TW418225B - Synthetic paper and inkjet recording paper with the use of the same - Google Patents
Synthetic paper and inkjet recording paper with the use of the same Download PDFInfo
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- TW418225B TW418225B TW87100979A TW87100979A TW418225B TW 418225 B TW418225 B TW 418225B TW 87100979 A TW87100979 A TW 87100979A TW 87100979 A TW87100979 A TW 87100979A TW 418225 B TW418225 B TW 418225B
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413225 ' A7 A7 _______ B7 五、發明説明(1 ) 發明蘇.園 本發明係關於一種由延伸聚烯.煙樹脂薄膜所製成之合成 •紙,其在平版適印性及噴墨油墨固著性質上特別優越,以 及關於使用此合成紙之喷墨記錄紙。 發明背景 已知由延伸薄膜所製成之合成紙,係包含結晶性聚缔烴-樹月曰組合物作爲載體,譬如含有〇.8至4微米平均粒子大小 之碳酸鈣粉末之聚丙烯與高密度聚乙烯(美國專利4,341,88〇 、4,340,639及4491J19)。此等合成紙已在市場上以商標 ”YUK) FPG"、_'YUP〇 KPG”、,,YUP〇 SGC"等銷售,得自 oji Yuka Koseishi公司,及”Polyak π",得自英國BXL公司。 經濟部中央標準局員Η消費合作社印製 在此等合成紙中採用之碳酸鈣粉末,係包括:⑴經乾磨 重質碳酸鈣粒子,具有平均粒子大小爲!至1〇微米;⑺經 由將上述乾磨粒子篩選或分類,而具有所要粒子大小(〇 5 至1微米)者;(3)合成膠態碳酸鈣粒子,具有粒子大小爲 〇.〇3至0.2微米;(4)經乾磨重質碳酸鈣粒子,已使用脂肪酸 之金屬鹽進行表面處理;及(5)碳酸鈣粒子,帶有經黏附,於 其上之分散劑,其已利用陰離子性聚合體分散劑,經由將 碳酸鈣分散在水性媒質中,濕磨,然後乾燥而得。 由於經乾磨重質破酸鈣粒子具有1微米或高於1微米之大 的平均粒子大小,故空隙係在延伸薄膜中環繞此等粒子形 成,因而,裂缝顯現在此薄膜之表面上/在平版印刷之步 骤中’油墨會滲入此等裂缝中’其會造成光澤損失。因此 ’此等碳酸鈣粒子不能夠使用在高品質印刷上,譬如具有 __________-4- 本紙張尺度適用中國國家標準(CNS ) Μ規格(210X297公釐) ^18225 A7 B7 五、發明説明(2 經濟部中央標準局員工消费合作社印製 優越光澤之海報,而是限私—如田、合、 J疋限於一般用途义印刷紙,馨如贺 與書籍。 ~ 當與結晶性聚烯烴摻合時,已在乾磨期間使用脂肪酸之 金屬鹽表面處理過之重質碳酸鈣粒子,會改良分散能力, 但不會施加防止光澤損失之作用。經由將碳酸鈣粒子分散 在水性媒質中,並利用陰離子性分散劑,研磨,然後乾 所獲得之碳酸舞粒子’幾乎不能夠使用於合成紙i,因爲 難以將其研磨成初生粒子,且其會形成嚴重之次生聚集體 0 另一方面,輕質碳酸鈣粒子不能夠良好地分散在結晶性 聚烯烴樹脂中,且經常遭遇聚集作用,此係由於其小的平 均粒子大小(0.2微米或較小)所致。在延伸後,此等聚集體 於合成紙之表面上呈現過大凸出β於是,此等凸出會從紙 表面分離出來,且因此造成稱爲白點之影像缺陷,其會擾 亂具有高清晰度之印刷(jp_B_6_55549、jp_b-5-51900 ; "jp-B” 一 詞,於本文中使用時,係意謂"經過審查之日本專利公告ti. 〇 在此等情況下.,本發明之目的係爲提供一種平版印刷用 紙,其允許油墨之快速乾燥,且不會遭受光澤損失,—種 適合用於凹版印刷等之合成紙,及一種使用此合成紙之嗜 墨.記錄紙。 發明摘述 因此,第一項發明係提供一種由延伸樹脂薄膜所製成之 合成紙;該延伸樹脂薄膜係.經由延伸一種樹脂薄膜而獲得 請 先 •閲 讀 背 之 注 意 事 項 f 裝 訂 5 - 本纸張尺度通用中國國家標準(CNS )人4规格(210X297公釐 B7 五、發明説明(3 ) ’此薄膜具有一種樹脂组合物作爲載體,此组合物包含: (A)該組合物重量之3〇至80 %之結晶性聚烯烴樹脂;與㊉) 孩組合物重量之70至2〇 %之碳酸鈣粒子,選自包括: (M)具有平均粒子大小爲〇.3至2微米之經研磨破酸匈粒子 ’其係經由在水性媒質中,於0.05至2重量份數之分散劑存 在下,濕磨100重量份數之碳酸鈣粒子,.接著乾燥而製成-’該分散劑包含一種由.10至95莫耳。/。選自二烯丙基胺鹽與 燒基晞丙基胺鹽之胺鹽與90至5莫耳。/。選自丙烯醯胺與甲 基丙缔醯胺之醯胺所形成之共聚物;與 怒漓部中央標準局員工消費合作社印製 (b2)具有平均粒子大小爲〇.3至2微米之經研磨碳酸約粒子 ’其係經由在水性媒質中’於〇_ 05至2重量份數之分散劑存 在下,濕磨100重量份數之凝酸鈣粒子,該分散劑包含— 種由10至95莫耳0/。選自二婦丙基胺鹽與烷基烯丙基胺鹽之 胺鹽與90至5莫耳%選自丙烯酿胺與甲基丙婦酿胺之酿胺 所形成之共聚物,然後在水性媒質中,使用〇·5至1〇重量份 數之一種磺酸鹽’處理經如此研磨之產物,接著乾燥而製 成’該確酸鹽係選自單羥醇之氧化烯加成物之靖酸鹽、烷 基磺酸鹽及烷基苯磺酸鹽;及其中該延伸係在溫度低於作 爲成份(A)採用之結晶性聚烯烴樹脂之熔點下進行。 第二項發明.係提供由本發明合成紙所製成之噴墨記綠紙 ,以致在將具有下列组成之水彩油墨(總計100重量。/。)滴 落至其表面上時,該水彩油墨對該記錄紙t之接觸角係爲20 至 42〇 : C.I.食品級黑色2號 2重量0/〇, _ _ - 6 - 本紙張尺度適用中國园家標準(CNS.) Λ4規格(2iix 297公釐) ~ ' 413225 Μ Β7 五、發明説明(4 N-甲基-2-四氫ϋ比洛酮 二乙二醇 聚乙二醇(分子量:200) 水 10重量%_, 20重量%, 15重量%,及 53重量%。 經濟部中央標準局貝工消f合作社印製 細由調整碳酸鈣粒子之平均粒子大小達〇·3至2微米,則 表面裂缝之直徑與深度可加以控制,因此油墨.可快速地乾 燥,而不會造成光澤損失。由於碳酸鈣粒子具有一個含氮 I陽離子性聚合體作爲分散劑’黏附至其表面上,故油墨 可良好地黏附至合成紙^ _ 發明_ j^述(A)結晶性聚婦烴: 作馬合成紙之載體樹脂使用之結晶性聚烯烴,較佳係使 用烯烴,其具有結晶度(藉χ_射線繞射法或汲分析測定 爲10至乃%,較佳爲20至75%,且係選自具有2至8個碳原 子之α _婦烴(乙烯、丙晞、丁烯4、己烯q、庚烯4、辛 烯-1、4-甲基-戊烯-i、3-甲基-戍稀4等)之均聚物,及2 至5種譬如上文引述之α _烯烴之無规則或嵌段共聚物。 更特定言之,結晶性聚婦煙之實例,包括分枝狀或線性 聚乙烯,其具有密度爲〇 89〇至〇 97〇克/立 、, ,乂万公分,及熔融 流動速率(l9〇°C,負載2_16公斤)爲〇.2至5〇克/ 1〇分鐘, 烯均聚物,其具有像融流動速率(酿1載216刀公斤^ 0.2至50克/ 10分鐘,丙烯/乙烯共聚物,、丙烯/ 丁烯1业 聚物,丙烯/乙烯/ 丁晞^共聚物,㈣/4_甲基戊 共聚物’两烯/3-甲基-戊綿'!共聚物,丙烯/乙烯以曱 本紙張尺度適用中國园家標準(CNS ) A4現iTT7l^297公Ϊ丁 f請先閱讀背面之注意事項^本頁) -裝413225 'A7 A7 _______ B7 V. Description of the invention (1) The invention Su. The invention relates to a synthetic paper made of stretched polyolefin and smoke resin film, which has good printability in lithography and fixed by inkjet ink. It is particularly superior in nature, as well as inkjet recording paper using this synthetic paper. BACKGROUND OF THE INVENTION It is known that synthetic paper made of stretched film contains a crystalline polyalkylene-zukiyaki composition as a carrier, such as polypropylene and calcium carbonate powder containing calcium carbonate powder with an average particle size of 0.8 to 4 microns. Density polyethylene (U.S. Patents 4,341,88, 4,340,639, and 4491J19). These synthetic papers have been sold on the market under the trademarks "YUK) FPG ", _'YUP〇KPG" ,, YUPOSGC ", etc., available from oji Yuka Koseishi, and "Polyak π ", available from BXL, UK The members of the Central Standards Bureau of the Ministry of Economic Affairs and the Consumer Cooperative printed the calcium carbonate powder used in these synthetic papers, including: ⑴ dry-milled heavy calcium carbonate particles with an average particle size of! To 10 microns; The above-mentioned dry-milled particles are screened or classified to have a desired particle size (0 to 1 micron); (3) Synthetic colloidal calcium carbonate particles having a particle size of 0.03 to 0.2 micron; (4) dry-milled Heavy calcium carbonate particles, which have been surface-treated with metal salts of fatty acids; and (5) calcium carbonate particles with a dispersant adhered to them, which has used anionic polymer dispersants, Dispersed in an aqueous medium, wet-milled, and then dried. Since the dry-milled heavy calcium acid particles have an average particle size of 1 micron or more, the voids surround the particles in the stretched film shape As a result, cracks appear on the surface of this film / 'ink will penetrate into these cracks' during the lithography step, which will cause loss of gloss. Therefore, these calcium carbonate particles cannot be used in high-quality printing, For example, with __________- 4- this paper size applies Chinese National Standards (CNS) M specifications (210X297 mm) ^ 18225 A7 B7 V. Description of the invention (2 The staff consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed a poster with superior gloss, and It is restricted for private use-Rutian, He, J 疋 is limited to general-purpose printing paper, Xinruhe and books. ~ When blended with crystalline polyolefin, the surface treatment of metal salts of fatty acids has been used during dry milling. Calcium carbonate particles will improve the dispersing ability, but will not prevent the loss of gloss. By dispersing calcium carbonate particles in an aqueous medium, grinding with an anionic dispersant, and then drying the obtained carbonic acid dance particles' almost Can not be used in synthetic paper i, because it is difficult to grind it into primary particles, and it will form severe secondary aggregates. 0 On the other hand, light carbonic acid The particles do not disperse well in the crystalline polyolefin resin and often encounter aggregation effects due to their small average particle size (0.2 microns or smaller). After elongation, these aggregates are on synthetic paper On the surface, there are too large protrusions β, so these protrusions will be separated from the paper surface, and thus cause image defects called white dots, which will disturb printing with high definition (jp_B_6_55549, jp_b-5-51900; The term " jp-B " as used herein means " examined Japanese patent publication ti. 〇 In these cases, the object of the present invention is to provide a lithographic printing paper which allows Fast drying of ink without loss of gloss, a kind of synthetic paper suitable for gravure printing, etc., and an ink-loving and recording paper using this synthetic paper. SUMMARY OF THE INVENTION Therefore, the first invention is to provide a synthetic paper made of an extended resin film; the extended resin film is obtained by extending a resin film. Please read the notes on the back f binding 5-this paper The scale is in accordance with the Chinese National Standard (CNS) Standard 4 (210X297 mm B7) V. Description of the invention (3) 'This film has a resin composition as a carrier, and this composition contains: (A) 30% of the weight of the composition. To 80% of crystalline polyolefin resin; and ii) 70 to 20% of calcium carbonate particles by weight of the composition, selected from the group consisting of: (M) milled particles having an average particle size of 0.3 to 2 microns The acid particles are prepared by wet milling 100 parts by weight of calcium carbonate particles in an aqueous medium in the presence of 0.05 to 2 parts by weight of a dispersant, followed by drying-'The dispersant contains a .10 to 95 moles. /. An amine salt selected from the diallylamine salt and the alkynylpropylamine salt and 90 to 5 moles. /. Copolymer of acrylamide selected from acrylamide and methacrylamide; printed with the Consumer Standards Cooperative of the Central Bureau of Standards (b2), milled with an average particle size of 0.3 to 2 microns Carbonic acid particles are obtained by wet milling 100 parts by weight of calcium coagulate particles in the presence of a dispersant in an aqueous medium of 0.05 to 2 parts by weight, the dispersant comprising-10 to 95 moles Ear 0 /. A copolymer formed from an amine salt of di-dipropylamine salt and an alkylallylamine salt and 90 to 5 mole% of an amine selected from the group consisting of acrylamine and methacrylamine, and then in water In the medium, 0.5 to 10 parts by weight of a sulfonate 'is used to treat the product thus ground, followed by drying to produce' the acid salt is selected from the group consisting of alkylene oxide adducts of monohydric alcohols. Acid salt, alkyl sulfonate and alkyl benzene sulfonate; and wherein the stretching is performed at a temperature lower than the melting point of the crystalline polyolefin resin used as the component (A). The second invention is to provide an inkjet green paper made of the synthetic paper of the present invention so that when a watercolor ink (100 weight in total) having the following composition is dropped on its surface, the watercolor ink pair The contact angle of the recording paper t is 20 to 42 °: CI food-grade black No. 2 2 weight 0 / 〇, _ _-6-This paper size applies to China Garden Standard (CNS.) Λ4 specification (2iix 297 mm ) ~ '413225 Μ B7 V. Description of the invention (4 N-methyl-2-tetrahydropyrrolidone diethylene glycol polyethylene glycol (molecular weight: 200) water 10% by weight, 20% by weight, 15% by weight %, And 53% by weight. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs, Co., Ltd. By fine-tuning the average particle size of calcium carbonate particles to reach 0.3 to 2 microns, the diameter and depth of surface cracks can be controlled, so the ink Can be dried quickly without loss of gloss. Since calcium carbonate particles have a nitrogen-containing I cationic polymer as a dispersant 'adhered to its surface, the ink can adhere well to synthetic paper ^ _ Invention_ j ^ Review (A) crystalline polyhydrofin: as a carrier for horse synthetic paper The crystalline polyolefin used in the resin is preferably an olefin having a crystallinity (measured by χ-ray diffraction method or dip analysis to be 10 to 10%, preferably 20 to 75%, and is selected from the group having 2 Α-Women to 8 carbon atoms (ethylene, propane, butene 4, hexene q, heptene 4, octene-1, 4-methyl-pentene-i, 3-methyl-fluorene 4 etc.) homopolymers, and 2 to 5 random or block copolymers of α-olefins such as those cited above. More specifically, examples of crystalline poly-methyl tobacco include branched or linear polymers Ethylene, which has a density of 0.890 to 0.997 g / litre,, and 10,000, and a melt flow rate (190 ° C, load 2-16 kg) of 0.2 to 50 g / 10 minutes, Olefin homopolymer, which has a melt flow rate (1 to 216 kg ^ 0.2 to 50 g / 10 minutes, propylene / ethylene copolymer, propylene / butene polymer, propylene / ethylene / butylene ^ Copolymer, ㈣ / 4_methylpentene copolymer 'diene / 3-methyl-pentane'! Copolymer, propylene / ethylene Applicable to Chinese Garden Standard (CNS) A4 now iTT7l ^ 297 Ϊ 丁 f Please read the back first Precautions ^ this page)-Pack
