A7 B7 五、發明説明（1 ) 〔發明之領域〕 - 本發明係有鬭於洗衣機，特別是有闞可將供給洗衣槽 的水中或洗衣液中所含有的游離氯除去的洗衣機。 〔發明之背景〕 通常洗衣機係使用自來水。而於自來水中，殘留有為 了殺菌所使用的游雛氯。殘留氯之濃度，係為約0.1PPM〜 約1.4PPM。習知，為了除去供給洗衣機的自來水中所殘留 之游離氯的技術，係被記載於特開平02-136170號公報、 特開平06-1544 7 4號公報及特開平06-238 0 92號公報。 記載於特開平02-136 170號公報之洗衣機的重要部位 之斜視圖，係被顯示於第4圖。於第4圖上，連接著給水 管101的給水閥10 2上，被連接著一內部水管103。該內部 水管103連接著給水路徑切換部104。由該給水路徑切換部 104通過一內藏填加入游難氯除去材料之儲存盒（未顯示 於圖上）的殘留游離氯除去装置105,並可將除去殘留游 離氯的自來水，從給水口 106向水槽內給水。 於特開平Q 6- 1 54474號公報所記載之洗衣機的重要部 位之斜視圖與截面圖，係被顯示於第5 I#。於第5圖上， 給水管101係連接於2連接頭給水閥107。並將一內藏充填 入游離氯除去材料108之儲存盒109的殘留游雠氯除去裝置 110，連接於該2連接頭給水閥107之一方。而由殘留游雛 氯除去裝置110之流入口 111所進入的自來水，係通過游離 氯除去材料108，而從流出口 112流出。而除去殘留游離氯 的自來水，係從給水口 10 6向水槽內給水。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） iklul! (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部中央標隼局員工消費合作社印製 A7 B7 五、發明説明（2 ) 記載於特開平06-2 38Q9 2號公報的洗衣機之重要部位 斜視圖與切除儲存盒之一部分的斜視圖，係顯示於第6圖 。於第6腫上，將收納充填著游離氯除去材料108之儲存 盒113的過濾網盒114，係在通過連接於給水閥1Q2的內部 水管10 3而給水的給水路徑上*圼抽屜式而可裝脫自如的 安裝著。在過濾網盒114被裝置著時，可向水槽內供入除 去了殘留游離氯的自來水。 於特開平02-136170號公報及特開平06-154474號公報 所記載的構成上，由於將供水路徑完全的切換，使所有供 入之水通過游雛氯除去材料，同時為了要通過充填緻密之 游離氯除去材料*故有必要附加水壓。 更且，使用了堪原劑的儲存盒方式上*當作邐原劑使 用係以有遨原作用的亞硫酸鈣粉末為主要成分，並使用著 Μ難溶於水的乙基鎩維素等當作结合劑的粒狀體遷原劑。 此時，其反應機構的原理，係使殘留游離氯接觸於粒狀體 之亞硫酸鈣的表面而反應者。. 更且，於充填粒狀體的構造上，會容易產生水容易通 過之部分與水難於通過之部分的兩大部分，因此在附加水 壓狀態下使用時，水容易通過部分之還原材科係比其他部 分的遷原材料與更多的殘留游離氯產生反應。該结果，於 水難於通過之部分，在還原材料的有效成分遒殘留很多的 狀態下而發生短傳現象，成為在無除去水中之殘留游離氯 的狀態，而到達游離氮除去材料之壽命盡頭。 更且，使用了活性碳的儲f盒上，由於自來水中所含 本紙張尺度逋用中國國家標準（CNS ) A4規格（2丨0乂297公釐） _ΕΕΙ-·· (請先閱讀背面之注意事項再填寫本頁) ....二.. 經濟部中央標準局員工消費合作社印製 6 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明（3 ) 的異物而發生網目阻塞，因此造成流量降低。更且，通過 活性碳中之水的流速增加，因超過活性碳之吸著能力，而 .使水中之殘留游離氯漸漸無法被除去，而到達壽命。 而於任一種情況，使用者也都不可能從洗衣機之外面 知道其壽命的狀況，因此，從使用之次數等來預測壽命。 記載於特開平06-238092號公報的構造上*係將除去 殘留游離氯的自來水注入於水槽內。因此，於該裝置著收 納儲存盒之過滅網盒的部分上，為了除去含於自來水中的 殘留游離氯，使用難溶性的遢原劑時，必需要與自來水有 高的接觸效率（大的接觸面機）。依此，於使用中慢慢的 使還原劑與自來水之接觸面積變小，有變成無法有效率的 將游離氯除去之缺點。更且，使用者不可能從外面知道其 壽命的狀況，因此，從使用次數等來預測遷原劑的壽命。 另外，於儲存盒內使用易溶解性的遷原劑時，從洗衣 .....過程經#至清洗過程之各過程_占.，.係不可能將所控制之規 定量的遷原劑加入於自來水中。因此，會有多餘之遒原劑 被含於洙衣液中的情況，此時由於遷原作用而使被洗濯衣 服之染料等之顔色，會有發生變色的情形。 本發明之洗衣機係解決上述課題，並將於洗濯時所使 用之水中所含有的殘留游離氯，有效.率且迅速的除去，而 且防止依含於自來水中之殘留游雛氛的氧化作用，而造成 被洗灌衣服之色澤褪色或絲綢的變黃或各種有機類之纖維 表面加工材料的氧化等，同時防止因剩餘之還原劑的堪原 作用所造成的有色衣服之變色，做為其目的。 (請先閲讀背面之注意事項再填寫本頁) 裝. 訂 .—I. 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 B7 五、發明説明（4 ) 〔發明的摘要〕 本發明之洗衣機係由：一洗衣槽，及一為了將水供入 前述洗衣槽內的供給裝置，及一為了除去含於前述水中之 游離氯的氯除去劑，及一為了將前述氯除去劑Μ期望之濃 度供入於前述之水中的濃度控制装置所構成。通過前述給 水裝置•將前述之水供給於洗衣槽時，其前述氯除去劑係 依前述之濃度控制裝置，使其被控制於期望之濃度，並混 入於前述之水中。被混入於前述之水中的前述氯除去劑， 係與含於前述之水中的游離氯產生反應*而使游離氯被除 去。 於上述構成上，尤其最希望的是該氯除去劑係為一種 遨原劑，並且該遷原劑會與游離氯產生反應，而使游離氯 被除去。尤其最希望的是將含有氯除去劑之水供入洗衣槽 之中。尤其最希望的是使氯除去劑呈分散或溶解的狀態而 被含於水中。尤其最希望的是將混入氯除去劑之水與不含 有氯除去劑之水，兩者都被注入於洗衣槽之中。 依上述構成，則不需要將給水路徑完全的轉換，另外 ，也不需要將水壓附加於儲存盒。更且，不要求使氯除去 劑與自來水有高接觸效率，而只要將預先設定之規定量的 氯除去劑，分散或溶解於自來水中或洗衣槽之中即可。更 且，於水中分散或溶解著氯除去劑，因此，使殘留游離氯 能Μ良好效率且迅速的產生反應，而將其除去。該结果， 可防止因含於自來水'中之殘留游離氯的氧化作用，而造成 '被洗灌衣服之色澤變色、褪色、及絲綢的變黃或各種有機 本纸張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐）. _ ο _ 1—Fr (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作社印製 Α7 Β7 經濟部中夬標準局員工消費合作社印製 五、發明説明（5 ) 類之纖維表面加工材料的氧化等。 於上述構成上，尤其最希望的是該氛除去劑係為一種 邐原劑*並且該堪原劑係Μ成型體、液體或是粉末之任一 種狀態所構成。 在還原劑為一成型體時》該成型體係由一遷原劑與一 能慢慢溶解於水的结合材料所構成。结合材料係將遨原劑 與其互相的結合著。此時，濃度控制装置係為控制结合材 料對水之溶解速度。亦即是，使從給水裝置供入之水接觸 於成型體的表面，且依該接觸使結合材料在控制之速度下 ，慢慢的溶解於水中，而隨著结合材料的溶解，使遷原材 料以期望之濃度被混入於水中。而混入之遷原劑與水中之 殘留游離氯產生氧化遨原反應，而可除去殘留游雛氛。 另一方面，液體之遷原劑依濃度控制裝置以計量該 規定量，並將其加入於將要供入於洗衣槽內之水之中，或 直接加入於洗衣槽內之水中。液體之遨原劑係快速的分散 或溶解於水中，且與殘留游離氯產生反應，而可除去該殘 留游離氯。 更且，粉末之還原劑係依濃度控制裝置以計量該規定 量，並將其加入於將要供入於洗衣槽內之水之中，或直接 加入於洗衣槽之洗衣水中。該粉末之選原劑係分散或溶解 於水中，且與殘留游雛氯產生反應，而可除去該殘留游離 氯。 於以上之構成上，尤其最希望的是至少於洗灌過程或 清洗過程兩者之任一種的過程上，構成使遨原劑呈分散或 _uEJLlJiu-it;. (請先閲讀背面之注意事項再填寫本頁) •裝. 訂 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） A7 B7 經濟部中央標隼局員工济費合作社印製 五、發明説明（6 ) 溶解之狀態。依該構成，從洗濯過程至清洗過程及至脫水 後之乾燥過程為止之過程上，使可用除去了有氧化作用之 殘留游離氯的水處理被洗濯衣观。 於Μ上之構成上，尤其最希望的是當作成型體而被構 成的還原劑，會依與水的接觸，而構成使該成型體之大小 變小。依該構成，由目視Μ確認還原劑的大小，而可告知 使用者遨原劑之交換或添加時期。 於Μ上之構成上，尤其最希望的是將要供入於洗衣槽 內之水之中或洗衣槽內之洗衣液之中，其所分散或溶解的 遷原劑之澹度，係為可餘去約O.lppm〜約4ppm (尤其最希 望的是約lppm〜約4ppm)的游離氯之湄度。依該構成，該 遷原劑為亞硫酸鈣時，為了除去含於自來水中之ΙΡΡ®的殘 留游離氣*則遷原劑之濃度必需為2 . 33ppm，因此，遷原 劑之濃度約lQppm時，則可除去約4ppm之濃度的殘留游離 氯。另外，遷原劑為亞硫酸f酵納時，為了除去含於自來 水中的lppm之殘留游離氯，則還原劑之濃度必需為2.4ppm ，因此，遨原劑之濃度約1 GPPm時，則可除去約4ppm之濃 度的殘留游離氯。於日本之自來水法上*規定殘留游離氯 之濃度必需為O.lppmM上，而實際之殘留游離氯之濃度約 為1.2ppai〜1.4ppm。因此，將可除去約4p_pm之游離氯的還 原劑濃度混入水中的話，則可完全除去自來水中的殘留游 _ _................離氯。 另一方面，檢討於洗衣液之中殘留過剩之還原劑時， 該被洗灌衣物所受的影響。结果，洗衣水中之遷原劑湄度 iiylLEE-l.b.l.. (請先閲讀背面之注意事項再填寫本頁) .裝. 訂 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -10 - 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明（7 ) 在lGppra時，對有染料等之顔色的被洗濯衣物之變色或褪 色的影響程度*係為在約2 0次洗濯後有輕微但可被接受之 程度，所以殘存之遷原劑幾乎對被洗濯衣物未造成影響。 〔圖面之簡單說明〕 第1圖係為本發明之第1實施例之洗衣機的重要部位 截面圖； '第2圖係為本發明之第2實施例之洗衣機的重要部位 截面圖； 第3圖係為本發明之第3實施例之洗衣機的重要部位 截面圖； 第4圖係為習知之洗衣機之一例的重要部位分解斜視 圖； 第5圖之（a)圖係為習知之洗衣機之另一例子的重要 部位分解斜視圖* 00圖係為該相同洗衣機之殘留游離氯 除去裝置之截面圖； 第6圖之（a)圖係為習知之洗衣機之另一例子的重要 部位分解斜視圖，（b)圖係為該相同洗衣機之儲存盒之一 部分切除的截面圖。 〔適當實施例之詳细說明〕 有關本發明之簧施例一邊參照圖面一邊予Μ說明。 第1實施例 本發明之實施例之洗衣機的重要部位截面圖係顯示於 第1圖。於第1圖上，給水管1係將其一端連接於自來水 龍頭（未顯示於圖），而將另一端鎖合於給水閥2。