TW442567B - Hard surface cleaning compositions comprising polymers - Google Patents

Abstract

Use of certain, relatively long chain, anionic water-soluble polymers in acidic or neutral surfactant compositions brings a primary cleaning benefit in addition to a secondary (anti-soiling) benefit. Commonplace acrylic, methacrylic and maleic anhydride derived polymers exhibit this effect in acidic solutions of nonionic surfactants to the same extent as expensive, quaternised cationic polymers. The invention provides liquid cleaning composition of pH 2-8, comprising: (a) 1-30% wt nonionic surfactant, (b) 0.005-5% wt of a water soluble, anionic polymer having an average molecular weight less than 1,000,000, said polymer being free of quaternary nitrogen groups.

Description

Α7 Β7 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, printed "Invention (i) Technology" 铕 "This invention has«-general purpose • Especially hard surface liquid ® »Jiejie compound * which includes interfacial activity Agent and polymer ingredients. Responsible for cleaning the hard surface (such as wood, glazed tiles * whitewashed gold tincture, etc.). • It is known to use M surfactant or solvent-based sister compound to remove B. * Lacquer, wax or brightener acts as a barrier to seal the surface and reduce the rate of redeposition of dirt. The two steps of cleaning and sealing are time consuming and complicated. It is known that ingredients can be incorporated into the K-Interactive _ master sister compound so that such ingredients can be deposited on the surface and provide a protective layer in a one-step cleaning operation. US 3679592 (1972) reveals a fermenting process Clean and anti-fouling adult products, including interfacial activity and 10 liters, especially 4¾ of the flag structure with a specific structure of the molecular S in the range of 500 to 100,000: in use * this sister compound It is said to inhibit the removal of contaminated deposits and ribbed dirt. GB 1528592 (1978) reveals a non-toxic flooring compound. It includes a molecular weight of 100,000 soluble in an aqueous solution of 8.5 or M. -2,500.000 organic polycarboxylic acid copolymer. These polymers are readily available from M commercial flea. GB 1534722 (1978) shows a granular milled surface cleaning compound. It includes interfacial activity, and polyvinyl alcohol or pyrrolidone and biopolysaccharides as " improved stick removal for dirt removal. &Quot; The molecular weight of these polymers is about -4 _ This paper size is applicable to the Chinese National Standard (CNS) M specifications (210 × 297 mm) 83.3.10,000 I --------- Packing ----- Order- ----— Line (Please read the precautions on the back before filling this page) 6 6 A7 B7 Printed by the Central Laboratories Bureau of the Ministry of Economic Affairs Printed by Shellfish Consumer Cooperatives V. Description of the Invention (2) 5000 to 360,0 00 Fanyuan • Provided by Kong Ledong. This sister compound forms an Ml-based solution. US 4252635 (1979) shows a water-soluble sickle hard-surfaced sister compound with a pH of 9-12. 100,000 "" animal cleansing power "of acrylic copolymer and anionic surfactant. US 07/297807 * as in EP 046472 A2 (CoUate Pa 1 · ο live) * proved on a hard surface clean In a mixed non-ionic surfactant system • Incorporating an ion-limiting polymer poly [dot- (methyldiethylammonium) ethyl-methacrylate] 15-20X Aqueous Solution • It can be improved after the pre-contaminated and cleaned ceramic tiles are easy to be washed again. Some ion-limiting polymers are slightly more expensive than commercially available acrylic and methacrylic polymers. And there are some doubts about the ring of quaternary nitrogen-containing refractory species. «Acceptability 〇 It is known that the surfactant-based cleaning compound contains help to provide good flow properties to enhance its distribution and compound pairing. Structural agents for the adhesion of clean hard surfaces, in particular, can provide enhanced adhesion to the soiled surface. Known agents include polymers such as polysaccharides, such as carboxymethyl divinyl and other chemicals. "Modified Cellulose Material * Xanthane" and other non-flocculating agents such as Biopolymer «er PS87, which are shown in US, Patent No. 4,329,448¾. Acrylic polymers, such as CARB0P0L®, can also be used as a structure. The amount of this structurant can be as low as 0.001X, but more typically at least 0.01X by weight of the sister compound. The further function of this structurant is suspension Granular ingredients such as mill stock-5-present Zhang Zhiji uses the Chinese National Standard (CNS) A4 specification (210X297 mm) 83.3,10,000 ------------ installation ------ order ------ line (please first Read the notes on the back and fill in this. 肓) Printed by the Central Ladder of the Ministry of Economic Affairs, Consumer Work Cooperative, Λ4256 «A7 · _B7_ V. Description of the Invention (5) It is also known that at least part of the esterified tree can be used. Pine cells and non-planar and at least partially esterified adducts of dicarboxylic acids or anhydrides or monocellular and aliphatic, cycloaliphatic or aromatic monocarboxylic acids without dicarboxylic acid or dicarboxylic acids or At least part of the cheated derivative of the copolymerization product of its anhydride is added as «. The purpose of this substance is to improve the wettability of the eosinophilic compound μ μ, which produces a “stripless” polished surface after drying. Typical examples of the latter type of Copolymer® are copolymers of ethylene, styrene, and vinyl-methyl® with butadiene-like acid, fumaric acid, itaconic acid, citraconic acid, and their anhydrides * Contains styrene / butadiene anhydride copolymer. EP 0467472 Α2 shows that polymers that promote the release of dirt, such as (but not limited to) cationic poly [/ 9-(methyldiethylammonium) ethyl-methacrylate] can also be effective with » Hatchling sex surfactant is used together. The application in the publication stated that "the adsorbed polymer forms on the surface the residual antifouling hydrophilic property of the polymer that promotes the release of dirt, and therefore requires less labor than those without the residual layer. Dirt deposited on it after removing it. Although it is better to use a polymer with a molecular weight higher than 50,000 for reasons of port resolution, the molecular weight range of the polymer falls within the range of 4,000-100,000. (See EP 3,467,472, page 3, paragraph 3). EP 0379256 (Xing Xing, similar sister of the above document) *, which contains _ 2 × weight of molecular weight in the range of 2,000-500,000 range of anti-static antistatic polymer. And its characteristics are acidic output of 2-4 and non-ionic interfacial activity ffl system with a weight of 2-4 ×. A specific example is “a non-carved system with a weight of 2.5 and including 2,2X weight and 〇 · 〇7χ specific ionicity --------------------------- order line (Please read the precautions on the back before filling this page) This paper Standards apply to the standards of the poor countries (CNS) A4 ^ (210X297 mm) 83.3.10,000 442567 A7 B7 Consumption of male workers in the Central Bureau of Standards, Ministry of Economic Affairs (4) Composition of polymer. This polymer can be regarded as having the function of releasing dirt. In addition to the above, it is known from US 4606842 to use low molecular weight polyacrylic acid. As a cloth wiping type glass, Jiejie's sister. Baker et al., Shown in US 4690779¾ on a hard surface. Jiejie uses a polyacrylic acid polymer with a molecular weight of less than 5000 and some non- Chronic interfacial activity m. The main function of this polymer in these systems is to serve as a sister. From the above, it can be seen that it is known to contain a certain kind of polymer on the surface of ordinary acids. When the compound is first used on the surface, the main cleaning effect can be obtained. Or, the surface can be modified to prevent the deposition of dirt to obtain a secondary cleaning effect, or to promote repeated cleaning. As explained in the "Examples later", The sister compound of knowledge usually cannot satisfy both the primary and secondary cleaning effects. The invention of the present invention has since determined that the use of some rather long bond-hardened hydrophilic polymerization can be achieved by using an acidic or neutral interface. Active agent In addition to the anti-fouling effect, it also has an unexpectedly major cleaning effect. Surprisingly * I have issued general acrylic, methacrylic acid, and polybutyric acid-derived polymer materials derived from non-carving In the acidic barren solution with a daughter interface activity, this effect can be regulated to the same degree as the expensive ionophore polymer. According to this, the present invention provides a liquid myelin complex of 2-8, including a) 1-30X weight of non-chrysene interfacial activity b; b) 0.005-5 »weight of water-soluble cationic polymer with average molecular weight below 1,000,000 * This polymer does not contain quaternary argon groups. -7- The size of this paper is applicable to China® Standards (CNS) A4 (21 × 297 mm) 83. 3.10,000 ----------------------- --- ,. line (please read the precautions on the back before filling this page) Amendment page of Chinese specification of patent application No. (February 1985) Α7 Β7 Amendment 1 V. Description of the invention It is a large part of the above-mentioned surface-active and surface-active polymers that are produced in the dirt. It is intended to be obtained, or the best. Ethylene, which is the best, and the best, acrylic acid are limited by any operating theory. The phase separation of the ionic interface activity is enhanced by the presently more effective deposit agent complex on the surface of the dirt. However, it is believed that the detergent of the water-soluble polymer causes penetration and / or sedimentation. This results in a concentration of the combination agent that does not contain the polymer; another interpretation is that a small range of water-soluble polymers can be formed by forming a trivial polymer, which is the basic composition of the composition of the present invention. * In the specific examples of the present invention. Acrylic or methacrylic polymers are preferred. Polymers of anhydrides or copolymers of multiple carcasses or copolymers with other monohips, including polyacrylic acid, copolymers of ethylene and methyl vinyl ether are maleic anhydride, methyl vinyl ether, and BM — poly Maleic anhydride and the aforementioned copolymers. Copolymers are more likely to form with ethylene. 5,000, preferably at least (please read the precautions on the back before filling out this page) Bureau of Standards and Missing Standards, Ministry of Economic Affairs Employees' cooperation in printing is relatively bad, and the molecular weight of the polymer is at least 50,000, preferably more than 100,000. The crude type · M surfactant-based cleaning composition includes at least 0,0, the most polymer of the product. . Unexpectedly found. The polymer storage boundary activator η agent w also has a positive effect when it is present in a very low amount, and it can be confirmed in the polymer. The paper size of the table at the beginning of this low concentration applies Chinese National Standard (CNS) Α4 Present (210X 297 mm), 442567 α7 Β7 Central Bureau of Standards, Ministry of Economic Affairs, MK: Printed by the Industrial and Consumer Cooperatives. 5. Description of Invention u) The properties are particularly advantageous in the application of the present invention where the degree of thinness is expected. The preferred amount of polymer is 0. 05 · 5.0 × resuspension. At this amount, the effect of preventing recontamination becomes particularly obvious. * The best polymer is 0.2-2.0 × weight. I have decided to use more polymers in order not to provide further benefits of general dilution of factors, but increase the cost of my sister compound. The most important polymers are the viscosity of the added products and hinder the product's ability to wet and penetrate dirt. However, for astringent products diluted before use, the initial amount of polymer can be as high as 5X. In the description of the present invention, the deionizing polymer is a similar polymer loaded with a negatively-charged or protonated state. A polymer oxalate may also be used. As mentioned above • The molecular weight of the polymer is less than 1,000,000 ear swallows * The molecular weight is increased • The polymer ’s S effect is reduced ”, and the sister compound of the present invention on this page includes at least one non-sickness Surfactant. The sister Hejun of the present invention includes cleaning active ingredients that can be buried in non-ionic cleaning active ingredients. We have determined that when anionic polymerization is used only with anionic interfacial surfactants *, or a large number of sticky complexes that include deionizing surfactants and non-diarrheal interfacial surfactants are used together * Adverse effects will occur. The non-refractory diarrhea active compound can be extensively described as the condensation reaction of the organic hydrophobic compounds of the nature of the hydrolyzed alkane "ghost street". The compound obtained. Hydrophilic condensation with any special hydrophobic group or the length of polyoxyalkylene residues-9-This paper size is based on Chinese national standards (CNS > Α4 格格 (210X297 mm) 83. 3. 