丁 -HP ^ Λ 8 2 2 νϊ Α7 _ Β7 五、發明説明(5 ) 基戊烯-1共聚物,聚丁烯-1,聚(4-甲基-戊烯-1)等β 在此等聚烯烴之中,特佳係使用丙烯均聚物或具有密度 爲0.950至0.970克/立方公分之高密度聚乙烯,因爲此等聚 婦烴較不昴貴,並具有高結晶度。 (Β)經濕磨之碳酸鈣粒子·· 成份(bl)之經濕磨碳酸妈粒子’係爲具有平均粒子大小— 0.3至2微米之經研磨碳酸鈣粒子,其係經由在水性媒質中 ,於0.05至2重量份數之陽離子性聚合體分散劑存在下,濕 磨100重量份數之破酸旬粒子(粒子大小:〇·5至50微米), 接著乾燥而製成’該分散劑包含一種由1〇至95莫耳%選自 二烯丙基胺鹽與坑基烯丙基胺鹽之胺鹽與9〇至5莫耳。/。選 自丙烯醯胺與甲基丙烯醯胺之醯胺所形成之共聚物。 經濟部中央標準局負工消费合作社印製 成份(b2)之經濕磨、經表面處理過之碳酸詞粒子,係爲 具有平均粒子大小0.3至2微米之經研磨破酸約粒子,其係 經由在水性媒質中,於0.05至2重量份數之分散劑存在下, 濕磨100重量份數之碳酸鈣粒子(粒子大小:05至50微米) ,該分散劑包含一種由10至95莫耳%選自二烯丙基胺鹽與 燒基烯丙基胺鹽之胺鹽與90至5莫耳%選自丙晞醯胺與甲 基丙烯酷胺之si胺所形成之共聚物,使該經研磨之產物乾 燥,然後在水性媒質中,使用〇·5至10重量份數之一種抗靜 電績酸鹽,處理100重量份數此碳酸鈣,接著乾燥而製成 ,該磺酸鹽係選自單羥醇之氧化烯加成物1之磺酸鹽、烷基 磺酸鹽及烷基苯磺酸鹽β 作爲用以產生成份(bl)與(b2)之碳酸鈣物質者,較佳係使 _________ - 8 - 本紙張尺度適用中國國家標车(CNS U4規輅(210X297公费) 41S225 Α7 Β7 五、發明説明(6 ) ~~ 用已經乾磨、分類或篩選之重質碳酸鈣粒子。 用以分散此等碳酸鈣粒子之水溶性陽離子性共聚物,係 爲一種由10至95莫耳%(較佳爲5〇至8〇莫耳%)胺鹽(a),選 自二烯丙基胺鹽與烷基烯丙基胺鹽,與9〇至5莫耳% (較佳 爲50至20莫耳。/。)醯胺㈨.,選自丙烯醯胺與曱基丙烯醯胺 ’所形成之共聚物。 - 構成此分散劑之烷基二烯丙基胺鹽,其實例爲帶有具1 至8個碳原子之規基者,較佳爲帶有具1至*個碳原子之烷 基者。+ 二歸丙基胺與燒基二烯丙基胺鹽之實例爲,二烯丙基胺 與燒基二烯丙基胺,和無機酸譬如鹽酸、硫酸及硝酸,或 有機酸譬如醋酸,所形成之鹽。 此水溶性陽離子性共聚物分散劑,可製自一種可聚合胺 鹽(a)與一種醯胺(b),视情況伴隨著其他可共聚合單體,譬 如苯乙晞、醋酸乙晞酯、N_乙烯基四氫吡咯酮、(甲基)丙 晞酸2-超乙酯、(曱基)丙缔酸甲酯、(甲基)丙晞酸乙酯及( 甲基)丙烯酸丁酯。 此陽離子性共聚物分散劑之固有黏度,通常範圍爲〇.〇5 土 3.00,較佳爲o.io.至ι_8〇,及又較佳爲〇,15至〇.7〇。此分散 劑藉GPC測#之重量平均分子量,通常範圍爲woo至 1,000,000,較佳爲5,〇〇〇至8〇〇,〇〇〇,及又較佳爲风〇〇〇至7〇〇,〇〇〇 。此陽離子性共聚物分散劑,可根據jp_A_5_263010中所述之 方法製備("JP-A” 一詞於本文中使用時,係意謂"未經審查而 經公告之日本專利申請案·,)。 -9 本紙張尺度適用中國國家標皁(CNS ) Α4規棺(210Χ297公釐) 請 先 Μ 讀 背 ιέ 之 注 意 事 項Butyl-HP ^ Λ 8 2 2 νϊ A7 _ B7 V. Description of the invention (5) β-pentene-1 copolymer, polybutene-1, poly (4-methyl-pentene-1), etc. β are here Among the polyolefins, particularly preferred are propylene homopolymers or high-density polyethylenes having a density of 0.950 to 0.970 g / cm <3> because these polyfones are less expensive and have high crystallinity. (B) Wet ground calcium carbonate particles ... The wet ground calcium carbonate particles of the component (bl) are ground calcium carbonate particles having an average particle size of 0.3 to 2 micrometers, which are passed through an aqueous medium, In the presence of 0.05 to 2 parts by weight of a cationic polymer dispersant, 100 parts by weight of acid-breaking particles (particle size: 0.5 to 50 micrometers) are wet-milled, and then dried to prepare 'the dispersant contains An amine salt of from 10 to 95 mole% selected from diallylamine salt and pit allylamine salt and 90 to 5 mole. /. It is selected from the copolymers of acrylamide and methacrylamide. Wet-milled, surface-treated carbonic acid particles printed in part (b2) by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives are milled acid-breaking particles with an average particle size of 0.3 to 2 microns. In an aqueous medium, 100 parts by weight of calcium carbonate particles (particle size: 05 to 50 micrometers) are wet-milled in the presence of 0.05 to 2 parts by weight of a dispersant. The dispersant contains a content of from 10 to 95 mole%. A copolymer formed of an amine salt selected from a diallylamine salt and an alkyl allylamine salt and 90 to 5 mol% of a siamine selected from the group consisting of propylamine and methacrylamine, such that The ground product is dried, and then in an aqueous medium, 0.5 to 10 parts by weight of an antistatic acid salt is used to treat 100 parts by weight of this calcium carbonate, followed by drying to prepare the sulfonate. The sulfonate, alkyl sulfonate and alkyl benzene sulfonate β of the alkylene oxide adduct 1 of the monohydric alcohol are preferably used as the calcium carbonate material for the components (bl) and (b2). _________-8-This paper size applies to Chinese National Standard Cars (CNS U4 Regulations (210X297 public fee) 41S 225 Α7 Β7 V. Description of the invention (6) ~~ Use heavy calcium carbonate particles that have been dry-milled, classified or screened. The water-soluble cationic copolymer used to disperse these calcium carbonate particles is a type from 10 to 95 Mole% (preferably 50 to 80 mole%) amine salt (a), selected from diallylamine salt and alkylallylamine salt, and 90 to 5 mole% (preferably It is 50 to 20 moles. /) Amine ㈨, selected from the copolymers of acrylamide and fluorenyl acrylamide '.-Alkyl diallylamine salts constituting this dispersant, examples thereof Those having a regulatory group having 1 to 8 carbon atoms, preferably those having an alkyl group having 1 to * carbon atoms. + Examples of diguidylpropylamine and alkyldiallylamine salts are , Diallyl amine and alkyl diallyl amine, and salts of inorganic acids such as hydrochloric acid, sulfuric acid and nitric acid, or organic acids such as acetic acid. This water-soluble cationic copolymer dispersant can be prepared from a The polymerizable amine salt (a) and an amidine (b) are optionally accompanied by other copolymerizable monomers, such as phenethylhydrazone, ethylacetate, N-vinyltetrahydropyrrolidone, ( Methyl) 2-superethyl propionate, methyl (fluorenyl) propionate, ethyl (meth) propionate and butyl (meth) acrylate. Intrinsic viscosity of this cationic copolymer dispersant , Usually in the range of 0.05 to 3.00, preferably in the range of o.io. to ι_80, and more preferably in the range of 0.15 to 0.70. This dispersant is measured by GPC in terms of weight average molecular weight, usually in the range It is woo to 1,000,000, preferably 5,000 to 800,000, and still more preferably 6,000 to 70,000. This cationic copolymer dispersant can be based on Prepared by the method described in jp_A_5_263010 (" JP-A ", as used herein, means " unexamined and published Japanese patent application ·,). -9 The size of this paper is applicable to Chinese National Standard Soap (CNS) Α4 Regulation Coffin (210 × 297 mm) Please read the notes and notes first
養 經濟部中央標準局員工消费合作社印製 經濟部中央橾隼局負工消費合作社印裝 ______B7_ 五、發明説明(7 ) 重質碳酸鈣係於上述陽離子性共聚物分散劑存在下濕磨 。更特定S之’係將水性媒質(較佳爲水)加入重質碳酸約 粒子中,其方式係爲獲得重質碳酸鈣/水性媒質之重量比 爲70/30至30/70 ’較佳爲60/40至40/60。然後.,將陽離子性业 聚物分散劑添加至其中,其量爲〇·〇5至2重量份數,較佳爲 οι至1重量份數,以每1〇〇重量份數重質碳酸鈣之乾物質爲’ 觀點。接著,將所獲得之混合物以習用方式濕磨。或者, 將陽離子性共聚物分散劑先行溶解於水性媒質中,以獲得 如上文所指定之比例,然後與重質碳酸句混合,接.著以習 用方式濕磨。濕磨可以分批方式或連續地進行。較佳係使 用具有研磨媒質之磨機,譬如砂磨機、超微磨碎機或球磨 機。因此’可獲得具有平均粒子大小爲2微米或較小,較 佳爲0.3至2微米之碳酸鈣粒子。 接著,使濕磨過之產物乾燥。亦可將濕磨過之粒子分類 ,因此在乾燥之前,自其中排除較粗者(35〇網目上者)。乾 燥可藉已知方法進行,譬如熱空氣乾燥或噴霧乾燥。其中 ,流體媒質乾燥方法係爲較佳的。在流體媒質乾燥方法中 ,係將一種漿液物質,經由熱空氣流餵入流體化媒質粒子 (流體化床)中。於是,經如此供應之漿液物質,係以薄膜 狀態黏附至激烈流體化之媒質粒子表面β因此,使物質分 散在流體化床中,並於其中藉熱空氣流乾燥。因此,流體 媒質乾燥作業,可容易地利用例如由Nar^幻以Seisgkush〇 κ κ 所製造之媒質漿液乾燥機進行。較佳係使用此種媒質流體 乾燥機,因爲可同時使物質乾燥並處理成初生粒子。 —_-____ -10^ 本紙張尺度適用) Α4規格(2丨Gx297公楚 1 ~~'— --- /諳先'M請背面之注意事項^本頁) 裝- 丁 4° ik* <U3225 五、發明説明(8 A7 B7 經濟部中决標準局貝工消費合作社印製 藉由上述流體媒質乾燥方法使濕磨過之漿液乾燥,則可 獲知含有很少粗粒子之碳酸鈣粒子。但是,在完成流體媒 式乾燥後,可藉任何所要之方法,將粒子進一步研磨及分 類。當經濕磨之產物並非藉由流體媒質乾燥方法乾燥,而 是藉習用熱空氣乾燥時,建議將如此獲得之濾餅藉任何所 要之方法進一步研磨與分類。 - 經如此獲得之濕磨產物之乾燥濾餅易被打碎,因此微細 碳酸鈣粒子可容易地自其獲得,無需研磨該乾燥濾餅。 欲被用以產生成份(b2)之單羥醇之氧化烯加成物之磺酸 鹽’係爲以下式(1)表示者,例如硬脂基聚乙晞醚磺酸納或 丁基聚乙歸"鍵·聚丙歸酸讀酸鋼: R0(AO)mSO3M ⑴ 其中R表示具有2至18個碳原子之烷基,或視情況被具有 1至10個碳原子之燒基取代之烯丙基;A表示具有2至4個 碳原子之次烷基;Μ表示Na、K、Li或銨基;及m爲數目2 至20。 此燒基罐酸鹽爲以下式(2)表示者’例如癸醯基績酸鋼或 硬脂基績酸納: R-SO3 Μ (2) 其中R1表示具有6至3〇個碳原子之跪基;及^^表示Na、K_ 、Li或銨基。 娱·基苯績酸鹽爲以下式(3)表示者,例如十二燒基苯碳酸 納或癸驗基苯橫酸鋼: •閱 讀 背 之 注 3- 裝 訂 本紙張尺度適用肀國國家摞準(CNS ) Λ4規格(2〗〇χ297公釐) ^18225 A_ A7 B7 - --—-------- 1 ·___ 五、發明説明(9 ) r"~~^^3/^~s〇3M (3) 其中R"表示具有6至23個碳原子之烷基;及Μ表示Na、 K、Li或銨基。 . 上述在水性媒質中處理之經研磨碳酸鈣粒子,係接著藉 上述流體媒質乾燥方法乾燥,於是獲得具有平均粒子大小-爲0.3至2微米之經研磨磲酸鈣粒子,其已使用磺酸鹽表面 處理過,並含有很少粗粒子。 薄膜载體: ' 此薄膜載體包含一種樹脂组合物,其含有:(A)該組合物 重量之30至80% .,較佳爲該组合物重量之45至80 %之結晶 性聚歸經樹脂;與(B)該組合物重量之7〇至2〇0/。,較佳爲該 組合^物重量之55至20%之經研磨碳酸鈣粒子,其具有平均 粒子大小爲0.3至2微米,較佳爲0.5至丄微米,藉上述濕磨 方法獲得。 當結晶性聚烯烴樹脂(A)之含量低於组合物重量之3 〇 %, 或經研磨碳酸鈣粒子之含量超過組合物重量之7〇%時’難 以獲得具有均勻厚度之薄膜。當結晶性聚烯烴樹脂之含量 超過組合物重量之80%,或經研磨碳酸鈣粒子之含量低於 組合物重量之20%時,均無法預期獲得經促造之淌墨乾燥 作用及經改良之油墨黏著性。 除了此等成份(A)與(B)之外,薄膜載體可、進一步含有5至 30重量。/。有機填料,其具有高於聚烯垣樹脂(A)之熔解溫度 (例如210至30CTC),譬如聚對苯二甲酸乙二酯、聚對苯二 __ -12, 本紙張尺歧财關ί辟--— - .---¾ ;-!··· --------Π裝-- 、 * 'Π {請先別讀背面之注意事項^/祕、寫本頁) 訂 經濟部中央標準局貝工消費合作社印^ A7 B7 418225 五、發明説明(10 ). 甲酸丁二酯、聚碳酸酯、耐綸6及耐綸66 ;及不超過1〇重 量%具有平均粒子大小1.5微米或較,之顏料’譬如二氧化 鈦、氧化鋅及硫酸鋇。若需要,可進一步含有熱安定劑、 UV吸收劑,填料用之分散劑,譬如油酸、潤滑劑等。 合成紙之製造: 將含有30至80重量。/。結晶性聚晞烴樹脂(A)與70至20重量 %經研磨碳酸鈣粒子(B)之樹脂薄膜,在低於上述成份(A)( 意即,結晶性聚烯烴樹脂)熔點之溫度下,較佳係在3至60 °C下,經單轴或雙軸延伸,於是獲得由微細多孔性延伸樹 脂薄膜製成之合成紙,在該薄膜表面上具有微細裂缝,及 在該薄膜内具有微細空隙(微空隙)。. 當使用下文表示式度量時,此合成紙具有空隙.比例爲10 至50%,密度爲〇 65至1.20克/平方公分,不透明度(JJS P-8138-1976)爲至少80%,及染槽平滑性(JISP-8119—1976)爲50至 2,500 秒: ί請先·Μ讀背面之注意事項再^iir本頁) 訂 空隙比(% )Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Printed by the Consumer Cooperatives of the Central Bureau of the Ministry of Economic Affairs. ______B7_ V. Description of the Invention (7) Heavy calcium carbonate is wet-milled in the presence of the above-mentioned cationic copolymer dispersant. More specifically, S 'is to add an aqueous medium (preferably water) to the particles of the heavy carbonic acid. The method is to obtain a weight ratio of heavy calcium carbonate / aqueous medium of 70/30 to 30/70. 60/40 to 40/60. Then, a cationic polymer dispersant is added thereto in an amount of 0.05 to 2 parts by weight, preferably οm to 1 part by weight, and the calcium carbonate is 100 weight parts per 100 parts by weight. The dry matter is the 'view. Next, the obtained mixture was wet-milled in a conventional manner. Alternatively, the cationic copolymer dispersant is first dissolved in an aqueous medium to obtain the ratio as specified above, and then mixed with the heavy carbonic acid sentence, followed by wet milling in a conventional manner. Wet milling can be carried out batchwise or continuously. It is preferred to use a mill having a grinding medium, such as a sand mill, an ultrafine mill, or a ball mill. Therefore, calcium carbonate particles having an average particle size of 2 µm or less, preferably 0.3 to 2 µm can be obtained. Then, the wet-milled product was dried. The wet-milled particles can also be classified, so the coarser ones (the ones on the 35 mesh) are excluded from them before drying. Drying can be performed by known methods, such as hot air drying or spray drying. Among them, the drying method of the fluid medium is preferable. In the fluid media drying method, a slurry substance is fed into a fluidized media particle (fluidized bed) via a stream of hot air. Therefore, the slurry material thus supplied is adhered to the surface of the fibrous fluidized medium particles β in a thin film state, so that the material is dispersed in the fluidized bed and dried by a stream of hot air therein. Therefore, the fluid medium drying operation can be easily performed using, for example, a medium slurry dryer manufactured by Nar ^ magic Seisgkush0 κ κ. It is preferred to use such a media fluid dryer because the material can be dried and processed into primary particles at the same time. —_-____ -10 ^ This paper size is applicable) Α4 size (2 丨 Gx297 male Chu 1 ~~ '— --- / 谙 Xian'M Please note on the back ^ this page) Pack-丁 4 ° ik * & lt U3225 V. Description of the invention (8 A7 B7 Printed by Shellfish Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs, etc.) By drying the wet-milled slurry by the above-mentioned fluid medium drying method, calcium carbonate particles containing few coarse particles can be found. However, after the fluid media drying is completed, the particles can be further ground and classified by any desired method. When the wet-milled product is not dried by the fluid media drying method, but by drying with hot air, it is recommended that The filter cake thus obtained is further ground and classified by any desired method.