TW444076B - Environmentally friendly water resin moisture-permeable water-proof processed fabric and the process method - Google Patents

Environmentally friendly water resin moisture-permeable water-proof processed fabric and the process method Download PDF

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TW444076B
TW444076B TW87108984A TW87108984A TW444076B TW 444076 B TW444076 B TW 444076B TW 87108984 A TW87108984 A TW 87108984A TW 87108984 A TW87108984 A TW 87108984A TW 444076 B TW444076 B TW 444076B
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Taiwan
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resin
coating
water
moisture
permeable
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TW87108984A
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Chinese (zh)
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Yi-Guang Chen
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Chen Yi Guang
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Abstract

This invention describes the environmentally friendly water resin moisture-permeable water-proof processed fabric and the process method which utilizes foam coating process for the underlying layer coating and hydrophilic water PU resin to perform paste coating on the surface layer. This can enhance the touch and fullness feeling and high moisture permeation of the fabric due to the foaming effect. The use of hydrophilic PU resin for paste coating can also render the fabric of water-proof and abrasion resistant characteristics. Compared with traditional solvent resin coating, better touch feeling, water pressure resistance and abrasion resistance can be achieved by the present invention. The product value is improved by replacing traditional solvent resin coating with hydrophilic water resin coating and thus granting the fabric excellent properties and environmentally friendly concept.

Description

444 0 7 6 Λ7 R7 經濟部中央標华局負工消资合作社印5ί 五、發明説明( 本發明係有關一種塗佈織物表層以親水性水性樹脂代替溶劑型 ,脂,以泡沫型PU樹脂作為織物之底層,以合乎環保需求之塗佈 產品。 II般傳統型的塗佈加工布,為一種以溶劑型樹脂直接塗444 0 7 6 Λ7 R7 Printed by the Central Standardization Bureau of the Ministry of Economic Affairs, Consumers and Consumers Cooperatives 5ί 5. Description of the invention (The present invention relates to a coating fabric with a hydrophilic water-based resin instead of a solvent-based, grease, and a foam-type PU resin as The bottom layer of the fabric is a coated product that meets environmental protection requirements. The traditional type II coated processing cloth is a direct coating with a solvent-based resin.

产’曰而完成一種透濕'防水產品,其織物透濕度介於 00〜3000g/m之間、耐水壓介於〇〜】〇_mni之間,若單以泡沫型PU ΐϊί接塗Ϊ於布上’其透濕度高㈤水性差,若單以水性PU樹脂 直,塗佈於布上,其透濕度與耐水性皆比前述溶劑型樹脂塗佈差, 脂對於近年環保意識抬頭下,無非是一種 之且織物經由塗佈後,其溶劑型樹腊塗佈於表層後織物 ΐΐϋΐ磨3防水性與親水性水性樹脂塗佈於表層後織物之物 軚較差,亦δ—般傳統型織物不具有環保性與織物物性的優異 ★ τif上缺失改進而創新一種『環保水性樹脂透濕防水 口布及八加工方法』’為一種創新之塗佈加工,主要係於 水性樹脂作為塗佈層,為環保性的水性樹脂作為織 ^ “而所經由塗佈之織物具有高透濕度及高对水壓產 市i首1^射^廣,例如;衣料用布(衣服、褲子)、醫療用 早頭套及防水貼膜)及休閒用布(帳蓬、睡袋、鞋子、帽子、 反V、乐布及手套)。 s v 進—步說明本創作之技術内容,配合以下表㈠及圖示說 【圖示】: 表(一)係為本創作各實施例與比較例布之性質測試夷 弟一圖係為本創之塗佈加工圖 y—圖係為本創作之塗佈結構分解圖 第二圖係為本創作之塗佈實施例圖 【圖號】: 1’1 布 1-2 發泡塗佈層 1-3 透濕防水塗佈層 ㈧ 底層塗佈加工 ⑻ 表層塗佈加工 本紙ίίί尺度通用中阗家標芈(CNS ) Λ4坭格(2丨ϋΧ297公廣) (靖无閱讀背*之注意事項再填寫本頁} j‘-訂 ~ 線 \ 444076 \五、發明説明( ~ Λ7 B7 經濟部中央標準局员工消f合ΐ"ί!?裝 本發明之『續保水性樹脂透濕防水加工布及其加 r第—圓為本發明之加工念程^ ^ ΐ隆平織規格布經由退裝、精練、染色 及預疋31伋並且,以壓吸率5〜25%作撥水處理,以1〇〇它〜丨2〇。〇 ίΐίΐΐ,乾時間為45秒〜1分。