/ 經濟部中央標準局员工消费合作社印製 A7 B7 五、發明説明（\ ) 本發明係有關在陰極射線管 方法，特収在面板外㈣做㈣處理的^故 成的帶電防止膜、或利用溶膠（ =utter)方式尸斤^ 反射防止崎f知之塗層處理製^霧處理所形成^ 止膜與反射防止膜間彻Sputttΐ ’ =上述帶， 的塗層的製造方法的陰歸線管塗/切形成氧切成份 本發曰q μ # 如此，爲提高陰極射線管的膜強度，且形 陰極射線管表面阻抗，使前端整 几 栌，Α 识^磲蛩幕表面具有防止帶電功^ Λ 反射率，而提高畫面對比（一μ) 者的不快解㈣手難觸畫㈣魏的問題，财卩制使用 示元件爲使易於觀t，乃在陰極射線管前作 防止帶電塗層處理，以除去畫面所生的靜電。 ^是根據個人電腦（PC)嘴用者的人體工學的問題， 以提高視感，底符合使用的便利性，而在陰極射線管 做防止帶電及反射功能的表面處理。 ---------痒------ir------碎. 广请先間讀fij-ilii-意事項寫本剪> 示 其備有這樣條件的陰極射線管的構成囷如第j 圏所 本構造區分爲爲漏斗型（D、面板（2);及爲消除在面 板（2)的外部表面當Pc因0N/0FF時，外加在陰極射線管 本紙張尺度適用中國國家標净（CNS ) A4規格（210X297公釐） 經濟部中决標準局負工消費合作社印裝 A7 B7 五、發明説明（l ) 的高壓電致使前面板產生帶電的電子（Electric charge) 的帶電防止膜（3)，以及防止從外部的螢光燈等外部光源 在前面板反射，以致枋害使用者視野的反射防止膜（4)。 第2U)〜（e)圖係習知之防止帶電及反射膜的陰極射 線管製造工程圖，圖中符號5爲帶電防止膜、6爲反射防 止膜、7爲固定台、8爲研磨機、9、13爲喷嘴（N〇zzle)、 11爲金屬標靶，I2爲旋轉台、I4爲發熱器或紫外線燈。 如此在陰極射線管用面板（2)外面加以塗層帶電防止 膜（3)、反射防止膜（4)，依習知技術係在面板（2)以Sputter 方式塗上錫氧化敏（ITO)而形成帶電防止膜（3)。 如此所形成的帶電防止膜（3)後，另在其上以噴霧方式塗 層以氧化矽（Si〇)爲主要成份的溶膠，並經熱處理使氧化 矽溶膠硬化而形成反射防止膜（4)。 但是上述的製造方法所形成的帶電防止膜Ο)及反射 防止膜（4) ’由於形成帶電防止膜（3)的錫氧化銥（ιτ〇)有 金屬成份’得在上部形成反射防止膜的氧化矽溶膠的阶著 力強度不佳。 另外，爲形成膜的塗層後塑性（熱處理），該膜的表面 阻抗値有升高的傾向。 \ 實際上，以ΙΤΟ膜做熱處理時（2〇〇度經利分鐘的熱處 理），表面阻抗値將從200〜300Q/cm2升到5〇〇{^/cnj2。 然而，爲達到監示器的電場及磁場，則該表面阻抗値 _________4----- 本紙张尺度適州中國國家標率（（:NS)A4規格U10X297公釐） ---' 裝------訂------^ »— (請先閱讀背面之注意事項寫本頁) 一/ Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (\) The present invention relates to the cathode-ray tube method, which specially collects the resulting anti-charge film or uses it outside the panel. Sol (= utter) method ^ Reflective anti-reflective coating treatment system ^ formed by mist processing ^ between the stop film and the anti-reflective film Sputtt ΐ = = the above-mentioned coating method of the coating / Cut the oxygen-cutting composition. This hair says q μ # In this way, in order to improve the film strength of the cathode ray tube and shape the surface impedance of the cathode ray tube, make the front end a few 栌, the surface of the screen has the function of preventing charging ^ Λ reflectance, and the problem of improving the contrast of the picture (one μ) is not easy to solve. It is difficult to touch and draw the picture. The financial system uses display elements to make it easy to observe t, which is treated with an anti-charge coating in front of the cathode ray tube. To remove static electricity generated by the screen. ^ According to the ergonomics of the mouthpiece of the personal computer (PC), in order to improve the visual sense and the convenience of use, the cathode ray tube is surface treated to prevent charging and reflection. --------- itch ------ ir ------ broken. Can you please read the fij-ilii-notes scissor > to show that it has a cathode ray tube with such conditions? The structure (such as j) is divided into a funnel type (D, panel (2); and to eliminate the external surface of the panel (2), when Pc is 0N / 0FF, it is added to the paper size of the cathode ray tube.) Applicable to China National Standard Net (CNS) A4 specification (210X297 mm) Printed on A7 B7 by the Consumers' Cooperatives of the Bureau of Standards and Decisions of the Ministry of Economic Affairs. 