-The dry filter cake of the wet-milled product thus obtained is easily broken, so fine calcium carbonate particles can be easily obtained therefrom without grinding the dry filter cake. The sulfonate 'of the alkylene oxide adduct of a monohydric alcohol to be used to produce the component (b2) is one represented by the following formula (1), for example, sodium stearyl polyethyl ether ether sulfonate or butyl poly Bingo " bond · polyacrylic acid acid steel: R0 (A O) mSO3M ⑴ where R represents an alkyl group having 2 to 18 carbon atoms, or an allyl group optionally substituted by a carbamoyl group having 1 to 10 carbon atoms; A represents a hypoalkylene group having 2 to 4 carbon atoms M represents a Na, K, Li or ammonium group; and m is a number of 2 to 20. This calcined can salt is represented by the following formula (2), for example, decanoyl acid steel or stearic acid sodium : R-SO3 Μ (2) wherein R1 represents a cyclinyl group having 6 to 30 carbon atoms; and ^^ represents a Na, K_, Li, or ammonium group. The ammonium benzoate salt is represented by the following formula (3) For example, dodecyl benzene sodium carbonate or decanoyl benzene phthalate steel: • Note 3 on the back of the book. The size of the paper is bound to the National Standard of China (CNS) Λ4 specification (2〗 〇χ297mm) ^ 18225 A_ A7 B7------------ 1 · ___ V. Description of the invention (9) r " ~~ ^^ 3 / ^ ~ s〇3M (3) where R " means 6 to 23 Alkyl groups of 1 carbon atom; and M represents Na, K, Li, or ammonium groups.. The above-mentioned ground calcium carbonate particles treated in an aqueous medium are then dried by the above-mentioned drying method of the fluid medium, thereby obtaining an average particle size- 0.3 to 2 Rice's milled calcium gallate particles have been surface treated with sulfonate and contain very few coarse particles. Film carrier: 'This film carrier contains a resin composition containing: (A) the weight of the composition 30 to 80% by weight, preferably 45 to 80% by weight of the composition of the crystalline polymerized resin; and (B) 70 to 2000% by weight of the composition, preferably the combination 55 to 20% of the ground calcium carbonate particles by weight, having an average particle size of 0.3 to 2 micrometers, preferably 0.5 to 丄 micrometers, is obtained by the above-mentioned wet milling method. When the content of the crystalline polyolefin resin (A) is less than 30% by weight of the composition, or the content of ground calcium carbonate particles exceeds 70% by weight of the composition ', it is difficult to obtain a film having a uniform thickness. When the content of the crystalline polyolefin resin exceeds 80% by weight of the composition, or the content of the ground calcium carbonate particles is less than 20% by weight of the composition, it is impossible to expect to obtain the promoted ink-drying effect and the improved Ink adhesion. In addition to these ingredients (A) and (B), the film carrier may further contain 5 to 30 weight. /. Organic fillers that have a higher melting temperature (for example, 210 to 30 CTC) than the polyolefin resin (A), such as polyethylene terephthalate, polyethylene terephthalate, etc. ----.--- ¾;-! ··· -------- Π installed-, * 'Π (please do not read the precautions on the back ^ / secret, write this page) Order Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shelley Consumer Cooperatives ^ A7 B7 418225 V. Description of the invention (10). Butyl formate, polycarbonate, nylon 6 and nylon 66; and not more than 10% by weight with average particle size 1.5 microns or less, pigments such as titanium dioxide, zinc oxide and barium sulfate. If necessary, it may further contain a heat stabilizer, a UV absorber, and a dispersant for the filler, such as oleic acid and a lubricant. Manufacture of synthetic paper: It will contain 30 to 80 weight. /. The resin film of crystalline polyalkylene resin (A) and 70 to 20% by weight of ground calcium carbonate particles (B) is at a temperature lower than the melting point of the above-mentioned component (A) (meaning, crystalline polyolefin resin), It is preferably uniaxially or biaxially stretched at 3 to 60 ° C, so that a synthetic paper made of a finely porous stretched resin film is obtained, which has fine cracks on the surface of the film, and fine particles in the film. Voids (micro voids). This synthetic paper has voids when measured using the following expressions. The ratio is 10 to 50%, the density is 065 to 1.20 g / cm², the opacity (JJS P-8138-1976) is at least 80%, and Slot smoothness (JISP-8119-1976) is 50 to 2,500 seconds: Please read the precautions on the back first, and then ^ iir this page) Set the void ratio (%)
P 〇-P X100 經濟部中Jji標华局員工消費合作社印製 -13 P 〇 其中p0表示樹脂薄膜在延伸前之密度;及0表示經延伸 樹脂薄膜之密度。. 此合成紙可具有單層結構。或者,其可具有層合薄膜結 構’具有上述經延伸薄膜作爲最外層,体隨著其他樹脂 膜。 層合薄膜之實例,包括以下述方式製成者,單軸延伸聚 烯烴樹脂薄膜,其含有0至40重量%(較佳爲3至33重量% 表紙張尺度適用中SSI家麵(CNS) M規格(2獻297公瘦 41S225 A7 B7 五、發明説明(11 ) 赵濟部中央摞率局負工消費合作社印製 微細碳酸鈣粉末,在低於該樹脂熔點之溫度下進行;在經 如此延伸之薄膜之兩個表面上’層合熔融態聚烯烴樹脂薄 膜,其含有30至80重量。/。結晶性聚烯烴樹脂(A)與7〇至2〇重 量。/。經研磨碳酸鈣粒子;然後,在蔚上述軸呈直角之方向 上延伸該複合膜,因此獲得具有許多微細空隙(微空隙)之 延伸薄膜。自此薄膜,可獲得具有層合結構且具有雙轴延 伸核芯層之合成紙。 此合成紙具有厚度爲30至300微米,較佳爲6〇至测微米 此得具有厚度爲1毫米者’其方式是利用黏著劑將 此寺合成紙互相黏著。 :長度與寬度上之延伸比’較佳範圍爲4至10。在聚丙 :二聚物(广……7r)之情況中,延伸溫度爲⑽至 110至me 度聚乙稀(橡點· 121至134。〇之情況中爲 合成紙可作爲平版印刷紙、凹版印刷紙、水彩 錄紙及熱熔噴墨記錄紙使用。 喷墨記綠紙之評估: 行: = = =紙;合適性藉由水對記錄紙之接觸角進 紙區別,這 (°成紙不能夠顯著地與習用噴墨記綠 之水彩油=適當評估爲不可能的。因此,將下列组成 錄紙之表^ i =428) H在製自本發明合成紙之喷墨記 c '評估'由墨液滴對記錄紙之接觸角: :,食品級黑㈣ 2重量%, 甲基-2,四氫吡咯酮 10重量%., i請先·Μ讀背面之注+^項本頁) -裝----- .. 訂. ----.P 〇-P X100 Printed by the Jji Biaohua Bureau employee consumer cooperative in the Ministry of Economic Affairs -13 P 〇 where p0 represents the density of the resin film before stretching; and 0 represents the density of the stretched resin film. This synthetic paper can have a single layer structure. Alternatively, it may have a laminated film structure 'having the above-mentioned stretched film as the outermost layer, following the other resin film. Examples of the laminated film include a uniaxially stretched polyolefin resin film made in the following manner, which contains 0 to 40% by weight (preferably 3 to 33% by weight) Table SSI Home Surface (CNS) M Specifications (2 offering 297 male thin 41S225 A7 B7 V. Description of the invention (11) Zhao Ji Ministry of Central China ’s Central Bureau of Work and Consumer Cooperatives printed fine calcium carbonate powder at a temperature below the melting point of the resin; in the film so extended On both surfaces are 'laminated molten polyolefin resin films containing 30 to 80 weight% crystalline polyolefin resin (A) and 70 to 20 weight% ground calcium carbonate particles; then, The composite film is extended in a direction in which the above-mentioned axis is at a right angle, so that an stretched film having many fine voids (microvoids) is obtained. From this film, a synthetic paper having a laminated structure and a biaxially extending core layer can be obtained. The synthetic paper has a thickness of 30 to 300 micrometers, preferably 60 to micrometers, so that it has a thickness of 1 millimeter '. The way is to use an adhesive to adhere this synthetic paper to each other.: Extension ratio in length and width 'Than The best range is 4 to 10. In the case of polypropylene: dimer (wide ... 7r), the elongation temperature is ⑽ to 110 to me degrees. Polyethylene (rubber point · 121 to 134. 0 in the case of synthetic paper) It can be used as lithographic printing paper, gravure printing paper, watercolor recording paper and hot-melt inkjet recording paper. Evaluation of inkjet recording green paper: Line: = = = Paper; Suitability Feed paper with contact angle of recording paper by water The difference is that (° C paper cannot be significantly different from the conventional inkjet green watercolor oil = proper evaluation is impossible. Therefore, the following composition recording paper table ^ i = 428) H is produced from the synthetic paper of the present invention The inkjet record c 'evaluation' of the contact angle of the ink droplets on the recording paper::, food-grade black ochre 2% by weight, methyl-2, tetrahydropyrrolidone 10% by weight., I Please read the back first (Note + ^ items on this page) -Installation ----- .. Order. ----.
418225 A7 B7 經濟部中央標準局負工消费合作社印敢 五、發明説明(12 ) 二乙二醇 20重量%, 聚乙二醇(分子量:2〇0) 15重量%,及 水 53重量%。 使用本發明之合成紙作爲噴墨記綠紙,則油墨液滴對記 錄紙之接觸角’較佳範園爲2〇至42〇。當油墨液滴之接觸角 超過420時’水彩油墨幾乎不會滲透至記錄紙中,且只能夠 _te慢地乾燥》當接觸角低於20。時,油墨會良好地滲透,並 顯示良好乾燥性質。但是,在此情況中,染料在油墨中之 固著性質變差,且其遭受光澤與流動性損失,因此獲致不 良影像品質。 爲進一步更詳細地説明本發明,故給予下述實例。 [水落性陽離子性共聚物(分散劑)之製造] <參考實例1 > 在具有回流冷凝管、溫度計、滴液漏斗、攪拌器及氣體 入口 ^之反應器中’银入5〇〇份二綿丙基.胺鹽酸鹽(6〇莫耳 % )與200份丙烯醯胺(4〇莫耳% ) β然後使系統中之溫度提 高至50 C,同時於其中引進氮氣。於攪拌下,將4〇份作爲 聚合引發劑採用之2,2-偶氮雙(2-甲脒基丙烷)二鹽酸鹽(1〇 莫耳% )’在2小時間隔下,加入其中4次。在反應1〇小時 後’獲得黏稠淡黃色液體。稱取5〇克此產物,並將其倒入 5〇〇毫升..丙酮中。藉過濾收集如此形成之白色沉澱物,以 每份100毫升丙酮充分洗滌兩次,然後在\咸壓下乾燥,於 是獲得水溶性陽離子性共聚物分散劑,爲白色固體。當以 GPC度量時,此共聚物具有重量平均分子量爲65〇,〇〇〇。 15- &紙張尺度適用中国國家標舉(CNS ) Α4規格(2!0χ 297公瘦 ·(請先肩讀背面之注意事項\^寫本頁) -裝· 訂 418225 A7 _ B7 拔濟部中央標準局員工消費合作社印製 五、發明説明(13 )<參考實例2 > 在具有回流冷凝管、溫度計、滴液漏斗、攪拌器及氣體 入口管之反應器中,餵入2〇〇份二烯丙基胺鹽酸鹽(6〇莫耳 % )、40份丙晞醯胺(4〇莫耳% )及200份水。然後使系統中 之溫度提高至6(TC ’同時於其中引進氮氣。於授拌下,將 40份作爲聚合引發劑採用之2,2-偶氮雙(2-曱脒基丙燒)二鹽 酸鹽(10莫耳% ),在2小..時間隔下,加入其中4次。在第— 次添加引發劑後1.5小時,自滴液漏斗將280份丙烯酿胺(18 莫耳% )滴入其中,歷經4小時。在最後添加引發劑完成後 ,使反應持續2小時,且因此獲得黏稠淡黃色液體。稱取 50克此產物’並將其倒入5〇〇毫升丙嗣中。藉過滤收集如 此形成之白色沉殿物’以每份毫升丙酮充分洗滌兩次 ,然後在減壓下乾燥,於是獲得水溶性陽離子性共聚物分 散劑’爲白色固體。當以GPC度量時,此共聚物具有重量 平均分子量爲260,000。 (濕磨碳酸飼之製造)<製造實例1 > 將具有平均粒子大小30微米之粗粒狀重質破酸鈣(由 Nihon水泥公司所製造之乾磨產物)與水混合,以獲得4〇/6〇 重量比。然後,以每100重量份數重質碳酸鈣,將〇 〇6重量 份數在上述參考實例1中獲得之水溶性陽離子性共聚物分 散劑添加至其中,並利用桌上超微磨碎機(型媒質揽拌磨機 ,使用玻璃珠(直徑:2.0毫米),在170%充填比率下,於 圓周速度10米/秒下,將所形成之混合物濕磨。接著,藉 -16 - 本紙張尺度適用中S國家標準(CNS ) A4規格(210X297公釐) /請先-"讀背面之注意事项寫本頁j m -裝· ,ϊτ ^118225 A7 B7 五、發明説明(14 ) 由通過350-網目篩網,將經研磨產物分類,並將通過35〇-網 目篩網之粒子,使用流體媒質乾燥機MDS-200 (由418225 A7 B7 Yin Dang, Consumers Cooperative, Central Standards Bureau, Ministry of Economic Affairs 5. Description of the invention (12) 20% by weight of diethylene glycol, 15% by weight of polyethylene glycol (molecular weight: 2000), and 53% by weight of water. When the synthetic paper of the present invention is used as the inkjet green paper, the contact angle of the ink droplets to the recording paper is preferably 20 to 42. When the contact angle of the ink droplets exceeds 420, the 'watercolor ink hardly penetrates into the recording paper, and can only dry slowly when the contact angle is lower than 20. As a result, the ink penetrates well and shows good drying properties. However, in this case, the fixing property of the dye in the ink is deteriorated, and it suffers from loss of gloss and fluidity, so that poor image quality is obtained. In order to explain the present invention in more detail, the following examples are given. [Production of water-falling cationic copolymer (dispersant)] < Reference Example 1 > In a reactor having a reflux condenser, a thermometer, a dropping funnel, a stirrer, and a gas inlet ^, 500 parts of silver was charged Dimethylpropyl.amine hydrochloride (60 mol%) and 200 parts of acrylamide (40 mol%) β were then used to increase the temperature in the system to 50 C while introducing nitrogen thereinto. Under stirring, 40 parts of 2,2-azobis (2-methylamidinopropane) dihydrochloride (10 mole%) 'used as a polymerization initiator was added at a time interval of 2 hours. 4 Times. After 10 hours of reaction ', a viscous pale yellow liquid was obtained. Weigh 50 g of this product and pour it into 500 ml. Acetone. The white precipitate thus formed was collected by filtration, washed thoroughly twice with 100 ml portions of acetone, and then dried under salty pressure, thereby obtaining a water-soluble cationic copolymer dispersant as a white solid. When measured in GPC, this copolymer has a weight average molecular weight of 650,000. 15- & Paper size applies to China National Standards (CNS) Α4 size (2! 0χ 297 male thin · (Please read the notes on the back shoulder first \ ^ Write this page)-Binding · Order 418225 A7 _ B7 Ministry of Economic Affairs Printed by the Consumer Standards Cooperative of the Central Bureau of Standards 5. Description of the Invention (13) < Reference Example 2 > In a reactor with a reflux condenser, a thermometer, a dropping funnel, a stirrer, and a gas inlet pipe, 200 was fed. Parts of diallylamine hydrochloride (60 mol%), 40 parts of propylamidamine (40 mol%), and 200 parts of water. Then the temperature in the system was raised to 6 (TC 'at the same time) Nitrogen was introduced. Under stirring, 40 parts of 2,2-azobis (2-fluorenylpropane) dihydrochloride (10 mole%) was used as a polymerization initiator in 2 hours .. Next, add 4 of them. 1.5 hours after the first initiator addition, 280 parts of acrylamide (18 mole%) was dropped into the dropping funnel from the dropping funnel over 4 hours. After the final addition of the initiator was completed The reaction was allowed to continue for 2 hours, and a viscous pale yellow liquid was thus obtained. 50 grams of this product were weighed and poured into 500 ml of propidium. The white sanctuary thus formed was collected by filtration, washed thoroughly twice with each ml of acetone, and then dried under reduced pressure, so that a water-soluble cationic copolymer dispersant was obtained as a white solid. When measured by GPC, this copolymerization The product has a weight-average molecular weight of 260,000. (Production of wet-milled carbonic acid feed) < Production Example 1 > Coarse granular heavy calcium acetic acid (dry mill product manufactured by Nihon Cement Co., Ltd.) having an average particle size of 30 m ) Mixed with water to obtain a weight ratio of 40/60. Then, water-soluble cationic copolymer obtained in the above-mentioned Reference Example 1 was dispersed in an amount of 0.006 parts by weight per 100 parts by weight of calcium carbonate. Add the agent to it, and use a table micro-grinding machine (type media mixing mill, using glass beads (diameter: 2.0 mm), at a filling rate of 170%, at a peripheral speed of 10 m / s, The resulting mixture is wet-milled. Then, borrow -16-this paper size applies the Chinese National Standard (CNS) A4 size (210X297 mm) / please first-" read the precautions on the back and write this page jm -pack ·, ϊτ ^ 118225 A7 B7 Described (14) of the invention, the classification of the ground product through a 350- mesh sieve, and particles through the mesh screen 35〇-, the fluid medium used dryer MDS-200 (manufactured by
