TW397718B - The sintered body of continuous through holes using industrial waste and unused resources as major raw materials - Google Patents

The sintered body of continuous through holes using industrial waste and unused resources as major raw materials Download PDF

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Publication number
TW397718B
TW397718B TW87106743A TW87106743A TW397718B TW 397718 B TW397718 B TW 397718B TW 87106743 A TW87106743 A TW 87106743A TW 87106743 A TW87106743 A TW 87106743A TW 397718 B TW397718 B TW 397718B
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Taiwan
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continuous
sintered
sintered body
holes
slag
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TW87106743A
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Chinese (zh)
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Jiun-Rung Chiou
Takahiro Nagata
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Hocheng Corp
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  • Soundproofing, Sound Blocking, And Sound Damping (AREA)

Abstract

This is a sintered body with continuous through hole using industrial waste and unused resource as major raw material. It is made by mixing 5.0-30% of cement and water mixture, 0.1-1.0% of aluminum, 10-50% of glass furnace residue, shale, pearl stones, black stones, or ceramic bits, and 20-80% of glass dregs, fly ash, or clay. The result is a multi-pores body; which is sintered in a brick furnace at 1000-1250 DEG C. Furnace temperature is then decreased to form a sinter body with 10-500 mu m continuous pores. This sintered body has fine sound absorbency.

Description

經濟部中央標準局員工消費合作社印製 397718 五、發朋_説明(ί ) <技術領域> 本發明偽利用産業廢棄物及未利用資源做為原料,燒 結成一種耐火及酎侯性均佳的陶磁質體,其體内具有多量 的連續貫通孔,藉此提供一種吸音率高的大型剛體吸音材 料為其持徵者。 <既有技術> 在産業的運用上,將某些製品製成具有氣泡的組織, 並藉以達到輕量、隔熱、吸音或過濾的目的,是一揮很普 遍且常用的技術;如在水硬性水泥内部分散存在大量的汽 泡,使之輕量化的汽泡水泥(A L C )即是一例。現有技 術中欲在製品中彤成氣泡組織,可透過下列幾種方式;. 1.在製程中加入金屬鋁和鹼,藉由這兩種元素的反應 産生了氫氣瓦斯,將氫氣瓦斯存留在製品中成為氣泡形成 的來源。 2 .在類似泥漿的物質中加入界面活性劑或油脂類等之 起泡劑,並在混合過程中産生氣泡並存留於泥漿中。 3 .利用具有發泡能力的材料直接加入泥漿中混合攪拌 ,直接形成氣泡。 4.在産製陶瓷的過程中加入一些有機纖維物質,隨箸 陶瓷燒結過程將有機纖維燒失而殘留成空洞氣孔。 5 .以發泡樹脂為基材,將陶瓷漿液摻入其中;同樣經 過燒結過程,使成為一種具有孔洞的陶瓷燒結體。 上述幾種方法中,第1〜3項的氣泡是預先即存在於 混合物的内部並隨箸混合物凝固而形成氣孔;而第4〜5 本紙張尺度適用中國國家標準(CNS ) A4規格(210Χ:297公釐) (請先閲讀背面之注意事項再填寫本頁)Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 397718 Fifth, _Explanation (Technical Field) The invention uses industrial waste and unused resources as raw materials, sintered into a fire-resistant and weather-resistant The ceramic magnetic body has a large number of continuous through holes in the body, thereby providing a large rigid body sound absorbing material with high sound absorption rate as its holder. < Existing technology > In industrial applications, it is a very common and commonly used technology to make certain products into a structure with bubbles, and to achieve the purpose of light weight, heat insulation, sound absorption or filtering; such as in A large amount of air bubbles are dispersed in hydraulic cement, and light weight air bubble cement (ALC) is an example. In the prior art, if you want to form a bubble structure in the product, you can use the following methods: 1. Add metal aluminum and alkali in the process. The hydrogen gas is generated by the reaction of these two elements, and the hydrogen gas is retained in the product. Becomes the source of bubble formation. 2. Add foaming agents such as surfactants or greases to the mud-like substance, and generate bubbles during the mixing process and stay in the mud. 3. Use the material with foaming ability to directly add to the mud and mix and stir to form bubbles directly. 4. Add some organic fiber substances in the process of producing ceramics, and the organic fibers will be burnt out during the sintering process of ceramics, and will remain as voids. 5. The foaming resin is used as the base material, and the ceramic slurry is incorporated therein; the sintering process is also performed to make the ceramic sintered body with holes. In the above several methods, the bubbles of items 1 to 3 exist in the mixture in advance and form pores as the mixture solidifies; and the size of paper 4 to 5 applies to the Chinese National Standard (CNS) A4 specification (210 ×: 297 mm) (Please read the notes on the back before filling this page)

