TW415886B - Naturally decomposable disposable dining ware and process for making the same and its process method - Google Patents
Naturally decomposable disposable dining ware and process for making the same and its process method Download PDFInfo
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415886 五、發明說明(丨) - 【發明之應用範圍】 _ 本發明係有關一種可自然分解之免洗餐具及其製程, 特別是一種以天然之有機質材為原料所製成,無毒性、具— 環保功效,可以解決傳統免洗餐具之高污染,或是危反環. 保目標的餐具。 【發明之相關技術】 利用天然質材製作飲食用之免洗餐具(如碗、盤), 以期達到環保之目標的技術開發,在產業界以及科技界已 然進行多年,其中某些技術亦早已為人所熟知且公開,例 如:中華民國專利申請第七四一〇三八二六號的「簡便衛 生餐具及其製造方法j (以下簡稱八二六號案),申請第 八二一〇四〇—九號的「環保餐盤之製造方法」(以下簡 稱0 —九號案),以及美國專利第5 5〇0 0 8 9號之 「免洗餐盤及碗的製造方法(Method for making disposable bowls and trays)」等專利中請案中均有揭 露相關之技術。 八二六號案所揭露的技術,係以五縠與自然之植物澱 物質(或是樹薯之粉狀物)為原料,以水調合,先蒸處一 段時間,待冷卻至某一溫度之後,再置入模具之内施以高 壓然後成型為餐具;這種餐具所用之原料雖然均以天然原 料為主,但於製成器物的過程中需經高溫高壓之製程(如 蒸處)始可成型,其所需之加工條件較嚴,而所含的植物 澱物質或樹薯(澱粉)成分,將會使得所製成餐具在耐濕 能力上顯然不佳,尤其是澱粉極易因為受潮而發霉變壞,415886 V. Description of the invention (丨)-[Scope of application of the invention] _ This invention relates to a kind of disposable tableware that can be decomposed naturally and its manufacturing process, especially a kind of natural organic material. — Environmental protection, can solve the high pollution of traditional disposable dishware, or the risk of anti-ring. [Related technology] The use of natural materials to make disposable tableware (such as bowls and plates) for food and beverages, in order to achieve the goal of environmental protection, has been developed for many years in the industry and science and technology, some of which have already been It is well known and published, for example, the Republic of China Patent Application No. 710402826, “Simple Sanitary Tableware and Manufacturing Method j (hereinafter referred to as Case No. 826), Application No. 821040 — No. 9 "Method for manufacturing environmentally-friendly dinner plates" (hereinafter referred to as the "No. 9" case), and "Method for making disposable for disposable plates and bowls" (U.S. Patent No. 5,500,089) related patents are disclosed in patent applications such as "bowls and trays". The technology disclosed in the case No. 826 is based on the materials of Wuzhi and nature (or cassava powder) as raw materials, blended with water, steamed for a period of time, and then cooled to a certain temperature , Then put it into the mold and apply high pressure and then shape it into tableware; although the raw materials used for this tableware are mainly natural materials, the high temperature and high pressure process (such as steaming) can be used in the process of making utensils. For molding, the processing conditions required are relatively strict, and the contained plant sediment or cassava (starch) ingredients will make the cutlery made obviously poor in moisture resistance, especially the starch is easily susceptible to moisture. Moldy and bad,
415886 五、發明說明(2) 而這些現象對於安全標準要求極高的飲食器具而言,無異 是一項致命的缺陷。 0 —九號案以及美國專利第5 5 0 0 0 8 9號專利之· 中所揭露的技術,其中所使用之材料係以一種具明顯條狀 分束纖維之天然植物中的有機性纖維載斷成短纖維,暨作 打散處理,再與作為黏著劑之澱粉,經充分之攪拌然後糊 化成一膠稠狀的混合物,利用極細網目之透氣性模具作壓 乾、脫水之處理後,再經以加溫、加壓之模具定型化處理 ,成為碗盤等餐具,最後經過乾燥、凝固等處理始可完成 ;所以其在製程方面顯然又遠較上述之八二六號案複雜, 又因為使用澱粉為黏著劑,故仍存在著不耐水,易受潮' 甚至於發霉等諸多問題,至於其採用天然之短纖維為基材 ,不但材料的取得步驟繁雜,短纖維所形成的組織,更將 使得製品之質地多孔而疏鬆,其在防漏防水之能力上勢必 受到考驗。 另一方面,以上二件已知之技術在製作的過程中,必 需使用要到大量的水,相對的將會造成許多的廢水,對於 環保將是一項威脅,而污水的處理又將造成生產成本的提 【發明之概述及目的】 本發明之主要目的係在提供一種可以自然分解,甚至 還可以充作肥料或飼料的環保免洗餐具。由於本發明所揭 露之免洗餐具係以取材自然穀類外皮的有機原料 '配合無 毒性又可自然分解之黏著劑暨填充劑等原料所製成,因此415886 V. Description of the invention (2) These phenomena are a fatal flaw for food and beverage appliances that require high safety standards. The technology disclosed in No. 0-9 and U.S. Patent No. 5 50 0 0 9 · The materials used are organic fibers contained in a natural plant with apparently striped fiber Broken into short fibers, and pulverized, and then mixed with starch as an adhesive, and then gelatinized into a gelatinous mixture. After using a fine mesh breathable mold for pressure drying and dehydration, After being shaped by a mold that is heated and pressurized, it can be made into dishes such as dishes and plates, and finally can be completed after drying and solidification. Therefore, its process is obviously more complicated than the aforementioned case No. 826, and because Using starch as an adhesive, there are still many problems such as resistance to water, moisture, and even mildew. As for the use of natural short fibers as the base material, not only the steps for obtaining the materials are complicated, but the structure formed by the short fibers will be more difficult. Making the texture of the product porous