206^70 Λ 6 B6_ 五、發明説明（I ) {^"聞-^而之：:£-spiij再填寫本頁) 透濕防水産品其加工方式一般大致可分為濕式、乾式 及阽合法三種。不論為何種加工方式，薄膜又可分為微多 孔質與無孔質二種型態薄膜，若透濕防水産品靥於微多孔 膜者，産品之透濕性雖高，但産品之耐水壓卻始終無法達 到令人滿意的結果；反之，産品若靥於無孔質者，則産品 之透濕性無法與微多孔膜産品相媲美，但耐水壓性卻相當 優異。今苕欲同時兼顧産品之透濕性及耐水壓性，則必須 結合二種薄膜之優良待性於一體，同時去除産品不良的性 質，因此考盧將二種性質迥異之薄膜利用貼合加工之方式 與織物緊密的結合在一起，使此産品不但能同時具有優異 的透濕、防水性能，而且還可因織物的伸縮性使産品更具 舒適性、流行性及多樣性。 一般微多孔膜均以濕式凝固浴之方式製作，由於在製 作過程中無法避免對離型紙所造成的損傷，因此徹多孔薄 膜無法以一般之離型紙進行製作；離型紙不適合製作微多 孔膜之另一原因為離型紙的密封狀態將會阻礙微多孔之形 成。由於以上之因素，欲逢到微多孔膜阽合於織物之目的 ，過去多以微多孔的PTFE薄膜為之，然微多孔的PTFE薄膜 因成本髙，而不合實用。本發明乃利用微多孔的PU微多孔 薄膜、EVAc撤多孔薄膜等以待殊的離型布進行加工。 本發明之主要目的乃在提供一種嶄新的加工方式，可 有效克服前述習知之缺點，而逢到産品最佳物性之功效。 經濟部中央標準局S工消費合作社印繫 現配合圖式，說明本發明之待殊方法及恃徵功效如下 圖一為本發明之加工流程圖 圖二為本發明與習知方法之效果比較表 諳參閲附圔一 •為本發明之加工改良方法流程圖； _首先選定經退漿、精練、染色、預定型等前處理之 各紙張又度通用中國Η家標準（CNS)甲4現格（210 X 297公货） 2〇62*V〇 a6 _ _ B6_ 五、發明説明〇 ) 70D/24F、170〜250T耐隆或聚醋平織物作為離型布之基布 Ο 首先以固型份為20〜40%併用0_1〜5 %三聚氛胺条添 加劑作為壓吸液，對上述之聚酯或耐曙平織物進行壓吸率 為30〜40?«·之壓吸處理，之後於12〇〜16〇° C之溫度下進 行熱菡理，熱處理時間以3〇秒〜3分鐘為宜。經處理後之 鏃物具有剝離強度小於之®良離型性，且離型性可 維持在使用逹六次以上後仍具有優良之離型效果。 接著使用一液型Polyester、MDI条濕式用PU樹脂配 合使用3%陰離子界面活性劑、3%非離子界面活性劑、3%抗 黏劑及10¾之色料作為塗佈原料，以刮刀上羅a ( knife on roll)之塗佈方式於上述離型布表面進行塗佈置為70〜 200g/m2之表面微多孔層塗佈加，之後進入含有5〜30% DMF之凝固浴中進行成型，隨後即進行7〇° C、1〜3分鐘 之熱水洗工程，藉此除去微多孔膜中殘餘之有機溶劑，接 著進入80〜120° C之供箱中進行乾燥1分鐘。卽可獲得透 濕度髙逢6 ,〇〇〇g/m2/Day之微多孔薄膜。 再以側鏈上含PEG親水性無黃變脂防族PU樹脂中添 加1〜10%三聚氣胺条架橋劑2〜5%之架橋促進劑作為接 箸靥塗佈原料，於尚未與離型布離型之微多孔層表面進行 塗佈置為30〜200g/m2之接著層塗佈加工，之後在0.1〜 經濟部中央標準局员工消費合作社印*'取 {請先間讀背‘面之注念麥項再場寫本頁) -裝· 5 kg/cm2之壓力條件下，將其與緦物或編物進行阽合處理 ，最後進入烘箱中以140〜170° C進行熱處理，熱處理時 間以30秒〜2分鐘為宜。 最後將離型布與透藤防水産品予以離型處理》卽得透 濕度5,000g/m2/Day以上、耐水壓l5,OOOmm.H2〇以上、具 有柔軟豐厚手感等優異性能之透灑防水産品。另，經離型 後之離型布尚可再次重覆使用。 比較例1 : 本紙張尺度通用中國國家標準（CNS)甲4規格（210 X 297公釐〉 ^06270 A6 . _ B6_ 五、發明説明（¾ ) 以2?ό之氟碩樹脂對70D/24F、21〇Τ且經退漿、精練、 染色、預定型之耐隆平織物進行壓吸率為40%之撥水處理 ，之後以12(T C之溫度下進行供乾，乾燥時間45秒。 以下列之塗布配方液對織物以刮刀上羅位（knif© on roll )之塗佈加工方式進行塗佈加工，塗佈量為250g/m2 ，經30° C、2分鐘之濕式凝固浴成型後，加工基布再經 70° C、2分鐘之熱水洗工程，藉以去除殘留於撒多孔膜中 之有機溶劑，最後進入120° C之烘箱中進行2分鐘之烘乾 工程，即得一般之濕式透濕防水加工産品。 塗佈加工液： (請先閲^"'面之注意事項再塡寫本頁> 1206 ^ 70 Λ 6 B6_ V. Description of the invention (I) {^ " Wen- ^ and :: £ -spiij then fill out this page) The processing methods of breathable and waterproof products can be roughly divided into wet, dry and dry Three legal. Regardless of the processing method, the film can be divided into two types of microporous and non-porous films. If the moisture-permeable and waterproof product is in the microporous film, the product's moisture permeability is high, but the product's water pressure resistance is Satisfactory results have never been achieved; on the contrary, if the product is not porous, the moisture permeability of the product cannot be comparable to the microporous membrane product, but the water pressure resistance is quite excellent. Today, if you want to take into account both the moisture permeability and the water pressure resistance of the product, you must combine the excellent hospitality of the two films and remove the bad properties of the product. Therefore, Kaulu uses the two films with different properties to process them together. The combination of the method and the fabric makes the product not only have excellent moisture permeability and waterproof performance, but also make the product more comfortable, popular and diverse due to the elasticity of the fabric. Generally, microporous membranes are made by wet coagulation bath. Since the damage to the release paper cannot be avoided during the manufacturing process, the porous membrane cannot be made with general release paper; release paper is not suitable for making microporous membranes. Another reason is that the sealed state