312703 Β7 經濟部中央標準局員工消費合作社印製 五、發明説明（/) 本發明是關於一種陶瓷金鋼砂的磨料，及其製備方法 與由該磨料所製成的工具。 除了溶化金鋼砂（fused corundum)以外，陶瓷金鋼 砂的使用情形已越來越多，原因在於陶瓷金鋼砂具有多結 晶結構(polycrystal 1 ine structure )而顯現出很好的 磨耗性質，同時在特殊材料（如高合金不鏽鋼）的機器製 造(machining)上可以大幅延長工具的使用赛命。丨容駿-凝膠法是一種廣泛用來製造此種陶瓷金鋼砂磨料的方法， 像將一種具有含水氣化錦（通常為氣化錦水合物）的溶膠 藉由添加酸而轉變為凝膠，經乾燥過後再將其段燒、粉碎 然後燒結。尤其在這十年來已有許多利用特殊製程（EP-B263810)或藉添加材料以改進此種磨料性質的各種嘗試 。添加材料的方式可根據其於燒結過程中的作用一方面分 類為核生成劑(M. Kuraagaiand G.L. Messing: Con-tro1 led Transformation and Sintering of a Boehmite Sol-Gel by «-Alumina Seeding, J. Am. Ceram. Soe. 68⑼，500-505 (1987))或另一方面分類為改質性成份 。後者會以不同的方式影響燒結過程以及最終産物的結構 與性質。使用的改質性成份如錢、給、銘、鎳、鋅（EP-B0024099)、參乙(EP-B 228856)、鐵的氣化物（EP-B 20 0487)、稀土金屬(EP-B 293164)、鋰(ΕΡ-Δ 441640) 。這些添加物中有的固然會對磨擦的性質有很重要的改進 ，但其價值因廣泛分散而有降低品質的作用。 除了諸如硬度、勒性、對微細裂痕擴大現象的抗性或 〜3〜 、-='5 (請先閱讀背面之注意事項再填寫本頁)312703 Β7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (/) The present invention relates to an abrasive for ceramic gold steel grit, and its preparation method and tools made from the abrasive. In addition to fused corundum, the use of ceramic gold steel sand has become more and more, because the ceramic gold steel sand has a polycrystalline structure (polycrystal 1 ine structure) and shows good wear properties, while The machining of special materials (such as high alloy stainless steel) can greatly extend the life of the tool.丨 Rongjun-Gel method is a method widely used to make this kind of ceramic diamond abrasives, like transforming a sol with water-containing gasified bromide (usually gasified bromide hydrate) by adding acid into condensate The glue is dried, crushed and then sintered. Especially in the past ten years, there have been many attempts to use special processes (EP-B263810) or by adding materials to improve the properties of such abrasives. The method of adding materials can be classified as a nuclear generating agent (M. Kuraagaiand GL Messing: Con-tro1 led Transformation and Sintering of a Boehmite Sol-Gel by «-Alumina Seeding, J. Am. Ceram. Soe. 68⑼, 500-505 (1987)) or on the other hand is classified as a modifying ingredient. The latter affects the sintering process and the structure and properties of the final product in different ways. Modified ingredients used such as money, to, Ming, nickel, zinc (EP-B0024099), Shen B (EP-B 228856), iron vapors (EP-B 20 0487), rare earth metals (EP-B 293164 ), Lithium (ΕΡ-Δ 441640). Of course, some of these additives will have an important improvement in the properties of friction, but their value has a role in reducing quality due to widespread dispersion. In addition to such things as hardness, stiffness, resistance to micro crack expansion phenomena or ~ 3 ~,-= '5 (please read the precautions on the back before filling this page)