and loose, its ability to prevent leakage and water resistance is bound to be tested. On the other hand, in the production process of the above two known technologies, a large amount of water must be used. Relatively, it will cause a lot of waste water, which will be a threat to environmental protection, and the treatment of sewage will cause production costs. [Summary and purpose of the invention] The main purpose of the present invention is to provide an environmentally friendly disposable tableware that can be naturally decomposed and can even be used as fertilizer or feed. Since the disposable tableware disclosed in the present invention is made of organic raw materials made of natural cereal crusts, combined with raw materials such as non-toxic and naturally decomposable adhesives and fillers,
415886 五、發明說明(3) 可以在自然的環境中分解,甚至再作為肥料或是飼料,暨 具有器物之效用,又可以在丟棄之後被分解或是再利用為— 肥料、或飼料等用途,實為一種暨環保又具有極高之利用 價值的免洗餐具。 .. 本發明的次一目的,係在提供一種製造容易、原料價 格低廉、原料取得容易暨符合環保要求的免洗餐具製造技· 術。 根據本發明所揭露,用以製成可自然分解之免洗餐具 的製程,主要係將由穀類外皮所製成的粉末狀基材、填充 劑(碳_酸妈;C a 1 c i u m C a r b ο n a t e ) '以及黏著劑(聚乙 稀醇;P V A,P ο 1 y v i n y I A 1 c c o h ο 1 ),依恰當之比例混合 均勻,再以水為媒介調和,致使粉末狀基材與填充劑藉著 黏著劑之鍵結作用黏結成一種具可塑性之混合物,再將此 混合物壓延成月狀之複合材料,經真空成型為餐具後,再 施以精簡的乾燥以及防水處理,便可製成一種質地細緻, 且具環保功效的免洗餐具。 本發明所使用的主要原料係為縠類之外皮,由於穀類 之產量極高,經取出縠粒之後的穀類外皮相對的亦具有極 大之數量,一般而言均視同廢料處理,縱使另有用途,則 其價格亦非常低廉,原料的取得亦不困難;反觀一般所謂 的環保餐具,大部份均是以木材或是紙質為其主要原料, 由於木材之取得不易,亦需砍閥林木方可取得,故其成本 較高,反而不及本發明之經濟,而為了取得材料所造成的 樹木砍閥,對於自然資料源日益珍貴且逐漸少的現今環境415886 V. Description of the invention (3) It can be decomposed in the natural environment, and even be used as fertilizer or feed, and it has the function of utensils, and can be decomposed or reused after being discarded for-fertilizer, or feed, etc. It is a kind of disposable tableware that is environmentally friendly and has a very high utilization value. .. The second object of the present invention is to provide a disposable tableware manufacturing technique that is easy to manufacture, has low raw material prices, easy raw material acquisition, and meets environmental protection requirements. According to the disclosure, the process for making naturally decomposable disposable tableware is mainly a powdery substrate made of cereal rind and a filler (Carbon acid); C a 1 cium C arb ο nate ) 'And adhesives (polyvinyl alcohol; PVA, P ο 1 yviny IA 1 ccoh ο 1), mixed uniformly according to the appropriate ratio, and then blended with water as a medium, so that the powdery substrate and the filler through the adhesive The bonding effect binds into a plastic mixture, and then the mixture is rolled into a moon-shaped composite material. After vacuum forming into tableware, and then applying a simple drying and waterproof treatment, a fine texture can be made, and Environmentally friendly disposable tableware. The main raw material used in the present invention is coriander rind. Due to the extremely high yield of cereals, the relative amount of cereal rind after taking out coriander grains is also relatively large. Generally speaking, it is treated as waste, even if it is used for other purposes. , Its price is also very low, and the acquisition of raw materials is not difficult; on the other hand, most of the so-called environmentally friendly tableware are mostly made of wood or paper as the main raw material. Due to the difficulty in obtaining wood, it is also necessary to cut the valve forest Obtained, so its cost is high, but it is not as economic as the present invention, and the tree cutting valve caused by the acquisition of materials is increasingly precious and natural resources of today's environment
第6頁 415886__ 五、發明說明(4) 而言,傳統以木材料為主要之環保材料顯然較不經濟,除 了間接影響生態的發展,甚至於還會造成水土保持的重大^ 問題。' - 本發明的又一目的在提供一種質地細緻的環保免洗餐. 具,由於本發明係採用粉末狀之穀類外皮,再以粉狀碳酸 妈(CaC03 ; Calcium Carbonate)為填充劑,用以填實餐 具組織的縫隙,因此可以得到一種質地不若纖維組織般疏 鬆的優質環保免洗餐具。 本發明所揭露之免洗餐具,在產製的過程中,僅會用 到少量的水,而這些水又將全數用於調製成具微黏性的複 合材料,所以在產製的過程中將不會產生大量的廢水,對 環保以及降低成本而言,均有極大的助益。 【圖式說明】 第1圖,依為本發明之餐具的構造斷面圖。 第2圖,係為本發明之製作流程圖3 第3圖,係為本發明之餐具的第一種實施例成品外觀圖。 第4圖,係為本發明之餐具的第二種實施例成品外觀圖。 