TW383423B - Chemical mechanical polishing method with controllable polishing depth - Google Patents

Chemical mechanical polishing method with controllable polishing depth Download PDF

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TW383423B
TW383423B TW87115856A TW87115856A TW383423B TW 383423 B TW383423 B TW 383423B TW 87115856 A TW87115856 A TW 87115856A TW 87115856 A TW87115856 A TW 87115856A TW 383423 B TW383423 B TW 383423B
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dielectric layer
layer
chemical mechanical
mechanical polishing
polishing method
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TW87115856A
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Chinese (zh)
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Ming-Shiung Jiang
Jen-Ming Wu
Jen-Ming Huang
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Taiwan Semiconductor Mfg
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Abstract

A kind of chemical mechanical polishing method with controllable polishing depth which is applied to semiconductor circuit with memory area. The surface of semiconductor circuit is covered by polysilicon layer. This kind of chemical mechanical polishing method is to form a predetermined thickness of silicon oxide on the surface of polysilicon and forming silicon nitride as barrier on the surface of silicon oxide; then, defining the memory area of semiconductor circuit which is to remove the silicon nitride, silicon oxide and polysilicon outside the memory area; forming another silicon oxide to cover whole semiconductor circuit and applying chemical mechanical polishing on the silicon oxide to expose the surface of silicon nitride; last, removing the exposed silicon nitride and complete the processes.

Description

五、發明說明(1) ' 本發明是有關於一種平坦化製程(planariza1:ion process)且特別是有關於一種可控制研磨深度的化學機 械研=法(Chemical Mechanical Polishing,CMP)。 «月參考第1 A〜1 C圖,此為習知動態隨機存取記憶體 (DRAM)化學機械研磨法的流程圖。 如第1A圖所示’用以建構半導體電路的半導體基底 1 0 ’如石夕基底,可分為記憶體區丨2及主動區丨4。記憶體區 12及主動區14表面同時覆蓋有頂層16,如電容上電極之複 晶矽層。圮憶體區1 2係甩以形成動態隨機存取記憶體 (DRAM)或其他類型的記憶體。主動區14則用以形成邏輯電 路或其他電路。一般情況下,由於記憶體區12會在動態隨 機存取記憶體或其他類型的記憶體表面另外形成電容的上 電極’因此厚度往往會高於主動區内的邏輯電路或其他 電路。 ^ 接著’如第1Β圖所示’蝕刻去除記憶體區丨2以外的頂 層(電容上電極的複晶矽層)。在半導體基底1〇(包括記憶 體區12及主動區14)上沈積一層厚度較大的BPTE〇s層18、 並回蝕或化學機械研磨BPTE0S層18以得到平坦化的半導體 電路表面,如第1C圖所示。 不過’這種方法卻難以精確控制化學機械研磨的深 度,亦即,BPTE0S層18在頂層16上的厚度。一般情況下, 化學機械研磨的深度誤差(CMP deviation)大約在2〇〇〇埃 左右。但是’線寬較細的製程’如〇 . 1 8 u m製程,卻不能忍 受這麼大的誤差。通常,當BPTE0S層18在頂層16上的厚度V. Description of the invention (1) The invention relates to a planarization process (planariza1: ion process), and in particular to a chemical mechanical polishing (CMP) method capable of controlling the depth of polishing. «Refer to Figures 1A ~ 1C. This is a flow chart of the conventional chemical mechanical polishing method for dynamic random access memory (DRAM). As shown in FIG. 1A, 'a semiconductor substrate 10 for constructing a semiconductor circuit', such as a Shi Xi substrate, can be divided into a memory region 丨 2 and an active region 丨 4. The surfaces of the memory region 12 and the active region 14 are simultaneously covered with a top layer 16, such as a polysilicon layer on the capacitor electrode. The memory area 12 is flipped to form dynamic random access memory (DRAM) or other types of memory. The active area 14 is used to form a logic circuit or other circuits. In general, since the memory region 12 will form an additional capacitor 'on the surface of the dynamic random access memory or other types of memory, the thickness is often higher than that of the logic circuit or other circuits in the active region. ^ Then “as shown in FIG. 1B”, the top layer (the polycrystalline silicon layer of the electrode on the capacitor) other than the memory region 丨 2 is removed by etching. A thicker BPTE0s layer 18 is deposited on the semiconductor substrate 10 (including the memory region 12 and the active region 14), and the BPTE0S layer 18 is etched back or chemically mechanically polished to obtain a planarized semiconductor circuit surface, as Figure 1C. However, it is difficult to precisely control the depth of the chemical mechanical polishing, that is, the thickness of the BPTEOS layer 18 on the top layer 16. In general, the CMP deviation of the chemical mechanical polishing is about 2000 Angstroms. However, the process with a thinner line width, such as the 0.18 μm process, cannot tolerate such a large error. Generally, when the thickness of the BPTEOS layer 18 on the top layer 16

