 π ester constituting m esters of the present invention. Furthermore, the fatty acids constituting the wax ester include those having an unsaturated carbon number of 1 1 and a fatty acid obtained by hydrogenation, or a lower alkyl group corresponding to the aforementioned hydroxy fatty acid 1 I of a fatty acid, such as methyl 'ethyl. The esters of propyl group 0 1 f Among them, the more general ones are, for example, C2 which is the acetic acid ester of rapeseed mash, 2 gluten 1 acid, which is the melamine C 24 docosauronic acid (Brazil Brown m 1 (I m mostly contains this acid), C 26 acetic acid f 橼 1 which constitutes the lanolin ester of lanolin, Cm browning acid which forms the m-ester of mastic, which is a brewing product of f. C 30 S 1 melamine and 〇 12: dodecanedioic acid, C 34 JHT-, tetradecyl I alkanoic acid constituting the carbamate of the gum, all are fatty acids constituting the gate ester of the present invention 0 1 1 Aspect t constitutes a cool C 1 S -44 higher fatty alcohol, which is equivalent to 1 1 of the aforementioned fatty acids. Generally there are, for example, C 10 stearin, C 20 eicosanol 1 1 1 -7- 1 1 1 .Paper size applies Home standard rate {CNS) Eight materials see the grid (2 [〇297297 mm) 464508 A7 Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, B7, 5. Description of the invention (), C22 behenyl alcohol, C24 di + Tetraalkanol, C26 hexacosanol, C28 octacosanol, C30 tricosane fermentation, C32 docosane fermentation, C34 tetracosane fermentation, etc. Ethanol has, for example, U-methyl + Λ-alkanease, 18-methyl eicosanol, 18-methyl eicosanease, 20-methyl eicosanease, 20-methyl eicosanease , 22-methylcosacosanease, 24-methylpentacosanease, etc., and contains what is found in wool wax. As long as the fermented carbon number is mentioned above, various kinds of articles obtained through chemical synthesis are also included in the above-mentioned advanced fat fermentation. Therefore, the roe used in the present invention contains any combination of a Cos 34 higher fatty acid and a Cis higher fat fermentation, and this roe can also be a mixture of two kinds of M. Generally speaking, this kind of pupa is convenient to use the higher fatty acids from natural pupa ingredients, such as Candelilla, Brazilian palm magpie, jojoba oil, wool wax, coriander pupa, rice pupa, etc. Constituents of high-grade fats and anti-fermentation. The 来自 _ which is derived from the fatty acid part and the fermented part can be an ester synthesized from individual fatty acids and alcohols, but it can also be obtained by the aforementioned wax extraction and the like. Specific esters are, for example, C20 fatty acids-C20 enzymes from Candida canadensis, Brazilian palm tree, jojoba oil, or lucky media, C20 fatty acids-C30 alcohol, C24 cytosolic acid-C28 alcohol, C24 Fatty acid-C 30 enzyme, C 24 fatty acid-C 32 alcohol, C26 fatty acid-C30 enzyme, C26 fatty acid-C32 enzyme, C28 fatty acid-C24 alcohol, C28 fatty acid-C2S enzyme, C28 fatty acid_C30 enzyme, Ca. Fatty acid-C2B enzyme, C3oSi fatty acid-Cao alcohol, CaoBS fatty acid-Cg2 alcohol, C32 fatty acid-Cao alcohol, C32 fatty acid_C32 enzyme, C34 fatty acid-C30 (Please read the notes on the back before filling (This page) This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 464508 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (7) Fermentation, C34 fatty acid-C 32 alcohol, etc. combination. Of course, the aforementioned combination II can be either chemically synthesized or extracted from natural rhenium. A commercially available product containing the wax of the present invention obtained by chemical synthesis includes, for example, Crodaaol ODL (trade name • Product of Croda Japan Co., Ltd.), which is a reaction product of lanolin fatty acid and 2-octyldodecanol. Among the aforementioned natural waxes, for the purpose of the present invention, as long as its composition does not have a bad influence, the M primary beam can be used together with the hydrazone component of the present invention. Compositions that do not affect rhenium include, for example, the Brazilian palm «butterfly, which contains 畺 畺, and the composition separates during emulsification, and tends to be difficult to solidify. Therefore, attention must be paid to its use. As the amphoteric surfactant which can be used in the present invention, any amphoteric surfactant which is generally used in cosmetic-based systems can be used. Specific examples include the glycosamino sugar beet sickle-type amphoteric surfactant represented by the following formula, which is equivalent to commercially available Sanyo Chemical Co., Ltd. > 2000, manufactured by Nippon Oil Co., Ltd.}. 0 (CH2) yCH3II 1 + Ri-C-NH (CH2) xN -ch2ch2ch2so3 'I (CH2) yCH3 Amidosulfobetaine-type amphoteric surfactant (equivalent to commercially available Ronza Company Π: / Bark > -CS. 5 = 5 y -child / two divisions 5 5 Ί y CSS etc .: (CH2) yCH3 l + _ R2 —N —CH2COOI (CHz) yCH3 (Please read the precautions on the back before (Fill in this page) This paper size applies Chinese National Standard (CNS) A4 specification (2! 0X297 mm) £ 4 4 5 Q 8 A7 B7 V. Description of the invention (2) Betaine amphoteric surfactant (equivalent to Available on the market from Japan Oil > BL, Henkel Co., Ltd. > 0-30 etc .: (Read the precautions on the back before filling this page) (CH2) vCH3 1 +

Ri —N — (CH2) xS03 (CH2) yCH3 Sulfobetaine-type amphoteric surfactants (equivalent to D > tf 彳 V12CS, etc., manufactured by the company):

0 (CH2) Z—〇H

II I

R, -C-NHCH2CH2N- (CH2) zCOO and an oxazoline-type amphoteric interfacial active compound represented by the following formula (equivalent to commercially available Toho Chemical Co., Ltd., made from Japan Oil: Fy> GLM, etc.). The composition for oil-in-water cosmetics of the present invention is based on the total weight thereof, and generally contains 0.1 to 10.0% by weight of the foregoing, preferably 0.1 to 5.0% by weight, and 0.5 to 10.0% by weight of the amphoteric surfactant, M0. 5 ~ 1.5% printed by the male workers' consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. On the other hand, the fluorenyl ester may contain a corresponding hydroxymethyl ester, occupying 40% by weight or less of the total fluorene. These amidines and amphoteric surfactants may also be a mixture of two kinds of M, respectively. When the content of fluorene ester in the composition of the present invention is less than 0.1% by weight, the vitamin M is solidified. On the other hand, when it exceeds 10% by weight, the "softness J" of the final product decreases, and there is a tendency to "tack". When the content of the amphoteric surfactant composition is less than 0.5% by weight, it is difficult to emulsify. On the contrary, the paper size applies the Chinese national standard (CNS} A4 specification (210 X 297 mm) 6. ^ 0 8 Explanation (When 9 exceeds 10.0% by weight, there may be problems with the completeness of the final product. 0 (Please read the precautions on the back before filling out this page) The composition of the present invention contains another major component, Ce-34 higher fatty acid. The effect of using these fatty acids is to generally improve the stability of the cosmetic composition of the present invention in a solid state. Specific examples of such fatty acids include C6 caproic acid in addition to the high-fat fatty acids exemplified as the constituents of the aforementioned ethyl esters. , Ce octanoic acid, or 2-ethylhexanoic acid, C10 capric acid, Ci2 dodecanoic acid (lauric acid), c14 tetradecanoic acid, c16 hexadecanoic acid (palmitic acid), but do not rule out an increase of one each Odd number of carbon fatty acids. When using more county-linked fatty acids, corresponding hydroxy fatty acids, such as 12-hydroxystearic acid, can be used. Therefore, the fatty acids referred to in the present invention include hydroxy fatty acids. Water in the present invention Based on the total weight of the cosmetic composition, it generally contains 0.1 to 10.0% by weight of higher fatty acids, preferably K0.1 to 2.0% by weight. These higher fatty acids may be a mixture of 2 μM. Generally, the high鈒 When the fatty acid content is less than 0.1% by weight, the emulsification stability will decrease. Conversely, when it exceeds 10.0% by weight, the possibility of problems in the stability of the final product will increase. When the above-mentioned high fat fat and acid are contained, the molar ratio of the higher fatty acid / amphoteric surfactant is preferably 1:15 to 1: 0.8. At 1:15 K, emulsification is difficult, and when it exceeds 1: 0.8, The oil-in-water emulsified composition cannot be formed. The composition of the present invention may contain one of the ingredients mentioned later mixed with other cosmetics. 