【實施例詳細說明】 請參閱「第1圖」,本發明所揭露之環保餐具1〇, 自其斷面之構造組成而言,包括有: 一複合材料層2 0 1用以構成餐具1 0的實體;以及 一防水層3 0 ,係覆蓋於於餐具1 0用以盛裝食物且 與食物接觸的接觸面1 0 1上,用以保護複合材料層2 0 不受食物中之水份或是其他成分浸潰而分解;但另一方面Page 6 415886__ V. Description of the invention (4) In terms of traditional environmental protection materials mainly using wood materials, it is obviously less economical. In addition to indirectly affecting ecological development, it may even cause major problems of soil and water conservation ^. '-Another object of the present invention is to provide a fine-texture, environmentally friendly disposable meal. Because the present invention uses a powdery cereal rind, and then uses powdered carbonate (CaC03; Calcium Carbonate) as a filler for Fill the gaps in the tableware structure, so you can get a high-quality environmentally friendly disposable tableware that is not as loose as the fiber structure. In the production process of disposable washware disclosed in the present invention, only a small amount of water is used, and all of this water is used to prepare a slightly viscous composite material. Therefore, during the production process, Does not produce a large amount of wastewater, which is of great help to environmental protection and cost reduction. [Explanation of drawings] FIG. 1 is a sectional view of the structure of a tableware according to the present invention. FIG. 2 is a production flow chart 3 of the present invention. FIG. 3 is a finished product appearance view of the first embodiment of the tableware of the present invention. FIG. 4 is a finished product appearance view of the second embodiment of the tableware of the present invention. [Detailed description of the embodiment] Please refer to "Fig. 1". The environmental protection tableware 10 disclosed in the present invention, as far as its cross-sectional structural composition is concerned, includes: a composite material layer 2 0 1 for forming the tableware 10 And a waterproof layer 3 0 covering the contact surface 1 0 1 of the tableware 10 for containing food and in contact with the food, for protecting the composite material layer 20 from moisture or food in the food Other ingredients impregnate and decompose; but on the other hand
415886 五、發明說明(5) ,為了使得以天然物質所組成的複合材料層2 0可以在丟 棄後自然分解,所以在餐具1 0未接觸食物之其餘表面, 則不施以防水層3 0 ;為達前述目的,在選擇防水層的材: 料時,以不與食物中之水份(H2 0 )或其它成份,如澱粉、. 脂肪等反應的物質為原則,另外由於此防水劑係直接與食 物接觸,故防水劑的分解性與毒性也是考慮因素之一,綜 合前述,能適用的防水劑材料係為環氧樹脂(Ε ρ ο X y R e s 1 n s )或是乙烯類之水性防水劑,前述乙烯類之水性防 水劑所指的是具有乙埽基(Ή n y 1 ,( C H2 = C Η - ) η),且可當作 防水劑的化合物,其中環氧樹脂的物化性已廣為人知,其 不具分解性與毒性,而其中一種所使用的乙烯類防水劑為 變性乙蹄樹脂,其經由美國食物藥品管理局(F ο 〇 d a n d Drug Administration,FDA)證明不具有分解性與毒性。 上述的複合材料層1 0 ,其基本的組成物質包括: a. 由榖類外皮所製成的粉末狀基材,其組成重量百分 比為5 0 % ± 3 % (亦即為4 7 %〜5 3 % ); b. 填充劑,用以填補複合材料層1 0之缝隙,其組成 重量百分比為2 8 % 士 3 % (亦即為2 5 %〜3 1 % );以及 c. 黏著劑,用以將基材以及填充劑藉鍵結作用而黏結 在一起,其組成重量百分比為2 21¾ 土 3 % (亦即為1 9 % - 2 5 % )。 其中的粉末狀基材,係取自於縠類(如稻、麥)之穀 實取出後的外皮,經研磨設備將此外皮研磨成粉末狀,再 經細目網篩選而成,其間無需施行淨化步驟,原則上此一 粉末狀基材以可通過5 0篩目者佔7 0 % ’可通過6 0 ~ 1 0 0篩目415886 V. Description of the invention (5), in order to make the composite material layer 20 composed of natural substances decompose naturally after being discarded, so the waterproof layer 3 0 is not applied when the tableware 10 does not contact the rest of the food; In order to achieve the foregoing purpose, when selecting the material of the waterproof layer: the material should not react with the water (H2 0) or other ingredients in the food, such as starch, fat, etc. In addition, because this waterproof agent is directly In contact with food, the decomposability and toxicity of the waterproofing agent is also one of the considerations. Based on the foregoing, the applicable waterproofing agent is epoxy resin (E ρ ο X y R es 1 ns) or vinyl water-based waterproofing. The above-mentioned ethylene-based water-based waterproofing agent refers to a compound having an ethyl fluorenyl group (Ή ny 1, (C H2 = C Η-) η), and can be used as a waterproofing agent, in which the physical and chemical properties of the epoxy resin have been It is widely known that it is non-decomposable and toxic, and one of the vinyl-based waterproofing agents used is denatured ethyl hoof resin, which has been certified by the US Food and Drug Administration (FDA and Drug Administration, FDA) to have no degradability and toxicity. Sex. The basic composition material of the above composite material layer 10 includes: a. A powdery base material made of a sloppy outer skin, whose composition weight percentage is 50% ± 3% (that is, 47% to 5%). 3%); b. Fillers to fill the gaps in the composite material layer 10, the composition weight percentage of which is 28% ± 3% (that is, 25% ~ 31%); and c. Adhesives, It is used to bond the substrate and the filler together by bonding, and its composition weight percentage is 2 21¾ soil 3% (that is, 19%-25%). The powdery substrate is obtained from the outer skin of the tadpoles (such as rice and wheat). The outer skin is ground into a powder by a grinding device, and then screened by a fine mesh screen. No purification is required. Steps: In principle, this powdery substrate takes 70% of those who can pass 50 meshes. 'It can pass 60 to 100 meshes.
