經濟部中央標準局員工消费合作社印" --4 Ο 5 Ο Ο 3—________Β7________ 五、發明説明（I) 本發明關於一锺製造具有添加劑在成品中的紙料之方 法，其方法中，使用鹼性疏水用紙膠料。這些膠料具有一 種反應性官能基能與孅維素纖維形成共價鍵，且使其疏水 性尾端由該纖維朝向外部。 由於一種使用沈澱的碳酸鈣（PCC)之設備，在鹼性條 件下所製造的高級紙料的製造量已經快速增加，其燴加抗 老化的持久性，且具有較佳的亮度。造紙機的水循環也已 經可能接近更完全。 目前高級紙料的印刷應用係定在一特定的加膠重量 ，後者之例子爲非衝擊性印刷（NIP)，尤其是噴墨印刷。 習用的辦公室紙料係被期望爲多功能且適用於各種影印機 及印表機，包括噴墨印表機，其已經不能符合所請的"多 用途"辦公室紙料之要求。這些紙料被期望能對於不同形 態的噴墨及雷射印表機以及影印機表現極佳的可印刷性（ 參考 Malmstr5m，〇·，Maier, K.H.: Leimungsstrategien fiir PCC-haltige Biiropapiere, Wochenblatt fiir papierfabrikation, 10/1996)。 可以由兩種基本變體來實施噴墨印刷：連續噴墨及 —經要求即打點（D0D)印表機。現今之噴墨印表機的應用 包括廣泛範圍的應用，從單色辦公室印表機至四色相片品 質印表機，線上鑑定及標記裝置及非常大版面的片/滾筒 媒介繪圖機。與其它NIP方法比較下，噴墨印表機具有最 大數目的不同應用。頃發現噴墨印表機的特殊優點係在多 色能力及印刷速度。此印刷方法所涉及的成本亦比較低。 3 裝一------^ i------線 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Λ4规格（2丨OX297公釐） 經濟部中央標準局員工消費合作社印¾ Λ Α7 __405003 _Β7____ 五、發明説明（ι) 在噴墨印刷中，可由電腦系統容易地控制印刷過程 ，因此所有的數據處理技術之設施係容易取得的°例如， 可藉數據處理系統之助簡單地控制色彩之滯留及色彩平衡 的調整。 依照噴墨印刷所獲得的經驗，印刷品質係受纖維組 成所影響，而主要受針葉木對闊葉木的比例所影響β就精 飾紙的品質而言，精飾紙的結構及孔隙的地形係對於所議 論的方法之印刷作業結果有關鍵性影響。就紙的品質而言 ，印刷結果係由紙張之不可壓縮的顆粒及其它影響紙張之 吸墨能力的參數所決定。最適宜噴墨印刷的紙料必須具有 吸收印墨的足夠能力，而且在墨水可能沿著纖維散佈或進 入紙張結構的孔隙之前容許墨水以足夠快之速度乾燥。因 此噴墨印刷中著重紙張之表面化學交互作用。 除了與紙結構有關的基本因素外，亦用造紙中所用 的添加劑來改善噴墨印刷的品質，如疏水用的內部膠料及 表面上膠配方，表面上膠澱粉及高表面面積的顏料。 該技藝中已經開發紙上膠用的配方，目的爲藉增加 紙的疏水性而改善紙的表面化學特性及黑-與-白單色印刷 的品質。藉由提升紙的疏水性，改良地控制墨水的吸收而 已經在紙張上達成較佳的黑墨印刷結果，該墨水於毛細管 力量下以紙張的橫向及深度方向進入紙張結構內。此方法 在紙張上產生銳利鮮明的圖案及消除黑墨的擴散（芯吸）。 適用於鹼性條件下所製造的高級紙之最常用的上膠配 方以烷基琥珀酸.酐（ASA)及烷基烯酮二聚物（AKD)爲主。這 4 ---------裝一-—.---訂-—-J---線 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國囤家標準（CNS ) Λ4規格（210X297公廣〉 經濟部中央標準局員工消費合作社印製 __405003 B7 _ 五、發明説明（今） 兩種膠料皆具有能與纖維素纖維形成共價鍵，且疏水性尾 端由纖維朝外之反應性官能基。這些疏水性尾端的特徵及 方向使得纖維係斥水的。AKD及ASA膠料以乳液形式計量 進入人造紙裝的濕端，而上膠力量在係乾燥器段及機器滾 筒中發展。 含一個万-內酯環的商品級烷基烯酮二聚物膠料係由二 個飽和的直鏈脂肪醯氯之二聚合反應而製得；最常用的院 基烯酮膠料係由棕櫚酸及/或硬脂酸所製得。烯基琥拍酸 酐或ASA化合物係以長鏈烯烴（C15-C2。)與馬來酸酐的反應 物獲得。 爲了在紙之內部上膠中有較高疏水性的紙，已經必須 在造紙機中使用較高計量比的ASA及AKD膠料，因此機器 的運轉性變差，而且製程中增加不同形態的污染問題。 不幸地，使用較高疏水性程度來控制黑色墨水之印 刷行爲的方法並不會給予彩色印刷最佳的結果。事實上， 由於改善密度的結果，此方法已經改善墨水覆蓋能力。然 而，在彩色印刷中，墨水的施用速率係比黑色印刷高，其 連同較高的吸收作用常常使印刷後的彩色墨水太慢乾燥， 導致在印刷的紙張上重疊顔色的擴散及混合（公知爲滲色） 〇 因此，已經作過不同的嘗試欲改善彩色噴墨印刷的 品質，例如改變量，及使用具有較高表面面積的塡充劑。 表面上膠亦是一種影響紙的印刷性之可行方式。 雖然針對噴.墨印刷法已經有提議不同方法來改善紙 5 本紙浪尺度適用中國國家標準（CNS ) Λ4規格（21(Tx297A# ) 裝一------1T-1------線一 (請先閲讀背面之注意事項再填筠本頁) 經濟部中央標準局員工消费合作社印製 __405003_Βτ_____ 五、發明説明（汁） 張的吸收能力及足夠疏水性的均衡度，但是業界中仍在尋 找高級的鹼性紙之替代方法，以便能最適合多色的噴墨印 刷。 當於中性或鹼性條件下製造一種含有添加劑的紙料 時，尤其含有沈澱的碳酸鈣當作塡充劑時，於紙內混入一 以泠-丙內酯爲主的膠料來達成良好的噴墨可印刷性，該 膠料係由一個或較大數目的脂肪酸（具有6-22個以飽和鍵 互相連結之碳原子的主鏈）開始製造得，且該酸包括至少 一個具有分枝的碳鏈。 於造紙中使用以/3-丙內酯爲主的膠料係長久已知的 (例如，參考美國專利號2,627,477，及J.W. Davis，等人 :紙用的新穎上膠劑-烷基烯酮二聚物，Tappi 1956，第 39冊，第1號，但是此文獻並沒有提到飽和脂肪酸所製 造的丙內酯之使用，其至少一個具有分枝的碳鏈。 類似於習用的AKD膠料，這些新穎膠料可由脂肪酸 開始製得，因此必須至少一個脂肪酸具有分枝碳鏈，然而 該鏈不含有雙鍵。起始材料脂肪酸中的碳鏈長度範園可在 6至22個碳範圍中改變》 已發現依本發明一觀點，特別地，一種直鏈及支麵 脂肪酸（例如具有50/50的比例）給予噴墨印刷用的紙料最 佳的品質’因此亦當作一種”多用途"紙。從造紙的角度餐 ，此處必須指出的是，達成合意目的結果所用的新穎方法 中所需要的膠料量係小於習用膠料配方中所需要者，因此 減輕造紙機中膠料所導致的污染及污物附著之問題。 6 本紙張尺度適用中國國家標4*- ( CNS ) Λ4規格（210X297^^ ~ ~~~ I I n I n I I n r n - (請先閲讀背面之注意事項再填寫本頁} 經濟部中央標準局員工消費合作社印製 40500¾_B7_ 五、發明説明（f ) ^ 本發明亦關於一種經膠料配方處理所製造的紙_, 該配方係以脂肪酸所製造的丙內酯爲主，其至少〜{固 具有分枝的碳鏈。紙可含有明礬及沈澱的碳酸鈣（Ρα:)。 可由相同於標準AKD乳液的方法製造新穎膠料的胃 定乳液。 本發明的紙料通常每公噸的紙被上膠至少200克， 有利上至少600克，且更有利爲添加至少一公斤。可使所 製造的紙料最適合於噴墨印刷，因此其亦可用於影印機及 雷射印表機（當作”多用途”紙）。 有利地，依本發明所製造的紙料係能符合黑色及彩 色墨水之噴墨印刷的需求，沒有通常噴墨印刷所伴隨的問 題。特別地，本發明的紙料在紙的吸附性及疏水性之間達 成拆衷平衡，俾以黑色及彩色皆能達成高品質的印刷結果 (即是，優點包括當用黑色或彩色墨水印刷時，最小透印 (show-through)、高印刷密度、沒有芯吸、沒有滲散以及 印刷輪廓之最小的破損性。再者，藉本發明的紙料可以達 成該均衡印刷結果而不需要依靠紙張的塗覆，藉表面處理 或利用在正常添加比率以上之較高量的表面上膠澱粉來改 善疏水性。因此，本發明的紙料能符合辦公室使用的印表 機紙料之要求，除此之外亦當作一種”多用途”紙。 再者，本發明的膠料配方能在噴墨印刷上達成想要 的最後結果，其之膠料用量係小於習用AKD膠料所需要的 量，因此可避免習用AKD膠料所造成的污物和細毛黏附於 滾筒上而污染造羝機的問題。 7 I I— - I I ^ r I 一 線 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Λ4规格（公犮） 經濟部中央標準局員工消費合作社印製 A7 --4fr50j&3--- 五、發明説明（t) 依本發明的一種膠料配方係由異硬脂酸或脂肪酸混 合物開始所製造的谷-丙內酯膠料，該脂肪酸混合物有利 地含有至少40%的異硬脂酸或其它具有分枝碳鏈的脂肪酸 〇 實例1 爲了對方法作評估，首先依照標準化的SCAN試驗方 法用一循環水紙張模具、一濕壓機及一乾燥筒來製造80 克/平方公分基重的試驗紙張。用60/40比例的樺樹/松樹 漿料、0.3%纖維重量的內部上膠澱粉Raisamyl 135 ESP(Raisio chemicals Oy 製）、22%紙張重量的 PCC 塡充 劑及0.16%纖維總重的滯留劑來製備紙漿。以纖維重量的 0.06、0.12及0.20%將內部膠料混入紙漿中。 在乾燥後立即、在硬化之前的次日及在乾燥和硬化後 ，對做成的試驗紙張作Cobb6。水吸收試驗及SchrSder墨 水滲透試驗。試驗紙張將保持在l〇5°C的加熱室內10分 鐘以進行硬化。 實例中的比較膠料配方係一種習用的AKD膠料 (Raisafob 5105)。以相同於習用的AKD膠料之方式使用 陽離子澱粉來分散異硬脂酸爲主的AKD膠料。 8 本紙張尺度適用中國國家標準（CNS ) Λ4规格（2丨0X297公麈〉 ---------裝 ------1T--一-----.^ (請先閲讀背面之注意事項再填寫本頁) 3οο 5ο 4Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs " --4 Ο 5 Ο Ο 3 —________ Β7 ________ V. Description of the Invention (I) The present invention relates to a method for manufacturing paper stock with additives in a finished product. In the method, Paper size for alkaline hydrophobic applications. These compounds have a reactive functional group capable of forming a covalent bond with the avidin fiber, with the hydrophobic end of the compound facing outward from the fiber. As a result of the use of precipitated calcium carbonate (PCC) equipment, the production volume of high-grade paper produced under alkaline conditions has rapidly increased, its durability is increased, and it has better brightness. The paper machine's water cycle may also be approaching more