TW396605B - Manufacturing method of metal capacitor constrcuture - Google Patents
Manufacturing method of metal capacitor constrcuture Download PDFInfo
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- TW396605B TW396605B TW87117812A TW87117812A TW396605B TW 396605 B TW396605 B TW 396605B TW 87117812 A TW87117812 A TW 87117812A TW 87117812 A TW87117812 A TW 87117812A TW 396605 B TW396605 B TW 396605B
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五、發明說明(1) ' ----- 一锸2明係有關於—種半導體裝置之製程,特別有關於 合動態隨機存取記憶體(咖)金屬電容結構和部分 邏輯裝置之製造方法。 番,ί ί ί ’半導體晶片係同時整合邏輯裝置和記憶袭 …欠ί-裝置係用來處理資訊或資料,記憶裝置則用來進 :i二儲存’此兩種裝置目前被大量應用到電腦系統,然 m裝置和'己憶裝置—般被分別封裝在各自之特定晶片 ,因此兩者間之資料信號在傳遞上就會有所延遲此 “士只製造邏輯晶片和只製造記憶晶片之晶圓,其生 產f本遠大於整合邏輯裝置和記憶裝置於相同晶片者,因 ^二ΐ成本和性能的考量’半導體業者必須製造一種整合 邏輯裝置和記憶裝置之半導體晶片。 此外,在先刖技術中,如美國第5,6 2 7,〇 9 5號專利, 係指述-種電谷結構,然而其使用之複晶妙電容結構並 不符邏輯裝置製程所需。 ,鑑於此本發明之一構想係提出一種適用於DRA Μ單疋之電容結構’其1^] 線結構^時形成 ,如此可同時整合邏輯裝置和記 憶裝置於同一半導體晶片上,以增加性能並減少製造成 本。 本發明之特徵在於炙儲存結構 時,成_ D-这粪,以及用於攞短裝 。而用於電容儲存節點之低阻值金屬材料,也可同時 用於鄰接邏輯裝置之連線。V. Description of the invention (1) '----- 1 ~ 2 is related to the manufacturing process of a semiconductor device, especially to a dynamic random access memory (MAC) metal capacitor structure and a manufacturing method of some logic devices . Fan, ί ί '' Semiconductor chip system integrates logic device and memory at the same time ... ίί-device is used to process information or data, memory device is used to: i two storage 'These two devices are currently widely used in computers The system, however, the m device and the 'memory device' are generally packaged on their own specific chips, so the data signal between the two will be delayed. Round, its production f is much larger than those who integrate logic devices and memory devices on the same chip, because of the cost and performance considerations, semiconductor manufacturers must manufacture a semiconductor chip that integrates logic devices and memory devices. In addition, prior technology In the United States, Patent No. 5,6 27,095 refers to a kind of valley structure, but the complex capacitor structure used by it does not meet the logic device manufacturing process. In view of this, one of the inventions The idea is to propose a capacitor structure suitable for the DRA M single cell, its 1 ^] line structure is formed at the same time, so that the logic device and the memory device can be integrated on the same semiconductor chip at the same time. It increases performance and reduces manufacturing cost. The present invention is characterized in that when the storage structure is heated, it becomes _ D- this dung, and is used for short installation. The low-resistance metal material used for capacitor storage nodes can also be used at the same time. Connection of logic devices.
C:\ProgramFiles\Patent\0503-3574-E.ptd第 4 頁 五、發明說明(2) 日只 + 造方法,a你—的在於提供一種〇11八1^電容結構之製 輯裝署於二用一些-同m來製造M〇SFET和邏 铒裝置於同一半導體晶片。 避 構之二目的是製造一使用金屬栓塞和内連線結 元線結構之全屬::f結構’冋時製造形成於D R Α Μ位 再ι金屬栓塞和内連線結構。 結構上Ϊ—目的是藉由在下層之金屬检塞和内連線 储ίΐ 口加金屬检塞和内連線結·,以形成。… 供-ί=ΐ;::ίΐ::法依ΐ第—實施例,本發明提 極結構導及體上底之位置形成-電晶體,包括一問 隙壁=—第區絕Λ潭極, 少取弟一絕緣層以覆蓋雷曰脚„, 第-絕緣層中,同時形成一位於儲:二導體基底’·在 位於位元線區之接觸窗,其暴 之:之接觸窗及- 以分別與對應之源"及極區形成接觸广在开第成一、= 刀別與儲存節點區及位元線區之第—砉 成接觸;形成一第二絕緣層以霜#筮,Η栓塞表面形 一内連線結構;在第二絕緣層中形成-栓塞,以與儲存節點區之第一内連線結構形成接 觸,在第二絕緣層表面’形成一第二内連線結冑其與儲C: \ ProgramFiles \ Patent \ 0503-3574-E.ptd page 4 5. Description of the invention (2) Japanese + manufacturing method, a you-is to provide a system of capacitor structure of 011 and 8 ^ The second one uses some-the same m to manufacture MOSFETs and logic devices on the same semiconductor wafer. The second purpose of the avoidance structure is to manufacture a genus that uses metal plugs and interconnecting wire element structures:: f structure ', which is formed at the position D R Α Μ and metal plugs and interconnecting wire structures. Structural Ϊ—The purpose is to form metal plugs and interconnects at the lower layer and add metal plugs and interconnects. … For -ί = ΐ; :: ίΐ :: method according to the first embodiment of the present invention, the electrode structure of the present invention and the position of the upper and lower body are formed-transistor, including a gap wall In order to cover the thunder leg, the first insulation layer is formed, and at the same time, a contact window located in the storage: two-conductor substrate is formed in the bit line area, and its contact window and- In order to form contact with the corresponding source " and the polar region, respectively, the first contact between the knife and the storage node region and the bit line region is formed; the second insulating layer is formed with frost # 筮, Η A plug structure is formed on the surface of the plug; a plug is formed in the second insulation layer to make contact with the first interconnect structure in the storage node area, and a second interconnect structure is formed on the surface of the second insulation layer. Its and Chu