本紙張尺度消)丨〗中阀®家標準（（，NS ) Λ4规格（21()Χ29?公釐） 312703 經濟部中央標率局員工消費合作社印製 A7 B7五、發明説明（丄） 傳統上用來指明金綱砂磨料的微磨耗等物理材料性質之外 ，工具使用赛命的延長也和一粒徑範圍内這雙物性值的高 度恆定性一樣是很重要的。而本發明即是基於此一認識而 開始進行的。 本發明的目的在於製備一種除具有一般性質特徵（尤 其是硬度）之外在同一枇顆粒内部僅有小幅度性質改變的 金鋼砂磨料。出人意料的是此種磨料可透過添加錫而達成 〇 因此主要含有陶瓷金鋼砂的本發明磨料像以含有錫為 待徵，其含量以氧化錫來計算時為燒結終産物的〇.〇1重 量％以上，以0.1重量％以上為較佳，但不得超過5 重量％，而以不超過1重量％為較佳。 目前已知添加錄可以改善硬度和顆粒的細度，經進一· 步證實發現，如果磨料中也含有鋰時則硬度和産品的均句 度（uniformity)可進一步改善，最後還可以用其他改質 性的成份，如銘、az、給、鐵、及/或稀土金屬。 以下實施例所製成的産物表面經破碎、触刻磨光後檢 測其光學性質顯示出一種與習知産品容易區別的結構。在 大粒子之間有的呈oc-氣化錦所特有的梯形結構（terrace structure) ( Petzold / Ulbricht - Alumina andalum ina materials, p.83，圖7.14 ),小粒子有累積的現 象，平均大小比例為至少3:1,通常大於5:1。臨近較大 粒子之間大多（在大部份情況下幾乎完金）被一靥較小粒 子呵分開。這些較小粒子層會形成連續的基質，而將較大 —一 木紙屮纠阐家標率（CNS ) Λ4说格（2丨()X297公梦―） (請先閲讀背面之注意事項再填寫本頁) 衣· 訂 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（3 ) 粒子嵌入。介於大粒子之間三角形空隙裡的小粒子的累積 現象至少在彼此之間像透過分支相互連接而涵蓋一大範圍 。與粒子外觀不同有相當關偽的是不同的組成，其中在形 態上可區別的粒子（晶體）裡含有特高濃度或低濃度的改 質性成份，而在f虫刻磨光的部份顯得相當突出。本文中粒 子是指在独刻磨光部份因明顯的界線而可彼此區別的成形 單元，亦指晶體而言。本發明磨料除具高硬度的性質以外 ，對高度熱負荷與機械負荷均具高抗性，故若用在撒有本 發明磨料的磨帶時除了大幅提高每單位時間可被磨掉的材 料量之外尚能大帽延長工具的壽命。 本發明磨料可在研磨性噴砂或磨光（abrasive blasting or lapping)方面用在基材(substrate)上作 為黏合研磨工具(bonded grinding tools)白勺一成份或 用作鬆散磨料。本發明磨料在所有應用領域上可和其他種 類的磨料以定性和定量的組合來使用，而與高硬度的研磨 性顆粒如硝化砂、正方氮化硼或鑛石混合時更具優點。此 夕卜，本發明的磨料也可以用作基質而將一種或一種以上性 質不同的磨料併入其中。後者鍤箸在本發明磨料的製備 過程中將其他磨料混入一中間物（以溶膠或凝駿為較佳） 裡而達成。 在此製程中須確保該含錫材料與其他起始材料緊密混 合並微細分散在這些起始材料裡。若製備過程是從經過加 歷與燒結的粉狀起始材料開始進行時則該含錫材料最好也 以粉狀形態加入。此含錫材料也可以呈液體狀態並混入該 本紙张又# MJfl中阀阀家標华（C’NS ) Λ4^格（210X297公释） (請先閱讀背面之注意事項再填寫本頁) 訂 312703 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（） . 待燒結的材料裡或噴在該待燒結的材料上。若使用溶顧-凝膠法且該含錫材料像在凝膠生成之前加入起始材料裡使 即將生成凝膠的分散液（溶膠）裡已含有該含錫材料時則 可達到相當緊密混合的效果。此含錫材料可呈固態、微細 分離的粉碎狀態或呈溶液狀。目前已經確定，與無錫法相 較之下本發明方法所製成的乾燥凝膠已具有一種能夠耐高 機械負荷的性質。這不僅表示本法有相當可觀的改質作用 ，同時在産量以及粉碎粒子的形狀方面也改善了乾燥凝膠 的粉碎效果。 以粉狀Sn〇2狀態加入起始材料或中間物理的氧化錫 已經過證實是本發明中一種特別有用的化合物，不過也可 以用其他的含錫材料，如錫鹽。 此溶顧以含有極微細分離並視需要經過粉碎的7 -氣 化鋁較為有利。 若進一步添加鋰（宜以鋰鹽的水溶液狀態混入任一階 段的中間物裡）則可達到特佳結果，鋰化合物（宜為鋰鹽 )最好已以溶解狀態出現在溶膠裡，而且溶膠裡若還含有 其他改質性的成份（尤其是先前所述者）則最好也以微細 分離的固體狀態或密解狀態存在於該溶膠裡，而這些成份 也可以加入另一中間物裡。其較佳含量範圍（以氣化物計 )為-· m 0.1-196 金乙 0.1-1% 娌 0.01-596，以1.5-3%為較佳 6 本紙張尺成適.if;中闽阐家標準（CNS ) Λ4現格（2丨0'〆W7公釐） ---------1' 裝------訂------I.V1--- (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明（） 齡 0.01-0.4% 稀土金屬 0.1-2¾ 除了以上所述之外，溶膠-凝駿法的製程步驟並無進 一步詳細說明的必要，因為這些步驟可利用現存的先前技 術尤其是前述專利文獻裡所述的步驟來進行。 使用的起始材料以一種氫氣化錦較有利，而且宜為水 錦石（boehmite)型白勺氧<匕iS氮氧彳匕年勿(aluminum oxide hydroxide),例如位於 Brunsbiitte 1 的Condea—Chemi e公 司所製造的各種Disperal氧化銘經證實都是很有用的材料 。在添加了去離子水和硝酸之後得到一種懸浮液，此懸浮 液可視需要經過離心以去除較粗的組成份。最好能添加核 生成劑(nucleus former)或-χ —氧彳匕, ί旦並多庐一"定要 使用這種物質。7 -氣化錦可先含在硝酸的水性分散液裡 ，此分散液可依同樣方式加以離心。將一定量的此等分散 液與任何改質性成份（宜呈水溶液或水性分散液狀態）混 合以得到一種懸浮液，此懸浮液利用水溶液裡的硝酸及/ 或其鹽類轉化為凝然後再將此凝膠乾燥並锻燒。把該 經過乾燥或段燒的中間物加以粉碎並視需要加以分類。接 箸將該锻燒過的中間物燒結，最後才把得到的磨料飾滴並 混合而製成一枇批具有均句粒徑的頼粒。 我們發現使用鋰並選擇性地使用前述成份但不用錫時 也能夠達到很好的效果，尤其是添加了 2重量％埋（ 在燒結産物中呈氧化物狀態）時尤然。雖然添加趣的技術 已屬已知（ΕΡ 0441640),該氣化物含蚩在燒結産物裡最 7 ·—^— (請先閲讀背面之注意事項再填寫本頁) 本紙依尺;^用中网闽家標苹（（^$)八4規格（210>(297公趙） 經濟部中央標準局員工消費合作社印裝 312703 A7 B7 五、發明说明（） .多只佔1.5重量％，而且該文獻指出ί吏用高於該數值的 量時會使磨料品質變差。但本發明卻得到相反的結果，我 們發現不論錫的添加量如何•鋰含量（以氣化物計）在燒 結産物中宜佔1*5重量％以上，不過同時使用鋰和錫時 更好。 ΜΆ=ζ ί}辱 2〇〇〇kg 去離子水(demineralized water , 50 ° C ) 、28 1 HM〇3溶液（濃度53%).