11 This paper is in accordance with the Chinese National Standard (CNS) A4 condition (210 × 297 mm) 6 4 45 0 8 r _ ψγ · ψ {^ \ λι __Λ- ”B 7 V. Description of the invention (β) (Please read the note on the back before filling this page) For example, in order to maintain the stability of Gu Zhao state, improve the feeling of use Role, available days The higher (long-chain) hydrocarbons contained in the wax are equivalent in physical properties. Usually, the melting point is above 50C. Specific examples include pentacosane, heptadecane, 31, dodecane, dodecane, The honey marriage of squalene, Brazil palm wax, candelilla tincture, and other animal and vegetable oil derivatives are worthy of hydrogenation, such as squalane's hydrogenation squalane, etc. The physical properties of the composition of the present invention have no adverse effects, and the amount of the wax ester used can be added, for example, it can be used more than twice the weight. Therefore, the composition of the present invention may be suitable for use of candelilla wax. Furthermore, in The finished product for cosmetics according to the present invention can be used for specific purposes, such as increasing the hardness of the final molded product, preventing cracks, improving the prevention of water volatilization, or specific effects during use, such as UV resistance, skin absorption, and pore shielding properties. Modifications such as mosquito road finishing can contain more than one ingredient. Specific examples of the printing of consumer cooperatives by employees of the Central Government Bureau of the Ministry of Economic Affairs include silicone oil, cool oil (semi-solid ester), higher alcohols, water-soluble polymers, ethylene glycol or glycerol fatty acid esters, titanium oxide and Spherical powder. Specific examples of the silicone oil include trimethylsiloxysilicic acid-decamethylcyclopentasiloxane, dimethylpolysiloxane and the like. This ingredient can be added to solid cosmetics alone or in combination. It is usually more expensive, and generally contains 0.1 to 40% by weight. The compounding method can be added to the oil phase during preparation (example). The addition of these ingredients has a rib to enhance the hardness of solid cosmetics. 0 _ 1 2-This paper is applicable to the standard of the Chinese standard (CNS), and the standard is (2! 0 × 297 mm). A7 B7 6 4 5 0 8 V. Description of the Invention (,,) (Please read the notes on the back before filling out this page) Specific examples of ester oils (semi-solid wax esters) can have C8 -24 saturated or unsaturated higher fatty acid derivatives and C 14-24 esters of saturated or unsaturated homoalcohol-derived moieties are used as ester moieties. The fatty acid constituting the fat portion includes the aforementioned saturated fatty acid having a corresponding carbon number or the corresponding unsaturated fatty acid, and the alcohol portion also includes a straight or branched chain, a saturated or unsaturated long or short composition having a corresponding carbon number. Of alcohol. Any fatty acid ester composed of these fatty acid portions and alcohol portions can be used. The amount used is based on the total weight of the solid cosmetic, generally 0.01 to 3.0% by weight. The compounding method is usually added to the oil phase during preparation. The addition of these ingredients helps prevent cracking of solid cosmetics. Specific examples of the higher alcohol include C16-22 saturated fatty alcohols or saturated fatty ether-fatty alcohols. More specifically, there are C16 cetyl fermenter, Cis stearyl alcohol, C22 mountain alcohol, Cis-0-C3 semideep alcohol, and the like. The method of addition is usually to add and dissolve in the oil phase under heating. The amount of the solid cosmetic used is based on the total weight of the solid cosmetic, and is generally 0,005 to 2.0% by weight. These ingredients can be used alone or as a mixture. They are often ribbed to prevent the water from evaporating from the cosmetics. Specific examples of water-soluble plutonium molecules printed by the staff of the Central Standards Bureau of the Ministry of Economic Affairs, including hydroxyethyl cellulose, hyaluronic acid, high-polymer polyethylene glycol, xanthan gum, poly (meth) acrylic acid, and methyl cellulose , Alkali alcohols, such as sodium salt, potassium salt, etc., of polyvinyl alcohol, dextran sulfuric acid, dextran sulfuric acid, polyvinylyangrolidine, acacia gum, and osteoporosis. One or two or more of them are generally based on the total weight of the solid cosmetic product, and contain 0.001 to 3.0% by weight, though they are ribbed to prevent the water from volatilizing from the solid cosmetic product. The mixing method is usually to apply the Chinese National Standard (CNS) Λ4 specification (2 丨 0X 297 male f) 464503 A7 at the scale of the cosmetics paper, and print the B7 by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Add to water phase. Specific examples of the fatty acid esters of acetic acid or glycerol include the aforementioned glycosides of Cis-e saturated fatty acid, or the triglycerol ft of Cjs-30 saturated fatty acid. Especially K is better to use the former, and its use amount is based on the total weight of the solid cosmetics, and it can be 0.001 to 5% by weight, and it can replace a part of the aforementioned wax ester, as the case may be. The mixing method is to add it to the formazan oil phase and heat it to about 801C to dissolve it. The addition of these ingredients usually helps to increase the hardness of the solid cosmetic of the present invention. Specific examples of the titanium oxide include ultrafine particles, plate-like or needle-like titanium oxide, and one or two types of titanium oxides having such shapes of titanium oxide are usually used. The amount of the solid cosmetic used is usually 0.1 to 20% by weight based on the weight. The mixing method is to mix with other ingredients contained in the general powder part when preparing cosmetics. The addition of these ingredients can reduce the hardness of solid cosmetics within the allowable range, and has a rib to enhance the ultraviolet prevention effect. Specific examples of spherical powders include spherical silica, spherical nylon powder, and spherical polyacrylic acid alkyl. _, Cross-linked polystyrene, squalane mixture, anabolic powder, anhydrous silicic acid, methylsilicone network polymer powder. It can contain one kind of M, based on the total weight of solid cosmetics K, generally containing 0.005 to 20% by weight. The addition of these ingredients, at least when solid cosmetics are used, will help to cover the pores of muscle muscles, and smooth out the wrinkles. Or improve the absorption of sebum. The water-oil type cosmetic composition or solid cosmetic of the present invention may further contain ingredients which can be mixed with other cosmetic. For example, the above mentioned oils, humectants, dispersants, powders, preservatives, fragrances, medicaments, -14- This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (2! 0 '乂 297 mm) (Please read the precautions on the back before filling this page) 6 4 45 0 8 Α7 Β7 V. Description of the invention (η Tackifier, According to this cosmetic, it can be touched with water "Non-sticky J, so there is no special note ( 1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11) Pigments, pigments, etc. According to the invention, the obtained oil-in-water cosmetics for the hair remain solid Μ solid state applied to myo oil type emulsion or cream also has "softness", excellent storage stability once. The system description of the present invention is as follows. The compounding amount in each example is as follows, all Μ (weight / Weight)% is expressed. Oil-in-water type emulsified powder foundation (foundation) Decamethylcyclopentylsiloxane stearate stearate red oxidized yellow iron oxide black iron oxide titanium dioxide kaolin slip powder 1, 3-butanedioyl p-oxyl When methyl benzoate ion-exchanges in water, "Dry 16. 10 25 Solidification and use is cool" and (Please read the note on the back first (Please fill in this page for the matters needing attention) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. 25. (12) 2-Amino-N-carboxymethylhydroxyethyloxazoline betaine (purity 30%). ) (2) Stir and dissolve into oil phase at 7 0 υ ~ 8 0 " 0, and dissolve (9) to (12) at 70 t ~ to dissolve into water phase. Add water phase to oil 15- this paper Standards are applicable to Chinese National Standards (CNS) Λ4 specifications (210 X 297 mm) 46 45 Ο δ Α7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs B7 V. Description of the invention (4) The phases are emulsified and mixed in advance Mix (3) to (8), mix on the foundation and flow, and cool to obtain an emulsified powder. This powder is soft, dry, non-sticky, and has usability. Comparative Example 1 Oil-in-water emulsified powder (foundation) Π) + methyl pentylsiloxane (2) hydroxystearate stearic acid (3) red oxidation (4) yellow oxidation (5) black oxidation (6) titanium dioxide (7) kaolin (8) slip Powder (9) 1, 3-butanediase (10)> methyl paraoxybenzoate (U) ion-exchanged water (12) 2-alkyl-N-carboxymethyl-N-hydroxyethyl 5.0 眯Oxazoline beet salt Purity 30%) The Mdan method was produced in the same manner as in Example 1, but was different from the actual example 1. Separation occurs during emulsification. Example 2 Oil-in-water emulsion powder (foundation) (1) Octamethylcyclobutadiene Oxane 13.69 (2) Dimethicone (6cs) 5.0 (3) Jojoba oil fully hydrogenated 0,07 This paper size is applicable to China National Standard (CNS) A4 (2! 0X297 mm) )

(Please read the precautions on the back before filling out this page) 464503 A7 Consumption Cooperation with Employees of the Central Bureau of Standards, Ministry of Economic Affairs, Printed B7 Du V. Invention Description (π) (4) Stearic Acid _ (5) Floor Broadcast (6) Paste Argonic acid _ treatment of red oxidized (7) dextrin fatty acid ester treatment of yellow osmium oxide (S) dextrin fatty acid _ treatment of black ferric chloride (9) dextrin fatty acid ester treatment of titanium dioxide (1 0) dextrin fatty acid Cool treated sericite (11> lake refined fatty acid_treated slip powder (12) polymethacrylate spherical powder (13) 6,6-nylon (14) malonase (1 5) dana fried_with glycerin ( 16) Hyaluronic acid (17) Methyl paraoxybenzoate (18) Ion-exchanged water (19) Coconut oil fatty acid aminopropyl betaine (purity (30%)) (20) Spice method 701 ~ 80Τ, The powder is searched and mixed in the oil phase portion, the water phase portion is added, emulsified, and then poured into the powder cake, and cooled to obtain an emulsified powder powder. This powder is soft, dry, non-sticky, and usable. Also, the refined fatty acids used here _Treatment powder is based on 95% by weight of raw material powder and 5% by weight of dextrin fatty acid ester. -17- This paper is applicable to China Standard (CNS) Λ4 specification (210 × 297 mm)