Nara Kikai Seisakusho K.K.製造)乾燥。.當以 Microtrack (由 Nilddso K-K製造)度量時,如此獲得之經研磨碳酸鈣具有平均粒子 大小爲1.5微米。 <製造實例2> 經濕磨重質竣酸釣係使用與上文聲造實例1中所述者相 同之組合物及相同程序獲得’但延長使用超微磨碎機型檀 拌磨機之攪拌時間,及使用1.5毫米直徑之破璃珠。 當以Microtrack度量時,如此獲得之經研磨碳酸約具有平 均粒子大小爲1.0微米。 <製造實例3 :> 經濕磨重質碳酸鈣係使用與上文製造實例1中所述者相 同之组合物及相同程序獲得,但與製造實例2比較,進一 步延長使用超微磨碎機型攪拌磨機之攪拌時間,及使用10 毫米直徑之玻璃珠。當以Microtrack度量時,如此獲得之經 研磨竣酸舞具有平均粒子大小爲0.4微米。 <製造實例4 > 經濟部中央標準局員工消費合作社印製 將具有平均粒子大小30微米之粗粒狀重質碳酸鈣(由 Nihon水泥公司所製造之乾磨產物)與水混合,以獲得#⑽〇 重量比。然後,以每100重量份數重質碳酸鈣,將〇〇6重量 份數在上述參考實例2中獲得之水溶性陽(離子性共聚物分 散劑添加至其中,並利用桌上超微磨碎機型媒質揽掉磨機 ,使用玻璃珠(直徑:15毫米),在17〇%充填比率下,於 -----—™ -17 - 本紙張尺度·巾_ ------------------ 418225 Si 五、發明説明(15 圓周速度10米/秒下,將所形成之混合物濕磨。接著,藉 由通過350-網目篩網,將經研磨產物分類,並將通過350-網 目篩網之粒子,使用流體媒質乾燥機MDS-200 (由 Nara Kikai Seisakusho K.K.製造)乾燥。當以 Microtrack (由 Nikkiso K.K.製造)度量時,如此獲得之經研磨碳酸鈣具有平均粒子 大小爲1.0微米。 [經表面處理之碳酸鈣之製造] <製造實例5 > 將具有平均粒子大小30微米之粗粒狀重質碳酸鈣(由 Νϋιόη水泥公司所製造之乾磨產物)與水混合,以獲得40/60 重量比。然後,以每100重量份數重質碳酸鈣,將0.06重量 份數在上述參考實例1中獲得之水溶性陽離子性共聚物分 散劑添加至其中,並利用桌上超微磨碎機型媒質攪拌磨機 ,使用玻璃珠(直徑:1.5毫米),在170%充填比率下,於 圓周速度10米/秒下,將所形成之混合物濕磨。 接著,將40份1重量%硬脂基聚乙烯醚磺酸鈉之水溶液 添加至其中並攪拌。藉由通過350-網目篩網,將所形成之 混合物分類,並將通過350-網目篩網之粒子,使用流體媒 質乾燥機 MDS-200 (由 NaraKikai Seisakusho K.K,製造)乾燥。當 以Microtrack (由Nikkiso K.K.製造)度量時,如此獲得之經研磨 破.酸約具有平均粒子大小爲1.5微米。 此粉末在純水中之10重量。/。分散液,^以YOKOGAWA所 製造之導電率儀錶SC82TMS度量時,顯示在25°C下之導電 率爲 300 "S/cm。 -18 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 請 先 .閲 讀 背 面 之 注 項 I t 經濟部中央標準局員工消費合作社印製 413225 Α7 ______ Β7 五、發明説明(16 ) <製造實例6> 平均粒子大小1.5微米之經研磨碳酸鈣粉末,係藉由與製 造實例5相同之程序獲得’但以十二基苯確酸鈉之}重量% 落液’取代硬脂基聚乙烯醚續酸鈉。此產物顯示在25。〇下 之導電率爲250 y S/cm。 <製造實例7> - 平.均粒子大小1_5微米之經研磨碳酸鈣粉末,係藉由與製 造實例5相同之程序獲得,但以烷基磺酸鈉sastm( 由Toho化學工業公司製造)之1重量。/〇溶液,取代硬脂基聚 乙烯醚磺酸鈉。此產物顯示在25°C下之導電率爲380 " S/cm 〇 <製造實例8 > 經磺酸鹽處理之重質碳酸鈣,係使用與製造實例5相同 之組合物及相同之程序獲得,但延長使用超微磨碎機型攪 拌磨機之攪拌時間,及使用1.5毫米直徑之玻璃珠。 當以Microtrack度量時,如此獲得之經研磨碳酸鈣具有平均 粒子大小爲1.0微米《其顯示在25X下之導電率爲340 ju S/cm 〇 經濟部中央標準局貝工消费合作社印製 <製造實例9 > 經磺酸鹽處理之重質碳酸鈣,係使用與製造實例5相同 之组合物及相同之程序獲得,但與製造實例8比較,係進 \' 一步延長使用超微磨碎機型攪拌磨機之攪拌時間,及使用 1.0毫米直控之玻璃珠。當以Microtrack度量時,如此獲得之 經研磨碳酸鈣具有平均粒子大小爲0.4微米。其顯示在25。匚 ____> _____- 19- 本紙張尺度適用中國國家標準YcNS. ) Λ4規格(2丨〇"^2们公釐) 413225 五、發明説明(17 ) 下之導電率爲420 "S/cm。 <製造實例1〇 > 將具有平均粒子大小30微米之粗粒狀重質碳酸躬(由 Nihon水泥公司所製造之乾磨產物)與水混合,以獲得40/60 重量比。然後,以每1〇〇重量份數重質碳酸舞,將〇.〇6重量 份數在上述參考實例2中獲得之水浴性陽離子性共聚物分 散劑添加至其中,並利用桌上超微摩碎機型媒質揽拌磨機 ,使用玻璃珠(直徑:1.5毫米),在170%充填比率下,於 圓周速度10米/秒下,將所形成之混合物濕磨。利用製造 實例5中所採用之硬脂基聚乙烯醚磺酸鈉,獲得平均粒子 大小爲1.0微米之經研磨後酸釣粒子。此產物顯示在25。〇下 之導電率爲320 "S/cm。 實例1 (1) 在7Ό重量%丙晞均聚物(由Mitsubishi化學公司製造), 其具有MFR爲0.8克/ 10分鐘,溶點i64°C (DSC尖味溫度)及 結晶度67%,與5重量%高密度聚乙烯之混合物中,添加 22重量。/。在上述製造實例1中獲得並具有平均粒子大小丄.5 微米之經研磨碳酸鈣。將如此獲得之摻合物[丨]在調整至27〇 °c之壓出機中熔融捏合,並以薄片形式壓出。於冷卻至5〇 °c後,獲得未被延伸之薄片。接著,將此薄片加熱至135=c 並延伸5-倍縱長。 (2) 40重金/。丙烯均聚物(由化學公司製造), 其具有MFR爲2克/ 1〇分鐘,熔點164〇c⑴sc尖峰溫度)及結 晶度65%,與6〇重量%在上述製造實例1中獲得並具有平 請 先 -聞 讀 背 面 意 事 項 f 經濟部中炎標準局員工消资合作社印製 本纸張尺度適用中國國家標準(CNS ) Λ4現格 -20- (210X 297公釐) 413225 A7 B7 五、發明説明(18 ) 請 先 閱 讀 背 之 注 意 事 項 均粒子大小0.7微米之經研磨碳酸鈣混合。將如此獲得之掺 合物[ii]在調整至270°C之壓出機中熔融揑合。接著,利用 兩個壓出機,將其層合至上述⑴中製成之經5-倍延伸薄片 之兩個表面上。 將由此三層所组成之層合薄片加熱至155°C,並在橫向上 利用擴幅器延伸機延伸8-倍。接著,使所獲得之延伸薄膜 在50瓦特/平方米•分鐘下,利用電暈放電處理機(由 Kasuga Denki K.Ki.製造)接受電暈放電,於是獲得三層延伸薄 膜。此延伸薄膜之諸層([ii]/[i]/[ii])個別具有厚度爲2〇微米/ 60微米/ 20微米,同時此薄膜具有染槽平滑性爲800秒, 密度爲0.78克/立方公分,及空隙比爲35%。. 比較實例1 經濟部中央標準局員工消費合作社印取 (1)在70重量%丙烯均聚物(由Mitsubishi化學公司製造), 其具有MFR爲0.8克/ 10分鐘,熔點164°C (DSC尖峰溫度)及 結晶度67%,與8重量。/。高密度聚乙綿·之混合物中,添加 22重量。/。具有平均粒子大小1.5微米之經乾磨碳酸鈣 (SOFTON 1800TM,由 Shiraishi CalciumK.K.製造)。將如此獲得 之摻合物[i]在調整至270°C之壓出機中熔融捏合,並以薄片 形式壓出。於冷卻至50°C後,獲得未被延伸之薄片。接著 ,將此薄片加熱至135°C並延伸5-倍縱長。 ⑺將40重量%丙烯均聚物(由Mitsubishi化學公司製造), 其具有MFR爲2克/ 10分鐘,熔點164°C (DS<C尖峰溫度)及結 晶度65%,與60重量%具有平均粒子大小L5微米之經乾磨 碳酸鈣(SOFTON 1800TM,由 Shiraishi Calcium K‘K‘ 製造)混合。 21 - 本纸張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) B7 B7 經濟部中央標準局員工消资合作社印製 五、發明説明(19 ) 將如此獲得之摻合物[ii]在調整至270°C之壓出機中熔融捏 合。接著,利用兩個壓出機,將其層合至上述⑴中製成之 經5-倍延伸薄片之兩個表面上。將由此三層所組成之層合 薄片加熱至155°C,並在橫.向上利用擴幅器延伸機延伸8-倍 。接著,使所獲得之延伸薄膜在50瓦特/平方米•分鐘下 ,利用電暈放電處理機(由Kasuga DenH K.Ki.製造)接受電暈 放電,於是獲得三層延伸薄膜。 . 此延伸薄膜之諸層([ii]/[i]/[ii])個別具有厚度爲2〇微米/ 60 微米/ 20微米,同時此薄膜具有染槽平滑性爲450秒,密 度爲0.70克/立方公分,及空隙比爲41%。 比較實例2 (1)在70重量。/。丙烯均聚物(由Mitsubishi化學公司製造), 其具有MFR爲0.8克/ 10分鐘,熔點164°C (DSC尖峰溫度)及 結晶度67%,與8重量%高密度聚乙歸之混合物中,添加 22重量%具有平均粒子大小1.5微米之合成輕質碳酸鈣 (BRILLIANT 15TM,由 Shiraishi Kogyo K.K.製造)。將如此獲得之 摻合物[i]在調整至270°C之壓出機中熔融捏合,並以薄片形 式壓出。於冷卻至50°C後,獲得未被延伸之薄片。接著, 將此薄片加熱至135°C並延伸5-倍縱長。 ⑺將40重量%丙烯均聚物(由Mitsubishi化學公司製造), 其具有MFR爲2克/ 10分鐘,熔點164°C (DSC尖峰溫度)及結 晶度65%,與60重量%具有平均粒子大小1.5微米之合成輕 質碳酸鈣(BRILLIANT ,由 Shiraishi Kogyo K.K·製造)混合。 將如此獲得之摻合物[ii]在調整至270°C之壓出機中熔融捏 _-22-_ 本紙張尺度適用中國國家標华(CNS ) A4規格(210X 297公釐) {請先閑讀背面之注意事項寫本頁} -裝. 418225 A7 p--------B7 五、發明説明(2〇 ) 合。接著,利用兩個壓出機,將其層合至上述⑴中製成之 經5-倍延伸薄片之兩個表面上。將由此三層所組成之層合 薄片加熱至155°C ’並在橫向上利用擴幅器延伸機延伸8_倍 。接著,使所獲得之延伸薄膜在50瓦特/平方米•分鐘下 ,利用電暈放電處理機(由Kasuga Denld K.K1製造)接受電暈 放電,於是獲得三層延伸薄膜。 此延伸薄膜之諸層([ii]/[i]/[ii])個別具有厚度爲20微米/ 6〇 微米/ 20微米。 實例2至6 藉由與實例1中所述者相同之程序,但使用如在表1中所 指定之摻合物[i]與[ii],獲得經延伸之層合薄膜。 實例7 經濟部中央標隼局貝工消費合作社印製 在70重量。/。丙烯均聚物(由Mitsubishi化學公司製造),其 具有MFR爲2克/10分鐘,熔點164°C (DSC尖峰溫度)及結晶 度67% ’與8重量。/。高密度聚乙烯之混合物中,添加22重 量%在上述製造實例2中獲得並具有平均粒子大小仙微米 之經研磨碳酸#5,於是獲得摻合物[i]。個別地,將40重量 %丙缔均聚物(由Mitsubishi化學公司製造),其具有]y[FR爲 20克/ 10分鐘,熔點i64°C (DSC尖峰溫度)及結晶度65%, 與60重量。/。在上述製造實例2中獲得並具有平均粒子大小 1.0微米之經研磨碳酸鈣混合,於是獲得摻合物问。將此 等摻合物[i]與[ii]個別在兩個各調整至270°C之壓出機中察融 捏合’然後共歷出成層合狀態?以致使掺合物[丨]夾在掺合 物[ii]之間。於冷卻後,獲得三層未被延伸之薄膜。 ___ -23-_____ 本紙伕尺度適用中国國家標準(CNS ) A4说格(210X297公釐) 413225五、發明説明(21 ) A7 B7 經濟部中央標準局負工消费合作社印製 然後’將此薄片加熱至135°C,並以單軸方式延伸5-倍縱 長。 再者’使所獲得之延伸薄膜在5〇瓦特/平方米•分鐘下 ’利用電暈放電處理機(由Kasuga Denici Κ,Κΐ.製造)接受電暈 放電’於是獲得三層廷伸薄膜。此延伸薄膜之諸膚 ([ii]/[i]/[ii])個別具有厚度爲2〇微米/ 60微米/ 20微米,同時 此薄膜具有染槽平滑性爲950秒,密度爲〇.85克/立方公分 ,及空隙比爲29%。 實例8 以上文實例7中所述之相同.组合物 '相同層構造(意即 [ii]/[i]/[ii])及相同程序,但改變各層厚度,獲得三層單軸延 伸薄片。 其次,將此薄膜在橫向上,利用經加熱至155。〇之擴幅器 延伸機延伸8-倍,於是獲得三層、經雙軸延伸之薄膜。 接著’使所獲得之延伸薄膜在50瓦特/平方米•分鐘下 ’利用電暈放電處理機(由Kasuga Denki K.Ki.製造)接受電暈 放電,於是獲得三層延伸薄膜。此延伸薄膜之諸層 ([ii]/[i]/[ii])個別具有厚度爲15微米/ 50微米/ 15微米,同時 此薄膜具有染槽平:滑性爲2,000秒,密度爲〇.7〇克/立方公 分,及空隙比爲42%。 比較實例3與4 藉由與實例7中所述者相同之程序,但^用如在表2中所 指定之掺合物[i]與[ii],獲得經延伸之層合薄膜。 比較實例5與6 ___-24- (度適用中國國家標绛(CNS ) Λ4規格(210X297公釐丁" ~ ~~-~ ί請先澗讀背面之注意事項务^本頁) 裝 訂 413225 A7 B7 麵濟部中央標準局員工消费合作社印製 五、發明説明(22 ) 藉由與實例8中所述者相同之程序,但使用如在表2中所 指定之摻合物[i]與[ii],獲得經延伸之層合薄膜。 [評估方法] 以下述方式評估合成紙 [光澤] 根據 ITS P-8142_ 丨 9 6 5 (75°)測定。 ' [於表面層中之切痕] 供· 以肉眼或在放大鏡下,於表面層中未發現切痕。 輕微:以肉眼未發現切痕,但在放大鏡下發現一些切 痕,實用上不會造成問題。 有:以肉眼發現些許切痕,並在放大鏡下確認。於實 用上會造成一些問題。 嚴重:以肉眼明顯地確認切痕,實際上無法使用。 (平版適印性) 將合成紙切成一種尺寸(長度:6%毫米,寬度:469毫米) ’並使用平版印刷機DIA 2型(由Mitsubishi重工業公司製造) ’在20°C及相對濕度5〇%下,連續印製5〇〇份複製品。 <油墨黏著性> 使黏膝帶"CdlotapeTM"(由Nichiban公司製造)強力黏著至平 版印刷試樣之油墨表面上,然後在性定速度與恒定角度下 剝離。根據下列標準評估油墨自試樣分離之程度。 ◎: 薄膜本身破裂。 ' 〇:油墨稍微分離,實用上不會造成問題。 A :油墨幾乎分離,但顯示剝離抵抗性。於實用上有 _ -25- 本紙張尺度適用中國國家標準(CNS ) Λ4規格(2]0X 297公釐) (請先·Μ讀背面之注意事項4-_f^r本頁) .裝- '-D. ik,. 3225 A7 B7 經濟部中央標準局貝工消费合作社印製 -26 五、發明説明(23 些問題。 X :油墨完全分離,而未顯示任何剝離抵抗性。實際 上無法使用。 <油墨轉移密度> 使用印刷光密度計Macbeth 900 (由Sakata Inx公司製造)度量 實體印刷部份之密度(網點密度:1〇〇。/。),並根據下列標準-進行評估。 ◎ : 1.5 g所度量之密度。 〇:I.2 $所度量之密度< 1.5。實用上沒有問題。 △ : 〇.9 S所度量之密度< u。實用上有些問題。 x : 0‘9 >所度量之密度。實際上無法使用。 <紙粉塵> 在印製500份複製品後,以肉眼根據下列標 矛(访π l Λ 丨丨*紙粉塵 黏著至包覆層上之程度。 ◎:幾乎沒有任何黏著。 〇:輕微黏著,不會影嚮印刷事物。 △:黏著,稍微影嚮印刷事物。 Χ :嚴重黏著’大爲影嚮印刷事物。 (凹版印刷適印性) 將合成紙切成Α4大小,並使用桿棒(8)及凹 (CCST-16.深紅色,由T〇y〇油墨製造公司製造)印 U油墨 印刷後,使合成紙在室中靜置i天,然後、使,在元成 估。 . 奏乂下述評 <油墨黏著性> , 本纸張尺度適用中i^^grCNS) A4規格“297公楚) ---------&-----—------ h . D -- . (請先閒讀背面之注意事項馬故穹本頁} A7 B7 五、發明説明(24 使黏膠帶"CellotapeTM"(由Nichiban公司製造)強力黏著至經 印刷試樣之油墨表面上,然後在恒定速度與恒定角度下剝 離。根據下列標準評估油墨自試樣分離之程度。 ◎:薄膜本身破裂。. 〇 : 油墨稍撤分雖,實用上不會造成問題。 但顯示剥離抵抗性。於實用上有 而未顯示任何剥離抵抗性。實際 <白.點> 在2份印刷試樣上,計算可以肉眼見及之因油墨分離所 造成之白點。 實例9與10及比較實例7 將實例1與7及比較實例丨中獲得之合成紙,使用水彩喷 墨印表機(由Canon公司製造)進行彩色印刷(黃色、紫紅色 、藍綠色、黑色),並度量油墨乾燥所需要之時間’。結果 ,其個別花費20、30及70秒,使實例!與7及比較實例工之 合成紙上之油墨乾燥。 經濟部中央標準局員工消φί合作社印製 油墨稍微分離 油墨幾乎分離 些問題。 油墨完全分離 上無法使用。 △Nara Kikai Seisakusho K.K.) is dried. When measured in Microtrack (manufactured by Nilddso K-K), the ground calcium carbonate thus obtained had an average particle size of 1.5 microns. < Manufacturing Example 2 > Wet-milled heavy acid fishing was obtained using the same composition and the same procedures as those described in Example 1 above, but extended the use of an ultra-fine sandal sand mill. Stir time and use broken glass beads with a diameter of 1.5 mm. When measured in Microtrack, the ground carbonic acid thus obtained had an average particle size of about 1.0 micron. < Manufacturing Example 3: > Wet ground heavy calcium carbonate was obtained using the same composition and the same procedure as those described in Manufacturing Example 1 above, but compared with Manufacturing Example 2, the use of ultrafine grinding was further extended The stirring time of the model stirring mill and the use of 10 mm diameter glass beads. When measured in Microtrack, the ground sour powder thus obtained had an average particle size of 0.4 m. < Manufacturing Example 4 > Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, coarse grained heavy calcium carbonate (a dry mill product manufactured by Nihon Cement Co., Ltd.) having an average particle size of 30 microns was mixed with water to obtain # ⑽〇 重量 比. Then, the water-soluble cation copolymer (ionic copolymer dispersant) obtained in the above-mentioned Reference Example 2 was added in an amount of 0.006 parts by weight per 100 parts by weight of the calcium carbonate, and was finely ground using a table. The model media removes the mill, using glass beads (diameter: 15 mm), at a filling rate of 17%, at -----— ™ -17-paper size · scarves_ ------- ----------- 418225 Si V. Description of the invention (15 At a peripheral speed of 10 m / s, the resulting mixture is wet-milled. Then, the milled product is passed through a 350-mesh screen Sorted and dried the particles passing through a 350-mesh screen using a fluid media dryer MDS-200 (manufactured by Nara Kikai Seisakusho KK). The ground calcium carbonate thus obtained was measured when measured by Microtrack (manufactured by Nikkiso KK) It has an average particle size of 1.0 micron. [Production of surface-treated calcium carbonate] < Manufacturing Example 5 > A coarse-grained heavy calcium carbonate (dry grinded by Νιιηη Cement Co., Ltd.) having an average particle size of 30 micrometers Product) and water to obtain a 40/60 weight ratio. Then, For every 100 parts by weight of heavy calcium carbonate, add 0.06 parts by weight of the water-soluble cationic copolymer dispersant obtained in Reference Example 1 above, and use a desktop ultra-fine grinding type media stirring mill, Using glass beads (diameter: 1.5 mm) at a filling rate of 170%, the resulting mixture was wet-milled at a peripheral speed of 10 m / s. Next, 40 parts of 1% by weight stearyl polyvinyl ether sulfonic acid An aqueous solution of sodium was added thereto and stirred. The resulting mixture