complete. At present, the printing application of high-grade paper is set at a specific glue weight. An example of the latter is non-impact printing (NIP), especially inkjet printing. Conventional office paper is expected to be multifunctional and suitable for a variety of photocopiers and printers, including inkjet printers, which are no longer able to meet the requirements of " multipurpose " office paper. These paper materials are expected to have excellent printability for different forms of inkjet and laser printers and photocopiers (see Malmstr5m, 〇 ·, Maier, KH: Leimungsstrategien fiir PCC-haltige Biiropapiere, Wochenblatt fiir papierfabrikation, 10/1996). Inkjet printing can be implemented in two basic variants: continuous inkjet and-on-demand dot-on-demand (DOD) printers. Today's inkjet printer applications include a wide range of applications, from monochrome office printers to four-color photo quality printers, online identification and marking devices, and very large-format film / drum media plotters. Compared to other NIP methods, inkjet printers have the largest number of different applications. It was discovered that the special advantages of inkjet printers are their multicolor capability and printing speed. The cost involved in this printing method is also relatively low. 3 Install a ------ ^ i ------ line (please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) Λ4 specifications (2 丨 OX297 mm) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ¾ Α7 __405003 _Β7 ____ V. Description of the Invention (ι) In inkjet printing, the printing process can be easily controlled by a computer system, so all data processing technology facilities are easily available. With the help of data processing system, you can simply control the retention of color and the adjustment of color balance. According to the experience gained by inkjet printing, the printing quality is affected by the fiber composition, and is mainly affected by the ratio of softwood to hardwood. Β In terms of the quality of the finishing paper, the structure of the finishing paper and the topography of the pores are The results of the printing operation of the method in question have a key influence. As far as the quality of paper is concerned, the printing result is determined by the incompressible particles of the paper and other parameters that affect the ink absorption capacity of the paper. The paper that is most suitable for inkjet printing must have sufficient capacity to absorb the ink and allow the ink to dry fast enough before the ink may spread along the fibers or enter the pores of the paper structure. Therefore, the surface chemical interaction of paper is emphasized in inkjet printing. In addition to the basic factors related to the paper structure, the additives used in papermaking are also used to improve the quality of inkjet printing, such as internal compounds and surface sizing formulations for hydrophobic applications, starches on the surface and high surface area pigments. In this technique, formulations for paper gluing have been developed with the aim of improving the surface chemical properties of paper and the quality of black-and-white monochrome printing by increasing the hydrophobicity of the paper. By improving the hydrophobicity of the paper and improving the control of ink absorption, better black ink printing results have been achieved on the paper. The ink enters the paper structure in the lateral and depth directions of the paper under capillary force. This method produces sharp and sharp patterns on the paper and eliminates black ink diffusion (wicking). The most commonly used sizing formulations for high-grade paper manufactured under alkaline conditions are mainly alkyl succinic acid, anhydride (ASA) and alkyl ketene dimer (AKD). This 4 --------- install one ---.--- order ---- J --- line (please read the precautions on the back before filling this page) This paper size is applicable to Chinese storehouse standards ( CNS) Λ4 specification (210X297) __405003 B7 _ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (today) Both rubber compounds have a covalent bond with cellulose fibers and a hydrophobic tail The end is composed of reactive functional groups with fibers facing outward. The characteristics and orientation of these hydrophobic tails make the fiber system water repellent. AKD and ASA compounds are metered into the wet end of human papermaking in the form of emulsion, and the sizing force is drying in the system Development and machine drum development. Commercial grade alkyl ketene dimer compound containing a 10,000-lactone ring is prepared by the dimerization of two saturated linear fatty acids, chlorine; the most commonly used hospital Alkenone compounds are made from palmitic acid and / or stearic acid. Alkenyl succinic anhydride or ASA compounds are obtained as reactants of long-chain olefins (C15-C2.) And maleic anhydride. Paper with higher hydrophobicity in the internal sizing, it has been necessary