^^482 ^^482 經滴部中央標準局員工消費合作社印製 A7 -------67 五、發明説明（1 ) 本發明有關於用於各種型式家具材料及建築物内 部的一種裝飾片和裝飾板，特別有關於可捕捉從基板所 釋放出之甲酸的一種裝飾片和裝飾板，並有關於其製造 方法。 裝飾板是由裝飾片接合在一基板之頂表面而組成 的，所謂的裝飾片是其上印有裝飾圖案的一紙片或合成 樹脂。傳統裝飾板的最大問題是，許多裝飾板使用會釋 放甲醛的基板。 例如，用來形成木材合板(plywood)、顆粒板（particle board)、或木質纖維板等木基基板的接著劑，用來形成 FRP(纖維強化塑膠，fiber-reinforced plastic)的樹脂，以 及用來形成樹脂基基板的樹脂都含有會產生甲醛的物 質’如尿素樹脂。因此，單純由裝飾片接合在此基板上 所構成的裝飾板會釋放甲醛於所處的房間中。因此，此 種裝飾板會污染環境。 為此’已有許多方法被提出以避免由裝飾板之基板 中釋放曱醛。例如，已知使用不含有甲醛的樹脂，如乙 酸乙烯酯基樹脂，或者將甲醛捕捉劑加入會產生甲醛的 樹脂（如尿素樹脂）中，如一有機胺基化合物 然而，不含甲藤的樹脂的黏著強度較弱（特別是， 較弱的初始黏著強度），因此其使用會導致顆粒板、木基 纖維板、或FRP之物理性質（如強度）的改變。此外，將 甲醛捕捉劑加入一基板中，不僅會增加基板的費用*而 且會改變其物理性質。 本紙张尺度適用中國國家標隼（CNS ) Α4現格（210X297公釐） C請光閱讀背命之注意事項再填寫本頁)^^ 482 ^^ 482 Printed by the Consumer Standards Cooperative of the Central Bureau of Standards, A7 ------- 67 V. Description of the invention (1) The present invention relates to a decoration for various types of furniture materials and the interior of buildings. The present invention relates to a sheet and a decorative board, and more particularly to a decorative sheet and a decorative board capable of capturing formic acid released from a substrate, and a manufacturing method thereof. The decorative plate is composed of a decorative sheet bonded to the top surface of a substrate. The so-called decorative sheet is a piece of paper or synthetic resin on which a decorative pattern is printed. The biggest problem with traditional decorative boards is that many decorative boards use substrates that release formaldehyde. For example, adhesives used to form wood-based substrates such as plywood, particle board, or wood fiber boards, resins used to form FRP (fiber-reinforced plastic), and resins used to form The resins of the resin-based substrates all contain substances that generate formaldehyde, such as urea resins. Therefore, a decorative board composed of a decorative sheet simply bonded to this substrate will release formaldehyde in the room where it is located. Therefore, such a decorative board pollutes the environment. To this end, many methods have been proposed to avoid the release of formaldehyde from the substrate of the decorative board. For example, it is known to use resins that do not contain formaldehyde, such as vinyl acetate-based resins, or to add formaldehyde trapping agents to resins that generate formaldehyde (such as urea resins), such as an organic amine-based compound. The strength is weaker (especially, the weaker initial adhesive strength), so its use will cause changes in the physical properties (such as strength) of particle board, wood-based fiberboard, or FRP. In addition, the addition of a formaldehyde trapping agent to a substrate not only increases the cost of the substrate *, but also changes its physical properties. This paper size applies to China National Standards (CNS) Α4 is now (210X297 mm) C Please read the precautionary notes before filling this page)
'1T ^^482 A7 ----------B7 五、發明説明（2 ) 再者，只要裝飾片是使用尿素基或類似的接著劑來 接合在基板上的，接著劑即不可避免地會釋放曱醛。 本發明之一目的即為提供一種可捕捉有毒甲醛的 裝飾片。本發明之另一目的為提供一種可避免甲醛釋放 的裝飾板。本發明之另一目的為提供一種製造此裝飾片 和裝飾板的方法。 為達成本發明之目的，依據本發明之特徵，由基片 和裝飾層所構成的一裝飾片，以一曱醛捕捉劑浸潰 (impregnated)。當此裝飾片與可能會釋放甲醛的物品之 表面接合時，裝飾片捕捉尹醛，於是可避免甲醛的釋 放。再者，在含有甲醛的大氣中，裝飾板可捕捉甲醛， 於是幫助曱醛從大氣中排除。 此甲醛捕捉劑可浸潰入基片中或裝飾層中。裝飾層 是形成為，例如，一墨水層或具有圖案的表面不規則。 藉由使用含有曱醛捕捉劑的墨水，可得到在裝飾層含有 甲醛捕捉劑的一裝飾片。 經濟部中央標準局員工消費合作社印繁 (請先閲讀背面之注意事項再填寫本頁) 也可以形成與裝飾層分開的含有甲醛捕捉劑之 層。在此情況下，裝飾層在基片之頂側上，且含有甲醛 捕捉劑之層在基片之底側上；或者，含有甲醛捕捉劑之 層在基片和裝飾層之間。 亦可以使用一紙基物質作為基片，並將其以曱醛捕 捉劑浸潰。亦可以另外提供一保護層當作最頂層，以保 護内層（即，裝飾層和其他層），且，在此情況下，亦可 以在保護層之上提供另一含有曱醛捕捉劑之層。 本紙張尺度適用中國國家標羋（CNS ) A4^7210X297TF) 412482 A7 -- 五、發明説明（3 ) 為達成上述目的’依據本發明之另一特徵，藉由將 一裝飾片（如上述）接合至一基板上以形成一裝飾板。裝 飾片可只接合在基板的頂表面，或接合在其頂面和底 面。 當裝飾片只接合在基板的頂表面時，最好基板的底 面是放在具有抵抗曱醛之通透、捕捉曱醛、抵抗濕氣通 透其中之一能力之片材上。如果此片材具有抵抗甲醛通 透的能力’即可避免從基板底面釋放出甲醛；如果此片 材具有捕捉甲醛的能力’則從基板所釋出的甲醛也可在 底面上被捕捉；和果此片材具有抵抗濕氣通透的能力， 可避免由基板的吸收和釋放濕氣，於是可避免由於基板 之膨脹和收縮所造成的彎曲。 經濟部中央標準局員工消費合作社印製 装------訂 一讀先閱讀背面之注意事項再填寫本頁} 當裝飾片接合在基板上，而含有甲醛捕捉劑之層面 向基板時，可有效捕捉大部分的甲醛◊在此情況下，裝 飾片之基片可使用具有不良氣體通透性的物質來製 造’例如合成樹脂。然而，只要裝飾片之基片是由具有 良好氣體通透性的物質製造的，即使當裝飾片接合在基 板上’而含有甲醛捕捉劑之層的相反側面向基板時，甲 醛也可以大部分有效地被捕捉。 當裝飾片之基片是由一透明物質所製，可以在面向 基板的基片側上形成裝飾層，而不會損壞裝飾層的美學 效果。 為了達成上述目的，依據本發明之另一特徵，依以 下方法製造一裝飾片。以含有一甲搭捕捉劑之落劑基墨 本纸張尺度適用中國國家標準（CNS ) A4規格（2I0X297公釐） 412482 A7 〜-____— 扪 五、發明説明（4 ) ~ ' - 水來塗佈-基片’藉此在基片之頂部形成—裝飾層；以 此方式’可得到-裝飾片’其具有被—甲㈣捉劑浸潰 的-裝飾層。當使用-水溶性甲㈣捉劑時，使其與溶 劑基墨水混合’以-無機物質粉末當作甲搭捕捉劑的载 劑。 當含有甲搭捕捉劑之層與裝飾層是分開形成的 時’亦可以藉由以含有甲_捉劑之—水基溶液來塗佈 基片或裝飾層，以形成含有甲醛捕捉劑之層。 當裝飾片是由一基片、一胺基甲酯層、和一以含有 胺之甲醛捕捉劑所浸潰之層之時，則可能在胺基甲酯層 中所含有的異氰酸根（如果還未反應）會與用作甲搭捕捉 劑之胺反應，於是減弱甲路的捕捉效果。為避免此現 象，藉由硬化來形成胺基曱酯層，使得沒有異氰酸根是 未反應的’之後含有甲醛捕捉劑之層形成在胺基甲酯層 之頂部，或形成在基片上胺基甲酯層形成之側的相反 側。這可避免異氰酸根和胺之間的反應，於是保護胺的 曱酸捕捉效果。 鯉濟部中央標準局員工消費合作社印製 ---------,.i衣------訂 1-4.先閱讀背面之ii意ί項再填寫本頁) 本發明之目的和特徵可藉由以下敘述、較佳實施 例、及參考所附之圖式而更為清楚。 里式之簡單銳.明： 第1圖顯示本發明第1具體實施例之裝飾片的載面 圖； 第2圖顯示本發明第2具體實施例之片材的载面 7 本紙狀度適用中國國家標準（CNS ) Α4規格（21〇><297公楚） 412482 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（5 ) 圖； 第3圖顯示本發明第3具體實施例之裝飾片的載面 1^1 _ 圃， 第4圖顯示本發明第4具體實施例之裝飾片的載面 圖； 第5圖顯示本發明第5具體實施例之裝飾片的載面 圖； 第6圖顯示本發明第6具體實施例之裝飾板的載面 圖； 第7圖顯示本發明第7具體實施例之裝飾板的載面 圖； 第8圖顯不本發明第8具體實施例之裝飾板的載面 rgl · 圍， 第9圖顯不本發明第9具體實施例之裝飾板的載面 圖； 第10圖顯示本發明第10具體實施例之裝飾板的載 面圖； 第11圖顯不本發明第u具體實施例之裝飾板的載 面圖； 第12圖顯不本發明第12具體實施例之裝飾板的載 面圖； 第13圖顯不本發明第13具體實施例之裝飾板的載 面圖； 第14圖顯示本發明第14具體實施例之裝飾板的載 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公复） ------：---4------,1T > 〈背先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 412482 A7 ________B7 五、發明説明（6 ) ~ 面圖； 第15圖顯示本發明第15具體實施例之裝飾板的載 面圖； 第16圖顯示本發明第16具體實施例之裝飾板的載 面圖； 第17圖顯示本發明第17具體實施例之裝飾板的載 面圖； 第18圖顯示本發明第18具體實施例之裝飾板的載 面圖；以及 第19圖顯示本發明第19具體實施例之裝飾板的載 面圖。 首先，參考第1至第5圖，將敘述依據本發明之含 有甲搭捕捉劑之 >；材。這些片材在其基片中含有甲膝捕 捉劑，或者在形成於基片上之一個或多個層中，或者是 在兩者中皆有。如果裝飾是施加在這些片材的頂側上， 或如果其構成層之一是形成為一裝飾層，則這些片材是 用作裝飾片。 第1圖顯示本發明之第一具體實施例之裝飾片51 的截面圖，其具有依據本發明之最基本的構造。裝飾片 51是由一基片1和一接合在基片丨頂部之裝飾層2所構 成的。 關於基片1之材料，可以使用紙，如無木材成份 紙積層紙、日本紙、牛皮紙（kraft paper)、鈦紙、林特 9 本紙張尺度適用中關家梯準（CNS) w規格（加心7公楚〉 ---.---.---d— > 請先閱讀背面之注意事項再填寫本頁) 訂---- A7 一__ B7__ 五、發明説明（7 ) 紙（linter paper)、硬紙板、石膏板紙、或羊皮紙（parchment paper)等；可以使用合成樹脂膜，如聚乙烯膜、聚丙烯 膜、聚氯乙烯膜、聚偏二氣乙烯膜、聚乙烯醇膜、聚乙 婦對苯二酸酯膜、聚碳酸酯膜、丙烯酸類樹脂膜、尼龍 膜、聚苯乙稀膜、乙稀-乙酸乙稀醋共聚物膜、或乙烯_ 乙烯醇共聚物膜；或合成樹脂纖維之未編織織物，如聚 S旨或維尼龍纖維，或玻璃纖維；或塑膠膜，如離子絡接 聚體（ionomer);或金屬之箔或片，如鐵、鋁、或銅。 這些材料可單獨使用’或組合使用為一積層之多層 片材。由紙基材料所製之基片具有良好的氣體通透性， 因此對於甲醛有相當高的通透性。相反的，由合成樹脂 基材料所製之基片通常具有不好的氣體通透性，因此對 於甲醛有相當低的通透性。 經濟部中央標準局肩工消費合作社印製 基片可以任何所需的方式裝飾。基片可以下列方式 裝韩’例如’以一色素或染料來原液上色（mass_c〇l〇ring) 材料，將墨水或金屬之裝飾層形成為一圖案，形成具有 一圖案的表面不規則。當基片是透明時，裝飾層或一表 面不規則圖案可形成在基片之頂側、或底側、或兩侧； 然而，當基片是不透明時，必須形成在頂側。 當材料是以一色素或染料來原液上色時，依據裝飾 片的使用，而決定以透明或不透明（遮蓋）上色。關於原 液上色’可以使用一無機色素，如鈦白、碳黑、群青、 氧化鐵紅、或鉻黃；或—有機色素或染料，如奎吖咬網、 異吲啼嗣、酞花青藍、或苯胺黑。若有需要，可使用例 10 本紙張尺度4用巾酬家轉（CNS)⑽格（21QX297公麓） 4124S2 A7 _B? 五、發明説明（8 ) 如碳酸鈣、矽石（二氧化矽）、氧化鋁、或硫酸鋇等延長 劑色素（填料）作為添加劑。 具有圖案的墨水裝飾層可以一般的印刷方法形 成，如照相凹板、平板印刷、印字機印刷、或絲螢幕印 刷；甚至可以搶晝形成。圖案可以是，例如，木頭色調 的、石頭色調的、布料色調的、皮革色調的、文字、幾 何圖案、或固體顏色。至於印刷墨水，可以是色素或染 料及溶劑基固定劑的混合物，此固定劑例如硝酸纖維素 /醇酸基、纖維素基，氣乙烯基、氣乙烯-醋酸乙烯基、 丙烯酸基、丙稀酸多元醇基、酯基、醯胺基、或胺基甲 酯基樹脂。為了要使得木頭色調圖案有較佳的「光澤」， 最好使用含有螢光色素的色素，如珍珠基色素或金屬粉 末。 也可以以所謂的轉移印刷來形成墨水圖案層。特別 是，使用轉移片，即具有墨水圖案層的撥絕墨水載劑 (ink-repellent carrier)，若有需要，使用在其表面上形成 的黏著層，則在轉移片上形成的墨水圖案層可藉由壓力 經濟部中央標準扃貝工消費合作社印製 -------^----4-------ΐτ ,. 「 (請4'聞讀背面之注意事項再填寫本頁) 或壓力及熱而轉移到表面上，使其上形成圖案層（墨水圖 案層）。 具有圖案的金屬裝飾層是藉由高真空沉積金屬而 形成的，金屬例如鋁、鉻、金、銀、或銅^金屬層可以 在整個表面形成，或可形成一個圖案。金屬層可以已知 的方法形成一個圖案。例如，將水溶性墨水（當作抵抗層） 施加於不需要金屬層的表面上’然後沉積金屬於整個表 11 本紙張尺纽财S} TTl〇7297^il--------- 經濟部中央橾率局員工消費合作社印製 ^2ί8Ζ at __________B7_ 五、發明説明（9 ) 面’之後’以水洗表面以除去抵抗層和在其頂部的金屬 層。或者’可以轉移印刷來形成金屬圖案層，亦即，藉 由將形成在一轉移片上的金屬圖案層轉移至表面上，使 形成一圖案層（金屬圖案層 表面不規則圖案可藉由毛製法（hairlining)、噴砂 法、或浮花壓製法（embossing)以將表面不規則形成於基 片之表面以得到。 浮花壓製法是使用熱壓型式的一層接一層或旋轉 式的浮花壓製’將一浮花壓製模頭壓在熱軟化的基片 上’藉此將基片的表面成形為模頭的形狀。例如，浮花 廢製法產生木導管凹槽、木粒、石表面粒、布表面組織、 毛面尾工（matte finish)、砂粒、毛髮等圖案，或其他， 或上述之組合。此外，若有需要，可以已知的拭塗（wiping) 方法以將著色墨水填入表面不規則的再進入部分。關於 著色墨水’可以將色素或染料加入通常使用的載劑中， 載劑例如胺基甲酯樹脂、丙烯酸類樹脂、聚酯樹脂；然 而’最好使用具有高黏著性和高耐溶劑性的兩部分硬化 型式。拭塗法可以是任可習知的拭塗法，例如摻和到刀 法（doctor blade process)或輥塗佈法。藉由上述方法之 一’著色墨水首先施加在表面不規則圖案的整個區域， 然後拭去在突出部分的著色墨水，使得只有在再進入部 分留有著色墨水。 當基片和裝飾層之間的黏著強度，或基片和黏著層 的黏著強度不足夠時，最好在其間提供一高度的黏著初 12 本紙張尺度適用中咖家辟（CNS ) Λ4規格（UGX 297公菜） I I n I 1 I ΙΊ I ! I If , i m (請t閲讀背面之注意事項再填寫本頁) 412482 A7 _ -____B7_ 五、發明説明（1〇) 層。當基片是由聚烯烴製造時’可使用例如兩部分硬化 聚胺基曱酯層或氣化的聚稀煙層來作為初層。 再者’若有需要’可形成透明樹脂之表面保護層作 為裝飾片的最頂層’以保護裝飾片不受磨耗、水、化合 物、及其他的損傷。為此目的，可以使用纖維基樹脂、 丙烯酸類樹脂、兩部分硬化聚胺基甲酯樹脂、不飽和聚 酯樹脂、環氧樹脂、氟碳樹脂、或其他。表面保護層是 藉由以一塗佈液體塗佈於裝飾片上而形成，而此塗佈液 體是由將上述之一樹脂與一添加物及其類似物等捏和 在一起而得到的。塗佈是已知的塗佈方法，例如照相凹 板、親塗佈、或刀塗佈，且操作方式是對於每平方米乾 塗伟液體，施加一至五克的樹脂。若有需要，也可以對 其加入色素、染料或其他以對塗佈液體著色。 可捕捉甲醛的最典型的物質是有機胺化合物，其很 容易與甲醛反應並產生無毒且穩定的產物，且不會分解 出甲醛。例如’作為甲醛捕捉劑，可使用醯胺類，如二 氰二醮胺、或尿素；或環狀稀烴尿素，如乙稀尿素、丙 烯尿素、5·羥基丙烯尿素、5-甲氧基丙烯尿素、5_曱基 丙烯尿素、仲班酸（parabanic acid; glyoxaimonoureine)、 或4,5-二甲氧基乙稀尿素；或飽和環狀二級胺類，如吐 洛烧、娘咬、或嗎淋；或胺類’如2-肼撐苯並三β坐或其 衍生物；或醯亞胺類。在這些物質中，尿素和環狀稀烴 尿素是特別好的。若有需要，可使用氫氧化銨作為添加 劑。 13 本紙張尺度適用中國國家標準（CNS ) Λ4規格（2iOX297公釐) -- ------^---装------訂 - r (請七閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 ^248^ a7'1T ^^ 482 A7 ---------- B7 V. Description of the invention (2) Furthermore, as long as the decorative sheet is bonded to the substrate using a urea-based or similar adhesive, the adhesive is not allowed. Avoiding the release of formaldehyde. An object of the present invention is to provide a decorative sheet capable of capturing toxic formaldehyde. Another object of the present invention is to provide a decorative board which can prevent the release of formaldehyde. Another object of the present invention is to provide a method for manufacturing the decorative sheet and the decorative plate. In order to achieve the object of the present invention, according to the features of the present invention, a decorative sheet composed of a base sheet and a decorative layer is impregnated with a formaldehyde capture agent. When this decorative sheet is bonded to the surface of an article that may release formaldehyde, the decorative sheet captures Yinaldehyde, so that the release of formaldehyde can be avoided. Furthermore, in an atmosphere containing formaldehyde, the decorative panel can capture formaldehyde, thereby helping to eliminate formaldehyde from the atmosphere. This formaldehyde trapping agent can be impregnated into a substrate or a decorative layer. The decorative layer is formed, for example, as an ink layer or a patterned surface is irregular. By using an ink containing a formaldehyde capturing agent, a decorative sheet containing a formaldehyde capturing agent in the decorative layer can be obtained. Yin Fan, a staff consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). A layer containing formaldehyde trapping agent can also be formed separately from the decorative layer. In this case, the decorative layer is on the top side of the substrate and the layer containing the formaldehyde trapping agent is on the bottom side of the substrate; or, the layer containing the formaldehyde trapping agent is between the substrate and the decorative layer. It is also possible to use a paper-based substance as a substrate and impregnate it with a formaldehyde trap. A protective layer may be additionally provided as the topmost layer to protect the inner layer (i.e., the decorative layer and other layers), and in this case, another layer containing the formaldehyde trapping agent may be provided on top of the protective layer. This paper size applies to Chinese National Standard (CNS) A4 ^ 7210X297TF) 412482 A7-V. Description of the invention (3) To achieve the above-mentioned objective, according to another feature of the present invention, a decorative sheet (as described above) is joined Onto a substrate to form a decorative plate. The decoration sheet may be bonded only to the top surface of the substrate, or to the top and bottom surfaces thereof. When the decorative sheet is bonded only to the top surface of the substrate, it is preferable that the bottom surface of the substrate is placed on a sheet having the ability of resisting permeal, capturing aldol, and resisting moisture permeation. If the sheet has the ability to resist formaldehyde penetration, 'the formaldehyde can be prevented from being released from the bottom surface of the substrate; if the sheet has the ability to capture formaldehyde', the formaldehyde released from the substrate can also be captured on the bottom surface; and This sheet has the ability to resist moisture permeability, which can avoid the absorption and release of moisture by the substrate, and thus can avoid bending caused by the expansion and contraction of the substrate. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs ------- Please read the precautions on the back before filling out this page} When the decorative sheet is bonded to the substrate and the layer containing the formaldehyde trapping agent faces the substrate, Can effectively capture most of the formaldehyde. In this case, the substrate of the decorative sheet can be made of a substance having poor gas permeability, such as a synthetic resin. However, as long as the substrate of the decorative sheet is made of a substance having good gas permeability, even when the decorative sheet is bonded to the substrate and the opposite side of the layer containing the formaldehyde trapping agent faces the substrate, formaldehyde can be mostly effective The ground is captured. When the substrate of the decorative sheet is made of a transparent material, a decorative layer can be formed on the side of the substrate facing the substrate without damaging the aesthetic effect of the decorative layer. To achieve the above object, according to another feature of the present invention, a decorative sheet is manufactured by the following method. The paper size of the base paper containing a catcher is applicable to the Chinese National Standard (CNS) A4 specification (2I0X297 mm) 412482 A7 ～ -____— 扪 5. Description of the invention (4) ~ '-Water to paint The cloth-substrate sheet thereby forms a decorative layer on top of the substrate sheet; in this way, a 'decorative sheet' is obtained which has a decorative layer impregnated with a formaldehyde trap. When a water-soluble formazan capture agent is used, it is mixed with a solvent-based ink 'with an inorganic substance powder as a carrier for the formazan capture agent. When the layer containing the nail catcher and the decorative layer are formed separately ', the substrate or the decoration layer may also be coated with a water-based solution containing nail catcher to form a layer containing the formaldehyde catcher. When the decorative sheet is a substrate impregnated with an amine methyl ester layer, and a layer impregnated with an amine-containing formaldehyde trapping agent, the isocyanate that may be contained in the amine methyl ester layer (if (Not yet reacted) will react with the amine used as a nail catcher, thus weakening the nail capture effect. In order to avoid this phenomenon, the amine ester layer is formed by hardening, so that no isocyanate is unreacted, and then a layer containing a formaldehyde trapping agent is formed on top of the amine methyl ester layer, or an amine group is formed on the substrate. The side opposite to the side where the methyl ester layer is formed. This avoids the reaction between the isocyanate and the amine, and thus protects the osmic acid capture effect of the amine. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Liji --------- ,. i clothing -------- Order 1-4. Read the meaning of item ii on the back before filling in this page) The present invention The purpose and characteristics can be made clearer by the following description, preferred embodiments, and with reference to the accompanying drawings. The Chinese style is simple and sharp. Figure 1 shows the loading surface of the decorative sheet of the first embodiment of the present invention; Figure 2 shows the loading surface of the sheet of the second embodiment of the present invention. National Standard (CNS) A4 Specification (21〇 < 297 Gongchu) 412482 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (5) Figure; Figure 3 shows the third specific implementation of the present invention Example 1 of the decorative sheet 1_1 _ garden, Figure 4 shows the decorative sheet of the fourth embodiment of the present invention; Figure 5 shows the decorative sheet of the fifth embodiment of the present invention Figure 6 shows a load-bearing view of a decorative plate according to a sixth embodiment of the present invention; Figure 7 shows a load-bearing view of a decorative plate according to a seventh embodiment of the present invention; Figure 8 shows an eighth embodiment of the present invention The loading surface rgl of the decorative plate of the example is shown in FIG. 9. FIG. 9 shows the loading surface of the decoration plate of the ninth embodiment of the present invention. FIG. 10 shows the loading surface of the decoration plate of the tenth embodiment of the present invention. FIG. 11 shows a side view of a decorative plate according to the u specific embodiment of the present invention; FIG. 12 shows A side view of the decorative board of the twelfth embodiment of the invention; FIG. 13 shows a side view of the decorative board of the thirteenth embodiment of the invention; and a fourteenth figure shows the side view of the decorative board of the fourteenth embodiment of the invention. This paper size applies to China National Standard (CNS) A4 specification (210X297 public copy) ------: --- 4 ------, 1T > <Read the precautions on the back before filling this page ) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 412482 A7 ________B7 V. Description of the Invention (6) ~ Side view; Figure 15 shows a side view of the decorative board of the 15th embodiment of the invention; Figure 16 shows the invention A sectional view of a decorative plate in a sixteenth embodiment; a sectional view of a decorative plate in a seventeenth embodiment of the invention; a sectional view of a decorative plate in the eighteenth embodiment of the invention; And FIG. 19 is a cross-sectional view of a decorative plate according to a nineteenth embodiment of the present invention. First, referring to Figs. 1 to 5, a > material containing a nail trapping agent according to the present invention will be described. These sheets contain a knee knee trap in their substrate, either in one or more layers formed on the substrate, or in both. If decoration is applied on the top side of these sheets, or if one of its constituent layers is formed as a decorative layer, these sheets are used as decorative sheets. FIG. 1 shows a cross-sectional view of a decorative sheet 51 according to a first embodiment of the present invention, which has the most basic structure according to the present invention. The decorative sheet 51 is composed of a substrate 1 and a decorative layer 2 bonded to the top of the substrate. Regarding the material of the substrate 1, paper can be used, such as wood-free paper laminated paper, Japanese paper, kraft paper, titanium paper, Lint 9 This paper standard applies to the Zhongguanjiatizhan (CNS) w specifications (plus Heart 7 Gongchu> ---.---.--- d-- > Please read the notes on the back before filling out this page) Order ---- A7 __ B7__ V. Description of the invention (7) Paper (Linter paper), cardboard, gypsum board, or parchment paper, etc .; synthetic resin films such as polyethylene film, polypropylene film, polyvinyl chloride film, polyvinylidene chloride film, polyvinyl alcohol film can be used , Polyethylene terephthalate film, polycarbonate film, acrylic resin film, nylon film, polystyrene film, ethylene-vinyl acetate copolymer film, or ethylene vinyl alcohol copolymer film; Or non-woven fabrics of synthetic resin fibers, such as polystyrene or vinylon fibers, or glass fibers; or plastic films, such as ionomers; or metal foils or sheets, such as iron, aluminum, or copper . These materials can be used alone 'or in combination as a laminated multilayer sheet. The substrate made of paper-based material has good gas permeability, and therefore has a relatively high permeability to formaldehyde. In contrast, substrates made of synthetic resin-based materials generally have poor gas permeability and therefore have relatively low permeability to formaldehyde. Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, substrates can be decorated in any desired way. The substrate can be loaded with a material such as a pigment or a dye (mass_colling) in the following manner, forming a decorative layer of ink or metal into a pattern, and forming a patterned surface irregularity. When the substrate is transparent, a decorative layer or a surface irregular pattern may be formed on the top side, the bottom side, or both sides of the substrate; however, when the substrate is opaque, it must be formed on the top side. When the material is colored with a pigment or a dye, the transparent or opaque (covering) color is determined according to the use of the decorative sheet. Regarding the dope coloring, you can use an inorganic pigment, such as titanium white, carbon black, ultramarine blue, iron oxide red, or chrome yellow; or-organic pigments or dyes, such as quinacline, isoindazole, phthalocyanine blue , Or aniline black. If necessary, you can use Example 10 paper size 4 paper towels (CNS) grid (21QX297) 4124S2 A7 _B? 5. Description of the invention (8) such as calcium carbonate, silica (silicon dioxide), An extender pigment (filler) such as alumina or barium sulfate is used as an additive. The patterned ink decorative layer can be formed by a general printing method, such as gravure, lithography, printer printing, or silk screen printing; it can even be formed by daylight. The pattern may be, for example, wood-tone, stone-tone, cloth-tone, leather-tone, text, geometric pattern, or solid color. As for printing ink, it can be a mixture of pigments or dyes and solvent-based fixatives such as nitrocellulose / alkyd, cellulose-based, vinyl