上述前處理過之财隆平織 塗佈其塗佈量為70〜200g/ni,於樹腊中添加 棬么气乂lr: %整泡劑及1〜5%增稠劑,此泡沫塗佈係利甩 方法加入水性樹脂使產生起泡体,再塗佈於織物表面第一層 f 細,再麵6(M5()t之溫錄雜擠壓之, 此種塗佈方法具有尚透濕度及耐水壓之優點,並且’使用之塗樹 烯酿醋(ACRYLATES)樹脂、聚尿醋樹腊、乳膠(丁二烯 型聚合物)樹脂、矽利康彈性體樹脂及乙烯基醋酸醋樹並 丙烯醯醋(ACRYLATES)樹脂(1:3〜1:6)、聚尿輯脂=七、發^匕 膠(丁二烯型聚合物)樹脂(1:3〜1:5)、矽利康彈性體樹脂(1:3〜1及 基酯酸酯樹脂(1:3〜1:5) ’此進行底層塗佈可得耐水壓2〇〇mm 十〇以上與透濕度5〇〇〇 g/m7Day以上,再於第二層(表層)(1_3)利用 夺游刮刀(knife 〇丨1 air)塗上水性(p〇lyukeTHANE)樹脂(SE_928昆 ,樹脂工業股份有限公司商品名)以塗佈量5〜2〇〇g/ni進行表層之塗 你,於樹脂中添加I〜丨〇%三聚氰胺系架橋劑、2〜8%陰離子界面活性 劑及2〜5%增稠劑,再經60〜150°C/0.5〜1.5分之乾燥並於120〜200°C /0.5〜2·5分之硬化條件下進行硬化處理而完成耐水壓5〇〇〇mmH2〇 ^亡與透-度5000 g/m7Day以上之高耐水壓與高透濕度之產品,如 苐二圖所示之塗佈加工層可得如第三圖所示之三層不同結構之織物 加工布(1-1)發泡塗佈層(〗_2)及透濕防水塗佈層(Η)。 兹為了使審查工作者更加明瞭本創作之發明特以實施例及比較例說 明本創作如下: 【實施例1】 以财隆平織物經退漿 '精練、染色及預定型而進行壓吸率為5〇/〇 之撥水處理,爾來以110 °c的溫度進行烘乾其乾燥時間為50秒。 耐隆布(700乂700,124乂8丨)作為塗佈加工布,以下列之塗佈液 對織物以泡沫塗佈機進行底層第一次塗佈,而塗佈用樹脂為聚尿酯 (POLYURETHANE)樹脂,以發泡比(1:5 )、塗佈量為75 g/nf ’以 本紙ifc尺度適用中阐闽家標準(CNS ) Λ4规格(210X297公楚) 一^先關讀背齑之泣意事項再填寫本育) V-----1訂 444 〇7 6 A7 五 、發明説明( B7 經濟部中失標象局^:工消f合作社印- ( 一)、表層塗佈加工液 、i〇 ◦ X1分鐘進行烘乾,再以浮游刮刀(knife 〇n air)之塗佈加 执行表層塗佈之親水性塗佈加工,塗佈量150 g/ni隨後進入 二』Ϊ行80 °c X I分鐘及150 °C X1分60秒之熱處理工程,即得 迷濕防水加工布。 其^斤使用塗佈加工液如下: (―)、底層塗佈加工液: 聚尿酯樹脂 100 三聚氰胺系架橋劑 2% 起泡劑 50/〇 整泡劑 8% ,. 增稠劑 2% (―)、表層塗佈加工液: PU 樹脂(SE-928) 1〇〇 三聚氰胺系架橋劑 5% 陰離子界面活性劑 3% 增稠劑 2% 【實施例2】 前處理相同條件下’以耐隆布(70DX70DJ24X81)作為塗佈加 ΪμΪ經由前處理後,以下列之塗佈條件對織物以泡涞塗佈機進行 底曰第—次塗佈’而塗佈用樹脂為丙烯醯醋(ACRYLATES'^M1^ ,以 J泡3( 1:6)、塗佈量為l〇〇g/m2,以乾燥85 °CX1分鐘‘行扭 乾’再以浮游刮刀(knife on air)之塗佈加工方法進行表層涂怖八 水性塗佈加工,塗佈量145g/ni隨後進入烘箱進行90 145 eC X 1分6G秒之熱處理工程’即得-透濕防水加工布。刀’里及 其所使用塗佈加液如下: (一)、底層塗佈加工液: 丙稀S區S旨(ACRYLATES)樹脂 二聚氛胺乐架橋劑 4% 起泡劑 5% 整泡劑 8% 增稠劑 2% PU 樹脂(SE-92S) 本紙張尺度通用中國國家榡卒(CNS ) Λ4说格(21〇X 297公·^ ) 100 I— .*^1 f VH - —i.i · - -» ^ II I 1- - IJ ->--1 -/ 'l-SJ.* (請先閱讀背面之注意事項再填寫本耳} 444076 五'發明説明( 寸 B7 Λ7 硬化劑(ISOCYANATE) 5.5% 陰離子界面活性劑 3% 增稠劑 2% 【實施例3】 以前處理相同條件下,耐隆布(7〇£>><7〇][),124乂81)作為塗佈加 工布’以下列之塗佈條件對織物以泡沫塗佈機進行底層第一次塗佈, 而塗佈用樹脂為乳膠(丁二烯型聚合物)(LATEX butadiene_base POLYMERS)樹脂’以發泡比(1:4 5 )、塗佈量為7〇 ,以乾燥 M C X 1 $鐘進行洪乾’再以浮游刮刀細池〇n 士)之塗佈加工方法 ^行巧層塗佈之親水性塗佈加工,塗佈量140 g/m2隨後進入烘箱進 行95CX 1分鐘及155°CX1分50秒之熱處理工程,即得一透濕 防水加工布。 … 其所使用塗佈加工液如下: (一) 、底層塗佈加工液: 乳膠(丁二烯型聚合物 >樹脂 100 三聚氰胺系架橋劑 2.5% 增稍劑 2% (二) 、表層塗佈加工液: PU 樹脂(SE-928) 100 硬化劑 4% 陰離子界面活性劑 1.5% 增稠劑 2% 【實施例4】 以前處理相同條件下,耐隆布(70Dx70D,124x81)作為塗佈加 工以下列之塗佈條件對織物以泡沫塗佈機進行底層第一次塗佈: 而塗佈用樹脂為妙利康彈性體(SiUC〇NEELAST〇ME 樹脂,以 發泡比(1:3.5_)、塗佈量為90 g/ni ,以乾燥95亡X 1分鐘進行 烘乾,再以浮游刮刀(knife on air)之塗佈加工方法進行表層塗佈之 親水性塗佈加工,塗佈量135 g/πί隨後進入供箱進行9〇 t XI分 鐘及140 °C X I分60秒之熱處理工程,即得一透濕防水加工布。 本紙浓尺度適用中闽國家樣準(cns ) Λ4规格(2】0>:297公釐) \ -----ίτ -----]/ -----^-訂,‘ -請先閱讀背面之注意事項再填'寫本頁} 444 0 7 6 Λ 7 Β7 五、發明説明( 其所使用塗佈加工液如下: (―)、底層塗佈加工液: 矽利康彈性體樹脂 100 三聚氰胺系架橋劑 1% 增稠劑 2% (二)、表屈塗佈加工液: PU 樹脂(SE-928) 100 三聚氰胺系架橋劑 12% 陰離子界面活性劑 5% 增稠劑 2% 【實施例5】 以前處理相同條件下,耐隆布(70DX70D,124X81)作為塗佈加# 工布,以下列之塗佈條件對織物以泡沫塗佈機進行底層第一次塗佈| 而塗佈用樹脂為乙烯基酯酸酯(VINYL ACETATE)樹脂,以發泡比‘Γ (1:4.5)、塗佈量為80 g/πί,以乾燥85 °C X 1分鐘進行烘乾,兵| 浮游到刀(knife on air)之塗佈加工方法進行表層塗佈之親水性塗佈^ 加工,塗佈量130 g/rri隨後進入烘箱進行100 °C XI分鐘及130 X 1分60 秒之熱處理工程,即得一透濕防水加工布。 其所使用塗佈加工液如下: (一)、底層塗佈加工液: ' (二)、表層塗佈加工液: 乙烯基醋酸g旨樹脂 100 三聚氰胺系架橋劑 2% 增稠劑 2% PU 樹脂(SE-928) 100 三聚氡胺系架橋劑 8% 陰離子界面活性劑 3.5% 增铜劑 2% 【比較例ί 水紙ft尺度適圯中國囡家拣车(CNS ) Λ4况格(2lO_X2V·?公釐) Λ7 Β7 —--- 五、發明説明( (*請先閱讀背面之注意事項再填寫本頁) 以【實施例】前處理相同條件下,耐隆布(7〇Dx7〇D 124χ 塗佈加工布’以溶劑型PU樹脂浮游刮刀作第一次 塗佈其塗佈量為SOg/πί,以乾燥12〇 tXI分鐘進行烘乾,再以^ 游刮刀(krnfeonau·)之塗佈加工方法進行表層塗佈之親水性塗佈加 工,塗佈量120 g/m隨後進入烘箱進行12〇 t χ丨分鐘及15〇艺χ i 分60秒之熱處理工程,即得一透濕防水加工布,其耐水性及透 比【比較例2及3】更優。 没 其所使用塗佈加工液如下: (一)、底層塗佈加工液: (二)、表層塗佈加工液 溶劑型PU樹脂 100 異氰酸酯 5% M.E.K 45% D.M.F 15% 溶劑型PU樹脂 100 異氱酸酯 5% D.M.F 15% M.E.K 10% 【比較例2】: 以【實施例】前處理相同條件下,耐隆布(70DX70D,124X81)作 為重佈加工布,以泡沫型PU樹脂利用浮游刮刀(knife on air)作塗佈 加工’其塗佈量為90g/rri,以乾燥90 °CX1分鐘進行烘乾,再150 °C X2分鐘作熱處理,如此可得耐水性差透濕度高之加工布。 其塗佈加工液如下:. 泡沫型PU樹脂 100 起泡劑 5% 整泡劑 8% 增稠劑 2% 【比較例3】: 本紙张尺度遍』Π中囤國家樣丰(CNS〉Λ4说格(2丨0x;j97公楚 Λ44076 Λ7 B? 五 發明説明( 作為^ίϊί】相同條件下’耐隆布(勘幻⑽似謂) 作i佈加工其塗佈9。'° ?爾犯—928)利用浮游到刀(knife on air) 再幻5。燥⑽。