5. Description of the invention (l) The high-voltage electricity caused the front panel to generate electrified electrons. ), Anti-charge film (3), and anti-reflection film (4) that prevents external light sources such as fluorescent lights from reflecting on the front panel, which will harm the user's field of vision. 2U) ~ (e) The pictures are known The drawing of the cathode ray tube manufacturing process of the anti-charge and reflection film. Symbol 5 in the figure is the anti-charge film, 6 is the anti-reflection film, 7 is the fixed table, 8 is the grinder, 9, 13 is the nozzle (Nozzle), 11 It is a metal target, I2 is a rotary table, and I4 is a heater or an ultraviolet lamp. In this way, the antistatic film (3) and the antireflection film (4) are coated on the outer surface of the panel (2) for the cathode ray tube, and tin oxide sensitive (ITO) is formed on the panel (2) by the Sputter method according to the conventional technology. Antistatic film (3). The anti-charge film (3) thus formed was spray-coated with a sol containing silicon oxide (Si0) as the main component, and the silica sol was hardened by heat treatment to form an anti-reflection film (4). . However, the anti-charge film 0) and the anti-reflection film (4) formed by the above-mentioned manufacturing method 'because the tin iridium oxide (ιτ〇) forming the anti-charge film (3) has a metal component', the oxidation of the anti-reflection film must be formed on the upper part The step strength of the silica sol is not good. In addition, the surface resistance of the film tends to increase in order to form the film after coating (heat treatment). \ In fact, when the ITO film is heat treated (200 degrees heat treatment for a minute), the surface resistance 升 will increase from 200 ~ 300Q / cm2 to 500 {^ / cnj2. However, in order to achieve the electric and magnetic fields of the monitor, the surface impedance is 値 _________ 4 ----- This paper is suitable for China ’s national standard ((: NS) A4 specification U10X297 mm) --- 'Pack- ----- Order ------ ^ »— (Please read the notes on the back to write this page)
I A7 B7 五、發明説明（；>/) 得維持在ΙΟΟθΩ/cra2的水準以下。 又，爲形成上述的帶電防止膜、反射防止膜，習知之 其它方法係將陰極射線管前板加以洗淨、並利用氧 (Ce〇2)加以研磨，再以純水、酒精將研磨表面加以洗淨、 乾燥。 、 奢 訂 經乾燥後的陰極射線管放置在預熱爐上使已塗層的陰 極射線管表面作4〇〜度加熱後，利用旋轉（Spin)或嘴厲 (Spray)方式，使具有3〜抓的銻（Sb)成份散佈在的溶 膠作塗層處利，以形成帶電防止膜（3)，並在上部形成1 述帶電防止膜、及具折射率的其它氧化矽成份，依上述方 法做塗層處理，使PC使用者在經長時使用下也不致疲勞 等使人體異常的反射防止膜（4)。 —線 此時，雖在反射防止膜上部以嘴霧方法形成凹凸狀的 抗閃光（Anti-Glare) ’但這種形成反射防止膜（AR)塗層時 造成問題的斑紋，爲使不易被感覺到，就需降低擴散反射 率，同時也可減少手指紋的問題。 經濟部中央標车局貝工消费合作社印製 但是，上述以Spin噴霧的方法對於形成帶電防止膜 時，不利於對藥品洗滌工程，且會增加面板上的刮痕，以 及附著痕跡等異物管理的困難。 像上述的ARAS塗層或AGARS塗層，現行對帶電層的 抗淨電AS(Anti-Static)塗層的表面阻抗達到10HQ/cm2 的水準，此雖符合MPRU本;發明的規格，但目前更關心的 是無法達到TCO規格。 本紙張尺度適( CNS ) ( 2丨0X2975公釐) 經滴部中央標準局貝Η消贽合作社印犁 銥化矽 本紙張尺度ϋ;种ϋ ® A7 B7 五、發明説明（彳） 另外’習知的AS層祛AR層法所使用的IT〇不僅價格 高，且現行ιτο的的表面阻抗爲i〇5_6Q/cm2，達不到TC〇 的要求標準，還有，以上述的ϊτ〇塗層時，EMI Shielding 效果不足，於是要達到表面阻抗纟i〇3Q/cm2#下的的TC〇 要求標準，監示器t在_償電路加以補強。 本發明詳細説明 本發明即針對上述的問題，使不論是以面板外部作帶 電防止膜的Sputter方式、或在其上部以氧化矽爲主要成 份的爲塗層Sputter方式，並在上部使用反射防止膜爲膠 膜的Spin方式’做塗層後塑性（熱處理）的製造方法以形 成陰極射線管的面板塗層膜。 