was classified by passing through a 350-mesh screen, and the particles passing through the 350-mesh screen were using a fluid medium dryer MDS-200 (by NaraKikai Seisakusho KK, (Manufactured) dry. When measured in terms of Microtrack (manufactured by Nikkiso KK), the ground powder thus obtained was ground. The acid had an average particle size of about 1.5 microns. The powder was 10 weight in pure water. When the conductivity meter SC82TMS manufactured by YOKOGAWA is measured, it shows that the conductivity is 300 " S / cm at 25 ° C. -18 This paper size applies to China National Standard (CNS) A4 specification (210X 297 mm) Please First, read the note on the back I t Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 413225 Α7 ______ Β7 V. Description of the Invention (16) < Manufacturing Example 6 > Milled calcium carbonate powder with an average particle size of 1.5 microns, borrowed By the same procedure as in Manufacturing Example 5, 'but with sodium dodecyl benzoate's weight% falling liquid' was used instead of sodium stearyl polyvinyl ether sulfonate. This product is shown at 25. The conductivity at 0 ° is 250 μS / cm. < Manufacturing Example 7 >-Flat. Milled calcium carbonate powder having an average particle size of 1 to 5 microns was obtained by the same procedure as in Manufacturing Example 5, except that sodium alkylsulfonate sastm (manufactured by Toho Chemical Industry Co., Ltd.) 1 weight. / 〇 solution, instead of sodium stearyl polyvinyl ether sulfonate. This product shows a conductivity of 380 at 25 ° C " S / cm 〇 < Production Example 8 > The sulfonate-treated heavy calcium carbonate uses the same composition and the same as those in Production Example 5 The procedure is obtained, but the stirring time of the ultra-fine grinding type stirring mill is extended, and the glass beads with a diameter of 1.5 mm are used. When measured in Microtrack, the ground calcium carbonate thus obtained had an average particle size of 1.0 micron, which shows a conductivity of 340 ju S / cm at 25X. Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy & Manufacturing Example 9 > The sulfonate-treated heavy calcium carbonate was obtained using the same composition and the same procedure as those of Manufacturing Example 5, but compared with Manufacturing Example 8, it was further extended by using an ultrafine attritor. The stirring time of the type stirring mill, and the use of 1.0 mm directly controlled glass beads. The ground calcium carbonate thus obtained had an average particle size of 0.4 m when measured in Microtrack. It is shown at 25.匚 ____ > _____- 19- This paper size applies the Chinese national standard YcNS.) Λ4 specification (2 丨 〇 " ^ 2mm) 413225 V. The conductivity of the invention (17) is 420 " S / cm. < Manufacturing Example 10 > A coarse-grained heavy carbonic acid bow (a dry milled product manufactured by Nihon Cement Co., Ltd.) having an average particle size of 30 m was mixed with water to obtain a 40/60 weight ratio. Then, in an amount of 100 parts by weight based on carbonic acid, 0.06 parts by weight of the water-bath cationic copolymer dispersant obtained in the above Reference Example 2 was added thereto, and superfine friction was performed using a table. The crushing type media mixing mill uses glass beads (diameter: 1.5 mm) and wet-mills the resulting mixture at a filling rate of 170% and a peripheral speed of 10 m / s. Using the sodium stearyl polyvinyl ether sulfonate used in Production Example 5, milled acid fishing particles having an average particle size of 1.0 m were obtained. This product is shown at 25. The conductivity below 〇 is 320 " S / cm. Example 1 (1) A 7% by weight propylamidine homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.) having an MFR of 0.8 g / 10 minutes, a melting point of i64 ° C (DSC sharp temperature), and a crystallinity of 67%, and To a 5% by weight high-density polyethylene mixture, 22% by weight was added. /. Milled calcium carbonate obtained in the above Production Example 1 and having an average particle size of 丄. 5 μm. The blend [丨] thus obtained was melt-kneaded in an extruder adjusted to 27 ° C. and extruded in the form of a sheet. After cooling to 50 ° C, unstretched flakes were obtained. Next, the sheet was heated to 135 = c and extended 5-fold in length. (2) 40 heavy gold. A propylene homopolymer (manufactured by a chemical company), which has an MFR of 2 g / 10 minutes, a melting point of 164 ° C (sc peak temperature) and a crystallinity of 65%, and 60% by weight were obtained in the above Production Example 1 and had a flat surface. Please read the following notice first: f Printed on the paper size of the China Consumer Standards Cooperative of the Ministry of Economic Affairs, China National Standards (CNS) Λ4 Appearance -20- (210X 297 mm) 413225 A7 B7 V. Invention Note (18) Please read the precautions below to mix the ground calcium carbonate with an average particle size of 0.7 microns. The blend [ii] thus obtained was melt-kneaded in an extruder adjusted to 270 ° C. Then, using two extruders, they were laminated on both surfaces of the 5-fold stretched sheet made in the above-mentioned maggot. The laminated sheet composed of the three layers was heated to 155 ° C and stretched 8-fold in the lateral direction using a tenter stretcher. Next, the obtained stretched film was subjected to a corona discharge using a corona discharge processor (manufactured by Kasuga Denki K.Ki.) at 50 W / m2 · min, thereby obtaining a three-layer stretched film. The layers ([ii] / [i] / [ii]) of this stretched film each have a thickness of 20 μm / 60 μm / 20 μm, and the film has a smoothness of dyeing grooves of 800 seconds and a density of 0.78 g / Cubic centimeters and a void ratio of 35%. Comparative Example 1 Printed by (1) a 70% by weight propylene homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.) at the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, which has an MFR of 0.8 g / 10 minutes and a melting point of 164 ° C (DSC spike Temperature) and crystallinity 67%, with 8 weight. /. To the mixture of high-density polyethylene and cotton, 22 weights were added. /. Dry-milled calcium carbonate (SOFTON 1800TM, manufactured by Shiraishi Calcium K.K.) having an average particle size of 1.5 microns. The blend [i] thus obtained was melt-kneaded in an extruder adjusted to 270 ° C, and extruded in the form of a sheet. After cooling to 50 ° C, an unstretched sheet was obtained. Next, the sheet was heated to 135 ° C and stretched 5-fold in length. ⑺ 40% by weight propylene homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.), which has an MFR of 2 g / 10 minutes, a melting point of 164 ° C (DS & C peak temperature) and a crystallinity of 65%, has an average of 60% by weight Dry ground calcium carbonate (SOFTON 1800TM, manufactured by Shiraishi Calcium K'K ') with a particle size of L5 microns was mixed. 21-This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) B7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (19) The blend obtained in this way [ii] Melt-knead in an extruder adjusted to 270 ° C. Then, using two extruders, they were laminated to both surfaces of the 5-fold stretched sheet made in the above-mentioned maggot. The laminated sheet composed of the three layers is heated to 155 ° C and stretched 8-fold in a horizontal direction with a tenter stretcher. Next, the obtained stretched film was subjected to a corona discharge using a corona discharge processor (manufactured by Kasuga DenH K.Ki.) at 50 watts / square meter • minutes, thereby obtaining a three-layer stretched film. The layers of this stretched film ([ii] / [i] / [ii]) each have a thickness of 20 μm / 60 μm / 20 μm. At the same time, the film has a dyeing tank smoothness of 450 seconds and a density of 0.70 g. / Cm3, and the void ratio is 41%. Comparative Example 2 (1) at 70 weight. /. A propylene homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.) having a MFR of 0.8 g / 10 minutes, a melting point of 164 ° C (DSC spike temperature) and a crystallinity of 67%, and a mixture of 8% by weight high-density polyethylene, 22% by weight of synthetic light calcium carbonate (BRILLIANT 15TM, manufactured by Shiraishi Kogyo KK) having an average particle size of 1.5 microns was added. The blend [i] thus obtained was melt-kneaded in an extruder adjusted to 270 ° C, and extruded in the form of a sheet. After cooling to 50 ° C, an unstretched sheet was obtained. Next, the sheet was heated to 135 ° C and stretched 5-fold in length. ⑺ 40% by weight propylene homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.), which has an MFR of 2 g / 10 minutes, a melting point of 164 ° C (DSC spike temperature) and a crystallinity of 65%, and has an average particle size of 60% by weight 1.5 micrometers of synthetic light calcium carbonate (BRILLIANT, manufactured by Shiraishi Kogyo KK ·) was mixed. The blend [ii] thus obtained was melt-kneaded in an extruder adjusted to 270 ° C _-22-_ This paper size is applicable to China National Standard (CNS) A4 specifications (210X 297 mm) {Please first Please read the notes on the back of this book to write this page} -Equipment. 418225 A7 p -------- B7 V. Description of the invention (20). Then, using two extruders, they were laminated to both surfaces of the 5-fold stretched sheet made in the above-mentioned maggot. The laminated sheet composed of the three layers is heated to 155 ° C ′ and stretched 8_ times in the lateral direction by a tenter stretcher. Next, the obtained stretched film was subjected to a corona discharge using a corona discharge processor (manufactured by Kasuga Denld K.K1) at 50 W / m2 · min, thereby obtaining a three-layer stretched film. The layers ([ii] / [i] / [ii]) of this stretched film each have a thickness of 20 micrometers / 60 micrometers / 20 micrometers. Examples 2 to 6 By the same procedure as described in Example 1, but using the blends [i] and [ii] as specified in Table 1, an extended laminated film was obtained. Example 7 Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs at 70 weight. /. A propylene homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.) having an MFR of 2 g / 10 minutes, a melting point of 164 ° C (DSC peak temperature), and a crystallinity of 67% 'and 8 weight. /. To the mixture of high-density polyethylene, 22% by weight of the milled carbonic acid # 5 obtained in the above Production Example 2 and having an average particle size of a few microns was added, and a blend [i] was thus obtained. Individually, 40% by weight of an propylene homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.) having [y = FR 20 g / 10 min, melting point i64 ° C (DSC spike temperature), and crystallinity 65%, and 60% weight. /. The ground calcium carbonate obtained in the above Production Example 2 and having an average particle size of 1.0 µm was mixed, and thus a blend was obtained. These blends [i] and [ii] were individually melted and kneaded in two extruder adjusted to 270 ° C, and then they were layered together? So that the blend [丨] is sandwiched between the blend [ii]. After cooling, three unstretched films were obtained. ___ -23 -_____ The size of this paper is applicable to the Chinese National Standard (CNS) A4 format (210X297 mm) 413225 V. Description of the invention (21) A7 B7 Printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs and then 'heat this sheet To 135 ° C and extend 5-times length in a uniaxial manner. Furthermore, 'the obtained stretched film was subjected to a corona discharge processor (manufactured by Kasuga Denici KK, KK.) At 50 watts per square meter per minute', thereby obtaining a three-layered stretched film. The skins of this stretched film ([ii] / [i] / [ii]) each have a thickness of 20 micrometers / 60 micrometers / 20 micrometers. At the same time, the film has dyeing tank smoothness of 950 seconds and a density of 0.85. G / cm3 and a void ratio of 29%. Example 8 The same as described in Example 7 above. Composition 'Same layer structure (meaning [ii] / [i] / [ii]) and the same procedure, but changing the thickness of each layer to obtain a three-layer uniaxially stretched sheet. Next, this film was heated to 155 in the transverse direction. 