⑶分鐘進行供乾, 其塗佈加工液如下:程 親水型^水性PU樹脂(SE-928) 100 —4氣胺乐架橋劑 ό % 增稠劑 2% 壓(依請比較表中表格内數據顯示,靖水 作比較,從3透〉ί度(依耶心1099^1法測試)的數據 11 仔知織物雖具有高透濕度與低耐水壓,但 水壓及透濕度卻比【比較例2及3】更優,以【比 施命ί較優。、Ά數據與【實糊1〜5】比較㈣祕及透濕度以實 壓之及ΐ佈層之特性上彳ί改進,可獲得高透濕度及高耐水 豐厚^手蠢了,比一般加工液之塗佈所獲得之產品更優且產品具有 (請先閱讀背面之注意事項再填寫本頁} -裝- -訂It can produce a moisture-permeable waterproof product. The moisture permeability of the fabric is between 00 ~ 3000g / m, and the water pressure resistance is between 〇 ~] 〇_mni. If it is only coated with foam PU ΐϊ On the cloth, its moisture permeability is high and its water resistance is poor. If the water-based PU resin is applied directly to the cloth, its moisture permeability and water resistance are poorer than those of the aforementioned solvent-based resins. The grease has increased its environmental awareness in recent years. It is a kind of fabric and after coating, its solvent-based wax is coated on the surface layer, and the fabric is honed. 3 Water resistance and hydrophilic water-based resin are poor on the fabric after coating on the surface layer. It has excellent environmental protection and physical properties of the fabric. ★ τif lacks improvement and innovation. A "environment-friendly water-based resin moisture-permeable waterproof cloth and eight processing methods" is an innovative coating process, mainly based on water-based resin as the coating layer. Environmentally-friendly water-based resins are used as weaving ^ "and the coated fabric has high moisture permeability and high water pressure. It is widely used, for example; cloth for clothing (clothing, pants), and early medical hoods And waterproof film) and leisure (Tent, sleeping bag, shoes, hat, anti-V, music cloth, and gloves). Sv further explains the technical content of this creation, with the following table and illustrations [picture]: Table (1) is based on The properties of each of the examples and comparative examples of the cloth are tested. The first picture is the coating process drawing of this creation. The picture is the exploded view of the coating structure of the creation. The second picture is the illustration of the coating embodiment of the creation. [Picture No.]: 1'1 Cloth 1-2 Foam coating layer 1-3 Moisture-permeable waterproof coating layer ㈧ Bottom coating processing ⑻ Surface coating processing paper ίίί Common Chinese Standard House Standard (CNS) Λ4 坭Grid (2 丨 ϋ297297) (Jing without reading the notes on the back * Please fill out this page again} j'-Order ~ Line \ 444076 \ V. Description of the invention (~ Λ7 B7 Employees of the Central Standards Bureau of the Ministry of Economic Affairs " ί !? The "continued water-repellent resin moisture-permeable waterproof processing cloth and its addition of the first round of the present invention are the processing ideas of the present invention. In addition, a water repellent treatment was performed at a pressure absorption rate of 5 to 25%, and it was 100 to 200. The drying time was 45 seconds. 1 point. The pre-treated Cailong plain weave coating has a coating amount of 70 ~ 200g / ni, and 棬 mochi 乂 lr:% foam stabilizer and 1 ~ 5% thickener is added to the tree wax. This foam The coating method is a method of adding a water-based resin to produce a foam, and then coating the first layer f on the surface of the fabric, and then extruding it at a temperature of 6 (M5 () t). This coating method has a The advantages of moisture permeability and water pressure resistance, and the use of ACRYLATES resin, polyurethane wax, latex (butadiene-type polymer) resin, silicone resin and vinyl acetate resin Acrylic acid