經濟部中央標隼局員工消費合作社印^ _^ 397718 五、發明説明(a) 項則是在燒成後才形成氣孔的;前者所形成的氣泡為彼此 不相連的獨立氣泡(如第一圖),後者則是呈毛細管狀, 並且管體是從内部貫通到外層面的貫通氣泡(如第二圖) 。現有幾種製造氣泡組織體的方式中,第1種在水泥中加 入金屬鋁及鹼的輕量化水泥,其凝結後的抗壓強度最大為 50kg / on2、彎曲強度最大則是2 Okg / c/,這樣的強度恃性 除非以内藏鋼筋來補強,否則超過900圆X 900咖之成形面 積就無法使用;再則,由於其成份只是金屬鋁、珪酸鈣等 化合物,長期經凍結、融解等氣侯侵襲,質地容易氧化而 變劣質,不適合屋外環境的使用;另外其氣泡大都為直徑 lm左右的獨立球狀氣泡,僅適用於室内的隔音材。第2 種以加入界面活性劑或油脂類等起泡劑來形成氣泡的方式 ,由於存在的獨立氣泡過多,其用途非常有限,大部只做 為輕量用材。第3種直接以氣泡材料攪拌所形成的氣泡過 大,對於尺寸在lOlUtm以下的微細氣泡是無法達成的。第 4種利兩有機物燒失形成氣孔的方式,其製品大都是做為 透水性的用途。第5種利用發泡樹脂浸滲陶瓷漿液的方式 ,其製品主要是做為金屬融爐的過濾材,其具有耐高溫的 特性。 <解決手段> 有鑑於既有技術所製成的氣泡組織體不是強度不足、 酎侯性不佳,就是氣泡的數量過多或尺寸太大以致於影鎏 其用途·,而具有適合的毛細管狀氣泡組織卻無法提供吸音 的能力;因此,本發明即是在提供一種具有從低周波到高 本紙乐尺度適用中国國家標準{ CNS ) Λ4規格(210X297公釐) (諳先閱讀背面之注意事項再填寫本頁) 裝- 、訂 經濟部中央標率局w工消费合作社印災 __:77 397718 五、發明説明(ό ) 周波均有高吸音率,且具有耐火、耐侯時性的陶瓷燒結體 ;該燒結體偽利用氣泡混合水泥的技術先在混合髏中形成 獨立的氣泡,然後在燒結時將預先加入於混合體中的産業 廢棄物加溫膨脹,利用這些膨脹物包圍並擠壓原已形成的 獨立氣泡,使之成為微細不規則狀但卻貫穿上下兩燒結後 表面的連續貫通孔。經由上逑製法所形成的燒結體同時可 採大型化的製作,其結構強度與一般的陶瓷吸音材不分軒 輊;又本發明在製作的用材上約有70%是採用産業廢棄物 ,對於産業廢棄物的處理及再生利用有很大的助益。以下 卽是本發明以數鍺較佳實施例的詳細說明; <圖式簡單説明> 第一圖偽獨立氣泡組織的剖視圖;Printed by the Employees' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs ^ ^ 397718 V. In the description of item (a), stomata are formed after firing; the bubbles formed by the former are independent bubbles that are not connected to each other (as shown in the first figure) ), The latter is capillary-shaped, and the tube body is a through-air bubble penetrating from the inside to the outer layer (as shown in the second picture). Among the several existing methods for manufacturing bubble structure, the first lightweight cement with metallic aluminum and alkali added to the cement has a maximum compressive strength of 50 kg / on after setting and a maximum of 2 Okg / c / Unless such strength is reinforced by built-in steel bars, the forming area exceeding 900 Yuan X 900 can not be used; furthermore, because its composition is only metal aluminum, calcium acetate and other compounds, it has been frozen and thawed for a long time. Invasion, the texture is easy to oxidize and deteriorate, and it is not suitable for outdoor environment. In addition, most of its bubbles are independent spherical bubbles with a diameter of about lm, which is only suitable for indoor sound insulation materials. The second method is to add foaming agents such as surfactants or oils to form bubbles. Because there are too many independent bubbles, their use is very limited, and most of them are only used as lightweight materials. The third kind of bubble formed by directly stirring the bubble material is too large, and it is impossible to achieve fine bubbles with a size of less than 101 Utm. The fourth method of stomata formation by burning the two organic compounds is mostly used for water permeability. The fifth method uses the foaming resin to impregnate the ceramic slurry. Its products are mainly used as filter materials for metal melting furnaces, which have the characteristics of high temperature resistance. < Solutions > In view of the fact that the bubble structure produced by the existing technology is either insufficient in strength and poor in weatherability, or the number of bubbles or the size is too large to affect its use, it has a suitable capillary. But the bubble-like tissue can not provide the ability to absorb sound; therefore, the present invention is to provide a paper with a scale from low frequency to high paper music applicable to the Chinese national standard {CNS) Λ4 specification (210X297 mm) (谙 Read the precautions on the back first (Fill in this page again.) Install-, order the disaster reduction of the Central Standards Bureau of the Ministry of Economic Affairs and Industrial Cooperatives. __: 77 397718 V. Description of the invention (ό) Zhou Bo has a high sound absorption rate, and has fire resistance, weather resistance, ceramic sintering The sintered body pseudo-uses the technology of air bubble mixing cement to form independent air bubbles in the mixed skull first, and then sinters the industrial waste added in the mixture in advance to heat and expand, and uses these expansions to surround and squeeze the original The independent air bubbles that have been formed make it a fine and irregular but continuous through hole that penetrates the upper and lower sintered surfaces. The sintered body formed by the top-up method can be produced at the same time, and its structural strength is not different from that of ordinary ceramic sound-absorbing materials; and about 70% of the materials used in the present invention are industrial waste. The treatment and recycling of waste is of great help. The following is a detailed description of the preferred embodiment of the present invention; < Simplified description of the drawings >