to use a higher metering ratio AS in the paper machine A and AKD rubber materials, so the machine's operability becomes worse, and different forms of pollution problems are added in the process. Unfortunately, the method of using a higher degree of hydrophobicity to control the printing behavior of black ink does not give the best color printing. In fact, as a result of improving density, this method has improved ink coverage. However, in color printing, the application rate of the ink is higher than that of black printing, which together with the higher absorption effect often makes the color after printing The ink dries too slowly, resulting in the diffusion and mixing of overlapping colors on the printed paper (known as bleeding). Therefore, different attempts have been made to improve the quality of color inkjet printing, such as changing the amount, and using a higher Surface area filling agent. Surface sizing is also a feasible way to affect the printability of the paper. Although for the inkjet printing method, different methods have been proposed to improve the paper. 5 The paper scale applies the Chinese National Standard (CNS) Λ4 specification. (21 (Tx297A #) Install one ----- 1T-1 ------ line one (Please read the precautions on the back before filling this page) Printed by the Consumer Bureau of the Standards Bureau __405003_Βτ _____ 5. Description of the invention (juice) The absorptive capacity of the sheet and the balance of sufficient hydrophobicity, but the industry is still looking for alternative methods of advanced alkaline paper in order to be most suitable for multicolor Inkjet printing. When manufacturing a paper containing additives under neutral or alkaline conditions, especially when containing precipitated calcium carbonate as an extender, mix a gel based on lin-propiolactone into the paper. Material to achieve good inkjet printability, the size is made from one or a larger number of fatty acids (with a main chain of 6-22 carbon atoms interconnected by saturated bonds), and the acid includes at least A branched carbon chain. The use of / 3-propiolactone-based rubber compounds in papermaking has long been known (see, for example, U.S. Patent No. 2,627,477, and JW Davis, et al .: A Novel Sizing Agent for Paper-Alkyl Ketone Dimerization) Material, Tappi 1956, Vol. 39, No. 1, but this document does not mention the use of propiolactone made from saturated fatty acids, at least one of which has a branched carbon chain. Similar to conventional AKD compounds, these Novel compounds can be made from fatty acids, so at least one fatty acid must have a branched carbon chain, but the chain does not contain double bonds. The carbon chain length range in the starting material fatty acid can be changed in the range of 6 to 22 carbons. " According to an aspect of the present invention, it has been found that, in particular, a linear and branched fatty acid (for example, having a ratio of 50/50) gives the best quality to the paper used for inkjet printing 'and is therefore also regarded as a "multipurpose " Paper. From the perspective of papermaking, it must be pointed out here that the amount of rubber required in the novel method used to achieve the desired result is less than that required in conventional rubber formulations, thus reducing the Dirty And the problem of dirt adhesion. 6 This paper size is applicable to China National Standard 4 *-(CNS) Λ4 specification (210X297 ^^ ~ ~~~ II n I n II nrn-(Please read the precautions on the back before filling this page } Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 40500¾_B7_ V. Description of the Invention (f) ^ The present invention also relates to a paper made by processing a rubber compound. This formula is mainly based on propiolactone made from fatty acids. It has at least ~ {solid with branched carbon chains. The paper may contain alum and Shendian calcium carbonate (Pα :). The fixed size emulsion of the novel size can be made by the same method as the standard AKD emulsion. A metric ton of paper is glued at least 200 grams, advantageously at least 600 grams, and more preferably at least one kilogram. The paper can be made most suitable for inkjet printing, so it can also be used in photocopiers and laser printing. Table machine (as "multi-purpose" paper). Advantageously, the paper stock produced according to the present invention can meet the needs of inkjet printing of black and color inks, without the problems associated with inkjet printing in general. In particular, this paper Invention paper Reach a compromise between paper's absorbency and hydrophobicity, and achieve high-quality printing results in both black and color (ie, advantages include minimal print-through when printing with black or color inks) ), High printing density, no wicking, no bleeding, and minimal breakage of the printing contour. Furthermore, the paper of the present invention can achieve this balanced printing result without relying on paper coating, surface treatment or The use of a higher amount of starch on the surface above the normal addition rate to improve hydrophobicity. Therefore, the paper of the present invention can meet the requirements of printer paper used in the office, in addition, it is also regarded as a kind of "multiple Use "paper. In addition, the rubber compound of the present invention can achieve the desired final result on inkjet printing, and the amount of the rubber compound is less than the amount required for the conventional AKD compound, so the dirt caused by the conventional AKD compound can be avoided. The problem that the fine hair adheres to the roller and contaminates the quilting machine. 