vinegar (ACRYLATES) resin (1: 3 ~ 1: 6), Polyurethane grease = seven, hair gel (butadiene polymer) resin (1: 3 ~ 1: 5), silicon Elastomer resin (1: 3 ~ 1 and base ester resin (1: 3 ~ 1: 5) 'The bottom coating can be obtained with a water pressure resistance of 2000mm or more and a moisture permeability of 50000g / m7Day or more, and then apply water-based (p〇lyukeTHANE) resin (SE_928 Kun, Resin Industry Co., Ltd.) to the coating amount on the second layer (surface layer) (1_3) with a knife 〇 丨 1 air. 5 ~ 200g / ni for surface layer Coat you, add I ~ 丨 0% melamine bridging agent, 2 ~ 8% anionic surfactant and 2 ~ 5% thickener to the resin, and then dry it at 60 ~ 150 ° C / 0.5 ~ 1.5 Hardened under 120 ~ 200 ° C / 0.5 ~ 2.5 minutes to complete the hardening process to complete the product with a water pressure resistance of 5000mmH2, and a product with high water pressure resistance and high moisture permeability above 5000 g / m7Day As shown in the second figure, the coating processing layer can be obtained as shown in the third figure. Three layers of fabric processing cloth (1-1) with different structures (foamed coating layer (〗 _2) and moisture-permeable waterproof coating layer (Η). In order to make the reviewers more aware of the invention of this creation, the following examples and comparative examples are used to explain this creation: [Example 1] The pressure absorption rate of Cailong plain fabric after desizing, refining, dyeing, and predetermined shape is 5 〇 / 〇 water repellent treatment, Erlai drying at a temperature of 110 ° c, the drying time is 50 seconds. Nylon cloth (700 乂 700, 124 乂 8 丨) was used as the coating processing cloth. The following coating liquid was used to coat the fabric for the first time with a foam coater, and the coating resin was polyurethane ( POLYURETHANE) resin, with a foaming ratio (1: 5) and a coating amount of 75 g / nf 'applies to the ifc scale of this paper in the China Standard (CNS) Λ4 specification (210X297 Gongchu) Weeping matters should be filled in this education) V ----- 1 Order 444 〇7 6 A7 V. Description of the invention (B7 Missing Bureau of the Ministry of Economic Affairs ^: Industrial Consumers Cooperative Cooperative Seal-(1), surface coating The processing liquid and i〇◦ are dried for 1 minute, and then coated with a floating knife (knife 〇n air) plus a hydrophilic coating process to perform surface coating. The coating amount is 150 g / ni and then enters the second line. 80 ° c XI minutes and 150 ° C X1 minutes and 60 seconds to obtain a wet waterproof fabric. The coating processing fluid used is as follows: (―), the bottom coating processing fluid: Polyurethane resin 100 Melamine-based bridging agent 2% Foaming agent 50 / 〇 Foam stabilizer 8%,. Thickener 2% (―), surface coating processing fluid: PU resin (SE-928) 100 melamine-based framework Agent 5% anionic surfactant 3% thickener 2% [Example 2] Under the same conditions of pre-treatment, using Nylon cloth (70DX70DJ24X81) as a coating and adding Ϊ μΪ After pre-treatment, the fabric was subjected to the following coating conditions The first coating was performed with a foam coater, and the coating resin was acrylic vinegar (ACRYLATES '^ M1 ^, J foam 3 (1: 6), and the coating amount was 100 g / m2, dry at 85 ° CX for 1 minute, then “line twist dry”, and then apply the coating process on the knife on air for surface coating and water-based coating. The coating amount is 145g / ni and then enter the oven for 90 145 eC. X 1 minute 6G seconds heat treatment project 'Ready-to-moisture