10,000 d ^ · II—-I (Please read the precautions on the back before filling out this page) Order 442567 A7 B7 Elemental structure J 2 Sex M with water Every degree is like Cheng Cheng's need to be cl 2. TK Order 2 3 Yes. The production of δ-condensation and synthesis of complexes can be seen in the alkane, and it contains acetic acid, soluble in oxygen, {water regulation example ring, W Zhishi and ί W, easy to balance fermentation, M Kepinte splashes, etc. Central Ministry of Economic Affairs, Central Bureau of Standardization, Shellfish Consumer Cooperatives, Benben 15 Molar Ethylene Oxide, Plum Oil, Ethylene Oxide; Its alkyl portion contains 6 to 12 «carbon atoms of alkylphenol and per fluorene Alkyl phenol is a box compound of 5 to 25 oxiranes. • Condensate of ethylene oxide produced by the reaction of ethylenediamine and propylene oxide, containing 40 to 80X weight * of polyoxyethylene residue. Radicals with a molecular weight from 5,000 to 11,000; tertiary amine oxides of the structure R3N0, in which one R group is an alkyl group of 8 to U carbon atoms, and the other R groups are methyl groups, Ethyl or hydroxyethyl, such as dimethyl * dodecane K oxide; tertiary phosphine oxide of structure RaP0. One of the «R groups is an alkyl group containing 10 to 18 俚 carbon atoms * and the other R groups are each 1 to 3 «« Atomic alkyl or hydroxyalkyl • such as dimethyldodecane hydrazine; and dialkylarylene of the structure RaS0, of which one «R group is an alkane containing 10 to 180 carbon atoms Base while A group was a SR Acer or ethyl, such as methyl myristyl grinding alkylene; extracellular glucosamine and fatty acid hydroxyalkyl alkyl alcohols pickled. The amount of the nonionic cleaning active ingredient to be used in the sister compound of the present invention is usually 1 to 30X, preferably 10 to 20X by weight, and most preferably 12 to 20X by weight. Suddenly, it can be used for most applications: in the products diluted before use, but the active ingredients of Dong at about 15X are special, at higher temperatures, the cleaning performance of direct use is only slightly improved. . Depending on the situation, there may be a relatively small proportion of deionizing surfactants -10- This paper size applies to China's national kneading rate (CNS) A4 specification (210X297 mm) 83.110,000 —iln ——————— — II ^ »1 I # 111 · 11 n HI—— I —line (please read the precautions before reading this page before filling out this page) Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 442567 A7 _B7_ Description of the invention (θ) Suitable deionizing detergent active compound is water-soluble B having a molecular reaction product having a molecular structure of an alkyl residue containing 8 to 22 carbon atoms, and the residue is obtained from sulfonic acid or Taste ester residues and mixtures thereof. Examples of deionizing detergents are sodium fermented acid and sodium, especially those obtained by sulfonating high-grade enzymes obtained from beef tallow or glycerol ester of coconut oil; sodium and potassium alkyl besylate, such as the alkyl Those containing 9 to 15 sulfonic atoms; Sodium and potassium secondary alkane sulfonates; Sodium glyceryl ether grades of alkyl tank water • Especially those derived from high-fermented ethers of tallow and coconut oil; Gardenia oil fatty acid monoester Glycerol_Sodium gallate; Sodium and potassium salts of gallate from the reaction product of one mol of higher fat enzyme and 1 to 8 mol of ethylene oxide; 1 to 8 molecular units of trioxane molecules, and in which Alkyl phenol ring gas ethane ether sulfonates and potassium sulfonates with residues containing 4 to 14 sulphur atoms; reaction products of fatty acids which are methylated with isethionate and oxidized by sodium oxide, for example where fatty acids are derived From coconut oil and its mixtures. Preferred water-soluble synthetic anionic cleansing active compounds are ammonium and sulfonium-substituted ammonium (such as Jun · 2- and triethylenzyme), alkali metal sulfonium (such as sodium and potassium) of higher alkyl benzylsulfonium sulfonium, and sickle metal sulfonium (Such as calcium and magnesium) salts * and a mixture of olefin sulfonate and homopentane bowl acid, and higher fatty acids monoglycerides. The most preferred anionic cleansing active compound is a higher alkyl aromatic sulfonate, such as a higher alkyl alkyl sulfonate having 6 to 20 carbon atoms in the alkyl group and a straight or branched chain. A specific example is a higher alkyl sulfonate. Sodium salt of alkyl benzyl sulfonic acid or higher alkyl methane xylene or phenol sulfonic acid, sodium alkyl sulfonate, ammonium dipentylnaphthalenesulfonate and sodium dinonylnaphthalenesulfonate. Synthetic female chick cleansing activity I, V for use in the cleaning compound of the present invention! * Thread C, please read the notes on the back before filling in this page) -11- This paper size is free to use Chinese garden standards (CNS) Α4 grid (210X297 mm) 81 3.10,000 Central Standards Bureau of the Ministry of Economic Affairs Industrial and consumer cooperatives printed "2567 A7 _B7__ V. Description of the invention (9) Amount of ingredients > usually from 0.5 to 501 weight (based on all active ingredients), preferably less than 33X weight (K All active ingredients are Quasi). For products containing 15X heaviest weight of surfactants • The amount of interfacial active agent 涮 is preferably not more than 5X 霣 ft of the product. In the composition of the present invention, it is also possible to include both sexes Active ingredients for gardenia or amphoteric carp cleaning. Should be used according to the situation. Amphoteric Taojie active chemical Hejun is a cell family containing 8 to 18 atomic alkyl groups and M water-soluble groups. Derivatives of aliphatic secondary and tertiary amines such as sodium 3-dodecylamine propionate, sodium 3-dodecylamine propane sulfonate and H-2-hydroxydodecane * -N-methyl Ji Niu "Suona.« 宜 之 «Ionic Clear" The active compound is an aliphatic residue with 8 to 18 valence broken atoms Quaternary ammonium salts, such as deca-hexane trimethyl ammonium bromide. Depending on the conditions, it is suitable to be used in both sexes. The active compound is an aliphatic residue with 8 to 18 carbon atoms and a female sex. Aliphatic quaternary ammonium, amidine and scale compounds of water-soluble substituted aliphatic residues, such as 3- (N, N-dimethyl-H-hexadecylammonium) propane-1-sulfonic acid trimethylammonium ethyl Lactone · 3- (dodecylmethyl sickle) propane-1-sulfonic acid trimethylglycolide and 3- (hexadecylmethyl soft) ethane trimethylammonium glycolide. Tongyizhi Further examples of detergent active compounds are compounds commonly used as interfacial active compounds, such as the known "Schwartz and Perry's Education" "Surfactants", Volume I, and Schwartz, Perry and Berch "surfactants and cleaning Agents "listed in Volume I." Small,