以下根據尸斤附的圖例來説明本發明a低阻抗用反射防 止陰極射線管製造方祛，，0 在第3圖所示之本發明的實施例的㈣的外面塗層以 帶電防止膜、反射防止膜，在面板的外面以 & 作帶電防止膜的塗層，並在 ^ 以氧化發Μ成份的…方式塗層 溶膠的反射防止層Uq4)用成&塗層/、(1°3)，再於其上以 製造方法》 Spin方式塗層而形成後塑性的 鉉枝_可利㈣氧化銥 銥氧化物、叫等任-種或其化合物以釭、 而形成厚度100-5〇〇(Α)的膜。。物乂 SPutter方式塗層 ^形成上述帶㈣止膜後，再於其 度適用中國國_ 氧化石夕爲主成 210X297公釐） --I------#衣------訂------ π請先閲讀背希之这意事項夕你寫本頁；Γ ' - 經濟部中央標率局貝工消f合作社印製 A 7 B7___ 五、發明説明（/ ) 份的一種或其化合物以sputter方式形成具氧化梦成份的 SiO成份塗層層（103)。 又，可利用形成反射防止層（104)的矽（Si)、二氧化 石夕（Si 02)中任一種或其化合物爲主要成份的溶膠以Spin 方法做塗層；其膜厚度500〜1500 (A)的膜。 以這樣的塗層方法，再具體言知之，其透過實施例的 特性評價，將有如下的結果。 在構成導電層時的陰極射線管的前表面（101)於清除 塵埃等異物後，利用Sputter機器，可以低阻抗的IT0做 塗層處理，使形成防止帶電膜，且再以Sputter方法將SiO 成份的塗層處理後（1〇3)，以Spin方式在反射防止層（1〇4) 覆以具有Si02微粒分子的矽溶膠的塗層處理。 上述的Sputter方式係在眞空中，使氬（Ar)氣體離子 化，而與標靶碰撞，此時所產生的標的原子即被塗層，這 種方式以原子狀態的塗層將具有絶佳的附著力。 因此，在帶電防止禎與反射防止層（1〇4)間以Sputter 方式使SiO成份做塗層，使得膜間有很好的附著力，並提 高膜強度。 而且，表面阻抗可有較低的阻抗，使得共塑性前/後 的表面阻抗値幾乎沒有變化。 本發明的實施例利用Sputter方式實際在陰極射線管 前面塗層以膜厚27〇 A的ITO成份而形成帶電防止膜，且 _______?------ 本紙張尺度適《中國S家標苹（rNS ) Λ4規格（210X 297公釐） I |訂 n. _ 線 (請先閲讀背面之注意事項寫本頁) „ A7 A7 經濟部中央標準局負工消费合作社印製 本紙張尺度適2ΐ〇χ298 B7 五、發明説明（ί-) 以Sputter方式塗層以膜厚1〇〇a的Si〇成份而形成矽塗 層（1ίΠ)後，再以SPin方式利用矽溶膠構成膜厚ΙΟΟΑ紙 反射防止層（1〇4)。在此，帛4目即表示固躲末含量詞 膜厚變化表，如圖所示，發溶勝的固態粉末量爲〇 時之塗層後膜厚爲11G〇A。 從上述的實施例評價結果觀之，帶電防止膜的膜厚2几 A的折射率爲I95，反射防止層（10 4)的膜厚1200A的折 射率爲I·35，在以波長55〇nm的範園，顯示有以下 的反射率。 r 而表面阻抗類示有ΙΟΟΩ/cm2的水準。 同時塗層後塑性前4灸的表面阻抗値也沒有變化。 如上所述，以習知的SPutter方式作ITO層塗雇而形 成帶電防止膜後，再以Spin方式作⑦溶膠塗層而形成反 射防止層（1G4)時所產生的問題，可在上述兩膜間以s處 理SpuUer方式以si〇成份加一塗層（1()3)，如此彳獲得 2 =較低的表面阻抗値，其在波長範園在55。⑽領域可 :二下的反射特性，且塗層後塑性前/後的表面 阻抗値也沒有變化，膜強度也佳。 渙金!Ιίΐϊ說明，本發明的陰極射線管製造方法中，在 =方亡膜與反射防止膜間以Sputt。方式作si。成份的 你冑電防止膜與反射防止膜間的siQ成份的塗層， 描ΓΓΐ'Γΐ方式在眞空中使氬氣體離子化，使與標把碰 尸生的標的原子即被塗層，這種方式以原子狀 I I 裝―———I I n .f n 線 • ! (請先閱讀背面之'if意事項#<转本頁) 一 A7 A7 發明说明（ B7 態的塗層將具有絶佳的附著力。且可形成表面阻抗値低、 塗廣後塑性前/後的表面阻抗値也沒有變化。且因反射防 止膦係使用Sl0成份，其塗層簡單，價格低、故可提高生 如此，可使螢幕表面具有防止帶電的功能、可降低外^ 部光的反射，以提高畫面的反差特性，同時可解決因手指 等對畫面朗所造柄指紋_，而㈣使用者不快的效 采。 g式説明： 第1 知之防止帶電及反射膜㈣成之陰極射線管概 第2 具有岐料及讀麟陰極射 第3 發明之_射線管面板表面形成各防止膜之形 第4圖石夕溶膠固態粉末厚度變化圖。 第5圖爲各塗廣的反射率曲線變化圖。 圖號説明： 1 漏斗型 2 面板 ---------批衣------1Τ------線 I (請先閱讀背面之注意事項"4^本頁) 一 經消部中央摞枣局貝工消费合作社印製 101面板 102帶電防止膜 本紙張尺度適用中國围家標埤（（'NS ) Μ規格（210X 297公釐） B7 五、發明説明（/) 3 帶電防止膜 103 SiO成份塗層層 4 反射防止膜 1〇4反射防止層 5 帶電防止膜 6 反射防止膜 7 固定台 8 研磨機 9 喷嘴 11 金屬標靶 12旋轉台 13 喷嘴 14 發熱器或紫外線燈 (請先閱讀背面之注意事項寫本頁) 經濟部中央標隼局员工消費合作社印製 本紙張尺度適州中國國家標率（（'NS ) Λ4規格（210X 297公釐)I A7 B7 V. Explanation of the invention (> /) It must be maintained below 100θΩ / cra2. In order to form the above-mentioned antistatic film and antireflection film, other known methods are to clean the front plate of the cathode ray tube and polish it with oxygen (CeO2), and then polish the polished surface with pure water or alcohol. Wash and dry. After the dried cathode ray tube is placed on a preheating furnace, the surface of the coated cathode ray tube is heated at 40 ~ degrees, and the spin or spray method is used to make the The dispersed antimony (Sb) component is spread on the sol as a coating to form an anti-charge film (3), and the first-mentioned anti-charge film and other silicon oxide components with refractive index are formed on the upper part, and the method is as described above. The anti-reflection film (4), which prevents PC users from causing fatigue even after long-term