第8頁 415886 五、發明說明(6) 者佔3 0 % ; 填充劑,係為碳酸釣(C a C 0 3 ; C a 1 c〖u m C a r b 〇 ri a t e ),用以填實複合材料的缝隙,以增加複合材料之密實-性,其中碳酸鈣係為粉末狀,且以可通過1 〇 〇篩目者佔 9 9% ; 黏著劑,係為聚乙豨醇(P V A ; Ρ ο 1 y v i n y 1 A 1 c 〇 h ο 1 ),可透過水作為潤滑劑,使得由這三種基本組成物質混 合而成的混合體,藉由鍵結之作用形成一種微具黏性的複 合材料,以便於進行成型加工而製成器物,而聚乙烯醇 (P V A )之特性請參考「表一」,其中聚乙烯醇係為高分 子,依照分子量的不同,黏度、溶解度等物化性也會隨之 不同,在本發明中所能適用之聚乙烯醇種類如「表二」所 示,且其對水的溶解度如「表三」所示,原則上以高黏度 聚乙烯醇C如B P - 2 4 )的效果較佳。 請參閱「第2圖」,本發明所揭露之環保餐具的製程 ,包括有: (1 )提供一具有微黏性的複合材料; (2 )將複合材料壓延成厚度約為0 · 8麵〜1 · 3 ram 的片狀複合材料; (3 )以成型加工法(如負壓成型),將片狀複合材料 成型為餐具初, (4)將餐具初枉乾燥定型;以及 (5 )形成一防水層於餐具1 0與食物接觸的接觸表面Page 8 415886 V. Description of the invention (6) accounted for 30%; the filler is carbonated fishing (C a C 0 3; C a 1 c 〖um C arb 〇ri ate), used to fill the composite material To increase the compactness of the composite material, in which the calcium carbonate is powdery and accounts for 99% of those who can pass through the 100 mesh; the adhesive is polyvinylacetate (PVA; ρ ο 1 yviny 1 A 1 c 〇h ο 1), can be permeated with water as a lubricant, so that a mixture of these three basic constituents is mixed to form a slightly viscous composite material by bonding, in order to facilitate Molding and processing to make utensils. For the characteristics of polyvinyl alcohol (PVA), please refer to "Table 1". Among them, polyvinyl alcohol is a polymer. Depending on the molecular weight, the physical properties such as viscosity and solubility will also vary. The types of polyvinyl alcohol that can be used in the present invention are shown in "Table 2", and its solubility in water is shown in "Table 3". In principle, high-viscosity polyvinyl alcohol C such as BP-2 4) The effect is better. Please refer to "Fig. 2". The manufacturing process of environmentally friendly tableware disclosed in the present invention includes: (1) providing a composite material with micro-adhesion; (2) calendering the composite material to a thickness of about 0. 8 faces ~ 1 · 3 ram sheet-like composite material; (3) forming the sheet-like composite material into a tableware using a molding process (such as negative pressure molding), (4) drying and shaping the tableware initially; and (5) forming a Waterproof layer on the food contact surface of tableware 10
五、發明說明(7) - 其中步驟(1 )係包括有下列步驟: . (1 - 1 )將取出縠實之榖類外皮研磨成可通過1 0 0篩目與 可通過60〜100篩目兩種的粉末,再將前述兩種粉 末依適當比例(其中可通過1 0 0篩目者佔了 0 %,. 6 0〜1 0 0篩目者佔3 0 % )混合成粉末狀基材; (1 - 2 )將粉末狀基材、填充劑以及黏著劑三者依組成 比例混合攪拌成均勻之混合物,而這三者彼此之 間的重量比大約為5 : 2. 8 : 2 . 2之關係1其中任 一種組成物質之容許變動量約為土 3 % ;以及 (1 - 3 )以重量比大約為1 : 2 · 5之關係,將水以及步驟 2所完成的混合物混合在一起(而此二者之容許變 動量約為± 5 % ),並且攪拌成複合材料,其中由於 填充劑(聚乙烯醇)於常溫下在水中只吸收膨潤,而 不溶解,致使所形成的複合材料具有微黏性。 而在步驟(3 )的成型方法,係將含有少許水分呈可塑 性的片狀複合材料,利用預設有餐具之形狀的抽引模具, 直接於模具之上抽引成餐具1 0之初坯;當然在餐具1 0 的初坯完成之初,若是具有不必要的毛邊亦可趁此初坯仍 具有可塑性之時,予以修整裁切較為容易。 步驟(4 )之乾燥步驟,則可以在柚引模具維持於負壓 柚引的條件下,利用不超過2 0 0 °C之熱風予以烘乾至定型 ,所需時間則視成型之餐具1 0的實際含水量,以及熱風 之溫度而定。 上述的步驟(5 )又包含有下列步驟:V. Description of the invention (7)-The step (1) includes the following steps: (1-1) Grinding the removed rind-like outer skin to pass through a 100 mesh and 60-100 mesh Two kinds of powders, and then the two kinds of powders are mixed into a powdery base material according to an appropriate ratio (of which 100% can pass through 0 mesh, and 0. 