{Please read the precautions on the back before filling in this page} 464508 A7 B7 V. Description of the invention (E (product made by Eisen Chemical Co., Ltd.) printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy, the solution is broken into 6 (Example 3) Oil in water Type emulsified rod-shaped foundation α) decamethyl pentylsiloxane (2) squalane (3) fluorinated hydrocarbon (4) octandodecanyl lanolinate (5) methyl hydroxystearate »(6) vaseline (7) Silicon oxide treated with red oxide (8) Silicone treated with yellow oxide (9) Silicon-treated with black iron oxide (10) Mica (11) Powder (12) 1 but 3-dioxanase (1 3) Dana explosive glycerin (14) methyl p-benzoate (15) sickle-exchanged water (16) lauryl dimethylaminoacetic acid betaine (purity 40%) Preparation method Manufactured by the same method as in Example 1 In the shape model, it is cooled to obtain an emulsified stalk-like foundation. This rod is soft, dry, non-sticky, and usable. Stir, desolvent, dry, powder. 9 0 2 0 5,0 10 0 25 25.0 (Please read first Note on the back, please fill out this page again) -18- This paper size applies to Chinese National Standard (CNS) Λ4 specification (210 × 297 mm) 6 4 45 0 8 β Α7 Β7 V. Description of the invention (Oil-in-water emulsified lipstick (1) Flow paraffin (2) Castor oil (3) Dimethyl polysiloxane (100cs) (4) Camellia succinate (5) Octyl hydroxystearate ( 6) malic acid diisostearic acid (7) red oxidation (8) yellow oxidation (9) red 204 (10) red 2 0 2 (1 1) sodium carboxymethyldividin (12) 1, 3 -Succinic acid (1 3) sorbitol (14) methyl parabenzoate (15) ion-exchanged water (16) 2-alkyl-N-carboxymethyl-N-hydroxyethyl 60. 0 89 5 01 (Please read the precautions on the back before filling out this page) 0 20. 4. Imidazoline betaine (purity 30%) printed by the staff of the Central Bureau of Standards of the Ministry of Economic Affairs and Cooperatives, manufactured in the same way as in Example 1, and flowing into the red horizontal type , Cool to obtain emulsified lipstick. This α red is soft, dry, non-sticky, and has usability. First application. Example ratio ... Comparative example 乳化 According to the formula shown in Table 1-2, emulsify is made in the same manner as in Example 1. Composition. Among them, Cell 5 is oil-in-water emulsified powder. -19. This paper size applies to China National Standard (CNS) A4 ^ (210X297 mm) 464508 A7 V. Description of the invention (< 〇 Central Ministry of Economic Affairs Each composition printed by the Bureau ’s consumer cooperative Η is not sticky and ④ hardness 〇 The results of the composition are listed in the same table t t Table 3 cannot be tested can not be emulsified 0 Comment Jt method evaluated by 20 experts An average of 0 is evaluated, 5 points are very good, 4 points are good, 3 points are slightly better, 2 points are normal, 1 point is inferior, 0 points are very poor, and evaluation indicates + + = 4 points, M + 3 points on 9 4 soil: 2 points or more 3 — 1 minute M upper »2 1 1 minute M lower point K lower point lower than the following B7 method evaluation ① tenderness, ② dry, ③ and each of the 30 manufacturers of Examples 1-4 and Comparative Example 1, indicating emulsification Separation occurs when using the test, add the evaluation results of each person (please read the precautions on the back before filling this page) This paper size applies the Chinese National Standard (CNS) A4 specification (210X2? 7 mm) 46 45 0 8 A7 B7 V. Description of Invention () Staff of Central Bureau of Standards, Ministry of Economic Affairs Printed by a consumer cooperative 1 Example 1 Application 5 Example 6 1 Comparative Example 2 (1) Decamethylcyclopentasiloxane 16.8 16.8 16.8 16.8 16.8 (2) Stearyl stearate 5.0 10.0 3.0-12.0 (3) Hydroxyl Deer stearic acid-2.0 5.0-(4) Microcrystalline osmium-----(5) Red iron oxide 1.0 1.0 1.0 1.0 1.0 1.0 (6) Yellow iron oxide 3.0 3.0 3.0 3.0 3.0 (7 > Black iron oxide 0.2 0.2 0.2 0.2 0.2 (8) Titanium dioxide 10.0 10.0 10.0 10.0 10.0 (9) Kaolin 5.0 5.0 5.0 5.0 5.0 5.0 (10) Slurry 25.8 25.8 25.8 25.8 25.8 (11) 1,3-butanediol 3.0 3.0 3.0 3.0 3.0 (12) Paraben benzoate 0.2 0.2 0.2 0.2 0.2 (13) Ion-exchanged water 25.0 23.33 25.0 25.0 18.0 (15) 2-alkyl-N-carboxymethyl-H-hydroxyethyl 5.0 1.67 5.0 5.0 5.0 Oxazoline Betaine (30%) h ^ — ^ — ^^^^ 1 ^ 1 ^ 1 ^ ^^^^ 1 1 ·.. ^ Λ,, va _ _-(Please read the notes on the back before filling this page ) This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X297mm) rc 4 Printed by the Central Consumers Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 4 5 0 8 A7 B7 V. Description of the invention (>-) 3 to 4 5 Case 6 (1) Shijia Pentasiloxane 16.8 16.8 6.8 16.8 (2) stearic stearate _ 0.05 10.0 5.0 2.0 (3) hydroxystearic stearate #---8.0 (4) microcrystalline osmium----(5 > red Oxidation 1.0 1.0 1.0 1.0 (6 > Yellow hafnium oxide 3.0 3.0 3.0 3.0 (7) Black oxidation starved 0.2 0.2 0.2 0.2 (8) Titanium dioxide 10.0 10.0 10.0 10.0 Kaolin 5.0 5.0 5.0 5.0 5.0 (10) Slurry powder 25.8 25.8 25.8 25.8 (im , 3-butanediase 3.0 3.0 3.0 3.0 (12) methyl paraoxybenzoate 0.2 0.2 0.2 0.2 (13) ion-exchanged water 29.95 24.0-20.0 (15) 2-alkyl 4-carboxymethyl-1hydroxyethyl Base oxazoline beetroot (30%) 5.0 1.0 40.0 5.0 -12- (Read the precautions on the back before filling in this 1) This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 cm) 6 4 Economy Printed by the Consumer Standards Cooperative of the Ministry of Standards of the People's Republic of China 45 Ο Β ρ Α Ί B7 V. Description of Invention (w) Table 3 Examples Comparative Examples 1 2 3 4 5 6 1 2 3 4 5 6 涠 + + + f + + + + + + (-) *-+--+ Dry + + + + + + + + + + + (-) — +--+ non-sticky + + + + + + + + ㈠ — +-- + Hardness + + + + + (-) + —— + + —— (-) Fen Shi Li 7 water-in-oil emulsified powder foundation (foundation) (1) Decamethylcyclopentasiloxane 15.8 (2) Candelilla m 5.0 (3) Stearic acid 1,0 (4) Red oxidized 1.0 (5) Yellow oxidized 3.0 (6) Black iron oxide 0.2 (7) Titanium dioxide 10.0 (8) Kaolin 5.0 (9) Talc 25.8 (10) 1, 3-Butadiene Fermentation 3.0 1 1) methyl para-benzoate 0.2 (12> ion-exchanged water 25,0 (13) 2-carbyl-N-carboxymethyl-N-hydroxyethyl 5. 0 oxazoline beet Alkali (purity 30%) (Please read the precautions on the back before filling out this page) This paper size is applicable to China National Standard (CNS) A4 (2! Ο X 293 mm) tD Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs System 4 ^ nr ^ A7 B7 V. Description of the invention (") Transfer method (1) to (3) and stir to dissolve into the oil phase at 70 ~ 80C. Mix (11) to (13) at 70 ~ 80C stir to dissolve into aqueous phase. The water phase portion is added to the oil phase portion to emulsify, and (4) to (9), which have been stirred and mixed in advance, are mixed, and the mixture is poured into a foundation dish, and cooled to obtain an oil-in-water emulsified powder cake. This powder is soft, dry, non-sticky and useful. (Higher lipid acid / amphoteric surfactant Molar ratio = 0.86). Ratio. 1. Example 7 Oil-in-water type emulsified powder (foundation) (1) Decamethylcyclopentasiloxane 15.8 (2) Brazil palm seed 5.0 (3) Stearic acid 1 (4) Red oxidation 1 (5 > yellow oxidant 3 (6) black iron oxide 0 (7) titanium dioxide 10 (8) kaolin 5 (9) slip powder 25 (10) 1, 3-butanediol 3 (11) methyl paraoxybenzoate 0 U2) ion-exchanged water 25 (13) 2-alkyl-N-carboxymethyl-N-hydroxyethyl 5.0 oxazoline beetroot (purity 30%) tuned by the same method as in Example 7 except that Different from Example 7, Emulsified-24- This paper size applies Chinese National Standard (CNS) A4 (210X297mm) • Square, -t-. J (Please read the notes on the back before filling this page) 6 4 4 5 0 8 A7 B7 V. Description of the invention (ii) Separation occurred. Comparative Example 8 Oil-in-water type emulsified powder (foundation) (U Decamethylcyclopentasiloxane 16.8 (2) Microcrystalline machine 5.0 (3) Stearic acid 1.0 (4) Red oxide 1.0 (5) Yellow iron oxide 3.0 (6) Black oxidized 0.2 (7) Titanium dioxide 10.0 (8 > Kaolin 5.0 (9) Slip powder 25.8 (10) 1,3-butanediase 3.0 (11) Methyl paraben deer 0.2 (12) Male exchange Water 25.0 (Read the precautions on the back before filling this page) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (13) 2-Alkyl-N-carboxymethylhydroxyethyl 5.0 Imidazoline beet sickle (purity 30 %) The diluent method was manufactured in the same manner as in Example 7. The difference from Example 7 was that it could not form an emulsifiable solid. Hh Comparative Example 9 Oil-in-water emulsified powder powder (foundation) (1) Decamethylcyclopentasil Gasane 15.8 (2) Candelilla 蠼 5.0 (3) Stearic acid 1.0 (4) Red oxidized 1.0 This paper size is applicable to China National Standard (CNS) A4 (2! 〇 × 29 · 7 mm) rc 4 5 4 5 0 8 A7 B7 V. Description of the invention (> 4- (5) Yellow oxide inlay (6) Black iron oxide (7) Titanium dioxide (8) Kaolin (9) Slurry powder (10) 1 3-Dibutanease 3 0 10 5 2 5 (11) Methyl p-benzoate 0 Π 2) Ion-exchanged water 28 Π 3) Polyoxyethylene (60 «ear) hardened castor oil 1 The preparation method is manufactured in the same manner as in Example 7, except that Example 7 is different, Emulsifiable matter has a low viscosity and is separated over a period of time. Example 8 Oil-in-water emulsified bark powder foundation (foundation) (1) Octamethylcyclobutanesilane 5.69 (2) Dimethylpolysiloxane ( 3) Small candle tree 蟠 | (4) East (please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (5) 1 2 -Hydroxystearic acid (6) Dextrin Fatty acid ester treatment Red iron oxide (7) Saccharin fatty acid Deer treatment Yellow oxide cut (8) Lake essence fatty acid ester treatment Black iron oxide (9) Dextrin fatty acid ester treatment Titanium dioxide (10) Dextrin fatty acid ester treatment Sericite (11) Dextrin fatty acid _ treatment slip powder -26- 10 510. The paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 6 4 45 0 8 A7 B7 V. Description of the invention (.0 ( 12) Polymethacrylic Cool Spherical Powder. 