CN106094434A - A kind of preparation method of high rapidity high stable novel photoactive glue - Google Patents
A kind of preparation method of high rapidity high stable novel photoactive glue Download PDFInfo
- Publication number
- CN106094434A CN106094434A CN201610715402.9A CN201610715402A CN106094434A CN 106094434 A CN106094434 A CN 106094434A CN 201610715402 A CN201610715402 A CN 201610715402A CN 106094434 A CN106094434 A CN 106094434A
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- Prior art keywords
- solution
- gained
- glue
- preparation
- rapidity
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/031—Organic compounds not covered by group G03F7/029
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
- G03F7/033—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
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- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention discloses the preparation method of a kind of high rapidity high stable novel photoactive glue, comprises the following steps: 1) fully dissolve, with 300ml water, the polyvinyl alcohol that 40g alkalizes, obtain the poly-vinyl alcohol solution that mass concentration is 0.114g/ml；2) in the solution of step (1) gained, 12g polyvinyl acetate emulsion, 20gSBQ light-hardening resin, 5g acrylamide, 3g ethyl methacrylate, 0.8g dibutyl ester, 0.4g ethylenediamine, 1.8g light trigger 0.3g polyacrylamide amine emulsifier, 0.2g polymerization inhibitor, 0.5g emulsified silicone oil defoamer and 0.8g stain are the most accurately added；3) by the solution of gained 85 DEG C reaction 3h in step (2), period is stirred continuously, forms finely dispersed emulsion system；4) solution of gained in step (3) being down to room temperature, after standing 24h froth breaking, sealing is kept in Dark Place；The preparation method of this high rapidity high stable novel photoactive glue is unlikely to deteriorate, holding time length, photosensitive property are good.
Description
Technical field
Present invention relates particularly to the preparation method of a kind of high rapidity high stable novel photoactive glue.
Background technology
Photosensitizer (photosensitizer), also known as sensitizer, sensitizer, photocrosslinking agent.In photochemical reaction,
Luminous energy is transferred on the reactant that some are insensitive to visible ray to improve or to expand the material of its photosensitive property.
In photochemical reaction, have molecule, they only absorb photons and transfer energy to those can not absorbing light
The molecule of son, promotees it and chemical reaction occurs, itself be then not involved in chemical reaction, return to original state, and this quasi-molecule claims
For photosensitizer.The photochemical reaction caused by photosensitizer is referred to as photosensitivity reaction.Generally, people are adjoint raw have oxygen molecule to participate in
The photosensitivity reaction of thing effect is referred to as photodynamic reaction, calls light power photodynamic reaction can be caused to destroy cyto-architectural medicine
Medicine, i.e. photosensitive drug.
What the present market of photosensitizer commonly used is that the diazo resin that common p-xylene-4-diazol synthesizes is photosensitive
Agent, exists apt to deteriorate, and the holding time is short, the shortcoming that photosensitive property is bad.
Summary of the invention
For overcoming the problems of the prior art, the invention provides a kind of use 3-methoxy diphenylamine-4-diazol with
Traditional hexichol amine salt 1:1 is used in mixed way, and is unlikely to deteriorate, the high novel sense of rapidity high stable that holding time length, photosensitive property are good
The preparation method of optical cement.
Technology and method in order to solve the employing of the above-mentioned problem present invention are as follows:
The preparation method of a kind of high rapidity high stable novel photoactive glue, it is characterised in that comprise the following steps:
1) fully dissolve the polyvinyl alcohol of 40g alkalization with 300ml water, obtain the polyvinyl alcohol that mass concentration is 0.114g/ml
Solution；
2) in the solution of step (1) gained, 12g polyvinyl acetate emulsion, 20gSBQ photo-hardening tree are the most accurately added
Fat, 5g acrylamide, 3g ethyl methacrylate, 0.8g dibutyl ester, 0.4g ethylenediamine, 1.8g light trigger 0.3g polyacrylamide
Amine emulsifier, 0.2g polymerization inhibitor, 0.5g emulsified silicone oil defoamer and 0.8g stain；
3) by the solution of gained 85 DEG C reaction 3h in step (2), period is stirred continuously, forms finely dispersed emulsion body
System；
4) solution of gained in step (3) being down to room temperature, after standing 24h froth breaking, sealing is kept in Dark Place.
The invention have the benefit that and use 3-methoxy diphenylamine-4-diazol with traditional hexichol amine salt 1:1 mixing
Using, make latex solid content, viscosity be obtained for bigger lifting, latex solid content reaches
30-43%, viscosity has reached 2000-7000mpa.s, and pH value is at 4.5-6.5, and time of exposure also controls at 0.2-
5.5min, resolution has reached below 0.09mm, and meanwhile, resolution and resistance to water have also been obtained raising, and pattern edge is apparent,
And can be under giant impacts, the 5-30 second does not falls off.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, but they are not to technical solution of the present invention
Restriction, based on present invention teach that any conversion made, all fall within protection scope of the present invention.
The preparation method of a kind of high rapidity high stable novel photoactive glue, it is characterised in that comprise the following steps:
1) fully dissolve the polyvinyl alcohol of 40g alkalization with 300ml water, obtain the polyvinyl alcohol that mass concentration is 0.114g/ml
Solution；
2) in the solution of step (1) gained, 12g polyvinyl acetate emulsion, 20gSBQ photo-hardening tree are the most accurately added
Fat, 5g acrylamide, 3g ethyl methacrylate, 0.8g dibutyl ester, 0.4g ethylenediamine, 1.8g light trigger 0.3g polyacrylamide
Amine emulsifier, 0.2g polymerization inhibitor, 0.5g emulsified silicone oil defoamer and 0.8g stain；
3) by the solution of gained 85 DEG C reaction 3h in step (2), period is stirred continuously, forms finely dispersed emulsion body
System；
4) solution of gained in step (3) being down to room temperature, after standing 24h froth breaking, sealing is kept in Dark Place.