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過大時’會對後續進行的接觸蝕刻(Contact etching)造 成困擾。反之’當BPTE0S層18在頂層16上的厚度過小時, 下方的頂層1 6則可能會受到損害。 有鏗於此,本發明的主要目的便是提供一種化學機械 研磨法’其可以有效地將頂層16上方的BPTE〇s層18厚度精 確控制在預定的範圍内。 本發明的 其可以避免覆 進行的接觸蝕 為達上述 磨法。在這種 體電路,其表 預定厚度的第 介電層具有適 的阻障層(CMP 的第二介電層 上形成第三介 蝕刻選擇比。 介電層,並去 在這種化 常高於半導體 由複晶矽層構 介電層則可以 BPTE0S 層。 蓋半導體電 刻步驟更為 及其他目的 方法中,首 面覆蓋一頂 一介電層及 當的蝕刻選 Barrier) 、第一介電 電層。第三 然後,化學 除露出之第 學機械研磨 電路之其他 成。另外, 是沈積法形 另一個目的就是提供一種化學機械研磨法 路之頂層1 6受到損害,並使後續 精確。 ’本發明乃提供一種化學機械研 先需提供一具有記憶體區之半導 層。然後,在頂層表面依序形成 第二介電層。第二介電層與第一 擇比’用以做為化學機械研磨法 。然後,蝕刻去除記憶體區以外 層及頂層’並在整個半導體電路 介電層及第二介電層具有適當的 機械研磨第三介電層至露出第二 二介電層以完成平坦化製程。 ,中’半導體電路之記憶體區通 ,域;且半導體電路之頂層通常 第一介電層、第二介電層、第三 成的氧化矽層、氮化矽層及If it is too large, it will cause trouble for subsequent contact etching. Conversely, when the thickness of the BPTEOS layer 18 on the top layer 16 is too small, the lower top layer 16 may be damaged. In view of this, the main object of the present invention is to provide a chemical mechanical polishing method, which can effectively control the thickness of the BPTE0s layer 18 above the top layer 16 within a predetermined range. According to the present invention, the contact erosion can be avoided to achieve the above grinding method. In such a bulk circuit, a second dielectric layer of a predetermined thickness has a suitable barrier layer (a third dielectric etch selectivity ratio is formed on the second dielectric layer of the CMP. The dielectric layer is often high in this type). In the case of semiconductors composed of a polycrystalline silicon layer, the dielectric layer can be a BPTE0S layer. In the step of covering the semiconductor etching process and other methods, the first surface is covered with a dielectric layer and a Barrier etch, and the first dielectric is selected. Floor. Third, the chemical mechanical polishing circuit is exposed in addition to the other components. In addition, it is a deposition method. Another purpose is to provide a chemical mechanical polishing method where the top layer 16 of the circuit is damaged and the subsequent accuracy is accurate. The present invention is to provide a chemical-mechanical research that firstly needs to provide a semiconductor layer having a memory region. Then, a second dielectric layer is sequentially formed on the top surface. The second dielectric layer and the first selective ratio are used as a chemical mechanical polishing method. Then, the outer layer and the top layer of the memory region are removed by etching, and the third dielectric layer is appropriately mechanically polished throughout the dielectric layer and the second dielectric layer of the semiconductor circuit to expose the second dielectric layer to complete the planarization process. The memory region of the semiconductor circuit is connected to the domain; and the top layer of the semiconductor circuit is usually a first dielectric layer, a second dielectric layer, a third silicon oxide layer, a silicon nitride layer, and

