五、發明説明（1 ) A7 B7 _本發明係關於揭示一種水泥摻合組合物，更特 而言之係關於一種用於水凝水泥 (Hydraulic,Cement)之組合物。例如對硫酸鋇，重 金屬污泥，火山灰，及農工業或家庭廢棄物等，予以 處理凝結硬化。其與一般混凝土所處理形成之凝 結體相較，經本摻合物之添加可避免流動性隨著時 聞而減少，並增其密度與抗壓強度，並可同時改良承 受超過時間之組合物的應用性。 ! 在混凝土工業上，重陷損失已成爲最大問題， 已有許多硏究人員嘗試各種方法，爲解決此重大問 題。因此發現一種解決該問題之方法，實爲當務之 急 〇· ;V::'. 眾所皆知，燒稀醚與順丁烯二酸和其所衍生物之 共聚物，可當作水泥添加劑，用來改良重陷損失，可 是前述共聚物之使用，僅是稍爲改良重陷損失或造 成經處理水泥組合物過度凝固延遲。 < H. 1!-. !. I II n—^ίν^· Hi In I (請先閲讀背面之注意事項再填寫本頁) 訂 線 經濟部中央標準局員工消費合作社印製 經長時間之硏究發現,以一特定之化合物等 組成的組合物，不但可不造成明顯凝固延遲，且可 有效地抑制重陷損失，並可增加水泥組合物密度及 抗壓強度，可有效解決混凝土工業所產生重陷損失 之問題。 3 本紙张只度適用中®固家標準（CNS ) A4规格（210'〆297公费） A9 B9 C9 D9 五、發明説明（2 ) 本發明係提供一種水泥摻合組合物，該組合物 係由鹼金屬或鹼土金屬及錳、鈷、鎳、銅等之金屬 鹵化物，或其水合物與鹼金屬硫化物等族群中選出組 合而成。 本發明特定水泥摻合組合物，其所形成之水泥組 合物，可超過承受時間，具高度重陷損失，明顯地改良 可用性或實用性，但並未使經處理組合物凝固時間顯 著延長。 本發明克服上述習知之問題，提供一種對各種 處理對象，均可用同一手段達成其目的之硬化用水泥 組合物之摻合組合物。 I,---^------Γ-I裝-----丨訂------r 線 - 、 (請先閲讀背面之注意事項再行繪掣) 經濟部中央標準局員工消費合作社印製 4 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A9 B9 C9 D9 五、發明説明（3 ) 本發明詳沭 本發明係提供一種可使水泥組合物，例如： 硫酸鋇'重金屬污泥'火山灰及農工業與家庭廢棄 物等混凝土組合之具高流動性，並且在不明顯延遲水 泥組合物硬化（Curing)情況下，超過延遲時間，提供高 流動性.利用本發明所述水泥摻合物，可順利的達到 該性質之提昇。 本發明之摻合組合物，是一種可增進抑制重陷 損失所須之水泥用新穎組合物，該組合物包括由一種 通式（Ι)Μ2Β407其中Μ爲鹼金屬原子,及鹼金屬鹵化 物，鹼土金屬鹵化物，及鋅、錳、鐵、鈷、鎳、銅等 金屬鹵化物，或前述化合物之水合物的族群中選出組 成。 本發被之組合物中最適用之金屬鹵化物 如:LiCh NaC卜 NaBr、KBr、MgCI2、SrCI2、ZnCI2、 NiCI2、CuCI2、MnCI2、ZnCI2 等。 (請先閲讀背面之注意事項再行繪製) -裝- 訂* •線 經濟部中央標隼局員工消費合作社印製 5 本紙掁尺度適用中國國家摞準（CNS〉A4規.格（210X297公潑） A9 B9 C9 D9 五、發明説明（4 ) 而對添加劑的調配組合係由 (a)鹼金屬氯化物 鹼金屬調配溴化物 鹼金屬硼酸鹽 選取一或多種予以組合 (b)鹼土金屬氯化物 鹼土金屬溴化物V. Description of the invention (1) A7 B7 _ The present invention relates to revealing a cement admixture composition, and more particularly to a composition for hydraulic cement (Cement). For example, barium sulfate, heavy metal sludge, volcanic ash, and agro-industrial or household waste are treated for coagulation and hardening. Compared with the aggregate formed by the treatment of general concrete, the addition of the admixture can prevent the fluidity from decreasing with time, and increase its density and compressive strength, and can simultaneously improve the composition of the composition that withstands over time. Applicability. In the concrete industry, subsidence losses have become the biggest problem, and many researchers have tried various methods to solve this major problem. Therefore, it is urgent to find a way to solve this problem. V :: '. It is well known that the copolymer of burned ether and maleic acid and its derivatives can be used as a cement additive. To improve the subsidence loss, the use of the aforementioned copolymers only slightly improves the subsidence loss or causes excessive retardation of the treated cement composition. < H. 1!-.!. I II n— ^ ίν ^ · Hi In I (Please read the precautions on the back before filling out this page). It was found that a composition composed of a specific compound not only does not cause a significant solidification delay, but also effectively suppresses the subsidence loss, and can increase the density and compressive strength of the cement composition, which can effectively solve the problems caused by the concrete industry. Recapture the problem of losses. 