C:\Program Files\Patent\0503-3574-E.ptd第 5 頁 存節點區之第_ 覆蓋第二絕缘屬栓塞形成接觸;形成H -第三金眉:層和第二内連線結構;在ί第二絕緣層以 接觸;除i ί 以與儲存節點區之S -二絕緣層中形成 金屬拴塞、g Γ '絕緣層*部/分之第連線結構形成 作為儲存節點:2連線結構、和第二金屬痊塞f:出第三 區之第—肉^頂部,而第二金屬栓塞夕塞之上部,以 絕 在暴露之儲存:ΪΓ第一栓塞則作為错點 緣層表面形成-上形成一電容絕緣層;及在ΐ; 造方^$二實施例,本發明提供另— 屬栓塞、其依據前述製帛,在第三絕緣屬電容結構製 :ί;;:另在第二絕緣層表面形成第三金 存即點之表面積。 接觸,糟此可增加儲 Μ制此外,依據第三實施例,本發明之另^ Λ Κ 構製造方法,it用於一半導體Α底月種金屬電容結 ,既定位置形成一電晶體,包導體基 區;在開極結構之上表面形成一::及極 壁形成一絕緣間隙壁.护# $ @ ,在閘極、,吉構夂側 半導體美麻.户: 第一絕緣層以覆蓋電晶體及 區之自ί對準接觸;】緣:二位同:形成-位於儲存節點 办〇觸及於位兀線區之自我對準接觸 :暴露出對應之源/没極區;在儲存節點區與位 區之自我對準接觸窗中同時形成一複晶矽接觸栓塞以 別與對應之源/汲極區形成接觸;形成一第二絕緣乃C: \ Program Files \ Patent \ 0503-3574-E.ptd page 5 of the storage node area _ covering the second insulating plug to form contact; forming the H-third golden eyebrow: layer and second interconnecting structure; The second insulation layer is contacted; except i, a metal plug is formed in the S-second insulation layer of the storage node area, and the g Γ 'insulation layer * part / minute of the first connection structure is formed as the storage node: 2 Wire structure, and the second metal recovery plug f: the top of the third zone-the meat ^ top, and the second metal plug above the plug, to be stored in the exposed: ΪΓ the first plug is used as the surface of the wrong point margin layer Forming-forming a capacitor insulation layer; and in the second embodiment of the invention, the present invention provides another-a plug, which is based on the foregoing system, and the third insulation is a capacitor structure system: ί ;: The surface of the second insulating layer forms the surface area of the third gold spot. In addition, according to the third embodiment, another manufacturing method of the ^ κ structure of the present invention is used for a semiconductor A metal capacitor junction at the end, and a transistor is formed at a predetermined position to cover the conductor. Base area; an upper surface is formed on the open electrode structure: and an insulating gap wall is formed on the electrode wall. Guard # $ @, at the gate electrode, the side of the semiconductor structure is beautiful. The first insulating layer covers the transistor. The self-aligned contact of the contact area;] edge: the two are the same: formed-located at the storage node office. The self-aligned contact that touched the position line area: exposed the corresponding source / impulse area; A polycrystalline silicon contact plug is simultaneously formed in the self-aligned contact window of the bit region to make contact with the corresponding source / drain region; a second insulation is formed.
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C:\Program Files\Patent\0503-3574-E.ptd第 6 頁 五、發明說明(4) 儲存節點S ί :及=曰矽接觸栓塞’·在第二絕緣層中,於 與储存口:第一金屬检塞,其分別 觸;在第-絕緩居Γί 接觸栓塞上表面形成接 面:::;!點區及位元線區形 ;-金屬…表面形成;:了 區=線,之 在第三絕緣声中凡線區之第-内連線結構; 儲存節點區形成-第二金屬栓塞,以虫 ,·名&之弟一内連線結構形丞Μ興 面,於儲存節點區形成—第二内連盖,^二絕緣層表 區之第二金屬栓塞形成接觸 二;絕:與儲存節點 j絕緣層和第二内連線結構層以覆蓋第 區形成-第三金屬栓塞,以與 層中之儲存節點 除去第四絕緣層和部分之第:、f邑結構形成接觸;C: \ Program Files \ Patent \ 0503-3574-E.ptd page 6 V. Description of the invention (4) Storage node S 及: and = silicon contact plug 'In the second insulation layer, between the storage port and the storage port: The first metal test plug, which respectively touches; a contact surface is formed on the upper surface of the first-stop contact plug :::;! Dot area and bit line area shape; -Metal ... surface formation ;: area = line, where the line area in the third insulation sound-the first interconnecting structure; storage node area formation-the second metal plug to Insect, the first name of the amp & an internal connection structure is formed in the storage node area-the second internal connection cover, the second metal plug in the surface area of the second insulation layer to form contact two; absolutely: and storage The node j insulation layer and the second interconnect structure layer are formed to cover the first region-the third metal plug, so as to make contact with the storage node in the layer except the fourth insulation layer and a part of the f, e structure;