7 II—-II ^ r I First line (please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) Λ4 specification (public money) Printed by A7, Consumer Cooperative of Central Standards Bureau, Ministry of Economic Affairs- -4fr50j & 3 --- V. Description of the invention (t) A rubber formulation according to the present invention is a glutamyl-propiolactone rubber produced from an isostearic acid or a fatty acid mixture, which advantageously contains at least 40% isostearic acid or other fatty acids with branched carbon chains. Example 1 To evaluate the method, a circulating water paper mold, a wet press, and a drying cylinder were first used to make 80 according to the standardized SCAN test method. Test paper with a basis weight of grams per square centimeter. 60/40 ratio of birch / pine pulp, 0.3% fiber weight internal starch Raisamyl 135 ESP (made by Raisio chemicals Oy), 22% paper weight PCC filler and 0.16% fiber total weight retention agent To make pulp. The internal size was mixed into the pulp at 0.06, 0.12, and 0.20% by weight of the fiber. Immediately after drying, the day before hardening, and after drying and hardening, Cobb6 was made on the finished test paper. Water absorption test and SchrSder ink penetration test. The test paper will be held in a heating chamber at 105 ° C for 10 minutes for hardening. The comparative compound formulation in the example is a conventional AKD compound (Raisafob 5105). Cationic starch is used to disperse AKD compounds based on isostearic acid in the same way as conventional AKD compounds. 8 This paper size applies to the Chinese National Standard (CNS) Λ4 specification (2 丨 0X297) 麈 --------- Installation ------ 1T-- 一 -----. ^ Read the notes on the back and fill out this page) 3οο 5ο 4
7 B 五、發明説明（"I ) 表1 經濟部中央標隼局負工消費合作社印製 膠料組成/ Cobbeo試驗 Schr0der 試驗 計量[%] [克/平方公分] [秒] 立即 次曰， 硬化(10 立即 次曰， 硬化(10分鐘， 沒有硬 分鐘， 沒有硬 105°C) 化 105°〇 化 棕櫚酸/硬脂酸 比例60/40 0.06 65 37 34.1 5 25 27 0.12 18.7 15.9 16.3 >1000 >1000 >1000 0.20 15.0 14.0 13.9 >1000 >1000 >1000 掠櫚酸/硬脂酸 比例40/60 0.06 29.S 23.1 26.1 47 70 112 0.12 17.3 16.0 15.6 >1000 >1000 >1000 0.20 16.3 12.8 14.6 >1000 >1000 >1000 異硬脂酸爲主的 AKD 膠料，100% 支鏈 0.06 通過 通過 通過 0 0 0 0.12 70.0 55.0 52.3 0 0 0 0.20 45.6 33.4 32.3 10 22 25 異硬脂酸爲主的 AKD藤料，50/50 分枝的/未分枝 的鍵 0.06 通過 通過 通過 0 0 0 0.12 22.8 24.7 19.S 165 137 217 0.20 17.3 16.2 15.7 775 >1000 >1000 由表1之結果明顯得知，異硬脂酸爲主的AKD膠料 (50/50分枝/未分枝的碳鏈）所達成的上膠品質係可相比 擬於習用以棕櫚酸/硬脂酸之混合物爲主的混合物所可取 9 本纸張尺度適用中國國家標準（CNS ) Λ4規格（210X297公犮） ---------裝— (請先閱讀背面之注意事項再填寫本頁) 訂 線· 經濟部中央標準局員工消費合作社印^ __40^03_87__ 五、發明説明（t) 得者。 實例2 以中間試驗規模的造紙機來評估不同型式的AKD膠料 ，該機器以60公尺/分鐘（4.1克/分鐘）運轉及製造出具 有80克/平方公分基重的高級紙。 中間規模試驗機器運轉中所用的紙漿成分係如下：樺 樹/松樹紙漿以75/25之比例混合及打解成250SR的游離 度。塡充劑爲沈澱的碳酸鈣（PCC)，佔紙重量的22%。內 部加膠澱粉係 Raisamyl 135(Raisio Chemicals)的佔纖 維重量的0.5%，而滯留劑的用量係佔纖維總重的0.22%。 將佔纖維重量0.15及0.20%的內部膠料投入紙漿中。 表面膠料爲 Raisio Chemicals 公司的 Raisamyl 408 SP 表面上膠澱粉，且其以乾燥基準的8%稠度使用。 藉Cobbe。水吸收試驗，使用由捲紙機所立即取下的樣 品及在試驗之前調濕10分鐘，而測試中間試驗規模造紙 機中所製造的紙張之疏水性。此外，利用中間試驗規模機 器中所製造疏水性紙經滾筒硬化的樣品作Cobb6。水吸收試 驗及HST墨水滲透試驗》HST試驗係以墨水滲透入紙張爲 基礎，監視在給定時間的墨點之反射性，例如在反射性掉 落至其初値之80%時的時間。使用商業級的噴墨印表機（ 惠普製）來測試紙樣品與噴墨印刷的相容性。藉目視及影 像分析設備及藉測量印刷後的彩色區域之光學密度而由印 刷後的試驗紙張評估印刷結果的芯吸和滲散性。 10 本紙張尺度適扪中國囤家標準（CNS ) Α4规格（210X 297公釐） ---------裝一-------,1τ-ί —_ —----線 (请先閱讀背面之注意事項再填寫本页) Μ405003_β7五、發明説明（Υ ) 表2 膠料組成/ 計量[%] Cobb™試驗 [克/平方公分] HST試驗 [秒] 在十分鐘曝 於滾筒中硬化 於滚筒中硬化 氣後立即 後 後 棕櫚酸/硬脂酸 比例60/40 0.13 50.3 41.9 38 0.20 23.2 19.3 345 掠櫚酸順脂酸 比例40/60 0.13 52.0 43.3 27 0.20 19.9 18.9 385 異硬脂酸爲主的 AKD 膠料，100% 支鏈 0.13 57.7 48.1 12 0.20 39.9 33.3 54 異硬脂酸爲主的 AKD®料，50/50 分枝的/未分枝 的鏈 0.13 51.5 42.6 33 0.20 20.2 19.2 355 -- ^^1 1- - - I - --1 ; --- m. -i HI - —-—--i - --- -- s--SJ- - * - 1!·*__ - - - ϊ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 由表2之結果明顯得知，異硬脂酸爲主的AKD膠料 (50/50分枝/未分枝的碳鏈）所達成的疏水性品質係可相 比擬於習用AKD膠料所可獲得者。 