再者,圮憶體區以外的第二介電層、第一介電層及頂 f可以用乾式蝕刻法去&。而露出之第二介電層則可用乾 式蝕刻法或濕式蝕刻法去除。 # a ί讓本發明之上述和其他目的、特徵、和優點能更明 * ,下文特舉一較佳實施例,並配合所附圖式,作詳 細說明如下: 圖式說明 第1A〜1 c圖係習知動態隨機存取記憶體化學機械研磨 法(DRAM CMP)的流程圖;以及 葶2A〜2F圖係本發明動態隨機存取記憶體化學機械研 磨法(DRAM CMP)的流程圖? 實施例 請參考第2A~2F圖’此為本發明動態隨機存取記憶體 化學機械研磨法(DRAM CMP)的流程圖。 首先,如第2A圖所示,提供一半導體電路,其具有一 §己憶體區且覆蓋一頂層。與習知相同,用以建構半導體電 路的半導體基底20,如矽基底’可分為記憶體區22及主動 區24。記憶體區22及主動區24的表面則覆蓋有頂層26,如 電谷上電極之複晶矽層。在這個實施例中,記憶體區2 2係 用以形成動態隨機存取記憶體(DRAM)或其他類型的記憶 體。主動區24則用以形成邏輯電路或其他電路。一般^況 下’由於記憶體區22會在動態隨機存取記憶體或其他類\ 的記憶體表面另外形成電容的上電極(如頂層26),因此型 度往往要高於主動區24内的邏輯電路或其他電路。 厚In addition, the second dielectric layer, the first dielectric layer, and the top f outside the memory region can be removed by dry etching. The exposed second dielectric layer can be removed by dry etching or wet etching. # a ί Make the above and other objects, features, and advantages of the present invention more clear *, a preferred embodiment is given below, and in conjunction with the accompanying drawings, the detailed description is as follows: Schematic illustrations 1A ~ 1 c The figure is a flowchart of a conventional dynamic random access memory chemical mechanical polishing method (DRAM CMP); and 2A ~ 2F are the flowcharts of the dynamic random access memory chemical mechanical polishing method (DRAM CMP) of the present invention? Example Please refer to Figs. 2A to 2F. This is a flowchart of a dynamic random access memory chemical mechanical polishing method (DRAM CMP) of the present invention. First, as shown in FIG. 2A, a semiconductor circuit is provided, which has a memory region and covers a top layer. As is conventional, a semiconductor substrate 20, such as a silicon substrate, used to construct a semiconductor circuit can be divided into a memory region 22 and an active region 24. The surfaces of the memory region 22 and the active region 24 are covered with a top layer 26, such as a polycrystalline silicon layer of an electrode on the valley. In this embodiment, the memory area 22 is used to form a dynamic random access memory (DRAM) or other types of memory. The active area 24 is used to form a logic circuit or other circuits. Under normal circumstances, because the memory area 22 will additionally form a capacitive upper electrode (such as the top layer 26) on the surface of the dynamic random access memory or other types of memory, the type is often higher than that in the active area 24. Logic or other circuits. thick