waterproof processing cloth. The knife and the coating liquid used are as follows: (1), the bottom coating processing liquid: Acrylic S zone S purpose (ACRYLATES) Resin Dimer Amines Bridge Crossing Agent 4% Foaming Agent 5% Foaming Agent 8% Thickener 2% PU Resin (SE-92S) This paper is standard for the Chinese National Cricket (CNS) Λ4 Grid (21〇X 297 males ^) 100 I—. * ^ 1 f VH-—ii ·--»^ II I 1--IJ->-1-/ 'l-SJ. * (Please read the precautions on the back first Refill this ear} 444076 five ' Description of the invention (inch B7 Λ7 hardener (ISOCYANATE) 5.5% anionic surfactant 3% thickener 2% [Example 3] Under the same conditions as before, Nylon cloth (70 £ > > < 7〇 ] [), 124 乂 81) As a coating process cloth, the fabric was first coated with a foam coater under the following coating conditions, and the coating resin was a latex (butadiene-type polymer) (LATEX butadiene_base POLYMERS) Coating processing method of resin 'with foaming ratio (1: 4 5), coating amount of 70, dry with MCX 1 $ bell for drying, and then floating blade fine pond 〇n person) ^ For the hydrophilic coating process of clever layer coating, the coating amount is 140 g / m2, and then enter the oven for 95CX for 1 minute and 155 ° CX for 1 minute and 50 seconds to obtain a moisture-permeable waterproof fabric. … The coating and processing fluids used are as follows: (1), the bottom coating and processing fluid: latex (butadiene-based polymer)> resin 100 melamine cross-linking agent 2.5% thinner 2% (two), surface coating Processing fluid: PU resin (SE-928) 100 hardener 4% anionic surfactant 1.5% thickener 2% [Example 4] Under the same conditions as before, Nylon cloth (70Dx70D, 124x81) is used as the coating process The coating conditions listed below apply the first coat to the fabric using a foam coater: The coating resin is Miao Li Kang elastomer (SiUCONEELASTOM resin, with a foaming ratio (1: 3.5_), coating The cloth amount is 90 g / ni, and it is dried at 95 ° C for 1 minute, and then the coating process method of knife on air is used for the hydrophilic coating process of the surface layer coating, and the coating amount is 135 g / πί then entered the supply box for 90t XI minutes and 140 ° CXI minutes and 60 seconds of heat treatment project, to obtain a moisture-permeable waterproof processing cloth. The paper's thick scale is applicable to the Chinese and Fujian national standards (cns) Λ4 specifications (2) 0 > : 297 mm) \ ----- ίτ -----] / ----- ^-Order, '-Please read the notes on the back first Refill this page} 444 0 7 6 Λ 7 Β7 V. Description of the invention (The coating and processing fluids used are as follows: (―), the bottom coating and processing fluid: Silicon elastomer resin 100 melamine bridging agent 1% Thickener 2% (two), surface flex coating processing fluid: PU resin (SE-928) 100 melamine-based bridging agent 12% anionic surfactant 5% thickener 2% [Example 5] Same conditions as before Next, Nylon cloth (70DX70D, 124X81) was used as the coating fabric, and the fabric was coated with a foam coater for the first time under the following coating conditions. The coating resin was vinyl ester (VINYL ACETATE) resin, with a foaming ratio of 'Γ (1: 4.5), a coating amount of 80 g / πί, and drying at 85 ° CX for 1 minute, Bing | coating on knife on air Cloth processing method The hydrophilic coating of the surface layer is processed. The coating amount is 130 g / rri, and then enters the oven for 100 ° C XI minutes and 130 X 1 minute and 60 seconds heat treatment works to obtain a moisture-permeable waterproof processing