I 第二圖傜貫通氣泡組織的剖視圖; 第三圖傜本發明燒結體之剖視圔; 第四圖傜第三圖之局部放大圖。 〈元件符號說明〉 1 燒結體 10 表面 1 1 底面 1 2 連續貫通孔 &lt;較佳實施例説明&gt; 本發明製造一種具有連續貫通孔之燒結體的製造方法 有兩種,其一是將水泥與水的混合物5.0〜30.0%、金屬 鋁0 . 1〜1. 0%以及從玻璃質嫿渣、垃圾焚化爐渣、下水道 污泥焚化爐渣、頁岩、真珠岩、黑曜石、衛生陶瓷器屑、 瓷磚屑等任取一種以上约10〜5 0% ,和從玻璃碎暦、飛灰 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公« ) (錆先閱讀背面之注意事項再填寫本頁)I The second figure is a cross-sectional view of a through-bubble structure; the third figure is a cross-sectional view of a sintered body of the present invention; the fourth figure is a partial enlarged view of the third figure. <Description of Element Symbols> 1 Sintered body 10 Surface 1 1 Bottom surface 1 2 Continuous through holes &lt; Description of preferred embodiments &gt; The present invention has two methods for manufacturing a sintered body with continuous through holes, one of which is to cement Mixture with water 5.0 ~ 30.0%, metal aluminum 0.1 ~ 1.0%, and from glassy slag, waste incineration slag, sewage sludge incineration slag, shale, pearlite, obsidian, sanitary ceramics, tile dust Take any one or more of about 10 ~ 50%, and apply the Chinese National Standard (CNS) A4 specification (210X297) «from glass shattered and fly ash paper size (锖 Please read the precautions on the back before filling this page)

