TW461125B - Organic inorganic hybrid light emitting diode device - Google Patents

Organic inorganic hybrid light emitting diode device Download PDF

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Publication number
TW461125B
TW461125B TW89127817A TW89127817A TW461125B TW 461125 B TW461125 B TW 461125B TW 89127817 A TW89127817 A TW 89127817A TW 89127817 A TW89127817 A TW 89127817A TW 461125 B TW461125 B TW 461125B
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Taiwan
Prior art keywords
light
emitting diode
organic
inorganic
excited
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TW89127817A
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Chinese (zh)
Inventor
Shu-Wen Sung
Ming-Shiun Shie
Jiuan-Ming Jang
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Epistar Corp
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Priority to TW89127817A priority Critical patent/TW461125B/en
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Publication of TW461125B publication Critical patent/TW461125B/en

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Abstract

An organic inorganic hybrid light emitting diode device includes an inorganic light emitting diode die capable of emitting light of a first wavelength range, and an encapsulating material containing an organic material capable of emitting light of a second wavelength range after being excited. The light emitting diode die is encapsulated inside the encapsulating material. Light in the range of the second wavelength is generated when the organic material in the encapsulating material is excited by part of the light in the range of the first wavelength transmitting through the encapsulating material. Light range of the third wavelength is generated when the other part of the light in the range of the first wavelength emitted by the light emitting diode die is transmitting through the encapsulating material and mixed with the light in the range of the second wavelength.

Description

461125 五、發明說明(1) 發明之領域 本發明係關於一種發光二極體,尤其關於 機混合式發光二極體,特別關於一種有機無機 發光二極體器件。 相關技藝之說明 發光二極體之應用頗為廣泛,例如,可應 示裝置、交通號誌、資料儲存裝置、通訊裝置 置、以及醫療裝置。發光二極體中潛在需求量 要者’為白色發光二極體,若能夠降低白色發 生產成本’並增長其使用壽命,則有可能取代 用之白.色螢光燈管或燈疼。 目前市面上最常見的白色發光二極體係利 二極體與輦光材料組合而成,其原理係利用藍 體晶粒所發射之藍光激發螢光材料,使後者產 混合原來的藍光而成為白光。 此先前技藝白色發光二極體之一主要缺點 裝發光二極體晶粒之前.,必須使螢光材料與個 體晶粒组合’因而造成複雜之製造程序,進而 生產成本。 該先前技藝白色發光二極體之另一缺點在 極體晶粒所發出之藍光中有一部分未透過螢光 接由發光二極體晶粗之側邊射出’故未能完全 所發出之黃光現合,因而光線混合不均勻之缺 發明概要 一種有秦無 混合式白色 用於光學顯 、照明裝 最大且最重 光二極體之 目前大量使 用藍色發光 色發光二極 生黃光,俾 在於:在封 別發光二極 導致高昂之 於:發光二( 材料,而直 與螢光材料 點。461125 V. Description of the invention (1) Field of the invention The present invention relates to a light-emitting diode, especially to an organic hybrid light-emitting diode, and particularly to an organic-inorganic light-emitting diode device. Description of related technologies Light-emitting diodes are widely used, such as display devices, traffic signs, data storage devices, communication devices, and medical devices. Potential demand for light-emitting diodes The main one is a white light-emitting diode. If it can reduce the production cost of white hair and increase its service life, it may replace white fluorescent tubes or lamp pain. At present, the most common white light-emitting diode system on the market is a combination of a diode and a phosphorescent material. The principle is to use the blue light emitted by the blue body grains to excite the fluorescent material, so that the latter produces a mixture of the original blue light and becomes white light. . One of the main disadvantages of this prior art white light-emitting diode is that before the light-emitting diode grains are mounted, the fluorescent material must be combined with the individual crystal grains', which results in a complicated manufacturing process and thus production costs. Another disadvantage of this prior art white light emitting diode is that a part of the blue light emitted by the crystal grains of the body does not pass through the fluorescent light and is emitted from the thick side of the light emitting diode crystal, so the yellow light cannot be completely emitted. Now, there is a lack of uneven light mixing. SUMMARY OF THE INVENTION A hybrid white with Qin and non-light is used for optical display, the largest and heaviest light-emitting diode. The blue light-emitting color light-emitting diode produces yellow light. : Luminous Diode in Fengbei leads to a high price: Luminous Di (material, while straight with fluorescent material dots.