窠、坌 . 乐—絕緣層,暴露出笙-A ::二内連線結構、和第二金屬 出第二金屬检 之頂,,而之下*、作為儲 點之庙線結構、第一金屬栓塞和複晶矽栓塞貝I:點區之第 及=部;在暴露之儲存節點之頂部形成 ^為儲存節 及在電容絕緣層表面形成一上金屬板。 電谷絕緣層; 其中,閘極結構上表面夕、奋# a < 氮η材質形成’第'絕緣層㈡隙壁“ 景:和選擇性蝕刻製程可蝕刻氧化矽材 【一如此藉由微 形成暴露源/汲極區之自我對準接觸窗、第一絕緣層,可 以下,就圖式說明本發明之實施例。固 頁 c:\Program F i1es\Patent\0503-3574-E. Ptd 第 7 五、發明說明(5) 圖式簡單說明 第1至8圖係顯示太 表面區域之電容儲存節:明之一 f 一實施例中,形成於-表面區域係包括-當點結構之製程步驟剖面圖’其中該 •〜、这5 4冉 金屬連線、和一第二 形成於一 ’其中該 第一金屬 以填入 表面區域係包括一篦 . 金屬栓塞上部。 金屬栓塞 第9-n圖係顯示本發明之一第二實 表面區域之電容儲存銘 ψ 表面區域係包括一第—結構之製程步驟剖面圖 ^ < 楚-Α Η» —金屬連線結構’一 栓塞、和一弟二金屬检塞上部9 第12-14屬係顯示太找 複晶妙接觸栓塞之自^三實施射,以填入 構至源極區。 我對準接觸窗來連楚DRAM金屬電赛結 [符號說明] 半導體基底七場氧化層~2;開 閘極〜4 ;絕緣罩幕〜5 ;闡 緣層J,複日日矽 〜7 . P卩p右辟《 . β仏 巧極、·,α構〜6 ;淡換雜源/没極區 〜7,間隙壁〜8 ’濃摻雜源/汲極區~ 夂 18、25;金屬栓塞〜u、12、16、19;^::: 元線金屬結構〜13;金屬内連線結構]4、17、2 .!二 H54;電容絕緣層〜2〇; 口 :層, 複晶矽栓塞〜31。 開口〜30, 實施例 一種製造DRAM電容結構之製程’包括一 結構’其中隨著金屬儲存節點結構,可 郎點 線結構,且同時形成金氧半電晶體(M〇SFET)位元 科哀置的元窠, 坌. Le-insulation layer, exposed Sheng-A :: two internal connection structure, and the second metal to the top of the second metal inspection, and below *, the temple line structure as a storage point, the first Metal plugs and polycrystalline silicon plugs I: the first and the third part of the dot area; a storage node is formed on the top of the exposed storage node and an upper metal plate is formed on the surface of the capacitor insulation layer. Electric valley insulation layer; Among them, the upper surface of the gate structure Xi, Fen # a < Ni η material to form a 'first' insulating layer gap wall "scene: and selective etching process can etch silicon oxide materials [One such The self-aligned contact window and the first insulating layer forming the exposed source / drain region can be illustrated in the following, and the embodiment of the present invention is illustrated below. C: \ Program F i1es \ Patent \ 0503-3574-E. Ptd Fifth, the description of the invention (5) Brief description of the drawings Figures 1 to 8 show the capacitor storage section of the too-surface area: one of the f. In one embodiment, the process steps formed on the -surface area include the -point structure Sectional view 'where the • ~, this 5 4 Ran metal line, and a second formed on a' where the first metal to fill the surface area includes a stack. The upper part of the metal plug. Figure 9-n of the metal plug Shows the capacitance storage inscription of the second real surface area of the present invention. The surface area includes a cross-sectional view of the first process step of the structure ^ < Chu-Α Η »-metal connection structure 'a plug and a second The upper part of the metal plug 9 The 12th to 14th genera shows that it is too complex The contact plugs were shot from ^ 3 to fill the structure to the source region. I aligned the contact window to connect the DRAM metal electric junction [Symbol Explanation] Seven field oxide layer of the semiconductor substrate ~ 2; Opening gate ~ 4; Insulation screen ~ 5; Interpretation margin layer J, day-to-day silicon ~ 7. P 卩 p right edge ". Β 仏 craft pole, ·, α structure ~ 6; light-changing heterogeneous / non-polar area ~ 7, gap wall ~ 8 'Densely doped source / drain region ~ 夂 18, 25; metal plugs ~ u, 12, 16, 19; ^ ::: element wire metal structure ~ 13; metal interconnect structure] 4, 17, 2 . Two H54; Capacitor insulation layer ~ 20; Mouth: layer, polycrystalline silicon plug ~ 31. Opening ~ 30, Example A manufacturing process for manufacturing a DRAM capacitor structure 'including a structure' where a metal storage node structure can be used Lang dotted line structure, and at the same time forming a metal oxide semiconductor (MOS transistor)
五、發明說明(6^ —---- 電曰曰其詳述如下。其中,本發明所用於DRAM裝置之傳輸閘 曰=體’為—N通道或NFET裝置,但也可&pFET傳輸閘 曰曰體。 第1圖係顯示一用MDRAM裝置之NFET傳輸 —P型輩曰访访—,A r , 节刊J丨甲J电日日肢 為3平印矽基底1為一 [1 〇 〇 ]方向,形成之場氧化區2則作 ^石5離之用,其中場氧化區2係藉沈積一氮化石夕層於一氧 石夕層之上’並使用傳統微影製程和非等向性R I E製程來 /成由氮化矽-氧化矽組成之氧化罩幕(〇xidati〇n S、k) ’再以氧電漿去灰製程(plasma oxygen ashing)除 光阻,隨之進行濕姓刻,並藉由溫度約在8 5 〇至1 〇 5 〇。匚 ^含氧環境下進行氧化,以在未被氧化罩幕覆蓋之區域形 ,場氧化層2,厚度約為300 0至5 0 00埃。作為氧化罩幕之 虱化矽層可以熱磷酸溶液蝕刻去除,隨之並去除在其下屛 之氧化矽層。 、曰 所欲形成之隔離區也可以是淺溝槽隔離結構,其先藉 由傳統微影製程和非等向性RIE製程以在半導體基底中形曰 成淺溝槽,之後藉由低壓化學氣相沈積(LPCVD)或電漿氣 相沈積(PECVD)製程沈積一絕緣層,如氧化矽層,然後藉 由選擇性蝕刻或化學機械研磨製程(CMP)來除去不要的絕 緣層,形成一填充絕緣材料之淺溝槽隔離區(未顯示)。 其次,一閘極絕緣層3 ’由氧化矽層組成,其在氧蒸氣環 境下熱氧化形成’溫度約為7 0 0到1 〇 5 0。(:,厚度約為3 〇到 100埃。接著可以LPCVD製程沈積形成一複晶梦W二溫度 約為50 0到65 0 °C ’厚度約為1 500到4000埃。或者複晶石/層V. Description of the invention (6 ^ —---- Electricity is described in detail below. Among them, the transmission gate of the DRAM device used in the present invention is-N channel or NFET device, but it can also be & pFET transmission The gate is shown in Figure 1. Figure 1 shows an NFET transmission using a MDRAM device—P-type generation visit—A r, Section J 丨 甲 J Electric sun and sun limbs are 3 lithographic silicon substrates 1 is a [1 〇]] direction, the formed field oxidation area 2 is used for the ^ stone 5 separation, of which the field oxidation area 2 by depositing a nitride stone layer on the oxide layer and using traditional lithography process and non- The isotropic RIE process comes / forms an oxide mask (〇xidati〇n S, k) composed of silicon nitride-silicon oxide, and then removes the photoresist by the plasma oxygen ashing process. Wet engraved and oxidized at a temperature of about 850 to 1050. 