經濟部中央橾率局員工消费合作社印褽 A7 397718 B7 五、發明説明(φ ) 、拈土等任取一種以上約20〜80%充分混合,然後由金屬 鋁反應産生10〜5 0 0/w之連續貫通孔的多乳體,接著將多 孔體送入隊道窯中以1000〜12501C的溫度燒結2小時並於 爐中冷卻至常溫後取出,即為一具有連續貫通孔之陶瓷器 燒結體(如第三〜四圖)。 本發明製造一種具有連續賃通孔之燒結體的3—製造 方法是將水硬性水泥5.0〜3G.G%、金屬鋁粉末0.1〜1.0 %以及從玻璃質爐渣、垃圾焚化爐渣、下水道污泥焚化爐 渣、頁岩、真珠岩、黑曜石、衛生陶瓷器屑、瓷磚屑等任 取一種以上約10〜50% ,和從玻璃碎屑、飛灰、粘土等任 取一種以上約2^〜80%充分均勻混合,然後加入適量的水 並調合成軟泥狀;再將軟泥狀物填入成型模内並使之發泡 、成型;接箸將成型物以常溫至Π 〇 °C的溫度予以烘乾; 最後將乾燥的成型體送入隧道窯中以1000〜1250¾的溫度 燒結2小時並於爐中冷卻至常溫後取出,即為一種如第三 〜四圖所示的具有連續貫通孔之陶瓷器燒結體。 在上述的製法中,水泥的用量傜取決於製成品的強度 和經濟性;而金屬鋁與水泥的用量比則是決定氣泡含量的 多寡,在一般狀態下偽0 . 1〜1 · 0%的比例,而本發明較佳 的比例為〇 . 3〜〇 . 5¾ ; 3外,本發明製法中所·添加的壚渣 、黑曜石、頁岩等傺做為膨脹材料之用,這些材料在加溫 至1 (3 Q 0 °C以上時即開始膨脹以擠壓先前形成的氣泡變成細 管狀的孔隙;因此本發明的燒结溫度必須超過1GQ()_sc,但 不得超過12〇〇°C ,以.¾燒.结體的i容融部彳分 '過-多而失去本發 本纸伕尺度適用中國國家標準(CN’S)A4規格(2丨0x297公釐) (請先閲讀背面之注意事項再填寫本頁)Employees' Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs, A7 397718 B7 V. Description of invention (φ), ocher, etc. Take any one or more of about 20 ~ 80% and mix them thoroughly, and then produce 10 ~ 50 0 / w by the reaction of aluminum metal The multi-emulsion with continuous through-holes, and then the porous body is sent into a line tunnel kiln and sintered at a temperature of 1000-12501C for 2 hours and cooled in a furnace to normal temperature. Then, it is taken out as a ceramic sintered body with continuous through-holes ( (Figures 3 to 4). The present invention manufactures a sintered body with continuous through-holes. The manufacturing method is to incinerate hydraulic cement 5.0 ~ 3G.G%, metal aluminum powder 0.1 ~ 1.0%, and incineration from glassy slag, waste incineration slag, sewage sludge Slag, shale, pearlite, obsidian, sanitary ceramic shavings, tile shavings, etc. are about 10 ~ 50%, and about 2 ^ ~ 80% of glass shards, fly ash, clay, etc. Mix, then add an appropriate amount of water and mix to form a slime; then fill the slime into the mold and foam and mold it; then dry the molded product at a temperature between normal temperature and Π 0 ° C; finally The dried molded body is sent into a tunnel kiln and sintered at a temperature of 1000 ~ 1250¾ for 2 hours and cooled out in the furnace to normal temperature. Then, it is taken out, which is a ceramic sintered body with continuous through holes as shown in Figures 3 ~ 4. . In the above manufacturing method, the amount of cement depends on the strength and economy of the finished product; and the ratio of the amount of metal aluminum to cement is to determine the amount of air bubbles, in the general state of false 0.1 ~ 1 · 0% 3 ~ 〇. 5¾; 3 In addition, the added slag, obsidian, shale, etc. used in the production method of the present invention are used as expansion materials, these materials are heated to 1 (above 3 Q 0 ° C, it will begin to expand to squeeze the previously formed bubbles to become thin tubular pores; therefore, the sintering temperature of the present invention must exceed 1GQ () _ sc, but must not exceed 1200 ° C. ¾ Burning. The volume of the volume is too much and the paper is lost. The standard of China National Standard (CN'S) A4 (2 丨 0x297 mm) is applicable. (Please read the notes on the back before filling (This page)

