TW358101B - Gas phase anionic polymerization of conjugated dienes and vinyl-substituted aromatic compounds - Google Patents

Gas phase anionic polymerization of conjugated dienes and vinyl-substituted aromatic compounds

Info

Publication number
TW358101B
TW358101B TW086118431A TW86118431A TW358101B TW 358101 B TW358101 B TW 358101B TW 086118431 A TW086118431 A TW 086118431A TW 86118431 A TW86118431 A TW 86118431A TW 358101 B TW358101 B TW 358101B
Authority
TW
Taiwan
Prior art keywords
vinyl
gas phase
substituted aromatic
mixtures
group
Prior art date
Application number
TW086118431A
Other languages
English (en)
Inventor
Monika Bradly
Kevin Joseph Cann
David Joseph Dovedytis
Original Assignee
Union Carbide Chem Plastic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic
Application granted granted Critical
Publication of TW358101B publication Critical patent/TW358101B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/913—Vapor phase polymerization in absence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
TW086118431A 1996-12-06 1998-03-18 Gas phase anionic polymerization of conjugated dienes and vinyl-substituted aromatic compounds TW358101B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/761,797 US5728782A (en) 1996-12-06 1996-12-06 Gas phase anionic polymerization of dienes and vinyl-substituted aromatic compounds

Publications (1)

Publication Number Publication Date
TW358101B true TW358101B (en) 1999-05-11

Family

ID=25063292

Family Applications (1)

Application Number Title Priority Date Filing Date
TW086118431A TW358101B (en) 1996-12-06 1998-03-18 Gas phase anionic polymerization of conjugated dienes and vinyl-substituted aromatic compounds

Country Status (3)

Country Link
US (1) US5728782A (zh)
TW (1) TW358101B (zh)
ZA (1) ZA9710973B (zh)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000001516A (ja) * 1998-06-15 2000-01-07 Nippon Zeon Co Ltd 樹脂改質剤、それを含む樹脂組成物、およびポリ芳香族ビニル系樹脂組成物
JP4085476B2 (ja) * 1998-06-15 2008-05-14 日本ゼオン株式会社 タイヤ用共役ジエン系ゴム組成物およびタイヤ
US6881795B2 (en) * 2001-03-28 2005-04-19 Firestone Polymers, Llc CO2 terminated rubber for plastics
US6987152B1 (en) 2005-01-11 2006-01-17 Univation Technologies, Llc Feed purification at ambient temperature
US7790816B2 (en) * 2006-08-04 2010-09-07 Univation Technologies, Llc Method of maintaining heat transfer capacity in a polymerization reaction system
US8716409B2 (en) * 2006-12-29 2014-05-06 Firestone Polymers, Llc Carboxylate terminated polymers and their use in impact-modified plastics
MX2009013178A (es) * 2007-06-07 2010-02-17 Albemarle Corp Aductos, aductos y oligomeros o aductos, oligomeros y polimeros de bajo peso molecular asi como su preparacion.
TW200936564A (en) * 2007-11-15 2009-09-01 Univation Tech Llc Methods for the removal of impurities from polymerization feed streams
US8993684B2 (en) * 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
US8642821B2 (en) * 2008-12-02 2014-02-04 Albemarle Corporation Bromination of telomer mixtures derived from toluene and styrene
WO2010065462A2 (en) * 2008-12-02 2010-06-10 Albemarle Corporation Toluene and styrene derived telomer distributions and brominated flame retardants produced therefrom
JO3423B1 (ar) * 2008-12-02 2019-10-20 Albemarle Corp مؤخرات لهب معالجة بالبروم و مواد مشتقه منها
EP2361269A1 (en) * 2008-12-02 2011-08-31 Albemarle Corporation Branched and star-branched styrene polymers, telomers, and adducts, their synthesis, their bromination, and their uses
WO2010127087A1 (en) 2009-05-01 2010-11-04 Albemarle Corporation Pelletized low molecular weight brominated aromatic polymer compositions
JO3059B1 (ar) 2009-05-01 2017-03-15 Albemarle Corp معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض
ITMI20121495A1 (it) * 2012-09-07 2014-03-08 Versalis Spa Procedimento per la preparazione di polimeri dienici o di copolimeri statistici vinilarene-diene