3 This paper is only applicable to China® Standards for Households (CNS) A4 specifications (210'〆297 public expense) A9 B9 C9 D9 V. Description of the invention (2) The invention provides a cement blending composition, which is composed of Alkali metals or alkaline earth metals, metal halides such as manganese, cobalt, nickel, copper, or their hydrates and alkali metal sulfides are selected and combined. The specific cement admixture composition of the present invention can form a cement composition that can withstand the time and has a high degree of subsidence loss, which significantly improves the usability or practicability, but does not significantly increase the curing time of the treated composition. The present invention overcomes the above-mentioned conventional problems and provides a blended composition of a hardening cement composition that can achieve its purpose by the same means for various treatment objects. I, --- ^ ------ Γ-I equipment ----- 丨 order ------ r line-(Please read the precautions on the back before drawing) Central standard of the Ministry of Economy Printed by the Bureau's Consumer Cooperatives 4 This paper size is applicable to Chinese National Standard (CNS) A4 specifications (210X297 mm) A9 B9 C9 D9 V. Description of the invention (3) The invention is detailed. The invention provides a cement composition, For example: Barium sulfate 'heavy metal sludge' volcanic ash and concrete combinations such as agricultural and household waste have high fluidity, and without significantly delaying the curing of the cement composition (Curing), it will exceed the delay time to provide high fluidity. By using the cement admixture of the present invention, the improvement of this property can be smoothly achieved. The blend composition of the present invention is a novel composition for cement which can improve the loss of collapse subsidence. The composition includes a general formula (I) M2B407, where M is an alkali metal atom, and an alkali metal halide, The composition is selected from the group of alkaline earth metal halides, metal halides such as zinc, manganese, iron, cobalt, nickel, and copper, or hydrates of the aforementioned compounds. The most suitable metal halides in the composition of this invention are: LiCh NaC, NaBr, KBr, MgCI2, SrCI2, ZnCI2, NiCI2, CuCI2, MnCI2, ZnCI2, etc. (Please read the precautions on the back before drawing)-Binding-Order * • Printed by the Consumers' Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, 5 paper sizes are applicable to China's National Standards (CNS> A4 regulations. Standard (210X297 ) A9 B9 C9 D9 V. Description of the invention (4) The combination of additives is (a) Alkali metal chloride Alkali metal bromide Alkali metal borate Select one or more combinations (b) Alkaline earth metal chloride alkaline earth Metal bromide