、1T 397718 五、發明説明(5) 明的特歡。再者,本發明製法中所加入的玻璃屑、飛灰、 粘土類是為固定氣泡形態及促進硬化之用;因為在實施時 當水與水泥的比例在0.7〜1.0的範圍時,水泥漿硬化的速 度較慢,這時形成的氣泡容易破滅,因此添加上逑材質充 作硬化促進劑使水泥漿的硬化速度加快;相同於上述硬化 促進劑的材料尚有鹽化鈣(CaCl)、水硬性鋁条(C3A、C/2A、 CA)、珪酸鈣条(CA3SiOs(C3S)、CaSi03(CS)及白水泥等; 另外在本發明製法中加入0 . 1〜0. 2%的合成樹脂類高分子 粘著劑,&amp;有助於氣泡含量的調整。 在以下的表1中,本發明經由各成份以不同比率的添 加製成了6値樣品,然後以這6個樣品完成了其各物性的 測試(表2 ),以及這6鍤樣品在低周波到高周波的吸音 率和此吸音率與傳统利用氣泡混合水泥所製成的吸音材之 吸音率的比較(表3 );另外這6値樣品的平均物性和傳 統陶瓷吸音板的物性比較則在表4 ;請參閲下列各表: _ &gt; (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員Η消費合作社印製 本纸伕尺度送用中國國家標準(CNS ) Α4規格.(210X297公漦), 1T 397718 V. Description of the invention (5) Ming Huan. Furthermore, the glass chips, fly ash, and clays added in the manufacturing method of the present invention are used to fix the shape of bubbles and promote hardening; because when the ratio of water to cement is in the range of 0.7 to 1.0 during implementation, the cement slurry hardens The speed is relatively slow, and the air bubbles formed at this time are easy to burst. Therefore, the addition of the top material as a hardening accelerator will accelerate the hardening speed of the cement slurry. The same materials as the above hardening accelerators include calcium chloride (CaCl) and hydraulic aluminum 1% ~ 0.2% of synthetic resin-based polymers (C3A, C / 2A, CA), calcium acetate strips (CA3SiOs (C3S), CaSi03 (CS) and white cement, etc.) Adhesive, &amp; helps to adjust the bubble content. In Table 1 below, the present invention made 6 値 samples by adding each component at different ratios, and then completed the physical properties of these 6 samples. Test (Table 2), and the sound absorption of the 6 锸 samples from low frequency to high frequency and the comparison of the sound absorption with the sound absorption materials made of traditional air-blend cement (Table 3); the other 6 値 samples Average physical properties and traditional ceramic sound absorption The comparison of physical properties is shown in Table 4; please refer to the following tables: _ &gt; (Please read the precautions on the back before filling out this page) Member of the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperative, printed this paper, and sent it to the Chinese National Standard (CNS) Α4 specifications. (210X297 males)