以及 1000kg Disperal混 合在一起産生一懸浮液，經離心之後得至ff第一前驅物,其 固體含量為30重量％左右。 1000kg 去離子水（50°C) . 27kg v -A1s〇3 (由 Bruns blittel的CondeaF^f提供的"Puralox 400”）以及5 1 HN〇3溶液（濃度53%)經混合離心後形成第二前驅物(其 固體含量為2.5重量％)。 將1000kg第一前驅物、500kg第二前驅物、lkg氧化錫 (呈水性懸浮液狀態）、3.3kg硝酸_六水合物（於水溶 液中）、0.2ks硝酸銘六水合物（於水溶液中）以及lkg氣 化多乙混合可得到第三前驅物。 第四前驅物.含有75kg去離子水和48kg硝酸錦九水合物 Ο 將1505.5kg第三前驅物與123kg第四前驅物混合形成 凝膠，再於130° C下乾燥20分鐘。 令該乾燥後的物質粉碎然後在850° C的溫度下锻燒15 分鐽。接箸在一管狀的迴轉爐中以145CT C的溫度燒結12 8 一一 本纸依反m丨，网阄家標牟（CNS ) Λ4规格（2丨0X297公釐） (請先閱讀背面之注意事項再填寫本頁) 装. 訂 經濟部中央標準局員工消費合作社印褽 A7 B7五、發明説明（） 分鐘再經飾滿分類。依此方式所得到的磨料顆粒含錫童（ 呈氣化錫狀態）為0.36重量％,其平均硬度為19.1 GPa。 審例二 重覆實例一的步驟，但在第三前驅物中氧化錫的用量 改為5.5kg。結果製成的顆粒平均硬度為18.1 GPa，密度 比實例一的産物高。 宵例三 重覆實例一的步驟，但額外使用25.4kg硝酸鋰。結果 製成的顆粒鋰含量（呈氣化鋰狀態）為2%,其平均Knoop 硬度為22.22 GPa〇 官例四----h 使用同於實例三的方法和材料組成，但改變硝酸鋰的 (請先閱讀背面之注意事項再填寫本頁) 装. 比例使最終産物中的氣化鋰含量為： 0· 1重量％ (實例四） 0.2重量％ (實例五） 0.3重量％ (實例六） 0.4車最9^ (實例七） 0·5重量％ (實例八） 1.0重量％ (實例九） 3.0重童％ (實例十） -In 、τ 本文所述之硬度（Knoop法）是以Shimadzu所製造 型號為HMV-2000的測試裝置測得的。 平均Knoop硬度 [GPa] 實例四 18.9 〜 9 〜 本紙張尺屮阒國家標準（C’NS ) Λ4規格（210X 297公聲） A7 B7 五、發明説明（） 經濟部中央標準局員工消費合作社印製The size of this paper) 丨〗 Zhong valve ® home standard ((, NS) Λ4 specifications (21 () Χ29? Mm) 312703 A7 B7 printed by the Employee Consumer Cooperative of the Central Standardization Bureau of the Ministry of Economic Affairs V. Description of invention (丄) Tradition In addition to the physical material properties such as the micro-abrasion of the gold sand abrasive, the life extension of the tool is also as important as the high stability of these two physical property values within a particle size range. The present invention is based on This knowledge was started. The purpose of the present invention is to prepare a gold-steel grit abrasive with only a small change in properties within the same lobe particles in addition to the general property characteristics (especially the hardness). Surprisingly, this kind of abrasive It can be achieved by adding tin. Therefore, the abrasive image of the present invention mainly containing ceramic gold steel grit contains tin as a sign, and its content is calculated as tin oxide to be 0.01% by weight or more of the final sintered product, with 0.1 weight % Is better, but not more than 5% by weight, and preferably not more than 1% by weight. It is currently known that addition recording can improve the hardness and fineness of particles, which has been confirmed by further confirmation. If the abrasive also contains lithium, the hardness and the uniformity of the product can be further improved, and finally other modifying ingredients such as Ming, az, feed, iron, and / or rare earth metals can be used. The surface of the product made by the example is broken, touched and polished, and its optical properties are tested to show a structure that is easily distinguishable from conventional products. Some large particles have a trapezoidal structure