vinyl, vinyl vinyl acetate, acrylic acid, acrylic acid Polyol-based, ester-based, amido-based, or aminomethyl-based resins. In order to make wood tone patterns have a better "gloss", it is best to use pigments containing fluorescent pigments, such as pearl-based pigments or metal powders. The ink pattern layer may be formed by so-called transfer printing. In particular, using a transfer sheet, that is, an ink-repellent carrier having an ink pattern layer, and if necessary, using an adhesive layer formed on the surface thereof, the ink pattern layer formed on the transfer sheet can be borrowed. Printed by the Central Standard of the Ministry of Economic Affairs, 扃 贝 工 消费 consuming cooperatives ------------ ^ ---- 4 ------- ΐτ,. "(Please read the notes on the back of the 4's and fill out this Page) or pressure and heat transferred to the surface to form a pattern layer (ink pattern layer) on it. The metal decorative layer with a pattern is formed by high vacuum deposition of metal such as aluminum, chromium, gold, silver The copper or metal layer can be formed on the entire surface, or a pattern can be formed. The metal layer can be patterned in a known method. For example, a water-soluble ink (as a resist layer) is applied to a surface that does not require a metal layer 'Then deposit the metal on the entire table of 11 paper rule New Zealand S} TT107297 ^ il --------- Printed by the Consumer Cooperatives of the Central Bureau of the Ministry of Economic Affairs ^ 2ί8Z at __________B7_ V. Description of the invention (9 ) Face 'after' wash surface with water to remove resist A metal layer on top of it. Alternatively, 'printing can be used to form a metal pattern layer, that is, a pattern layer is formed by transferring a metal pattern layer formed on a transfer sheet to a surface (the surface of the metal pattern layer is irregular The pattern can be obtained by hairlining, sandblasting, or embossing to irregularly form the surface on the surface of the substrate. The embossing method is to use a hot pressing pattern one by one or rotate The floating flower pressing method “presses a floating flower pressing die on a heat-softened substrate”, thereby forming the surface of the substrate into the shape of a die. For example, the floating flower waste method generates grooves, grains, Stone surface grain, cloth surface texture, matte finish, sand grain, hair and other patterns, or other, or a combination of the above. In addition, if necessary, a known wiping method can be used to color The ink fills the irregular reentry part of the surface. Regarding coloring inks, pigments or dyes can be added to commonly used carriers, such as amino resins, acrylic resins, polymers Ester resin; however, 'two-part hardening type with high adhesion and high solvent resistance is preferred. The swab method can be any conventional swab method, such as blending into a doctor blade process or a roller Coating method. By one of the above methods, the "coloring ink is first applied to the entire area of the irregular pattern on the surface, and then the coloring ink on the protruding portion is wiped off, so that the coloring ink remains only in the re-entry portion. When the substrate and decoration When the adhesive strength between the layers, or the substrate and the adhesive layer are not enough, it is best to provide a high degree of adhesion between them. This paper size is suitable for CNS Λ4 specification (UGX 297). II n I 1 I ΙΊ I! I If, im (Please read the notes on the back and fill in this page again) 412482 A7 _ -____ B7_ V. Description of the invention (1〇) layer. When the substrate is made of polyolefin, for example, a two-part hardened polyurethane layer or a vaporized polysmoky layer can be used as the preliminary layer. Furthermore, a "surface-protective layer of transparent resin can be formed as the topmost layer of the decorative sheet if necessary" to protect the decorative sheet from abrasion, water, compounds, and other damage. For this purpose, a fiber-based resin, an acrylic resin, a two-part hardened polyurethane resin, an unsaturated polyester resin, an epoxy resin, a fluorocarbon resin, or the like can be used. The surface protective layer is formed by applying a coating liquid on the decorative sheet, and the coating liquid is obtained by kneading one of the above resins with an additive and the like. Coating is a known coating method, such as gravure, parental coating, or knife coating, and is operated by applying one to five grams of resin per square meter of dry coating liquid. If necessary, pigments, dyes, or the like may be added to color the coating liquid. The most typical substances that can capture formaldehyde are organic amine compounds, which can easily react with formaldehyde and produce non-toxic and stable products without decomposing formaldehyde. For example, as formaldehyde trapping agents, amines such as dicyandiamide or urea; or cyclic dilute hydrocarbon ureas such as ethylene urea, propylene urea, 5-hydroxypropylene urea, 5-methoxypropylene Urea, 5-methylpropenyl urea, parabanic acid (glyoxaimonoureine), or 4,5-dimethoxyethylene urea; or saturated cyclic secondary amines, such as tortoise, bitumen, or Morin; or amines' such as 2-hydrazinobenzotrisine or its derivatives; or amidines. Among these materials, urea and cyclic thin hydrocarbon urea are particularly good. If necessary, ammonium hydroxide can be used as an additive. 13 This paper size applies Chinese National Standard (CNS) Λ4 specification (2iOX297 mm)------- ^ --- Packing ------ Order-r (Please read the notes on the back before filling (This page) Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs ^ 248 ^ a7
" -----..--- I 五、發明説明（u) 可以使用一種以上的捕捉劑的混合物。可以在捕捉 劑與固定劑捏合之後來使用，固定劑如硝酸纖維素/醇酸 基樹脂、纖維素基樹脂、乙烯基樹脂、聚酯基樹脂、或 聚醯胺基樹脂。在此情況下，可在捕捉劑和固定劑之中 加入適當量的有機溶劑，如乙醇、乙酸乙酯、或甲苯， 並且若有需要，可加入其他添加物。即使當使用一水溶 性的甲醛捕捉劑時，其可藉由矽石、滑石、黏土、活性 碳、沸石、或海泡石等無機物質之粉末作為載劑，以與 大範圍的固定劑捏合。 曱醛捕捉劑可藉由以下方式而浸潰入裝飾片中： (1) 以捕捉劑來塗佈、浸潰、或捏合基片之頂側、 底側、或兩側； (2) 將捕捉劑加入用來形成一墨水裝飾層的墨水 中，若有此裝飾層； (3) 將捕捉劑加入初層中； (4) 將捕捉劑加入表面保護層之中；或 (5) 組合上述方法（1)至（句之兩種或多種。 經濟部中央標準局員工消費合作社印製 {請七閱讀背面之注意事項再填寫本頁) 第2圖顯示本發明第二具體實施例之片材52的載 面圖。此片材52是由一基片1和接合在基片1之頂部 的一甲醛捕捉層（此後簡單地稱作捕捉層）3所構成的。捕 捉層3是將一含有甲醛捕捉劑之溶液塗佈在基片1之表 面而形成的。塗佈可使用一般的方法，如照相凹板 '輥 塗佈、刀塗佈、或類似方法。 關於基片1 ’乃依據片材52如何接合在一基板上 14 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X297公t > 扣482 Α7 Β7 五、發明説明（12) 而決定使用紙基片或合成樹脂基片。例如，當片材52 接合在一基板上，而捕挺層3面向基板時，不論基片i 是由紙基片或合成樹脂基片所製造的，都可有效地捕捉 甲醛。 相反的，當片材52接合在一基板上，而捕捉層3 向外時，最好使用具有良好氣體通透性的紙基基片。這 是因為，如果使用對於甲醛之通透性低的合成樹脂基基 片，從基板釋放出的甲醛不能達到捕捉層3，於是不能 有效地被捕捉層3所捕捉。特別是，最好是20至80 g/m2 的積層紙，不僅是因為不貴，而且因為即使溶液是水基 的，因為其具有良好的氣體通透性，可很容易被含有甲 醛捕捉劑的溶液所塗佈。 然而，即使當使用合成樹脂基基片時，且片材52 接合在一基板上的方式是捕捉層3面向外，片材52可 捕捉在大氣中的甲醛。例如，當片材52接合在會自其 邊緣面釋放出甲路的—基板上時，片材52會很快地捕 捉所釋放出的甲醛。或者，當片材52放在一房間内， 而這房財有-片家具含有未被處理成抵抗甲酸釋放 經濟部中央標隼局員工消費合作社印製 ---1 n I - n -- I I n - - n ^ 4 (讀4'閱讀背面之注意事項再填寫本頁) 的基板時，片材52可捕捉由其釋放的甲醛，於是可保 持大氣乾淨。 ^ 以上關於基片之材料和裝飾片如何接合在一基板 上的方法’亦適用於以下具體實施例。 第3圖顯示本發明第三具體實施例之裝飾片幻的 截面圖。此裝飾片53是藉由將一裝飾層4印刷在上述 15 本紙張尺度it财關家料（CNS ) A4規格（2l〇T297公釐] 經濟部中央樣準局員工消費合作社印製 Α7 --—____________Β7 五、發明説明（13) ' 一 " 片材52之捕捉層3的相反側。關於裝飾# 53的基片卜 最好使用具有如前述性質及適合於印刷之表面平滑性 的積層紙。 第4圖顯示本發明第四具體實施例之裝飾片54的 截面圖。此裝飾片54是藉由在片材52之捕捉層3之頂 部形成一裝飾層4而得到的。 第5圖顯示本發明第五具體實施例之裝飾片55的 截面圖。此裝飾片55是由形成在一基片i之頂部的一 裝飾層4所構成的。此裝飾層4包括一固體墨水層亏和 一圖案化的墨水層ό，且是由含有甲醛捕捉劑和固定劑 的溶劑基（如乙醇基、乙酸乙酯基、或甲苯基）墨水所製 成的。 通常’如上述之含有曱醛捕捉劑之多層片材可以任 何積層方法來製造。然而，應注意的是，在基片上有裝 飾層和保護層（如有需要）的一裝飾片中，以及在其中之 裝飾層和保護層之至少一者是由可藉由異氰酸根而形 成胺基甲輯鏈的一樹脂所製成的一裝飾片中，在樹脂硬 化完成之前（亦即，當樹脂正在硬化時），當試圖形成一 含有作為甲醛捕捉劑之有機胺基化合物之層時，便會有 問題產生。 詳而言之，形成胺基甲酯鍵之前的異氰酸根（即， 未反應的異氰酸根）會與有機胺基化合物中的胺反應，而 生成一單獨的胺基甲酯分子。這不僅會阻礙甲链的捕 捉，而且會阻礙形成保護層之聚胺基甲酯基樹脂的硬 本紙張尺度適用中國國家標準（CNS ) Α4说格（210Χ297公釐） (請Α'閱讀背面之注意事項#填寫本頁) 、17 412482 Μ ____ Β7 五、發明説明（14) ~ ~ 化。結果使得裝飾片的表面不能得到所需的耐磨耗性和 耐化學性，而且也不能得到所需的基片和裝飾層之間的 點著強度。 在裝韩片中，其在基片上所形成的裝飾層和保護 層之至少一者是由樹脂所製成的，而此樹脂會藉由異氰 酸根而形成一胺基甲酯鍵，則即使含有一有機胺基化合 物的一曱醛捕捉層是預先形成在基片上的，也會有同樣 的問題發生。 經濟部中央標準局貝工消費合作社印製 為了解決這個問題，對於在一基片之上形成含有有 機胺基化合物之甲酿捕捉劑的一裝飾片，以及對於在基 片表面上形成樹脂之裝飾層或保護層的一裝飾片，而此 樹脂會藉由異氰酸根而形成一胺基甲酯鍵，此兩種裝飾 片可以下述之方式製造。首先’在基片的一側上形成裝 飾層’然後對於整個裝飾層的表面形成保護層；接著， 用來形成至少裝飾裝飾層或保護層的樹脂（藉由異氰酸 根而形成胺基甲醋鍵）經由乾加熱成熟（dry_heat maturing) 或其他方式以實質上去除未反應的異氰酸根；接著，在 基片的另一侧形成含有有機胺基化合物的甲搭捕捉 層。以此方式，可得到一裝飾片，其具有甲醛捕捉能力， 並且可得到由完全硬化之聚胺基甲酯基樹脂所製成的 足夠耐磨耗性及抗化學性的保護層，或穩固地接合在基 片上的裝飾層。 接著’參考第6至19圖’以下將敘述依據本發明 的方法，藉由將含有甲醛捕捉劑之一片材接合在一基板 本紙浪尺度適用中國國家標準（CNS ) Λ4現格（210X297公嫠） ----- -----B7 五、發明説明（15) 一 〜一 上而得到裝飾板。 ‘ 一基板為以下種類的基板時，會釋出甲醛： (1) 一板材，其是由會釋出甲醛的一樹脂所製 的； (2) —木材合板（包括所謂的接合木材（b〇nded wood)) ’其中會釋出樹脂的樹脂是用作積層間接著劑； (3) —顆粒板或木質纖維板（如MDF)，其中會釋出 甲醛的樹脂是用作一固定劑：或 (4) 一板材，其是由以一甲醛釋出樹脂來捏合或浸 潰一纖維物質而製得的。 會釋出甲醛的樹脂包括酚樹脂，其由酚和甲醛的縮 合聚合反應而得；尿素樹脂（或尿素-f醛樹脂），其由聚 合尿素和甲醛而得；胺基醇酸樹脂，其由將三聚氰胺樹 脂、尿素樹脂、胍胺（guanamine)樹脂、或其他至醇酸樹 脂、三聚氰胺樹脂、和其他。 甲酸之所以會存在於一基板中主要是因為 (1) 在形成樹脂之後，未反應而殘留； 經濟部中央標準局負工消費合作社印餐 (2) 在樹脂之硬化反應時（在施以熱和壓力之下）而 釋出； (3) 因為樹脂之自然分解而產生；或 (4) 被樹脂之外的物質（如木材或紙）所捕捉。 亦即，原本存在於一樹脂基物質中的甲醛，會漸漸 地釋出，最後完全釋出，除非有以某種方式防止此釋 出。 18 本紙張尺度適用中國國家標準（CNS ) 規格（210X297公釐） 4i2482 A7 _____B7 五、發明説明（~~~~-- 木材合板、顆粒板、及木質纖維板是由一般使用的 材材所製成的，如日本橡木、杉木、松木、常青橡木、 讀帽、柳安木、或袖木。關於用來與甲搭釋出樹脂捏 if使_ ’如無木材成份紙、 牛皮紙、鈦紙、或曰本紙；或無機纖維，如玻璃纖維' 碳纖維、或石綿；或有機纖維之編織的或無編織的織 物，如麻、綿、或維尼龍；或甚至不連續的纖維，由將 上述之無機或有機纖維切成一至十毫長而得。所謂的 FRP是由將一種或多種這些纖維物質與樹脂捏合或浸 潰，並硬化此混合物而得的。 將一裝飾片接合在一基板上的方式’最簡單的是， 使用一壓親（pressing roll) ’將前者以一接著層而壓在後 者之上。然而，可以任何其他接合技術來接合。 第6圖顯示本發明第六具體實施例之裝飾板1〇1的 載面圖。此裝飾板101是藉由在其間的接著層u而將 先前所述之第二具體實施例的片材52接合在基板1〇的 頂面上而得。片材52接合在基板1〇上的方式是，甲醛 捕捉層3面向基板10。 經濟部中央標準局員工消費合作社印製 -------：---装------訂 (請七閱讀背面之注意事項再填寫本頁) 第7圖顯示本發明第七具體實施例之裝飾板1〇2的 載面圖。此裝飾板102是藉由在其間的接著層u而將 第二具體實施例的裝飾片53接合在基板1〇的頂面上而 得。捕捉層3面向基板1〇,且裝飾層4面向外a 第8圖顯示本發明第八具體實施例之裝飾板丨〇3的 載面圖。此裝飾板103是藉由在其間的接著層u而將 19 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公4 ) A7 _ B7 _ 五、發明説明（17) ~~~ 第三具體實施例的裝飾片53接合在基板10的項面上， 且藉由其間接著層π而將第二具體實施例之片材52接 合在基板10的底面而得。藉由將含有甲醛捕捉劑的片 材接合至一基板的頂面和底面上，可使甲醛捕捉效果加 倍’於是可更有效地避免甲醛自基板10中的釋出。 第9圖顯示本發明第九具體實施例之裝飾板1〇4的 載面圖。此裝飾板104與上述裝飾板1〇3不同之處只在 於接合在基板10之底面上的成份不同。詳而言之，接 合在基板10之底面的片材55,具有形成在其表面上的 裝飾層4’且在裝飾層4的整個表面上，有一保護層7 形成以保護裝飾層4。結果，裝飾片55的最頂層是保護 層7。 經濟部中央標準局員工消費合作社印製 ------^---d — > · (讀七閱讀背面之注意事項再填寫本頁) 第10圖顯示本發明第十具體實施例之裝飾板1〇5 的載面圖。此裝飾板105與上述裝飾板1〇3不同之處只 在於接合在基板10之底面上的成份不同。詳而言之， 接合在基板1〇之底面的片材56包括三層，即，熱塑性 樹脂層12’其具有低甲醛通透性，以及兩片積層紙，分 別接合在熱塑性樹脂層12的兩側。關於具有低甲醛通 透性的熱塑性樹脂而言，可以使用聚烯烴基樹脂，如聚 乙稀、聚丙烯、乙烯-乙酸乙烯酯共聚物、氯乙烯樹脂、 聚酯基樹脂、聚醯胺基樹脂、或其他。 三層的積層是藉由將紙基片材13接合在熱塑性樹 脂層12上而得，可使用接著劑或加熱而不使用接著劑， 或者’藉由擠壓積層法，即，將一熔融的熱塑性樹脂擠 20 本紙張尺度適用巾®畔轉（CNS)如規格（2!(}><297公髮） 412482 •s. A7 _____B7 五、發明説明（u) 壓於兩紙基片材13之間’藉此形成在其間之熱塑性樹 脂，依熱塑性樹脂層12的材質而定。在此具體實施例 中，熱塑性樹脂層12是由將熔融聚乙烯樹脂擠壓積層 於紙基片材13之間而形成。 裝飾板105之頂側有會捕捉甲醛的裝飾片53，其 底侧有低甲藤通透性的片材56。結果，裝飾板1 〇5可更 有效地防止甲酿的釋出。此外，由於熱塑性樹脂層12 不透濕氣，因此裝飾板105可避免因基板1〇吸收及釋 出濕氣所造成的基板10的彎曲。在片材56之基板1〇 側的積層紙13上再提供含有甲醛捕捉劑之層，可更提 高甲醛捕捉效果。 第11圖顯示本發明第Ί 具體實施例之裝飾板 106的載面圖。此裝飾板106是藉由在其間的接著層u 而將第五具體實施例的裝飾片55接合在基板1〇的頂面 上。如前所述，裝飾層4包括固體墨水層5和圖案化的 墨水層6,並含有甲醛捕捉劑。 經濟部中央標準局貝工消費合作社印掣 ^^^1 ^^^^1 ^^^^1 ^^^^1 ^i^iB m· BBC n^i ml ^^^^1-- J. • IT (請七鬩讀背面之注意事項再填寫本頁) 第12圖顯示本發明第十二具體實施例之裝你板 107的載面圖。此裝飾板1〇7使用裝飾片57，其是由對 於上述之裝飾片55之裝飾層4的整個表面上形成一保 護層7而得。 