匚 ^ oxidized in an oxygen-containing environment to form an area not covered by the oxidation mask, field oxide layer 2, thickness is about 300 0 Up to 5000 angstroms. The siliconized silicon layer as an oxidation mask can be removed by etching with a hot phosphoric acid solution, and then the silicon oxide layer underlying it is removed. The isolation region can also be a shallow trench isolation structure, which is firstly formed into a shallow trench in a semiconductor substrate by a conventional lithography process and an anisotropic RIE process, and then by low pressure chemical vapor deposition (LPCVD) or The plasma vapor deposition (PECVD) process deposits an insulating layer, such as a silicon oxide layer, and then removes the unnecessary insulating layer by selective etching or chemical mechanical polishing (CMP) to form a shallow trench isolation filled with insulating material. (Not shown). Secondly, a gate insulating layer 3 'is composed of a silicon oxide layer, which is formed by thermal oxidation under an oxygen vapor environment. The temperature is about 700 to 1050. (:, the thickness is about 3 〇 to 100 angstroms. Then LPCVD can be deposited to form a polycrystalline dream. The temperature is about 50 0 to 65 0 ° C. The thickness is about 1 500 to 4000 angstroms. Or polycrystalline spar / layer
C:\ProgramFiles\Patent\0503-3574~E.ptd第 9 頁C: \ ProgramFiles \ Patent \ 0503-3574 ~ E.ptd page 9
五、發明說明(7) 4可在矽甲烷環境下增加砷或磷以隨同沈積反應(in_si tu) 進行摻雜,複晶矽層4也可先行沈積,然後藉由離子植入 法進行磷或砷離子摻雜。此外,若有低字元線阻值的需 要’複晶矽層4能以複晶矽化金屬層取代,例如藉由在複 曰曰石夕層上沈積如石夕化鶴之金屬石夕化物層而形成。最後,使 用LPCVD或PECVD製程沈積絕緣層5,其包括有氧化矽物或 氮化矽物,厚度約為5 〇 〇到1 5 〇 〇埃。 另以傳統微影和RIE蝕刻製程,例如以四氟化碳(c &) 為氮化矽層5之蝕刻氣體(三氟甲烷CHF3可作為氧化矽層4之 蝕刻氣體),和以氣氣為複晶矽層或複晶矽金屬層4之蝕刻 氣體進行蝕刻,以定義一具有絕緣上表面5之閘極結構6, 如第1圖所示。 其次,在藉由氧電漿去灰和濕式清洗來除去用來定義 複晶矽閘極結構4之光阻後,淡摻雜源/汲極區7係藉由磷 或砷離子植入半導體基底丨中未被複晶矽閘極結構6覆蓋之 區域形成,其植入能量約為25到50KeV,劑量約為1£13到 5E14 at〇ms/cm2,接著,一用以作為後續間隙壁8之絕緣 層,、包括氮化矽材質,係再度藉由“以1)或1)£:(^1)製程沈積 形成2厚度約為1〇〇〇至3〇〇〇埃。間隙壁8所用之絕緣層也 可化矽材質,並藉由LPCVD或pECVDt程沈積獲得, 經由非等向β IE蝕刻製程,如以三氟甲炫A ' 技 氣T況马亂化石夕層之蝕 刻现體(或以三亂甲烷作為氧化矽層之蝕刻氣體),以 晶矽閘極結構6之側壁上形成絕緣間隙壁8,最後,如 圖所示,濃摻雜源/汲極區9係藉由磷或砷離子植入半導體V. Description of the invention (7) 4 The arsenic or phosphorus can be added in the silicic methane environment to be doped with the deposition reaction (in_situ). The polycrystalline silicon layer 4 can also be deposited first, and then phosphorus or Arsenic ion doping. In addition, if there is a need for a low word line resistance, the polycrystalline silicon layer 4 can be replaced with a polycrystalline silicon silicide layer, for example, by depositing a metal lithium oxide layer such as a stone xihua crane on a composite shixi layer And formed. Finally, the insulating layer 5 is deposited using a LPCVD or PECVD process, which includes silicon oxide or silicon nitride, and has a thickness of about 500 to 15 Angstroms. In addition, traditional lithography and RIE etching processes are used, for example, carbon tetrafluoride (c &) is used as the etching gas for silicon nitride layer 5 (trifluoromethane CHF3 can be used as the etching gas for silicon oxide layer 4), and Etching is performed on the etching gas of the polycrystalline silicon layer or the polycrystalline silicon metal layer 4 to define a gate structure 6 having an insulating upper surface 5 as shown in FIG. 1. Secondly, after removing the photoresist used to define the polycrystalline silicon gate structure 4 by oxygen plasma deashing and wet cleaning, the lightly doped source / drain region 7 is implanted into the semiconductor by phosphorus or arsenic ions The area in the substrate 丨 that is not covered by the polycrystalline silicon gate structure 6 is formed with an implantation energy of about 25 to 50 KeV and a dose of about 1 £ 13 to 5E14 at 0 ms / cm2. Then, one is used as a subsequent gap wall The insulation layer of 8, including silicon nitride material, is again deposited by a "1) or 1) £: (^ 1) process to form a thickness of about 1000 to 3000 angstroms. The spacer 8 The insulating layer used can also be made of silicon material and obtained by LPCVD or pECVDt process deposition, through an anisotropic β IE etching process, such as the etched body of the fossil evening layer with trifluoromethane A 'technology gas T condition (Or use three random methane as the etching gas for the silicon oxide layer), and form an insulating spacer 8 on the side wall of the crystalline silicon gate structure 6. Finally, as shown in the figure, the heavily doped source / drain region 9 is formed by Phosphorus or arsenic ions implanted into semiconductors