01 (Read the precautions on the back before filling this page) (13) 6,6-Nylon (1 4 ) Malonase (1 5) Dana explosive glycerol ί 16 > Hyaluronic acid (17) methyl paraoxybenzoate 0,1 (18) Coconut oil fatty acid etheramine propyl beet _ 30.0 (purity (30%) (19) Fragrance 0.1: The blending method is performed at 70 ~ 80C, and the powder is stirred and mixed in the oil phase part, the water phase part is added, and after emulsification, the powder is poured into a dish and cooled to obtain an emulsified powder. This powder is soft, dry, non-sticky and useful. (Higher fatty acids / amphoteric surfactant Molar ratio = 1.08). The dextrin fatty acid ester treatment powder used here is obtained by adding 95% by weight of the raw material powder to a 5% by weight solution of Essence Chemicals (Essen Chemical Co., Ltd.) solution, stirring, desolvating, drying, and pulverizing. Got. Consumption cooperation with employees of the Central Bureau of Standards, Ministry of Economic Affairs, Du printed Example 9 Oil-in-water emulsified protective foundation (1) Decacyclopentanesiloxane 2.9 (2) Squalane 2.0 (3) Fluorinated hydrocarbon 0.2 (4) Small candle tree 蠼 10.0 (5) a Shilin 3.0 27- This paper size applies to China National Standard (CNS) A4 (210X297 mm) 6 5 〇 B Α7 Β7 V. Description of the invention (a) ί 6) Stiff Cyclic acid 3.0 (7) Silicon_treated with red hafnium oxide 1.0 (8) Silicone treated with yellow iron oxide 2.5 (9) Silicone treated with black oxide cut 0.2 (1 0) mica 5.0 (m slip powder 5.0 (12) 1 1,3-butanediol 5.0 (13) Suona explosive glycerol 10.0 (14) Methyl parabenzoate 0.2 (15) Young exchange water 40.0 (16) Lauryl dimethylaminoacetic acid beetroot 10.0 (purity 40%) _ Dan Method (Please read the notes on the back before filling this page)

1, 1T Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Manufactured by the same method, it flows into a rod-shaped chess pattern and is cooled to obtain an oil-in-water rolled rod-shaped foundation. It is soft, dry, non-sticky and useful. (Molar ratio of higher fatty acid / amphoteric surfactant = 0.72) 〇Example 10 Water-in-oil emulsified lipstick (1) Flow stone 60.69 (2 > Castor oil 0.5 (3) Dimethicone (100cs ) 1.0 (4) Candelilla 蝈 3.0 (5) Brazil brown 櫊 蟠 1.0 (6) 12 -Hydroxystearic acid 0.1 This paper scale is applicable to China National Standard (CNS) / Vf specification (210 × 297 male) V. Invention Explanation (>? (7) olein (8) malate diisostearate (9) red iron oxide (1 0) yellow hafnium oxide (11) red 2 0 4 (1 2 > red 2 0 2 No. (13) Carboxymethylpyrazine 14) 1,3-Butylase A7 B7 0. 01 (15) Sorbitol (16) Formamidine p-oxybenzate (17) Ion-exchanged water (18) 2 -Alkyl-N-Carboxymethyl-N-Hydroxyethyl 20 (Please read the notes on the back before filling in this page) The Central Standards Bureau of the Ministry of Economy %) Manufactured according to the same plum method as in Example 7, a red model, and a water-in-oil emulsion lipstick was obtained after cooling. This lipstick is soft, dry, non-sticky and useful. (Higher fatty acid / amphoter surfactant Molar ratio = 0.10). G _ Example ΐ 1-1 7. Comparative Example Ί 0-1 fi According to the formula shown in Table 4-7, an oil-in-water emulsified composition was produced in the same manner as in Example 7. The formulas of Example 7 and Comparative Examples 7-9 are also listed on the table. , M for reference. According to the same method as in Examples 5-6 and Comparative Examples 2-6, the obtained compositions were evaluated for ① softness, ② dryness, ③ non-stickiness, and ④ hardness. The results together with Examples 7-10 and Comparative Example 7 -9 The results of each composition are shown in Table 8-9. According to the aforementioned evaluation and evaluation criteria. -29- This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) Order 4 8 ο 5 4 / 5

7 B V. Description of the invention (4) Example 7 11 12 13 14 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs t Shellon Consumer Cooperative ⑴ Decamethylcyclopentasiloxane 15.8 12.5 17.2 15.8 15.8 (2) Candelilla 蠼 5.0 5.0 5.0 5.0 5.0 (3) Stearic acid 1.0 1.0 0.3 1.0 0.4 (4) 12-hydroxystearic acid---(5) Red oxide 1.0 1.0 1.0 1.0 1.0 1.0 (6) Yellow iron oxide 3.0 3.0 3.0 3.0 3.0 ⑺ Black iron oxide 0.2 0.2 0.2 0.2 0.2 (8) Titanium dioxide 10.0 10.0 10.0 10.0 10.0 ⑼ Kaolin 5.0 5.0 5.0 5.0 5.0 (10) Slurry powder 25.8 25.8 25.8 25.8 25.8 (11) 1,3-butanediase 3.0 3.0 3.0 3.0 3.0 ( 12) Methyl paraoxybenzoate 0.2 0.2 0.2 0.2 0.2 (13) Ion-exchanged water 25.0 27.63 26.57 4.74 (14) 2-Alkyl-carboxymethyl-«-hydroxyethyl 5.0 33.3 1.67 3.43 25.86 Imidazoline beet Sickle (purity 30%) (15) Polyoxyethylene (60 箕 ear) hardened ramie oil _---Higher fatty acid / amphoteric surfactant (Molar ratio) 0.86 0.13 0.77 1.25 0.066-^ 2 〇 ^ (Read first Note for occasional fateful reading, please fill out this page again) A 'bound paper size is applicable to China National Standards (CNS) A4 size (210X297 mm) € 4 Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 45 0 8 A7 B7 V. Description of the invention (> 9) 15 Example 16 17 (1) Decamethylcyclopentasiloxane 3.5 15.8 5.8 (2 > Candelilla 5,5 5.0 5.0 (3) Stearic acid 0.7 0.3 (4) 12-hydroxystearic acid 10.0--(5) Red iron oxide 1.0 1.0 1.0 (6) Yellow oxidation 3.0 3.0 3.0 (7) Ochre iron oxide 0.2 0.2 0.2 (8) Titanium dioxide 10.0 10.0 10.0 (9) Kaolin 5.0 5,0 5.0 (10) Slip powder 25.8 25.8 25.8 (11) 1,3-butanediase 3.0 3.0 3.0 ( 12) Methyl paraoxybenzoate 0.2 0.2 0.2 (13) Ion-exchanged water-28.5 10.7 (14) 2-Alkyl-1 acetomethyl-((-hydroxyethyl 33.3 1.8 30,0 mileline beet test (Purity 30% > (15 > Polyoxyethylene (60 Molar) Hardened Ramie God-One-High Fatty Acid / Amphoteric Surfactant (Molar Ratio) 1.22 1.67 0.04 (Please read the precautions on the back before (Fill in this page) This paper size applies to Chinese National Standard (CNS) A4 specification (2! 0 × 297 mm) A7 4 6 45 0 8 B7 V. Description of invention (M) Staff Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs System 7 to 8 to 9 cases 10 11 Π) + methyl pentasiloxane 15.8 15.8 15.8 5.8 16.6 (2) candelilla 蠼--5.0 5.0 5.0 (3) Brazil palm tree 5.0----(4 ) Microcrystalline osmium-5.0--(5) stearic acid 1.0 1.0 1.0 1.0 0.2 (6) red iron oxide 1.0 1.0 1.0 1.0 1.0 1.0 (7) yellow osmium oxide 3.0 3.0 3.0 3.0 3.0 (8) black iron oxide 0.2 0.2 0.2 0.2 0.2 (9) titanium dioxide 10.0 10.0 10.0 10.0 10.0 (10) kaolin 5.0 5.0 5.0 5.0 5.0 (ιυ slippery powder 25.8 25.8 25.8 25.8 25.8 (12) 1,3-butanediol 3.0 3.0 3.0 3.0 3.0 (13) oxygen Methyl benzoate 0.2 0.2 0.2 0.2 0.2 (14) ion-exchanged water 25.0 25.0 18.0-29.0 (15) 2-alkyl- »1-carboxymethyl- | {-hydroxyethyl 5.0 5.0-40.0 1.0 oxazoline Beet H (Purity 30%) (16) Polyoxyethylene (60 mol) hardened ramie oil--12.0--Higher fatty acid / amphoteric surfactant (Molar ratio) 0.86 0.86 1.05 0.11 0.86 One (please wait) Read the notes on the back and fill in this page again) -59 This paper size applies to Chinese national standards (CNS 丨 A4 size (2 丨 0 X 297 cm) A7 46 45 0 8 B7 V. Description of the invention (V) 7 Comparative Example Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs 12 13 14 15 (1) + methylcyclopentasiloxane 15.8 15.8 2.8 15.8 (2) Candelilla wax 5.0 12.0 5.0 12.0 (3 > Brazil Brown wax----(4) Microcrystalline tincture---One (5) stearic acid 0.05 0.05 11.0 1.0 (6) Red iron oxide 1.0 1.0 1.0 1.0 (7) Yellow iron oxide 3.0 3.0 3.0 3.0 (8 > Black oxide cut 0.2 0.2 0.2 0.2 (9) Titanium dioxide 10.0 10.0 10.0 10.0 (10) Kaolin 5.0 5.0 5.0 5.0 5.0 (11) Sliding powder 25.8 25.8 25.8 25.8 (12) 1,3-butanediol 3.0 3.0 3.0 3.0 (13) Pair Methyl oxybenzoate 0.2 0.2 0.2 0.2 (14) Ion-exchanged water 29.15 22.15-18.0 (15) 2-Alkyl 4-carboxymethylfluorenyl-hydroxyethyl 1.8 1.8 33.0 5.0 Oxidazole W sugar beet_ (purity 30% ) (16) Polyoxyethylene (60 Molar) hardened castor oil---Higher fatty acid / amphoter surfactant (Molar ratio) 0.12 0.12 1.43 0.86 — (Please read the precautions on the back & fill in this page) This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 464508 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 &Amp; Description of the invention Table 8 Example 7 8 9 10 11 12 13 14 15 16 17 Tenderness + + + + + + + + + + + + + + + + Dry + + + + + + + + + Ten + + + Not sticky + + + + + + + + + + + + + + + Hardness + + + + + + + + + + + + + Soil Table 9 Comparative Example 7 8 9 10 11 12 13 14 15 Soft涠 (-) * + + + +--+----Dry (-) + + + + Taxi + — ^ — · Non-sticky (-) + + + + —-4 · —-- Hardness (-) —-- + —--+ + • (-) Cannot be trial-produced (please read the precautions on the back before filling out this page) This paper uses the Chinese National Standard (CNS) A4 size (210X297 mm) ) A7 464508 B7 V. Description of the Invention (〇) (Please read the precautions before filling this page) g Example 18-27 solid cosmetics with other cosmetic ingredients (a) These examples are to prove that When preparing water, amphiphilic surfactant, amphoteric surfactant, and higher fatty acid composition, especially the oil phase contains other added cosmetic ingredients, silicone varnish, ester oil (or semi-solid ethyl ester), and advanced enzymes. , The effect of addition of ethylene glycol or glycerol fatty acid of yeast. Except for a part of decamethylcyclopentasiloxane in the composition described in Example 7, the components shown in Table 10 were used instead of K, and each composition was prepared according to the preparation method described in Example 7 (implementation Examples 18-27). The hardness, the effect of preventing cracking and the effect of preventing water volatilization were evaluated by adding M to the above-mentioned addition of each composition, and the results are shown in Table 10 together with the results of the evaluation of the composition in Example 7. The evaluation method is as