unique to oc-gasification bromide ( terrace structure) (Petzold / Ulbricht-Alumina andalum ina materials, p.83, Figure 7.14), small particles have a cumulative phenomenon, the average size ratio is at least 3: 1, usually greater than 5: 1. Most of the adjacent large particles (Almost finished gold in most cases) separated by a small particle. These smaller particle layers will form a continuous matrix, and the larger-a wooden paper correction standard rate (CNS) Λ4 says Grid (2 丨 () X297 Gongmeng―) (Please read the precautions on the back before filling in this page) Clothing · Order A7 B7 Printed by the Employees Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Invention Instructions (3) Particle embedding. Triangle between large particles The accumulation of small particles in voids covers at least a large range as if they are connected to each other through branches. What is quite different from the appearance of particles is the different composition, in which particles (crystals) that are morphologically distinguishable Contains a very high or low concentration of modifying ingredients, and the part polished by the worm is quite prominent. In this article, the particles refer to the forming units that can be distinguished from each other due to the obvious boundaries in the single part polished. , Also refers to crystals. In addition to its high hardness, the abrasive of the present invention is highly resistant to high thermal and mechanical loads, so if it is used in an abrasive belt with the abrasive of the present invention, it will greatly increase the per unit time In addition to the amount of material that can be worn away, a large cap can extend the life of the tool. The abrasive of the present invention can be used on a substrate as a component of bonded grinding tools in terms of abrasive blasting or lapping or as a loose abrasive. The abrasive of the present invention can be used in a qualitative and quantitative combination with other kinds of abrasives in all fields of application, and is more advantageous when mixed with high-hardness abrasive particles such as nitrated sand, tetragonal boron nitride or ore. In addition, the abrasive of the present invention can also be used as a matrix to incorporate one or more abrasives with different properties. The latter is achieved by mixing other abrasives into an intermediate (preferably sol or gel) in the preparation process of the abrasive of the present invention. In this process, it must be ensured that the tin-containing material is intimately mixed with other starting materials and finely dispersed in these starting materials. If the preparation process starts from a powdered starting material that has undergone calendaring and sintering, the tin-containing material is preferably added in the form of powder. This tin-containing material can also be in a liquid state and mixed into this