I n I-n II nnnnn I (Please read the notes on the back of the fund before filling out this page) I I-. I! —___________ I -12- This paper size is applicable to China National Standards (CNS) A4 Washing (210X297) Shame) 81110,000 442567 A7 B7 printed by the Central Government Bureau of the Qing Dynasty Ministry of Labor and Consumer Cooperatives Fifth, the description of the invention (10) is usually 1.5 to 30X, preferably from 2 to 20X, and most preferably from 10 to 20X alas. The secondary compound of the present invention may contain other additives that are ribbed to its cleaning properties. For example, this compound may contain detergent ingredients other than the aforementioned specific water-soluble salts, such as hydrazone. _Acids, Polycarboxylates, Citric Acids, Dicarboxylic Acids > Water-soluble phosphoric acid < < >, in particular, a complex of polyphosphates, orthophosphoric acid phosphonium and pyrophosphate * zeolites and mixtures thereof. Such a serving may function as a thief if it is present in the amount of water solubility described herein *. Usually * when using this particular water-soluble ingredient, * it is preferred to use an amount of 0.1 to 25 × by weight of the compound. Multivalent chelating surfaces of metal sculptures such as ethylenediamine tetrahexate, amine-polyphosphate hydrazone (DEQUEST®) and phosphate M, and a wide range of other multifunctional anoic acids and hydrazones * are also visible Use situationally. A further optional component of the sister compound of the present invention is a K soap foam regulating substance, which can be used in the sister compound of the present invention which has a tendency to generate soap foam during use. One example of a soap foam regulating substance is soap. Soaps are STs of fatty acids and contain alkali gold tincture soaps, such as »salt 'potassium salts, ammonium salts and alkanes of high halogen fatty acids containing about 8 to about 24 carbon atoms, and preferably about 10 to about 20 carbon atoms. Fermented ammonium salt. Particularly useful are sodium salts and potassium M and monodi- and triethylammonium amines derived from a mixture of fatty acids derived from »seed oil and genistein oil. When used • The amount of soap may be at least 0.005 × ′, preferably 0.5 × to 2 × by weight. Further examples of soap foam adjusting substances are organic solvents, hydrophobic silica * silicone oil or hydrocarbons. (Please read the cautions on the back before filling this page) -13- This paper size applies to Chinese National Standards · (CNS) A4 wash case (210X297 mm) 83.110,000 442567 A7 B7 V. Description of the invention (u) In addition to the aforementioned ingredients, the sister compound of the invention * may also contain various other optional ingredients, such as by adjusting tincture, coloring »* brightening agent * dirt" floating agent, cleaning enzymes · compatible bleaching agents, coagulation control Agent, freeze-thaw stability and two, sterilization 觌 · storage purchase · solvent · fungicide, insect repellent, detergent water-soluble panyu and phosgene. Preferably, the sister compound of the present invention is substantially free of rhenium particles. Although grinding "the agent itself can provide additional cleaning effect", experiments have shown that the presence of abrasion thin will reduce the cleaning effect of the polymer. It is believed that this abrasive • interfacial activity »and the polymer will form a compound on the surface to be cleaned that will reduce the effective degree of the surfactant 6 As described above • The product of the present invention is acidic or neutral • Myself It has been determined that in these cases, improved cleaning and / or anti-recontamination effects can be obtained. The best product is 3-7, but the best product in the range of 3-6 is better, and the reason of the range of 4-6 is particularly good. It can provide the danger of acidity and the amount of lime removal. The balance of the advantages of the acid. According to the present invention, the Jiajie compound is a liquid aqueous solution with a fluidity of 3-6 ', which includes: a) 1010X weight of alkoxygenase, non-ionic interfacial activity · b) lower than 3X weight ft Carved surfactant, c) 0.2-2S weight ^^ 1 ^^^ 1 1 ·--丨 ί * ^^ 1 1 ^ 1 n (Please read the Please fill in this page again before ordering) Order I-line Ministry of Economic Affairs Central Bureau of Standards and Quarantine Bureau Shellfish Consumer Cooperative Co., Ltd. Printed acid-butane-prone polyacrylic acid * methacrylic acid methylene, oligoacrylic acid to methacrylic acid, ether. It is an alkenyl compound of ethinyl aziridine and polymethyl methacrylate, and it contains, I, olefins, and oligomeric compounds, and stupid polymers. Intrinsic anhydride, benzene, hexanoic acid, ethyl ions, and diisocyanates * The nature of Ding _, and the color of the second, water or olefins-14- This paper size, using China National Standard (CNS) A4 size (210XW7 mm) 83. 3.10,000 Printed by the Bayer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Equipment 442567 A7 B7 V. Description of the invention (12) In order to further understand the present invention, it can be explained by following examples and with reference to the accompanying drawings, in which: Figure 1 shows the polymer concentration versus cleaning power and anti-recontamination. The effect of fruit is sculpted. · 1 Figure 2 A pseudo-blue ring shape showing the major and minor cleaning effects of the polymer type. The following substances are used in Examples 1-8:

Sokolan Series (TM) Gantrez Strip (TM) Scripset 520 (TM) EMA 31 SCMC (Courlose A600) 6047 Polyacrylamide FRS 3966 Jaguar C162 Polyoxyethylene-Polyvinylpyrrolidone such as BASF such as GAF such as Monsanto Monsanto company such as Monsanto, such as Courtaulds, Cote, Co., Ltd., such as `` Co., Ltd., such as Maiha Corporation (WSRN 80), such as United Carbonation Corporation, such as PolyScience, and polyethylene DT rolidone, has a molecular weight of about 386,000 channels. .窨 莉 1 a-Γ. J > j 皤 "芊 柹 物 物 物 夕 屮" Μ 呗 mist deposits 0.25 g / cm² (based on non-volatile content) of dirt J deposited in the area of A4 size " On the test surface of "DECAMEL" (RTM such as 赝 米加), the dirt system includes 1¾ tripalmitate glyceride in methylated alcohol, 0.5! S triolein, 0.53J kaolin, 0.2X liquid rock. , 0.1X Brown-15- This paper size is applicable to China National Standards (CNS) A4 format (210X297 mm) 83.3.10,000 i " 矣 (Please read the notes on the back * before filling this page) Ministry of Economic Affairs tCentral Bureau of Standards Consumer Cooperatives Cooperative Policy 442567 A7 B7 V. Invention Description (13) «Acid, 0.02X carbon black. The dirt was aged in the room for 24 hours before cleaning. The effectiveness of using fiber sponge cloth to remove dirt from the test surface. The R-sides include non-androgenic surfactants and water with or without polymers. The surfactant used was Iibentin 91-35 0FA (TH) (C9-C11 alkyl, 3-5 E0 alkyl ethoxide such as KOLB). The polymer exemplified in the present invention is polyacrylic acid (e.g., 8DH) having an average molecular weight of 230,000 channels. The phosphonium ionic polymer used in the comparative example is the polymer JR-40 0 (TM: such as Union Genghua) | and has an average molecular weight of 400,000 channels. The required efficacy in formulation and cleaning operations are shown in Table 1 below. The result obtained is the geometric mean of 8 replay tests. In order to remove the day-to-day variables and normalize the differences proposed in the amount of dirt data, the same polymer-free sister compound was used.效力 DECAMEL magnetic thin film required to maintain constant efficiency. As can be seen from the results obtained by His Majesty's Majesty, the sister compound of the present invention has a better cleaning performance than the comparative example la which does not contain polymer. . To study the recontamination performance * Use the same dirt and the same cleaning tools to recontaminate and reclean the DEC ΑΜΕΙΓ Η. The cleaning results of the first and second recleaning cycles are shown under "Same (2)" and "Same (3)". These results show the significant effect of the presence of polymers. As for the polymer-free sister compound (see Example 1a), the potency in the post-sugar cleaning cycle remains essentially constant. This shows that cleaning the surface with a polymer-containing sister compound and subsequently cleaning the surface with the same sister compound requires significantly less potency. i I pack I I I order — I I I I line (read the precautions on the back before filling out this page) This paper size is not applicable to Chinese National Standard (CNS) Μ specifications (210X29? mm) 83. 3.10,000 442567 Μ Β7