〇 Amplifier Extender stretches 8-fold, so a three-layer, biaxially stretched film is obtained. Then, 'the obtained stretched film was subjected to a corona discharge treatment machine (made by Kasuga Denki K.Ki.) at 50 watts per square meter per minute, and a three-layer stretched film was obtained. The layers ([ii] / [i] / [ii]) of this stretched film each have a thickness of 15 μm / 50 μm / 15 μm, and the film has a dyeing tank flatness: the slip is 2,000 seconds, and the density is 0. 70 g / cm3 and a void ratio of 42%. Comparative Examples 3 and 4 By the same procedure as described in Example 7, but using the blends [i] and [ii] as specified in Table 2, an extended laminated film was obtained. Comparative Examples 5 and 6 ___- 24- (degrees apply to Chinese National Standards (CNS) Λ4 specifications (210X297 mm D " ~ ~~-~ ί Please read the precautions on the back first ^ this page) Binding 413225 A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Nation 5. Description of Invention (22) By the same procedure as described in Example 8, but using the blends [i] and [ ii] to obtain a stretched laminated film. [Evaluation method] The synthetic paper [gloss] was evaluated in the following manner according to ITS P-8142_ 丨 9 6 5 (75 °). '[Cut marks in the surface layer] · No cut marks were found in the surface layer with the naked eye or under a magnifying glass. Slight: No cut marks were found with the naked eye, but some cut marks were found under the magnifying glass, which did not cause practical problems. Yes: Some cut marks were found with the naked eye And confirm it under a magnifying glass. It will cause some problems in practical use. Serious: The cut marks are clearly recognized with the naked eye, which is actually unusable. (Lithographic printability) Cut synthetic paper into a size (length: 6% mm, Width: 469 mm) 'and using a lithographic printing press type DIA 2 (by Mi (Tsubishi Heavy Industries Co., Ltd.) '500 copies were continuously printed at 20 ° C and 50% relative humidity. < Ink Adhesiveness > Make the knee tape " CdlotapeTM " (manufactured by Nichiban) strong Adhere to the ink surface of a lithographic printing sample, and then peel it at a constant speed and constant angle. Evaluate the degree of separation of the ink from the sample according to the following criteria. ◎: The film itself is broken. '〇: The ink is slightly separated, not practical It may cause problems. A: The ink is almost separated, but it shows peel resistance. _ -25- This paper size applies to Chinese National Standard (CNS) Λ4 specification (2) 0X 297 mm) (Please read first. Μ Note on the back 4-_f ^ r this page). Packing-'-D. Ik ,. 3225 A7 B7 Printed by Shelley Consumer Cooperatives, Central Bureau of Standards of the Ministry of Economics -26 5. Description of the invention (23 questions. X: Ink Completely separated without showing any peel resistance. Actually unusable. ≪ Ink Transfer Density > The density of the solid printed portion was measured using a printing densitometer Macbeth 900 (manufactured by Sakata Inx) (dot density: 10) 〇. /.), And evaluated according to the following criteria. ◎: Density measured at 1.5 g. 〇: Density measured at 1.5 g $ 1.5. There is no practical problem. △: Density measured at 0.9 S < u. There are some practical problems. x: 0'9 > Density measured. Actually unusable. < Paper dust > After printing 500 copies, use the following standard spear (visit π) with the naked eye. l Λ 丨 丨 * The degree of paper dust adhesion to the coating. ◎: There was almost no adhesion. 〇: It is slightly sticky and does not affect printed matter. △: Adhesion, slightly affecting printed matter. Χ: Severe adhesion ’greatly affects printed matter. (Gravure printability) Cut the synthetic paper into A4 size, and use a rod (8) and a concave (CCST-16. Crimson, manufactured by Toyo Ink Manufacturing Co., Ltd.) to print U ink and then synthesize The paper was left standing in the room for i days, and then, made, in Yuan Cheng estimates. Play the following comments < Ink Adhesiveness >, this paper size is suitable for i ^^ grCNS) A4 specification "297 Kung Chu) --------- & -------- ---- h. D-. (Please read the precautions on the back page of the horse's dome first) A7 B7 V. Description of the invention (24 Make the adhesive tape "CellotapeTM" (manufactured by Nichiban) adhere strongly to the warp Print the sample on the ink surface, and then peel at a constant speed and constant angle. Evaluate the degree of separation of the ink from the sample according to the following criteria. ◎: The film itself is broken. 〇: Although the ink is slightly withdrawn, it will not cause practical problems. The problem. However, it shows peel resistance. It is practical but does not show any peel resistance. Actual < White. Dots > On two printed samples, calculate the white spots caused by ink separation which can be seen with the naked eye. Examples 9 and 10 and Comparative Example 7 The synthetic paper obtained in Examples 1 and 7 and Comparative Example 丨 was used for color printing (yellow, magenta, cyan, black) using a watercolor inkjet printer (manufactured by Canon). ) And measure the time it takes for the ink to dry '. As a result, it takes 20 30 and 70 seconds, so that instance! Synthesis of paper 7 and Comparative Examples of the ink drying station. Ministry of Economic Affairs Bureau of Standards staff printed ink consumption φί cooperative separation ink is slightly separated almost these problems. Complete separation can not be used on the ink. △
X 在確認每一種顏色均已良好地顯色後,使黏勝管 ’’CellotapeTM"(由Nichiban公司製造)強力地黏著至各印刷紙之 一部份上’然後沿著黏著面迅速地剝離。接著,以肉眼評 估留在合成紙上之油墨。結果’各合成紙顯示高油墨殘留 比(95 至 1〇〇% )。 另一方面,將經印刷之合成紙浸沒在流動水中5分鐘並 27 Μ氏張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ^225 A7 B7 五、發明説明(25 ) 乾燥。然後,檢查留在其上之影像與敵紋之程度。結果, 各試樣顯示優越之影像留在其上且無皺紋。 實例11 (1) 在70重量%聚丙烯(由Mitsubishi化學公司製造),其具 有MFR爲0.8克/ 10分鐘,熔點164°C (DSC尖峰溫度)及結晶 度67%,與8重量%高密度聚乙晞之混合物中,添加22重 量%.在上述製造實例5中獲得並具有平均粒子大小u微米 之經研磨碳酸鈣。將如此獲得之摻合物[i]在調整至270°C之 壓出機中溶融捏合,並以薄片形式壓出。於冷卻至_5〇°c後 ,獲得未被延伸之薄片。接著’將此薄片加熱至135°C並延 伸5-倍縱長。 (2) 將40重量%丙烯均聚物(由Mitsubishi化學公司製造), 其具有MFR爲2克/ 10分鐘,熔點164X: (DSC尖峰溫度)及結 晶度65%,與60重量0/。在上述製造實例5中獲得並具有平 均粒子大小1.5微米之經研磨碳酸鈣混合。將如此獲得之摻 合物[ii]在調整至27(TC之壓出機中熔融捏合。接著,利用 兩個壓出機,將其層合至上述⑴中製成之經5_倍延伸薄片 之兩個表面上。 經濟部中央標準局員工消費合作社印製 將由此三層所组成之層合薄片加熱至155Ό,並在橫向上 利用擴幅器延^伸機延伸8-倍。接著,使所獲得之延伸薄膜 在.50瓦特/平方米•分鐘下,利用電暈放電處理機(由 KasugaDenJdK.Ki·製造)接受電暈放電,於是^獲得三層延伸薄 膜°此延伸薄膜之諸層(間/叩问)個別具有厚度爲2〇微米/ 60微米/ 20微米,同時此薄膜具有染槽平滑性爲〗,〇〇〇秒, _____ -28- 本紙張尺度適用中國§]家標準((^5>六4規格(2]0>< 297公釐 418225 ΑΊ Α7 Β7 五、發明説明(26 ) 密度爲0.78克/立方公分,及空隙比爲93%。 其對具有上述组成之水彩喷墨油墨,顯示接觸角爲25°。 比較實例8 ⑴在70重量%丙烯均聚物(由Mitsubishi化學公司製造), 其具有MFR爲0.8克/ 10分鐘,熔點164°C (DSC尖峰溫度)及 結晶度67%,與8重量。/。高密度聚乙烯之混合物中,添加 22重量%具有平均粒子大小1.5微米及顯示在25°C下之導電 . * 率爲 63 ju S/cm 之經乾磨碳酸鈣(SOFTON 1800TM,由 Shiraishi Calcium K.K.製造)。將如此獲得之摻合物[i]在調整至270°C之 壓出機中熔融揑合,並以薄片形式壓出。於冷卻至50°C後 ,獲得未被延伸之薄片。接著,將此薄片加熱至135°C並延 仲5-倍縱長。 經濟部中央標隼局員工消f合作社印絮 (請先聞讀背面之注意事項寫本頁} ⑺將4〇重量%丙烯均聚物(由Mitsubishi化學公司製造), 其具有MFR爲2克/ 10分鐘,熔點164°C (DSC尖峰溫度)及結 晶度65%,與60重量%具有平均粒子大小1.5微米及顯示在 25°C下之導電率爲63 # S/cm之經乾磨碳酸鈣(SOFTON 1800tm ,由Shiraishi Calcium K.K.製造)混合。將如此獲得之掺合物[ii] 在調整至270°C之壓出機中熔融揑合。接著,利用兩個壓出 機,將其層合至上述(1)中製成之經5-倍延伸薄片之兩個表 面上。將由此.三層所组成之層合薄片加熱至155°C,並在橫 向上利用擴幅器延伸機延伸8-倍。接著,使所獲得之延伸 薄膜在50瓦特/平方米•分鐘下,利用4:暈放電處理機( 由Kasuga Denki K.K.製造)接受電暈放電,於是獲得三層延伸 薄膜-。 -29 - 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X297公釐) 413225 at B7 五、發明説明(27 ) 此延伸薄膜之諸層個別具有厚度爲2〇微米/ 60 微米/ 20微米,同時此薄膜具有染槽平滑性爲450秒,密 度爲0.70克/立方公分,空隙比爲41%及不透明度爲93%。 其對具有上述组成之水彩噴墨油墨,顯示接觸角爲55°。 比較實例9 ⑴在70重量%丙稀均聚物(由Mitsubishi化學公司製造), 其具有MFR爲0.8克/ 10分鐘,熔點164°C (DSC尖峰溫度)及 結晶度67%,與8重量%高密度聚乙烯之混合物中,添加 22重量%具有平均粒子大小0.15微米及顯示在25°C下之導 電率爲89 a S/cm之合成輕質碳酸鈣(BRILLIANT 15TM,由 Shiraishi Kogyo K.K製造)。將如此獲得之摻合物[i]在調整至 270°C之壓出機中熔融捏合,並以薄片形式壓出。於冷卻至 50Ό後,獲得未被延伸之薄片。接著,將此薄片加熱至135 °C並延伸5-倍縱長。 ⑺將40重量%丙烯均聚物(由Mitsubishi化學公司製造), 其具有MFR爲2克/ 10分鐘,熔點164°C (DSC尖峰溫度)及結 晶度65%,與60重量%具有平均粒子大小(U5微米及顯示 在25°C下之導電率爲89 # S/cm之合成輕質碳酸鈣(BRILLIANT lew,由Shiraishi Kogyo K.K.製造)混合。將如此獲得之播合 物[ii]在調整至270°C之壓出機中熔融揑合。接著,利用兩 個壓出機,將其層合至上述⑴中製成之經5-倍延伸薄片之 兩個表面上。將由此三層所组成之層合薄片加熱至155°C, 並在橫向上利用擴幅器延伸機延伸8-倍。接著,使所獲得 之延伸薄膜在50瓦特/平方米•分鐘下,利用電暈放電處 -30- 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X 297公釐) 請 先 Μ 請 背 之 i 事 項 本 頁 裝 訂 經濟部中央標準局員工消f合作社印製 413225 A7 B7 五、發明説明(28 ) 理機(由KasugaDenkiK.K.製造)接受電暈放電,於是獲得三 層延伸薄膜。 此延伸薄膜之諸層([ii]/[i]/[ii])個別具有厚度爲2〇微米/ 60 微米/20微米,而此薄膜具有染槽平滑性爲2,000秒,空隙 比爲25%及不透明度爲85%。 其顯示對具有上述组成之水彩噴墨油墨之接觸角爲53〇。 實例12至18 藉由與實例11中所述者相同之程序,但使用如在表3中 所指定之摻合物[i]與[ii],獲得經延伸之層合薄膜。 實例19 在70重量%丙烯均聚物(由Mitsubishi化學公司製造),其 具有MFR爲2克/ 10分鐘,熔點164°C (DSC尖峰溫度)及結晶 度67%,與8重量。/。高密度聚乙烯之混合物中,添加22重 量。/。在上述製造實例8中獲得並具有平均粒子大小1.0微米 之經研磨碳酸鈣,於是獲得摻合物[i]。個別地,將40重量 %丙烯均聚物(由Mitsubishi化學公司製造),其具有MFR爲 20克/ 10分鐘,熔點164°C (DSC尖峰溫度)及結晶度64%, 與60重量%在上述製造實例8中獲得並具有平均粒子大小 1.0微米之經研磨碳.酸鈣混合,於是獲得摻合物[ii]。將此 等摻合物[i]與[H]個別在兩個各調整至270°C之壓出機中熔融 揑合,然後共壓出成層合狀態,以致使摻合物[i]夾在摻合 物[ii]之間。於冷卻後,獲得三層未被延伸之薄膜。 然後,將此薄片加熱至135°C,並以單軸方式延伸5-倍縱 長。 -31 - 本紙張尺度適用中国國家標準(CNS ) A4規輅(210 X 297公釐) 418225 A7 經濟部中央標準局員工消費合作社印犁 _________B7 五、發明説明(29 ) 再者’使所獲得之延伸薄膜在50瓦特/平方米•分鐘下 ,利用電暈放電處理機(由KasugaDenki K.K.製造)接受電暈 放電,於是獲得三層延伸薄膜。此延伸薄膜之諸層 ([ii]/[i]/[ii])個別具有厚度爲20微米/ 60微米/ 20微米,同時 此薄膜具有染槽平滑性爲950秒,密度爲0.85克/立方公分 ,空隙比爲29%及不透明度爲93%。 實例20 以上文實例19中所述之相同組合物、相同層構造(意即 及相同程序,但改變各層厚度,獲得三層單軸延 伸薄片。 .其次’將此薄膜在橫向上,利用經加熱至155°C之擴幅器 延伸機延伸8-倍,於是獲得三層' 經雙軸延伸之薄膜。 接著,使所獲得之延伸薄膜在50瓦特/平方米•分鐘下 ,利用電暈放電處理機(由Kasuga DenM Κ·Κ·製造)接受電暈 放電,於是獲得三層延伸薄膜。此延伸薄膜之諸層 ([ii]/[i]/[ii])個別具有厚度爲15微米/ 50微米/ IS微米,同時 此薄膜具有染槽平滑性爲2,000秒,密度爲0.70克/立方公 分’空隙比爲42%及不透明度爲90%。 比較實例11與12 藉由與實例.19中所述者相同之程序,但使用如在表4中 所指定之摻合物[i]與[ii],獲得經延伸之層合薄膜。 比較實例13與14 ' 藉由與實例20中所述者相同之程序,但使用如在表4中 所指定之掺合物[i]與[ii],獲得經延伸之層合薄膜。 __ - 32- 本紙張尺度適用中运^:標準(CNS ) A4規格(2I0X297公釐) ί請先凋讀背面之注意事項再,紅,^本頁) -裝 J5 .k.. 418225 Α7 Β7 五、發明説明(3〇 [評估方法] <對水彩喷墨印刷油墨之接觸角> (1) 在53重量%水中添加2重量% C.I.食品級黑色2號(由X After confirming that each color has been well developed, the sticky tube ‘’ Cellotape ™ ”(manufactured by Nichiban) is strongly adhered to a part of each printing paper’ and then quickly peeled along the adhesive surface. Next, the ink remaining on the synthetic paper was evaluated with the naked eye. As a result, each of the synthetic papers showed a high ink residual ratio (95 to 100%). On the other hand, the printed synthetic paper was immersed in flowing water for 5 minutes and the 27 MM scale was applied to the Chinese National Standard (CNS) A4 specification (210X297 mm) ^ 225 A7 B7 V. Description of the invention (25) Dry. Then, check the extent of the image and enemy lines remaining on it. As a result, each sample showed superior images remaining on it without wrinkles. Example 11 (1) In 70% by weight polypropylene (manufactured by Mitsubishi Chemical Co., Ltd.), which has an MFR of 0.8 g / 10 minutes, a melting point of 164 ° C (DSC spike temperature) and a crystallinity of 67%, and a high density of 8% by weight To the mixture of polyethyleneimine, 22% by weight was added. The ground calcium carbonate obtained in the above Production Example 5 and having an average particle size of u μm. The blend [i] thus obtained was melt-kneaded in an extruder adjusted to 270 ° C, and extruded in the form of a sheet. After cooling to -50 ° C, unstretched flakes were obtained. This sheet was then 'heated to 135 ° C and stretched 5-fold in length. (2) A 40% by weight propylene homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.) having an MFR of 2 g / 10 minutes, a melting point of 164X: (DSC spike temperature) and a crystallinity of 65%, and 60% by weight of 0 /. The ground calcium carbonate obtained in the above Production Example 5 and having an average particle size of 1.5 m was mixed. The thus obtained blend [ii] was melt-kneaded in an extruder adjusted to 27 ° C. Then, using two extruders, it was laminated to the 5-fold stretched sheet made in the above-mentioned ⑴ The