of the release paper will hinder the formation of micropores. Due to the above factors, in order to meet the purpose of microporous membranes being integrated with fabrics, microporous PTFE membranes have been used in the past, but microporous PTFE membranes are not practical due to their high cost. The present invention utilizes microporous PU microporous film, EVAc porous film, etc. to be processed with special release cloth. The main purpose of the present invention is to provide a brand-new processing method, which can effectively overcome the aforementioned shortcomings of conventional knowledge, and meet the best physical properties of the product. The printing system of the S Industry and Consumer Cooperative Society of the Central Bureau of Standards of the Ministry of Economic Affairs now cooperates with the diagram to illustrate the special method and the efficacy of the present invention. The following figure 1 is the processing flow chart of the present invention. Please refer to Appendix 1 for a flowchart of the improved processing method of the present invention; _ First select the papers that have been pre-processed such as desizing, refining, dyeing, and pre-processing, and they are all in accordance with the Chinese Standard NH (CNS) A4. (210 X 297 public goods) 2〇62 * V〇a6 _ _ B6_ V. Description of invention 〇) 70D / 24F, 170 ~ 250T nylon or vinegar flat fabric as the base fabric of the release cloth. First, the solid content 20 ~ 40% and using 0_1 ~ 5% melamine strip additive as the pressure-absorbing liquid, the pressure-absorbing rate of the above-mentioned polyester or Shushuping fabric is 30 ~ 40? The heat treatment is carried out at a temperature of 〇 ~ 16 ° C, and the heat treatment time is preferably from 30 seconds to 3 minutes. After treatment, the noodles have good peeling property with peel strength less than ®, and the peeling property can be maintained after six or more times of use and still has excellent releasing effect. Then use one-component Polyester, MDI strip wet PU resin with 3% anionic surfactant, 3% nonionic surfactant, 3% anti-sticking agent and 10¾ color material as the coating raw material, use the spatula to pull a (knife on roll) coating method: apply the surface microporous layer of 70 ~ 200g / m2 on the surface of the release cloth, and then enter into the coagulation bath containing 5 ~ 30% DMF for molding. Subsequently, a hot water washing process at 70 ° C. for 1 to 3 minutes is performed to remove the residual organic solvent in the microporous membrane, and then it is dried in a supply box at 80 to 120 ° C. for 1 minute. A microporous film with a moisture permeability of 6,000 g / m2 / Day can be obtained. Then use PEG hydrophilic non-yellowing fat-resistant PU resin on the side chain to add 1 ~ 10% trimeramine cross-linking agent 2 ~ 5% bridging accelerator as the coating material for the coating. The surface of the microporous layer of the release fabric is coated with a coating layer of 30 ~ 200g / m2, and then printed on the 0.1 ~~ Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy. Reminiscence Mai Xiang re-write this page)-Pack · Under the pressure condition of 5 kg / cm2, treat it with the braided or braided fabric, and finally enter the oven for heat treatment at 140 ~ 170 ° C, heat treatment time 30 seconds to 2 minutes is appropriate. Finally, the release fabric and the translucent water-proof product are released. The permeable and waterproof product with excellent performance such as moisture permeability above 5,000g / m2 / Day, water pressure resistance above 1,500mm.H2〇, soft and rich feel, etc. In addition, the release fabric after release can still be used again. Comparative Example 1: The paper scales are in accordance with the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) ^ 06270 A6. _ B6_ V. Description of invention (¾) With 2? 