follows. Beibeiyu Co., Ltd. Hardness tester manufactured by Fudo Industries Co., Ltd. was used to measure the hardness of each composition with 20 samples in accordance with the measurement conditions described in "Solid j or" Solid ", and the average value of the measurement results K was shown. Anti-ih effect is printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The composition is exposed for 1 hour at room temperature (2 5 Ί 0), and the weight change of 20 samples is measured, compared to the original weight. The average weight loss rate is as shown below. The evaluation indicates a reduction rate of + + + 0.7% + + 0 · 7% to 1.0% + 1.0% to 1.3% + 1.3% to 1.3% + 1.3% or less -35- This paper size applies China National Standard (CNS) A4 specification (2〗 〇297297 mm) 46 45 0 8 Α7 Β7 V. Description of the invention (M) Anti-fouling 丨 After the surface of each composition is taken out, the sample is placed at room temperature ( 25t) Exposure. The tendency of crack occurrence in 20 samples was observed over time. The average behavior is classified as follows. The evaluation indicates that the toad cracking tendency is + + + extremely difficult to occur + + difficult to occur + there are some samples with small cracks Most of the samples have small cracks (please read the precautions on the back before filling this page) Order the Ministry of Economic Affairs The paper standard printed by the Central Bureau of Standards Consumer Cooperatives applies the Chinese national standard (CNS > A4 size (210 × 297 mm)) I amended and supplemented this month I 9-? 〇I64508 A7 B7 V. Description of the invention (# Economic Ministry Central Bureau of Standards—Industrial and Consumer Cooperation and Printing • it ^ BIIIlrs ^^ iNhglhgicstHntfl'vi / ^ fal / 'i ^ r ^ ERL-r ^ lifE & nl ^^ aJieBn) I 00 is coming out one by one: 洚 洄a trend! © ± 洚 滟 U31 58 H- + ± H- 55 S each 6 < 0OT30001private 107 73 + + + + + ++ + i + ii ±± 屮 ++++++ ±± -f- fflsiist ^ 尔 iri |||. 苕 爷 苕 _ 苕 赵 2—ZWDJ Tan Jian Jian Fu Fu 4Z: Zou Zou Zou Tian Miao 卅 Interpretation and Translation of Miscellaneous + U 筘 园 薄 »谌 藤 赵 (疵) E ^ raw 0 ^ 0 Shu chrysanthemum NhsBmlrspsBi * 15.8 13.0015.3 15.3 15.3 15.3 15.6 15.cri15.6 15.6 13.00 〇 2.0 000000000 00 0.5 00000000 000 0.5 0000000 〇 〇.〇〇0.5 〇 00 〇 OO 0.5 00000 000000 0,2 0000 0000000P2 000 00000000 0.2 00 000000000 0.2 ο 〇〇〇〇〇〇〇〇〇〇2.0 2.0 18 g 20 21 22 23 2 Ren 25 2B 27 mlo (Please read the precautions on the back before filling this page) This paper size applies China National Ladder Standard (CNS) with specifications (210X297 Gt) 464508 A7 B7 V. Description of the invention (from) Table 10 can be summarized with the addition of silicone varnish, _ oil (or semi-solid methyl ester), advanced fermentation, or The effect of the addition of higher fatty acid diesters of adipic acid is as follows. (Please read the precautions on the back before filling this page) Adding varnish or the two has no adverse effects on the cracking behavior and volatility of the composition, which can improve the composition Hardness, which can be easily taken with fingers, sponges, or powder puffs. The addition of gull oil has little or no adverse effect on the hardness and volatility of the composition, and can deliberately improve the effect of preventing cracking. The hardness of the composition by higher alcohols There is no adverse effect on the cracking behavior, and the effect of preventing volatilization can be intentionally improved. Fenshi Examples 28-34 Solid Cosmetics with Additional Cosmetic Ingredients (Second) These examples demonstrate the effect of changing the slip powder to other spherical powders among the ingredients of Example 7. For the preparation of the composition, except that a part of the powder of Example 7 was changed to the ingredients shown in Table 11, it was marinated according to the preparation method described in Example 7. The composition was evaluated for the effects of the above-mentioned additions on hardness, muscle pore covering effect, and tack prevention effect (non-sticking). The hardness and non-stickiness are listed in Table 11 according to the above evaluation results. The Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs printed and tested the tests. They were all added with the level of M, and the evaluation of the results of the evaluation of the industry and the names of the names ο _ 2 by the matter-Cheng, the fruit group 11 effect 7 table example In the list shown, Kong Shizhan estimated that Mao had different effects on the basic muscles of the captives, and M did not cover the entire hole ± Mao equivalent. Comment on the case when there is an example of a bright picture l. Look at the actual γ phase to see if the paper size and Chinese paper standards (CNS > Λ4 specifications (210X297 mm) 46 46 0 0 8 Λ7 Β7 DESCRIPTION OF THE INVENTION (^ 7) i 谢) Shaped i-pin 31¾¾ 筘 ael i box glow spine i-ffis®® thin and smooth ° >? Ast chrysanthemum? 1 Thin 鎇 73 55 60 65 S3 (Read the precautions on the back before filling in this page) 0 0 0 0 0 5 0 0 0 0 0 5 0 0 0 0 0 CJ1 0 0 0 0 0 0 0 0 0 0 5 Duplicate printing of work and consumption cooperation of the Central Standards Bureau of the Ministry of Economic Affairs 52 0 0 0 0 0 0

OI This paper size applies Chinese National Standard (CNS) A4 specification (2 规格 0X297 mm) 20,8 20.8 20,8 20 «20.〇〇20'8 20.8 28 2 < oOJ0 31 32 33CO4 Order 464508 Α7 Β7 V. Description of the invention (w) (a) to (g) trade names {manufacturer or seller) are as follows (a) spherical aluminized silicon P-1500 (b) nylon SP-5 Ο Ο ίEast Corporation) ic) 7 r 彳 > A 3000SPQ (Sumitomo Chemical Co., Ltd.) (d) 7 彳 口 口 工 7M306 (ethylene glycol dimethacrylic acid_) (Matsumoto Oil & Fats Pharmaceutical Co., Ltd.) (e) Qierkou 7 mouth (： -25 ( Company > (f) Bu 7A-Λ / 145Α (Toshiba Silicon Corporation) (g) Gua E-506S (Toray Corporation) From Table 11, it can be seen that the addition of spherical powders has no adverse effects on other properties of the composition, such as hardness. Effects, can deliberately change the pore cover and stickiness (absorptivity of sebum, etc.) of tuberculosis muscles. Examples 35-38 Solid cosmetics with additional cosmetic ingredients (third) These examples demonstrate the titanium dioxide of Example 7 The effect of completely changing the shape of each titanium oxide is used. The composition is prepared except that the titanium dioxide of Example 7 is changed to the titanium oxide K of the specific shape shown in Table 12. The preparation method in Example 7 was marinated. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). The hardness of each composition, the effect of covering muscle pores, and the effect of preventing stickiness. , UV shielding effect, plus M evaluation, the results are shown in Table 12. 阚 For hardness, pore coverage, non-sticky, can be based on the above evaluation criteria, and for the UV shielding effect (UV medium-shielding pseudo-number UV-CVT (SPF )), 20 professional appraisers carried out the use test, and after one hour, the relative sun exposure (value "14" > Paper size is applicable to China National Standard (CNS) A4 specification (2Η: IX 297 mm) 464508 A7 B7 V. Description of invention (shirt) 苒 Example 35 36 37 38 Fine particle titanium oxide 10 0 0 0 Fatty acid needle needle titanium oxide 0 10 0 0 Needle-shaped hafnium oxide 0 0 10 0 Contains a part of plate-like needle-shaped titanium oxide (treated with fatty acid) 0 0 0 10 Hardness 63 11 2 90 Pore coating + + + + Non-stick ten + + + UV- CUT (SPF) 18 17 19 20 (Please read the note on the back first Please fill in this page for further details.) According to the consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs, it can be seen from Table 12 that when titanium dioxide is changed to titanium oxide with a specific shape, although the hardness of the composition is reduced, the pores are not covered and the adhesion is not improved. , Can deliberately improve the UV shielding effect. g _ Examples 39-49 Solid cosmetics with additional cosmetic ingredients (No. 4) These examples demonstrate the effect of adding a water-soluble polymer to the composition of Example 7 instead of part of ion-exchanged water. The composition was prepared according to the preparation method described in Example 7 except that each water-soluble polymer shown in Table 13 was added to the water phase portion of Example 7. Table 13 shows the results of evaluating the hardness and the effect of preventing volatilization of each composition obtained according to the above-mentioned evaluation method. 1- This paper size applies the Chinese National Standard (CMS) A4 specification (210 X 297 mm) 464508 Amendment] Α7 This month gi Β7 ^ 83. 9. 20 J V. Description of the invention (〇) a berry a h float钿 284 73 H- 77 93 ± 89002 s S γογοο tanning 屮 »_2_ 兹 菡 铖 萡 杯 菡 铖 萡 猓 菡 铖 萡 酙 翊 iNua 0 ^ 0 -ffi 脚 戡 麻 麻 翊 2, ¾¾ M: t 莸 湘郴 S 漤 lining up ¾ irritating and irritating thorns ^ ^ employees of the Central Standards Bureau of the Ministry of Economic Affairs, the Ministry of Economic Affairs, the staff to allow the cooperatives to print 24.9 24. < rl24'co24.9 24, (024.1024.9 24. < 024. Magic 24'9 24-9 0 · 10000 000 000 000 0 · 100 000 000 000 000. 100 000 000 000 0 0 0.10 0 0 0.0 0 0 〇〇〇〇〇. 〇0 a 〇〇〇〇〇〇00000 0.1 000 000 000 0_10 0,000,000,000 00,000,000,000 0.1 0.1 00 〇〇〇〇〇〇〇〇〇 〇 一 〇0 〇0 0 0 0 0 0 0 0 0 0-1 4 The paper scale is applicable to China National Standards (CNS) Α4 specifications (210 × 297 mm) (Please read the precautions on the back before filling in this page )

