CN101613451A - High-content aqueous polyurethane latex and preparation method - Google Patents
High-content aqueous polyurethane latex and preparation method Download PDFInfo
- Publication number
- CN101613451A CN101613451A CN200910012952A CN200910012952A CN101613451A CN 101613451 A CN101613451 A CN 101613451A CN 200910012952 A CN200910012952 A CN 200910012952A CN 200910012952 A CN200910012952 A CN 200910012952A CN 101613451 A CN101613451 A CN 101613451A
- Authority
- CN
- China
- Prior art keywords
- reaction
- chainextender
- aqueous polyurethane
- preparation
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 19
- 239000004814 polyurethane Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000004816 latex Substances 0.000 title claims abstract description 8
- 229920000126 latex Polymers 0.000 title claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000839 emulsion Substances 0.000 claims abstract description 23
- -1 hydroxyalkyl siloxanes Chemical class 0.000 claims abstract description 22
- 229920000728 polyester Polymers 0.000 claims abstract description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002253 acid Substances 0.000 claims abstract description 16
- 239000000539 dimer Substances 0.000 claims abstract description 16
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical class CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims abstract description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 13
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 claims abstract description 13
- RLMGYIOTPQVQJR-UHFFFAOYSA-N cyclohexane-1,3-diol Chemical class OC1CCCC(O)C1 RLMGYIOTPQVQJR-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000004985 diamines Chemical class 0.000 claims abstract description 13
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 13
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 13
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 13
- 239000011734 sodium Substances 0.000 claims abstract description 13
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- 239000007787 solid Substances 0.000 claims abstract description 11
- 239000004970 Chain extender Substances 0.000 claims abstract description 10
- 238000005516 engineering process Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims description 12
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 4
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical class CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000003825 pressing Methods 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 239000004744 fabric Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- 229910018540 Si C Inorganic materials 0.000 description 2
- 239000012296 anti-solvent Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Abstract
Description
Coating-forming agent | Solid content (%) | Wear resisting property (inferior) | Water pressure resistance (mmH before the washing 2O) | Wash ten times water pressure resistance (mmH 2O) | The oven dry thickness of filming |
Embodiment 1 | ??55.5 | ??≥5000 | ??2380 | ??2250 | ??45 |
Embodiment 2 | ??55.3 | ??≥5000 | ??2532 | ??2450 | ??43 |
Embodiment 3 | ??55.2 | ??≥5000 | ??2510 | ??2490 | ??42 |
Embodiment 4 | ??54.9 | ??≥5000 | ??2430 | ??2390 | ??41 |
Embodiment 5 | ??55.4 | ??≥5000 | ??2360 | ??2330 | ??43 |
Wenzhou whole world URA301G | ??35±1 | ??2480 | ??1840 | ??1578 | ??31 |
The WIT-769 of Britain Baxenden company | ??40±1 | ??3260 | ??2230 | ??1920 | ??35 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009100129524A CN101613451B (en) | 2009-08-05 | 2009-08-05 | High-content aqueous polyurethane latex and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009100129524A CN101613451B (en) | 2009-08-05 | 2009-08-05 | High-content aqueous polyurethane latex and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101613451A true CN101613451A (en) | 2009-12-30 |
CN101613451B CN101613451B (en) | 2011-04-06 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2009100129524A Expired - Fee Related CN101613451B (en) | 2009-08-05 | 2009-08-05 | High-content aqueous polyurethane latex and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101613451B (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102505500A (en) * | 2011-11-01 | 2012-06-20 | 吴江市北厍盛源纺织品助剂厂 | Preparation method for novel radiation-proof coating agent |
CN103484008A (en) * | 2013-09-03 | 2014-01-01 | 盐城市昶桦户外用品有限公司 | Organic silicon modified water-based polyurethane paint and preparation method |
CN104975521A (en) * | 2015-07-06 | 2015-10-14 | 辽宁恒星精细化工有限公司 | Waterborne polyurethane latex emulsion for nylon fabric and preparation method thereof |
CN105418883A (en) * | 2015-12-08 | 2016-03-23 | 佛山佛塑科技集团股份有限公司 | Waterborne polyurethane acrylate, waterborne ultraviolet-curable paint thereof and corresponding preparing method |
CN107057032A (en) * | 2017-04-26 | 2017-08-18 | 合肥科天水性科技有限责任公司 | A kind of high-performance water-based polyurethane resin and preparation method for spinning coating |