給水 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） -11 - 、(請先閱讀背面之注意事項再填寫本頁)A7 B7 V. Description of the Invention (1) [Field of Invention]-The present invention relates to a washing machine, particularly a washing machine capable of removing free chlorine contained in water or laundry liquid supplied to a washing tub. [Background of the Invention] Generally, a washing machine uses tap water. On the other hand, there is residual chlorine in tap water for sterilization. The residual chlorine concentration is about 0.1 PPM to about 1.4 PPM. Conventionally, techniques for removing free chlorine remaining in tap water supplied to a washing machine are described in Japanese Patent Application Laid-Open No. 02-136170, Japanese Patent Application Laid-Open No. 06-1544 74, and Japanese Patent Application Laid-Open No. 06-238 0 92. A perspective view of an important part of the washing machine described in Japanese Patent Application Laid-Open No. 02-136 170 is shown in FIG. 4. In Fig. 4, an internal water pipe 103 is connected to the water supply valve 102 connected to the water pipe 101. The internal water pipe 103 is connected to a water supply path switching unit 104. The water supply path switching unit 104 fills the residual free chlorine removal device 105 of a storage box (not shown in the figure) for adding free chlorine removal material, and the tap water from which the residual free chlorine is removed can be removed from the water supply port 106. Feed water into the sink. An oblique view and a cross-sectional view of an important part of the washing machine described in Japanese Patent Application Laid-Open No. Q 6-1 54474 are shown in No. 5 I #. In FIG. 5, the water supply pipe 101 is connected to the 2-connector water supply valve 107. A residual chlorine removal device 110 containing a storage box 109 filled with the free chlorine removal material 108 is connected to one of the two-connector water supply valves 107. The tap water entering through the inflow inlet 111 of the residual chlorine removing device 110 passes through the free chlorine removing material 108 and flows out from the outflow outlet 112. The tap water from which residual free chlorine is removed is fed into the water tank from the water supply port 106. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) iklul! (Please read the notes on the back before filling this page) Order the A7 B7 printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (2) An oblique view of an important part of the washing machine described in Japanese Patent Application Laid-Open No. 06-2 38Q9 No. 2 and an oblique view of a part of the storage box cut out are shown in FIG. 6. On the 6th swelling, the filter box 114 containing the storage box 113 filled with the free chlorine removing material 108 is attached to the water supply path through the internal water pipe 103 connected to the water supply valve 1Q2. Removably installed. When the filter box 114 is installed, tap water from which residual free chlorine has been removed can be supplied into the water tank. In the structures described in Japanese Patent Application Laid-Open No. 02-136170 and Japanese Patent Application Laid-Open No. 06-154474, because the water supply path is completely switched, all the supplied water is passed through the chlorine removing material to remove the material, and at the same time, it is required to be dense by filling. Free chlorine removal material * requires additional water pressure. In addition, the storage box method using kangen agent * is used as a rhenium agent. The main component is calcium sulfite powder with horogen effect, and ethyl stilbene, which is insoluble in water. As a binding agent, the granule migration agent. At this time, the principle of the reaction mechanism is that the residual free chlorine contacts the surface of the calcium sulfite of the granular body and reacts. In addition, in the structure of the filled granular body, there are two major parts that are easy to pass through and the parts that are difficult to pass through. Therefore, when used under an additional hydraulic pressure, water is easy to pass through some reducing materials. It reacts with more residual free chlorine than other raw materials. As a result, in the part where water is difficult to pass, a short transmission phenomenon occurs in a state where the active ingredient 还原 of the reducing material remains in a large amount, and it becomes a state where free chlorine is not removed from the water, and the end of the life of the free nitrogen removing material is reached. In addition, on the storage box using activated carbon, because of the paper size contained in tap water, the Chinese National Standard (CNS) A4 specification (2 丨 0 乂 297 mm) _ΕΕΙ- · (Please read the back Note: Please fill in this page again.) ..... 2: Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 6 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 5. The foreign matter of the invention description (3) is blocked , Thus reducing traffic. Furthermore, the velocity of water passing through the activated carbon increases, which exceeds the adsorption capacity of the activated carbon, so that the residual free chlorine in the water gradually cannot be removed, and the life span is reached. In either case, it is impossible for the user to know the life of the washing machine from the outside of the washing machine. Therefore, the life is predicted from the number of uses. The structure described in Japanese Patent Application Laid-Open No. 06-238092 * is a method in which tap water from which residual free chlorine is removed is poured into a water tank. Therefore, in order to remove the residual free chlorine contained in tap water on the part of the device that holds the storage box, it is necessary to have high contact efficiency with tap water (large Contact surface machine). Accordingly, the contact area between the reducing agent and tap water is gradually reduced during use, and there is a drawback that free chlorine cannot be removed efficiently. Furthermore, it is impossible for the user to know the life status of the agent from the outside. Therefore, the life of the regenerative agent is estimated from the number of uses. In addition, when using the easily soluble migration agent in the storage box, it is impossible to change the controlled amount of migration agent from the washing ..... process through # to the washing process. Add to tap water. Therefore, there may be cases where an excess osmium agent is contained in the yam