本紙張尺度適用巾國國家標準（CNS ) Λ4規格（210X21)7公犮） 405003 五、發明説明（〖σ) Λ7 B7 3 表7 B Fifth, the invention (" I) Table 1 Composition of printed rubber of the Central Bureau of Standards of the Ministry of Economic Affairs and Consumer Cooperatives / Cobbeo test Schr0der test measurement [%] [g / cm²] [sec] Hardening (10 Immediately, Hardening (10 minutes, no hard minutes, no hard 105 ° C)) 105 °° C Palmitic acid / stearic acid ratio 60/40 0.06 65 37 34.1 5 25 27 0.12 18.7 15.9 16.3 > 1000 > 1000 > 1000 0.20 15.0 14.0 13.9 > 1000 > 1000 > 1000 ratio of palmitic acid / stearic acid 40/60 0.06 29.S 23.1 26.1 47 70 112 0.12 17.3 16.0 15.6 > 1000 > 1000 > 1000 0.20 16.3 12.8 14.6 > 1000 > 1000 > 1000 Isostearic acid-based AKD compound, 100% branched 0.06 pass through 0 0 0 0.12 70.0 55.0 52.3 0 0 0 0.20 45.6 33.4 32.3 10 22 25 Isostearic acid-based AKD rattan, 50/50 branched / unbranched bond 0.06 Passed through 0 0 0 0.12 22.8 24.7 19.S 165 137 217 0.20 17.3 16.2 15.7 775 > 1000 > 1000 It is clear from the results in Table 1 that isostearic acid-based AKD compounds (50/50 The sizing quality achieved by the branched / unbranched carbon chain) can be compared to the conventional mixture of palmitic acid and stearic acid. The paper size is applicable to the Chinese National Standard (CNS) Λ4 specification. (210X297) --------- Installation— (Please read the precautions on the back before filling this page) Threading · Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^ __40 ^ 03_87__ V. Description of the invention ( t) Winner Example 2 An intermediate test scale paper machine was used to evaluate different types of AKD compounds. The machine was operated at 60 m / min (4.1 g / min) and manufactured with a basis weight of 80 g / cm2. High-grade paper. The pulp composition used in the operation of the intermediate-scale test machine is as follows: Birch / pine pulp is mixed at a ratio of 75/25 and dissociated to a freeness of 250SR. The filler is precipitated calcium carbonate (PCC), which accounts for 22% of the paper weight. The internal gelatinized starch Raisamyl 135 (Raisio Chemicals) accounts for 0.5% of the fiber weight, and the amount of the retentive agent accounts for 0.22% of the total fiber weight. 0.15 and 0.20% of the internal weight of the fiber was put into the pulp. The surface compound was Raisamyl 408 SP, a starch coated on the surface of Raisio Chemicals, and used at a consistency of 8% on a dry basis. Borrow Cobbe. The water absorption test used a sample immediately removed from the paper roll machine and humidity-controlled for 10 minutes before the test to test the hydrophobicity of the paper produced in the intermediate test scale paper machine. In addition, a cylinder hardened sample of a hydrophobic paper produced in an intermediate test scale machine was used as Cobb6. The water absorption test and HST ink penetration test "HST test is based on the ink penetrating into the paper, and monitors the reflectivity of the ink dot at a given time, for example, the time when the reflectivity falls to 80% of its initial value. A commercial grade inkjet printer (made by Hewlett-Packard) was used to test the paper samples for compatibility with inkjet printing. The wicking and bleeding properties of the printed results were evaluated from printed test paper by visual and image analysis equipment and by measuring the optical density of the colored areas after printing. 10 This paper is suitable for China Store Standard (CNS) Α4 size (210X 297mm) --------- Package 1 -------, 1τ-ί —_ —---- (Please read the precautions on the back before filling this page) Μ405003_β7 V. Description of the invention (Υ) Table 2 Compound composition / metering [%] Cobb ™ test [g / cm²] HST test [second] Exposure in ten minutes Hardened in a roller Immediately after hardening gas in a roller, the ratio of palmitic acid / stearic acid is 60/40 0.13 50.3 41.9 38 0.20 23.2 19.3 345 the ratio of palmitic acid and maleic acid is 40/60 0.13 52.0 43.3 27 0.20 19.9 18.9 385 iso AKD compound based on stearic acid, 100% branched 0.13 57.7 48.1 12 0.20 39.9 33.3 54 AKD® compound based on isostearic acid, 50/50 branched / unbranched chain 0.13 51.5 42.6 33 0.20 20.2 19.2 355-^^ 1 1---I---1; --- m. -I HI-—----- i-----s--SJ--*-1! · * __---ϊ (Please read the notes on the back before filling out this page) Printing from the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs It is obvious from the results in Table 2 that AKD rubber based on isostearic acid (50 / 50 branched / unbranched carbon chain Reached hydrophobic quality comparable to a conventional system that may be obtained with AKD size were used. This paper size is applicable to the national standard (CNS) Λ4 specification (210X21) 7 cm) of the paper towel 405003 V. Description of the invention (σ) Λ7 B7 3 Table
綜橋酸/硬 脂酸比例 60/40 計量0.20% 棕櫚酸/硬脂 酸比例40/60 計量0.20% 異硬脂酸爲主 的AKD膠料， 100%支鍵 計量0.20% 噴墨印刷黑-與 -白 乾燥時間 芯吸 密度 1.38 Is 1.44 立即 10 1.1 全彩印刷 滲散 7.4 7.5 6.5 印届晒積 50749 51850 49595 印刷周長 2045 2016 1949 密度，黑色 1.24 1.28 0.98 表面膠料消耗 [升/分鐘] 1.51 1.43 1.60 鏈 ο 勺勺 5 ^ 硬的，椬枝 異主料分分 由表3之結果明顯得知，異硬脂酸爲主的AKD 爲膠G 酸KD/5 le.曰AKio 来Heterobolic acid / stearic acid ratio 60/40 meter 0.20% Palmitic acid / stearic acid ratio 40/60 meter 0.20% Isostearic acid-based AKD compound, 100% branch bond meter 0.20% Inkjet printing black- With-white drying time wicking density 1.38 Is 1.44 Immediate 10 1.1 Full color printing bleed 7.4 7.5 6.5 Yin session sun product 50749 51850 49595 Printing circumference 2045 2016 1949 Density, black 1.24 1.28 0.98 Surface rubber consumption [l / min] 1.51 1.43 1.60 Chain Scoop 5 ^ Hard, different main ingredients of rambutan. It is clear from the results in Table 3 that AKD based on isostearic acid is gum G acid KD / 5 le. AKio