1T 46 45 0 8 A7 B7 V. Description of the invention (heart) From Table 13, it can be seen that adding a certain water-soluble polymer, in addition to deliberately improving the effect of preventing volatility, also has the effect of improving hardness. Utilization value of the present invention The water-in-oil type cosmetic composition or the solid cosmetic product of the present invention can provide the intermediate composition or the final product for cosmetics which is excellent in the feeling of using M and muscles and can be stored stably. Therefore, it has a strong use value in the cosmetics manufacturing industry. (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs -43- This paper size applies to China National Standard (CNS) Α4 specifications (2 丨 0 X 297 mm)

Claims (1)

d 6 45 0 8 ........ | [ί ^ Τ This month, supplemented with 7 · 3 ί 6. Patent Application No. 84107822 "Solid Cosmetic Composition and Solid Cosmetic" Patent Case (90 years (Amended on July 31) 6. Scope of patent application: 1. A solid cosmetic composition, which is an oil-in-water cosmetic composition composed of water, wax ester, and one or more other cosmetic ingredients. Based on the total weight of the product, it contains: (A) 0.1 to 10.0% by weight of one or more wax esters, the constituents of which have a portion derived from Cl8.34 high carbon number fatty acid, and a portion derived from C18_34 high carbon number fatty alcohol And (B) 0.5 to 10.0% by weight of one or more amphoteric surfactants selected from the group consisting of amidobetaine, amidosulfobetaine, betaine, sulfobetaine, and imidazoline. 2. A solid cosmetic composition, which is an oil-in-water cosmetic composition composed of water, ethyl ester, and one or more other cosmetic ingredients, based on the total weight of the composition, containing: (Α) 0.1 to 10.0% by weight of one or more wax esters, the constituents of which have a Ci8_34 high carbon number fatty acid derived portion, a C18.34 high carbon number fatty alcohol derived portion, and (B) 0.5 to 10.0% by weight of one or more amphoteric surfactants selected from the group consisting of amidobetaine type, amidosulfobetaine type, betaine type, sulfobetaine type, and imidazoline type, and (C) Ol to 2.0 C6_34 high carbon number fatty acid. 4645 0 8 VI. Scope of Patent Application 3. For the composition in the scope of patent application item 2, the molar ratio of component (C) to component (B) is 1:15 to 1: 0.8. 4. If the composition of the scope of application for the patent item 1 or 2, the component (A) is more than one wax ester, and its constituent part has a C26_ „high carbon number fatty acid derived part, and C2 (i.34 high carbon Number of fatty alcohol-derived parts. 5. If the composition in the scope of patent application No. 1 or 2, wherein the component (A) is a wax ester derived from candelilla wax. 6. A kind of solid cosmetics, mixed with Water-in-oil type solid cosmetics composed of hydration, ethyl ester, and one or more other cosmetic ingredients, based on the total weight of the composition, containing: (A) 0.1 to 10.0% by weight of one or more wax esters, and its constituent parts Portions have C18.34 high carbon number fatty acid-derived portions, Cl8.34 high carbon number fatty alcohol-derived portions: (B) 0.5 to 10.0% by weight of one or more selected from the group consisting of amidobetaine, amidine Amphoteric surfactants of sulfobetaine type, betaine type, sulfobetaine type, and imidazoline type; (C) 0 to 10.0% by weight of one or more C6_34 high carbon number fatty acids; and (〇) other cosmetic ingredients , Selected from silicone oil, ester oil (or semi-solid wax ester), high carbon number alcohols Water-soluble polymers, fatty acid esters of ethylene glycol or glycerol, and one or more of titanium oxide and spherical powder groups. 7_ For solid cosmetics as claimed in item 6, the silicone oil is Trimethylsiloxysilicic acid-decamethylcyclopentylsiloxane, dimethyl poly 6 45 0 8____ j Amendment this year Λ a Supplement 9 (U0 ·-3 6. Applicants for patents in Silicon Oxygen Institute 8. If you apply for solid cosmetics under item 6 of the patent application, the ester oil (or semi-solid wax ester) contains more than one component of esters, and its constituent part has a C8_24 saturated or unsaturated high carbon number fatty acid derivative part. , And those derived from C14.24 saturated or unsaturated high carbon number alcohols. 9. For example, the solid cosmetics of the scope of application for patent 6, wherein the high carbon number alcohols are C] 6.22 saturated fatty alcohols or saturated fatty ethers- Fatty alcohol. I 0. The solid cosmetics as described in the sixth item of the patent application, wherein the water-soluble polymer is one or more selected from the group consisting of hydroxyethyl cellulose, hyaluronic acid, highly polymerized polyethylene glycol, xanthan gum, and poly (methyl formazan). Based) acrylic acid, methyl cellulose, polyvinyl alcohol, Dextran sulfate, chondroitin sulfate, polyvinylpyrrolidone, and gum arabic. II. Solid cosmetics such as the scope of patent application No. 6, wherein ethylene glycol or glycerol fatty acid esters are saturated with C18.3Q Ethylene glycol diesters of fatty acids, or more than one triglyceride of C18.3 () saturated fatty acids. 1 2. The solid cosmetics such as the scope of patent application No. 6, wherein the titanium oxide is ultra-fine particles, plate-shaped and needle-shaped. The composition of two or more kinds of titanium oxides. 1 3. The solid cosmetics as claimed in item 6 of the patent application, wherein the spherical powder is one or more kinds selected from spherical silica, spherical nylon powder, and spherical soft polyacrylic acid alkyl. Ester, cross-linked polystyrene-squalane mixed powder, cellulose powder, anhydrous silicic acid powder, and methylsiloxane network polymer. Bulletin wood A4 C4 464508 Printed by the central government ’s industrial and commercial cooperatives %% Invention ---, ~ -Ji patent specification invention A, ---, the new name Zhongzhang solid cosmetic composition and solid plaque cosmetics (April 18 Amendment) English ---- ~ COMPOSniOK FOR SOLID COSMETIC AHD SOLID COSMETIC Name 1. Tomoko Ikeda 2. Masaru Aizawa (Sarasho Masaru) 1-2 Borrowed from Japan _Invention ”—, creative residence, residence 1. Kanagawa Prefecture No. 1050, Shinbudo Ding, Gangbei District, Hengtan City. The first yose-kochi of Aso-do & Co .; > Xi-in 2. Ibid. 'Name (Name) (Shiseido Co., Ltd.) Shiseido Co., Ltd. Nationality B Benzo-san' Applicant Residence, Residence (Office) 7 Ginza, Ginza, Chuo-ku, Tokyo Name of Representative No. 5 Fukuhara Kyoharu 4 6 4 5 〇 B (by this bureau ^ :) Coordinator of Printing Policy, Central Bureau of Standards, Ministry of Economic Affairs, Bei X Consumer Cooperatives Code category pc is divided into cheeks A6 丨 ηΦ \ This case has been applied for: a patent application in the region of Benben⑴, claiming that the 4th year, the 21st of the month miscellaneous flat 6_19_ There are microorganisms have been deposited in: mail Date: * 2a- Chinese paper standard (CNS) A4 * t (210X297mm) 37¾ □ No owner ί Long-term priority registration number: ^ Pack. Order '♦ (Please read the precautions on the back first (Fill in the columns on this page) 46 45 0 8 A7 B7 V. Description of the invention (,) a '... — ------- Ϊ This invention relates to oil-in-water cosmetic compositions, and more particularly to oil-in-water solid compositions suitable for foundations, eyeshadows, lipsticks, and the like. Back long branch is known as solid cosmetic type. Generally, solid oily type with solidified oil with wax, solid ingot type made by pressing powder or a mixture of powder and oil agent, specific oily coagulant and hydrophobized powder The solid water-in-oil type dehydration formula composed of water, water, and lipophilic surfactants is divided according to the purpose or method of use of the cosmetics, respectively. Among them, the solid oil-in-water emulsification type has good stability and water resistance, and has a feeling of use after wetting. For example, it is known to use a silicone varnish with solid tincture and water, and use polyalkylene oxide to modify organic polysiloxane. Ethane plus kappa emulsifier (Japanese Patent Laid-Open No. 64-79104). However, this type of oil-in-water emulsion type, with an external phase mixed with oil or oil-based coagulant, is inferior to oil-in-water rolling fluids or creams in terms of "softness", "dryness" and "non-stickiness". In addition, examples of the oil-in-water emulsified coagulate in which a higher alcohol or a clay mineral is blended in a large amount are known. However, because of this oil-in-water emulsification type, the older child mixes the aforementioned ingredients, which loses the characteristics of "soft moisturizing," "dry," and "non-sticky" that oil-based emulsions or creams have. Other examples of solid water-in-oil type emulsification are those in which external phase water is coagulated by fatty acid soap (Japanese Patent Application Laid-Open No. 5-178723, Japanese Patent Application Laid-Open No. 7-17828). The former has a lot of soap. * The pH is high, and it has problems with skin irritation and safety. The latter does not have sufficient hardness, and it is not easy to use a sponge. This is the problem. -3- (Please read the precautions on the back before filling this page) The dimensions of this paper are applicable to the Chinese cabinet (CNS) A4, see the grid (210X 297 cm) zj. 5 0 O A 7 '— ‘ B7 ft V. Description of the invention (>) _ You (please read the notes on the back before filling this page) The emulsification technology developed in recent years, it is known to combine the amphoteric surfactant and high-fat fatty acid to form a water-insoluble compound This compound forms an emulsification interface film to ensure the stability of emulsification (Japanese Patent No. 3-166367). There is also a solid emulsification method using this technology, but it is difficult to obtain a "soft and smooth" and "not dry" Sticky. On the other hand, general lotions or creams are from 0¾ to 50t: Fanpu has fluidity, so when it is in the form of a container such as a bottle or tube, it is slightly lacking in portability or ease of use, especially in the case of foundations. Due to this background, there has not been a solid solid composition with good portability or ease of use, and it has all the "soft", "dry" and "non-sticky" feels of emulsions or creams. Therefore, the object of the present invention is to provide a composition that shows the "soft" f dry, "non-sticky" feel of an oil-in-water emulsion or cream, and at the same time can be used as a portability or easy to use. Solid cosmetics are beneficial to use. Mingxi Xi was reported that Yin Xian, the incumbent consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs and the present inventors, etc., in order to achieve the above-mentioned purpose, devoted themselves to the research and development of the use of specific phosphonium esters and amphoteric surfactants, or to combine phospholipids with these two ingredients It can obtain a stable and stable oil-in-water emulsion composition with excellent touch. The composition thus obtained can exhibit the aforementioned excellent physical properties without using, for example, a water-soluble coagulant or a water-soluble adhesive contained in a conventional water-in-oil type cosmetic. Therefore, according to the present invention, a water-in-oil composition according to the present invention, consisting of water, methyl ester, and other cosmetic formula ingredients, is provided. A4C grid U10 X 297 public 嫠) ί-ζ- ------- ^ Α7 Β7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Ⅴ 5. Invention Description (々), the total weight of the M composition is based on the standard, including: U) — The phosphonium ester on species K from 0.1 to 10.0% by weight, and its constituents have C18-C34 higher fatty acid-derived moieties, and ClS-C4i higher fatty alcohol-derived moieties, and (B) — amphoteric on species M The surfactant is 0.5 to 10.0% by weight. Another cosmetic inhibitor is provided. * In addition to the above (A) component and (B) component, it also contains a certain amount of (C) component, which is more than one C6-C34 higher fatty acid. In addition, 遨 can provide solid cosmetics, based on the above (A) and (B) ingredients, or U), (B) and (C) ingredients, and other ingredients used in this technology model, selected from silicon light One or more types of oil, cool oil (or semi-solid stilbene ester), stilbene alcohols, water-soluble polymers, ethylene glycol or glycerol fatty acids, titanium oxide, and spherical powder group, K means the purpose.最佳 Best specific examples of the axillary invention The "solid" or "solid J" as referred to in the present invention refers to its composition or ingredient at a temperature of 50 or less, which does not take into account the fluidity, and is usually used even under misuse and storage conditions. There is no obvious change in the state below. Specifically, it refers to the required amount of components or ingredients in a certain shape, while the rest can maintain the hardness of the original shape. Furthermore, the hardness is specifically at 37T. , Using this technical range _ When the commonly used hardness tester measures t, the hardness (γ) shown in the following formula is above 7 ~ 5-This paper size is generally Chinese National Standard (CNS) Λ4 specification (210X297 mm) (Please read the back first (Please fill in this page again) A7 B7 46 45 0 8 The seal of Xiaoxian Cooperative of Employees of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention) 1 1 It is better to use saturated aliphatic bases at the point of view. 1 1 C ΐ 3-3- i higher fatty acids constituting the m ester. Specific examples include C 1S octadecane 1 1 acid (IIB, fatty acid) 1 C20 eicosanoic acid (arachidic acid), C 22 dodecanedioic acid Please i first 1 (Small ¥ acid) C24 Docosaic acid, C26 Hexadecanoic acid (Phenylic acid) > Read II C2B Octacosanoic acid (Yancoic acid), C BO Di + alkanoic acid (bee Flower acid), C 3; 1 back 1 I 1 32 m acid, C34 tetracosanoic acid and other natural waxes choose 4 fi f itself or pay attention to 1 thing · 1 includes the ester form 〇 commonly used in the above brackets Name C Item 1 The above-mentioned even-numbered fatty acids »are generally easy to obtain, but c L 39 Nineteen acids are filled in < Odd-numbered fatty acids such as this I and C 33 triclosanic acid, as long as they are available, do not exclude 1 I except Based on the aforementioned carbon number of fatty acids. In addition, the aliphatic group may be 1 1 m »For example, the fatty acid component of lanolin contains at least -38 kinds of C 38-32 iso fatty acids (even 1 carbon). And C 19-33 anteiso fatty acids, also Included in the fatty acids of the 1 π ester constituting m esters of the present invention. Furthermore, the fatty acids constituting the wax ester include those having an unsaturated carbon number of 1 1 and a fatty acid obtained by hydrogenation, or a lower alkyl group corresponding to the aforementioned hydroxy fatty acid 1 I of a fatty acid, such as methyl 'ethyl. The esters of propyl group 0 1 f Among them, the more general ones are, for example, C2 which is the acetic acid ester of rapeseed mash, 2 gluten 1 acid, which is the melamine C 24 docosauronic acid (Brazil Brown m 1 (I m mostly contains this acid), C 26 acetic acid f 橼 1 which constitutes the lanolin ester of lanolin, Cm browning acid which forms the m-ester of mastic, which is a brewing product of f. C 30 S 1 melamine and 〇 12: dodecanedioic acid, C 34 JHT-, tetradecyl I alkanoic acid constituting the carbamate of the gum, all are fatty acids constituting the gate ester of the present invention 0 1 1 Aspect t constitutes a cool C 1 S -44 higher fatty alcohol, which is equivalent to 1 1 of the aforementioned fatty acids. Generally there are, for example, C 10 stearin, C 20 eicosanol 1 1 1 -7- 1 1 1 .Paper size applies Family standard rate {CNS) Eight materials can be seen (2 [〇X297mm) 6. ^ 0 8 Ninth Five-Year, Invention Description (9 When it exceeds 10.0% by weight, there may be problems with the completeness of the final product 0 (please first Read the notes on the back and fill in this page again.) The composition of the present invention contains another main ingredient, Ce-34 higher fatty acid. The use of these fatty acids can generally improve the stability of the cosmetic composition of the present invention in a solid state. Specific examples of such fatty acids include, in addition to the above-mentioned examples of the constituents of the phosphonium esters, high-fluorinated fatty acids such as C6 hexanoic acid, Ce caprylic acid, or 2-ethylhexanoic acid, C10 capric acid, and Ci2 dodecanoic acid (lauric acid). Acid), c14 tetradecanoic acid, c16 hexadecanoic acid (palmitic acid), but does not exclude the addition of an odd number of carbon fatty acids, respectively. When using more county-linked fatty acids, the corresponding hydroxy fatty acids can be used, such as 12 -Hydroxy stearic acid, so the fatty acids referred to in the present invention include hydroxy fatty acids. The oil-in-water cosmetic composition of the present invention, based on the total weight, generally contains 0.1 to 10.0% by weight of higher fatty acids, and K 0.1 to 2.0 Amount% is better. These higher fatty acids can be a mixture of two 棰 Μ. Generally, when the high 鈒 fatty acid content is less than 0.1% by weight, the emulsification stability will decrease. On the contrary, when it exceeds 10.0% by weight, the final product will be Increased likelihood of problems with use stability. Indo Slave, Consumer Work Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs When the above-mentioned high fat and anti-acid are contained, the molar ratio of the higher fatty acid / amphoter surfactant is preferably 1:15 to 1: 0.8. At 1:15 K, emulsification is difficult, and when it exceeds 1: 0.8, an oil-in-water emulsion composition cannot be formed. The composition of the present invention may contain one of the ingredients described later mixed with other cosmetics. 11 The paper size is in accordance with the Chinese National Standard (CNS) Α4 condition (210 × 297 mm) 6 4 45 0 8 r _ ψγ · ψ {^ \ λι __Λ- ”B 7 V. Description of the invention (β) (Please read first Note on the back of this page and fill in this page again.) For example, in order to maintain the stability of the solid state and improve the feeling of use, you can use the higher (long-chain) hydrocarbons contained in natural wax and their physical properties. Usually the melting point is above 50C. Specific examples include melanosides such as pentacosane, heptacosane, 31-dodecane, dodecane, squalene, etc., Brazilian palm wax, candelilla tincture, and other animal and vegetable oil derivatives. There are also hydrogens, such as squalane, and the like. As long as these hydrocarbons have no adverse effect on the physical properties of the composition of the present invention, they may be added in an amount exceeding the aforementioned wax ester, for example, they may be used in an amount exceeding twice as much. Therefore, for example, the composition of the present invention may be suitable for use of candelilla wax. Furthermore, depending on the purpose of the cosmetic product of the present invention, for example, increasing the hardness of the final molded product, preventing cracks, and preventing water volatilization, or Specific effects during use, such as anti-ultraviolet rays, skin absorption, pore shielding, and mosquito remediation, can contain more than one ingredient. Specific examples of the printing of consumer cooperatives by employees of the Central Government Bureau of the Ministry of Economic Affairs include silicone oil, cool oil (semi-solid ester), higher alcohols, water-soluble polymers, ethylene glycol or glycerol fatty acid esters, titanium oxide and Spherical powder. Specific examples of the silicone oil include trimethylsiloxysilicic acid-decamethylcyclopentasiloxane, dimethylpolysiloxane and the like. This ingredient can be added to solid cosmetics alone or in combination. It is usually more expensive, and generally contains 0.1 to 40% by weight. The compounding method can be added to the oil phase during preparation (example). The addition of these ingredients has a rib to enhance the hardness of solid cosmetics. 