五、發明說明(4) 曰接著,如第2B圖所示,在該頂層表面依序形成一預定 厚度之第一介電層及一第二介電層,其中,該第二介電層 及該第一介電層具有一第一蝕刻選擇比。在這個實施例 第一介,層28及第二介電層30可分別是沈積法形成的 氧化=層及氮化矽層。氮化矽層及氧化矽層的CMp選擇比 大約疋1 : 2。第一介電層28的厚度即是在後續的化學機械 研磨後,欲保留於頂層26(電容上電極)表面的介電層厚 度而第一介電層30則是在後續的化學機械研磨步驟中, ,以作為阻障層。由於第一介電層28表面形成有阻障用的 第二介電層30,因此化學機械研磨步驟令欲保留於頂層26 表面的介電層厚度可在這個步驟中精確決定,並且,由於 化學機械研磨的深度可以精確控制,因研磨深度難以控制 而產生,頂層損害及接觸蝕刻不易亦可以同時獲得解決。 接著,如第2C圖所示,蝕刻該第二介電層、該第一介 層及該頂層,藉以定義該記憶體區之該頂層圖案。 H例中’第二介電層3〇上首先形成一光阻層32,露出主動 區24及圮憶體區22不欲保留頂層26(電容上電極)的 然後,利用這層光阻層32為罩幕,蝕刻第二介電層3〇 °、 介電層26及頂層26,藉以定義記憶體區的電容上電 案。待定義步驟結束後,去除光阻層3 2。 接著,如第2D圖所示,形成一第三介電層以覆 體電路及該第二介電層,其中,該第三介電層及誃第二人 電層具有一第二餘刻選擇比,在這個實施例中,g三5 ‘ 層34可以是利用沈積法形成的BpTE〇s層,用以覆蓋整個半V. Description of the Invention (4) Next, as shown in FIG. 2B, a first dielectric layer and a second dielectric layer with a predetermined thickness are sequentially formed on the surface of the top layer, wherein the second dielectric layer and The first dielectric layer has a first etching selectivity. In this embodiment, the first dielectric layer 28 and the second dielectric layer 30 may be oxide layers and silicon nitride layers formed by a deposition method, respectively. The CMP selection ratio of the silicon nitride layer and the silicon oxide layer is approximately 疋 1: 2. The thickness of the first dielectric layer 28 is the thickness of the dielectric layer to be retained on the surface of the top layer 26 (capacitor upper electrode) after the subsequent chemical mechanical polishing, and the first dielectric layer 30 is used in the subsequent chemical mechanical polishing step. , As a barrier layer. Since the second dielectric layer 30 for barrier is formed on the surface of the first dielectric layer 28, the chemical mechanical polishing step allows the thickness of the dielectric layer to be retained on the surface of the top layer 26 to be accurately determined in this step. The depth of mechanical grinding can be precisely controlled, which is caused by the difficulty in controlling the grinding depth. The damage to the top layer and the contact etching are not easy, and can be solved at the same time. Next, as shown in FIG. 2C, the second dielectric layer, the first dielectric layer, and the top layer are etched to define the top layer pattern of the memory region. In the H example, a photoresist layer 32 is first formed on the second dielectric layer 30, and the active area 24 and the memory body area 22 are not intended to retain the top layer 26 (capacitance upper electrode). Then, this photoresist layer 32 is used. For the mask, the second dielectric layer 30 °, the dielectric layer 26 and the top layer 26 are etched to define a capacitor power-on scheme of the memory region. After the definition step is completed, the photoresist layer 32 is removed. Next, as shown in FIG. 2D, a third dielectric layer is formed to cover the body circuit and the second dielectric layer, wherein the third dielectric layer and the second human electrical layer have a second choice. In contrast, in this embodiment, the G3 5 'layer 34 may be a BpTE0s layer formed by a deposition method to cover the entire half.

C:\ProgramFiles\Patent\0503-3876-E.ptd第 7 頁C: \ ProgramFiles \ Patent \ 0503-3876-E.ptd page 7