V. Description of the invention (14) The results under "Normal Sister (4)" are obtained by cleaning the test surface used in Example la-e after sugar cleaning of the sister compound used in MS Example la (that is, only the surfactant). As a result, this shows that when the test surface is cleaned with a conventional compound containing only a surfactant, the test surface can be cleaned of the effect of the present invention. It should be noted that if it is not better than that achieved by the quaternary polymer (such as those used in Comparative Examples Η and Id), the initial cleaning effect of the polymer of the present invention (Example 1 (: and le) can be compared. H_L

la lb lc Id le Imbentin 10% 10% 10% 10% 10% polymer-.25%-1%; polyacrylic acid (up to 230KD in Moore)--.25%-1% water to 100X Ph 4.2 4.4 3.7 4.6 3.3 Initially 1.29.24.36.25 is the same (2) 1.11-15.12.14 is the same (3) 1.05.06.06.06 Normal group.1.18-18.17. 21 Fenji 2d-g polymer XI Xi (Please read the precautions on the back before filling out this page) Assembling and Threading Central Printing Bureau of the Ministry of Economic Affairs—Industrial and Consumer Cooperative Cooperative Printing The formula is repeated »Example 1: But the polypropylene-17 used in this paper is applicable to the national standard (CNS) Α4 size (210X297 mm) of the country t. 83. 3.10,000 Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs 44256 ^ A7 B7 V. Description of the invention (15) The enoic acid is VERSICOL E11 (RTM) (such as Lianjiao Rubber Co., Ltd .: Moore weight 250KD). The effectiveness of this DECAMEL (RTM) tile is the effect of K. (M 10 is a mole). Weight "with and without polymer and examples of cocoon concentration at different interfaces. The value obtained is the average of 4 repetitions." Initially The result is obtained by using the sister compound with the specified polymer. The result of the "normal sister (1)" is the result obtained by using the sister compound without the polymer. 0 "The same value (2) " The polymer-containing sister compound, Ji Jiefeng's tile, is then cleaned to obtain the result *, and the original tile cleaned using the same sister compound M in the same way is listed under "Initial (1)" The result. The value of "normal sister (2)" is the result of recontamination of the magnetic confinement in the "normal sister (1)" of polymer-free sister compound with the same surfactant 霣. Normal The value of sister (3-5) is obtained by pseudo-M containing no polymer sister, and the cleaned tile (the result of "interphase (2)") that was originally cleaned by polymer containing sister compound. All re-cleaning * In the normal sister (3-5) column, the same amount of interfacial activity _ (7 × weight: ΙΜΒΕΝΤΙΝ) is used. IIIIIIII installed IIIII order I line (please. «Read the precautions on the back before (Fill in this page) The paper scale is applicable to China National Sample Rate (CNS) Α4 Washing (210 × 297 mm) 83. 3.10,000 6 .Vi

7 7 AB V. Description of the invention (16) 2d 2e 2f 2g Imbentin 16% 8% 4% 2% Polypropylene ((mole weight 250)) 1% 0.5% 0.25% 0.15% Water is added to 100S for the initial potency Logarithmic initial (1) 2.36 2.38 2.69 3.35 normal sister (1) 2,37 3.04 3.43 ★ ★ * ★ same (2) 2.18 2.14 2.18 -2.80 normal sister (2) and normal "(1) than without significant reduction Μ without aggregation The property owner's "same (2)" and then clean the normal (3) '2ΛΊ 1,98 1.99 2.02 normal group (4) 2.86 2.92 2.90 2.83 normal sister (5) 3.02 3.04 2.99 3.03 order ^ (please. First read the notes on the back and then fill out this page.) Printed by the Central Standards Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives. According to the results, it can be seen that the presence of polymers has the main cleaning effect: that is, the presence of polymers is greater than the absence of polymerization. The owner needs less cleaning effectiveness (compare "normal sister (1)" result with "initial (1)" result). The degree of this effect increases dramatically at lower surfactant concentrations. This is believed to be due to the excellent primary cleanliness expected under high surfactant 1 masking the effect of the polymer. It is proved in Example 2g that the use of low -19 in the absence of polymer is applicable to this paper standard (CNS} A4 size (210X297 mm) 83.3,10,000 442567 Ministry of Economic Affairs Central Government Bayer Consumer Cooperative India A7 B7 V. Description of the invention (17) It is impossible to clean the tile with a reasonable amount of interfacial activity and use of reasonable efficacy. It can also be seen that the effect of the polymer remains in the subsequent cleaning cycle. The cycle failure will increase and decrease. Obviously, the low amount of polymer and interfacial activity will be slightly improved, and the secondary cleaning performance will be slightly improved. Therefore, including the low amount of surfactant and polymer sister compound The cleaning power is at least equal to that of the sister compound containing a higher amount of these ingredients. Comparing 2d and 2f, there are four times the amount of surfactant and polymer, but the same efficacy is required to clean the tile The sister compound that does not contain a polymer cannot be cleaned when there is only a low amount of interfacial activity. It also holds that the sister compound that does not contain a polymer does not reduce the required efficacy under repeated use. H-1 than city Evening SP Xian Erjun uses a very dilute solution of the products listed in Table 2c. • Comparative example 2h-21 potency. These sister compounds are diluted to the general floor cleaning dilution recommended by the manufacturer (about 3g / The formula for S8 cases of the present invention is: 285 IMBENTIN, 2X polyacrylic acid (250 KD: VERSICOL Ell (RTM)). If the footwear rubber warming company only uses the formula of the non-diarrheal comparative example, the polymer is omitted. The percentage of dirt removed on a hydrophobic surface as measured by the standard colorimeter method after 40 cleansing strokes. * SHEEN (RTH) type string linearity was used at a pressure of 80 g / cm2. Those who obtained the cloth. The surface is DECAMEL UTM) and the pre-contaminated by K0.061 mg / cm2 (based on non-volatile content). The cleaning is pre-impregnated with the appropriate cleaning solution-20-- ------ l · —Packing— (Please read the notes on the back before filling in this page) The size of the paper for the thread guide is applicable to China National Standard (CNS) A4 (210X297 mm) 83 · 3,10,000 442567