60 to 100% pass through 30%). ; (1-2) The powdery substrate, filler and adhesive are mixed and mixed into a homogeneous mixture according to the composition ratio, and the weight ratio between the three is approximately 5: 2.8: 2.2. The allowable variation of any of the constituents in relation 1 is approximately 3%; and (1-3) in a relation of approximately 1: 2 · 5 by weight, the water and the mixture completed in step 2 are mixed together ( The allowable variation of the two is about ± 5%), and they are stirred into a composite material. The filler (polyvinyl alcohol) only absorbs swelling in water at normal temperature, but does not dissolve, which results in the formed composite material having Slightly sticky. In the forming method in step (3), a sheet-like composite material containing a small amount of moisture and being plastic is drawn directly above the mold into a preliminary blank of tableware 10 by using a drawing mold preset with a shape of tableware; Of course, at the beginning of the preliminary blank of the tableware 10, if it has unnecessary burrs, while the preliminary blank is still plastic, it is easier to trim and cut. In the drying step of step (4), the grapefruit mold can be dried under the condition that the grapefruit mold is maintained at a negative pressure by using hot air at a temperature not exceeding 200 ° C to set the shape. The time required depends on the shape of the tableware. Depends on the actual water content and the temperature of the hot air. The above step (5) includes the following steps:
第10頁 415886 五、發明說明(8) (5-1)塗佈(Coating)如環氡樹脂(epoxy resins)或 是乙烯類之水性防水劑於餐具1 0與食物接觸的接觸表面 ,在此因防水層不具分解性,為避免當餐具除防水層之外_: 其餘部份皆自然分解後,殘留太多的防水層,故將防水層_ 的塗層厚度減到最低,為6〜1 0 m,一般而言,為了便於 塗佈,防水劑内都會添加溶劑(S 〇丨v e n t ),以增加其流動 性,其中溶劑所選用的種類、及添加量都與防水劑種類有 關,這些資訊在使用者購買防水劑的同時廠商都會提供, 通常使用者所購買到的防水劑,已添加有溶劑,以便利使 用者無需調配,即可直接使用;以及 (5 - 2 )烘乾去除防水劑内含的溶劑,致使防水劑可以 固定於餐具1 0的表面,其中前述烘乾條件與所選用的溶 劑種類有關,前述烘乾條件在防水劑的使用說明上都會有 所標示,舉例言之,本發明向得利塗料(D u 1 u X P a i n t s )公 司購買變性乙烯樹脂當作防水劑,其所提供的溶劑為 F 8 5 0 - 5 9 4 5 3 (此為產品代號),烘乾條件為T (溫度)=1 9 3 °C ,t (時間)=3 . 5分鐘。 當然在製成餐具1 0之後,應當再施予一般的殺菌處 理(如紫外線殺菌),以確保餐具的衛生安全。 最後請參「第3 ,4圖」,係為根據本發明所揭露之 製程所完成之免洗餐具1 0的實施例外觀圖,由於本發明 係利用生產快速的負壓成型技術及片狀的可塑性複合材料 ,較適用於餐盤1 0 a或是免洗便當盒1 0 b這類深度較淺 之容器或是承物餐具的製作,配合這類餐具1 0之深度較Page 10 415886 V. Description of the invention (8) (5-1) Coating (such as epoxy resins) or vinyl-based water-repellent water-repellent agent on the contact surface of tableware 10 with food, here Because the waterproof layer is not decomposable, in order to avoid that when the rest of the tableware except the waterproof layer is decomposed naturally, too much waterproof layer remains, so the coating thickness of the waterproof layer _ is minimized to be 6 ~ 1 0 m, in general, in order to facilitate coating, a solvent (S 〇 丨 vent) is added to the water-repellent agent to increase its fluidity. The type of solvent used and the amount of the solvent are related to the type of water-repellent agent. These information When the user purchases the waterproofing agent, the manufacturer will provide it. Usually, the waterproofing agent purchased by the user has been added with a solvent to facilitate the user to use it without preparation; and (5-2) drying and removing the waterproofing agent. The contained solvent makes the waterproofing agent can be fixed on the surface of the tableware 10. The aforementioned drying conditions are related to the type of solvent used. The aforementioned drying conditions will be marked on the instructions of the waterproofing agent, for example. The present invention purchases a denatured vinyl resin as a waterproofing agent from Dui Xu XP aints, and the solvent provided is F 8 50-5 9 4 5 3 (this is the product