TW334452B - Process for hydrogenation of conjugated diene polymers and catalyst compositions suitable for use - Google Patents
Process for hydrogenation of conjugated diene polymers and catalyst compositions suitable for useInfo
- Publication number
- TW334452B TW334452B TW086104872A TW86104872A TW334452B TW 334452 B TW334452 B TW 334452B TW 086104872 A TW086104872 A TW 086104872A TW 86104872 A TW86104872 A TW 86104872A TW 334452 B TW334452 B TW 334452B
- Authority
- TW
- Taiwan
- Prior art keywords
- phenyl
- hydrogenation
- alkalimetal
- lower alkyl
- catalyst compositions
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title abstract 6
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 150000001993 dienes Chemical class 0.000 title abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 4
- 229910052783 alkali metal Inorganic materials 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical class 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 3
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910000102 alkali metal hydride Inorganic materials 0.000 abstract 1
- 150000008046 alkali metal hydrides Chemical class 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000002619 bicyclic group Chemical group 0.000 abstract 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 abstract 1
- 125000002950 monocyclic group Chemical group 0.000 abstract 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 1
- 125000002071 phenylalkoxy group Chemical group 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
- B01J31/0208—Ketones or ketals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0204—Ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/121—Metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96302600 | 1996-04-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW334452B true TW334452B (en) | 1998-06-21 |
Family
ID=8224884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW086104872A TW334452B (en) | 1996-04-12 | 1997-04-15 | Process for hydrogenation of conjugated diene polymers and catalyst compositions suitable for use |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5814709A (enExample) |
| EP (1) | EP0801079B1 (enExample) |
| JP (1) | JPH1036421A (enExample) |
| DE (1) | DE69700309T2 (enExample) |
| ES (1) | ES2134050T3 (enExample) |
| TW (1) | TW334452B (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10101727A (ja) * | 1996-09-24 | 1998-04-21 | Shell Internatl Res Maatschappij Bv | オレフィン又はポリマーを水素化するための触媒及び方法 |
| KR100267080B1 (ko) * | 1998-08-03 | 2000-10-02 | 박찬구 | 공액디엔 중합체의 수소화 방법 |
| US6521694B2 (en) | 1998-08-11 | 2003-02-18 | Dsm N.V. | Process for hydrogenation of carbon-carbon double bonds of an unsaturated polymer |
| NL1009841C2 (nl) * | 1998-08-11 | 2000-02-15 | Dsm Nv | Werkwijze voor de hydrogenering van koolstof-koolstof dubbele bindingen van een onverzadigd polymeer. |
| KR100287961B1 (ko) * | 1998-09-30 | 2001-05-02 | 박찬구 | 공역디엔을 포함하는 고분자의 수소첨가 방법 |
| US6291386B1 (en) * | 1999-05-25 | 2001-09-18 | Equistar Chemicals, Lp | Process for the in-situ preparation of single-site transition metal catalysts and polymerization process |
| KR100348761B1 (ko) * | 1999-11-26 | 2002-08-13 | 금호석유화학 주식회사 | 공액디엔을 포함하는 중합체의 선택적 수소화 방법 |
| US6881795B2 (en) | 2001-03-28 | 2005-04-19 | Firestone Polymers, Llc | CO2 terminated rubber for plastics |
| ITMI20012267A1 (it) * | 2001-10-29 | 2003-04-29 | Chemi Spa | Preparazione ed uso di un catalizzatore eterogeneo per l'idrogenerazione di un doppio legame di un composto carbonilico b-insaturo |
| ITMI20022052A1 (it) * | 2002-09-27 | 2004-03-28 | Polimeri Europa Spa | Composti metallocenici stabilizzati di metalli di transizione del gruppo 4 e processo per la loro preparazione. |
| ITMI20022054A1 (it) * | 2002-09-27 | 2004-03-28 | Polimeri Europa Spa | Composizione catalitica per la (co)polimerizzazione delle alfa-olefine. |
| US7166679B2 (en) * | 2003-09-24 | 2007-01-23 | Kraton Polymers Llc | Conjugated diene polymers and copolymer blocks having high vinyl content prepared using mixed microstructure control agents and process for preparing same |
| ITMI20050860A1 (it) * | 2005-05-13 | 2006-11-14 | Polimeri Europa Spa | Procedimento per la idrogenazione selettiva di copolimeri stirene-butadiene |