cloth. The coating processing fluid used is as follows: (1), the bottom coating processing fluid: '(2), the surface coating processing fluid Vinyl acetate g resin 100 melamine-based bridging agent 2% thickener 2% PU resin (SE-928) 100 melamine-based bridging agent 8% anionic surfactant 3.5% copper increasing agent 2% [Comparative Example ί Water paper ft scale is suitable for Chinese car pickers (CNS) Λ4 condition (2lO_X2V ·? Mm) Λ7 Β7 ———- 5. Description of the invention ((* Please read the precautions on the back before filling this page) to [Example] Under the same conditions of pretreatment, Nylon cloth (70Dx7〇D 124χ coated processing cloth) was coated with a solvent-based PU resin floating doctor blade for the first time, and the coating amount was SOg / πί, and dried for 12 minutes. 〇tXI minutes for drying, and then the surface coating of the hydrophilic coating process by ^ krnfeonau coating processing method, the coating amount of 120 g / m and then enter the oven for 120 χ 丨 minutes and The heat treatment process of 150 ° χ i minutes and 60 seconds can obtain a moisture-permeable and water-repellent processed cloth with better water resistance and permeability than [Comparative Examples 2 and 3]. The coating and processing fluids used are as follows: (1), bottom coating and processing fluids: (2), surface coating and processing fluids Solvent PU resin 100 isocyanate 5% MEK 45% DMF 15% Solvent PU resin 100 isocyanate Ester 5% DMF 15% MEK 10% [Comparative Example 2]: [Example] Under the same conditions as in the pretreatment, a nylon cloth (70DX70D, 124X81) was used as a heavy cloth processing cloth, and a foamed PU resin was used for a floating blade ( knife on air) for coating processing. Its coating amount is 90g / rri, and it is dried at 90 ° C × 1 minute for drying, and then 150 ° C × 2 minutes for heat treatment. In this way, a processing cloth with high water resistance and high differential humidity can be obtained. The coating and processing fluid is as follows :. Foam PU resin 100 Foaming agent 5% Foaming agent 8% Thickener 2% [Comparative Example 3]: This paper has been scaled in the national scale of China ”(CNS> Λ4 said格 (2 丨 0x; j97 公 楚 Λ44076 Λ7 B? Five invention descriptions (as ^ ίϊί) under the same conditions 'Nailong cloth (like the name of the imaginary fantasy)] i cloth processing and its coating 9.' ° 尔 犯 — 928) Use the float to the knife on air to make it dry again. 3. Dry for three minutes. The coating process fluid is as follows: Cheng hydrophilic ^ water-based PU resin (SE-928) 100-4 gas amine bridge Agent%% thickener 2% pressure (according to the comparison in the table, the data in the table shows that Jingshui is compared, from the data of 3 through>〉 degree (tested according to the 1099 ^ 1 method) 11 Although the fabric has a high Moisture permeability and low water pressure resistance, but the water pressure and moisture permeability are better than [Comparative Examples 2 and 3], and [Better than Shi Minglong.], The data is more secretive and transparent than [Solid paste 1 ~ 5] The humidity is improved by the characteristics of the solid pressure and the fabric layer, which can obtain high moisture permeability and high water resistance. It is stupid. It is better than the product obtained by the coating of general processing fluid and the product has (Please read the notes on the back before filling out this page} -Install--Order

444 07 6 Μ m C9444 07 6 Μ m C9