C:\ProgramFiles\Patent\0503-3574-E.ptd第 1〇 頁 五、發明說明(8) 基底1中,其植入能量約為2 0到8 0 K e V,劑量約為1 E 1 5到 5E15 atoms / cm2 〇 請參閱第2圖,一絕緣層1 〇,包括氧化矽層,係藉由 LPCVD或PECVD製程沈積形成,厚度約為loooo至20000埃。 化學機械研磨製程被用來平坦化絕緣層丨〇,形成一平滑之 上表面,微影和以三氟甲烷為蝕刻氣體之非等向性rie製 程 了用以在絕緣層1 0中之位元線區開設一位元線接觸窗 51,和在儲存節點區開設一儲存節點接觸窗52,其暴露源 /汲極區9的上表面,在藉由氧電漿去灰和濕式清洗來除去 用來定義接觸窗51、52之光阻後,形成一栓塞n、12,其 中栓塞11、12可為一以LPCVD製程沈積形成之複晶矽層/、 f度約為3000至loooo埃,其用以完全地填入位元線接觸 窗51和儲存節點接觸窗5 2。或者複晶矽層可在矽曱烷環境 下增加砷或磷以隨同沈積反應(in-situ)進行摻雜。另外 複晶矽層能以金屬材料取代,例如藉由LPCVD或減鍵沈積 之金屬鎢層。隨之,從絕緣層10表面以CMp製程或選擇性 姓刻來除去不要的複晶矽或金屬鎢層,進而在位元線接觸 窗^中形成位元線接觸栓塞丨1,以及在儲存節點接觸窗52 中形成儲存節點接觸栓塞1 2。此外,在形成金屬鎢層時另 可在其表面形成一阻障層,例如氮化鈦層,以提升鶴金屬 之附著能力。 請參閲第3圖,其顯示在位元線區和儲存節點區同時 形成之位元線.金屬結構13和DRAM金屬内連線結構14,沈積 之金屬材料如鎢金屬,可藉由LPCVD或射頻濺鍵製程形C: \ ProgramFiles \ Patent \ 0503-3574-E.ptd page 10 V. Description of the invention (8) In the substrate 1, the implantation energy is about 20 to 80 K e V, and the dose is about 1 E 1 5 to 5E15 atoms / cm2 〇 Please refer to FIG. 2. An insulating layer 10, including a silicon oxide layer, is formed by a LPCVD or PECVD process and has a thickness of about loooo to 20,000 angstroms. The chemical mechanical polishing process is used to planarize the insulating layer, forming a smooth upper surface. The lithography and anisotropic rie with trifluoromethane as the etching gas are used to place the bit in the insulating layer 10. A wire contact window 51 is opened in the wire area, and a storage node contact window 52 is opened in the storage node area, which exposes the upper surface of the source / drain region 9 and is removed by ash removal and wet cleaning with an oxygen plasma. After defining the photoresist of the contact windows 51 and 52, a plug n, 12 is formed, wherein the plug 11, 12 can be a polycrystalline silicon layer formed by LPCVD process, and the degree of f is about 3000 to loooo, which It is used to completely fill the bit line contact window 51 and the storage node contact window 52. Alternatively, the polycrystalline silicon layer can be doped with in-situ by adding arsenic or phosphorus in a siloxane environment. In addition, the polycrystalline silicon layer can be replaced with a metal material, such as a metal tungsten layer deposited by LPCVD or reduced bond. Then, the unnecessary polycrystalline silicon or metal tungsten layer is removed from the surface of the insulating layer 10 by a CMP process or selective engraving, and a bit line contact plug 1 is formed in the bit line contact window ^, and a storage node is formed. A storage node contact plug 12 is formed in the contact window 52. In addition, when a metal tungsten layer is formed, a barrier layer, such as a titanium nitride layer, may be formed on its surface to improve the adhesion of crane metal. Please refer to FIG. 3, which shows bit lines formed in the bit line area and the storage node area at the same time. The metal structure 13 and the DRAM metal interconnect structure 14 are deposited with a metal material such as tungsten metal by LPCVD or RF sputtering process
五、發明說明(9) f =約為1〇〇〇至500 0埃。微影製程和 程’可用來同時形成-與位元線接觸 栓塞11接觸之位儿線金屬結構13,以及一與儲存節點 栓塞12接觸之DRAM金屬内連線結構η。 請參閱第4圖,藉由氧電漿去灰和濕式清洗來除去用 來定義的光阻後,一絕緣層丨5,如氧化矽層,係藉由 LPCVD或PECVD製程沈積形成,厚度約為1〇〇〇〇至2〇9〇〇〇埃, 然後利用CMP製程進行平坦化。微影製程和以三氟甲院為 姓刻來源之非等向性RIE製程,係用以在絕緣層丨5中開言史 一介層窗53,其暴露DRAM金屬内連線結構14之上表面,藉 由氧電衆去灰和濕式清洗來除去用來定義介層窗53之光阻 後’一金屬層,如金屬鎢層,係藉由LPCVI)或射頻濺鍍製 程沈積形成’厚度約為2000至5000埃,其完全填入介層窗 53。其次,可利用選擇性RIE製程或CMP製程來除去在絕緣 層表面15不要之金屬材料’以在介層窗53中形成dram金屬 栓塞16。 接著’請參閱第5圖,另一金屬層,如金屬鎢層,係 藉由LPCVD或射頻濺鍍製程沈積形成,厚度約為1〇〇〇至 500 0埃’然後藉由微影和非等向性rie製程以在DRAM金屬 栓塞16表面形成與之接觸的DRAM金屬内連線結構17。其中 形成介層窗53和DRAM金屬内連線結構17時,亦同時形成用 在MOSFET邏輯裝置的介層窗和金屬内連線結構,此m〇sFET 邏輯裝置係和DRAM記憶裝置設在相同的半導體晶片上,其 並未顯示於圖中。