A B 397718 五、發明説明(g) 經濟部中央標準局員工消贤合作社印製 樣品 成 份 鑄鐵爐渣 0.5画以下 焚化爐渣 0.5_以下 玻璃碎屑 0.5_以下 水泥 金屬錦 VS. 水泥比 合成樹脂粒 2-3臓 H01 30 15 30 25 0.2 — H02 45 一 30 25 0.5 — N03 45 — 27 25 0.5 3 樣品 膨潤土 玻璃纖維 紙漿 N04 30 5 30 30 0.3 — 5 H05 30 5 30 30 0.5 5 — 樣品 起泡劑 N06 ' 30 5 30 30 5 0.5 〔表二〕燒結體之物性 樣品 容積比重 氣孔率 (%) 強 度 (kg / CB?) 氣孔尺寸分渖 N01 0.75 68. 1 70 5 0/^〜2 5 0々· N02 0.62 73.5 52 5 0/&lt;_ 〜5 0 0/λ H03 0.60 75 . 5 48 5 〇a〜3 aun N04 0.55 81. 0 35 5 0/&lt;〜2 0 N05 0.48 86 . 0 30 5 0,〜 2 0 0a N06 0.41 8 7.5 26 5 0/λ〜2 0 Oyu (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標隼(CNS ) A4規格(210X 297公釐) 397718 五 經濟部中央標準局員工消f合作社印製 發明説明(7) 〔表三]吸音特性AB 397718 5. Description of the invention (g) Samples printed by the staff of the Central Standards Bureau of the Ministry of Economic Affairs, Xiaoxian Cooperative, cast iron, slag, incineration slag below 0.5 drawing, glass slag below 0.5_, glass slag below 0.5_, cement ratio VS. 3 臓 H01 30 15 30 25 0.2 — H02 45 — 30 25 0.5 — N03 45 — 27 25 0.5 3 Sample bentonite glass fiber pulp N04 30 5 30 30 0.3 — 5 H05 30 5 30 30 0.5 5 — Sample foaming agent N06 ′ 30 5 30 30 5 0.5 [Table 2] Physical properties of the sintered body Volumetric specific gravity Porosity (%) Strength (kg / CB?) Stomatal size analysis N01 0.75 68. 1 70 5 0 / ^ ~ 2 5 0々 · N02 0.62 73.5 52 5 0 / &lt; _ ~ 5 0 0 / λ H03 0.60 75. 5 48 5 〇a ~ 3 aun N04 0.55 81. 0 35 5 0 / &lt; ~ 2 0 N05 0.48 86. 0 30 5 0, ~ 2 0 0a N06 0.41 8 7.5 26 5 0 / λ ~ 2 0 Oyu (Please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210X 297 mm) 397718 The Ministry of Economic Affairs, Central Bureau of Standards, the staff of the cooperative, printed a description of the invention (7) [Table 3] Sound absorption characteristic

周波數據 (Hz) 200 (Hz) 300 (Hz) 500 (Hz) 750 (Hz) 1000 (Hz) 2000 (Hz) 3000 (Hz) 氣泡混合水泥吸音材 52 85 97 94 91 87 85 樣 Nol 20 40 60 80 92 75 90 No2 30 55 70 85 98 70 85 No3 30 58 72 85 98 85 95 No4 45 72 86 90 90 82 80 No5 50 80 90 93 91 90 90 σ 口口 No6 55 84 95 95 93 90 92 j_1_|_I_1_I_1_L 〔表4〕本發明燒結體與陶瓷吸音板的物性比較 比較品 容積比重. (gr/ CC) 氣孔率 (%) 彎曲強f (kg / oa2) 本發明樣品1〜6 0 · 4 1 〜0 . 7 5 68· 1 〜87.5 2S〜70 陶瓷趿音板 i 1. 4〜1. 5 f 40 7 0 I 'f (請先閲讀背面之注意事項再填寫本頁)Frequency data (Hz) 200 (Hz) 300 (Hz) 500 (Hz) 750 (Hz) 1000 (Hz) 2000 (Hz) 3000 (Hz) Bubble mixed cement sound absorbing material 52 85 97 94 91 87 85 sample Nol 20 40 60 80 92 75 90 No2 30 55 70 85 98 70 85 No3 30 58 72 85 98 85 95 No4 45 72 86 90 90 82 80 No5 50 80 90 93 91 90 90 σ mouth No6 55 84 95 95 93 90 92 j_1_ | _I_1_I_1_L [Table 4] Physical properties of the sintered body and ceramic sound-absorbing plate of the present invention are compared. Volumetric specific gravity. (Gr / CC) Porosity (%) Bending strength f (kg / oa2) Samples of the present invention 1 to 6 0 · 4 1 to 0 . 7 5 68 · 1 ~ 87.5 2S ~ 70 Ceramic sound board i 1. 4 ~ 1. 5 f 40 7 0 I 'f (Please read the precautions on the back before filling in this page)