\加1 條件 布\ 規\ .格\ 底層 (笫一次塗佈) (泡沫塗佈用 樹脂) 表 層 (第二次塗佈) (泡床塗佈樹脂+P U 樹脂(SE-928)) 耐 水 壓 (mm.H2〇) 透 濕 度 (g/m/Day) 耐隆布(Nylon) 70DX70D.124X81 【賞施例i】 聚尿酯樹脂 400 6000以上 PU(POLYURETHANE)樹 脂(SE-· 6000以上 5000 耐隆布(Nylon) 70DX70D.124X81 【實施例2】 丙彿酿臨 (ACRYLATES) 樹脂 200 6000以上 PU(POLYURETHANE)樹 脂(SE-92S) 5000 5000 对隆布(Nylon) 70DX70D.124X81 [實狍例3】 乳膠(丁二烯型 聚合物) 250 5000 PU(POLYURFTHANE)樹 脂(SE-92S) 5000 4000 对隆布(Nylon) 70DX70D,124X81 【實施例4】 矽利康彈性體 500 6000 PU(POLYURETHANE)樹 脂(SE-928) 8000 5000 耐隆布(Nylon) 70DX70D, 124X81 E實施例5】 乙烯基酯酸酯 250 7000 Plj(POLYURETHANE)樹 脂(SE-928) 7000 6000 隆布(Nylon) 70DX70DJ24X81 溶劑型PU樹 脂(比較例1) 5000 3000 对隆布(Nylon) 70DX70DJ24XS1 泡沫型PU樹 脂(比較例2) 200〜500 5000 耐 1¾:布(Nylon) 70DX70D.124XS1 水性PU樹脂 (比較例3) 4500 2500 ί請先閲讀背do之注意事項再行繪衮) -1.訂 線; 經濟部中央端毕工ί/ίΐ,·:'·ί·咋;£印亿 註: 1 布之規格:Nylon 70D(經紗支數)X70D(緯紗支數),124(經密) X81(緯密) 2.SE-928(昆怡樹脂工業股份有限公司商品名) 3.實施例1〜5之表層耐水壓及透濕度是經底層與表層塗佈後之 測試數據。 表(一) ( CNS ) Λ4^(Λ- ( :U)\)\ Plus 1 condition cloth \ gauge \ .grid \ bottom layer (笫 on coating) (foam coating resin) surface layer (second coating) (foam bed coating resin + PU resin (SE-928)) water pressure resistance (mm.H2〇) Moisture permeability (g / m / Day) Nylon 70DX70D.124X81 [Reward Example i] Polyurethane resin 400 6000 or more PU (POLYURETHANE) resin (SE- · 6000 or more 5000 resistant) Nylon 70DX70D.124X81 [Example 2] ACRYLATES resin 200 6000 or more PU (POLYURETHANE) resin (SE-92S) 5000 5000 Nylon 70DX70D.124X81 [Example 3 ] Latex (butadiene-based polymer) 250 5000 PU (POLYURFTHANE) resin (SE-92S) 5000 4000 Nylon 70DX70D, 124X81 [Example 4] Silicone elastomer 500 6000 PU (POLYURETHANE) resin ( SE-928) 8000 5000 Nylon 70DX70D, 124X81 E Example 5] Vinyl ester 250 7000 Plj (POLYURETHANE) resin (SE-928) 7000 6000 Nylon 70DX70DJ24X81 solvent-based PU resin ( Comparative Example 1) 5000 3000 pairs of Nylon 70DX70DJ24XS1 foam PU resin (Comparative Example 2) 200 to 500 5000 Resistance to 1¾: cloth (Nylon) 70DX70D.124XS1 water-based PU resin (Comparative Example 3) 4500 2500 ί Please read the precautions before drawing do) -1. Ordering; Complete work at the central end of the Ministry of Economics ί / ί, ·: '· Ί · 咋; £ 100 million Note: 1 Specification of cloth: Nylon 70D (warp count) X70D (weft count), 124 (warp density) X81 (weft density) 2.SE-928 (Kunyi Resin Industry Co., Ltd.) 3. The water pressure resistance and moisture permeability of the surface layer of Examples 1 to 5 are test data after coating the bottom layer and the surface layer. Table (1) (CNS) Λ4 ^ (Λ- (: U) \)

Claims (1)

(第87涵84號申請專 A A 4 0 7 6 申請專利範圍 環保水性樹脂透濕防水加工布之加工方法,其加工方法之程 (1) .以一般之前處理織物其壓吸率為; -請先閑讀背面之注意事項再填寫本頁} (2) .,以水性樹脂作底層泡沫塗佈其塗佈量為7〇〜2〇〇以诅、 為1:3〜1·‘7、乾燥溫度為60〜15〇它烘乾時間為4.5^ ^包比 擠壓等步驟; ‘Ί r ^ 1 73 (3) ,施以水性PU樹脂作表層塗佈其塗佈量為1〇〇〜15〇g/irf、乾 广150。(:/0.5〜1.5分、以120〜200。。/0 5〜2 5分作熱處'|等 主要係於表層以水性PU樹脂與底層發泡層間之結合,而獲 口以上高耐水壓及5000 g/m7Day以上高透濕度具環保 2·^申請專利範圍第1項所述之環保水性樹脂透濕防水加工方法, 其中,底層塗佈中之水性樹脂為丙烯醯酯、乙烯基酯酸酯、砂 彈性體、聚尿酯樹脂及乳勝(丁二烯型聚合物)。 3·如申請專利範圍第2項所述之環保水性樹脂透濕防水加工方法, 其中,丙烯醯酯樹脂之泡床塗佈之發泡比為1:3〜1:6。 4. 如申請專利範圍第2項所述之環保水性樹脂透濕防水加工方法, 其申,聚尿酯樹脂之泡沫塗佈之發泡比為1:3〜1:7。 5. 如申請專利範圍第2項所述之環保水性樹脂透濕防水加工方法, 其中’乳膠(丁·一稀型聚合物)樹脂之泡床塗佛之發泡比為1:3〜1:5。 6. 如申請專利範圍第2項所述之環保水性樹脂透濕防水加工方法, 其中’梦利康彈性體樹脂之泡沫塗佈之發泡比為1:3〜1:6。 7. 如申請專利範圍第2項所述之環保水性樹脂透濕防水加工方法, 其中,乙烯基酯酸酯樹脂之泡沫塗佈之發泡比為1:3〜1:5。 經濟部中央標準局員工消費合作社印製 8. —種如申請專利範圍第1項方法所製成之環保水性樹脂透濕防水 加工布’其係為織物底層以水性樹脂作泡洙塗佈層,再施以水性 Ρϋ樹脂塗佈液作表層之塗佈’其特徵為底層為發泡層而表層為合 乎環保性之水性PU樹脂。 9. 如申請專利範圍第8項所述之環保水性樹脂透濕防水加工布,其 中’底層塗佈層為丙烯醯酯樹脂、乙烯基酯酸酯樹脂、矽利康彈性 體樹脂、聚尿酯樹脂及乳膠(丁二烯型聚合物)樹脂。 