solution. At this time, the color of the dye or the like being washed may be discolored due to the migration effect. The washing machine of the present invention solves the above-mentioned problem, and effectively and quickly removes residual free chlorine contained in the water used in washing, and prevents the oxidation of residual free atmosphere contained in tap water, and It can cause the discoloration of washed clothes or the yellowing of silk or the oxidation of various organic fiber surface processing materials, and prevent the discoloration of colored clothes due to the kangaric action of the remaining reducing agent. (Please read the notes on the back before filling in this page) Binding. Ordering—I. This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Description of the invention (4) [Abstract of the invention ] The washing machine of the present invention is composed of: a washing tank, and a supply device for supplying water into the aforementioned washing tank, and a chlorine removing agent for removing free chlorine contained in the aforementioned water, and one for removing the aforementioned chlorine The concentration of the desired concentration of the agent M is constituted by a concentration control device which is supplied to the aforementioned water. When the aforementioned water is supplied to the washing tub through the aforementioned water supply device, the aforementioned chlorine removing agent is controlled to a desired concentration according to the aforementioned concentration control device, and is mixed into the aforementioned water. The chlorine removing agent mixed into the water is reacted with the free chlorine contained in the water to remove the free chlorine. In the above configuration, it is particularly desirable that the chlorine removing agent is a rhenium agent, and the migration agent reacts with the free chlorine to remove the free chlorine. It is particularly desirable to supply water containing chlorine remover to the washing tub. It is particularly desirable that the chlorine removing agent be contained in water in a dispersed or dissolved state. It is particularly desirable that water mixed with the chlorine removing agent and water not containing the chlorine removing agent are both injected into the washing tub. According to the above structure, it is not necessary to completely change the water supply path, and it is not necessary to add water pressure to the storage box. Furthermore, it is not required to make the chlorine removing agent have high contact efficiency with tap water, but it is only necessary to disperse or dissolve a predetermined amount of the chlorine removing agent in tap water or a washing tub. Furthermore, since the chlorine removing agent is dispersed or dissolved in water, the residual free chlorine can be reacted efficiently and quickly to remove it. This result can prevent the discoloration and discoloration of clothes being washed and washed, and the yellowing of silk due to the oxidation of residual free chlorine contained in tap water, or various organic paper standards. Applicable to Chinese national standards (CNS) ) Α4 specification (210 × 297 mm). _ Ο _ 1—Fr (Please read the notes on the back before filling out this page) Printed by the Consumers 'Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Α7 Β7 Employees' Cooperatives of the China Standards Bureau of the Ministry of Economic Affairs Printing 5. The description of invention (5) oxidation of fiber surface processing materials. With regard to the above constitution, it is particularly desirable that the atmosphere removing agent is a rhenium agent * and that the kangen agent is any one of a molded body, a liquid, or a powder. When the reducing agent is a molded body, the molding system is composed of a migration agent and a binding material capable of slowly dissolving in water. The binding material binds the primogenogen to each other. At this time, the concentration control device is to control the dissolution rate of the binding material to water. That is, the water supplied from the water supply device is brought into contact with the surface of the molded body, and according to the contact, the bonding material is slowly dissolved in the water at a controlled speed, and as the bonding material is dissolved, the raw materials are transferred. It is mixed in water at a desired concentration. The mixed priming agent reacts with residual free chlorine in the water to generate a osmium oxide reaction, which can remove residual free-living atmosphere. On the other hand, the liquid original agent is measured by the concentration control device to measure the prescribed amount and added to the water to be supplied into the washing tub, or directly into the water in the washing tub. Liquid rhenium agents disperse or dissolve in water quickly and react with residual free chlorine to remove the residual free chlorine. Moreover, the reducing agent of the powder is measured according to the concentration control device and added to the water to be supplied in the washing tub, or directly into the washing water in the washing tub. The powder's original agent is dispersed or dissolved in water and reacts with residual free chlorine to remove the residual free chlorine. With regard to the above composition, it is particularly desirable that it is constituted to disperse the rhenium agent or _uEJLlJiu-it; at least in either of the washing process or the washing process; (Please read the precautions on the back first (Fill in this page again) • Binding. The size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 Printed by the Employees' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of the invention (6) Dissolved state . According to this structure, from the washing process to the washing process and to the drying process after dehydration, the water treatment which can remove the residual free chlorine with oxidation effect can be washed. With regard to the constitution of M, it is particularly desirable that the reducing agent constituted as a molded article will be made smaller in size by contact with water. According to this configuration, the size of the reducing agent can be confirmed by visual inspection, and the user can be informed of the time of replacement or addition of the rhenium agent. In terms of the composition on M, it is particularly desirable that the degree of dispersal or dissolution of the migratory agent to be supplied into the water in the washing tank or the washing liquid in the washing tank is redundant. Remove about 0.1 ppm to about 4 ppm (especially most desirable is about 1 ppm to about 4 ppm) of free chlorine. According to this configuration, when the migrating agent is calcium sulfite, in order to remove the residual free gas of IPP® contained in tap water, the concentration of the migrating agent must be 2.33ppm. Therefore, when the migrating agent is about 1Qppm , You can remove residual free chlorine at a concentration of about 4ppm. In addition, when the original agent is sulfite ferment, in order to remove 1 ppm of residual free chlorine contained in tap water, the concentration of the reducing agent must be 2.4 ppm. Therefore, when the concentration of the original agent is about 1 GPPm, Residual free chlorine was removed at a concentration of about 4 ppm. According to the Japanese tap water law *, the concentration of residual free chlorine must be 0.1 ppmM, and the actual concentration of residual free chlorine is about 1.2ppai ~ 1.4ppm. Therefore, if a concentration of a reducing agent capable of removing about 4 p_pm of free chlorine is mixed into the water, the residual free chlorine in tap water can be completely removed. On the other hand, when the excessive reducing agent is left in the washing liquid, the influence on the laundry to be washed is examined. As a result, the original agent in the washing water Maedii iiylLEE-lbl. (Please read the precautions on the back before filling this page). Packing. The size of the paper is applicable to China National Standard (CNS) A4 (210X297 mm) -10 -Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (7) At lGppra, the degree of influence on the discoloration or fading of washed clothes with dyes and other colors is about 20 washings There is a slight but acceptable degree, so the residual migration agent has almost no effect on the clothes being washed. [Brief description of the drawing] Fig. 1 is a cross-sectional view of an important part of a washing machine according to the first embodiment of the present invention; 'Fig. 2 is a cross-sectional view of an important part of the washing machine according to the second embodiment of the present invention; FIG. Is a sectional view of an important part of a washing machine according to a third embodiment of the present invention; FIG. 4 is an exploded perspective view of an important part of an example of a conventional washing machine; FIG. (A) of FIG. 5 is another alternative of the conventional washing machine An exploded perspective view of an important part of an example * 00 is a cross-sectional view of the residual free chlorine removal device of the same washing machine; FIG. 6 (a) is an exploded perspective view of an important part of another conventional washing machine, (B) The figure is a partially cutaway sectional view of a storage box of the same washing machine. [Detailed Description of Appropriate Embodiment] The spring embodiment of the present invention will be described with reference to the drawings. First Embodiment A sectional view of an important part of a washing machine according to an embodiment of the present invention is shown in FIG. In Fig. 1, the water supply pipe 1 is connected to one end of a water tap (not shown), and the other end is locked to the water supply valve 2. Water supply This paper size applies Chinese National Standard (CNS) Α4 specification (210 X 297 mm) -11-, (Please read the precautions on the back before filling this page)
A7 B7 五、發明説明（8 ) 閥2之出口側係藉一内部水管3而與給水噴嘴15相連通。 而於給水唄嘴15之下方，裝置有一抽屜狀之盒16,並於該 盒之凸出部裝置著一含有成型體17,且更於其下方配置著 一給水口 18。如此而構成一給水構件。並通過給水口 18, 而向被設置於給水口 18之下方的洗衣槽19内注水。 成型體17係Μ當作還原劑的亞硫酸鈣為主要成分，由 一能慢慢溶解於水中的结合材料而被固定结合。而該能慢 慢溶解於水中的结合材料係成為濃度控制裝置。亦即是* 依控制遨原劑與结合材料之含有比率，而使混入於水中之 遷原劑的濃度被控制。更且，對應接觸於成型體之水量· 依控制成型體的表面積，而使混入於水中之遨原劑的澹度 被控制。 於洗衣過程或清洗過程之給水時，使給水閥打開而向 洗衣槽給水時，含有遷原劑之成型體17,係接觸到從給水 噴嘴15出來的水，而使其表面慢慢的分解，並使遷原劑混 入於水中，而被分散或溶解於洗衣槽19內的洗衣液之中。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 此時，在供給於洗衣槽19之水中圼分散或溶解.之遷原 劑的濃度，係約為可除去0. lppm〜約4ppm之殘留游雛氯的 濃度（亞硫酸鈣之濃度是約〇.24ppm〜約lOppm)，在與給 水流i的相關上，係由成型體17之大小或遷原劑與结合材 料的比率而做決定。另外，成型體Π係依對洗衣槽的給水 而使结合材料慢慢的溶解，而使成型體17之體積變小。上 述範圍所必需之遨原劑的濃度，係於利用日本之自來水的 場合才有效。含於自來水或所使用：£水中的殘留游離氯之 本纸張尺度適用中國國家標隼（ces ) A4規格（210X297公釐） -12 - A7 B7 五、發明説明（9 ) - 濃度不同時，對照該水中所含有之殘留游離氯的濃度，而 使用必需要之遨原劑的濃度。 於上述之構成上，在洗衣過程及清洗過程的各過程上 ，給水閥2打開時，自來水係藉著一内部水管3,而從給 水噴嘴15向裝於盒16內含有遨原劑之成型體17，圼噴灑狀 噴入而接觸到成型體17。此時，成型體17並不限於噴灑狀 態的接觸，而可用浸入於水中做接觸之構造。在成型體Π 接觸到自來水時·使含於成型體17中之结合材料慢慢的溶 解於水，而使成型體Π之表面被分解。該结果，使作為堪 原劑之亞硫酸鈣的微粒子混入於自來水中而被釋放出。並 使混入該微粒子的自來水經由給水口 18供入洗衣槽19内。 被混入於自來水中的亞硫酸鈣之微粒子，係與自來水 中的殘留游離氯做氧化遨原反應。依該反應使殘留游離氯 被除去。此時，於供入洗衣槽19內之水中呈分散或溶解的 遨原劑之濃度，因係為可除去約〇 ..lppm〜約4PP®之殘留遊 離氯的澹度•故可有效率的除去自來水或洗衣槽內之水中 所含有的殘留游離氯。因此，可防止因含於水中之殘留游 離氯之氧化作用，而造成的有色衣物的變色、褪色及絲綢 變葺，或可防止各種有機糸列之纖維表面加工材料之氧化 的缺點。另外，依對洗衣槽的給水而使成型體Π慢慢的溶 解，並使成型髏17之體積漸漸的變小，故由確認盒16内之 成型體Π大小，而可容易的知道遷原劑之交換時期。..該结 果，可提高洗衣懺之使用便利性，同時可減少遨原劑之損 失。