CN108359072A (en) * | 2018-03-16 | 2018-08-03 | 上海汇得科技股份有限公司 | A kind of high wet and heat ageing resistant polyester-type sofa artificial leather polyurethane tie layer resins and preparation method thereof |
CN110684172A (en) * | 2019-11-12 | 2020-01-14 | 东莞市米儿塑胶原料有限公司 | Water-pressure-resistant water-based polyurethane resin |
CN111875774A (en) * | 2020-08-05 | 2020-11-03 | 辽宁恒星精细化工有限公司 | Preparation method of aqueous flame-retardant water-pressure-resistant polyurethane emulsion for fabric |
CN112480352A (en) * | 2020-11-24 | 2021-03-12 | 桐乡市正嵘纺织助剂有限公司 | Aqueous polyurethane textile coating agent |
CN114316206A (en) * | 2021-12-14 | 2022-04-12 | 福建汇得新材料有限公司 | Wet-process polyurethane resin and preparation method and application thereof |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1854165A (en) * | 2005-04-20 | 2006-11-01 | 广州宏昌胶粘带厂 | Organic silicon modified aqueous polyurethane |
CN101092538B (en) * | 2006-06-23 | 2010-11-10 | 宜兴市新光化工有限公司 | Waterproof, humidity permeable resin in aliphatic series for overcoating synthetic leather, manufacturing method of half-advanced polymerization |
CN101429417A (en) * | 2008-12-08 | 2009-05-13 | 广州市科霖水性材料有限公司 | High-adhesive property watersoluble polyurethane adhesion agent and method of producing the same |
CN101429407B (en) * | 2008-12-08 | 2011-03-09 | 广州市科霖水性材料有限公司 | Water soluble polyurethane acrylic acid composite coating agent and method of producing the same |
-
2009
- 2009-08-05 CN CN2009100129524A patent/CN101613451B/en not_active Expired - Fee Related
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102505500A (en) * | 2011-11-01 | 2012-06-20 | 吴江市北厍盛源纺织品助剂厂 | Preparation method for novel radiation-proof coating agent |
CN102505500B (en) * | 2011-11-01 | 2013-11-20 | 吴江市北厍盛源纺织品助剂厂 | Preparation method for novel radiation-proof coating agent |
CN103484008A (en) * | 2013-09-03 | 2014-01-01 | 盐城市昶桦户外用品有限公司 | Organic silicon modified water-based polyurethane paint and preparation method |
CN104975521A (en) * | 2015-07-06 | 2015-10-14 | 辽宁恒星精细化工有限公司 | Waterborne polyurethane latex emulsion for nylon fabric and preparation method thereof |
CN104975521B (en) * | 2015-07-06 | 2016-11-30 | 辽宁恒星精细化工有限公司 | Nylon facing material aqueous polyurethane rubber cement emulsion and preparation method |
CN105418883A (en) * | 2015-12-08 | 2016-03-23 | 佛山佛塑科技集团股份有限公司 | Waterborne polyurethane acrylate, waterborne ultraviolet-curable paint thereof and corresponding preparing method |
CN107057032A (en) * | 2017-04-26 | 2017-08-18 | 合肥科天水性科技有限责任公司 | A kind of high-performance water-based polyurethane resin and preparation method for spinning coating |
CN108359072A (en) * | 2018-03-16 | 2018-08-03 | 上海汇得科技股份有限公司 | A kind of high wet and heat ageing resistant polyester-type sofa artificial leather polyurethane tie layer resins and preparation method thereof |
CN108359072B (en) * | 2018-03-16 | 2020-12-08 | 上海汇得科技股份有限公司 | Polyurethane adhesive layer resin for high-humidity-heat-aging-resistance polyester sofa leather and preparation method thereof |
CN110684172A (en) * | 2019-11-12 | 2020-01-14 | 东莞市米儿塑胶原料有限公司 | Water-pressure-resistant water-based polyurethane resin |
CN111875774A (en) * | 2020-08-05 | 2020-11-03 | 辽宁恒星精细化工有限公司 | Preparation method of aqueous flame-retardant water-pressure-resistant polyurethane emulsion for fabric |
CN112480352A (en) * | 2020-11-24 | 2021-03-12 | 桐乡市正嵘纺织助剂有限公司 | Aqueous polyurethane textile coating agent |
CN114316206A (en) * | 2021-12-14 | 2022-04-12 | 福建汇得新材料有限公司 | Wet-process polyurethane resin and preparation method and application thereof |
CN114316206B (en) * | 2021-12-14 | 2023-10-24 | 福建汇得新材料有限公司 | Wet polyurethane resin and preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
CN101613451B (en) | 2011-04-06 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: LIAONING FIXED STAR CHEMICALS CO., LTD. Free format text: FORMER NAME: HENGXING FINE CHEMICAL INDUSTRY CO., LTD., LIAONING |
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CP01 | Change in the name or title of a patent holder |
Address after: 118003 Liaoning province Dandong City Zhen'an District Wu Ying Road No. 168 Patentee after: LIAONING FIXED STAR FINE CHEMICAL Co.,Ltd. Address before: 118003 Liaoning province Dandong City Zhen'an District Wu Ying Road No. 168 Patentee before: Liaoning Fixed Star Chemicals (Group) Co.,Ltd. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210420 Address after: 215000 No. 6 Sha Yuan Road, Suzhou Industrial Park, Jiangsu, Suzhou Patentee after: Jiangsu Zhuote Intellectual Property Service Co.,Ltd. Address before: 118003 Liaoning province Dandong City Zhen'an District Wu Ying Road No. 168 Patentee before: LIAONING FIXED STAR FINE CHEMICAL Co.,Ltd. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210622 Address after: 276000 Jiazhuang village, gaofengtou Town, Tancheng County, Linyi City, Shandong Province Patentee after: Tancheng Huachen Coatings Co.,Ltd. Address before: No.6, Shayuan Road, Suzhou Industrial Park, Suzhou, Jiangsu 215000 Patentee before: Jiangsu Zhuote Intellectual Property Service Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110406 Termination date: 20210805 |