第13圖顯示本發明第十三具體實施例之裝飾板 108的載面圖。裝飾板1〇8與第11具體實施例的裝飾板 106不同之處在於裝飾片58之成份與裝飾片55不同。 詳而言之’裝飾片58具有一透明基片1，並且在基片1 21 本紙張尺度適用中國國家標準{ CNS ) A4規格（210X297公釐） 經濟部中央標隼局員工消費合作社印製 A7 s_____ B7__ 五、發明説明（19) 的頂侧和底側都有含曱醛捕捉劑之溶劑基墨水之裝飾 層4、6。結果，此裝飾板108比裝飾板1〇6可捕捉更多 的曱搭’於是可經由其頂面而降低甲醛的釋出。此外， 此裝飾板108因具有不同深度的裝飾層4和6，因此可 形成三度空間的圖案。 第14圖顯示本發明第十四具體實施例之裝飾板 109的載面圖。此裝飾板1〇9是藉由其間之接著層^， 將上述之具有低甲搭通透性的片材56接合在第十二具 體實施例之裝飾板107之基板1〇的底面上而得的。此 裝飾板109’像第十具體實施例之裝飾板1〇5 一樣，可 非常有效地避免甲醛的釋出，且可避免因基板1〇吸收 及釋出濕氣而造成的基板的彎曲。 第15圖顯示本發明第十五具體實施例之裝飾板 110的載面圖。此裝飾板110是由將不含有甲醛捕捉劑 之裝飾片59接合在基板1〇的頂面上，及將含有甲酿 捕捉劑之一裝飾片60接合在基板1〇的底面上而得的。 裝飾片59包括一基片丨a，其由具低甲醛通透性的一合 成樹脂所製成；以及一裝飾層9,其形成於基片la的頂 側。由基板10所釋出的甲醛，在頂面上可由具低甲醛 通透性的裝飾片59所阻擋，而在底面上可由在片材6〇 中所含有的甲醛捕捉劑而捕捉及吸收。結果，只有些微 量的甲醛會釋放到大氣中。 第16圖顯示本發明第十六具體實施例之裝飾板 1Π的載面圖。不接合上述裝飾板110的裝飾片6〇,裝 22 本紙張尺度適用中) M規格（-21〇心7公後 ----- (諳4?閱讀背面之注意事項再填寫本頁) i-·*衣- 訂 412482 A7 I------ B7 五、發明説明（20) 飾板111是由將第二具體實施例之雙層片材52接合在 一基板10上而得。片材52使用具有高甲醛通透性的紙 基基片。雖然圖示之捕捉層3是面向基板的，但片材52 的接合在基板上的方式也可以是使得捕捉層3向外，或 在基片1的兩侧都形成捕捉層3。 第17圖顯示本發明第十七具體實施例之裝飾板 112的載面圖。裝飾板112與上述之裝飾板ηι不同之 處在於其不使用片材52’而使用一甲醛捕捉片61，其 中之基片la是由具低曱醛通透性的合成樹脂所製成 的。捕捉層3面向基板1〇。片材61不僅會捕捉甲醛， 且和片材59 —樣以同樣的方式避免甲醛的通透。結果， 此裝飾板112只釋放出些微量的甲醛。此外，裝飾板U2 在頂面和底面均不透濕氣，因此裝飾板1ί2可更有效地 避免基板的脊曲。 經濟部中央標準局員工消費合作社印裝 - I I - 1- » - - - -—1 I is !- I - I m ' T - 1-5 z- (請it*閱讀背面之注意事項再填寫本頁) 第18圖顯示本發明第十八具體實施例之裝飾板 U3的載面圖。此裝飾板ι13與具體實施例十七之裝飾 扳112的不同之處在於，所使用的甲醛捕捉層62的基 片包括二層’即’具有低曱經通透性的一熱塑性樹脂層 12,以及接合在熱塑性樹脂層12之兩側的兩紙基片13。 和裝飾板112相同的’捕捉層3是在具低甲搭參透性之 片材56的基板10側上形成的。因寫片材56資兩側均有 紙基；i 13,捕捉層3可容易形成及接合於基板上。 此外’由於裝飾板113的底面有紙基片，其可更穩固地 接合於另一個物品上。 23 本紙張尺度適财關家料（CNS ) 21〇^< 297公釐) ----- 41248¾ A7 _______B7 五、發明説明（21) ~ 第19圖顯示本發明第十九具體實施例之裝飾板 114的載面圖。此裝飾板114是藉由將不含甲醛捕捉劑 的一裝飾片59接合於一基板之頂面上，及將含有甲搭 捕捉劑之一裝飾片51接合於基板之底面上而得。裝飾 片51包括一紙基基片1和含有曱酸捕捉劑的一裝飾層 2。如此’像裝飾板114這樣兩面都有裝飾層的裝飾板， 可適合於作為眼睛所見到的物品的材料，如廚房流理台 的門。 在以上所述之所有具體實施例中，裝飾板的侧面都 沒有作曱酿捕捉的處理，因此曱酸會從側面釋出。然 而’由於側面的面積遠小於頂面和底面的面積，因此只 會釋出微量的甲越·。此外’甲搭的釋出相當慢，因此大 部分的甲越可被大面積中所分佈的甲醛捕捉劑所捕 捉。結果’只有微量的甲經會釋放到大氣中。也可以在 側面上提供具底甲搭滲透性之層，或曱醛捕捉層，或具 有上述層之片材。藉此，可更降低由基板釋放到大氣中 的甲醛’於是可得到幾乎沒有甲醛味的一裝飾板。 經濟部中央標準局員工消費合作社印製 ^—^1 ^^^1 ^^^1 ^^^1 ^^^1 ^^^1 ^^^1 - m V .， - 1 *vs - - (諳t閱讀背面之注意事項再填{"本頁} 即使裝飾片接合在基板上是使用會產生曱酷的一 接著劑時，甲醛捕捉劑也會某種程度地捕捉所產生的甲 醛。然而，除非有必要’最好是使用不會產生甲醛的接 著劑。 若有需要，除了具體實施例之裝飾板的甲醛捕捉片 和基板之外’亦可添加抗菌劑和防黴菌的裝飾板。 以下’顯示依據本發明之裝飾板的具體例子，及其甲醛 24 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） A7 B7 五、發明説明（22) ~~ 捕捉效果的試驗結果。 實施例1 將一甲搭捕捉層形成於30 g/m2之強化積層紙 ("HP-30"’ 由 Tenma Tokushu Seishi 公司所製造）的頂側。 以此方式，得到一曱醛捕捉片。將含有一曱搭捕捉劑 ("FC-18-6"，由Miki Riken公司所製造）之溶液，以輥塗 佈機塗佈於積層紙片的表面上，而形成捕捉層，如此當 乾燥時’捕捉層重5 g/m2。接著，使用乙酸乙烯基乳化 接著劑’將上述之甲醛捕捉片接合於木材基之木材合板 所製成的一基板上’使得捕捉層面向此木材基之木材合 板’該木材合板是以一尿素樹脂基接著劑將柳安木板接 合而成的。如此’而得到含有一甲醛捕捉劑的一裝飾 板。 實施例2 經濟部中央標準局員工消費合作社印製 將一甲醛捕捉層形成於30 g/m2之強化積層紙 ('ΉΡ-3〇'’ ’ 由 Tenma Tokushu Seishi 公司所製造）的頂側。 以此方式’得到一甲醛捕捉片。將含有一甲醛捕捉劑 ("FC-18-6” ’由Miki Riken公司所製造）之溶液，以輥塗 佈機塗佈於積層紙片的表面上，而形成捕捉層，如此當 乾燥時’捕捉層重5 g/m2。藉由照相凹板技術，以纖維 素基墨水（"SAM"，由Showa Inku Kogyosho公司所製造） 將一木材顆粒的圖案印刷在上述甲醛捕捉片的底面上 25 本紙張尺度適用中關家榡準（CNS〉M規格（2〗0><297公楚） ^<482 A7 -____B7 五、發明説明（23) 。以此方式，得到-裝飾片。接著，使用乙酸乙稀基乳 化接著劑，將上述之裝飾片接合於木材基之木材合板所 製成的一基板之一面上，將上述之曱醛捕捉片接合於此 基板之另一面上，使得捕捉層面向此木材基之木材合 板，該木材合板是以一尿素樹脂基接著劑將柳安木板接 合而成的。如此，而得到含有一曱醛捕捉劑的一裝飾 板。 實施例3 經濟部中央標準扃員工消費合作社印製 I n n I - ------ - - « (請it-聞讀背面之注意事項再填寫本I ) 將一甲醛捕捉層形成於30 g/m2之強化積層紙 (’ΉΡ-30” ’ 由 Tenma Tokushu Seishi 公司所製造）的頂側。 以此方式’得到一曱醛捕捉片。將由混合一甲醛捕捉劑 ("FC-18_6" ’由Miki Riken公司所製造）和一丙烯酸類樹 脂基固定劑和甲醇所製成之墨水，藉由照相凹板技術塗 佈於積層紙片的表面上，以形成捕捉層，如此當乾燥 時，捕捉層重4 g/m2。接著，使用乙酸乙烯基乳化接著 劑’將上述之裝飾片接合於木材基之木材合板所製成的 一基板之一面上，將上述之甲醛捕捉片接合於此基板之 另一面上，使得捕捉層面向此木材基之木材合板，該木 材合板是以一尿素樹脂基接著劑將柳安木板接合而成 的。如此，而得到含有一甲搭捕捉劑的一裝飾板。 比較實施例1 藉由照相凹板技術，以纖維基墨水（"SAM"，由 本紙張尺度適用中國國家標準（CNS ) A4規格（2iOX297公釐） 412482 A7 ___B7____ 五、發明説明（24) '" -----..--- I V. Description of the invention (u) A mixture of more than one type of capture agent can be used. It can be used after the capture agent is kneaded with a fixing agent such as a nitrocellulose / alkyd resin, a cellulose-based resin, a vinyl resin, a polyester-based resin, or a polyamide-based resin. In this case, an appropriate amount of an organic solvent such as ethanol, ethyl acetate, or toluene may be added to the capturing agent and the fixing agent, and other additives may be added if necessary. Even when a water-soluble formaldehyde trapping agent is used, it can be kneaded with a wide range of fixing agents by using powders of inorganic substances such as silica, talc, clay, activated carbon, zeolite, or sepiolite as a carrier. The formaldehyde capture agent can be impregnated into the decorative sheet by: (1) coating, impregnating, or kneading the top, bottom, or both sides of the substrate with a capture agent; (2) capturing Adding agent to the ink used to form an ink decorative layer, if there is such a decorative layer; (3) adding a capturing agent to the initial layer; (4) adding a capturing agent to the surface protective layer; or (5) combining the above methods (1) to (two or more of the sentences. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs {Please read the precautions on the back before filling out this page) Figure 2 shows the second specific embodiment of the present invention. Section map. This sheet 52 is composed of a substrate 1 and a formaldehyde capture layer (hereinafter simply referred to as a capture layer) 3 bonded to the top of the substrate 1. The capture layer 3 is formed by applying a solution containing a formaldehyde trapping agent to the surface of the substrate 1. The coating may be performed by a general method such as gravure coating, knife coating, or the like. Regarding the substrate 1 ', the paper 52 is bonded to a substrate. 14 This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X297 male t > Buckle 482 Α7 B7. V. The description of the invention (12) determines the use of paper. Substrate or synthetic resin substrate. For example, when the sheet 52 is bonded to a substrate and the trap layer 3 faces the substrate, it is effective whether the substrate i is made of a paper substrate or a synthetic resin substrate. On the contrary, when the sheet material 52 is bonded to a substrate and the capture layer 3 faces outward, it is better to use a paper-based substrate having good gas permeability. This is because if the For synthetic resin substrates with low permeability, the formaldehyde released from the substrate cannot reach the capture layer 3, so it cannot be effectively captured by the capture layer 3. In particular, a laminated paper of 20 to 80 g / m2 is preferred, not only Because it is not expensive, and because even if the solution is water-based, because it has good gas permeability, it can be easily coated with a solution containing a formaldehyde trapping agent. However, even when using a synthetic resin-based substrate, And sheet 52 is joined The method on a substrate is that the capture layer 3 faces outward, and the sheet material 52 can capture formaldehyde in the atmosphere. For example, when the sheet material 52 is bonded to a substrate that will release a pathway from its edge surface, the sheet material 52 Quickly capture the released formaldehyde. Or, when the sheet 52 is placed in a room, and the property has-a piece of furniture containing printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, which has not been processed to resist the release of formic acid- --1 n I-n-II n--n ^ 4 (read 4 'read the precautions on the back and fill in this page), the sheet 52 can capture the formaldehyde released by it, so the atmosphere can be kept clean ^ The above method of how the material of the substrate and the decorative sheet are bonded to a substrate is also applicable to the following specific embodiments. Figure 3 shows a cross-sectional view of a decorative sheet of a third specific embodiment of the present invention. This decorative sheet 53 is printed by printing a decorative layer 4 on the above 15 paper standards. It is a financial standard (CNS) A4 (2l0T297mm). It is printed by the Consumer Cooperatives of the Central Bureau of Procurement, Ministry of Economic Affairs. A7 ---____________ B7 5 、 Explanation (13) 'One " Capture of Sheet 52 The opposite side of layer 3. As for the substrate # 53 of the decoration # 53, it is preferable to use a laminated paper having the aforementioned properties and a surface smoothness suitable for printing. FIG. 4 shows a cross section of the decoration sheet 54 according to the fourth embodiment of the present invention. Fig. This decorative sheet 54 is obtained by forming a decorative layer 4 on top of the capture layer 3 of the sheet 52. Fig. 5 shows a cross-sectional view of the decorative sheet 55 of the fifth embodiment of the present invention. This decorative sheet 55 is composed of a decorative layer 4 formed on the top of a substrate i. The decorative layer 4 includes a solid ink layer and a patterned ink layer, and is formed of a formaldehyde trapping agent and a fixing agent. Solvent-based (such as ethanol-based, ethyl acetate-based, or toluene-based) inks. Generally, the multi-layer sheet containing the formaldehyde trapping agent as described above can be produced by any lamination method. It should be noted, however, that in a decorative sheet having a decorative layer and a protective layer (if necessary) on the substrate, and at least one of the decorative layer and the protective layer therein is formed by isocyanate In a decorative sheet made of a resin of an amino chain, before the resin is cured (that is, when the resin is being cured), when trying to form a layer containing an organic amine compound as a formaldehyde trapping agent , There will be problems. Specifically, the isocyanate (ie, unreacted isocyanate) before the amino methyl ester bond is formed will react with the amine in the organic amino compound to form a single amino methyl ester molecule. This will not only hinder the capture of the methyl chains, but also hinder the rigid paper size of the polyurethane-based resin that forms the protective layer. The standard of China National Standards (CNS) Α4 (210 × 297 mm) is applied. (Please read 'A' on the back Note #Fill this page), 17 412482 Μ ____ Β7 V. Description of the invention (14) ~ ~. As a result, the surface of the decorative sheet cannot obtain the required abrasion resistance and chemical resistance, and the desired spot strength between the substrate and the decorative layer cannot be obtained. In the Korean film, at least one of the decorative layer and the protective layer formed on the substrate is made of resin, and the resin will form an amino methyl ester bond through isocyanate. The same problem occurs when the mono-aldehyde capture layer containing an organic amine compound is formed on the substrate in advance. Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumer Cooperative, in order to solve this problem, a decorative sheet is formed on a substrate to contain a methyl alcohol capture agent containing an organic amine compound, and a decoration is formed to form a resin on the surface of the substrate. Layer or a protective layer of a decorative sheet, and the resin forms an amino methyl ester bond through isocyanate. These two decorative sheets can be manufactured in the following manner. First 'form a decorative layer on one side of the substrate' and then form a protective layer over the entire surface of the decorative layer; then, the resin used to form at least the decorative layer or protective layer (the aminomethyl acetate is formed by isocyanate) Bond) through dry_heat maturing or other methods to substantially remove unreacted isocyanate; then, a formaldehyde trapping layer containing an organic amine compound is formed on the other side of the substrate. In this way, a decorative sheet can be obtained, which has formaldehyde-capturing ability, and a protective layer made of a fully hardened polyurethane-based resin with sufficient abrasion resistance and chemical resistance can be obtained, or firmly A decorative layer bonded to a substrate. Next, with reference to Figures 6 to 19, the method according to the present invention will be described below. By bonding a sheet containing formaldehyde trapping agent to a substrate, the paper scale is applicable to the Chinese National Standard (CNS) Λ4 and (210X297). ) ----- ----- B7 V. Description of the invention (15) One to one to get the decorative board. '' Formaldehyde is released when a substrate is the following types of substrate: (1) a board made of a resin that releases formaldehyde; (2) wood plywood (including so-called bonded wood (b〇 nded wood)) 'The resin in which the resin is released is used as a laminating agent; (3) — particle board or wood fiber board (such as MDF), in which the resin that releases formaldehyde is used as a fixative: or ( 4) A plate made by kneading or impregnating a fibrous substance with a formaldehyde-releasing resin. Formaldehyde-releasing resins include phenol resins, which are obtained by the condensation polymerization reaction of phenol and formaldehyde; urea resins (or urea-f aldehyde resins), which are obtained by polymerizing urea and formaldehyde; amino alkyd resins, which are obtained by Melamine resin, urea resin, guanamine resin, or other alkyd resin, melamine resin, and others. The reason why formic acid exists in a substrate is mainly because (1) it remains after reacting after forming the resin; it is printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (2) during the curing reaction of the resin (while applying heat And under pressure); (3) It is caused by the natural decomposition of the resin; or (4) It is captured by substances other than resin (such as wood or paper). That is, formaldehyde, which is originally present in a resin-based substance, is gradually released and finally released completely, unless it is prevented in some way. 18 This paper size applies Chinese National Standard (CNS) specifications (210X297 mm) 4i2482 A7 _____B7 V. Description of the invention (~~~~-Wood plywood, particle board, and wood fiberboard are made of commonly used materials , Such as Japanese oak, cedar, pine, evergreen oak, reading hat, Liuanmu, or sleeve wood. Regarding the resin used to release with the nail pinch if make _ 'such as wood-free paper, kraft paper, titanium paper, or Paper; or inorganic fibers, such as glass fibers' carbon fibers, or asbestos; or woven or non-woven fabrics of organic fibers, such as hemp, cotton, or nylon; or even discontinuous fibers, made of the above-mentioned inorganic or organic The fibers are cut into one to ten millimeters. The so-called FRP is obtained by kneading or impregnating one or more of these fiber substances with a resin and hardening the mixture. The method of joining a decorative sheet to a substrate is' most Simply, a pressing roll is used to press the former onto the latter layer by layer. However, any other joining technique can be used to join. Figure 6 shows a sixth embodiment of the present invention. A side view of the decorative board 101 of this embodiment. The decorative board 101 is formed by bonding the sheet 52 of the second embodiment described above to the top surface of the substrate 10 by bonding the layer u therebetween. The way the sheet 52 is bonded to the substrate 10 is that the formaldehyde capture layer 3 faces the substrate 10. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs --Order (please read the precautions on the back and fill in this page again) Figure 7 shows a side view of the decorative board 102 of the seventh embodiment of the present invention. This decorative board 102 is formed by a bonding layer in between. u is obtained by bonding the decorative sheet 53 of the second embodiment to the top surface of the substrate 10. The capture layer 3 faces the substrate 10 and the decorative layer 4 faces a. FIG. 8 shows an eighth specific embodiment of the present invention. A decorative surface of the decorative plate 丨 〇3. This decorative plate 103 is applied to the 19 paper sizes by applying a layer u between them. The Chinese paper standard (CNS) A4 specification (210X297 male 4) A7 _ B7 _ five, Description of the Invention (17) ~~~ The decorative sheet 53 of the third embodiment is bonded to the top surface of the substrate 10, and the second tool The sheet 52 of the present embodiment is obtained by bonding the bottom surface of the substrate 10. By bonding the sheet containing the formaldehyde trapping agent to the top and bottom surfaces of a substrate, the formaldehyde trapping effect can be doubled, and can be avoided more effectively. Formaldehyde is released from the substrate 10. Fig. 9 shows a side view of a decorative plate 104 of a ninth embodiment of the present invention. The decorative plate 104 differs from the above-mentioned decorative plate 103 only in that it is bonded to the substrate The composition on the bottom surface of 10 is different. In detail, the sheet 55 bonded to the bottom surface of the substrate 10 has a decorative layer 4 'formed on the surface thereof and a protective layer 7 is formed on the entire surface of the decorative layer 4. To protect the decorative layer 4. As a result, the topmost layer of the decorative sheet 55 is the protective layer 7. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ------ ^ --- d-> (Read the notes on the back of the reading and fill in this page) Figure 10 shows the tenth embodiment of the present invention. Side view of the decorative board 105. This decorative plate 105 differs from the above-mentioned decorative plate 103 only in that the components bonded to the bottom surface of the substrate 10 are different. In detail, the sheet 56 bonded to the bottom surface of the substrate 10 includes three layers, namely, a thermoplastic resin layer 12 ′ having low formaldehyde permeability, and two sheets of laminated paper, which are bonded to two of the thermoplastic resin layer 12, respectively. side. As for the thermoplastic resin having low formaldehyde permeability, polyolefin-based resins such as polyethylene, polypropylene, ethylene-vinyl acetate copolymer, vinyl chloride resin, polyester-based resin, and polyamide-based resin can be used. ,or others. The three-layer laminate is obtained by joining the paper-based sheet 13 to the thermoplastic resin layer 12, and can use an adhesive or heat without using an adhesive, or 'by extrusion lamination, that is, a melted Thermoplastic resin extruded 20 This paper is suitable for paper towels (CNS) such as specifications (2! (} ≫ < 297) 412482 • s. A7 _____B7 V. Description of the invention (u) Pressed on two paper base sheets The thermoplastic resin formed therebetween depends on the material of the thermoplastic resin layer 12. In this specific embodiment, the thermoplastic resin layer 12 is formed by extruding a molten polyethylene resin onto a paper-based sheet 13 On the top side of the decorative plate 105, there is a decorative sheet 53 that captures formaldehyde, and on the bottom side, there is a sheet material with low permeability of rattan. As a result, the decorative plate 105 can more effectively prevent the release of nails. In addition, since the thermoplastic resin layer 12 is impermeable to moisture, the decorative plate 105 can avoid bending of the substrate 10 caused by the substrate 10 absorbing and releasing moisture. The laminated paper on the substrate 10 side of the sheet 56 A layer containing formaldehyde trapping agent is provided on 13 to further improve the formaldehyde trapping effect. Fig. 11 shows a side view of the decorative plate 106 of the first embodiment of the present invention. The decorative plate 106 is a substrate 1 bonded to the decorative plate 55 of the fifth embodiment by a layer u therebetween. 〇 On the top surface. As mentioned before, the decorative layer 4 includes a solid ink layer 5 and a patterned ink layer 6 and contains a formaldehyde trapping agent. Printed by the Bayer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^^^ 1 ^^ ^^ 1 ^^^^ 1 ^^^^ 1 ^ i ^ iB m · BBC n ^ i ml ^^^^ 1-- J. • IT (please read the precautions on the back and fill in this page) FIG. 12 is a side view of a twelfth embodiment of the present invention. The decorative plate 107 uses a decorative sheet 57 formed on the entire surface of the decorative layer 4 for the decorative sheet 55 described above. A protective layer 7 is obtained. Fig. 13 shows a side view of the decorative plate 108 of the thirteenth embodiment of the present invention. The decorative plate 108 differs from the decorative plate 106 of the eleventh embodiment in the decorative sheet 58. Its composition is different from that of the decorative sheet 55. In detail, the 'decorative sheet 58 has a transparent substrate 1, and the paper size applies to the Chinese National Standard {CNS) A4. (210X297 mm) A7 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs s_____ B7__ 5. The top and bottom sides of the description of the invention (19) have a decorative layer of solvent-based ink containing an aldol trapping agent 4, 6 . As a result, the decorative board 108 can capture more laps' than the decorative board 106, so that the release of formaldehyde can be reduced through its top surface. In addition, the decorative plate 108 can form a three-dimensional pattern because the decorative layers 4 and 6 have different depths. Fig. 14 is a sectional view showing a decorative plate 109 according to a fourteenth embodiment of the present invention. This decorative board 109 is obtained by bonding the above-mentioned sheet 56 with low nail permeability to the bottom surface of the substrate 10 of the decorative board 107 of the twelfth specific embodiment through an adhesive layer therebetween. of. This decorative plate 109 ', like the decorative