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ii-Fi. I------I----- (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作社印製 經濟部中央擦準局員工消費合作社印製 A7 B7 五、發明説明(10 ) 於本賁施例上，構成將經混入有期望之濃度的遨原劑 之水，供入於洗衣槽内。而代替該構成，將經混入有堪原 劑之水與不含有埵原劑之水，兩者都供入於洗衣槽中，並 且可構成使該等之水於洗衣槽之中混合，而使邐原劑之濃 度變成所期望之濃度。例如，於第1圖上，於給水閥2之 出口側設有一持有兩個分歧出口的分歧給水閥，並使從該 兩個出口的其中之一出口所流出的水與成型體接觸，並且 ，使從另一出口所流出的水直接被供人於洗衣槽之中。 第2實施例 本發明之另一實施例之洗衣機之重要部位的截面圖係 被顯示於第2圖。於第2圖上，於透明容器20之中加入有 一作為還原劑之亞硫酸碳酸鈉的高濃度水溶液21。該透明 容器20係用一水管23而與定量水泵22連接，而連接於定量 水泵22之吐出口側的水管24，係與配設於姶水構件内之吐 出口 25相連通。由定量水泵2 2所吐出的亞硫酸碳酸鈉之高 濃度水溶液21之量，係將分散或溶解於洗衣槽內之洗衣水 的濃度，控制成為在可除去約O.lppm〜約4ppm之殘留游離 氯的濃度。此時，亞硫酸碳酸鈉濃度是為約0.25ppm〜約 ΙΟρρπι之間。其他之構成係與上述之第1實施例相同。 於上述構成上，在洗衣過程及清洗過程之各過程，給 水閥2打開時，自來水係藉一內部水管3，從給水噴嘴15 圼噴灑狀的供入於盒16内。此時，透明容器20內之亞硫酸 碳酸鈉之高濃度水溶液21，係依定量水泵22之動作，藉水 管23、2 4而僅將其規定量自動的從吐出口 2 5供入於自來水 本紙張尺度適用中國國家標準（CMS ) A4規格（ZIOXM7公釐） 14 (請先閲讀背面之注意事項再填寫本貫) .AS'裝. 訂 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明（11). 中。 供給於自來水中之規定量的亞硫酸碳酸納，之高濃度水 溶液21，係於給水口 18及洗衣槽19內，與自來水中具有氧 化作用之殘留游離氯進行氧化遷原反應，而將游離氯除去 • . .... . 0 此時，依定童水泵22所吐出的亞硫酸碳酸鈉之高濃度 水溶液21之量，該量係為將分散或溶解於洗衣槽內之洗衣 液時的濃度，變成可餘去約O.lPPm〜約4ppm之殘留游離氯 的濃度之量，故可有效率的除去自來水中所含有的殘留游 離氯。因此，可防止因含於自來水中之殘留游離氯的氧化 作用，而造成具有染料之顔色的被洗濯衣服之色澤變色、 褪色、及防止絲綢的變黃或各種有機類之纖維表面加工材 料的氧化等。另外，因透明容器20係為透明體，故液體之 遨原劑的殘留量’，可容易的從外面目視到而得知。因此* 可容易的知道向透明容器2G補充遨原劑的時期。 於本實施例上，構成使混入有期望之遷原劑濃度的水 能供入於洗衣槽之中。而代替該構成，另可構成使還原劑 直接供入於洗衣槽之中，並且在洗衣槽之中*使該遨原劑 與直接被供入於洗衣槽中之水混合。更且，使經混入有遷 原劑之水與不含遷原劑之水的兩者，一齊被供入於洗衣槽 之中，並且，構成可使該等之水被於洗衣槽之中混合*而 使還原劑之濃度成為所期望之濃度。 第3實施例 將本發明之再另一實施例之洗衣機的重要部位之截面 (請先間讀背面之注意事項再填寫本頁) 訂 0_ I. 1|~~'=. 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） -15- A7 __B7___ 五、發明説明（I2) - 圖表示於第3圖。於第3圖上，收納堪原劑之盒26,係收 納著作為還原劑的亞硫酸碳酸納之粉末41。於該遷原劑收 納盒2 6之下方設置有一馬達27。依馬達27並藉一傳達機構 28而使線圈彈簧29回轉，而將遨原劑收納盒26內之亞硫酸 碳酸鈉粉末，僅將所規定量之粉末從吐出口 30送入給水機 構內之自來水。依馬達27之回轉而送出的亞硫酸碳酸納之 粉末之量，係在分散溶解於洗衣槽19内之洗衣液中時，使 其量被控制在可除去約0. lppm〜約4ppm之殘留游離氯的濃 度之量。其他的構造1與上逑例相0^。 於上述構成上，在洗衣過程及^洗過程之各過程，給 水閥2打開時，自來水係藉一內部水管3 *從給水噴嘴15 圼噴灑狀的供入於盒16內。此時•依驅動馬達27並藉一傳 達機構28而使線圏彈簧29回轉，而將還原劑收納盒26內之 亞硫酸碳酸鈉粉末，僅將所規定量之粉末從吐出口 30送入 給水機構內之自來水。 供入於自來水中之規定量的亞硫酸碳酸納粉末，係藉 一給水口 18而進入洗衣槽，並於自來水或洗衣液中具有氧 化作用之殘留游離氯產生氧化還原反應。依該反應而將游 離氯除去。此時，因依馬達27之回轉而送出的亞硫酸碳酸 鈉之粉末之量，係在分散或溶解於洗衣槽19內之洗衣液中 時*使其量被控制在可除去約O.IPPffl〜約4ppm之殘留游離 氛的濃度之量，故可有效率的除去殘留游離氯。因此，可 防止因含於自來水中之殘留游離氛的氧化作用，所造成具 有顔色之被洗濯衣服之色澤、褪色•及防止絲綢的變黃或 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） .MiFigJLiMEJ6..i:. (請先聞讀背面之注意事項再填寫本頁)A7 B7 V. Description of the invention (8) The outlet side of the valve 2 is communicated with the water supply nozzle 15 by an internal water pipe 3. Below the water supply nozzle 15, a drawer-shaped box 16 is installed. A protruding body 17 is formed on the protruding portion of the box, and a water supply port 18 is arranged below the box. In this way, a water supply member is constructed. Water is injected into the washing tub 19 provided below the water supply port 18 through the water supply port 18. The molded body 17 is mainly composed of calcium sulfite serving as a reducing agent, and is fixedly bonded by a binding material capable of slowly dissolving in water. The binding material that can be slowly dissolved in water becomes a concentration control device. That is to say * the concentration of the migratory agent mixed in water is controlled by controlling the content ratio of the rhenium agent and the binding material. Furthermore, in accordance with the amount of water that comes into contact with the molded body, the surface area of the molded body is controlled so that the degree of the rhenium agent mixed in the water is controlled. When the water supply valve is opened during the washing process or the washing process, and the water is supplied to the washing tank, the molding body 17 containing the migration agent is contacted with the water coming out of the water supply nozzle 15 and its surface is slowly decomposed. The migration agent is mixed in water and dispersed or dissolved in the washing liquid in the washing tub 19. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). At this time, the concentration of the original agent in the water supplied to the washing tank 19 is dispersed or dissolved. The concentration of residual chickling chlorine from 0.1 ppm to about 4 ppm (the concentration of calcium sulfite is about 0.24 ppm to about 10 ppm) is determined by the size of the molded body 17 or the migration agent in relation to the feedwater flow i. And the ratio of binding materials. In addition, the molded body Π slowly dissolves the bonding material according to the water supply to the washing tub, so that the volume of the molded body 17 becomes small. The concentration of rhenium agent required in the above range is effective only when using Japanese tap water. Contained in tap water or used: The paper size of residual free chlorine in water applies to the Chinese national standard (ces) A4 (210X297 mm) -12-A7 B7 V. Description of the invention (9)-When the concentration is different, Contrast the concentration of residual free chlorine contained in the water, and use the necessary concentration of rhenium agent. In the above-mentioned structure, when the water supply valve 2 is opened in each process of the washing process and the washing process, the tap water system passes an internal water pipe 3 from the water supply nozzle 15 to the molded body containing the rhenium agent in the box 16 17. The trowel is sprayed into contact with the molded body 17. At this time, the molded body 17 is not limited to contact in a sprayed state, but may be immersed in water for contact. When the molded body Π comes into contact with tap water, the binding material contained in the molded body 17 is slowly dissolved in water, and the surface of the molded body Π is decomposed. As a result, fine particles of calcium sulfite, which is a virgin agent, are mixed in tap water and released. Tap water mixed with the fine particles is supplied