21〇Τ and desizing, scouring, dyeing, predetermined type of nylon flat fabric with a water absorption treatment with a pressure absorption rate of 40%, then supplied at a temperature of 12 (TC temperature, drying time 45 seconds. With the following The coating solution is applied to the fabric by the knife processing method of knife on roll (knif © on roll), the coating amount is 250g / m2, and it is processed after being formed in a wet coagulation bath at 30 ° C for 2 minutes. The base fabric is then subjected to a hot water washing process at 70 ° C for 2 minutes to remove the organic solvent remaining in the porous membrane, and finally enters an oven at 120 ° C for 2 minutes to dry the project. Wet and waterproof processing products. Coating processing fluid: (Please read ^ " 's precautions before writing this page > 1
Polyester、MDI 条 PU樹脂 100 陰離子界面活性劑 3¾ 非離子界面活性劑 3¾ 抗黏劑 3¾ 色料 10% 比較例2 : 以2¾之氣碩樹脂對70D/24F、210T且經退漿、精練、 染色、預定型之耐隆平織物進行壓吸率為40¾之撥水處理 ，之後以12CT C之溫度下進行烘乾，乾燥時間4S秒。 以下列之接箸層塗佈配方液對織物之浮游刮刀（knife on roll)之塗佈加工方式進行第一次塗佈加工，塗佈置為 75g/m2,經80° C、1分鐘之供乾後，加工基布後再以刀 上羅拉（knife on roll)之塗佈加工方式進行親水性表面 層之塗佈加工，塗佈量為150 g/m2,之後隨卽進入烘箱進 行80° C、1分鐘之烘乾及150° C、1分30秒之熱處理工 程，即得一般之乾式透潺防水塗佈産品。 塗佈加工液： 1.接著靥： _二液型脂肪族PU樹脂_100 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） ---^------—,订-----^ 碌 經 濟 部 中 標 準 為J 工 消 費 合 作 社 印 製 ^---------— I. 206^^0 5¾ 2¾ 100 3¾ 5¾ 10¾ Λ6Polyester, MDI strip PU resin 100 Anionic surfactant 3¾ Non-ionic surfactant 3¾ Anti-sticking agent 3¾ Color 10% Comparative Example 2: Using 2¾ gas resin to 70D / 24F, 210T and desizing, refining, dyeing 1. The predetermined type of nylon flat fabric is subjected to a water repellent treatment with a pressure absorption rate of 40¾, and then dried at a temperature of 12CT C, with a drying time of 4S seconds. The coating process of the knife on roll of the fabric is carried out for the first time with the following coating solution of the coating layer of the coating layer. The coating arrangement is 75g / m2, which is supplied at 80 ° C for 1 minute. After drying, after processing the base fabric, the coating process of the hydrophilic surface layer is carried out by the knife on roll coating process, the coating amount is 150 g / m2, and then enter the oven for 80 ° C , 1 minute drying and 150 ° C, 1 minute and 30 seconds heat treatment project, you can get general dry-type waterproof coating products. Coating processing fluid: 1. Next: _Two-component aliphatic PU resin_100 The paper size is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm) --- ^ ------ —, Set ----- ^ The standard of the Ministry of Economy is printed by J Industrial Consumer Cooperative ^ ---------— I. 206 ^^ 0 5¾ 2¾ 100 3¾ 5¾ 10¾ Λ6
BG 五、發明説明（ψ) 三聚氣胺条架橋劑 架橋促進劑 2.表面層： 一液型芳香族ρυ樹脂 陰離子界面活性劑 矽利康条添加劑 色料 比較例3 : 以2¾之氣硕樹脂對70D/24F、210Τ且經退漿、糟練、 染色、預定型之耐隆平織物進行壓吸率為40¾之撥水處S ,之後以120° C之溫度下進行烘乾，乾燥時間45秒。 以下列之表面層塗佈配方液對離型紙以刮刀上羅拉 (knife on roll)之塗佈加工方式進行第一次塗佈加工， 塗佈量為150g/m2,經80° C、1分鐘之烘乾後，再以刮 刀上羅拉（knife on roll)之塗佈加工方式對離型紙上之 表面層進行接著曆之塗佈加工，塗佈量為75g/m2 ,接著 將前述經撥水處理過之耐隆平織物以壓力3kg/cm2之條件 下進行阽合加工，之後隨即進入烘箱進行80" C、1分鐘 之供乾及150° C、1分30秒之熱處理工程，經離型後卽 可得一般之阽合透濕防水塗佈産品。 塗佈加工液： 先 -Λ uil -;-ϊ. 而 Ji fL·. ··:. 塡 % 本 頁 經 濟 部 中 央 標 準 局 员 消 費 合 作 社 印 製 1. 表面層： —液型芳香族PU樹脂 100 陰離子界面活性劑 3¾ 矽利康条添加劑 5% 色料 10% 2. 