use, such as coating treatment. —At this time, although an anti-glare with unevenness is formed on the upper part of the anti-reflection film by a mouth mist method, this kind of streaks that cause problems when forming an anti-reflection film (AR) coating is not easy to feel. Therefore, it is necessary to reduce the diffuse reflectance, and at the same time, reduce the problem of hand fingerprints. Printed by the Shell and Consumer Cooperative of the Central Bureau of Standard Vehicles of the Ministry of Economic Affairs. However, the above-mentioned Spin spray method is not conducive to the washing of pharmaceuticals when forming a charge prevention film, and will increase the scratches on the panel and the management of foreign objects such as adhesion marks difficult. Like the above-mentioned ARAS coating or AGARS coating, the current surface resistance of the anti-static AS (Anti-Static) coating on the charged layer reaches the level of 10HQ / cm2, which conforms to the specifications of the MPRU; the invention, but is currently more The concern is that TCO specifications cannot be met. This paper is of suitable size (CNS) (2 丨 0X2975 mm) The standard paper of the Ministry of Standards of the Ministry of Standards and Technology of the People's Republic of China, Beiyang Consumer Cooperatives, Co., Ltd., India, iridium silicon paper, ϋ; Seed ϋ ® A7 B7 V. Description of the invention (彳) In addition, The IT layer used in the known AS layer and AR layer method is not only expensive, but the current surface resistance of ιτο is i〇5_6Q / cm2, which does not meet the required standard of TC〇. In addition, the above ττ〇 coating is used. At this time, the effect of EMI Shielding is insufficient. Therefore, it is necessary to meet the TC0 requirement standard under the surface impedance 纟 i〇3Q / cm2 #, and the monitor t is reinforced in the compensation circuit. The present invention is explained in detail in the present invention. The present invention aims at the above-mentioned problems. Whether it is a Sputter method using an anti-charge film on the outside of the panel, or a coating Sputter method using silicon oxide as its main component, and using an anti-reflection film on the top The Spin method of the adhesive film is a manufacturing method of plasticity (heat treatment) after coating to form a panel coating film of a cathode ray tube. In the following, the invention is described with reference to the illustration attached to the dead weight. The method for manufacturing a low-impedance reflection-preventing cathode ray tube of the present invention is described below. In the embodiment of the present invention shown in FIG. The anti-film is coated with & on the outside of the panel, and the anti-reflection layer Uq4 of the sol is coated in a manner of oxidizing the hair component by using a & coating /, (1 ° 3 ), And then coated thereon by the "manufacturing method" Spin method to form a post-plastic cymbidium_Colidium iridium oxide iridium iridium oxide, or any other species or a compound thereof, to form a thickness of 100-5 〇. (A). . Material: SPutter coating ^ After forming the above-mentioned film with stopper, it is applicable to the country of China _ oxide stone eve is mainly 210X297 mm) --I ------ # 衣 ------ Order ------ π Please read the meaning of the Greek matter before you write this page; Γ--Printed by the Cooperative Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A 7 B7___ 5. Description of the invention (/) One or a compound thereof forms a SiO coating layer (103) with an oxide dream component in a sputter manner. In addition, the sol may be used as a coating to form a coating using any one of silicon (Si) and silicon dioxide (Si 02) or a compound thereof which forms the anti-reflection layer (104); the film thickness thereof is 500 to 1500 ( A). With such a coating method, and more specifically, it is known that the characteristics of the examples are evaluated and the following results are obtained. After the front surface (101) of the cathode ray tube when forming the conductive layer is cleaned of foreign matter such as dust, a Sputter machine can be used to coat the low-resistance IT0 to form an anti-charge film, and then the SiO component is formed by the Sputter method. After the coating treatment (103), the anti-reflection layer (104) was spin-coated with a coating of silica sol having SiO2 particles. The above-mentioned Sputter method is in the radon space, which ionizes argon (Ar) gas and collides with the target. At this time, the target atom generated is coated. The atomic coating in this way will have excellent adhesion. force. Therefore, the SiO component is coated by the Sputter method between the anti-cathode and the anti-reflection layer (104), so that the films have good adhesion and improve the film strength. Moreover, the surface impedance may have a lower impedance, so that the surface impedance 値 before / after coplasticity hardly changes. The embodiment of the present invention uses the Sputter method to actually coat the front surface of the cathode ray tube with an ITO component with a thickness of 27 Å to form an anti-charge film, and _______? ------ This paper is suitable for "China S House Standard" Ping (rNS) Λ4 specification (210X 297 mm) I | Order n. _ Line (please read the notes on the back to write this page) „A7 A7 The printed paper of the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives has a paper size suitable for 2ΐ 〇χ298 B7 V. Description of the invention (ί-) After coating the Si coating with a thickness of 100a by the Sputter method to form a silicon coating (1ίΠ), the silica film is used to form the film thickness by the SPin method. Preventive layer (104). Here, 目 4 mesh represents the film thickness change table of solid content, as shown in the figure, when the amount of solid powder is 0, the film thickness after coating is 11G. A. From the evaluation results of the above examples, the refractive index of the anti-static film with a thickness of 2 to A is I95, and the refractive index of the anti-reflection layer (10 4) with a thickness of 1200 A is I · 35, at a wavelength of 55. The Fanyuan of 0nm shows the