TW418183B - Hair hydrolysis to produce amino acids by microwave radiation - Google Patents

Hair hydrolysis to produce amino acids by microwave radiation Download PDF

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Publication number
TW418183B
TW418183B TW86109148A TW86109148A TW418183B TW 418183 B TW418183 B TW 418183B TW 86109148 A TW86109148 A TW 86109148A TW 86109148 A TW86109148 A TW 86109148A TW 418183 B TW418183 B TW 418183B
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TW
Taiwan
Prior art keywords
hair
microwave radiation
hydrolysis
amino acids
watts
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TW86109148A
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Chinese (zh)
Inventor
You-Jr Chen
Jr-Ru Jou
Hua-Shan Dai
Original Assignee
Chen You Jr
Jou Jr Ru
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Priority to TW86109148A priority Critical patent/TW418183B/en
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Publication of TW418183B publication Critical patent/TW418183B/en

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Abstract

This method applied microwave radiation to hydrolyze hair to produce amino acids. It dissolved hair in; 20.5% HCl, 6N NaOH or 6NBa(OH)2. The weight ratio of hair: solvent is at a range of 1:10-20. The solvent with hair was hold for 20 minutes before placed in a high-pressure reactor. A microwave energy of 800 to 1,000 watts was radiated to the reactor for 60 seconds. It followed a microwave radiation of energy increasing from 0 to 200 watts with a period 120-second lasting 25 to 35 minutes. The final product was yellow-color acid of a non-newtonian fluid.