paper. # MJfl 中 VALVE VALVE Biaohua (C'NS) Λ4 ^ Grid (210X297 public release) (please read the precautions on the back before filling this page) 312703 A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (). The material to be sintered or sprayed on the material to be sintered. If the dissolution-gel method is used and the tin-containing material is added to the starting material before the gel is generated so that the tin-containing material is already contained in the dispersion liquid (sol) that will form the gel, then it can achieve a fairly intimate mixing effect. This tin-containing material can be in a solid, finely divided, crushed state or in a solution. It has been determined that the dry gel produced by the method of the present invention has a property capable of withstanding high mechanical loads in comparison with the Wuxi method. This not only indicates that this method has a considerable modification effect, but also improves the crushing effect of the dried gel in terms of yield and the shape of the crushed particles. The addition of the starting material or intermediate physical tin oxide in the form of powdered Sn〇2 has been proved to be a particularly useful compound in the present invention, but other tin-containing materials such as tin salts can also be used. It is advantageous for this solution to contain 7-vaporized aluminum which is separated very finely and crushed if necessary. If further adding lithium (preferably mixed into the intermediate in any stage in the form of an aqueous solution of lithium salt), a particularly good result can be achieved. The lithium compound (preferably a lithium salt) should preferably appear in the sol in a dissolved state, and in the sol If it contains other modifying ingredients (especially those mentioned above), it is best to also exist in the sol in a finely separated solid state or in a state of dissolution, and these ingredients can also be added to another intermediate. Its preferred content range (in terms of vaporization) is-· m 0.1-196 gold B 0.1-1% 娌 0.01-596, 1.5-3% is preferred 6 paper ruler suitable.if; Zhongmin Jiejia Standard (CNS) Λ4 present style (2 丨 0'〆W7mm) --------- 1 'outfit ------ order ------ I.V1 --- (please Read the precautions on the back first and then fill out this page) A7 B7 printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of invention () Age 0.01-0.4% Rare earth metal 0.1-2¾ In addition to the above, Sol-Ningjun The process steps of the method are not necessary to elaborate further because these steps can be performed using existing prior art, especially the steps described in the aforementioned patent documents. The starting material used is a kind of hydrogenated bromide, and it is preferably a boehmite type oxygen <aluminum oxide hydroxide, such as Condea-Chemi at Brunsbiitte 1. Various Disperal Oxidation Marks manufactured by e Company have proved to be very useful materials. After the addition of deionized water and nitric acid, a suspension is obtained. This suspension may be centrifuged as necessary to remove coarser components. It is best to add a nuclear generator (nucleus former) or -χ —oxygen dagger, and it is necessary to use this substance. 