code), and the drying conditions For T (temperature) = 193 ° C, t (time) = 3.5 minutes. Of course, after making the tableware 10, general sterilization treatment (such as ultraviolet sterilization) should be applied to ensure the hygiene and safety of the tableware. Finally, please refer to "Figures 3 and 4", which are external appearance drawings of the disposable tableware 10 according to the process disclosed by the present invention. Since the present invention uses rapid negative pressure forming technology and sheet-like Plastic composite material, which is more suitable for the production of shallow-deep containers such as dinner plates 10 a or disposable lunch boxes 10 b
415886 五、發明說明¢9) . 淺,配合片狀複合材料未予以乾燥時的極佳可塑性,故極 易藉由負壓成型之技術製成。 ^ 因為餐具1 0在使用的過程中,難免與水接觸,此時: 可藉著防水層而維持數小時之使用能力而不會分解,使用. 完畢若是當作垃圾丟棄,因餐具未與食物接觸之其餘表面 未施以防水層,可接觸空氣中的水份,受潮而軟化、分解 ,待最外層軟化分解後,曝露出内層表面,再進行相同地 分解過程,如此一層層地分解,最後只剩下一層薄防水層 ,在此因防水層不具毒性及分解性,不會對環境造成影響 ,依上述分解步驟,餐具將可於短期内自然分解,並具備 肥料之價值,若是流入河川或是湖泊之中,則以天然有機 物為主要成分所構成的主體,仍可以為魚類所食用,而不 會造成任何污染,顯然是暨環保又具實用性。 當然、以上的實施例係用以揭示本發明之技術内容, 並非用以限定本發明之範圍,惟熟習此項技藝人士在瞭解 本發明之技術内容之後,在不脫本發明之技術特徵下的任 何變化,均應由後述之申請專利範圍所限定= 【發明之功效】 1 .具環保之功效,於丟棄之後亦不會造成污染;本發明 所揭露之免洗餐具,係為取自於天然以及無毒性之原 料所製成的一種環保餐具,使用完畢若是當作垃圾丟 棄,將可於短期内自然分解,並具備肥料之價值,若 是流入河川或是湖泊之中,則以天然有機物為主要成 分所構成的主體,仍可以為魚類所食用,而不會造成415886 V. Description of the invention ¢ 9). Shallow, excellent plasticity when the sheet-like composite material is not dried, so it can be easily made by negative pressure forming technology. ^ Because the tableware 10 will inevitably come into contact with water during use, at this time: it can be used for several hours by the waterproof layer without being decomposed and used. If finished, it is discarded as garbage because the tableware is not in contact with food The rest of the contact surface is not provided with a waterproof layer. It can contact the moisture in the air and soften and decompose when damped. After the outermost layer is softened and decomposed, the inner surface is exposed, and the same decomposition process is performed. There is only one thin waterproof layer left here, because the waterproof layer is not toxic and decomposable, and will not affect the environment. According to the above decomposition steps, the tableware will naturally decompose in a short period of time and have the value of fertilizer. In the lake, the main body composed of natural organic matter can still be eaten by fish without causing any pollution, which is obviously environmentally friendly and practical. Of course, the above embodiments are intended to disclose the technical content of the present invention and are not intended to limit the scope of the present invention. However, those skilled in the art will understand the technical content of the present invention without departing from the technical features of the present invention. Any change should be limited by the scope of the patent application mentioned below = [effect of the invention] 1. Environmental protection effect, it will not cause pollution after being discarded; the disposable tableware disclosed in the present invention is taken from natural And an environmentally-friendly tableware made of non-toxic raw materials. If it is discarded as garbage after use, it can be naturally decomposed in a short period of time, and it has the value of fertilizer. The main body of ingredients can still be eaten by fish without causing