Description

4 18 183 A7 B7 五、發明説明(.1 ) 本發明像有關於一種徹波幅射毛髮水解反應製造氨基 酸之方法,係尤指一種經馆酸混合、浸潰及微波幅射後, ^ 可將動物毛髮分解成可利用之氨基酸,而將原本無用之毛 髮作再回收利用,而達到資源之回收及再利用。 台潍地區泰豬約一千四百萬頭,養雞、鴨、鵝物一億 二千萬隻,宰殺後之毛髮約二萬公噸K上,疽些毛髮焚化 處理有惡臭,若經掩埋需多年才能經微生物逐漸分解而回 歸大地;主因為動物的毛髮中含有90Ϊ Μ上的角蛋白,該 角蛋白係不被一般微生物所分泌的蛋白質水解,亦不被植 物性及動性性酵素水解,而只能被少收能夠分泌角蛋白水 解酵素之微生物水解,且不同動物毛髮所需要的此類微生 物所分解之角蛋白水解酵素亦有不同;於目前僅知一種名 為Bacillus Lichenifoniis的细菌能分解雞毛而產生氨基酸;而 一般酸性或鹼性水解亦能達水解動物毛髮並產生氨基酸, 但Μ酸性、鹼性來水解各種動物毛髮極為耗時,在最佳操 作條件(反應溫度108.5Ό ,毛繫與20.5¾塩酸、6Ν的氳氧化 納或氫氧化鋇的重1比為1:20 )下,一次水解係需要約12 (請先閱讀背而之注意事項再填寫本頁) 訂 經濟部中央標準局貝工消费合作社印裝 發期 解試可 係, 水解係 -法 髮水中 試方 毛等間 實之 射酸時 及酸 幅馆之 究基 波與短 研胺 微髮極 斷出 種毛於 0 不造 一物, 求間製 β 供動後 需時並的提將射 ~ 上長 髮目於係 幅 2 業經毛之在其波 i 產係物用係 ,徽 符人動利的法經 不 明解再 目方再 為發水及要之 , 極 ·速收主酸後 故此快回之基潰 ,於可源明氨浸 上鑑種資發堦 、 M有一到本製合 時 出達 懕混 小 明能 反劑 本紙張尺度適用中國國家摞率(CNS ) A4洗格(210x 297公釐) 418183 A7 B7 五、發明説明(2 ) 完成毛髮之水解,且經水解後之毛髮係可為-.具再使用功 效之氨基酸。 為使本發明使用之技術特擞、方法及發明目的易於明 白了解,茲配合圖式及圖號詳细說明如下: 參照圖式: 第一画:本發明之示意圖 第二圖:本發明之姐成物一覽表 第三圖:本發明之姐成表 參照圓號: ⑴微波室 (11}轉盤 (12)火力_ (13)計時器 (14>級波照射器 (15)排氣孔 (16)導管 (17)中和槽 (2) 容器 (21)平台 (22)水 (23)錐形容室 (24)塞子 本發明之微波糂射毛髮水解反應製造氨基酸之方法, 其係以各種動物之毛髮與濃度20.53;之塩酸等水解試劑混合 ,而動物毛髮與塩酸之重量比是1:10-20 ,將該混合物浸漬 20分鐘後,容置於一密閉錐形容器中,該密閉维形容器係 為石英或玻璃材霣所製成。諝參閲第一圈所示,微波室⑴ 内設有轉盤(11)供放置容器⑵,容器⑵内放有平台(21)及水(22) ,將故入毛髮及塩酸之錐形容器(23)置於平台(21>上,配合火 力鍵(12)及計時器(13)的控制,利用激波照射器(14)Μ微波幅射 〜3〜 本紙張尺度適用中國明家樣率(CNS ) A4*l格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁) 訂 -1 經濟部中央揉準局負工消費合作社印製 經濟部中央梂準局兵工消费合作社印製 五、發明説明(.3 ) 1.0-加分鐘浚,該毛髮將水解成黃色黏稱狀之蛋白質,而其 7K解後之溫度為攝氐;錐形容器⑶)上具有塞子(24)且 利用鋁鉑予K包覆而達到密閉之功效;當微波進行時,利 用鋁鉑防止高壓產生的氣體彈開,且配合水(22)K達到降低 災害之目的;另外,高溫高壓氣體可藉由排氣孔(14)及導管 (16)導引到中和槽(17)中作中和。該經激波幅射後之動物毛 髮係水解成含不同重量百分率之麩胺酸醯胺(G1ut.Mine)、天 門冬醸胺(Asparagine)、白胺酸(Leucine)、腩胺酸(Proline)等二十 餘種不同成份含最之可利用物質,請配合參閲附件一、二 圃表所示。 經微波幅射水解各種動物毛髮較省時亦較省能,本發 明K功率800-1000瓦特的微波輻射加熱60秒,繼之由功率0瓦特提升 至200瓦特的淅進能量方式微波輻射加熱丨20秒的週期性方式加熱25-35分 趣,水解宪畢產生氨基酸,其產生的氨約為化學性水解的 1/5-1/6 ,僅ί占總重量的102¾左右;氨基酸的含氮百分率比 19.8% ;藉本發明之胺基酸製造方法,其水解後之各種化合 物質得Μ再取回或為原料如:動物阏補充劑料、藥劑等等 ,而達到資源苒利用之效果。 综上所述,本發明實施例確能達到所預期之使用功效 ,又其所揭鼉之具髏構進,不僅未曾見諸於同類產品中, 亦未曾公開於申講前,誠已完全符合專利法之規定與要求 ,爰依法提出發明專利之申請.懇請惠予審査,並賜准專 利,則實感德便。 本紙張尺度適用中國困家揉準(CNS } A4現格(210X297公釐) {請先閱讀背面之注意事項再填寫本頁) 訂 "4 18 183 A7 B7 V. Description of the invention (.1) The present invention relates to a method for producing amino acids through the hydrolysis of cut-wave radiation hair, especially a method of mixing, dipping and microwave irradiation of acid in the hall, ^ 可The animal hair is decomposed into available amino acids, and the originally useless hair is recovered and reused to achieve the recovery and reuse of resources. There are about 14 million Thai pigs in Taiwan and Weihai, 120 million chickens, ducks, and geese. The hair after slaughter is about 20,000 metric tons K. The incineration of some gangrene hairs has a foul odor. It can take many years for the microorganisms to gradually decompose and return to the earth; the main reason is that the hair of animals contains keratin on 90ΪM. This keratin is not hydrolyzed by proteins secreted by general microorganisms, and is not hydrolyzed by plant and animal enzymes. It can only be hydrolyzed by microorganisms that can secrete keratin hydrolytic enzymes, and the keratin hydrolytic enzymes broken down by such microorganisms required by different animal hairs are different; only a bacterium called Bacillus Lichenifoniis can be broken down at present. Chicken hair produces amino acids; generally acidic or alkaline hydrolysis can also hydrolyze animal hair and produce amino acids, but M acidic and alkaline to hydrolyze various animal hair is extremely time-consuming. Under the best operating conditions (reaction temperature 108.5Ό, hair system) Under the ratio of 20.5¾ acetic acid, 6N arsenic sodium oxide, or barium hydroxide, the ratio of 1: 1 is 1:20, the primary hydrolysis system needs about 12 (please read the precautions in the back first) (Fill in this page again) Set the test period for the printing and distribution period of the Central Standards Bureau Shellfish Consumer Cooperative of the Ministry of Economic Affairs, the hydrolysis system-Fafa water test square hair, etc., and the base wave and short time Research amine micro hair cuts out the seed hair at 0, does not make a thing, and seeks the systemic beta. It takes time to raise the shoot after the movement ~ The long hair is in the line 2 and the hair is used in its wave i. The reason is that the law of Huiyu people's action is not clear, and then the purpose is to send water and ask for it. After the main acid is quickly collected, the base will quickly return, and the seed material will be dipped