五、發明說明(5) 導體電路。氮化矽層32及BPTEOS層3 4的CMP選擇比大約為 1:6。由於記憶體區22表面已形成有預定厚度的第一介電 層28及阻障用的第二介電層3〇,亦即,已決定在化學機械研 磨後欲保留於頂層26表面的厚度(如上述),因此第三介電 層34主要是用於主動區24的平坦化。 接著,如第2E圖所示,化學機械研磨該第三介電層至露 出該第二介電層。在這個實施例中,由於第二介電層32(氮 化矽層)及第三介電層34 (BPTEOS層)的CMP選擇比大約是!: 6,當化學機械研磨持續進行至露出第二介電層32(氮化矽 層)表面時,半導體電路在記憶體區22的“卩速度便會遠小 於主動區24的蝕刻速度。也因此,化學機械研磨法便可以 在露出第二介電層32(氮化矽層)後停止,精確地控制記憶 體區22在頂層26上方的介電層厚度。 … 接著,如第2F圖所示,去除露出之該第二介電 個實施例中,當化學機械研磨的步驟停止後,亦即,平掉 ^程結束後,Τ利用乾式#刻$濕式㈣去 表面露出的第二介電層32(氮化矽層)。 Κ體區22 綜上所述,本發明的化學機械研磨法可有效地控 :體電路在記憶體區表面的介電層厚度。並且,由於化與 ,械研1的研磨深度可精確控制,因研磨深度不均而: 的頂層損害及接觸蝕刻不易亦可同時得到解決。_ 雖然本發明已以較佳實施例揭露如上, 限定本發明,任何熟習此技藝者,在:f並非用以 和範圍内,當可做更動與潤飾,因5. Description of the invention (5) Conductor circuit. The CMP selection ratio of the silicon nitride layer 32 and the BPTEOS layer 34 is approximately 1: 6. Since the first dielectric layer 28 and the second barrier layer 30 for barrier have been formed on the surface of the memory region 22 with a predetermined thickness, that is, the thickness to be retained on the surface of the top layer 26 after chemical mechanical polishing ( As described above), the third dielectric layer 34 is mainly used for planarization of the active region 24. Next, as shown in FIG. 2E, the third dielectric layer is chemically and mechanically polished until the second dielectric layer is exposed. In this embodiment, the CMP selection ratio of the second dielectric layer 32 (silicon nitride layer) and the third dielectric layer 34 (BPTEOS layer) is approximately! : 6, when the chemical mechanical polishing is continued until the surface of the second dielectric layer 32 (silicon nitride layer) is exposed, the “卩” speed of the semiconductor circuit in the memory region 22 will be much lower than the etching rate of the active region 24. The chemical mechanical polishing method can be stopped after the second dielectric layer 32 (silicon nitride layer) is exposed, and the thickness of the dielectric layer of the memory region 22 above the top layer 26 can be accurately controlled. Then, as shown in FIG. 2F In the embodiment of removing the exposed second dielectric, when the step of chemical mechanical polishing is stopped, that is, after the flattening process is completed, the second dielectric exposed on the surface is removed by using a dry type #etching $ wet method. Layer 32 (silicon nitride layer). K body region 22 In summary, the chemical mechanical polishing method of the present invention can effectively control: the thickness of the dielectric layer of the body circuit on the surface of the memory region. The grinding depth of Research 1 can be precisely controlled, because of the uneven grinding depth: the damage to the top layer and the contact etching can not be easily solved at the same time._ Although the present invention has been disclosed in the preferred embodiment above, the present invention is limited, anyone familiar with this technique Or, in: f is not used for and scope When do alterations and modifications due

五、發明說明(6) 視後附之申請專利範圍所界定者為準。 iumw C:\ProgramFiles\Patent\0503-3876-E.ptd第 9 頁V. Description of the invention (6) Subject to the scope of the attached patent application. iumw C: \ ProgramFiles \ Patent \ 0503-3876-E.ptd page 9

Claims (1)