two printed surfaces are printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. The laminated sheet composed of the three layers is heated to 155Ό, and it is extended 8-fold in the horizontal direction by an expander stretcher. The obtained stretched film was subjected to a corona discharge using a corona discharge processor (manufactured by KasugaDenJdK.Ki ·) at .50 watts / square meter • minutes, and thus three stretched films were obtained. Time / inquiry) Individually have a thickness of 20 microns / 60 microns / 20 microns, and at the same time this film has dyeing tank smoothness of 〖, 00 seconds, _____ -28- This paper size applies to China §] home standards (( ^ 5 > Six 4 specifications (2) 0 > < 297 mm 418225 ΑΊ Α7 Β7 V. Description of the invention (26) The density is 0.78 g / cm3 and the void ratio is 93%. It is for watercolor spray with the above composition. Ink ink, showing a contact angle of 25 °. Comparative Example 8 ⑴ at 70 weight Propylene homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.), which has a MFR of 0.8 g / 10 minutes, a melting point of 164 ° C (DSC spike temperature) and a crystallinity of 67%, in a mixture of 8% by weight high density polyethylene 22% by weight of dry-milled calcium carbonate (SOFTON 1800TM, manufactured by Shiraishi Calcium KK) having an average particle size of 1.5 microns and showing conductivity at 25 ° C. * Will be obtained in this way Blend [i] was melt-kneaded in an extruder adjusted to 270 ° C and extruded as a sheet. After cooling to 50 ° C, an unstretched sheet was obtained. Next, this sheet was heated to 135 ° C and extended 5-fold vertical length. Employees of the Central Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China should read the cooperative printed matter (please read the notes on the back to write this page) ⑺ 40% by weight of propylene homopolymer (by Mitsubishi Chemical (Manufactured by the company), which has an MFR of 2 g / 10 minutes, a melting point of 164 ° C (DSC spike temperature) and a crystallinity of 65%, and 60% by weight has an average particle size of 1.5 microns and shows a conductivity at 25 ° C 63 # S / cm of dry ground calcium carbonate (SOFTON 1800tm, manufactured by Shiraishi Calc (made by ium KK)). The blend [ii] thus obtained was melt-kneaded in an extruder adjusted to 270 ° C. Next, it was laminated to the above-mentioned (1) by using two extruders. The finished sheet is stretched 5-fold on both surfaces of the sheet. The laminated sheet composed of the three layers is heated to 155 ° C, and stretched 8-fold in the transverse direction using an expander stretcher. Next, the obtained stretched film was subjected to a corona discharge using a 4: corona discharge treatment machine (manufactured by Kasuga Denki K.K.) at 50 watts per square meter · minute, thereby obtaining a three-layer stretched film-. -29-This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X297 mm) 413225 at B7 V. Description of the invention (27) Each layer of this stretched film has a thickness of 20 microns / 60 microns / 20 microns. At the same time, the film has a dyeing tank smoothness of 450 seconds, a density of 0.70 g / cm3, a void ratio of 41%, and an opacity of 93%. It shows a contact angle of 55 ° for a watercolor inkjet ink having the above composition. Comparative Example 9: 70% by weight acrylic homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.) having an MFR of 0.8 g / 10 minutes, a melting point of 164 ° C (DSC spike temperature), and a crystallinity of 67%, with 8% by weight To the mixture of high-density polyethylene, 22% by weight of synthetic light calcium carbonate (BRILLIANT 15TM, manufactured by Shiraishi Kogyo KK) having an average particle size of 0.15 micrometers and an electrical conductivity of 89 a S / cm at 25 ° C was added. . The blend [i] thus obtained was melt-kneaded in an extruder adjusted to 270 ° C, and extruded in the form of a sheet. After cooling to 50 ° C, an unstretched sheet was obtained. This sheet was then heated to 135 ° C and stretched 5-fold in length. ⑺ 40% by weight propylene homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.), which has an MFR of 2 g / 10 minutes, a melting point of 164 ° C (DSC spike temperature) and a crystallinity of 65%, and has an average particle size of 60% by weight (U5 microns and synthetic light calcium carbonate (BRILLIANT lew, manufactured by Shiraishi Kogyo KK) showing a conductivity of 89 # S / cm at 25 ° C were mixed. The pod [ii] thus obtained was adjusted to Melt and knead in an extruder at 270 ° C. Then, using two extruders, they were laminated to the two surfaces of the 5-fold stretched sheet made in the above-mentioned maggot. The laminated sheet was heated to 155 ° C and stretched 8-fold in the transverse direction using a tenter stretcher. Next, the obtained stretched film was subjected to a corona discharge at 50 watts per square meter · minutes. This paper size applies to Chinese National Standards (CNS) Λ4 specifications (210X 297 mm) Please note the following items: This page is bound to be printed by the staff of the Central Standards Bureau of the Ministry of Economic Affairs and printed by the cooperative 413225 A7 B7 V. Description of the invention (28) Machine (made by KasugaDenkiK.K.) Accepts electricity Discharge, and thus obtain three stretched films. The layers ([ii] / [i] / [ii]) of this stretched film each have a thickness of 20 μm / 60 μm / 20 μm, and the film has smoothness of the dyeing tank. It was 2,000 seconds, the void ratio was 25% and the opacity was 85%. It showed that the contact angle to the watercolor inkjet ink having the above composition was 53. Examples 12 to 18 By the same procedure as described in Example 11 However, using the blends [i] and [ii] as specified in Table 3, stretched laminated films were obtained. Example 19 At 70% by weight of a propylene homopolymer (manufactured by Mitsubishi Chemical Co.), which had The MFR is 2 g / 10 minutes, the melting point is 164 ° C (DSC peak temperature) and the crystallinity is 67%, and a mixture of 8 wt.% High-density polyethylene is added with 22 wt.% Obtained in the above production example 8. And having a milled calcium carbonate with an average particle size of 1.0 micron, thus obtaining a blend [i]. Individually, a 40% by weight propylene homopolymer (manufactured by Mitsubishi Chemical Co., Ltd.) having an MFR of 20 g / 10 minutes , Melting point 164 ° C (DSC peak temperature) and crystallinity 64%, and 60% by weight in the above The ground carbon obtained in Example 8 and having an average particle size of 1.0 μm was mixed with calcium acid to obtain a blend [ii]. These blends [i] and [H] were individually adjusted in two to It was melt-kneaded in an extruder at 270 ° C, and then co-extruded into a laminated state, so that the blend [i] was sandwiched between the blends [ii]. After cooling, three unstretched films were obtained. This sheet was then heated to 135 ° C and stretched 5-fold in length in a uniaxial manner. -31-This paper size is subject to Chinese National Standard (CNS) A4 Regulations (210 X 297 mm) 418225 A7 Employee Consumer Cooperative Cooperative Plow of Central Standards Bureau, Ministry of Economic Affairs _________B7 V. Description of Invention (29) Furthermore, the The stretched film was subjected to a corona discharge using a corona discharge processor (manufactured by KasugaDenki KK) at 50 watts / square meter • minutes, thereby obtaining a three-layer stretched film. The layers ([ii] / [i] / [ii]) of this stretched film each have a thickness of 20 microns / 60 microns / 20 microns, and the film has a dyeing tank smoothness of 950 seconds and a density of 0.85 g / cubic. Cm, the void ratio is 29% and the opacity is 93%. Example 20 The same composition and the same layer structure described in Example 19 above (meaning the same procedure, but changing the thickness of each layer to obtain a three-layer uniaxially stretched sheet. Secondly, this film was used in the transverse direction, using heated The Extender Stretcher to 155 ° C was extended 8-fold, and thus three layers of biaxially stretched film were obtained. Next, the obtained stretched film was treated with corona discharge at 50 W / m2 · min. The machine (manufactured by Kasuga DenM K · K ·) received a corona discharge, thereby obtaining a three-layer stretched film. The layers ([ii] / [i] / [ii]) of this stretched film each had a thickness of 15 microns / 50 Micron / IS micron, at the same time, this film has a dyeing tank smoothness of 2,000 seconds, a density of 0.70 g / cm³, a void ratio of 42%, and an opacity of 90%. Comparative Examples 11 and 12 The same procedure was described, but using the blends [i] and [ii] as specified in Table 4, stretched laminated films were obtained. Comparative Examples 13 and 14 ′ By the same as described in Example 20 Same procedure, but using blends [i] and [ii] as specified in Table 4, obtain Stretched laminated film. __-32- This paper size is suitable for Chinese transportation ^: Standard (CNS) A4 size (2I0X297 mm) ί Please read the precautions on the back, red, ^ this page)-installed J5 .k .. 418225 Α7 Β7 V. Description of the invention (3 [Evaluation method] < Contact angle to watercolor inkjet printing ink > (1) Add 2% by weight of CI food grade black No. 2 in 53% by weight of water ( by
Mitsubishi化學品公司製造)、重量% N-甲基-2-四氫p比略嗣 、20重量%二乙二醇及15重量%聚乙二醇(分子量:200), 並以攪拌器充分攪拌,於是獲得供水彩喷墨印刷用之黑色 記錄液(油墨)。 , (2) 在恒溫室(23°C,RH 50% )中,以注射器收集上述油墨, 並以適當量滴落在實例Π .至20及比較實例7至13中所獲得 之合成紙之表面上,而得直徑2毫米之液滴區域。於滴加後 土 即使用 CONTACT-ANGEL METER? Μ (由 Kyowa Kaimenkagaku K.K·製造)度量接觸角。表3與4顯示如此獲得之數據。 <喷墨油墨適印性> ⑴乾燥時間(秒) 利用噴墨印表機BJC-410J (由Canon公司製造),將實例η 至20及比較實例7至13獲得之合成紙,使用水彩噴墨記錄 液BCI-21 (黃色、紫紅色、藍綠色 '黑色)進行彩色印刷。 然後,將以各種顏色印刷之部份,以手指摩擦,不會導致 痕跡所需要之時間係被稱爲乾燥時間。 ⑺流動性 以肉眼根據下列標準評估在上述條件下印刷之各種顏色 油墨之流動性。 、 Ό : 未發現任何顏色流動。 〇:在特定顏色上發現輕微流動,於實用上不會造成 -33 本紙张尺度適用中國园家標準(CNS ) Α4規格(2Ι0Χ297公潑) i 裝 訂 經濟部中央摞準局員工消費合作社印$ί 41 ^ 41 ^ 經濟、部中央標準局員工消费合作社印則木 Α7 Β7 五、發明説明(31 ) -- 問題。 △:在各種顏色上發現流動,實際上無法使用。 X :在各種顏色上發現嚴重流動。 (3)影像品質 利用相同印表機與記錄液印刷肖像,並以肉眼根據下列 標準評估影像品質。 ◎:良好。 〇:油墨密度稍低,於實用上不會造成問題。 △:由於低油墨密度及油墨流動性,故實際上無法使 用。 X : 不良。 <在噴墨印刷上之油墨殘留性質> 接著,使黏勝帶"Cell〇tapeT M"(由Mchiban公司製造)強力黏 著至各印刷紙之—部份,然後沿著黏著面迅速剝離。表3 與4顯示留在合成紙上之油墨。 <水性黏著劑之乾燥性質> 將實例11至20及比較實例8至14中所獲得之合成紙,切 成片塊(8 X 8公分)。然後,將一種澱粉黏著劑 600TM(固含量:33%,由TokiwaKagakuK.K.製造)使用塗液器 均勻地塗敷在其表面上,而得1〇微米厚度。黏著劑之光澤 消失所需要之時間,係被稱爲乾燥時間,該光澤消失係由 於其水份浸透至紙中所致。 本發明使得能夠提供一種具有微細研磨碳酸鈣粒子凸出 之合成紙,該粒子具有親水性表面,環繞此表面形成許多 ____ __ - 34 - 本紙浪尺度適用中ϋ家標準(Λ4規格(210><297公漦)' —— - {請先閲讀背面之注意事項^^寫本頁) 裝. --° 418225 A7 B7 五、發明説明(32 ) 微細裂缝,且此合成紙顯示對水彩油墨及水性黏著劑之經 改良水份吸收率,快乾性質及優越適印性。 (請先開讀背面之注意事項本頁} 裝. -11 經濟部中央標準局員工消费合作社印掣 35- 本紙张尺度適用中國國家標牟(CNS ) Λ4規格(2!0X 297公釐) 418225 五、發明説明(33 ) pp:al專!好萃 pml^^^^c1-^ 經濟部中央標準局員工消f合作社印製 A7 B7 比較 實例2 比較 文例1 實例 6 實例 5 實例· 4 實例 3 實例 z 實例. 1 〇 s CD σι 〇 摻合量(重量%) 摻合物[i] 03 C0 CD C〇 CD CO ςο 22 輕質 碳酸鈣 嵙每 22 製造 實例1 32 製造 實例1 27 . 製造 i實例ΐ^ 22 製造 實例3 _ 22 製造 ±.n2. 22 製造 實例1 破醢鈣 ρ ϋΊ c: οι ΟΙ ρ O ίη 粒子大小 (微米) 二 g CD § έ 二 ο *Ό 摻合量(重量%) #合物[i] 丨 60 . ΪΜΗ 1 GO 乾磨 碳酸鈣 50 製造 官·例4 70 製造· 實例1 40 製造 赏-例 3 — 60- 製造 1實例3 60 製造 實例2 GO 製造 實例1 碳酸鈣 P ’〇 '〇 L--T ρ JS. Ο Ο in 粒于大小 (微米). ? N3 ο . 4J .Ό ςη 3福 表而性f 嚴朮 :ks. ;P 聆 微 V=x :‘;、 輕微 •J=、 於表而 層十之' 切痕 > i> Q ,.·=ϊ·- •ϋ' ο • ◎ ΐ» 平版印刷 | 適生 | : 〇 /=> D 0 »* > !> ◦ 〇 S ◎ ◎ Ο .