in the ammonia from the source of ammonia. M has one-to-one system when it is ready for use. The paper size is applicable to the Chinese national standard (CNS) A4 wash (210x 297 mm) 418183 A7 B7 V. Description of the invention (2) Complete hydrolysis of hair, And the hair after hydrolysis can be-. Amino acid with re-use effect. In order to make the technical features, methods, and purposes of the present invention easy to understand, the following detailed description is given with reference to the drawings and figures: Refer to the drawings: First picture: Schematic diagram of the present invention Second picture: Sister of the present invention The list of finished products The third picture: The sister of the present invention refers to the horn: ⑴Microwave chamber (11) turntable (12) firepower _ (13) timer (14 > stage wave irradiator (15) exhaust hole (16) duct (17) Neutralization tank (2) Container (21) Platform (22) Water (23) Conical chamber (24) Stopper The method for producing amino acids by the hydrolysis reaction of microwave radiated hair of the present invention is based on the hair of various animals and Concentration 20.53; mixed with hydrolysis reagents such as gallic acid, and the weight ratio of animal hair to gallic acid is 1: 10-20. After immersing the mixture for 20 minutes, it is placed in a closed conical container. The closed-dimensional container is Quartz or glass 霣. 谞 Refer to the first circle, the microwave chamber 盘 is equipped with a turntable (11) for placing the container ⑵, and the container ⑵ contains the platform (21) and water (22). The conical container (23) for hair and acetic acid is placed on the platform (21 >), with the fire button (12) and the meter Control of the device (13), using a microwave irradiator (14), microwave radiation ~ 3 ~ This paper size is applicable to China Mingjia sample rate (CNS) A4 * l grid (210X297 mm) (Please read the note on the back first Please fill in this page for further details) Order-1 Printed by the Ministry of Economic Affairs Central Labor Bureau Consumers' Cooperatives Printed by the Ministry of Economic Affairs Central Labor Bureau Consumers ’Cooperatives Printed by the Ministry of Economic Affairs Central Labor Bureau Consumers’ Cooperatives V. Invention Description (.3) 1.0-plus minutes, the hair will It is hydrolyzed into a yellow sticky protein, and its temperature after 7K solution is photographed; there is a plug (24) on the conical container (3) and it is sealed with aluminum platinum to cover K; when microwave is performed, Aluminium platinum is used to prevent the high-pressure gas from bouncing, and water (22) K is used to reduce the disaster; in addition, high-temperature and high-pressure gas can be guided to the neutralization tank (14) and the duct (16) through the exhaust hole (14) 17) Neutralization. The hair of the animal after the shock wave is hydrolyzed into G1ut.Mine, Asparagine, Leucine with different weight percentages. More than 20 different ingredients, including proline, contain the most available substances, please refer to the attached As shown in Tables 1 and 2. Hydrolysis of various animal hairs by microwave radiation is time-saving and energy-saving. The microwave radiation of K power 800-1000 watts of the present invention is heated for 60 seconds, and then increased from 0 watts to 200 watts. It is heated by microwave radiation in energy mode. It is heated for 25-35 minutes in a periodic mode of 20 seconds. Hydrolysis can produce amino acids, and the ammonia produced is about 1 / 5-1 / 6 of chemical hydrolysis, which only accounts for the total weight. About 102¾ of the amino acid; the nitrogen content of the amino acid is 19.8%; according to the amino acid manufacturing method of the present invention, the various compounds obtained after hydrolysis can be recovered or used as raw materials such as: animal supplements, pharmaceuticals, etc. To achieve the effect of resource 苒 utilization. In summary, the embodiments of the present invention can indeed achieve the expected use effect, and the skeleton structure disclosed by it is not only not seen in similar products, nor has it been disclosed before the presentation. According to the provisions and requirements of the Patent Law, an application for an invention patent is filed in accordance with the law. It is sincere to ask for approval and grant the patent. This paper size is suitable for Chinese families (CNS) A4 now (210X297 mm) {Please read the notes on the back before filling this page) Order "