Ni，Cu,Mn,Zn等二價金屬氯化物或溴化物 ； - 選取一或多種予以組合 其中（a)輿（b)之組成配比爲10:1至1:1範圍，最佳爲 6:1至4.·1之範圍。 (請先閲讀背面之注意事項再行繪製) .裝. 訂l· 本發明之組合物，不同於傳統水泥分散劑,並不會 使流動性隨著時間減少，而且常常可使經處理水，泥組 合物流動性增加，因此使用時，在抑制混凝土重陷損 失方面具有優良性質.本發明可與現有水泥分散劑、 防水劑、硬化加速劑、抑制劑、加氣劑等混合使用。 6 線 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A9 B9 C9 D9 387866 五、發明説明（5 ) 本發明水泥摻合組合物可用於各類型水泥，例如: —般卜特蘭水泥（Port land Cement)、高快固水泥 (High ear 丨 y Strength Cement)、超高固水泥、 高爐礦澄水泥（Blast-fnrance Slag Cement)、 中抽度水泥（Moderate heat Cement) '飄塵水泥 (Fly ash Cement )、耐硫酸鹽水泥等等，以及一些 可以硬化材料，例如石膏等等《> 經加入添加劑處理之水泥組合物，除建築之使用 外，亦可供做下述之使用.即在土木工程方面，可用 路基或路盤之處理，農林用產業道路，街道及道路等 之簡易舖裝.水泥或柏油路面之底層之凝結，或河川 淤泥之凝結，若被處理爲混入有多量土壤的產業廢棄 物，或都市垃圾、下水道污泥、焚燒灰燼或污泥乾燥 物之場合。 本發明對添加劑、對水泥組合物添加量爲0.5〜5%， 較佳爲1.50~3%。. 本發明組合物 I-^------裝------訂------- 線 - \ (請先閱讀背面之注意事項再行繪製) 經濟部中央榇準局員工消費合作杜印製 A 成分 NaCI KCI KBr BaCI, 0 3 017 0 u 01 NaBr Na2B07 NiCI2 重量（g) 82 156 2 21 16 1 2 4 12 B 成分 NaCI KCI KBr Bacl2 Bad? CaCI, NaBr Na2B07 NiCI2 重量（g) 95 172 7.5 13 16 2 4 2.5 5.5 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 387866 b9 C9 D9 五、發明説明（6 ) 實例：每立方（Μ3)之含量 實例（1):污泥 水泥 砂 污泥 水 摻合組成物 抗壓強度/28天 ⑴ 500kg 750kg 800kg 150/ 40 1 (A) 2760psi (2) 500kg 750ka 800kg 190 l 0 l 1 60〇Dsi 實例（2):7」 fc泥砂漿 水泥 砂 固化劑 水 摻合組成物 抗壓強度/7天 (1) 900kg 950kg 0 l 320 l 60 / (A) 421 Opsi (2) 900kg 950kg 0 l 380 l 0 1 3911 psi 水泥 砂 污泥 水 摻合組成物 抗壓強度/14天 (1) 900kg 950kg 0 l 320 l 60 / (B) 4778psi (2) 900kg 950kfl 0 t 380 l 0 1 4430psi 水泥 砂 固化劑 水 摻合組成物 抗壓強度/28天 (1) 900kg 950kg 0// 320 l 60 / (B) 5613psi (2) 900kg 950kg 0 7 380 l 0 1 52121psi (請先閱讀背面之注意事項再行繪製) 經濟部中央標準局員工消費合作社印製 實例（3):早強水泥 早強水泥 砂 碎石 水 摻合組成物 抗壓強度/28天 (1) 950kg 1000kg 0 320 1 60 1(A) 7794psi (2) 950kg 1000kg 0 380 1 0 1 5746psi 8 紙張尺庹適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 387866 A9 B9 C9 D9 五、發明説明（7 ) 實例（4):高爐水泥 高爐水泥 砂 碎石 水 摻合組成物 抗壓強度/28天 (1) 950kg 1000kg 0 320 1 60 / (B) 5244psi (2) 950kg 1000kg 0 380 1 0 1 3991 psi 實例（5):焚化爐灰 水泥 砂 焚化爐灰 水 慘合組成物 抗壓強度/28天 (1) 966kg 600kg 300kg 380 / 60 1 (A) 4500psi 實例（6):硫酸鋇 水泥 砂 硫酸鋇 水 摻合組成物 抗壓強度/28天 (1) 750kg 600kg 600kg 320 1 60/(B) 5200psi 實例（7):火 山灰 水泥 火山灰 水 摻合組成物 抗壓強度/28天 (1) 1250kg 650kg 400kg 380 l 60 1 (A) 7800psi (2) 400kg 900kg 500kg 320 l 60 t (B) 3437psi I 1!- 1— -II - -I I - ' —I— ------ - ' - ..ϋ\. (請先閱讀背面之注意事項再行缘製) 訂 -線 經濟部中央標準局員工消費合作社印製 實例（8):碳灰 水泥 砂 碳灰 水 摻合組成物 抗壓強度/28天 (1) 966kg 440kg 432kg 380 l 60 1 (A) 6175psi 9 本紙張尺度適用中國國家標準（CNS )六4規格（210X297公釐〉 387866 at B7 五、發明説明（8 )Ni, Cu, Mn, Zn and other divalent metal chlorides or bromides;-Select one or more of them to be combined. The composition ratio of (a) and (b) is in the range of 10: 1 to 1: 1, preferably 6 : 1 to 4. · 1 range. (Please read the precautions on the back before drawing). Installation. Order l. The composition of the present invention, unlike traditional cement dispersants, does not