plate 105 of the tenth embodiment, can very effectively prevent the release of formaldehyde, and can prevent the substrate from bending due to the substrate 10 absorbing and releasing moisture. Fig. 15 is a sectional view showing a decorative plate 110 according to a fifteenth embodiment of the present invention. This decorative board 110 is obtained by bonding a decorative sheet 59 not containing a formaldehyde trapping agent on the top surface of the substrate 10 and a decorative sheet 60 containing a formazan capturing agent on the bottom surface of the substrate 10. The decorative sheet 59 includes a substrate sheet a made of a synthetic resin having low formaldehyde permeability, and a decorative layer 9 formed on the top side of the substrate sheet la. The formaldehyde released from the substrate 10 can be blocked on the top surface by a decorative sheet 59 having low formaldehyde permeability, and can be captured and absorbed on the bottom surface by a formaldehyde trapping agent contained in the sheet 60. As a result, only a small amount of formaldehyde is released into the atmosphere. Fig. 16 is a sectional view showing a decorative plate 1Π according to a sixteenth embodiment of the present invention. The decorative sheet 60, which does not join the above-mentioned decorative plate 110, is installed in 22 paper sizes. M specifications (-21 ° heart 7 male -------- (谙 4? Read the precautions on the back and fill out this page) i -· * 衣-Order 412482 A7 I ------ B7 V. Description of the invention (20) The decorative panel 111 is obtained by joining the two-layer sheet 52 of the second embodiment on a substrate 10. Sheet The paper 52 uses a paper-based substrate with high formaldehyde permeability. Although the capture layer 3 shown in the figure is facing the substrate, the method of bonding the sheet 52 to the substrate may also be such that the capture layer 3 faces outward, or The capture layer 3 is formed on both sides of the substrate 1. Fig. 17 shows a side view of the decorative plate 112 of the seventeenth embodiment of the present invention. The decorative plate 112 differs from the above-mentioned decorative plate in that it does not use a sheet A formaldehyde capture sheet 61 is used as the material 52 ', wherein the substrate la is made of a synthetic resin with low permeability to formaldehyde. The capture layer 3 faces the substrate 10. The sheet 61 not only captures formaldehyde, but also In the same way as sheet 59, the penetration of formaldehyde is avoided in the same way. As a result, the decorative plate 112 only releases a small amount of formaldehyde. In addition, the decoration The board U2 is impermeable to moisture on the top and bottom, so the decorative board 1ί2 can more effectively avoid the ridge of the substrate. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs-II-1- »-----1 I is!-I-I m 'T-1-5 z- (Please * read the notes on the back and fill in this page again.) Figure 18 shows a side view of the decorative plate U3 of the eighteenth embodiment of the present invention. This decorative plate ι13 is different from the decorative plate 112 of the seventeenth embodiment in that the substrate of the formaldehyde capture layer 62 used includes two layers of a thermoplastic resin layer 12 having low permeability. And two paper substrates 13 bonded to both sides of the thermoplastic resin layer 12. The 'capturing layer 3', which is the same as the decorative plate 112, is formed on the substrate 10 side of the sheet 56 having low nail permeability. There are paper bases on both sides of the material 56; i 13, the capture layer 3 can be easily formed and bonded to the substrate. In addition, because the bottom surface of the decorative plate 113 has a paper substrate, it can be more firmly bonded to another article. 23 This paper is suitable for household wealth (CNS) 21〇 ^ < 297 mm) ----- 41248¾ A7 _______B7 V. Invention theory Ming (21) to Fig. 19 are sectional views showing the decorative plate 114 of the nineteenth embodiment of the present invention. The decorative plate 114 is obtained by bonding a decorative sheet 59 containing no formaldehyde trapping agent to the top surface of a substrate, and bonding a decorative sheet 51 containing a nail trapping agent to the bottom surface of the substrate. The decorative sheet 51 includes a paper-based substrate 1 and a decorative layer 2 containing an acid scavenger. In this way, a decorative board with a decorative layer on both sides, such as the decorative board 114, can be suitable as a material for articles seen by the eyes, such as a door of a kitchen counter. In all the specific embodiments described above, the side of the decorative plate is not treated for simmering, so the osmic acid is released from the side. However, since the area of the side surface is much smaller than that of the top surface and the bottom surface, only a small amount of Jiayue · will be released. In addition, the release of the nail is quite slow, so most of the nails can be captured by the formaldehyde trapping agent distributed in a large area. As a result, only a small amount of nail polish will be released into the atmosphere. It is also possible to provide a base layer with a permeable layer on the side, or a formaldehyde capture layer, or a sheet having the above layer. Thereby, the formaldehyde 'released from the substrate into the atmosphere can be further reduced, so that a decorative panel having almost no formaldehyde smell can be obtained. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ^ — ^ 1 ^^^ 1 ^^^ 1 ^^^ 1 ^^^ 1 ^^^ 1 ^^^ 1-m V.,-1 * vs--(阅读 t read the precautions on the back of the page and fill in {" this page} Even if the decorative sheet is bonded to the substrate using an adhesive that generates 曱, the formaldehyde trapping agent will capture the generated formaldehyde to some extent. However Unless necessary 'It is best to use an adhesive that does not generate formaldehyde. If necessary, in addition to the formaldehyde capture sheet and substrate of the decorative plate of the specific embodiment', antibacterial agents and mold resistant decorative plates can also be added. The following 'Show specific examples of decorative boards according to the present invention, and their formaldehyde 24 This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) A7 B7 V. Description of the invention (22) ~~ Test results of capture effect Example 1 A monolayer capture layer was formed on the top side of a 30 g / m2 reinforced laminated paper (" HP-30 " manufactured by Tenma Tokushu Seishi). In this way, a formaldehyde capture sheet was obtained. . Will contain a catcher (" FC-18-6 " by Miki Riken) Solution), coated on the surface of the laminated paper with a roll coater to form a capture layer, so that the 'capture layer weighs 5 g / m2 when dried. Then, use the acetic acid vinyl emulsion adhesive' to convert the above The formaldehyde capture sheet is bonded to a substrate made of a wood-based wood plywood such that the capture layer faces the wood-based wood plywood. The wood plywood is joined by a Liu resin board with a urea resin-based adhesive. 'And a decorative board containing a formaldehyde trapping agent was obtained. Example 2 Printed by a consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, a formaldehyde trapping layer formed on a reinforced laminated paper (' HP-3-0 ') formed at 30 g / m2 (Made by the company Tenma Tokushu Seishi). In this way, a formaldehyde capture sheet was obtained. A solution containing a formaldehyde capture agent (" FC-18-6 "'made by Miki Riken) was rolled with a roller. The coater is applied to the surface of the laminated paper sheet to form a capture layer, so that when dry, the 'capture layer weighs 5 g / m2. By photogravure technology, cellulose-based ink (" SAM " Inku Kog Manufactured by yosho company) A pattern of wood particles is printed on the bottom surface of the above formaldehyde capture sheet. 25 paper standards are applicable to Zhongguanjia standard (CNS> M specification (2 〖0 > < 297 公 楚) ^ < 482 A7 -____ B7 V. Description of the invention (23). In this way, a decorative sheet is obtained. Then, the above decorative sheet is bonded to a substrate made of wood-based wood plywood using an ethyl acetate-based emulsifying adhesive. On one side, the above-mentioned formaldehyde capture sheet is bonded to the other side of the substrate so that the capture layer faces the wood-based wood plywood, which is formed by joining a Liuan wood board with a urea resin-based adhesive. In this way, a decorative board containing an acetaldehyde trapping agent was obtained. Example 3 Printed by the Central Standard of the Ministry of Economic Affairs and printed by an employee consumer cooperative I nn I---------«(Please read the notes on the back and fill in this I) Form a formaldehyde capture layer at 30 g / m2 of the top layer of reinforced laminated paper ('HP-30' 'made by Tenma Tokushu Seishi). In this way' a formaldehyde capture sheet was obtained. A formaldehyde capture agent (" FC-18_6 " ' (Manufactured by Miki Riken) and an acrylic resin-based fixing agent and methanol are applied on the surface of the laminated paper by photogravure technology to form a capture layer, so that when dry, the capture layer The weight is 4 g / m2. Next, the above-mentioned decorative sheet is bonded to one side of a substrate made of a wood-based wood plywood using an acetate vinyl emulsifying adhesive, and the above-mentioned formaldehyde capture sheet is bonded to another On one side, the capture layer faces the wood-based wood plywood, which is formed by joining a Liuan wood board with a urea resin-based adhesive. In this way, a decorative board containing a preform capture agent is obtained. Implement 1 by gravure techniques, a fiber-based ink (" SAM ", by the China National Standard paper suitable scale (CNS) A4 size (2iOX297 mm) 412482 A7 ___B7____ V. invention is described in (24) '