into the washing tub 19 through the water supply port 18. The fine particles of calcium sulfite mixed in the tap water react with the remaining free chlorine in the tap water to react with osmogen. According to this reaction, residual free chlorine is removed. At this time, the concentration of the rhenium agent dispersed or dissolved in the water supplied into the washing tub 19 is effective to remove residual free chlorine of about 0.1 ppm to about 4PP®. Remove residual free chlorine contained in tap water or water in the laundry tub. Therefore, it can prevent the discoloration, discoloration and silk tarnishing of colored clothing caused by the oxidation of residual free chlorine contained in water, or the oxidation defects of surface processing materials of various organic fibers. In addition, according to the water supply to the washing tank, the molded body Π is slowly dissolved, and the volume of the molded skeleton 17 is gradually reduced. Therefore, by confirming the size of the molded body Π in the box 16, the original agent can be easily known. Period of exchange. .. This result can improve the convenience of using laundry detergent and reduce the loss of rhenium agent. This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) ii-Fi. I ------ I ----- (Please read the precautions on the back before filling this page) Order the Ministry of Economic Affairs Printed by the Consumers Cooperative of the Central Bureau of Standards Printed by the Consumers Cooperative of the Central Bureau of Accreditation of the Ministry of Economic Affairs Printed A7 B7 V. Description of the Invention (10) In this example, the water that will be mixed with the desired concentration of rhenium agent Feeds into the laundry tub. Instead of this structure, both the water mixed with the kangen agent and the water not containing the rhenium agent are supplied into the washing tub, and the water can be mixed in the washing tank so that The concentration of the rhenium agent becomes a desired concentration. For example, on FIG. 1, a branch water supply valve having two branch outlets is provided on the outlet side of the water supply valve 2, and water flowing from one of the two outlets is brought into contact with the molded body, and So that the water flowing from the other outlet is directly supplied to the washing tub. Second Embodiment A sectional view of an important part of a washing machine according to another embodiment of the present invention is shown in Fig. 2. In Fig. 2, a transparent container 20 is filled with a high-concentration aqueous solution 21 of sodium carbonate sulfite as a reducing agent. The transparent container 20 is connected to the metering water pump 22 by a water pipe 23, and the water pipe 24 connected to the discharge outlet side of the metering water pump 22 is communicated with a discharge outlet 25 arranged in the dewatering member. The amount of the high-concentration aqueous solution 21 of sodium bisulfite discharged from the quantitative water pump 22 is the concentration of the washing water dispersed or dissolved in the washing tank, and controlled to remove about 0.1 ppm to about 4 ppm of residual free The concentration of chlorine. At this time, the sodium carbonate sulfite concentration is between about 0.25 ppm and about 10 ρρπι. The other structures are the same as those of the first embodiment. In the above configuration, when the water supply valve 2 is opened in each of the washing process and the washing process, the tap water is supplied into the box 16 by spraying from the water supply nozzle 15 圼 through an internal water pipe 3. At this time, the high-concentration aqueous solution 21 of sodium bisulfite in the transparent container 20 is actuated by the fixed-rate water pump 22, and only a predetermined amount is automatically supplied from the outlet 25 to the tap water by the water pipes 23 and 24. The paper size applies the Chinese National Standard (CMS) A4 specification (ZIOXM7 mm) 14 (Please read the notes on the back before filling in this document). AS 'Packing. Order printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Invention Description (11). A predetermined amount of sodium sulfite carbonate and a high-concentration aqueous solution 21 supplied to the tap water are connected to the water supply port 18 and the washing tank 19, and undergo an oxidation migration reaction with residual free chlorine that has an oxidizing effect in the tap water, thereby converting the free chlorine Remove •.... 0 At this time, the amount of the high-concentration aqueous solution 21 of sodium bisulfite discharged by the Dingtong water pump 22 is the concentration when the laundry liquid is dispersed or dissolved in the laundry tub. The amount of residual free chlorine remaining at about 0.1 ppm to about 4 ppm is left, so the residual free chlorine contained in tap water can be efficiently removed. Therefore, it can prevent the discoloration and discoloration of the washed clothes with dye color caused by the oxidation of residual free chlorine contained in tap water, and prevent the yellowing of silk or the oxidation of various organic fiber surface processing materials. Wait. In addition, since the transparent container 20 is a transparent body, the residual amount of the rhenium agent of the liquid 'can be easily seen visually from the outside. Therefore * it is easy to know the timing of replenishing the transparent container with 2G. In this embodiment, it is constituted so that the water mixed with the desired concentration of the original agent can be supplied to the washing tub. Instead of this configuration, another configuration may be adopted in which the reducing agent is directly supplied