reduce fluidity over time, and often allows treated water. The mud composition has increased fluidity, so when used, it has excellent properties in suppressing the loss of concrete subsidence. The present invention can be used in combination with existing cement dispersants, waterproofing agents, hardening accelerators, inhibitors, aeration agents and the like. 6 Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Standards for this paper Applicable to Chinese National Standard (CNS) A4 (210X297 mm) A9 B9 C9 D9 387866 V. Description of the invention (5) The cement admixture composition of the present invention can be used for Various types of cement, for example: —Port land Cement, High ear 丨 y Strength Cement, Ultra-high solid cement, Blast-fnrance Slag Cement, Medium pumping Moderate heat Cement 'Fly ash Cement', sulfate-resistant cement, etc., and some hardenable materials, such as gypsum, etc. > Cement compositions treated with additives, except for construction use It can also be used for the following purposes. In civil engineering, it can be used for subgrade or road surface treatment, simple paving of agricultural and forestry industrial roads, streets and roads, etc. Condensation on the bottom layer of cement or asphalt pavement, or river silt Condensation, if it is treated as industrial waste mixed with a large amount of soil, or in the case of municipal waste, sewage sludge, incineration ash or sludge dry matter. In the present invention, the additive amount to the cement composition is 0.5 to 5%, preferably 1.50 to 3%. The composition of the present invention I-^ ------ install ------ order ------- line-\ (Please read the precautions on the back before drawing) Central Bureau of Standards, Ministry of Economic Affairs Employee Consumption Cooperation Du printed A Ingredient NaCI KCI KBr BaCI, 0 3 017 0 u 01 NaBr Na2B07 NiCI2 Weight (g) 82 156 2 21 16 1 2 4 12 B Ingredient NaCI KCI KBr Bacl2 Bad? CaCI, NaBr Na2B07 NiCI2 Weight ( g) 95 172 7.5 13 16 2 4 2.5 5.5 This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 387866 b9 C9 D9 V. Description of the invention (6) Example: Example of content per cubic meter (M3) ( 1): Compressive strength of sludge cement sand sludge water admixture composition / 28 days ⑴ 500kg 750kg 800kg 150/40 1 (A) 2760psi (2) 500kg 750ka 800kg 190 l 0 l 1 60〇Dsi Example (2) : 7 '' fc mud mortar cement sand curing agent water blending composition compressive strength / 7 days (1) 900kg 950kg 0 l 320 l 60 / (A) 421 Opsi (2) 900kg 950kg 0 l 380 l 0 1 3911 psi Cement sand sludge water blend composition compressive strength / 14 days (1) 900kg 950kg 0 l 320 l 60 / (B) 4778psi (2) 900kg 950kfl 0 t 380 l 0 1 4430psi cement sand Curing agent water blend composition compressive strength / 28 days (1) 900kg 950kg 0 // 320 l 60 / (B) 5613psi (2) 900kg 950kg 0 7 380 l 0 1 52121psi (Please read the precautions on the back first Line