Showa Inku Kogyosho公司所製造），將木材顆粒的圖案 印刷於30 g/m2之強化積層紙片（”hp_30，i，由丁如邮 Tokushu Seishi公司所製造）的頂側。以此方式，得到一 裝飾片。接著’使用乙酸乙烯基乳化接著劑，將上述之 裝飾片接合於木材基之木材合板所製成的一基板之— 面上，該木材合板是以一尿素樹脂基接著劑將柳安木板 接合而成的。如此而得到一裝飾板。 試驗1 經濟部中央標隼局員工消費合作社印製 ^^^^1 ^^^^1 n ^^^^1 ^^^^1 ^^^^1 ^^^^1 ^^^^1 ^11^1-1* i諳4'閱讀背面之注意事項再填寫本頁} 從實施例1至3和比較實施例1之裝飾板中，各切 出5 cm寬xl5 cm長的12個試片。每個板的12個試片 分別置於24 cm的乾燥器中，在乾燥器底部的中央，置 有含300 ml蒸餾水的小盤。在20°C下，使試片於乾燥 器中放置24小時’以乙酿丙酮比色法測量蒸餾水中所 吸收的甲醛濃度。試驗結果顯示，對於實施例1的裝飾 板’蒸館水吸收2·9 mg/1的甲醛，對於實施例2的裝飾 板’蒸顧水吸收0.7 mgM的甲搭，對於實施例3的裝飾 板’蒸館水吸收1.0 mg/1的曱醒，對於比較實施例1的 裝飾板，蒸德水吸收5.0 mg/1的甲酸。 由試驗結果可知，可藉由將含有一甲醛捕捉劑的一 片材接合在基板的一面上，而有效降低由基板中釋出甲 醛；而藉由將含有一甲醛捕捉劑之片材接合在基板之頂 面和底面，則可捕捉更多的甲醛- 27 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 B7 五、發明説明（25) 實施例4 藉由照相凹板技術，使用硝化纖維基墨水，將木材 顆粒的圖案印刷在30 g/m2積層紙的一片材的一側，且， 對於此木材顆粒圖案層的整個表面，以照相凹板技術， 以一兩部分硬化聚胺基甲酯樹脂之塗佈流體來印刷此 表面，以形成一表面保護層。在40°C下成熟48小時之 後，藉由以一硝化纖維基塗佈流體來印刷該表面，以在 上述積層紙片之另一側上形成一甲醛捕捉層。此硝化纖 維基塗佈流體含有10%與黏土混合的哌啶，哌啶是—種 飽和的環狀（六員環）二級胺，當作一甲醛捕捉劑。以此 方式’可得到含有一甲醛捕捉劑的一裝飾片。 比較實施例2 藉由照相凹板技術，使用硝化纖維基墨水，將木材 顆粒的圖案印刷在30 g/m2積層紙的一片材的一側，且， 對於此木材顆粒圖案層的整個表面，以照相凹板技術， 以一兩部分硬化聚胺基甲酯樹脂之塗佈流體來印刷此 表面’以形成一表面保護層。接著，立刻藉由以一硝化 纖維基塗佈流體來印刷該表面，以在上述積層紙片之另 —側上形成一甲醛捕捉層。此硝化纖維基塗佈流體含有 10%與黏土混合的π底咬，β底。定是一種飽和的環狀（六員環） 二級胺’當作一甲醛捕捉劑。以此方式，可得到含有一 甲醛捕捉劑的一裝飾片。 28 本紙张尺度適用中國國家標準（CNS ) A4規掊（210X297公釐） 讀 先* 閱 讀 背 ιδ . i 事. 項 再 填 寫 本 頁 装 訂 經濟部中央標準局員工消費合作社印製 經漪部中央標準局負工消費合作社印製 4i2482 A7 ____ B7 五、發明説明（26) 比較實施例3 藉由照相凹板技術，使用硝化纖維基墨水，將木材 顆粒的圖案印刷在3 0 g/m2積層紙的一片材的一側，且， 對於此木材顆粒圖案層的整個表面，以照相凹板技術， 以一兩部分硬化聚胺基曱酯樹脂之塗佈流體來印刷此 表面，以形成一表面保護層。以此方式而得到一裝飾 片° 試驗2 以一乙烯-乙酸乙晞酯基接著劑，將實施例4和比 較實施例2和3的裝飾片接合在2.5 mm厚的木材基木材 合材之兩側，使得具有曱醛捕捉層的表面或裝飾片之紙 表面面向木材基之木材合板，該木材合板是以一尿素樹 脂基接著劑將柳安木板接合而成的。以此方式，對於每 個裝飾片’可製造出一裝飾板。依據Japanese Agriculatural Standard所定之甲醛濃度測定法來測定每 個裝飾板。試驗結果顯示，對於實施例4的裝飾片，甲 醛濃度是2.0 mg/1的甲醛，對於比較實施例2的裝飾片， 甲醛濃度是4.0 mg/1的曱醛，對於比較實施例3的裝飾 片’甲醛濃度是5.0 mg/1的曱醛， 由試驗結果可知，在胺基甲酯硬化完成之前形成含 有胺的一甲醛捕捉層’會使得胺的甲醛捕捉效果降低， 這可藉由在胺基甲酯樹脂完全硬化之後才形成捕捉層 而得以避免。 29 本紙張尺度適用中國國家標準（CNS) Λ4規格（210χ297公釐〉 (讀先閲讀背面之注意事項再填寫本頁) —装_Showa Inku Kogyosho company), the pattern of wood particles is printed on the top side of a 30 g / m2 reinforced laminated paper sheet ("hp_30, i, manufactured by Torushu Seki Co., Ltd.). In this way, a decoration is obtained Then, using the vinyl acetate emulsion adhesive, the above-mentioned decorative sheet was bonded to one side of a substrate made of a wood-based wood plywood. The wood plywood was made of a Liuan wood board with a urea resin-based adhesive. It is made by joining. In this way, a decorative plate is obtained. Test 1 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs ^^^^ 1 ^^^^ 1 n ^^^^ 1 ^^^^ 1 ^^^^ 1 ^^^^ 1 ^^^^ 1 ^ 11 ^ 1-1 * i 谙 4 'Read the notes on the back and fill out this page} From the decorative plates of Examples 1 to 3 and Comparative Example 1, cut each Twelve test pieces of 5 cm wide by 15 cm long were produced. The 12 test pieces of each plate were placed in a 24 cm dryer, and in the center of the bottom of the dryer, a small dish containing 300 ml of distilled water was placed. At 20 The test piece was allowed to stand in a desiccator for 24 hours at ° C. The concentration of formaldehyde absorbed in distilled water was measured by the acetone colorimetry. The test results showed that For the decorative board of Example 1, the steaming hall water absorbs 2.9 mg / 1 of formaldehyde, for the decorative board of Example 2, the steaming hall water absorbs 0.7 mgM formaldehyde, and for the decorative board of Example 3, the steaming hall water Absorbed 1.0 mg / 1, and for the decorative board of Comparative Example 1, distilled water absorbed 5.0 mg / 1 formic acid. From the test results, it can be seen that a sheet containing a formaldehyde trapping agent can be bonded to the substrate. Side of the substrate, which can effectively reduce the release of formaldehyde from the substrate; and by bonding a sheet containing a formaldehyde trapping agent to the top and bottom surfaces of the substrate, more formaldehyde can be captured-27 This paper is applicable to China Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Description of the invention (25) Example 4 The pattern of wood particles was printed on a 30 g / m2 laminated paper by photogravure technology using nitrocellulose-based ink. One side of a sheet and, for the entire surface of the wood particle pattern layer, this surface is printed with a gravure technique with a two-part hardened polyurethane resin coating fluid to form a surface protection Layer. Mature at 40 ° C for 48 hours Then, the surface is printed by using a nitrocellulose-based coating fluid to form a formaldehyde capture layer on the other side of the laminated paper sheet. This nitrocellulose-based coating fluid contains 10% piperidine mixed with clay, Piperidine is a saturated cyclic (six-membered ring) secondary amine used as a formaldehyde trapping agent. In this way, a decorative sheet containing a formaldehyde trapping agent can be obtained. Comparative Example 2 Using a gravure Technology, using nitrocellulose-based ink, the pattern of wood particles is printed on one side of a sheet of 30 g / m2 laminated paper, and for the entire surface of this wood particle pattern layer, photogravure technology is used, one or two A coating fluid of a partially hardened polyurethane resin is used to print this surface to form a surface protective layer. Then, the surface was immediately printed by using a nitrocellulose-based coating fluid to form a formaldehyde capture layer on the other side of the laminated paper sheet. This nitrocellulose-based coating fluid contains 10% π bottom bite and β bottom mixed with clay. It must be a saturated cyclic (six-membered ring) secondary amine 'as a formaldehyde trapping agent. In this way, a decorative sheet containing a formaldehyde trapping agent can be obtained. 28 This paper size applies the Chinese National Standard (CNS) A4 Regulation (210X297mm) Read first * Read the back δ. I matters. Please fill in this page and bind this page 4i2482 A7 ____ B7 printed by the Bureau of Standards and Consumer Cooperatives V. Description of the Invention (26) Comparative Example 3 The pattern of wood particles was printed on 30 g / m2 laminated paper by photogravure technology using nitrocellulose-based ink One side of a piece of material, and for the entire surface of the wood particle pattern layer, this surface is printed with a gravure technique with a two-part hardened polyurethane resin coating fluid to form a surface The protective layer. A decorative sheet was obtained in this way ° Test 2 The decorative sheets of Example 4 and Comparative Examples 2 and 3 were joined to two of a 2.5 mm thick wood-based wood composite with an ethylene-acetic acid acetate-based adhesive. Side, so that the surface of the formaldehyde capture layer or the surface of the decorative sheet faces the wood-based wood plywood, which is formed by joining a Liuan wood board with a urea resin-based adhesive. In this way, a decorative plate can be manufactured for each decorative sheet '. Each decorative panel was measured in accordance with the formaldehyde concentration measurement method determined by the Japanese Agriculatural Standard. The test results show that for the decorative sheet of Example 4, the formaldehyde concentration is 2.0 mg / 1 formaldehyde, for the decorative sheet of Comparative Example 2 the formaldehyde concentration is 4.0 mg / 1 of formaldehyde, and for the decorative sheet of Comparative Example 3 'The formaldehyde concentration is 5.0 mg / 1 of formaldehyde. According to the test results, it is known that the formation of an amine-containing formaldehyde capture layer before the hardening of the amino methyl ester' will reduce the formaldehyde capture effect of the amine. The capture layer is formed after the methyl resin is completely hardened to avoid it. 29 This paper size applies the Chinese National Standard (CNS) Λ4 specification (210x297 mm) (read the precautions on the back before filling in this page) —pack_
*1T 412482 A7 B7 五、發明説明（27) 實施例5 在30 g/m2強化積層紙片的一側，以照相凹板技 術’使用一溶劑基墨水來印刷一固體墨水層以著色，此 溶劑基墨水是由將一甲醛捕捉劑與一丙烯酸類樹脂基 固定劑和甲醇混合混合而製得的。在其上，以确化纖維 基墨水印刷具有木材顆粒圖案之層。以此方式，可製造 出可有效捕捉甲醛的一裝飾片。將此裝飾片接合在塗有 乙稀·乙酸乙稀醋基接著劑之接著面的2.5 mm厚的MDF 上’使得含有曱醛捕捉劑之印刷層面向外。如此，可得 到能有效捕捉甲醛的一裝飾板。 實施例6 經濟部中央標準局貝工消費合作社印製 在30 g/m2強化積層紙片的一側，以照相凹板技 術，使用一硝酸纖維素/醇酸基墨水來印刷一固體墨水層 以著色，此硝酸纖維素/醇酸基墨水含有1 〇%的黏土基色 素與一曱醛捕捉劑。在其上，以硝化纖維基墨水印刷具 有木材顆粒圖案之層。以此方式，可製造出可有效捕捉 甲醛的一裝飾片。將此裝飾片接合在塗有乙烯-乙酸乙稀 酯基接著劑之接著面的 2.5 mm厚的MDF上，使得含有 甲醛捕捉劑之印刷層面向外。如此，可得到能有效捕捉 甲醛的一裝飾板。 實施例7 在150 μηι厚之透明聚氣乙烯膜之片材的底面上， 30 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X 297公釐） 412482 A7 _ B7_____ 五、發明説明（28) 以氯乙烯樹脂基墨水印刷木材顆粒的一圖案，在其上， 以氣乙烯樹脂基墨水印刷一固體墨水層以著色，此氣乙 烯樹脂基墨水含有10%之黏土基色素與一甲醛捕捉劑。 接著’以旋轉棒來反轉此膜，在透明聚氯乙烯膜的表面 上’以含有暗淡劑（matting agent)的丙烯酸樹脂基暗淡黑 色墨水來印刷與木材顆粒圖案之導管圖案相配合的一 圖案。然後，加熱並乾燥此膜。以此方式，可製造出具 有配合導管圖案及有效捕捉甲醛的一裝飾片。此裝飾片 然後接合2.5 mm厚之MDF之塗有乙烯-乙酸乙烯基接 著劑之接著劑表面上’使得甲醛捕捉層面向木材基之基 板。如此可得到可有效捕捉甲醛的一裝飾板。 實施例8 經濟部中央標準局員工消費合作社印繁 (請，先閱讀背δ之注意事項再填寫本頁) 在30 g/m2強化積層紙片的—側，以照相凹板技 術’使用一硝酸纖維素/醇酸基墨水來印刷一固體墨水層 以著色’此硝酸纖維素/醇酸基墨水含有1 〇%的黏土基色 素與一甲醛捕捉劑。在其上，以硝化纖維基墨水印刷具 有木材顆粒圖案之層。以此方式，可製造出可有效捕捉 甲醛的一裝飾片。個別地，在30 g/m2強化積層紙片的 頂側上，使用一輥塗佈機，塗佈含有一曱醛捕捉劑 ("FC-18-6"，由Miki Riken公司所製造）的水溶液，以形 成一甲酿捕捉層’使得當乾燥時捕捉層重5 g/m2。以此 方式以得到一曱盤捕捉片。 接著，以乙酸乙烯基乳化接著劑，將上述可有效捕 31 本紙張尺度適用中國國家標準（CNS) M規格（2⑴xW7公楚〉 H2482 A7 ___ B7 五、發明説明（29) 捉甲醛的裝飾片接合在2.5 mm厚之MDF基板的一面， 將上述甲酿捕捉片接合在基板的另一核上，使得甲酿捕 捉層面向MDF。以此方式得到可有效捕捉曱醛的一裝飾 板。 實施例9 以照相凹板法，使用由氣乙烯_丙烯酸樹脂基樹脂 所製成的墨水，在150 μηι厚之著色氣乙烯膜之片材之 一側上’印刷具有一木材顆粒圖案之層。以此方式，得 到一氣乙烯裝飾片。個別地，將一 30 g/m2強化積廣紙 片、一 30 μπι厚聚乙稀樹脂層、及一 30 g/m2強化積層 紙片依序接合以製得一化合物片，且，在強化積層片的 頂側上，使用輥塗佈機，以含有一甲醛捕捉劑之—塗佈 流體來塗佈’以形成一甲醛捕捉層，使得當乾燥時，甲 醛捕捉層重5 g/m2。以此方式製造一甲醛捕捉片。在此， 此甲醛捕捉劑含有： 樹脂（酪蛋白） 14%重量比 經濟部中央標準局員工消費合作社印裝 ------^--- 装-- (請，先閱讀背面之注意事項再填寫本頁} 甲醛捕捉劑 14%重量比 --"RIKEN RESINT FC-18-6”，由 Miki Riken 公司所製造 水 66%重量比 曱醇 5.5%重量比 消泡劑 0.5%重量比 32 ^纸張尺度適用中國國家標隼（CNS > A4規格（210X 297公釐) ~ 一 418482 A7 _______B7 五、發明説明（30) ~ 接著，以乙烯-乙酸乙烯酯基乳化接著劑以將上述 之裝飾片接合在2_7 mm厚之MDF基板之一側上，且， 以以乙烯-乙酸乙烯酯基乳化接著劑以將上述之曱醛捕 捉片接合在基板之另一側上，使得曱駿捕捉層面向基 板。以此方式得到具有甲醛捕捉層之一裝飾板。 實施例10 以和實施例9之裝飾板的製作方式相同以得到具 有甲鳝捕捉層之一裝飾板，但對於甲醛捕捉片之基片是 使用30 g/m2之強化積層紙片。 較實施例4 在150 μπι厚之著色氣乙烯膜之片材的一側上，使 用由氣乙稀-丙稀酸樹脂基樹脂所製造的墨水，以照相凹 板法’印刷具有木材顆粒圖案的一層。以此方法以得到 一氣乙烯裝飾片。接著，以一乙烯-乙酸乙烯酯基乳化接 著劑將上述之裝飾片接合在2.7 mm厚之MDF基板之一 侧上。以此方式得到一裝飾板。 經濟部中央標準局貝工消費合作社印製 試驗3 從實施例1和9和比較實施例4之裝飾板中，各切 出5 cm寬X 15 cm長的12個試片。每個板的η個試片 分別置於24 cm的乾燥器中，在乾燥器底部的中央，置 有含300 ml蒸餾水的小盤。在20°C下，使試片於乾燥 33 本紙張尺度適用中國囤家標準（CNS ) A4規格（2!〇X 297公釐） 412482 A7 ___ B7 五、發明説明（31) 器中放置24小時，以乙醯丙酮比色法測量蒸餾水中所 吸收的甲醛濃度。試驗結果顯示，對於實施例9的裝飾 板’蒸餾水吸收1 1 mg/I的甲醛，對於實施例1〇的裝飾 板’蒸德水吸收1 .〇 mg/1的甲經，對於比較實施例4的 裝飾板，蒸餾水吸收3_3 mg/1的曱醛。 本發明在此所述之裝飾片不僅可接合在一木材基 基板上’亦可接合在由任何材質所製成之一基板上，如 由會釋放甲醛之一樹脂所製成的一模製物品；再者，這 些裝飾片甚至可以接合在不是板子的任何形狀的物品 上0 本發明裝飾片的接合，不僅可以如上述地使用一壓 力輥，以在其間之一接著層將裝飾片壓在一板狀的基體 物品上，而且可以以下列列舉的方式施行： (1)將裝飾片插入射出成型之公模頭和母模頭之 間，關閉模頭，從公模頭的門中射出填入一熔融樹脂， 冷卻樹脂，將裝飾片接合在一樹脂成型物品的表面上， 同時樹脂成型物品被成型（所謂的射出成型和積層方 法’揭露於日本特公昭5049132中。 ⑺使用一接著齊卜將t飾片置於一成型物品之· 或其表面上，使用由成型物品側之真空吸引所造成的_ 壓力差，而將裝飾片接合在成型物品上(所謂的真空壓; 接合方法’揭露於日本特公昭56_45768和6G_58〇i4中 面」二以在其間之一接著層’沿著柱狀基體物品(具琴 圓柱或夕角柱等形狀)之抽，將裝飾片填入，同時，連, 閱 讀 背 面： 之 注： 意 事* 項 再 填 窍 本 頁 装 訂 經 濟 部 中 央 標 準 局 Μ X 消 f 合 作 社 印 製 34 ^tS483 A7 B7 五、發明説明（32) 一 地在柱狀基體物品的不同角度下以複數個輥所提供的 壓力，以將裝飾片接合在柱狀基體物品的側面上（所謂的 包裝方法，揭路於曰本特公昭6U895中 (4)以在其間之一接著層，將裝飾片置於一板狀之 基體物品之頂側上，在板狀基體物品之底側中，形成v 或U形載面的溝槽’使達到裝飾片和板狀基體物品之頂 面之間的界面’以-接著劑填人溝槽中，以及將板狀基 體物c口以及裝飾片形成為一箱形或多角柱的开)狀(所謂 的V-切或U-切方法，揭露於日本特開昭48-47972中。 依據本發明接合有裝飾片的物品，包括本發明之裝 飾板可用來作為裝飾房屋或建築物的内部（如牆壁、地 板 '和天花板）㈣料；可用來作為裝飾房屋或建築物的 配件（如窗戶、門、和攔干）的材料；可用來作為裝飾家 具（如抽履）表面的材料：可用來作為製造家庭和辦公室 用具之櫃子的材料’如電視機接收器；可用來 容器的（如箱子）的材料；以及可用來作為裝飾車 表面的材料。 