第4頁Page 4

461125 五、發明說明(2) 本發明之一目的在於提供一種 發光一極體 料係由環氧樹脂與受激=以以3 I以色:=裝習…色發以^461125 V. Description of the invention (2) One of the objects of the present invention is to provide a light-emitting polar material made of epoxy resin and stimulated = to 3 I to color: = dressing ... color hair to ^

Alq3產生黃★,該藍色^光_ =出藍★中之—部分激發該 ^王兴元.該1色發先一極體晶粒所發出藍弁 餘》卩为透過該封裝材料與該黃光混合而, 合,故製造程序簡單’因而能夠降低生產成本。體曰曰拉組 ^發明之另一目的在於提供一種白色發光二抑 件,广中之封裝材料係由環氧樹脂與受激妒土= A: 3 ,合而成,以此種封裝材料封裝習用:^ ::= 體晶粒,此藍色發光.二極體晶粒所發出藍光^發^一極 產生黃光,該藍.色發光二極體晶粒所 藍色發光二極體晶粒所發出之所有藍光皆透 二: 射出,故能夠避免先前技藝光線混合不均勻之缺點材枓 無機各I:器: 处私欲山朴件包含—無機發先二極體曰耠 月匕夠發出監光;以及一封裝材料,係由環炉阳, 能夠發黃光之Alq3混合而成,其中該發光二與受激後 裝於該封裝材料中,且該藍光透過該封裝:料:晶::封 一部分激發該Alq3產生黃光,該藍色發光二舻曰八中之 出藍光中之其餘部分透過該封裝材料與該i光混=粒所發 461125 五、發明說明(3) 詳細說明 首先說明本發.明之概令:士政' 榀鲈突杜 心本發明提供一種白色發先二 極體器件’其中之封裝材料俜由擇 龙本夕A ] nq、?入而士 糸由環氧樹脂與受激後能夠發 汽光之A 1 q3混口而成,以此種封奘 # -搞辨曰勒,μ „ , 裡訂装村科封裝習用之藍色發 先一極體日日拉,此藍色發光二極體曰 卹八、虹益兮A 1 Q本Λ 4 但體日日粒所發出藍光中之一 藍光,該藍色發光二極體晶粒所發出 ί :ϊ ί:ϋ 裝材料與該黃光混合而產生白 “:二”念並不限於用以產生白★,用以產 生_其他顏色之混合光線亦.無不可。 右撤ΐί前段所述之發明概念,依本發明一較佳實施例之 有機無機混合式發光二極體器件,如圖丄中所示,包含一 =用藍色無機發光二極體晶粒2〇,此晶粒2〇包含形成於一 基板21上方之一氮化鎵系疊層構造、一ρ型電極28、一η 電極29,ρ型電極28經由一導線丨3連接於一第一導電元件 U之一突出部11a上,η型電極29經由一導線丨3連接於一第 =導電元件12,封裝材料14係由環氧樹脂與受激後能發 頁光之A 1 q 3混合而成。 顯然’該藍色發光二極體晶粒之製造程序簡單較前述 先前技藝者簡單,且其所發出之所有藍光皆透過該封1材 料射出’故能夠避免前述先前技藝製造程序複雜與光^混 合不均勻之缺點。 、 以上所述者,僅為用以方便說明本發明之一較佳實施 例’本發明之範圍不限於該較佳實施例,凡依本發明所做 的任何變更’皆屬本發明申請專利之範圍。例如,使封裝Alq3 produces yellow ★, the blue ^ light _ = out of blue ★-partly excite the ^ Wang Xingyuan. The 1-color hair first issued by a polar crystal blue 弁 卩 弁 卩 is through the packaging material and the yellow light Mixing and combining, so the manufacturing process is simple 'and thus can reduce production costs. The body group is another object of the invention is to provide a white light emitting suppressor. The packaging material of Guangzhong is made of epoxy resin and stimulated jealous earth = A: 3, and is packaged with this packaging material. Conventional: ^ :: = bulk crystal, this blue light emitting. The blue light emitted by the diode crystal ^ emits yellow light at one pole, the blue light emitting diode crystal by the blue. Color emitting diode crystal All the blue light emitted by the granules are transparent: It can be emitted, so it can avoid the disadvantages of uneven mixing of light in the previous technique. Materials: Inorganic components: Included in the desires of the mountain. Inorganic hair-producing diodes can be emitted. Monitoring light; and a packaging material, which is a mixture of Alq3 that can emit yellow light, and the light emitting diode 2 is excited and loaded into the packaging material, and the blue light passes through the packaging: material: crystal :: seal One part stimulates the Alq3 to produce yellow light, and the other part of the blue light emitted from the blue light emitting medium is mixed with the i light through the encapsulating material. The invention is issued by the particle. Fat. Ming's Order: Shizheng's Batu Duxin This invention provides a White hair first diode device 'forlorn wherein the encapsulating material present by a majority Long Xi A] nq ,? In addition, 糸 糸 is made of epoxy resin and A 1 q3 which can emit steam after being stimulated. This kind of seal is used to seal #-to identify Yuele, μ „, custom blue used in village packaging. The first light-emitting diode is pulled, the blue light-emitting diode is called the eight, Hong Yixi A 1 Q Ben Λ 4 but one of the blue light emitted by the sun-grain is blue, and the blue light-emitting diode is blue. The ί: ϊ ϋ: ϋ mixed with the yellow light to produce white ": 二" is not limited to the use of white ★, and it is also used to produce _ other colors of mixed light. Nothing is impossible. The inventive concept described in the previous paragraph, according to an organic-inorganic hybrid light-emitting diode device according to a preferred embodiment of the present invention, as shown in FIG. The die 20 includes a gallium nitride-based stacked structure formed on a substrate 21, a p-type electrode 28, and an n-electrode 29. The p-type electrode 28 is connected to a first conductive element U through a wire 3 On a protruding portion 11a, the n-type electrode 29 is connected to a first conductive element 12 through a wire 3, and the packaging material 14 is made of epoxy resin and excited. A 1 q 3 of the light emitted from the page is mixed. Obviously, the manufacturing process of the blue light-emitting diode grains is simpler than that of the previous artist, and all the blue light emitted by it is emitted through the seal 1 material. It can avoid the disadvantages of the complex manufacturing process and the uneven mixing of light and light in the prior art. The above is only for the convenience of describing a preferred embodiment of the present invention. The scope of the present invention is not limited to the preferred embodiment. Any changes made according to the present invention are within the scope of the present invention patent application. For example, making the package