六、申請專利範圍 1. 一種化學機械研磨法,包括: 提供一半導體電路,具有一記憶體區且覆蓋一頂層; 形成一預定厚度之第一介電層於該頂層表面; 形成一第二介電層於該第一介電層表面,該第二介電 層及該第一介電層具有一第一蝕刻選擇比; 蝕刻該第二介電層、該第一介電層及該頂層,藉以定 義談記憶體區.之該頂層圖案; 形成一第三介電層,覆蓋該半導體電路及該第二介電 層,該第三介電層及該第二介電層具有一第二蝕刻選擇 比; 化學機械研磨該第三介電層至露出該第二介電層;以 犮 去除露出之該第二介電層。 2. 如申請專利範圍第1項所述的化學機械研磨法,其 中,該、半導體電路之記憶體區係高於該半導體電路之其他 區域。 3. 如申請專利範圍第1項所述的化學機摊研磨法,其 中,該半導體電路之頂層係電容上電極之複晶矽層。 4. 如申請專利範圍第1項所述的化學機械研磨法,其 中,該第一介電層係氧化矽層,該第二介電層係氮化矽 層。 5. 如申請專利範圍第4項所述的化學機械研磨法,其 中,該第一介電層及該第二介電層係利用沈積法形成。 6. 如申請專利範圍第1項所述的化學機械研磨法,其6. Scope of Patent Application 1. A chemical mechanical polishing method, comprising: providing a semiconductor circuit having a memory region and covering a top layer; forming a first dielectric layer of a predetermined thickness on a surface of the top layer; forming a second dielectric An electric layer is on the surface of the first dielectric layer, the second dielectric layer and the first dielectric layer have a first etching selection ratio; and the second dielectric layer, the first dielectric layer and the top layer are etched, The top pattern of the memory area is defined by this; a third dielectric layer is formed to cover the semiconductor circuit and the second dielectric layer, and the third dielectric layer and the second dielectric layer have a second etch Selection ratio; chemically and mechanically grinding the third dielectric layer to expose the second dielectric layer; and removing the exposed second dielectric layer. 2. The chemical mechanical polishing method according to item 1 of the scope of patent application, wherein the memory area of the semiconductor circuit is higher than other areas of the semiconductor circuit. 3. The chemical machine polishing method according to item 1 of the scope of patent application, wherein the top layer of the semiconductor circuit is a polycrystalline silicon layer of an electrode on a capacitor. 4. The chemical mechanical polishing method according to item 1 of the scope of patent application, wherein the first dielectric layer is a silicon oxide layer and the second dielectric layer is a silicon nitride layer. 5. The chemical mechanical polishing method according to item 4 of the scope of patent application, wherein the first dielectric layer and the second dielectric layer are formed by a deposition method. 6. The chemical mechanical polishing method described in item 1 of the scope of patent application, which C:\ProgramFiles\Patent\0503-3876-E.ptd第 10 頁 六、申請專利範圍 中,該第二介電層係氮化矽層,該第三介電層係BPTEOS 層。 7. 如申請專利範圍第6項所述的化學機械研磨法,其 中,該第二介電層及該第三介電層係利用沈積法形成。 8. 如申請專利範圍第1項所述的化學機械研磨法,其 中,該記憶體區之該頂層係利用蝕刻法定義圖案。 9. 如申請專利範圍第1項所述的化學機械研磨法,其 中,露出之該第二介霓層係利用乾式蝕刻法去除。 1 0 .如申請專利範圍第1項所述的化學機械研磨法,其 中,露出之該第二介電層係利用濕式蝕刻法去除。C: \ ProgramFiles \ Patent \ 0503-3876-E.ptd page 10 6. In the scope of patent application, the second dielectric layer is a silicon nitride layer, and the third dielectric layer is a BPTEOS layer. 7. The chemical mechanical polishing method according to item 6 of the patent application scope, wherein the second dielectric layer and the third dielectric layer are formed by a deposition method. 8. The chemical mechanical polishing method according to item 1 of the patent application scope, wherein the top layer of the memory region is patterned by an etching method. 9. The chemical mechanical polishing method according to item 1 of the patent application scope, wherein the exposed second interlayer is removed by a dry etching method. 10. The chemical mechanical polishing method according to item 1 of the scope of patent application, wherein the exposed second dielectric layer is removed by a wet etching method. C:\ProgramFiles\Patent\0503-3876-E. ptd 第 11 頁C: \ ProgramFiles \ Patent \ 0503-3876-E. Ptd page 11
TW87115856A 1998-09-23 1998-09-23 Chemical mechanical polishing method with controllable polishing depth TW383423B (en)

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