following reflectance. R The surface impedance class shows a level of 100Ω / cm2. At the same time The surface resistance 値 of the first 4 moxibustion after plasticization has not changed. As mentioned above, after the ITO layer is coated by the conventional SPutter method to form an anti-charge film, the spin method is used to form the anti-reflection layer to form a reflection prevention layer The problem caused by (1G4) can be treated as SpuUer between the above two films, and a coating (1 () 3) is added to si0 component, so that 2 = lower surface impedance is obtained, which is at the wavelength Fan Yuan is in the field of 55. The field can be: two reflection characteristics, and the surface impedance before and after plasticization has not changed, and the film strength is also good. 涣 金! ΙίΐϊDescribes the method of manufacturing the cathode ray tube of the present invention In the method, a Sputt. Method is used between the square film and the anti-reflection film as the si. Component. The coating of the siQ component between the anti-electron film and the anti-reflection film is described. To make the target atom that has collided with the target is coated. In this way, it is installed in atomic II —---- II n .fn line •! (Please read the 'if 意 事 # < This page) A7 A7 invention description (B7 coating will have excellent adhesion It can form a low surface impedance and no change in the surface impedance before / after plastic coating. And because the anti-reflection phosphine system uses the Sl0 component, its coating is simple and the price is low, so it can be improved, which can make the screen The surface has the function of preventing electrification, which can reduce the reflection of external light to improve the contrast characteristics of the screen. At the same time, it can solve the unpleasant effect of the user's fingerprints caused by the finger on the screen. : The first known cathode ray tube to prevent the formation of electrification and reflection films. The second invention has a cathode and a read cathode. The third invention is the shape of the prevention film on the surface of the ray tube. Illustration. Fig. 5 is a graph showing the change of the reflectance curve of each coating. Description of drawing number: 1 funnel type 2 panel --------- batch ----- 1T -------- line I (please read the precautions on the back first " 4 ^ this page) Once printed by the Central China Jujube Bureau, Shellfish Consumer Cooperative, 101 panels, 102, anti-charge film, the paper size is applicable to the Chinese family standard (('NS) M specifications (210X 297 mm) B7 V. Description of the invention (/) 3 Anti-static film 103 SiO component coating layer 4 Anti-reflection film 104 Anti-reflection layer 5 Anti-static film 6 Anti-reflection film 7 Fixed table 8 Grinder 9 Nozzle 11 Metal target 12 Rotary table 13 Nozzle 14 Heater or UV lamp (Please read the notes on the back first to write this page) Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Consumer Cooperatives Paper size Shizhou China National Standard (('NS) Λ4 Specification (210X 297mm)