TW372199B - Catalyst and a process for the preparation of aldehydes in the presence of this catalyst - Google Patents

Catalyst and a process for the preparation of aldehydes in the presence of this catalyst

Info

Publication number
TW372199B
TW372199B TW086108670A TW86108670A TW372199B TW 372199 B TW372199 B TW 372199B TW 086108670 A TW086108670 A TW 086108670A TW 86108670 A TW86108670 A TW 86108670A TW 372199 B TW372199 B TW 372199B
Authority
TW
Taiwan
Prior art keywords
carbon atoms
catalyst
group
aldehydes
hydrogen
Prior art date
Application number
TW086108670A
Other languages
Chinese (zh)
Inventor
Helmut Bahrmann
Dieter Regnat
Peter Lappe
Original Assignee
Celanese Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Gmbh filed Critical Celanese Gmbh
Application granted granted Critical
Publication of TW372199B publication Critical patent/TW372199B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

The present invention relates to a catalyst comprising rhodium and a compound of the formula (I) where R1, R2, R3 are identical or different and are, independently of one another, hydrogen, an alkyl or alkoxy group having from 1 to 4 carbon atoms, an alkenyl group having from 2 to 4 carbon atoms or R1 and R2 together with the carbon atoms connecting them from a ring having 6 carbon atoms, m and n are, independently of one another, 0 or 1 and (m+n) is 1 or 2, and R is a phenyl or naphthyl radical which may be unsubstituted or substituted by an alkyl group having from 1 to 4 carbon atoms or an amino or dialkylamino group having a total of from 2 to 8 carbon atoms. The invention further relates to a process for preparing aldehydes by reaction of an olefinic compound having from 2 to 20 carbon atoms with carbon monoxide and hydrogen in the presence of this catalyst.
TW086108670A 1996-06-24 1997-06-20 Catalyst and a process for the preparation of aldehydes in the presence of this catalyst TW372199B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19625168A DE19625168A1 (en) 1996-06-24 1996-06-24 Re-usable rhodium catalyst containing ligand resistant to oxygen,

Publications (1)

Publication Number Publication Date
TW372199B true TW372199B (en) 1999-10-21

Family

ID=7797809

Family Applications (1)

Application Number Title Priority Date Filing Date
TW086108670A TW372199B (en) 1996-06-24 1997-06-20 Catalyst and a process for the preparation of aldehydes in the presence of this catalyst

Country Status (12)

Country Link
EP (1) EP0909218A1 (en)
JP (1) JP2001502594A (en)
KR (1) KR20000022119A (en)
AU (1) AU3340197A (en)
BR (1) BR9709955A (en)
CA (1) CA2258280A1 (en)
DE (2) DE19625168A1 (en)
ID (1) ID17186A (en)
PL (1) PL330789A1 (en)
TW (1) TW372199B (en)
WO (1) WO1997049490A1 (en)
ZA (1) ZA975540B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6573409B1 (en) 1999-07-02 2003-06-03 The Nutrasweet Company Process for the preparation of 3,3-dimethylbutanal
EP1532094A1 (en) * 2002-08-31 2005-05-25 Oxeno Olefinchemie GmbH Method for the hydroformylation of olefinically unsaturated compounds, especially olefins, in the presence of cyclic carbonic acid esters

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4960949A (en) * 1988-12-22 1990-10-02 Eastman Kodak Company Low pressure rhodium catalyzed hydroformylation of olefins
DE4242723A1 (en) * 1992-12-17 1994-06-23 Hoechst Ag Process for the preparation of aldehydes
DE4447067A1 (en) * 1994-12-29 1996-07-04 Hoechst Ag Process for the preparation of aldehydes

Also Published As

Publication number Publication date
KR20000022119A (en) 2000-04-25
PL330789A1 (en) 1999-06-07
DE19625168A1 (en) 1998-01-08
ID17186A (en) 1997-12-11
DE19654908A1 (en) 1998-01-29
EP0909218A1 (en) 1999-04-21
WO1997049490A1 (en) 1997-12-31
AU3340197A (en) 1998-01-14
BR9709955A (en) 1999-08-10
CA2258280A1 (en) 1997-12-31
ZA975540B (en) 1997-12-24
JP2001502594A (en) 2001-02-27

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