A B V. Description of the invention (18) Liquid fibrous sea nickel. Under the same conditions but under a single cleaning blow *, the same dirt was applied to the ceramic floor tiles to determine the percentage of dirt removed on the hydrophilic surface. Results. * Both tests are performed under the following three series of soil types: a) IX tripalmitate in methylated alcohol * 0.5% glycerol trioleate, 0.5X kaolin &gt; 0.2X liquid Paraffin &gt; 0.1X palmitic acid, 0.02X carbon black (ie 80:20 fat: particulate matter) b) 50: 50 fat: particulate matter like (a), and c) 20: 80 like (a) Cell: Particulate matter. These three types of obscure model soils and two types of surfaces are used to illustrate the actual performance of the composition. Each of these three types of dirt was repeated 3 r times and the average of all 9 measurements shown in the table was taken as the actual performance index of the compound on the surface shown. Lane 3: Printed sample solution DECAMEL by the Central Bureau of Standards, Ministry of Economic Affairs, Consumer Cooperatives »Magnetic 2h. With" Example. 65% 47% 2i Non-ionic only 58% 35% 2j ajax compact house (RTM) 45% 30% 2k Super Flash (RTM) 40% 12% 21 Flash Liquid (RTM) 28% 8% From these results, it can be seen that the inventive examples of the present invention are significantly easier to perform than the comparative examples under the above conditions. -21- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 83. 3.10,000 --------- ^ ------ 1T --- <--- 0 (. # Please read the notes on the back before filling in this page) A7 B7 Printed by the China Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, Co., Ltd. 5. Description of the invention (β) In further experiments • It was determined that the “2 The comparative formula of the black ceramic tile compared to Example 2i-2I has less retentate and enhanced brightness (determined by gloss reading). Yin-Jiang interface activity _ / Except for "Sichuan plant compound use simple formula made only with water containing anionic surfactants and with and without Yinjiao or cationic polymer repeat Example 1 . The surfactant used was the magnesium salt of PAS. The overcast sickle polymer is the polyacrylic acid used in Example 1.隈 Ionic polymer is the polymer used in Example 1 The JR ° formulation and the efficacy required for cleaning operations as described in Example 1 are shown in Table 4 below. The round form is the average value of 8 repeated tests. It is normalized to indicate that the sister compound without polymer usually requires this same cleaning efficacy data. The initial cleaning performance numbers are listed in "Initial (1)". It can be seen that the polymer-containing composition (3b-3e) does not have a significant main cleaning effect, but is usually better than similar polymers without polymer. (Such as Example 3c), it is more difficult to clean the surface with an anionic ionic polymer containing a deionizing or ion-limiting polymer. It can be seen that compared with an ionic polymer containing no polymer, The polymer's sister compound was originally about 2.5 times more effective. To study the recontamination performance • Use the same tool to recontaminate and reclean the DEC AMEL film. Cleaning by the first and second recleaning cycles The results are described in the "same (2)" and "same (3)" machines. These results show general negative effects. • Believe that there is a pseudoactive polymer and the interfacial activity of the same kind of charge. Therefore, the result of the normal sister (4) "椤 is the sister compound used in Example 3a, followed by Jijie-22- This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 83. 3.10,000 II! IIIIII order-IIIII line (please read the precautions on the back first (Fill in this page) In A7 B7 V. Description of the invention (2〇) The results obtained from the test surface used in Example 3a-e *, that is, only interfacially active cocoons (essentially known compounds) are cleaned without polymer . This shows that the negative effects of dangerous ionic polymers still remain when the test surface is cleaned with a sister compound containing only Jinzhi surfactants. This result also shows that meteorological ionic polymers exhibit a secondary cleaning effect * which is pseudo-invisible to anionic polymers in the presence of deionizing interface activity. 3a 3b 3σ 3d 3e Magnesium-PAS 5% 5% 5% 5% 5% Polymer JR 0.25%-1% — Polyacrylic acid--0.25%--1% Water is added to 100X Ph 6.5 5.5 3.4 5.3 3.0 Initially (1 ) 1 1.18 2.42 1 1.18 same (2) 1 0.20 2,10 0.18 1.10 same (3) 1 0.15 2.01 0.16 0.90 normal sister (4) ~ 1 '0.22 1.47 0.22 1.26 — II.—, u 1 II —ϋ i 11 :: 111- 、 tTI: I / I. .1 I (Read the precautions on the reverse side before filling out this page) Printed with erbium ion polymer (Polymer JR) in the Shell Standard Consumer Cooperative of the Ministry of Economic Affairs, China Similar experiments were performed with strong ionic surfactant (trimethylammonium phosphonium tetradecyl sulfate). It can be seen that there is no rose fruit. It is believed that this lack of effect is due to the surfactants and polymers with the same charge, so the surfactants and polymers cannot form lysates. 23- This paper is applicable to China National Standard (CNS) A4 (210X29) ·; Mm) 83.3.10,000 2567 A7 B7 V. Description of the invention (21)

SJ0U ian other polymer B; »Use the substances listed in Table 5 below for further enumeration. The formula is made from non-jasmine surfactant (10X weight) and water with and without polymer. The surfactant used was Inbentu 9 and 35 OPA (C9-C11 alkyl, 3-5 E0 alkyl ethoxylate). The polymer pseudo-list is listed and S is present at 0.5X weight. The results were normalized so that the initial potency of only M surfactant was 100 J !. Only the 7.5 × reset aqueous solution of non-ionic surfactant was used to clean the surface and measure the required efficacy to evaluate the recleaning effect: the results were again normalized assuming that the cleaning efficacy of only the surfactant was 100 ×. --------- Installation-- (Please read the note on the back of the page before filling in this page) Printed by the Department of Economics and Standards of the Central Bureau of Standards for Consumer Cooperative Du printed -24 National Standard (CNS) A4 specification (210X297 mm) 83. 3.10,000 442567