---------參— 一請先閲讀背而之注意事項真填寫本\〇〇 經濟部中央標準局員工消費合作社印製 r -feiw ^ 5¾ (50/50分枝/未分枝的碳鏈）在黑-與-白之印刷 印刷輪廓之粗键性<raggedness>(包含滲散、心吸疋/ 周邊的試驗圖案）與膠料消耗之特性的參數之間'達^ 係 平衡。再者，必須注意的是，執行依本發明的表面上膠’卞 不需要使用習用的疏水劑或其它表面疏水技術。 實例3 依本發明的一種內部膠料，尤其是在實驗室及中間試 驗規模的試驗中發現最佳性能的以異硬脂酸爲主的AKD膠 料（50/50分枝/未分枝的碳鏈）’在工業規摸的細緻級紙 12 本紙張尺度適用中国國家標準（CNS ) Λ4规格（210X2^7公势） A7 A7 經濟部中央標率局員工消费合作社印製 4Π^003___ 五、發明説明（丨I) 用之造紙機中被更進一步試驗。使用習用的AKD膠料作比 較性樣品的試驗。所製造的紙之組成係等於一種典型含有 沈澱碳酸鈣（PCC)的高級紙，因此適用於噴墨印刷。試運 轉中所製造的紙之基重爲70克/平方公分。所添加的膠料 量係爲紙的1.3公斤/噸。 在試運轉中由一些機器滾筒上取得紙張樣本，分析它 們頂面的疏水性（Cobb6。及HST)及與噴墨印刷之相容性有 關的參數（芯吸、滲散及光學密度）。 表4 上膠/測量的參數 異硬脂麟主的AKD 商業級AKD膠料，具 膠料，50/50分枝的/ 有棕搬/硬脂酸比例 未分枝的鍵 爲40/60 CobU試驗[克/平方 細 22.2 28.8 HST試驗fS].表面 86.5 54 噴墨印刷 表面上的芯吸 3 4 表面上的渗散 2 2 噴墨印刷 黑色 1.84 1.4 黑色*複合的 1.10 1.13 藍綠 1.37 1.36 洋紅 0.93 0.92 黃色 0.91 0.88 由異硬脂爲主的AKD膠料所上膠的紙張與市售的AKD 膠料所上膠的紙張之噴墨印刷相容性比較，明顯得知異硬 脂爲主的AKD膠料給予黑色墨水和彩色墨水之明顯較佳的 印刷結果。以異硬脂酸爲主的膠料所上膠的紙既沒有墨水 13 本紙張尺度適用中囡囤家標準（CNS ) Λ4规格（210X 297公f ) (請先閲讀背面之注意事項再填寫本頁) •裝- ΪΤ- Λ7 Β7 經濟部中失標準局員工消费合作社印製 五、發明説明（/ h) 滲透過紙張的情形也沒有任何芯吸或滲散。再者’印墨的 密度係本質上比商業級AKD膠料所上膠的紙樣本較佳》再 者，必須注意的是，紙張可達成高品質的可印刷性而不需 要對紙張表面作任何的疏水處理。 最後，根據工業規範（full scale)製造試驗’證明在 造紙機上的試運轉所製造的紙不僅適用於噴墨印刷而且能 符合，，多用途”紙的要求，如適合影印機及雷射印表機之輸 出的充足疏水度。在試驗期間，造紙機的運轉性係極佳的 且發現造紙機構件的表面上沒有污物附著或污染° 實例4 此實例中，紙料係經過表面處理，在紙漿製造時已經 加有內部膠料以使紙具有某些程度的疏水性。依據Cob— ，疏水效果係在30克/平方公分的程度。利用Helicor-裝置來達成紙的表面上膠。其中要被處理的紙係置於一可 轉動的鼓上，且其中利用一選定的刀磨來塗佈一表面上膠 澱粉連同一表面疏水劑。 此實例中所用的表面上膠澱粉係一種氧化的陽離子表 面澱粉，爲 10% 溶液（Raisamyl 406 SF，Raisio Chemicals 0y)。此具有10%稠度的澱粉溶液係與不同量 的表面上膠添加劑混合，該不同量係根據澱粉乾燥物質上 的活性劑來計算。表面上膠添加劑爲經試驗的異硬脂酸_ 硬脂酸AKD、苯乙烯丙烯酸酯及SMA表面上膠添加劑。異 硬脂酸-硬脂酸（分枝-未分枝的鏈）與ΑΚϋ膠料的關係係 1:1。所用的.苯乙烯芮烯酸酯係膠料Misafob 14 (請先閱讀背面之注意事項再填寫本頁) $—- ，1' r. 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X29?公兑)--------- Refer to the first-please read the back of the note and fill it out. \ 〇〇 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. R -feiw ^ 5¾ (50/50 branches / undivided) The carbon chain of the branch) is between the parameters of the rough bond < raggedness > of black-and-white printed contours (including the test pattern of bleed, wicking / periphery) and the characteristics of rubber consumption. Department of balance. Furthermore, it must be noted that performing surface sizing according to the present invention does not require the use of conventional hydrophobic agents or other surface hydrophobic techniques. Example 3 An internal compound according to the present invention, especially an isostearic acid-based AKD compound (50/50 branched / unbranched) found to have the best performance in laboratory and intermediate test scale tests (Carbon chain) 'Fine grade paper in industrial regulation 12 This paper is in accordance with Chinese National Standard (CNS) Λ4 specification (210X2 ^ 7 public power) A7 A7 Printed by the Consumer Standards Cooperative of the Central Standards Bureau, Ministry of Economic Affairs 4Π ^ 003 ___ Description of the invention (丨 I) is further tested in a paper machine. A comparative sample was tested using a conventional AKD compound. The paper produced is equivalent to a fine paper typically containing precipitated calcium carbonate (PCC) and is therefore suitable for inkjet printing. The basis weight of the paper manufactured during the trial operation was 70 g / cm2. The amount of rubber added is 1.3 kg / ton of paper. During the test run, paper samples were taken from some machine rollers, and their top surfaces were analyzed for hydrophobicity (Cobb6 and HST) and parameters related to compatibility with inkjet printing (wicking, bleed, and optical density). Table 4 Glue / Measured parameters Isostearin-based AKD commercial grade AKD compound with rubber, 50/50 branched / brown / stearic acid ratio unbranched 40/60 CobU Test [g / square fine 22.2 28.8 HST test fS]. Surface 86.5 54 wicking on the surface of inkjet printing 3 4 bleed on the surface 2 2 inkjet printing black 1.84 1.4 black * composite 1.10 1.13 blue green 1.37 1.36 magenta 0.93 0.92 Yellow 0.91 0.88 Inkjet printing compatibility of paper coated with AKD rubber based on isostearin and paper coated with commercially available AKD rubber, it is clear that AKD compounds give significantly better printing results for black and color inks. Isostearic acid-based compounds do not have ink on the paper. 13 This paper size applies the Chinese Standard (CNS) Λ4 specification (210X 297 male f) (Please read the precautions on the back before filling in this Page) • Equipment-ΪΤ- Λ7 Β7 Printed by the Consumers' Cooperatives of the Bureau of Intermediate Standards of the Ministry of Economic Affairs. 