1 35* 1T 412482 A7 B7 V. Description of the invention (27) Example 5 Using a gravure technique 'print a solid ink layer for coloring on one side of a 30 g / m2 reinforced laminated paper sheet, this solvent based The ink is prepared by mixing a formaldehyde trapping agent with an acrylic resin-based fixing agent and methanol. On it, a layer having a pattern of wood particles was printed with a confirmed fiber-based ink. In this way, a decorative sheet capable of efficiently capturing formaldehyde can be manufactured. This decorative sheet was bonded to a 2.5 mm-thick MDF coated with a vinyl acetate-vinyl acetate-based adhesive bond 'so that the printed layer containing the formaldehyde capture agent was outward. In this way, a decorative board capable of effectively capturing formaldehyde can be obtained. Example 6 Printed on the side of a 30 g / m2 reinforced laminated paper sheet by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, using a gravure technique, using a nitrocellulose / alkyd-based ink to print a solid ink layer for coloring This nitrocellulose / alkyd-based ink contains 10% clay-based pigments and a formaldehyde capture agent. On it, a layer having a pattern of wood particles was printed with nitrocellulose-based ink. In this way, a decorative sheet capable of efficiently capturing formaldehyde can be manufactured. This decorative sheet was bonded to a 2.5 mm thick MDF coated with an ethylene-vinyl acetate-based adhesive so that the printed layer containing the formaldehyde trapping agent was outward. In this way, a decorative board capable of effectively capturing formaldehyde can be obtained. Example 7 On the bottom surface of a 150 μm thick transparent polyethylene film sheet, 30 paper sizes are applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 412482 A7 _ B7_____ V. Description of the invention (28) A pattern of wood particles was printed with vinyl chloride resin-based ink, and a solid ink layer was printed with gas vinyl resin-based ink for coloring. The gas vinyl resin-based ink contained 10% of a clay-based pigment and a formaldehyde capture agent. Then 'reverse this film with a rotating rod and on the surface of the transparent polyvinyl chloride film' print a pattern that matches the wood grain pattern of the duct pattern with an acrylic resin-based matt black ink containing a matting agent. . This film is then heated and dried. In this way, a decorative sheet having a pattern matching the duct and effectively capturing formaldehyde can be manufactured. This decorative sheet was then bonded to a 2.5 mm thick MDF-coated adhesive-coated adhesive surface ' such that the formaldehyde capture layer faced the wood-based substrate. In this way, a decorative board capable of effectively capturing formaldehyde can be obtained. Example 8 Yin Fan, a Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back δ before filling this page). On the side of 30 g / m2 reinforced laminated paper, use photogravure technology to use a nitrate fiber. Pigment / alkyd-based ink to print a solid ink layer for coloring. This nitrocellulose / alkyd-based ink contains 10% clay-based pigment and a formaldehyde trapping agent. On it, a layer having a pattern of wood particles was printed with nitrocellulose-based ink. In this way, a decorative sheet capable of efficiently capturing formaldehyde can be manufactured. Individually, on the top side of a 30 g / m2 reinforced laminated paper sheet, an aqueous solution containing a formaldehyde scavenger (" FC-18-6 ", manufactured by Miki Riken Co., Ltd.) was applied using a roll coater. To form a paraffin-capturing layer 'so that when dry, the capturing layer weighs 5 g / m2. In this way, a disc capture is obtained. Then, using the acetic acid vinyl emulsification adhesive, the above-mentioned effective paper size 31 is applicable to the Chinese National Standard (CNS) M specification (2⑴xW7) Chu H2482 A7 ___ B7 V. Description of the invention (29) Formaldehyde catching decorative sheet bonding On one side of a 2.5 mm thick MDF substrate, the aforementioned formazan capture sheet was bonded to the other core of the substrate so that the formazan capture layer faced the MDF. In this way, a decorative board capable of effectively capturing formaldehyde was obtained. Example 9 A gravure method was used to print a layer with a pattern of wood particles on one side of a 150 μm thick colored vinyl film sheet using ink made of vinyl-acrylic resin-based resin. In this way An ethylene decorative sheet was obtained. Individually, a 30 g / m2 reinforced laminated paper sheet, a 30 μm thick polyethylene resin layer, and a 30 g / m2 reinforced laminated paper sheet were sequentially joined to obtain a compound sheet, And, on the top side of the reinforced laminated sheet, a roll coater was used to coat with a coating fluid containing a formaldehyde trapping agent to form a formaldehyde trapping layer, so that when dry, the formaldehyde trapping layer weighed 5 g / m2 In this way, a formaldehyde capture tablet is manufactured. Here, this formaldehyde capture agent contains: resin (casein) 14% by weight based on printing by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ------ ^ --- Pack- (Please read the precautions on the back before filling out this page} 14% by weight of formaldehyde trapping agent-" RIKEN RESINT FC-18-6 ", 66% by weight of water produced by Miki Riken and 5.5% by weight of methanol Specific antifoam agent 0.5% by weight 32 ^ Paper size applies to Chinese national standard (CNS > A4 size (210X 297mm) ~ 418482 A7 _______B7 V. Description of the invention (30) ~ Next, ethylene-vinyl acetate An ester-based emulsification adhesive is used to join the above-mentioned decorative sheet on one side of a 2-7 mm thick MDF substrate, and an ethylene-vinyl acetate-based emulsification adhesive is used to join the aforementioned formaldehyde capture sheet to another substrate On one side, make the Junjun capture layer face the substrate. In this way, a decorative plate with a formaldehyde capture layer is obtained. Example 10 The same method as that of the decorative plate of Example 9 is used to obtain a decoration with a formazan capture layer. Plate, but for the base of formaldehyde capture sheet A reinforced laminated paper sheet of 30 g / m2 is used. Compared to Example 4 On the side of a 150 μm thick colored vinyl film sheet, an ink made of a gas-acrylic-acrylic resin-based resin is used. The gravure method 'prints a layer having a pattern of wood particles. In this way, a monolithic vinyl decorative sheet is obtained. Then, the aforementioned decorative sheet is bonded to a 2.7 mm thick MDF substrate with an ethylene-vinyl acetate-based emulsifying adhesive. On one side, a decorative plate is obtained in this way. Printed by Shellfish Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs, Test 3 From the decorative plates of Examples 1 and 9 and Comparative Example 4, 12 test pieces each having a width of 5 cm by 15 cm were cut out. The n test pieces of each plate were placed in a desiccator of 24 cm, and a small dish containing 300 ml of distilled water was placed in the center of the bottom of the desiccator. Allow the test piece to dry at 20 ° C. This paper size is applicable to the Chinese standard (CNS) A4 (2! 〇X 297 mm) 412482 A7 ___ B7 V. Description of the invention (31) Place in the container for 24 hours The formaldehyde concentration absorbed in distilled water was measured by acetonitrile and acetone colorimetry. The test results show that for the decorative plate of Example 9 'distilled water absorbs 11 mg / I of formaldehyde, for the decorative plate of Example 10' distilled water absorbs 1.0 mg / 1 of formazan, and for Comparative Example 4 Decorative board, distilled water absorbs 3_3 mg / 1 of formaldehyde. The decorative sheet of the present invention can be bonded not only on a wood-based substrate, but also on a substrate made of any material, such as a molded article made of a resin that releases formaldehyde. In addition, these decorative sheets can even be joined to articles of any shape other than a board. 0 The joining of the decorative sheets of the present invention can not only use a pressure roller as described above to press the decorative sheets one by one in between. It can be implemented on the plate-like base article in the following enumerated ways: (1) Insert the decorative sheet between the male and female die heads for injection molding, close the die head, and inject from the door of the male die head. A molten resin, a cooling resin, and a decorative sheet are bonded to the surface of a resin-molded article, and at the same time, the resin-molded article is molded (the so-called injection molding and lamination method is disclosed in Japanese Patent Publication No. 5049132). The decorative sheet is placed on the surface of a molded article or on its surface, and the decorative sheet is bonded to the molded article using the pressure difference caused by the vacuum suction on the molded article side (the so-called true Air pressure; joining method 'exposed on the middle side of Japanese Patent Publication Nos. 56_45768 and 6G_58〇i4', followed by one layer in the middle, followed by drawing along the columnar substrate (with the shape of a piano column or a horn corner column), and pulling the decorative sheet Fill in, at the same time, read, read the back: Note: Remarks * Note: This page is bound by the Central Bureau of Standards of the Ministry of Economic Affairs MX X f Cooperative printed 34 ^ tS483 A7 B7 V. Description of invention (32) One place At different angles of the columnar base article, the pressure provided by a plurality of rollers is used to join the decorative sheet to the side of the columnar base article (the so-called packaging method is disclosed in Japanese Patent Publication No. 6U895 (4). In one layer in between, the decorative sheet is placed on the top side of a plate-like base article. In the bottom side of the plate-like base article, a groove forming a v or U-shaped carrier surface is used to reach the decorative sheet and board. The interface between the top surfaces of the substrate-like substrates is filled into the trench with -adhesive, and the plate-shaped substrate c and the decorative sheet are formed into a box-shaped or polygonal column) (so-called V-cut Or U-cut method, disclosed in Japanese Patent Application Laid-Open No. 48-47972 Articles with decorative sheets joined in accordance with the present invention, including the decorative panels of the present invention, can be used as decorative materials for the interior of a house or building (such as walls, floors' and ceilings); and can be used as accessories (such as Materials such as windows, doors, and drains); materials that can be used as decorative furniture (such as pumping) surfaces: materials that can be used as cabinets for home and office appliances' such as television receivers; containers that can be used (such as Box); and materials that can be used to decorate the surface of a car. 1 35