AB V. Description of the invention (22) Printed by Zhengong Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs 4 Initially cleaned butadiene anhydride copolymer. Propylene 4a Sokolan CP12 (TM) 24 10 4b Sokolan CPU (TM) 32 17 Methyl vinyl ether 4c Gantrez AN119 (TM) 25 8 4d Gantrez AN169 (TM) 34 12 Stupid ethylene 4e Scripset 520 (TM) 29 9 Ethylene 4f EMA 31 22 -11 Carboxylated polymer 4g SCMC 48 22 Polypropylene amine 4h 6047A 34 21 4i 6047B.: · 42 26 4j 6047C &quot; 47 23 4k 6047D 82 16 41 FRS 3966 80 24 Modified Guar] Jaguar Cl62. 54 J 22 Non-carved polymer 4n Polygasified Ethylene 29 49 4〇 Polyvinylpyrrolidine means 37 43 '25-This paper size applies to Chinese National Standards (CNS &gt; M Specifications (210X297 mm) 83. 3.10,000 -------- -Meal ------ ΐτ --- ^ --- line (please read the notes on the back and fill in this page again) Print the A7 B7 Five 'Invention Note (3) ) These results are shown in the shape of Figure 2. In this beautiful, the primary (primary) and secondary (re) (Clean) Performance _ on individual axes. The data of reference surface 2 is referenced in a seating manner. Examples of non-ionic polymers as described in GB 1534722, such as coating agent P0 (at 49, 29) Although PVP (43, 37) has good main cleaning performance, it has a particularly poor re-cleaning effect. Although this tendency indicates that the two factors have opposite effects, that is, the best in one case. Jie will be accompanied by "another poor performance, but» ionic polymers show some effects at the same time in the primary and secondary cleanings. · Compare polypropylene (82, 16) »amine and (42, 20) ) Of polypropylene "amine. It can be clearly seen from the surface 2 that the effect obtained by the deionizing polymer of the present invention is obtained, in particular, glutaric anhydride copolymer, preferably with styrene, Acrylic acid • methyl vinyl ether and copolymers of ethylene. This result shows that in addition to carboxymethyl cellulose (22, 48) and Sokolan CP13 (TM) (17, 32) Μ, Among the secondary cleanliness, the anionic polymer is better than all comparative examples, showing improved performance 0 S 5 R was Bu it will see the too Ya insert 1 »which shows polymer concentration (230 kD, such as BDH) on cleaning effect and anti-Qing recontamination * Movies effect of embroidery. The properties of all sister compounds are 4 * and include 10X by weight of the surfactant Unbent in 91-35 OFA: C9-C11 alkyl, 3-5 E0 alkyl ethoxylate). The effect of cleaning and re-pollution prevention was evaluated as in Example 4. I n IHII —— I! I —— III Order 1 line (please read the note ^^ on the back before filling this page) -26- This paper size applies to China's national kneading rate (CNS &gt; A4 size (210X297)嫠) 83. 3. 10,000 442567 A7 B7 V. Description of the invention (24) This circular formula shows that the sister compound of the present invention is even under the lowest polymer • the initial (main) cleaning effect becomes obvious, and Hold on to the increase in the amount of polymer. The anti-recontamination effect becomes obvious with the polymer of about 0.2X and #continued again. This is consistent with the results obtained in Example 2d-g. 窨 Example 6 Crude Table 6 shows the effect on the compound of the present invention including 0.5X polyacrylic acid polymer (23kD, such as BDH) and the comparative compound containing no polymer. All compositions include the amount of 10X Li Dong Surfactants (Iibentin 91-35 OFA: C9-C11 alkyl, 3-5 E0 alkyl ethoxide). Modified from K NaOH. As in Example 4, the cleaning and anti-recontamination effects are more critical. Cleaning effectiveness Expressed as the logarithm of the required potency (base M 10): 羌 β Major i ft Force Minor potency PH Including Compound does not contain polymer. Polymer does not contain polymer. 6a 3.5 2.25 2.45 2.25 2.72 6b 5.0 2.30 2.45 2.30 2.72 6c 7.0 2.50 2.45 2.85 2.72 6d 9.0 2.70 2,45 2.72 2.72 (Please read the first (Please fill in this page for attention)

.II line of the Ministry of Economic Affairs, Central Bureau of Standards and Quarantine Bureau, shellfish consumer cooperation Du printed, it can be seen that at low levels, especially below 7.0, the major and secondary cleanliness of polymer systems are included. Significantly lower than a composition that includes only non-chicken sex. -27- This paper size is applicable to China® Home Standard (CNS) M specifications (210 × 2 to 7 mm) 83.3.10,000

Claims (1)

&gt;, Α8 4s'- Β8 丨 C8 ___....-D8 y! ί 苐 53 Want to issue a case "Chinese application for patent scope revision ΕΕΪ (37 years ΪFebruary) Application for patent scope 丨 丨 _fill '1 J ._ · .-... · μρι_ 1. A hard surface liquid cleaning compound containing 3 to 7 containing-· a) 1-30 weight S: ethoxylated C8-C22 alcohol with 2-25E0 or C6-C12 alkylphenols are non-sexy surfactants, b) less than 3% by weight of genitals surfactant, c) 0.2-2% by weight and having an average molecular weight greater than 100,000, but A water-soluble, anionic polymer of less than 1,000,000. The polymer is composed of at least one of acrylic acid, methacrylic acid, or succinic anhydride, and acrylic acid, methacrylic acid * maleic anhydride, ethylene, styrene, and At least one polymer of methyl vinyl ether, and the polymer is substantially free of quaternary gas groups' wherein the ratio of polymer: nonionic surfactant is 0.1: 1 or lower · d ) The difference is made up of conventional ingredients. I-—-II--I 1 = i—----. I I. 1 1 (Please read the notes on the back before filling Page) Ministry of Economic Affairs Central Office staff standard Falcon consumer cooperatives printed paper ------- This scale applies China National Standard (CMS &gt; Μ wash grid (2 0Χ297 mm!)