5. Description of the Invention (/ h) There was no wicking or wicking when it penetrated the paper. Furthermore, the density of the printing ink is substantially better than the paper samples glued by commercial grade AKD compounds. Furthermore, it must be noted that the paper can achieve high-quality printability without any need to make any changes to the surface of the paper. Hydrophobic treatment. Finally, according to the industrial scale (full scale) manufacturing test, it is proved that the paper produced in the trial run on the paper machine is not only suitable for inkjet printing but also can meet the requirements of "multipurpose" paper, such as suitable for photocopiers and laser printing. Sufficient hydrophobicity of the output of the meter. During the test, the paper machine's operability was excellent and no dirt or contamination was found on the surface of the papermaking mechanism. Example 4 In this example, the paper is surface treated. Internal pulp has been added during pulp manufacture to make the paper have a certain degree of hydrophobicity. According to Cob-, the hydrophobic effect is about 30 g / cm2. Helicor-device is used to achieve the surface sizing of the paper. Among them The paper system to be treated is placed on a rotatable drum, and a selected knife mill is used to coat a surface of the starch with the same surface hydrophobic agent. The surface of the starch used in this example is an oxidized Cationic surface starch, 10% solution (Raisamyl 406 SF, Raisio Chemicals 0y). This starch solution with 10% consistency is mixed with different amounts of surface sizing additives, which are different It is calculated based on the active agent on the dried starch. The surface sizing additive is the tested isostearic acid_stearic acid AKD, styrene acrylate and SMA surface sizing additive. Isostearic acid-stearic acid ( The relationship between branched-unbranched chains) and ΑΚϋ size is 1: 1. Used. Styrene acrylate type Misafob 14 (Please read the precautions on the back before filling this page) $ —- ， 1 'r. This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X29? KV)
表5 iMOOWaisio Chemicals 〇yp所用的SMA係苯乙烯馬來 酸酐’爲 Raisio CheiBicais 製，以 Raisafob D1〇〇 之名 稱販售^ 試驗結果在以下袠5中，其中上膠結果以C〇bb6Q& HST値表示β 表面±0 添加劑 表面上膠的添加量 、％> Cobbeo,克/ 平方败 HST(S0%), 秒 辨整紙 〇~~-- 30.4 67 精氣表面上 粉 --- 46.6 60 異硬脂酸/硬脂酸_ AKD 1 22.4 126 22.4 137 2 20.4 140 — 4 20.0 182 本乙烯丙烯酸醋 1Γ- 41.6 65 2 39.2 69 SMA 4 36.0 78 1 - 38.4 75 2 29.2 115 4 21.6 117 $ 5 値顯示’由含有異硬脂酸的脂肪酸所作成 AKD膠料顯示在最低的添加用量上已有最佳的性質，且依 據Cobbw及HST試驗値給予最高的疏水性。 評估黑白可印刷性用的試驗結果係在以表6中》利用 惠普500C型噴墨印表機來印刷以試驗紙，及測量印出物 的光學密度。 15 本紙張尺度適州中國丨翌家標準（（:呢）/\4規格（21〇><:297公楚） 裝一.--.---.1T---.丨---線 (請先閲讀背面之注意事項再填寫本頁) 經濟·部中央標準局負工消费合作社印裝 經濟部中央標準局員工消費合作社印 A7 __40500¾_B7 五、發明説明（丨十） 表6，噴墨印刷結果，HP 560C印表機 表面上膠添加劑 表面上膠的添加量 黑白印刷： 黑色密度 彩色晒結 合黑色密度 精整紙 0 1.33 0.98 精备表面上膠澱_ 粉 0 1.58 1.26 異硬脂酸/- 0.5 1.67 1.19 硬脂酸AKD 1 1.76 1.22 2 1.85 1.31 4 1.86 1.32 苯乙烯丙烯酸酯 1 1.58 1.23 2 1.60 1.25 4 1.67 1.25 SMA 1 1.74 1.27 2 1.75 1.31 4 1.80 1.30 表6中的結果顯示黑白印刷之可印刷性甚至較佳於常 用於紙之表面上膠的化合物。 實例5 亦在中間試驗用的造紙機上試驗表面上膠添加劑，其 中使用池（pond)紙表施膠機及薄膜紙表施膠機來對尙未經 預先表面上膠的紙料作上膠。精整紙（paper finish)係由 具有80克/平方公分的克數的細緻紙料所構成，且其含有 20%的沈澱碳酸鈣當作精整紙（一種常見的多用途辦公室紙 )的塡充劑。所用的表面膠料係氧化的陽離子表面澱粉， (Raisamyl 405 SP，Raisio Chemicals Oy)，爲 8%稠度 溶液。表面上膠澱粉係與不同量的疏水用表面上膠添加劑 混合：基本AKD(棕櫚酸/硬脂酸，60/40%)，異硬脂酸-硬 脂酸AKD(分枝的/未分枝的，50/50%)，苯乙烯·丙烯酸酯 (Raisafob P400·，Raisio Chemicals Oy)及 SMA 爲主的（ ---------裝 1-----、1τ·—ι-------線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X297公釐> 經濟部中火標隼局貝工消費合作社印掣 4〇5qQ3_^__五、發明説明（I艾）苯乙嫌馬來酸酐，Raisafob D100，Raisio Chemicals Oy)表面上膠添加劑。下表7含有中間試驗造紙機的試驗結果，其中使用薄 膜紙表施膠機。 表7 ,在中間試驗造紙機上使用薄膜紙表施膠機的上膠結果 表面上膠添加劑 表面±0的添加量 >% Cobb»,克/ 平方公分 HST(80%), 秒 精斷表面±« 0 42.3 143 粉 S$AKD 0.25 25.6 255 0.50 23.8 273 1 20.3 310 2 19.2 380 異硬脂酸/硬脂酸 0.25 27.8 247 AKD 0.50 25.7 251 1 22.3 239 2 20.4 285 苯乙烯丙烯酸酯 2 30.8 223 4 25.6 229 SMA 2 25.3 266 4 21.1 282 下表8含有紙之噴墨印刷試驗的結果’其中使用 HP 560C印表機來印刷。依照乾燥評估方法來分析印刷 結果。 ---------裝一Η------,11---->---線 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度朗悄财標準（⑽）Λ4_· ( 21GX 297公楚） 405003 at Β7 五、發明説明（ I V) 表8，在HP 560C印袠機的黑白可印刷性 黑白印刷 彩色 印刷 表面上膠添加劑 密度 芯吸 乾燥時間 密度 滲散：面積 滲散：周長 精整+表面上膠 1.07 2.1 1 0.95 49057 1834 基本AKD 0.5% 1.19 1.6 16 0.97 51103 2019 基本AKD 1.0% 1.22 1.5 24 0.98 49152 1923 異硬脂酸/ 硬脂酸AKD 0.50% 1.18 1.6 7 0.97 48313 1913 異硬脂酸/ 硬脂酸AKD 1.0% 1.21 1.5 13 0.98 47609 1898 苯乙烯丙烯酸酯 1.0% 1.14 1.8 2 0.95 47654 1847 苯乙烯丙烯酸醋 2.0% 1.14 1.7 4 0.96 47966 1821 SMA 1.0% 1.20 1.6 17 0.96 47058 1808 SMA 2.0% 1.23 1.5 26 0.97 47099 1909 (請先閱讀背面之注意事項再填寫本頁) 、-* Γ. 經濟部中央標準局貝工消費合作社印製 表7及8中的數字顯示基本AKD在評估調査中已經 給予非常好的疏水性結果。然而，高的疏水性可能導致 色彩的太低乾燥，使彩色印刷的色彩不均勻。這些結果 似乎顯示利用異硬脂酸/硬脂酸AKD(其係由分枝的及未 分枝的碳鏈所構成）可以在膠料的消耗、黑白印刷及彩色 印刷中達成最佳的平衡。 18 本紙张尺度適用中國國家標準（CNS ) Λ4規格（210X 297公釐）Table 5 SMA-based styrene maleic anhydride 'used by iMOOWaisio Chemicals 〇yp is manufactured by Raisio CheiBicais and sold under the name Raisafob D100. ^ The test results are shown in the following 袠 5, where the sizing results are shown as 〇bb6Q & HST. Means β surface ± 0 Additive amount of glue on the surface of additive,% > Cobbeo, g / sq. HST (S0%), second discriminating paper 〇 ~~-30.4 67 powder on fine gas surface --- 46.6 60 iso Stearic acid / stearic acid_ AKD 1 22.4 126 22.4 137 2 20.4 140 — 4 20.0 182 Natural vinyl acrylic vinegar 1Γ- 41.6 65 2 39.2 69 SMA 4 36.0 78 1-38.4 75 2 29.2 115 4 21.6 117 $ 5 値 Show 'AKD compounds made from fatty acids containing isostearic acid have shown the best properties at the lowest added amount, and give the highest hydrophobicity according to Cobbw and HST tests. The test results for evaluating the printability of black and white are shown in Table 6 "using an HP 500C inkjet printer to print test paper, and measuring the optical density of the printed matter. 