第6頁 461125 五、發明說明.(4) — —_____〜 材料U Ϊ Ϊ氧樹脂與受激後能夠發綠光之Alq3混合而出 :此種:裝材料14封裝習用之無機紫外光發光二:’ 九一極體日日粒所發出紫外光中之一八 乂 u q產生綠光;或使封裝材料14由環氧樹脂成刀數 能夠發黃光之p p V爭人物、、曰人 、文數後 驻羽m ^ 聚合物此合而成,以此種封裝#料14封 裝I用之無機藍色發光二極體晶粒,此藍色發封 所赞出成光中之一部分激發該ppv聚合物產生黃光,嗲 ^色發光二極體晶粒所發出藍光中之其餘部分透過該封裝 材料與該黃光混合而產生白光,顯然皆不脫離發明 神與範圍。 啊Page 6 461125 V. Description of the invention. (4) — — _____ ~ Material U Ϊ Phenoxy resin is mixed with Alq3 which can emit green light after being excited: This type: Packing material 14 is used for inorganic UV light emitting. : 'One of the ultraviolet light emitted by the nine-day polar sun and the sun ’s rays produces green light; or the encapsulation material 14 is made of epoxy resin and can emit yellow light. The resident feather m ^ polymer is combined to form an inorganic blue light-emitting diode grain used in this package # 料 14 to encapsulate I. The blue hair seal praises part of the light to excite the pPV polymer. Yellow light is generated, and the rest of the blue light emitted by the 嗲 -color light-emitting diode grains is mixed with the yellow light through the packaging material to generate white light, obviously without departing from the spirit and scope of the invention. what

Claims (1)