into the washing tub, and the vatogen is mixed with the water directly supplied into the washing tub in the washing tub *. Furthermore, both the water mixed with the regenerative agent and the water not containing the regenerative agent are supplied into the washing tub at the same time, and the water can be mixed in the washing tub. * The concentration of the reducing agent is set to a desired concentration. The third embodiment is a cross section of an important part of a washing machine according to another embodiment of the present invention (please read the precautions on the back before filling this page) Order 0_ I. 1 | ~~ '=. This paper size is applicable to China National Standard (CNS) A4 Specification (210 X 297 mm) -15- A7 __B7___ 5. Description of Invention (I2)-The figure is shown in Figure 3. In Fig. 3, a box 26 containing the original agent is a powder 41 containing sodium bisulfite as a reducing agent. A motor 27 is provided below the regenerator receiving box 26. The coil spring 29 is rotated by the motor 27 and a transmission mechanism 28, and the sodium carbonate sulfite powder in the rhenium agent storage box 26 is sent only the prescribed amount of powder from the outlet 30 to the tap water in the water supply mechanism. . Lppm〜 约 4ppm of residual free when the amount of sodium sulfite carbonate powder sent out by the rotation of the motor 27 is dispersed in the washing liquid dissolved in the washing tank 19 The amount of chlorine concentration. The other structure 1 is similar to the above example. In the above configuration, when the water supply valve 2 is opened in each of the washing process and the washing process, the tap water is supplied into the box 16 by spraying from the water supply nozzle 15 圼. At this time, according to the driving motor 27 and the wire coil spring 29 being rotated by a transmission mechanism 28, the sodium carbonate sulfite powder in the reducing agent storage box 26 is sent to the feed water from the discharge port 30 only Tap water in the institution. The prescribed amount of sodium carbonate sulphite carbonate powder supplied into the tap water enters the washing tub through a water supply port 18, and the residual free chlorine which has an oxidizing effect in the tap water or the laundry liquid generates a redox reaction. This reaction removes free chlorine. At this time, the amount of the sodium carbonate sulfite powder sent out due to the rotation of the motor 27 is when the powder is dispersed or dissolved in the laundry liquid in the washing tub 19 * so that the amount can be controlled to remove about 0.1 IPPffl ~ The concentration of residual free atmosphere is about 4 ppm, so the residual free chlorine can be efficiently removed. Therefore, it can prevent the oxidization of the residual free atmosphere contained in the tap water, which can cause the color and fading of the washed clothes with color, and prevent the yellowing of silk or the application of the Chinese National Standard (CNS) A4 specifications ( 210X297 mm) .MiFigJLiMEJ6..i :. (Please read the notes on the back before filling this page)
、tT 經濟部中央標準局員工消費合作杜印製 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（13 ) 各種有機類之纖維表面加工材料的氧化等。另外，粉末遨 原劑之殘留量，係可依遷原劑收納盒26之透明部做確認。 另外，於上述之各種實腌例上，構成使在供給於洗衣 槽的水之中混入遷原劑，並將經混入堪原劑之水供入於洗 衣槽之中，但代替該構成，而成為直接將所期望量之遷原 1 · ... ............. ... _ 劑谭Λ.嚴衣槽內的樺成亦可。更且，使經混入有遨原劑之 水與不含遷原劑之水的兩方，一齊被供入於洗衣槽之中， 而成為使該等之水被混合於洗衣槽之中的構成亦可。 如以上依使為了除去含於水中的游離氯之期望量的氯 除去劑，混入供給於洗衣槽的水之中的構成，而使該氯除 去劑與含於水中的殘留游離氯產生反應，該结果使可將殘 留游雛氯除去。更且，依將期望量之氯除去劑混入於洗衣 槽中的洗衣液的構成，使該氯除去劑與含於該洗衣槽中的 殘留游離氯產生反應，該结果可將殘留游離氯除去。更且 ，將混入期望量之氯除去劑的水與不含氯除去劑的水*兩 方一齊供入於洗衣槽中，而使該氯除去劑與含於水中的殘 留游雛氯產生反應，該结果可將殘留游離氯除去。該结果 ，可達到防止由於在洗衣中或乾燥中含於水中之殘留游離 '氯的氧化作用，所造成具有顔色之衣服變色、'褪色，及防 止絲綢的變黃或各種有機類之纖維表面加工材科的氧化等 〇 更且，使用由遷原劑與慢慢的赉解_於水中的結合材料 所構成的成型體，且依構成可控制該成型體之分解速敗的 結合材料，而可供給規定量的還原劑。另外，使用液體或 sluii (請先閲讀背面之注意事項再填寫本頁) -裝., TT printed by the consumer cooperation of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (13) Oxidation of various organic fiber surface processing materials. In addition, the residual amount of the powdered tincture agent can be confirmed in accordance with the transparent portion of the tincture agent storage box 26. In addition, in each of the above-mentioned actual pickling examples, it is constituted that the original agent is mixed in the water supplied to the laundry tank, and the water mixed with the original agent is supplied to the laundry tank, but instead of this configuration, It is possible to directly relocate the desired amount of 1 · ... ............. _ Agent Tan Λ. Hua Cheng in the tight clothes trough is also possible. Furthermore, both the water mixed with the primogenizer and the water not containing the primogenizer are supplied into the washing tub at the same time, so that the water is mixed in the washing tub. Yes. As described above, in order to remove a desired amount of chlorine removing agent contained in water, the chlorine removing agent is mixed with water supplied to the washing tub, and the chlorine removing agent reacts with residual free chlorine contained in water. As a result, residual residual chlorine can be removed. Furthermore, depending on the constitution of the laundry liquid in which a desired amount of chlorine removing agent is mixed in the washing tub, the chlorine removing agent reacts with the residual free chlorine contained in the laundry tub, and as a result, the residual free chlorine can be removed. Furthermore, both the water mixed with the desired amount of the chlorine removing agent and the water containing no chlorine removing agent are supplied into the washing tub together, so that the chlorine removing agent reacts with the residual free chlorine contained in the water. As a result, residual free chlorine can be removed. This result can prevent the discoloration and discoloration of clothes with color due to the oxidation of residual free chlorine in water during washing or drying, and prevent the yellowing of silk or the surface processing of various organic fibers. Oxidation of materials, etc. Furthermore, it is possible to use a molding material composed of a migration agent and a binding material that slowly disintegrates in water, and it can be used as a bonding material that can control the rapid degradation of the molding body. Supply a predetermined amount of reducing agent. In addition, use liquid or sluii (please read the precautions on the back before filling this page) -pack.