V. Description of the invention (9) f = about 1000 to 5000 Angstroms. The lithography process and process can be used to simultaneously form a bit line metal structure 13 in contact with the bit line plug 11 and a DRAM metal interconnect structure η in contact with the storage node plug 12. Please refer to Figure 4. After the photoresist used to define the photoresist is removed by oxygen plasma deashing and wet cleaning, an insulating layer, such as a silicon oxide layer, is formed by LPCVD or PECVD process deposition, and the thickness is about The thickness is 10,000 to 29,000 angstroms, and then planarized by a CMP process. The lithography process and the anisotropic RIE process with trifluoromethane as the source of engraving are used to open the history-intermediate window 53 in the insulation layer 5 and expose the upper surface of the DRAM metal interconnect structure 14 After removing the photoresist used to define the interlayer window 53 by oxygen ash removal and wet cleaning, a metal layer, such as a metal tungsten layer, is formed by LPCVI) or RF sputtering process to form a thickness of about It is 2000 to 5000 Angstroms, which completely fills the interlayer window 53. Next, a selective RIE process or a CMP process can be used to remove the metal material 'unnecessary on the surface 15 of the insulating layer to form a dram metal plug 16 in the interlayer window 53. Then 'see Fig. 5. Another metal layer, such as a metal tungsten layer, is formed by LPCVD or RF sputtering with a thickness of about 1,000 to 50,000 angstroms', and then by lithography and non-equivalent. The directional RIE process is performed to form a DRAM metal interconnect structure 17 on the surface of the DRAM metal plug 16 in contact therewith. When the via window 53 and the DRAM metal interconnect structure 17 are formed, the via window and the metal interconnect structure used in the MOSFET logic device are also formed at the same time. The MOSFET logic device system and the DRAM memory device are arranged in the same It is not shown on the semiconductor wafer.
C:\Program Files\Patent\0503-3574-E.ptd第 12 頁 五、發明說明(10) ---- 請參閱第6圖,再度藉由氧電漿去灰和濕式清洗來除 去用,定義這些金屬内連線結構的光阻後,一絕緣層丨8', 包括氧化矽層,係藉由LPCVD或PECVD製程沈積形成7厚声 約為1 0 0 0 0至20 0 00埃,並利用CMP製程進行平坦化。;" 製程和非等向性RIE製程則用來開設一介層窗54,其位於; 絕緣層18中,並暴露dram金屬内連線結構17之上表面。— 金屬層,如金屬鎢層,係再度藉由“口1)或射頻濺鍍製一 沈積形成,厚度約為200 0至5000埃,其完全地填入 * 54,利用選擇性RIE製程㈣p製程可除去在絕緣層18^ 不要之金屬材料,以在介層窗54中形成DRAM金屬栓塞Η。 其中,介層窗54和DRAM金屬栓塞19的形成,係屬於 MOSFET邏輯裝置之最後一層金屬層形成後之附加步驟, 過,在考量有關金屬栓塞和内連線結構的層數和順序時, 排除具有高縱寬比且難以填入金屬材料特性的深介戶 窗。 曰 請參閱第7圖,暴露部分的金屬栓塞和金屬内 構以作細AM電容結構的儲存節點。坦覆式除去絕緣層^ 和絕緣層15的上部約1 00 0至15〇〇〇埃,用以暴露⑽^金 栓塞19、DRAM金屬内連線結構17、和DRAM金屬栓塞“的上 部約〇至1〇〇〇埃。除去這些絕緣層可利用選擇性rie姓刻製 ^完成’其可以三氟甲燒為蚀刻來源,或者利用緩衝d 心#刻液亦可完成去除的動作’這些金屬栓塞和内連線社 構的暴露表面·將作為DRAM電容結構的儲存節點表面,而藉° 由破入絕緣層W金屬检塞和内連線結構,可使儲存節點壯C: \ Program Files \ Patent \ 0503-3574-E.ptd Page 12 V. Description of the invention (10) ---- Please refer to Figure 6 and remove again by oxygen plasma deashing and wet cleaning. After defining the photoresist of these metal interconnect structures, an insulating layer, including 8 ', including a silicon oxide layer, is deposited by LPCVD or PECVD process to form a thick sound with a thickness of about 100 to 2000 Angstroms. The CMP process is used for planarization. The " process and the anisotropic RIE process are used to open a via window 54 which is located in the insulating layer 18 and exposes the upper surface of the dram metal interconnect structure 17. — A metal layer, such as a metal tungsten layer, is again formed by "port 1" or radio frequency sputtering with a thickness of about 200 to 5000 angstroms, which is completely filled in * 54, using a selective RIE process and a pp process. The unnecessary metal material in the insulating layer 18 ^ can be removed to form a DRAM metal plug Η in the via window 54. The formation of the via window 54 and the DRAM metal plug 19 is the last metal layer formed by the MOSFET logic device. In the latter additional step, when considering the number and order of layers regarding metal plugs and interconnect structures, deep mediator windows with high aspect ratios and difficult to fill in the characteristics of metal materials are excluded. Please refer to Figure 7, The metal plug and metal internal structure of the exposed part are used as storage nodes of the fine AM capacitor structure. The insulating layer ^ and the upper part of the insulating layer 15 are removed approximately 1000 to 150,000 angstroms to expose the gold plug. 19. The upper part of the DRAM metal interconnect structure 17, and the DRAM metal plug "is about 0 to 1000 angstroms. Removal of these insulating layers can be engraved using a selective rie surname ^ it can be trifluoromethane fired as an etching source, or it can be removed by using a buffer solution. These metal plugs and interconnects The exposed surface will be used as the storage node surface of the DRAM capacitor structure, and the storage node can be made stronger by breaking through the insulation layer, the W metal plug, and the interconnect structure.