| US8716409B2 (en) * | 2006-12-29 | 2014-05-06 | Firestone Polymers, Llc | Carboxylate terminated polymers and their use in impact-modified plastics |
| EP2204094A1 (en) | 2008-12-29 | 2010-07-07 | Bayer CropScience AG | Method for improved utilization of the production potential of transgenic plants Introduction |
| DK2272588T3 (da) * | 2009-06-22 | 2013-08-05 | Dynasol Elastomeros Sa | Katalysator til hydrogenering af umættede forbindelser |
| JP2012082186A (ja) | 2010-09-15 | 2012-04-26 | Bayer Cropscience Ag | 殺虫性アリールピロリジン類 |
| BR112013020399A2 (pt) | 2011-02-18 | 2016-10-25 | Kraton Polymers Us Llc | composição polimérica curável, cabo, selante, e, método de enchimento de um cabo de fibra óptica |
| TR201802544T4 (tr) | 2011-06-06 | 2018-03-21 | Bayer Cropscience Nv | Önceden seçilmiş bir bölgede bir bitki genomunu modifiye için yöntemler ve araçlar. |
| US9265252B2 (en) | 2011-08-10 | 2016-02-23 | Bayer Intellectual Property Gmbh | Active compound combinations comprising specific tetramic acid derivatives |
| EP2742059A1 (en) | 2011-08-12 | 2014-06-18 | Bayer CropScience NV | Guard cell-specific expression of transgenes in cotton |
| EP2606732A1 (en) | 2011-12-19 | 2013-06-26 | Bayer CropScience AG | Use of an anthranilic diamide derivatives with heteroaromatic and heterocyclic substituents in combination with a biological control agent |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE737574A (enExample) * | 1968-09-05 | 1970-02-02 | ||
| US3766300A (en) * | 1971-04-05 | 1973-10-16 | Shell Oil Co | Process for hydrogenation of polar copolymers and complexed copolymercompositions |
| US3898208A (en) * | 1971-06-21 | 1975-08-05 | Dow Chemical Co | Hydrogenation of oil-insoluble diene polymers |
| US4501857A (en) * | 1983-01-20 | 1985-02-26 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for hydrogenation of polymer |
| JPS60220147A (ja) * | 1984-04-18 | 1985-11-02 | Asahi Chem Ind Co Ltd | オレフイン水添触媒および該触媒を用いた重合体の水添方法 |
| JP2609534B2 (ja) * | 1988-05-17 | 1997-05-14 | 旭化成工業株式会社 | オレフィン性不飽和ポリマーの水添方法 |
| JP2969771B2 (ja) * | 1989-12-22 | 1999-11-02 | ジェイエスアール株式会社 | オレフィン性不飽和重合体の水素添加方法および水素添加用触媒組成物 |
| US5039755A (en) * | 1990-05-29 | 1991-08-13 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers |
| US5141997A (en) * | 1990-08-15 | 1992-08-25 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers |
| US5206307A (en) * | 1991-09-09 | 1993-04-27 | Shell Oil Company | Process for selective hydrogenation of conjugated diolefin polymers |
| US5270274A (en) * | 1991-11-28 | 1993-12-14 | Japan Synthetic Rubber Co., Ltd. | Catalyst composition for hydrogenating olefinically unsaturated polymers |
| ES2053363B1 (es) * | 1991-12-05 | 1995-02-16 | Repsol Quimica Sa | Procedimiento de hidrogenacion de olefinas. |
| US5173537A (en) * | 1991-12-20 | 1992-12-22 | Shell Oil Company | Selective hydrogenation of conjugated diolefin poylmers |
| WO1995025136A1 (en) * | 1992-03-05 | 1995-09-21 | Exxon Research And Engineering Co. | Sulfonated unhydrogenated copolymers of styrene and butadiene |
| ES2050620B1 (es) * | 1992-11-03 | 1994-12-16 | Repsol Quimica Sa | Procedimiento de hidrogenacion en disolucion de los dobles enlaces de polimeros de dienos conjugados y copolimero bloque hidrogenado producido. |
| US5541272A (en) * | 1994-06-03 | 1996-07-30 | Phillips Petroleum Company | High activity ethylene selective metallocenes |
-
1997
- 1997-04-09 US US08/831,631 patent/US5814709A/en not_active Expired - Lifetime
- 1997-04-10 JP JP9092394A patent/JPH1036421A/ja not_active Withdrawn
- 1997-04-11 ES ES97201094T patent/ES2134050T3/es not_active Expired - Lifetime
- 1997-04-11 EP EP97201094A patent/EP0801079B1/en not_active Expired - Lifetime
- 1997-04-11 DE DE69700309T patent/DE69700309T2/de not_active Expired - Fee Related
- 1997-04-15 TW TW086104872A patent/TW334452B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| JPH1036421A (ja) | 1998-02-10 |
| ES2134050T3 (es) | 1999-09-16 |
| US5814709A (en) | 1998-09-29 |
| EP0801079B1 (en) | 1999-07-07 |
| DE69700309D1 (de) | 1999-08-12 |
| DE69700309T2 (de) | 2000-01-27 |
| EP0801079A1 (en) | 1997-10-15 |
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