鸯 > 〇 〇 Ο Ο ◎ ◎ /5=¾. \ 黏著性 凹版印刷; 〇 CJ οι 白點 "|Sa ^51 择專 請 先 讀 背 之 注 意 事 項 t 裝 訂(Manufactured by Mitsubishi Chemical Co., Ltd.), weight% N-methyl-2-tetrahydro p ratio slightly higher, 20% by weight of diethylene glycol and 15% by weight of polyethylene glycol (molecular weight: 200), and stir thoroughly with a stirrer Then, a black recording liquid (ink) for watercolor inkjet printing was obtained. (2) In a thermostatic chamber (23 ° C, RH 50%), collect the above ink with a syringe, and drop the appropriate amount on the surface of the synthetic paper obtained in Examples Π. To 20 and Comparative Examples 7 to 13. To obtain a droplet area of 2 mm in diameter. After the dropwise addition, the contact angle was measured using CONTACT-ANGEL METER? M (manufactured by Kyowa Kaimenkagaku K.K.). Tables 3 and 4 show the data thus obtained. < Printability of inkjet inks > ⑴ Drying time (seconds) Using inkjet printer BJC-410J (manufactured by Canon), the synthetic papers obtained in Examples η to 20 and Comparative Examples 7 to 13 were made using watercolor. The inkjet recording liquid BCI-21 (yellow, magenta, cyan 'black) is used for color printing. Then, the time required for the parts printed in various colors to be rubbed with fingers without causing traces is called the drying time. ⑺ Fluidity The fluidity of various color inks printed under the above conditions was evaluated with the naked eye according to the following criteria. , Ό: No color flow was found. 〇: Slight flow is found in specific colors, which will not cause -33 in practical use. This paper size applies the Chinese Garden Standard (CNS) A4 specification (2Ι0 × 297). 41 ^ 41 ^ Yin Zemu A7 B7, Consumer Cooperative of Employees' Cooperatives of the Central Bureau of Standards of the Ministry of Economy and Economics 5. Explanation of the Invention (31)-Question. △: Flow is found in various colors, but it is practically unusable. X: Severe flow was found on various colors. (3) Image quality Use the same printer and recording solution to print portraits, and evaluate the image quality with the naked eye according to the following criteria. :: Good. 〇: The ink density is slightly lower, which does not cause a problem in practical use. △: Due to the low ink density and ink flowability, it is practically unusable. X: Defective. < Ink Residue Properties on Inkjet Printing > Next, the adhesive tape " Cell〇tapeT M " (manufactured by Mchiban) was strongly adhered to a part of each printing paper, and then quickly peeled off along the adhesive surface. . Tables 3 and 4 show the inks left on the synthetic paper. < Drying properties of water-based adhesive > The synthetic papers obtained in Examples 11 to 20 and Comparative Examples 8 to 14 were cut into pieces (8 X 8 cm). Then, a starch adhesive 600TM (solid content: 33%, manufactured by Tokiwa Kagaku K.K.) was uniformly applied on the surface thereof using a liquid applicator to obtain a thickness of 10 µm. The time it takes for the gloss of the adhesive to disappear is called the drying time. This gloss disappears because its moisture penetrates into the paper. The present invention makes it possible to provide a synthetic paper with finely milled calcium carbonate particles protruding, the particles having a hydrophilic surface, and forming a plurality of __ __-34-This paper is compliant with the Zhongjia standard (Λ4 specification (210 > < 297 公 漦) '——-{Please read the notes on the back ^^ write this page first).-° 418225 A7 B7 V. Description of the invention (32) Fine cracks, and this synthetic paper shows the effect of watercolor ink And water-based adhesives have improved moisture absorption, fast-drying properties and superior printability. (Please read the precautions on the back page first) Packing. -11 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 35- This paper size applies to China National Standards (CNS) Λ4 specifications (2! 0X 297 mm) 418225 V. Description of the invention (33) pp: al special! Good extract pml ^^^^ c1- ^ Employees of the Central Bureau of Standards of the Ministry of Economic Affairs, printed by the cooperative A7 B7 Comparative example 2 Comparative example 1 Example 6 Example 5 Example 4 Example 3 Example z Example. 1 〇s CD σι 〇 Blending amount (% by weight) Blend [i] 03 C0 CD Co CD CO ο 22 Light calcium carbonate 嵙 per 22 Manufacture example 1 32 Manufacture example 1 27. Manufacture i Example ΐ 22 Manufacturing Example 3 _ 22 Manufacturing ± .n2. 22 Manufacturing Example 1 Broken calcium ρ ϋΊ c: οι ΟΙ ρ O ίη particle size (micron) 2 g CD § 二 2 ο * Ό blending amount (% by weight) ) # 物 [i] 丨 60. ΪΜΗ 1 GO dry ground calcium carbonate 50 Manufacturing Officer · Example 4 70 Manufacturing · Example 1 40 Manufacturing Award-Example 3 — 60- Manufacturing 1 Example 3 60 Manufacturing Example 2 GO Manufacturing Example 1 Carbonic acid Calcium P '〇'〇L--T ρ JS. 〇 〇 in Particle size (micron).? N3 ο. 4J .Ό ς 3 Fortune-telling f Strict technique: ks .; P Listen V = x: ';, Slight • J =, On the surface and ten layers of' Cut > i > Q,. · = Ϊ ·-• ϋ 'ο • ◎ ΐ »Lithography | Shi Sheng |: 〇 / = > D 0» * >! > ◦ 〇S ◎ ◎ 〇. 鸯 > 〇〇〇 〇 ◎ ◎ / 5 = ¾. \ Adhesive Intaglio printing; 〇CJ οι White Dots " | Sa ^ 51 Please read the notes before choosing the special t binding
.I __-36- 本紙張尺度適用中國國家標準(CNS ) Λ4規格(2〗〇X297公釐) ilS225 ΑΊ B7 五、發明説明(34 ) 經濟部中央梂準局員工消f合作社印製 比較 .實例^ 比較 實例5 比較 •實例4 ;「匕較 實例3 •實例8 、實例7 2 'vl *0 -〇 摻合贵(Φ量%) 摻合物[i] 〇? Ο CD & CO CO 菸垮 3r 22 乾磨 碳酸鈣 22 輕質 碳酸鈣 离陆 OH 22 製造 實例1 Ί 22 製造. ir- m ί '碳酸鈣 〇 cn CJ1 Ο ί. C71 _Λ b _> σ 粒子大小 (微米) 〇 έ 二 〇 > o 摻合量(重量%) 摻合物[i] 彝Sr g 雜持ο 熟锫 耜銲S 60 . 製造 實-例1 60 製造 t例丨: 碳酸鈣 p bi p »A b b 粒子火小 (微来) .二 CD .*〇 w on Ό jn Ο*-'·'! 、,· 丧而性ΐί_ Ik ΊΓ .十.¾微; 輕微 1 P S*念芩 ?Ξ> ~S- M.&' > > ζ~\ > 0 «sy· 乎版印刷 > ζ-\ 0 .◎ .今· 密度 _> 0 ο ' r~\ 〇 紙粉麂 ί> ο > 〇 ◎ © 黏著性 g 戸、 JTs Ν> ◦ Λ <_n CO N5 ro Ί 3—層便軸 3-層單抽 3-層雙軸- 3-層艰軸 ^ ;:^ w·· · 37 - 請 先 閲 讀 背 面 之 注 項 寫 本 頁 本紙張尺度適用中國國家標卒(CNS ) Λ4規格(210X 297公釐) 52CM3 V1 4.I __- 36- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (2〗 〇297297 mm) ilS225 ΑΊ B7 V. Description of the invention (34) Employees of the Central Procurement Bureau of the Ministry of Economic Affairs printed and compared with the cooperatives. Example ^ Comparative Example 5 Comparative • Example 4; “Comparative Example 3 • Example 8 and Example 7 2 'vl * 0 -〇 Blended expensive (Φ%) Blend [i] 〇? 〇 CD & CO CO Yanbian 3r 22 Dry ground calcium carbonate 22 Light calcium carbonate off-shore OH 22 Manufacturing example 1 Ί 22 Manufacturing. Ir- m ί 'Calcium carbonate 〇cn CJ1 Ο ί. C71 _Λ b _ > σ Particle size (micron) 〇έ 〇 > o Blending amount (% by weight) Blend [i] Yi Sr g Miscellaneous ο Cooked S 60. Manufacturing Practice-Example 1 60 Manufacturing Example 丨: Calcium Carbonate p bi p »A bb The particle fire is small (micro come). Two CDs. * 〇w on Ό jn Ο *-'·'! ,,, and funeral ΐ_ Ik ΊΓ. Ten .¾ micro; slight 1 PS * 念 芩? Ξ > ~ S -M. & '> > ζ ~ \ > 0 «sy · Huban Printing > ζ- \ 0. ◎. Today · Density_ > 0 ο' r ~ \ 〇 纸 粉 麂 ί > ο > 〇 ◎ © Adhesive g 戸, JTs Ν > ◦ Λ < _n CO N5 ro Ί 3--layer toilet shaft 3-layer single pump 3-layer dual shaft-3-layer hard shaft ^ : ^ w ·· · 37-Please read the note on the back first Written on this page This paper is sized for China National Standards (CNS) Λ4 (210X 297 mm) 52CM3 V1 4
AA
7 B 五、發明説明(35 經濟部中央標準局員工消f合作社印¾ :出 % 比較 實例8 實例 1S t例 A ‘ S tn崎 實例 u 實例. 13 實例 12 實例. 11 Ol f〇 s *O -a 摻合f (京1%) .摻合物[i] CD CO CD CD CD 0» CD CB CO ca -〇 m ro .〇 ro ?i NJ ro r〇 fO N5 ro fO N> Ν» ro ro 碳酸鈣 輕質 碳酸鈣 乾磨 碳酸鈣 製造 實例5? 製造 實例8 製造: 實例10 製造 實例9 . .製造 實例8 製造 實例7 製造 實例6 製造 實例5 〇 CJ1 Ο In p o ίη bi 粒子 火小 (微米) έ A CJ JV S έ s έ έ # 合贵(1r f %) 摻合物[i] g g g g ο o g ο g 碳故鈣 輕贺 碳酸钙 [^磨 破敁鈣 〇〇 製造 : 實例8 製造 f例10 製造 f例9 製造 實例8 製造 實例7 ο 製造 f例5 P LT, C· 〇 二 Ο C~ u ), 坆小 (微來) 0, wl ,Ό ΓΟ 3 n; .*〇 CJ ro w Ln 對水彩 喷.1:油 之接 觸Λ 〇 g 0*1 CTi Ο ο CO 5 乾垛 (秒) 水彩噴墨油墨之 適印性 X X ◎ 3 Q ◎ ◎ «a 流 ίν; I X X Ο •ss> «as/ ◎ ◎ ◎ /«*· 影像 品f ,Ό g ΓΟ σϊ S iO C3 ro CP. CJ cn CJ fVJ JX ro ο g Cl g g g ra ΟΊ Ο Cn \ 殘留油 ‘墨(%) g CT> p ΟΊ ΙΝί o ο Ch 0*1 ◦ 水性黏著 劑之乾燥 時間 〔分铖) -iw- ί-Γ^ -^r· C請先聞讀背面之注意事項再4;寫本頁) . ^ ~ 7=;,裝. 訂 —\Λ^_____ -38 本紙張尺度適用中國國家標準(CNS ) A4規格(21〇Χϊ97公釐) 413225 ' A7 B7 五、發明説明(36 ) PP: a尊甚漪參. pm:舯锻碎渖6莓· 經濟部中央標準局員工消費合作社印裝 比較 實例 12 =够 %% 〇崎 實例1 20 實例 19 *v| -j v 摻合量(重量%) 摻合物[i] ca ο CO CD cq CD ~3 n ro Νί PO jNi PsJ N> ΓΟ ΓΟ ro ΓΟ ISJ 碳酸鈣 輕質 碳酸鈣 乾磨 碳酸鈣 輕質 碳酸鈣 爵输· <Jri 宣.β- ΟΟ 00 p in It Ο C/l ϊη ο b 粒子大小 (微米) έ % ,合 έ ο i. 摻合量(重量%) 摻合物[i] § ο ο Οϊ g ο S · 碳酸鈣 輕質 碳酸鈣 乾磨 碳酸鈣 輕質 碳酸鈣 乾磨 破酸鈣 製造 f例S 畸裤 〇〇 p ΙΛ ί?Ί ρ οτ ί: b b 粒子大小 mm Ci tn ίΛ Ο ο N: ro Ca 迹翁駟驷改璋 遨~芬喊斧 Ο ο Ο Ο G Ο cz 乾燥 (秒) S'跨 X X X. X Q · o 流動 X X X X .1¾ ◎ 影像 品質 Ο έ σΐ U ro lO 1 空隙 比例 (%) 1 -«J Ο ο CJ 〇 Μ穿 Οϊ Ο CD p - g <Τι o to 水性黏 著劑之 乾燥時 間 (分鐘) 3-層哽軸 3-層雙軸 3-層單李ib 3-層單軸 3-艰货軸 3-層單轴 經延 伸層 構造 C請先聞讀背面之注意事項再取寫本頁) __-39- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐〉7 B V. Description of the invention (35 Employees of the Central Standards Bureau of the Ministry of Economic Affairs of the People's Republic of China Cooperative Association ¾: Out% Comparative Example 8 Example 1S t Example A 'S tn Qi Example u Example. 13 Example 12 Example. 11 Ol f〇s * O -a Blend f (Beijing 1%). Blend [i] CD CO CD CD CD 0 »CD CB CO ca -〇m ro .〇ro? i NJ ro r〇fO N5 ro fO N > Ν» ro ro Calcium Carbonate Light Calcium Carbonate Dry Milled Calcium Carbonate Manufacturing Example 5? Manufacturing Example 8 Manufacturing: Example 10 Manufacturing Example 9.. Manufacturing Example 8 Manufacturing Example 7 Manufacturing Example 6 Manufacturing Example 5 〇CJ1 〇 In po ί fire small ( Micron) έ A CJ JV S έ s έέ # 合 贵 (1r f%) Blend [i] gggg ο og ο g Carbon So Calcium Caesar Calcium Carbonate [^ 磨破 敁 Calcium 〇〇Manufacture: Example 8 Manufacturing f Example 10 Manufacturing f Example 9 Manufacturing Example 8 Manufacturing Example 7 ο Manufacturing f Example 5 P LT, C · 〇20 C ~ u), 坆 小 (微 来) 0, wl, Ό ΓΟ 3 n;. * 〇CJ ro w Ln Spray on watercolor. 1: Oil contact Λ 〇g 0 * 1 CTi 〇 ο CO 5 Dry stacking (seconds) Printability of watercolor inkjet ink XX 3 Q ◎ «a flow ίν; IXX Ο • ss >« as / ◎ ◎ ◎ / «* · Video product f, Ό g Γ〇 σϊ S iO C3 ro CP. CJ cn CJ fVJ JX ro ο g Cl ggg ra ΟΊ Ο Cn \ Residual oil ink (%) g CT > p ΟΊ ΙΝί o ο Ch 0 * 1 ◦ Drying time of water-based adhesives (minutes) -iw- ί-Γ ^-^ r · C Please read the notes on the back first (4 more; write this page). ^ ~ 7 = ;, binding. Order — \ Λ ^ _____ -38 This paper size is applicable to Chinese National Standard (CNS) A4 specification (21〇 × 97 mm) 413225 'A7 B7 V. Invention Explanation (36) PP: a respected ginseng. Pm: 舯 fortified 渖 6 berry · Comparison of printing by employee consumer cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 12 = %%% 〇 Example 1 20 Example 19 * v | -jv Blend (% by weight) Blend [i] ca ο CO CD cq CD ~ 3 n ro Νί PO jNi PsJ N > ΓΟ ΓΟ ro ΓΟ ISJ calcium carbonate light calcium carbonate dry milling calcium carbonate light calcium carbonate · ≪ Jri Xuan. Β- ΟΟ 00 p in It 〇 C / l ϊη ο b Particle size (micron) %%, ο i. Blending amount (% by weight) Blend [i] § ο ο Οϊ g ο S · Calcium Acid Light Calcium Carbonate Dry Milled Calcium Carbonate Dry Calcium Carbonate Dry Milled Calcium Acid Manufacture f Case S Abnormal pants 〇〇p ΙΛ ί? Ί ρ οτ ί: bb Particle size mm Ci tn ίΛ Ο ο N: ro Ca trace翁 驷 驷 改 璋 遨 ~ fen shout ax 〇 ο Ο Ο G Ο cz Dry (seconds) S 'span XX X. XQ · o flow XXXX .1¾ ◎ image quality 〇 σΐ U ro lO 1 void ratio (%) 1-« J Ο ο CJ 〇Μ Through 〇ϊ 〇 CD p-g < T o o to the drying time of the water-based adhesive (minutes) 3-layer 哽 axis 3-layer double-axis 3-layer single li 3-layer single-axis 3- Difficult cargo shaft 3-layer single-axis extended layer structure C, please read and read the notes on the back before writing this page) __- 39- This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm>
Claims (1)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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JP01048497A JP3600703B2 (en) | 1997-01-23 | 1997-01-23 | Synthetic paper with excellent printability |
JP2733697A JP3599520B2 (en) | 1997-01-28 | 1997-01-28 | Stretched resin film |
JP3145997A JP3853006B2 (en) | 1997-01-31 | 1997-01-31 | Water-based inkjet recording paper |
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TW418225B true TW418225B (en) | 2001-01-11 |
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Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW87100979A TW418225B (en) | 1997-01-23 | 1998-01-23 | Synthetic paper and inkjet recording paper with the use of the same |
Country Status (1)
Country | Link |
---|---|
TW (1) | TW418225B (en) |
-
1998
- 1998-01-23 TW TW87100979A patent/TW418225B/en not_active IP Right Cessation
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