，1T =_―>>»1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -17 - 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（14 ) 粉末狀之遷原劑時，依濃度控制裝置，使自動計量規定量 之還原劑並供給之。因此，可使期望之遷原劑量混入於供 給之水中或洗衣槽内之水中。該结果，使不需要如習知將 所有的水供給，一邊加大水壓之負荷，而一邊通過被緻密 充填著的殘留游離氯除去劑。更且，含有還原劑之成型體 *與對水的接觸面積因不需要大的面積，故可將遷原劑做 約10 0%的有效使用。 更且，洗衣過程或清诜過程中至少於其中之任一過程 上，依使混入遷原劑的過程，從洗衣過程、清洗過程及脫 水後之乾燥為止的所有過程上，可用除去一有氧化作用的 殘留游離氯之水進行洗衣處理。 更且*於使用包含遷原劑之成型體的構成上，該成型 體在依其與水的接觸，而從該表面開始分解而使其變小， 該结果，依得知所見之成型體的大小，而可告知使用者遨 原麵之交換時期或補給時期。 更且，還原劑含於洗衣液之濃度，，係依構成為可除去 約0 · lppm〜約4ppm之游離氯的濃度，而可充分的除去自來 水中之殘留游離氯。而且，可使殘留於洗衣液中之過剩遢 原劑對洗衣物幾乎沒有影響。 另外，含於使用水之中的殘留游離氯之濃度不同時， 可控制遨原劑之湄度使可與該所有之殘留游離氯發生反應 ，於該構成上可得與上述相同的效果。 於本發明上*當柞遨原劑者並不限於亞硫酸碳酸納或 亞碲酸鈣，可使用能與游離氯發生還原反應的材料。 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） -18- (请先閱讀背面之注意事項再填寫本頁) •裝. -.、tx A7 B7 五、發明説明（is) 更且，當作氯除去劑雖使用了遷原劑，但並不限於此 ，可使用持有可除去氯之性質的其他材料。 元件標號對照 經濟部中央標準局員工消費合作社印製 1， 101----給水管 26… .收納還原劑之盒 2， 102....給水閥 27··· .馬達 3， 103....內部水管 28... .傳達機構 15.. ..給水噴嘴 29... .線圏彈簧 16.. ..盒 41… .粉末 17.. ..成型體 104.. ..給水路徑切換部 18， 106----給水口 105 * 110....殘留游離氯除去裝置 19. · ..洗衣槽 107.. ..2連接頭給水閥 20.. ..透明容器 108.. ..游離氯除去材料 21.. ..高濃度水溶液 109， 113----儲存盒 22.. ..定量水泵 111.. .·流入口 23.. ..水管 112.. ..流出口 24.. ..出口側水管 114.. ..過濾網盒 -2-5 > —3—Q—.…吐 S 口 ----------裝------訂—^----'"W / - - · (請先閱讀背面之注意事項再填寫本頁) 19 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐）， 1T = _― > > »1 This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -17-Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (14) When the powder is used as the original migration agent, a predetermined amount of reducing agent is automatically measured and supplied according to the concentration control device. Therefore, the desired original dose can be mixed into the water supplied or the water in the washing tub. As a result, it is not necessary to supply all the water as is conventionally known, and it is possible to pass the residual free chlorine removing agent densely packed while increasing the water pressure load. In addition, the molded body containing reducing agent * The contact area with water does not require a large area, so the original agent can be effectively used at about 100%. In addition, during the washing process or the cleaning process, at least one of the processes, depending on the process of mixing the migration agent, can be removed from the washing process, washing process and drying after dehydration. The residual residual chlorine water is washed. Moreover, in the configuration using a molded body containing a migration agent, the molded body is decomposed from the surface to make it smaller according to its contact with water. According to the results, it is known that Size, and can inform the user of the original exchange period or supply period. Furthermore, the concentration of the reducing agent contained in the laundry liquid is such that the concentration of free chlorine of about 0.1 ppm to about 4 ppm can be removed, and the residual free chlorine in the tap water can be sufficiently removed. Moreover, the excess rhenium agent remaining in the laundry liquid can have little effect on the laundry. In addition, when the concentration of the residual free chlorine contained in the used water is different, it is possible to control the maize degree of the rhenium agent so that it can react with all of the residual free chlorine, and the same effect as the above can be obtained in this structure. In the present invention, those who act as rhenium agents are not limited to sodium carbonate sulfite or calcium tellurite, and materials capable of undergoing a reduction reaction with free chlorine may be used. This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) -18- (Please read the precautions on the back before filling this page) • Packing.-., Tx A7 B7 V. Description of the invention (is ) Furthermore, although a virgin agent is used as the chlorine removing agent, it is not limited to this, and other materials having properties capable of removing chlorine can be used. The reference numbers of the components are printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 1, 101 ---- Water supply pipe 26 .... Box for storing reducing agent 2, 102 .... Water supply valve 27 ... Motor. 3, 103 .. .. Internal water pipe 28 .... Transmission mechanism 15 ... Water supply nozzle 29 .... Coil spring 16 ... Box 41 .... Powder 17 ... Molded body 104 ... Water supply path Switching section 18, 106 ---- Water supply port 105 * 110 .... Residual free chlorine removal device 19. · .. Laundry tank 107 .. .. 2 Connector water supply valve 20 ... Transparent container 108 .. .. Free chlorine removal material 21 ... High concentration aqueous solution 109, 113 ---- Storage box 22 ... Quantitative water pump 111 ... · Inlet 23 ... Water pipe 112 ... Outlet 24 .... outlet water pipe 114 .... filter box-2-5 > —3—Q —.... spit out S-port ---------- installation ------ order — ^ ---- '" W /--· (Please read the notes on the back before filling out this page) 19 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)