五 '發明說明(11) 構連接到半導體基底。 仆物5t參閱Ϊ8圖,一電容絕緣層20,如氧化钽,鋇鈦氧 成勒相冰说制 等,可藉由MOCVD(meta卜organic CVD) 靥,、項、"鍍衣程沈積形成,厚度約為4到50埃,一金屬 金屬鶴層,係藉由LPCVD或射頻濺錢製程沈積形 為1〇〇°至100 00埃,最後,利用微影製程和非 .1 衣程形成一上金屬板21,藉由氧電漿去灰和濕 κί來t去用來定義上金屬板21的光阻後’完成DRAM金 〜5令結構,其包括上金屬板21、電容絕緣層2 0、和儲存 =點結構,儲存節點結構依序由DRAM金屬栓塞1 9、金 屬内連線結構17、和DRAM金屬栓塞16的上部組成。 、本發明之第二實施例顯示於第9至11圖,其為一用來 增加DRA^I金屬電容結構之表面積的方法,其依據第6圖之 第了實施例’在嵌入絕緣層之堆疊金屬栓塞和内連線結構 上增加另一DRAM金屬内連線結構。 ^ —請配合第6圖並參閱第9圖,一金屬層,如金屬鎢層, 係藉由LPCVD或射頻濺鍍製程沈積形成,厚度約為2〇〇〇至 5 0 0 0埃’其次’利用微影製程和非等向性RIE製程形成一 DRAM金屬内連線結構22 ’其位於DRAM金屬栓塞丨9表面並與 之接觸’最後’藉由氧電漿去灰和濕式清洗來除去用來定 義DRAM金屬内連線結構22的光阻。 請參閱第10囷,和先前第一實施例相同的製程,除去 絕緣層1 8和絕緣層1 5的上部約2 〇 〇 〇至1 5 〇 〇埃,除去這些絕 緣層可利用選擇性R IE蝕刻製程完成,其可以三氟曱烷為The five 'invention description (11) is connected to a semiconductor substrate. Refer to Figure 8 for the servant 5t. A capacitor insulation layer 20, such as tantalum oxide, barium titanium oxide, etc., can be formed by MOCVD (meta organic CVD), coating, " coating process deposition. , The thickness is about 4 to 50 angstroms, a metal metal crane layer, deposited by LPCVD or radio frequency sputtering process to 100 ° to 100,000 angstroms, finally, using the lithography process and non-.1 clothing process to form a The upper metal plate 21 is deoxidized and wet with oxygen plasma. It is used to define the photoresistance of the upper metal plate 21 to complete the DRAM gold ~ 5 order structure, which includes the upper metal plate 21 and the capacitor insulation layer. And storage = point structure, the storage node structure is composed of DRAM metal plug 19, metal interconnect structure 17, and the upper part of DRAM metal plug 16 in order. 2. The second embodiment of the present invention is shown in FIGS. 9 to 11, which is a method for increasing the surface area of the DRA ^ I metal capacitor structure. It is based on the embodiment of FIG. 6 'stacking embedded in the insulation layer. Add another DRAM metal interconnect structure to the metal plug and interconnect structure. ^ — Please refer to Figure 6 and refer to Figure 9. A metal layer, such as a metal tungsten layer, is deposited by LPCVD or RF sputtering process and has a thickness of about 2000 to 5000 Angstroms. A lithography process and an anisotropic RIE process are used to form a DRAM metal interconnect structure 22 'which is located on the surface of the DRAM metal plug 9 and is in contact with it' finally 'by oxygen plasma deashing and wet cleaning to remove The photoresist of the DRAM metal interconnect structure 22 is defined. Please refer to Section 10 (b). The same process as in the previous first embodiment, removing the insulating layer 18 and the upper part of the insulating layer 15 from about 2000 to 15 Angstroms, and removing these insulating layers can use the selective R IE The etching process is completed.