drawing) Example printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (3): Compressive strength of early-strength cement early-strength cement sand crushed stone water mixed composition / 28 days (1) 950kg 1000kg 0 320 1 60 1 (A ) 7794psi (2) 950kg 1000kg 0 380 1 0 1 5746psi 8 Paper size applies to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 387866 A9 B9 C9 D9 V. Description of the invention (7) Example (4): Blast furnace cement Compressive strength of blast furnace cement sand crushed stone water admixture composition / 28 days (1) 950kg 1000kg 0 320 1 60 / (B) 5244psi (2) 950kg 1000kg 0 380 1 0 1 3991 psi Example (5): Incinerator ash Cement sand incinerator ash-water mixed composition compressive strength / 28 days (1) 966kg 600kg 300kg 380/60 1 (A) 4500psi Example (6): Barium sulfate cement sand barium sulfate water mixed composition compressive strength / 28 days (1) 750kg 600kg 600kg 320 1 60 / (B) 5200psi Example (7): Volcanic ash cement volcanic ash water Compression strength of composite composition / 28 days (1) 1250kg 650kg 400kg 380 l 60 1 (A) 7800psi (2) 400kg 900kg 500kg 320 l 60 t (B) 3437psi I 1!-1- -II--II-' —I— -------'-..ϋ \. (Please read the precautions on the back before proceeding to the margin system) Order-line printing example from the Central Consumers Bureau of the Ministry of Economic Affairs Consumer Cooperatives (8): Carbon Ash Cement sand carbon ash water blend composition compressive strength / 28 days B7 V. Description of Invention (8)
A 實例（8):碳灰 水泥 砂 碳灰 水 摻合組成物 抗壓強度/28天 ⑴ 966kg 440kfl 432kg 380 1 60 1 (B) 6175dsi 實例（9):金剛砂 水泥 砂 金剛砂 水 摻合組成物 抗壓強度/28天 (1) 1250kg 0kg 1155kg 380 1 60 1 (A) 8000psi -—»1-·1 - I - I- - - - ! f 士又 4 /Ϊ— . (请先閱讀背面之注意事項再填寫本頁) 實例（10):石英砂 水泥 砂 石英砂 水 摻合組成物 抗壓強度/28天 (1) 1250kg 0kg 600 kg 380 / 60/(B) 6950psi 實例（11):鉛 水泥 砂 銘 水 摻合組成物 抗壓強度/2 8天 (1) 950kQ 550kg 750kg 500 / 80 1 (A) 6 7 5 0 p s i 訂· 丨線 經濟部中央標準局員工消费合作社印製 以上實例僅代表本發明之良好性質態樣， 並不能限定本發明之範圍。 10 本好巧舟消用中阀阀家標嗥（CNS ) Λ4样.格（2丨0X297公錡）A Example (8): Compressive strength of carbon ash cement sand carbon ash water blended composition / 28 days⑴ 966kg 440kfl 432kg 380 1 60 1 (B) 6175dsi Example (9): Emery cement cement sand emery water blended composition resistance Compressive strength / 28 days (1) 1250kg 0kg 1155kg 380 1 60 1 (A) 8000psi -— »1- · 1-I-I----! F taxi again 4 / Ϊ—. (Please read the note on the back first (Please fill in this page again for details) Example (10): Compressive strength of quartz sand cement sand quartz sand water composite composition / 28 days (1) 1250kg 0kg 600 kg 380/60 / (B) 6950psi Example (11): lead cement Compressive strength of sand-water blend composition / 2 8 days (1) 950kQ 550kg 750kg 500/80 1 (A) 6 7 50 0 psi The good nature of the present invention does not limit the scope of the present invention. 10 This is a clever boat consumption standard for the domestic valve valve (CNS) Λ4 sample. Grid (2 丨 0X297)