Claims (1)

公告本 、申請專利範圍 (1> —種微波幅射毛髮水解反應製堦氨基酸之方法,其像 將乾淨的毛髮混於水解試劑,其濃度爲20.5%之鹽酸’ ⑽氫氧化鈉或6N氫氧化鋇等中,使其毛髮與水解試劑之重最比 為1:10-2(丨浸潰20分鐘Μ上,再容置於一密閉耐壓容器中Μ 功率SIHHOOO瓦特的微波幅射加熱60秒,繼之由功率0瓦特提升至 2〇〇瓦特的漸進能量方式微波輻射加熱120秒的週期性方式加熱25-35分鐘,使 該毛髮經.水解反應後形成具攝氐lQS.rc之黃色黏稠狀氨基 酸。 (請先閲讀背面之注意事項再填寫本頁) 、tT 經濟部中央揉準局貞工消费合作社印製 娜 率 困 面 中' 用 逋 5 <- 7 29 X ο 1Announcement and scope of patent application (1 > — A method for preparing ytterbium amino acids by microwave radiation hair hydrolysis reaction, which is like mixing clean hair with a hydrolysis reagent, and its concentration is 20.5% hydrochloric acid '⑽ sodium hydroxide or 6N hydroxide In barium, the ratio of the weight of hair to the hydrolysis reagent is 1: 10-2 (丨 immersed for 20 minutes Μ, and then placed in a closed pressure container Μ power SIHHOOO watt microwave radiation heating for 60 seconds Then, the power was gradually increased from 0 watts to 200 watts. Microwave radiation was heated for 120 seconds in a cyclical heating mode for 25-35 minutes to cause the hair to undergo a hydrolysis reaction to form a yellow viscous film with lQS.rc. (Please read the notes on the back before filling out this page), tT printed by the central government of the Ministry of Economic Affairs, the Jungong Consumer Cooperative Co., Ltd., printed on the rate of noodles, 逋 5 <-7 29 X ο 1
TW86109148A 1997-06-30 1997-06-30 Hair hydrolysis to produce amino acids by microwave radiation TW418183B (en)

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TW86109148A TW418183B (en) 1997-06-30 1997-06-30 Hair hydrolysis to produce amino acids by microwave radiation

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TW86109148A TW418183B (en) 1997-06-30 1997-06-30 Hair hydrolysis to produce amino acids by microwave radiation

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017192052A1 (en) * 2016-05-02 2017-11-09 Subasinghe Nissanke George Premalal Jayantha Dias Treatment of keratin-containing biological materials

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017192052A1 (en) * 2016-05-02 2017-11-09 Subasinghe Nissanke George Premalal Jayantha Dias Treatment of keratin-containing biological materials
CN109451722A (en) * 2016-05-02 2019-03-08 奥塔哥创新有限公司 The processing of biomaterial containing keratin
US11613557B2 (en) 2016-05-02 2023-03-28 Wool Research Organisation Of New Zealand Incorporated Treatment of keratin-containing biological materials

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