接箸曆： 二液型脂肪族PU樹脂 100 三聚氰胺条架橋劑 5% 本紙張尺度適用中國國家標準（CNS>甲4规格（210 X 297公釐） A6 206^V0 _ B6__ 五、發明説明（<) 架橋促進劑 2¾ 請參閲附圖二，藉由上述之待殊改良加工方法，本發 明所製得之産品，其透濕性（依LYSSY法於40。C、95%RH條 件下測試）、耐水壓（依JIS L-l〇92法測試）、剝離強度及 手感（ί衣Kawabata Evaluation System法測試）方面等性質 與習知方法比較，依数據顯示，本發明確具改良之功效者。 註：柔軟度之評定等级範圍：〇〜级。1级最佳， 10級最差。 緦手感之評定等級範圍；〇.〜5級。S級最佳， 1级最差。 一般塗佈産品之總手感等级範圍約在0.1〜1.S级 經上述加工方式所獲致之透濕防水産品，其不僅在透 濕性、防水度等加工物性上可獲突破性的提昇，産品亦較 傳統加工方式産品具有恃殊柔軟及豐厚之手感，同時解決 産品 Peeling Strength、Tack等問題者。 經濟部中央標準局员工消費合作杜印射衣 本紙張又度適用中國國家標準（CNS) f 4规格（21〇 X 297公釐）BG 5. Description of the invention (ψ) Trimeric gas amine bridging agent bridging accelerator 2. Surface layer: One-liquid aromatic ρυ resin anionic surfactant Silicone strip additive coloring material Comparative example 3: 2¾ of the gas resin The 70D / 24F, 210T and desizing, scouring, dyeing, and pre-preparation of the long-nap fabrics are subjected to a water repellent point S with a pressure absorption rate of 40¾, and then dried at a temperature of 120 ° C. The drying time is 45 seconds . Use the following surface layer coating formula to carry out the first coating process on the release paper by knife on roll coating method, the coating amount is 150g / m2, after 80 ° C, 1 minute After drying, the surface layer on the release paper is then coated with a knife on roll coating process, the coating amount is 75g / m2, and then treated with water The Nylon flat fabric is subjected to laminar processing under a pressure of 3kg / cm2, and then immediately enters the oven for 80 " C, 1 minute supply drying and 150 ° C, 1 minute 30 seconds heat treatment project, after release It is a general-purpose moisture-permeable waterproof coating product. Coating processing fluid: first -Λ uil-;-ϊ. And Ji fL · ···: .. 塡% This page is printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 1. Surface layer: —Liquid type aromatic PU resin 100 Anionic surfactant 3¾ Silicone strip additive 5% Colorant 10% 2. Connection calendar: Two-component aliphatic PU resin 100 Melamine strip bridging agent 5% This paper scale is applicable to Chinese national standards (CNS> A4 specifications (210 X 297 mm) A6 206 ^ V0 _ B6__ V. Description of the invention (<) Bridging accelerator 2¾ Please refer to the second figure, through the above-mentioned to be improved processing method, the product made by the present invention, its penetration Wetness (tested at 40 ° C and 95% RH according to LYSSY method), water pressure resistance (tested according to JIS L1092 method), peel strength and feel (tested by Kawabata Evaluation System method), etc. Method comparison, according to the data shows that the present invention does have an improved effect. Note: Softness evaluation grade range: 〇 ~ grade. 1 grade is the best, 10 grade is the worst. The evaluation grade range of the hand feel; 〇. ~ Grade 5. S grade is best, Grade 1 is worst. General coating The total hand feel grade range of the product is about 0.1 ~ 1. S-level moisture-permeable and waterproof products obtained through the above processing methods, not only can it achieve breakthrough breakthroughs in the processing properties of moisture permeability and waterproofness, but also the products are more traditional The processing method of the product has a special soft and rich feel, and at the same time solves the problems of products such as Peeling Strength and Tack. The Ministry of Economic Affairs Central Standards Bureau employee consumption cooperation Du Yin shot clothing paper is again applicable to the Chinese National Standard (CNS) f 4 specifications ( 21〇X 297 mm)