C:\ProgramFiles\Patent\0503-3574-E. ptd第 14 頁C: \ ProgramFiles \ Patent \ 0503-3574-E. Ptd page 14
蝕刻來源。而用以暴露第10圖之儲存節點結構, DRAM金屬内連線結構22、難金屬栓塞⑺ ^ 、和DRAM金屬检塞16的上部。堆叠於二=連 額外增加的DRAM金屬内連線結構22,係用以增 J點之 且因此可增加電容和性能。 面積, 第11圖顯示一完整的⑽“電容結構,由於辦 金屬内連線結構22,使得表面積隨之增加,其中電c ,20 ::上金屬板21,係和先前第8圖之第一實:用緣 同之製程和材料。 」便用相 請參閱/12圖,第三實施例係使用自我對準接觸窗 (),’、;|於各閘極結構之間並填入有複晶矽栓塞, 與源/汲極區接觸,和鎢栓塞或傳統直徑較窄之接觸 比,在自我對準接觸窗中使用複晶矽栓塞,可以改善 漏電流m2圖所示’其顯示一為平坦化】 蓋的閘極結構6。 本增25覆 請參閱第1 3圖,位於儲存節點區及位元線區之 ΠΓα窗Γ篡係以問極結構6之氮化石夕遮蔽層5和氬化石夕間 隙土8為罩幕,並稭由微影和選擇性蝕刻製程蝕刻氧化矽 材質之第一絕緣層25,形成暴露源/汲極區9之自 觸窗30。例如SAC開口 30可藉微影製程和以三氟甲 刻來源之選擇性RIE製程形成,其中,利用氮化石夕間隙㈣ 和氮化矽層5為罩幕,藉由三氟甲烷為蝕刻來源之選擇性 RIE製程,可在各閘極結構間之絕緣層25中蝕刻形成sac開 口,且其寬度大於閘極結構之間隔。隨之沈積—複晶矽層Etching source. And to expose the storage node structure of FIG. 10, the DRAM metal interconnect structure 22, the hard metal plug ⑺, and the upper part of the DRAM metal plug 16. Stacked on two = connected additional DRAM metal interconnect structure 22 is used to increase the J point and therefore can increase capacitance and performance. Area, Figure 11 shows a complete ⑽ "capacitor structure, due to the metal interconnect structure 22, which increases the surface area, in which the electric c, 20 :: on the metal plate 21, the same as the first of the previous Figure 8 Reality: use the same process and materials. "Please refer to Figure / 12. The third embodiment uses self-aligned contact windows (), ',; | between the gate structures and fill in the complex Crystal silicon plug, contact with the source / drain region, and tungsten plug or traditional narrower contact ratio. The use of polycrystalline silicon plug in the self-aligned contact window can improve the leakage current m2. Flattening] Covered gate structure 6. Please refer to Fig. 13 for the 25th increase. The ΓΓα window Γ located in the storage node area and the bit line area is covered by the nitrided layer 5 of the interfacial structure 6 and the interstitial soil 8 of the argonized group. The lithography and selective etching process etch the first insulating layer 25 made of silicon oxide to form a self-contact window 30 that exposes the source / drain region 9. For example, the SAC opening 30 can be formed by a lithography process and a selective RIE process using a trifluoromethyl engraving source. Among them, a nitride nitride gap and a silicon nitride layer 5 are used as a mask, and trifluoromethane is used as an etching source. In the selective RIE process, a sac opening can be formed by etching in the insulating layer 25 between the gate structures, and the width is larger than the interval between the gate structures. Deposition followed-polycrystalline silicon layer
C:\ProgramFiles\Patent\0503-3574-E.ptd第 15 頁 五、發明說明(13) 31 ’如使用矽曱烷為氣體來源而以LPCVD製程沈積形成, 厚度約為3 0 0 0至7 0 0 0埃,以完全填入S AC開口 3 0,複晶矽 層31可在矽甲烷環境下增加砷或磷以隨同沈積反應 (in-si tu)進行摻雜’或者複晶矽層31也可先行沈積,然 後藉由離子植入法進行填或珅離子摻雜。另利用選擇性 ίΠ E製程或CMP製程可除去在絕緣層2 5表面不要之複晶矽材 料’以在SAC開口30中形成經摻雜之複晶矽栓塞31,坌盥 源/汲極區9接觸。 =參閱第14圖’如先前所述’其包括相同的元件,如 一相同之金屬栓塞和内連線結構形成之堆疊 中堆疊儲存節點藉由在SAC開口中填入經摻雜4 ·· ’ /、 塞以連接到源/没極區,因此可改呈接&、b ” 日日石夕栓 雖然本發明已以一較佳實施例揭接露面如属電流之問題。 以限定本發明,任何熟習此技藝者,在、,然其並非用 神和範圍内,當可作些許之更動與潤不脫離本發明之精 護範圍當視後附之申請專利範圍所界本因此本發明之保 义者為準。C: \ ProgramFiles \ Patent \ 0503-3574-E.ptd page 15 V. Description of the invention (13) 31 'If silazane is used as a gas source and deposited by the LPCVD process, the thickness is about 3 0 0 0 to 7 0 0 0 Angstroms, in order to completely fill the S AC openings 30, the polycrystalline silicon layer 31 can be added with arsenic or phosphorus in a silicon methane environment to be doped with the deposition reaction (in-si tu) or the polycrystalline silicon layer 31 It can also be deposited first, and then filled or doped with erbium ions by ion implantation. In addition, selective selective E process or CMP process can be used to remove the polycrystalline silicon material unnecessary on the surface of the insulating layer 25 to form a doped polycrystalline silicon plug 31 in the SAC opening 30, and the source / drain region 9 contact. = Refer to Figure 14 'as described previously' which includes the same elements, such as a same metal plug and interconnect structure formed in a stack storage node by filling the SAC opening with doped 4 ·· '/ The plug is connected to the source / inverted region, so it can be changed to connect &, b ”Riri Shi Xishuan Although the present invention has been exposed in a preferred embodiment as an issue of current. To limit the present invention, Anyone who is familiar with this skill can use the scope of God and the scope, but can make some changes and embellish it without departing from the scope of the present invention. The righteous shall prevail.
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