裝------訂-------- J 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 397718 五、發明説明(2) 由表3的數據可以看出,以傳統氣泡混合水泥吸音材 在各周波的吸音率為基準,本發明之燒結樣品No 1〜Nc 3在 高周波區域具有良好的吸音率,而Mo4〜Mo6在低周波的吸 音率則有較佳的表現。 由表4的數據則可看出,本發明燒結樣品No 1〜No 3和 陶瓷吸音板的物性比較上,無論就本體之比重ί輕量與·否 )或氣孔的比率都呈現較優的物性,至於抗彎曲的強度也 能達到和陶瓷吸音板一樣,因此用以取代陶瓷吸音板至為 恰當,綜上所逑,本發明燒結體具有如下的幾項特徵; 1.氣孔率60%以上、容積比重0.7gr/cc以下,為一 種輕量、酎熱、耐侯性均佳的甩材。 2 .具有10〜5 0 連續貫通氣孔分布,吸音恃性佳 ,適合做為從低周波到高周波的各種音域之吸音材使用,: 3 .利用將近70%成份的廢秦物做為製造用材,能節省 資源耗»暨任進産業翳棄物的有效處理。 - . ..一...... 4 .可以藉此製造大型的陶瓷燒結板(6 0 0關X 6 QQmni X 5 Qm ) ,增加産品的利用價值。 (請先閩讀背面之;1意事哼再填寫本頁) 裝- 、v5 經濟部中央標率局負工消费合作社印裝 本紙張尺度適用中囱國家標準(CNS ) A4規格(210X 297公楚)------ Order -------- J This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) 397718 V. Description of the invention (2) From the data in Table 3, you can see Based on the sound absorption ratio of traditional bubble-mixed cement sound-absorbing materials at various frequencies, the sintered samples No. 1 to Nc 3 of the present invention have good sound absorption in the high frequency region, while Mo4 to Mo6 have relatively low sound absorption in the low frequency. Good performance. From the data in Table 4, it can be seen that the physical properties of the sintered samples No. 1 to No. 3 of the present invention and the ceramic sound absorbing plate show superior physical properties regardless of the proportion of the body (light weight or not) or the ratio of pores. As for the bending strength, it can reach the same as that of the ceramic sound-absorbing board. Therefore, it is appropriate to replace the ceramic sound-absorbing board. In summary, the sintered body of the present invention has the following features: 1. Porosity is 60% or more, The volume specific gravity is below 0.7gr / cc, which is a kind of lightweight, heat-resistant and weather-resistant throwing material. 2. It has a continuous through-hole distribution of 10 ~ 50, good sound absorption, and is suitable for use as a sound absorbing material in various frequency ranges from low frequency to high frequency: 3. Using waste materials of nearly 70% content as manufacturing materials, Can save resource consumption »and effective disposal of industrial waste. -.. I ... 4. This can be used to manufacture large ceramic sintered plates (600 off X 6 QQmni X 5 Qm), increasing the value of product use. (Please read the back of the book first; please fill in this page before filling in this page.) Packing-, v5 The printed paper size of the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, printed paper standards are applicable to the National Standard (CNS) A4 specification (210X 297) Chu)

Claims (1)