0 _ 1 2-This paper is applicable to the standard of the Chinese standard (CNS), and the standard is (2! 0 × 297 mm). A7 B7 6 4 5 0 8 V. Description of the Invention (,,) (Please read the notes on the back before filling out this page) Specific examples of ester oils (semi-solid wax esters) can have C8 -24 saturated or unsaturated higher fatty acid derivatives and C 14-24 esters of saturated or unsaturated homoalcohol-derived moieties are used as ester moieties. The fatty acid constituting the fat portion includes the aforementioned saturated fatty acid having a corresponding carbon number or the corresponding unsaturated fatty acid, and the alcohol portion also includes a straight or branched chain, a saturated or unsaturated long or short composition having a corresponding carbon number. Of alcohol. Any fatty acid ester composed of these fatty acid portions and alcohol portions can be used. The amount used is based on the total weight of the solid cosmetic, generally 0.01 to 3.0% by weight. The compounding method is usually added to the oil phase during preparation. The addition of these ingredients helps prevent cracking of solid cosmetics. Specific examples of the higher alcohol include C16-22 saturated fatty alcohols or saturated fatty ether-fatty alcohols. More specifically, there are C16 cetyl fermenter, Cis stearyl alcohol, C22 mountain alcohol, Cis-0-C3 semideep alcohol, and the like. The method of addition is usually to add and dissolve in the oil phase under heating. The amount of the solid cosmetic used is based on the total weight of the solid cosmetic, and is generally 0,005 to 2.0% by weight. These ingredients can be used alone or as a mixture. They are often ribbed to prevent the water from evaporating from the cosmetics. Specific examples of water-soluble plutonium molecules printed by the staff of the Central Standards Bureau of the Ministry of Economic Affairs, including hydroxyethyl cellulose, hyaluronic acid, high-polymer polyethylene glycol, xanthan gum, poly (meth) acrylic acid, and methyl cellulose , Alkali alcohols, such as sodium salt, potassium salt, etc., of polyvinyl alcohol, dextran sulfuric acid, dextran sulfuric acid, polyvinylyangrolidine, acacia gum, and osteoporosis. One or two or more of them are generally based on the total weight of the solid cosmetic product, and contain 0.001 to 3.0% by weight, though they are ribbed to prevent the water from volatilizing from the solid cosmetic product. The compounding method is usually to apply the Chinese National Standard (CNS) Λ4 specification (2 丨 0X 297 male f) 6 4 45 0 8 β Α7 Β7 at the scale of the cosmetics paper. V. Description of the invention (water-in-oil emulsion lipstick (1) flow Paraffin (2) Castor oil (3) Dimethyl polysiloxane (100cs) (4) Camellia acid (5) Octyl hydroxystearate (6) Diisostearic acid (7) Red oxidation (8) Yellow Oxidation (9) Red 204 (10) Red 2 0 2 (1 1) Sodium Carboxymethyl Dividin (12) 1, 3-butanediase (1 3) Sorbitol (14) Methyl p-benzoate (15) Ion-exchanged water (16) 2-alkyl-N-carboxymethyl-N-hydroxyethyl 60. 0 89 5 01 (Please read the precautions on the back before filling this page) 0 20. 4. The imidazoline betaine (purity 30%) printed by the staff of the Central Standards Bureau of the Ministry of Economic Affairs was produced in the same manner as in Example 1. It was poured into a red horizontal type and cooled to obtain an emulsified lipstick. This α red was soft, dry, Non-sticky, usable. First application. Example ratio ... Comparative example 乳化 According to the formula shown in Table 1-2, the emulsified composition is made in the same manner as in Example 1. Among them, Example 5 is a water-in-oil type. milk胼. -19. This paper size is applicable to China National Standard (CNS) A4 ^ (210X297 mm) I amended to supplement this month I 9-? 〇I64508 A7 B7 V. Description of the invention (# The central standard of the Ministry of Economy Bureau-Industrial and Consumer Cooperation and Printing • it ^ BIIIlrs ^^ iNhglhgicstHntfl'vi / ^ fal / 'i ^ r ^ ERL-r ^ lifE & nl ^^ aJieBn) I 00 shows one by one: 洚 洄 a trend ! ±± U31 58 H- + ± H- 55 S each 6 < 0OT30001private 107 73 + + + + + ++ + i + ii ±± 屮 ++++++ ±± -f-fflsiist ^ Iridium 苕 苕 爷 苕 _Zhao Zhao 2—ZWDJ Tan Jian Jian Fu Fu 4Z: Zou Zou Tian Miao 卅 Interpretation and Translation of Miscellaneous + U 卅 园 筘 »谌 藤 赵 (赵) E ^ raw 0 ^ 0 Book Chrysanthemum NhsBmlrspsBi * 15.8 13.0015.3 15.3 15.3 15.3 15.6 15.cri15.6 15.6 13.00 〇 2.0 000000000 00 0.5 00000000 000 0.5 0000000 Ο 〇.〇〇0.5 〇 00 Ο ο 〇 00000 0.5 00000 000000 0,2 0000 0000000P2 000 00000000 0.2 00 000000000 0.2 ο 〇〇〇〇〇〇〇〇〇〇〇〇2.0 18 1 g 20 21 22 23 2 Ren 25 2B 27 mlo (Please read the precautions on the back before filling this page) This paper size applies to the Chinese national ladder (CNS) (Specification (210X297g) 464508)] Α7 This month gi Β7 ^ 83. 9. 20 J V. 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Abstract of Chinese Invention (Name of the invention: solid cosmetic composition and solid cosmetics) A solid cosmetic composition composed of water and wax Esters and other cosmetics use more than one composition, containing (: 18.34 fatty acids and C18_34 higher alcohol esters, amphoteric surfactants, and c18.34 higher fatty acids. Intermediate composition for cosmetics and its final products can be provided. It has physical and chemical properties that are superior to muscles and can be stored stably, especially for foundation, lipstick, eye shadow, etc. English Abstract of Invention (Name of the Invention:) COMPOSITION FOR OIL-IN-WATER TYPE COSMETIC A composition includes water, wax ester and. At leas t one which is the other component used in cosmetic, which contains Cig _ ^ ai iphat ic acid- C (fi _ ^ higher a 1 coho 1 ester and amphoteric surfactant, further contains C ^ higher aliphatic acid. This invention provides an intermediate composition for cosmetic having an excellent in feeling Co skin and physical-chemical properties in keeping stably, which is especial 1 y effectively used in foundation, lip-stick, eyeshadow etc., and the above-ment ioned final product (-2-d 6 45 0 8 ........ | [ί ^ Τ 7. · 3 Ⅵ. Application for Patent No. 84107822 "Solid Cosmetics Composition and Solid Cosmetics" Patent (Amended on July 31, 1990) VI. Patent Application Scope: 1. A solid cosmetic composition, composed of Oil-in-water cosmetic composition composed of water, wax ester, and one or more other cosmetic ingredients. Based on the total weight of the product, it contains: (A) 0.1 to 10.0% by weight of one or more wax esters, the constituents of which have a portion derived from Cl8.34 high carbon number fatty acid, and a portion derived from C18_34 high carbon number fatty alcohol And (B) 0.5 to 10.0% by weight of one or more amphoteric surfactants selected from the group consisting of amidobetaine, amidosulfobetaine, betaine, sulfobetaine, and imidazoline. 2. A solid cosmetic composition, which is an oil-in-water cosmetic composition composed of water, ethyl ester, and one or more other cosmetic ingredients, based on the total weight of the composition, containing: (Α) 0.1 to 10.0% by weight of one or more wax esters, the constituents of which have a Ci8_34 high carbon number fatty acid derived portion, a C18.34 high carbon number fatty alcohol derived portion, and (B) 0.5 to 10.0% by weight of one or more amphoteric surfactants selected from the group consisting of amidobetaine type, amidosulfobetaine type, betaine type, sulfobetaine type, and imidazoline type, and (C) Ol to 2.0 C6_34 high carbon number fatty acid. 6 45 0 8____ j Revision i This year Λ a Supplement 9 (U0 ·-3 VI. Those who apply for patent scope silicon oxygen institute. 8. If you apply for the solid cosmetics of the scope of patent No. 6, the ester oil (or semi-solid wax ester) ) Contains more than one kind of esters, and its constituents have C8_24 saturated or unsaturated high carbon number fatty acid derived parts, and C14.24 saturated or unsaturated high carbon number alcohol derived parts. 9. If applying The solid cosmetics of item 6 of the patent, wherein the high carbon number alcohols are C] 6.22 saturated fatty alcohols or saturated fatty ether-fatty alcohols. I 0. The solid cosmetics of item 6 of the patent application, wherein the water-soluble polymer It is more than one kind selected from hydroxyethyl cellulose, hyaluronic acid, highly polymerized polyethylene glycol, xanthan gum, poly (meth) acrylic acid, methyl cellulose, polyvinyl alcohol, dextran sulfate, chondroitin sulfate, poly Vinylpyrrolidone, and gum arabic. II. The solid cosmetics such as the scope of application for patent No. 6 in which ethylene glycol or glycerol fatty acid esters are glycol diesters of C18.3Q saturated fatty acids, or C18 .3 () Three of saturated fatty acids One or more types of oil esters. 1 2. The solid cosmetics as claimed in item 6 of the patent application, in which titanium oxide is a combination of two or more kinds of ultrafine particles, plate-shaped and needle-shaped titanium oxides. The solid cosmetic of item 6, wherein the spherical powder is one or more selected from the group consisting of spherical silica, spherical nylon powder, spherical soft polyalkyl acrylate, cross-linked polystyrene-squalane mixed powder, cellulose powder, Anhydrous silicic acid powder and methylsilane network polymer.