461125 六、申請專利範圍 ' 1. 一有機無機混合式發光二極體器件,包含: 一無機發光二極體晶粒,能夠發出第一波長範圍 線,以及 -ί:;!;:;;晶粒係封裝於該封裝材料中,且該第 及長軏圍之先線透過該封 ^弟 該封裝材料中之該有機材料,峰勢楚其中之一部分激發 線,該發光二極體晶粒所發=該第二波長範圍之光 餘部分透過該封裝材料與該::線中之其 生第三波長範圍之光線。乐—波長粑圍之光線混合而產 2.依申請專利範圍第丨項之 盔罕 恭 ^ ^ t ^ ^ t ^ ^ ^ 1 二波長範圍光線之Alq3混合而:、又激後此夠發出該第 3件依ΓΪ專利範圍第1項之有機無機混合式發光二極體器 一 ^中該封裝材料係由環氧樹脂與受激後能出 —波長範圍光線之PPV聚合物混合而成。 出該第 .—有機無機混合式發光二極體器件,包含: 一無機發光二極體晶粒,能夠發出藍光;以及 材料I::::係由環氧樹脂與受激後能夠發黃光之有機 第9頁 #4 6112 5 六、.申請專利範圍 二1::ί 一極體晶粒係封裝於該封裝材#中’且該藍 立“ ^封裝材料時,其中之一部分激發該有機材料產生 Κ光、藍色發光一'極體晶粒所發出藍光中之其餘部分透 過該封裝材料與該黃光混合而產生白光。 第光造 圍發構 範機層 利無疊 專該系 請中鎵 申其化 依.,氮 •件 一 5 yl 一 無 機 有 之 項 器 體 極 二 光 發 式 合 混 之 方 上 板 基 一 於 成 形 含 包 粒 晶 體 極 6.依申請專利範圍第4項之有機無機混合式發光二極體器 件,其中該封裝材料係由環氧樹脂與受激後能夠發出黃光 之A 1 q 3混合而成。 7··依申請專利範圍第4項之有機無機混合式發光二極體器 件’其中該封裝材料係由環氧樹脂與受激後能夠發出黃光 之PPV聚>物混合而成。461125 VI. Application for patent scope '1. An organic-inorganic hybrid light-emitting diode device, including: an inorganic light-emitting diode crystal grain, capable of emitting a first wavelength range line, and -ί:;!;: ;; crystal The granules are encapsulated in the encapsulation material, and the first line of the first and the second pass through the organic material in the encapsulation material, one of the peaks excites the line, and the light emitting diode grains are The remaining part of the light in the second wavelength range passes through the packaging material and the light in the third wavelength range in the: line. Music-produced by mixing light with a wavelength of 2. Surrounding the helmet according to item 丨 of the patent application ^ ^ t ^ ^ t ^ ^ ^ 1 Two-wavelength range of light is mixed with Alq3: and then excited enough to emit this The third organic-inorganic hybrid light-emitting diode according to the first item of the scope of the patent, the packaging material is a mixture of epoxy resin and PPV polymer that can emit light in the wavelength range after being excited. The first.—Organic-inorganic hybrid light-emitting diode device, including: an inorganic light-emitting diode crystal grain, capable of emitting blue light; and the material I :::: is an organic resin that can emit yellow light after being excited by an epoxy resin Page 9 # 4 6112 5 VI. Scope of patent application 2: 1: When a polar crystal is encapsulated in the encapsulation material # and the blue material is encapsulation material, one part of it excites the organic material to produce The remaining part of the blue light emitted by the K light and blue light-emitting polar crystal grains passes through the packaging material and is mixed with the yellow light to generate white light. Its chemical reliance. Nitrogen, a 5 yl, an inorganic item, a body pole, a light-emitting type, a square base plate, and a shaped crystal with a coated particle. 6. An organic and inorganic material according to item 4 of the scope of patent application. The hybrid light-emitting diode device, wherein the packaging material is a mixture of epoxy resin and A 1 q 3 that can emit yellow light after being excited. 7. · Organic-inorganic hybrid light-emitting diode according to item 4 of the scope of patent application Body device 'where The packaging material is made by mixing epoxy resin with PPV polymer which can emit yellow light when excited.
TW89127817A 2000-12-21 2000-12-21 Organic inorganic hybrid light emitting diode device TW461125B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7169326B2 (en) 2003-03-28 2007-01-30 South Epitaxy Corporation Fluorescent material of terbium aluminum garnet and producing methods therefor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7169326B2 (en) 2003-03-28 2007-01-30 South Epitaxy Corporation Fluorescent material of terbium aluminum garnet and producing methods therefor

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