g 397718 D8 經濟部中央樣準局員-消費合作社印製 六、申請專利範圍 1. 一種以産業廢棄物及未利用資源為主原料所製造之 具有連續貫通孔之燒結體,其製法是 取水泥與水的混合物5.0〜30.0%、金屬鋁0.1〜1.0 %以及從玻璃質爐渣、垃圾焚化爐渣、下水道污泥焚化爐 渣、頁岩、真珠岩、黑曜石、衛生陶瓷器屑、瓷磚屑等任 取一種以上10〜50%,和從玻璃碎屑、飛灰、粘土等任取 —種以上20〜80%加以充分混合後形成具有連绩貫通孔之 多孔體;多孔體經〜125010的溫度燒結2小時並在爐 中降至常溫狀態後取出。 2 . —種以産業廢棄物及未利用資源為主原料所製造之 具有連續貫通孔之燒結體,其製法是; 取水硬性水泥5.0〜30.0%、金屬鋁粉末0.1〜1.0% 以及從玻璃質爐渣、垃圾焚化爐渣、下水道污泥焚化爐渣 、頁岩、真珠岩、黒曜石、衛生陶瓷器屑、瓷磚屑等任取 —種以上10〜50%,和從玻璃碎屑、飛灰、粘土等任取一 - .... 種以上20〜80%加以充分均勻混合,然後加入適量的水調 合成軟泥狀;軟泥狀物槙入成型模中進行發泡成型;成型 物以常溫至11 〇 C的溫度烘乾,再將烘乾的成型體以1 〇 0 0 〜1 2 5 0 °C窯燒2小時並在爐中降至常溫狀態後取出。 3.如申請專利範圍第1項或第2項製法的嬈結體内部 具有10〜50G/^的連續貫通孔。 (請先閲讀背面之注意事項再填寫本頁) 11 、1T -L.:\ If .A— · 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐&gt;g 397718 D8 Printed by the Central Procurement Bureau of the Ministry of Economic Affairs-Consumer Cooperatives 6. Scope of Patent Application 1. A sintered body with continuous through-holes manufactured by using industrial waste and unused resources as the main raw materials. The manufacturing method is to take cement and Water mixture 5.0 ~ 30.0%, metal aluminum 0.1 ~ 1.0%, and any one or more selected from glassy slag, waste incineration slag, sewage sludge incineration slag, shale, pearlite, obsidian, sanitary ceramics, ceramic tile, etc. 10 ~ 50%, and randomly selected from glass shards, fly ash, clay, etc.-more than 20 ~ 80% of these are thoroughly mixed to form a porous body with continuous through-holes; the porous body is sintered at a temperature of ~ 125010 for 2 hours and sintered at Remove from the furnace after dropping to room temperature. 2. A kind of sintered body with continuous through-holes manufactured with industrial waste and unused resources as the main raw materials, the method is: take hydraulic cement 5.0 ~ 30.0%, metal aluminum powder 0.1 ~ 1.0%, and glassy slag , Waste incineration slag, sewage sludge incineration slag, shale, pearlite, vermiculite, sanitary ceramic swarf, tile swarf, etc.-10 to 50% of the above types, and any one from glass shards, fly ash, clay, etc. -.... More than 20 ~ 80% of the above species are mixed thoroughly and evenly, and then an appropriate amount of water is added to prepare a soft mud; the soft mud is poured into a mold for foam molding; the molded product is baked at a temperature of normal temperature to 11 ℃ After drying, the dried molded body is kiln-fired at 1000 ~ 125 ° C for 2 hours, and then taken out in the furnace to a normal temperature state. 3. As in the first or second manufacturing method of the patent application scope, the inside of the body has a continuous through hole of 10 ~ 50G / ^. (Please read the notes on the back before filling this page) 11 、 1T -L.: \ If .A— · This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm &gt;
TW87106743A 1998-04-30 1998-04-30 The sintered body of continuous through holes using industrial waste and unused resources as major raw materials TW397718B (en)

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TWI465300B (en) * 2012-12-12 2014-12-21 Stone & Resource Ind R & D Ct Method for manufacturing lightweight bulk materials
TWI731556B (en) * 2020-01-17 2021-06-21 財團法人工業技術研究院 Porous material and method for preparing the same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI465300B (en) * 2012-12-12 2014-12-21 Stone & Resource Ind R & D Ct Method for manufacturing lightweight bulk materials
TWI731556B (en) * 2020-01-17 2021-06-21 財團法人工業技術研究院 Porous material and method for preparing the same
CN113135767A (en) * 2020-01-17 2021-07-20 财团法人工业技术研究院 Porous material and preparation method thereof
US20210221746A1 (en) * 2020-01-17 2021-07-22 Industrial Technology Research Institute Porous material and method for preparing the same
CN113135767B (en) * 2020-01-17 2022-12-13 财团法人工业技术研究院 Porous material and preparation method thereof
US11767271B2 (en) 2020-01-17 2023-09-26 Industrial Technology Research Institute Porous material and method for preparing the same

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