Experimental example
High rapidity high stable novel photoactive glue obtained by the present invention is carried out parameter testing, obtains parameter such as following table:
The invention have the benefit that and use 3-methoxy diphenylamine-4-diazol with traditional hexichol amine salt 1:1 mixing
Using, make latex solid content, viscosity be obtained for bigger lifting, latex solid content has reached 30-43%, and viscosity reaches
2000-7000, pH value is at 4.5-6.5, and time of exposure also controls at 0.2-5.5s, and resolution has reached below 0.09mm, meanwhile,
Resolution and resistance to water have also been obtained raising, and pattern edge is apparent, and can be under giant impacts, and the 5-30 second does not takes off
Fall.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, and any
The change expected without creative work or replacement, all should contain within protection scope of the present invention, therefore, and the present invention's
Protection domain should be as the criterion with the protection domain that claims are limited.
Claims (1)
1. the preparation method of one kind high rapidity high stable novel photoactive glue, it is characterised in that comprise the following steps:
1) fully dissolve the polyvinyl alcohol of 40g alkalization with 300ml water, obtain the poly-vinyl alcohol solution that mass concentration is 0.114g/ml；
2) in the solution of step (1) gained, 12g polyvinyl acetate emulsion, 20gSBQ light-hardening resin, 5g are the most accurately added
Acrylamide, 3g ethyl methacrylate, 0.8g dibutyl ester, 0.4g ethylenediamine, 1.8g light trigger 0.3g polyacrylamide breast
Agent, 0.2g polymerization inhibitor, 0.5g emulsified silicone oil defoamer and 0.8g stain；
3) by the solution of gained 85 DEG C reaction 3h in step (2), period is stirred continuously, forms finely dispersed emulsion system；
4) solution of gained in step (3) being down to room temperature, after standing 24h froth breaking, sealing is kept in Dark Place.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610715402.9A CN106094434A (en) | 2016-08-23 | 2016-08-23 | A kind of preparation method of high rapidity high stable novel photoactive glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610715402.9A CN106094434A (en) | 2016-08-23 | 2016-08-23 | A kind of preparation method of high rapidity high stable novel photoactive glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106094434A true CN106094434A (en) | 2016-11-09 |
Family
ID=57224938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610715402.9A Pending CN106094434A (en) | 2016-08-23 | 2016-08-23 | A kind of preparation method of high rapidity high stable novel photoactive glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106094434A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106502050A (en) * | 2016-11-25 | 2017-03-15 | 江苏环宇纺织科技有限公司 | A kind of preparation method of Novel fireproof photoresists |
| CN106527048A (en) * | 2016-11-25 | 2017-03-22 | 江苏环宇纺织科技有限公司 | Preparation method of photo-sensitive resist with high water resistance and easy flame retardance |
| CN106543784A (en) * | 2016-11-25 | 2017-03-29 | 江苏环宇纺织科技有限公司 | A kind of preparation method of the high surely Waterproof gum of high rapidity |
Citations (5)
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|---|---|---|---|---|
| CN1667508A (en) * | 2005-03-29 | 2005-09-14 | 上海中大科技发展有限公司 | Aqueous emulsion type cylinder photoresist |
| CN101957558A (en) * | 2010-10-20 | 2011-01-26 | 武强县武环印刷材料有限公司 | Screen printing photosensitive emulsion and production method thereof |
| CN103760750A (en) * | 2013-12-13 | 2014-04-30 | 浙江荣生科技有限公司 | Preparation method and application method of light-cured silk-screen printing photosensitive glue |
| CN104849961A (en) * | 2015-05-11 | 2015-08-19 | 黄云景 | High efficient environment friendly flat screen blu-ray plate-making material |
| CN105068379A (en) * | 2015-08-21 | 2015-11-18 | 田菱新材料（厦门）有限公司 | Photosensitive resin component for silk-screen printing |
-
2016
- 2016-08-23 CN CN201610715402.9A patent/CN106094434A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1667508A (en) * | 2005-03-29 | 2005-09-14 | 上海中大科技发展有限公司 | Aqueous emulsion type cylinder photoresist |
| CN101957558A (en) * | 2010-10-20 | 2011-01-26 | 武强县武环印刷材料有限公司 | Screen printing photosensitive emulsion and production method thereof |
| CN103760750A (en) * | 2013-12-13 | 2014-04-30 | 浙江荣生科技有限公司 | Preparation method and application method of light-cured silk-screen printing photosensitive glue |
| CN104849961A (en) * | 2015-05-11 | 2015-08-19 | 黄云景 | High efficient environment friendly flat screen blu-ray plate-making material |
| CN105068379A (en) * | 2015-08-21 | 2015-11-18 | 田菱新材料（厦门）有限公司 | Photosensitive resin component for silk-screen printing |
Non-Patent Citations (1)
| Title |
|---|
| 胡平藩 等: "《筛网印花》", 31 January 2005, 中国纺织出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106502050A (en) * | 2016-11-25 | 2017-03-15 | 江苏环宇纺织科技有限公司 | A kind of preparation method of Novel fireproof photoresists |
| CN106527048A (en) * | 2016-11-25 | 2017-03-22 | 江苏环宇纺织科技有限公司 | Preparation method of photo-sensitive resist with high water resistance and easy flame retardance |
| CN106543784A (en) * | 2016-11-25 | 2017-03-29 | 江苏环宇纺织科技有限公司 | A kind of preparation method of the high surely Waterproof gum of high rapidity |
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Application publication date: 20161109 |
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