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2514203A (en) * 1947-08-08 1950-07-04 Firestone Tire & Rubber Co Vapor phase polymerization of butadiene with sodium
US2495137A (en) * 1948-05-05 1950-01-17 Firestone Tire & Rubber Co Polymerization of butadiene
US3157604A (en) * 1960-10-24 1964-11-17 Phillips Petroleum Co Polymerization initiators
US3784637A (en) * 1969-01-30 1974-01-08 Phillips Petroleum Co Multifunctional polymerization initiators from vinylsilanes or vinylphosphines and organomonolithium compounds
US3624057A (en) * 1969-01-30 1971-11-30 Phillips Petroleum Co Polymerization with multifunctional iniators prepared from vinylsilanes or vinylphosphines and organomonolithium compounds
US3644322A (en) * 1969-02-03 1972-02-22 Phillips Petroleum Co Polymerization of conjugated dienes and monovinyl aromatic compounds with multifunctional polymerization initiators
US3652516A (en) * 1969-02-10 1972-03-28 Phillips Petroleum Co Polymerization of conjugated dienes or monovinyl aromatic monomers with multifunctional initiators from diisopropenylbenzene
US3716495A (en) * 1970-09-02 1973-02-13 Phillips Petroleum Co Polymerization initiator composition and use thereof
US3674760A (en) * 1970-09-02 1972-07-04 Firestone Tire & Rubber Co Method of producing butadiene-styrene copolymer
US3776964A (en) * 1971-03-18 1973-12-04 First National City Bank Organolithium polymerization initiators
US3723575A (en) * 1971-04-14 1973-03-27 Firestone Tire & Rubber Co Method of producing graft polymers
US3734973A (en) * 1971-11-04 1973-05-22 Phillips Petroleum Co Multifunctional polymerization initiators from diisopropenylbenzene
US4130703A (en) * 1975-06-14 1978-12-19 Agence Nationale De Valorisation De La Recherche (Anvar) Heterogeneous anionic polymerization process
US4230841A (en) * 1979-01-31 1980-10-28 The Goodyear Tire & Rubber Company Process for medium vinyl polybutadiene
US4497748A (en) * 1981-07-13 1985-02-05 The General Tire & Rubber Company Preparation of lithium initiator for the preparation of star polymers
US4409368A (en) * 1981-07-13 1983-10-11 The General Tire & Rubber Company Preparation of star polymers
US4588790A (en) * 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) * 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4520123A (en) * 1984-07-02 1985-05-28 The Firestone Tire & Rubber Company Catalyst system and process for polymerizing conjugated dienes
US4696986A (en) * 1986-08-12 1987-09-29 The Goodyear Tire & Rubber Company Modifier for lithium catalysts
ZA876594B (en) * 1986-09-17 1988-03-14 The Goodyear Tire & Rubber Company Triblock polymer and synthesis technique
ZA876712B (en) * 1986-09-22 1988-03-16 The Goodyear Tire & Rubber Company Star polymer
US4730025A (en) * 1986-09-22 1988-03-08 The Goodyear Tire & Rubber Company Hexachlorocyclopentadiene end group polymers
US4845165A (en) * 1987-03-13 1989-07-04 The Goodyear Tire & Rubber Company Anionic diene polymerization process with branching
JPH0681392B2 (ja) * 1988-12-28 1994-10-12 三菱電線工業株式会社 ケーブル端末削成工具
US4994534A (en) * 1989-09-28 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Process for producing sticky polymers
US5304588A (en) * 1989-09-28 1994-04-19 Union Carbide Chemicals & Plastics Technology Corporation Core-shell resin particle
US5231152A (en) * 1990-12-18 1993-07-27 Bridgestone Corporation Continuous process for preparing copolymers of conjugated dienes and aromatic vinyl compounds
US5112929A (en) * 1991-04-05 1992-05-12 Bridgestone Corporation Oxolanyl cyclic acetals as anionic polymerization modifiers
US5210144A (en) * 1991-12-20 1993-05-11 Bridgestone Corporation Diene polymers having reduced hysteresis and improved raw viscosity incorporating primary partial coupling and fused-ring polynuclear aromatic terminators
US5231153A (en) * 1992-04-06 1993-07-27 The Goodyear Tire & Rubber Company Anionic polymerization of conjugated dienes modified with alkyltetrahydrofurfuryl ethers
US5272220A (en) * 1992-09-14 1993-12-21 The Goodyear Tire & Rubber Company Process for preparing styrene-isoprene-butadiene rubber
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
DE4333491A1 (de) * 1993-10-01 1995-04-06 Studiengesellschaft Kohle Mbh Verfahren zur Herstellung von Methylencyclopropan
DE4333838A1 (de) * 1993-10-05 1995-04-06 Hoechst Ag 3,4-Difluorbenzole und ihre Verwendung in Flüssigkristallmischungen
US5416168A (en) * 1994-03-31 1995-05-16 Shell Oil Company Protected functional initiators for making terminally functionalized polymers
US5464914A (en) * 1994-06-29 1995-11-07 The Dow Chemical Company Preparation of a low polydisperse polymer
US5496940A (en) * 1995-02-01 1996-03-05 Bridgestone Corporation Alkyllithium compounds containing cyclic amines and their use in polymerization

Also Published As

Publication number Publication date
ZA9710973B (en) 1998-06-15
US5728782A (en) 1998-03-17

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