本紙張尺度逋用中國國家樣丰(CNS ) A4规格(210X297公釐)(No. 87 Han No. 84 Application No. AA 4 0 7 6 Application for patents Processing method of environmentally-friendly water-based resin moisture-permeable waterproof processing cloth, the process of the process (1). The pressure absorption rate of the fabric before the general treatment;-please Please read the precautions on the back before filling in this page} (2). Use a water-based resin as the bottom foam coating. The coating amount is 70 ~ 200. The curse is 1: 3 ~ 1'7. Dry The temperature is 60 ~ 150. Its drying time is 4.5 ^ ^ bag ratio extrusion and other steps; 'Ί r ^ 1 73 (3), water-based PU resin is applied as the surface coating, and the coating amount is 100 ~ 15. 〇g / irf, dry wide 150. (: /0.5~1.5 points, with 120 ~ 200 ... / 0 5 ~ 25 points as hot place '| etc. It is mainly between the surface layer with water-based PU resin and the bottom foam layer. Combined to obtain a high water pressure resistance above the mouth and a high moisture permeability of 5000 g / m7Day or more. The environmentally-friendly water-repellent water-repellent and water-repellent processing method described in item 1 of the patent application scope, wherein the water-based resin in the coating of the bottom layer Acrylic ester, vinyl ester, sand elastomer, polyurethane resin and Rusheng (butadiene type polymer) 3. If the scope of patent application is the second The environmentally-friendly water-soluble resin moisture-permeable and water-repellent processing method, wherein the foaming ratio of the foamed bed coating of the acrylic resin is 1: 3 to 1: 6. 4. The environmentally-friendly water-based as described in item 2 of the scope of patent application A resin moisture-permeable and water-repellent processing method, which claims that the foaming ratio of the polyurethane resin foam coating is 1: 3 ~ 1: 7. 5. The environmental-friendly water-based resin moisture-permeable and water-repellent processing described in item 2 of the scope of patent application The method, wherein the foaming ratio of the latex (butadiene polymer) resin foam coated foam is 1: 3 ~ 1: 5. 6. The environmentally-friendly water-based resin described in item 2 of the patent application is permeable to moisture Waterproof processing method, wherein the foaming ratio of the foam coating of Meng Likang elastomer resin is 1: 3 ~ 1: 6. 7. The environmentally-friendly water-soluble resin moisture-permeable and waterproof processing method described in item 2 of the patent application scope, wherein , The foaming ratio of the foam coating of vinyl ester resin is 1: 3 ~ 1: 5. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. Environmentally friendly water-based resin moisture-permeable waterproof processing cloth 'is the bottom layer of fabric with water-based resin as the foam coating layer, and then applied The coating with water-based PH resin coating liquid as the surface layer is characterized in that the bottom layer is a foamed layer and the surface layer is an environmentally friendly water-based PU resin. Processed cloth, where 'the bottom coating layer is acrylic resin, vinyl ester resin, silicone resin, polyurethane resin, and latex (butadiene-type polymer) resin. This paper uses China National Samples (CNS) A4 specifications (210X297 mm)
TW87108984A 1998-06-25 1998-06-25 Environmentally friendly water resin moisture-permeable water-proof processed fabric and the process method TW444076B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI598240B (en) * 2013-10-16 2017-09-11 Ji-Sheng Yang Marking made of woven fabric method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI598240B (en) * 2013-10-16 2017-09-11 Ji-Sheng Yang Marking made of woven fabric method

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