第12頁 415886 五、發明說明(ίο) 任何污染。 2 ·原料容易取得,且低成本;用以生成本發明所揭露之 環保餐具的原料,主要係以取材自穀類外皮之基材為— 主,而在縠類產量極大的助力之下,穀類外皮的取得. 並不困難,其原本便已視如廢料,除了充作飼料之外 並無其他明顯的利用價值,故在取得的成本上顯然要 較廣為使用的另一種環保原料(木材)更為低廉。 【圖示之符號說明】 10.......餐具 l〇a.......免洗餐盤 10b.......免洗便當盒 10 1......接觸面 2 0.......複合材料層 3 0.......防水層Page 12 415886 V. Description of the Invention (ίο) Any pollution. 2 · The raw materials are easy to obtain and low cost; the raw materials used to generate the environmentally-friendly tableware disclosed in the present invention are mainly based on the base material derived from the grain outer skin. It is not difficult to obtain. It is already regarded as waste material. There is no other obvious use value other than as feed. Therefore, the cost of obtaining is obviously more than another widely used environmentally friendly raw material (wood). For cheap. [Illustrated Symbols] 10 ....... Tableware 10a ....... Disposable Dinner Plate 10b ....... Disposable Lunch Box 10 1 ...... Contact surface 2 0 ....... composite material layer 3 0 ....... waterproof layer
第13頁 415886 五、發明說明(11) CCP PVA的一般特性 項 目 說 明 外觀 白色至淡黃色顆粒或粉末。 熱安定性 I真比重1. 26〜1. 31,克填比重0. 6〜0. 7: 以ί C 2 。 二 2 -ο,解 6 1色分 至變全 熱速完 加迅則 間上上 時以以 長c C 「 ο α 黃 變 漸 逐 上Page 13 415886 V. Description of the invention (11) General characteristics of CCP PVA Item Description Appearance White to light yellow particles or powder. 7 : 以 ί C 2。 Thermal stability I true specific gravity 1. 26 ~ 1. 31, grams filled specific gravity 0. 6 ~ 0. 7: ί C 2。 Two 2 -ο, solution 6 1 color separation to change to full heat, speed up, and time up, with a long time c C "ο α yellow change gradually one by one
始 開 右 左 V 過至 超’ ’解 分 2 而十藥品性、 耐溶劑性 植双之 、高料 ' 動巧材 對、劑 ,酯溶 鹹、抗 弱物的 酸合佳 弱化最 对氯 -^ 油 石 ' 匕曰 月 油 性 物 性 定 安 度 高 具 等 享 丨吸濕性 !比其他水溶性高分子吸濕性低,受濕度影響 '丨 : , 較小。 透氣性 丨PVA薄暝除Η20以外,對H2、N2、C02等氣體: 1均具阻絕性3 而才光性 ;品質不受3光照射而受影響。 造膜性 丨PVA造膜性優 '其坑張強度、撕裂強度、耐 磨強度等物理性質,均較其他水溶性樹脂 ; 丨好。 ! 無毒性 :純粹的PVA對人體無害;例如,現今亦有某丨 |些藥品採用為黏著劑。 (表一)Start to open right and left V to the extreme '' Solution 2 and ten drug-resistant, solvent-resistant plant double, high-grade materials', good materials, agents, esters, salt, acid resistance of weak substances weaken weakest chlorine- ^ Youshi 'dagger said that the oily physical properties are stable and stable, such as moisture absorption! It has lower hygroscopicity than other water-soluble polymers and is affected by humidity. Permeability 丨 Except for thin PVA, except for 暝 20, for H2, N2, C02 and other gases: 1 is barrier 3 and only light; quality is not affected by 3 light exposure. Film-forming properties 丨 PVA film-forming properties are good 'its physical properties such as pit tensile strength, tear strength, and abrasion resistance are better than other water-soluble resins; !! Non-toxic: Pure PVA is not harmful to the human body; for example, some drugs are also used as adhesives today. (Table I)
第14頁 415886 五、發明說明(12) PVA的分子量與平均聚合度 1 完全鹼化品 2 平均聚合度(DP) 3 .分 子量 - BF-26 2,500-2,600 1 1 :.000 -1 2 0.0 00 BF-24 2,400-2,500 I 1 07.000-1 1 :.000 i -- BF-24E 2,400〜2.500 1 I0S,000-1 15.000 BF-22 E 2 , : 5 0 〜2.3 5 ϋ ! 10 0.0〇0〜丨06.000 | BF-20 2.000-2.100 ί S9.000 〜9.5 0 00 Sf- 1 7H 1.7 0 0 -1 .S00 1 7 5.0 00^ 8 0.0 0 0 ! BF- 1 7 1.70 0 -1.8 00 i 7 5 0 0 0 〜S 0.0 0 0 ' BF- 1 7E 1 .7 00- 1 .S00 76,000^81.000 ; BF- 1 4 1 . 1 0 0 〜1 2 0 0 i 5 0.0 0 0 - 5 5 . 0 0 0 BF-OS SOO-900 3 5.0 0 0 〜4 ◦ . 0 0 0 B F - 0 5 500-600 1 2 : . 0 0 0 - 2 ' . 0 0 0 < 1 B F-04 400-500 j ! s, ο ο 〇 〜m〕ο BF-03 3 0 0〜400 . 13.000〜is.000 i B F - 2 0 W 2.000-2.100 j 9 L 0 0 0 〜9 6.0 ⑼ 1 1 B F - 1 7 W 1 . 