15 This paper size is suitable for China China Standards ((:?) / \ 4 specifications (21〇 > <: 297 Gongchu) Pack one .--.---. 1T ---. 丨- -Line (Please read the precautions on the back before filling this page) Printed by the Ministry of Economy and the Central Bureau of Standards, Consumer Cooperatives, printed by the Ministry of Economic Affairs, the Central Bureau of Standards, the Consumers' Cooperative, printed by A7 __40500¾_B7 V. Description of the invention (丨 十) Table 6, spray Ink printing results, HP 560C printer surface glue additive amount of glue on the surface black and white printing: black density color sun combined with black density finishing paper 0 1.33 0.98 prepared surface glue _ powder 0 1.58 1.26 isostearic acid /-0.5 1.67 1.19 AKD stearic acid 1 1.76 1.22 2 1.85 1.31 4 1.86 1.32 Styryl acrylate 1 1.58 1.23 2 1.60 1.25 4 1.67 1.25 SMA 1 1.74 1.27 2 1.75 1.31 4 1.80 1.30 The printability is even better than the compounds commonly used for sizing on the surface of paper. Example 5 The surface sizing additive was also tested on a paper machine for intermediate testing, where a pond paper sizing machine and film paper sizing were used. Melter comes to stand without prior The surface glued paper is used for gluing. The paper finish is composed of a fine paper with a weight of 80 grams per square centimeter, and it contains 20% precipitated calcium carbonate as a finishing paper ( A common multi-purpose office paper) filler. The surface size used is an oxidized cationic surface starch (Raisamyl 405 SP, Raisio Chemicals Oy), which is an 8% consistency solution. The surface of the gum starch is different from that of the Hydrophobic surface sizing additive mix: basic AKD (palmitic acid / stearic acid, 60/40%), isostearic acid-stearic acid AKD (branched / unbranched, 50/50%), benzene Ethylene · acrylate (Raisafob P400 ·, Raisio Chemicals Oy) and SMA-based (--------- install 1 -----, 1τ · —ι ------- line (please (Please read the notes on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X297 mm > Printed by the Shellfish Consumer Cooperative of the China Fire Standards Bureau, Ministry of Economic Affairs, China 4505qQ3 _ ^ __ Description of the invention (I Ai) Phenylethylmaleic anhydride, Raisafob D100, Raisio Chemicals Oy) Surface sizing additive. Table 7 below contains intermediate test paper machines The test results, in which the paper sheet film size press. Table 7: Results of sizing using a film paper sheet sizing machine on an intermediate test paper machine. Surface sizing additive surface addition amount of ± 0% Cobb », g / cm2 HST (80%), finely broken surface in seconds. ± «0 42.3 143 powder S $ AKD 0.25 25.6 255 0.50 23.8 273 1 20.3 310 2 19.2 380 Isostearic acid / stearic acid 0.25 27.8 247 AKD 0.50 25.7 251 1 22.3 239 2 20.4 285 Styryl acrylate 2 30.8 223 4 25.6 229 SMA 2 25.3 266 4 21.1 282 Table 8 below contains the results of the inkjet printing test with paper 'wherein an HP 560C printer was used for printing. The print results were analyzed according to the dryness evaluation method. --------- Install a stack ------, 11 ---- > --- line (Please read the precautions on the back before filling out this page) (⑽) Λ4_ · (21GX 297 Gong Chu) 405003 at Β7 V. Description of the invention (IV) Table 8. Black and white printability on HP 560C printing machine. Black and white printing color printing surface. Additive density wicking drying time density penetration Scatter: area seepage: perimeter finishing + surface coating 1.07 2.1 1 0.95 49057 1834 basic AKD 0.5% 1.19 1.6 16 0.97 51103 2019 basic AKD 1.0% 1.22 1.5 24 0.98 49152 1923 isostearic acid / stearic acid AKD 0.50 % 1.18 1.6 7 0.97 48313 1913 Isostearic acid / stearic acid AKD 1.0% 1.21 1.5 13 0.98 47609 1898 Styryl acrylate 1.0% 1.14 1.8 2 0.95 47654 1847 Styryl acrylic vinegar 2.0% 1.14 1.7 4 0.96 47966 1821 SMA 1.0 % 1.20 1.6 17 0.96 47058 1808 SMA 2.0% 1.23 1.5 26 0.97 47099 1909 (Please read the notes on the back before filling out this page),-* Γ. Printed in Tables 7 and 8 by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Figures show that basic AKD has been given very well in the assessment survey Water-based results. However, high hydrophobicity may cause the colors to be too low to dry out, making the colors printed unevenly. These results seem to show that the use of isostearic acid / stearic acid AKD, which consists of branched and unbranched carbon chains, can achieve the best balance between the consumption of rubber, black and white printing, and color printing. 18 This paper size applies to Chinese National Standard (CNS) Λ4 specification (210X 297 mm)