7 0 0 〜!,3 0 0 77.0 0 0-82.00 {) : j B F - 1 4 W 1 . 1 0 0 〜1 . 2 0 丨〕 i 5 0.0 () 0 - 5 5 . 0 0 0 1 2, 部份鹼化品 i BP-26 2500-2650 124.0 0 0 〜13 0.0 0 0 BP-24 2400〜:5 (DO 1 I S,000〜1 24.000 BP-20 2000-2100 j 9 9』0 0 〜1 0 4 0 ϋ 0 B P - 2 0 Η 2000〜2100 99.000-100.000 ι | BP- I 7 1 700〜1 S00 S4.000-S9.000 Β Μ 4 110 0 -1 2 0 0 ί 54.000-60.000 i j BP-0 8 8 0 0 - 1 000 40,000- 5 0.00 0 BP-05 5 5 0 〜6 5 0 i 27.000〜3 :,000 : 1 BP-04 420-550 : :1 .0〇0-:7,00ΰ : Γ~ B P - 0 3 3 0 0 〜4 H 0 15,000-21.000 3 超低驗化品 BC-24 2,5 00 -2,700 ; m000〜140.00 0 ! BC-20 2.300〜2.500 120,000〜13 2.00 0 ! B C - 0 7 7 0 0 〜7 5 0 j 33.000〜45.000 , BC-07P 700〜750 1 39.000-45.000 B C - 0 5 600〜700 33.000-33,000 i B C - 0 5 P 600〜700 1 3 4.0 0 0- 3 9.0 0 0 4 低灰份部汾鹼化品 BC-24R 2 4 0 0 〜2 - 5 0 0 i 122.000-127.000 : BC-l7 R 1 .7 00〜1 ,S00 3 6 , 5 0 0 - 9 1 . 6 0 0 ι BC-05 R 550-650 i 28.000-33,000 (表二) 1匯_1 第15頁 415886 五、發明說明(13) 產品名稱 : 溶解度(%): BF-24, QF-24E'AW-40 1-BF-26BP-24-BC-24| i 1 0¾〜1 5% BF-20, BP-20 ' BF-1 7E B F - 1 7 Η ' B F - 1 7 · B F - 2 0 W - B F - 1 7 W i BP-20H,BP-17,AW-201,BC-20 ' 15%-20% ! 1 ! BF- 1 4, BP-08, BF-08 ' BF^05 · BF-14W - BP-14 · 1 BP,05,BC-05 2 0 % 〜3 0 % i | BP-03, BF-03 ' BP-04 4 0 0/〇 ^ 5 0 % ! (表三)Page 14 415886 V. Description of the invention (12) Molecular weight and average degree of polymerization of PVA 1 Completely basic product 2 Average degree of polymerization (DP) 3. Molecular weight-BF-26 2,500-2,600 1 1: .000 -1 2 0.0 00 BF-24 2,400-2,500 I 1 07.000-1 1: .000 i-BF-24E 2,400 to 2.500 1 I0S, 000-1 15.000 BF-22 E 2,: 5 0 to 2.3 5 ϋ! 10 0.0〇0 to丨 06.000 | BF-20 2.000-2.100 ί S9.000 ~ 9.5 0 00 Sf- 1 7H 1.7 0 0 -1 .S00 1 7 5.0 00 ^ 8 0.0 0 0! BF- 1 7 1.70 0 -1.8 00 i 7 5 0 0 0 to S 0.0 0 0 'BF- 1 7E 1 .7 00- 1 .S00 76,000 ^ 81.000; BF- 1 4 1. 1 0 0 to 1 2 0 0 i 5 0.0 0 0-5 5. 0 0 0 BF-OS SOO-900 3 5.0 0 0 to 4 ◦. 0 0 0 BF-0 5 500-600 1 2:. 0 0 0-2 '. 0 0 0 < 1 B F-04 400-500 j ! s, ο ο 〇 ~ m] ο BF-03 3 0 0 ~ 400. 13.000 ~ is.000 i BF-2 0 W 2.000-2.100 j 9 L 0 0 0 to 9 6.0 ⑼ 1 1 BF-1 7 W 1. 7 0 0 ~! , 3 0 0 77.0 0 0-82.00 {): j BF-1 4 W 1. 1 0 0 ~ 1. 2. 0 丨] i 5 0.0 () 0-5 5. 0 0 0 1 2 , Partial alkalization Product i BP-26 2500-2650 124.0 0 0 to 13 0.0 0 0 BP-24 2400 to: 5 (DO 1 IS, 000 to 1 24.000 BP-20 2000-2100 j 9 9 ′ 0 0 to 1 0 4 0 ϋ 0 BP-2 0 Η 2000 ~ 2100 99.000-100.000 ι | BP- I 7 1 700 ~ 1 S00 S4.000-S9.000 Β Μ 4 110 0 -1 2 0 0 ί 54.000-60.000 ij BP-0 8 8 0 0-1 000 40,000- 5 0.00 0 BP-05 5 5 0 ~ 6 5 0 i 27.000 ~ 3:, 000 : 1 BP-04 420-550: : 1.00〇-: 7,00ΰ: Γ ~ BP-0 3 3 0 0 to 4 H 0 15,000-21.000 3 Ultra-low test chemical BC-24 2,5 00 -2,700; m000 to 140.00 0! BC-20 2.300 to 2.500 120,000 to 13 2.00 0! BC-0 7 7 0 0 ~ 7 5 0 j 33.000 ~ 45.000, BC-07P 700 ~ 750 1 39.000-45.000 BC-0 5 600 ~ 700 33.000-33,000 i BC-0 5 P 600 ~ 700 1 3 4.0 0 0- 3 9.0 0 0 4 Low-ash content Fen alkali chemicals BC-24R 2 4 0 0 ~ 2-5 0 0 i 122.000-127.000: BC-l7 R 1 .7 00 ~ 1, S00 3 6, 5 0 0-9 1 . 6 0 0 BC-05 R 550-650 i 28.000-33,000 (Table 2) 1 sink_1 page 15 415886 5. Description of the invention (13) Product name: Solubility (%): BF-24, QF-24E'AW-40 1 -BF-26BP-24-BC-24 | i 1 0¾ ~ 1 5% BF-20, BP-20 'BF-1 7E BF-1 7 Η' BF-1 7 · BF-2 0 W-BF-1 7 W i BP-20H, BP-17, AW-201, BC-20 '15% -20%! 1! BF- 1 4, BP-08, BF-08' BF ^ 05 · BF-14W-BP- 14 · 1 BP, 05, BC-05 2 0% to 3 0% i | BP-03, BF-03 'BP-04 4 0 0 / 〇 ^ 5 0%! (Table 3)
第16頁Page 16
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