7-Gasification broth can be contained in the aqueous dispersion of nitric acid first, and this dispersion can be centrifuged in the same way. Mixing a certain amount of these dispersions with any modifying ingredients (preferably in the form of an aqueous solution or aqueous dispersion) to obtain a suspension, this suspension is converted to coagulation using nitric acid and / or its salts in the aqueous solution and then This gel was dried and calcined. The dried or burnt intermediate is crushed and classified as necessary. Then, the calcined intermediate is sintered, and finally the obtained abrasive is dripped and mixed to make a batch of grains having a uniform particle size. We have found that the use of lithium and the selective use of the aforementioned components but without tin can also achieve very good results, especially when 2% by weight of embedding (in the oxide state in the sintered product) is added. Although the technique of adding interest is already known (ΕΡ 0441640), this gasified substance contains clams in the sintered product is the most 7 · — ^ — (please read the precautions on the back before filling in this page) This paper is based on size; ^ Use net Minjia Biaoping ((^ $) August 4 specifications (210> (297 public Zhao) Ministry of Economic Affairs Central Standards Bureau employee consumer cooperatives printed 312703 A7 B7 V. Invention description (). It only accounts for 1.5% by weight, and the document It is pointed out that the use of an amount higher than this value will deteriorate the quality of the abrasive. However, the present invention has obtained the opposite result. We found that regardless of the amount of tin added • The lithium content (calculated as gasification) should be accounted for in the sintered product 1 * 5% by weight or more, but it is better when using lithium and tin at the same time. ΜΆ = ζ ί} 200kg demineralized water (50 ° C), 28 1 HM〇3 solution (concentration 53%) ). And 1000kg Disperal mixed together to produce a suspension, after centrifugation to get ff first precursor, its solid content is about 30% by weight. 1000kg deionized water (50 ° C). 27kg v -A1s〇3 ( &Quot; Puralox 400 ″ provided by CondeaF ^ f of Bruns blittel) and 5 1 HN〇3 The solution (concentration 53%) is mixed and centrifuged to form a second precursor (its solid content is 2.5% by weight). 1000 kg of the first precursor, 500 kg of the second precursor, lkg tin oxide (in the state of aqueous suspension), 3.3 Kg nitric acid hexahydrate (in aqueous solution), 0.2ks Ming nitrate hexahydrate (in aqueous solution) and lkg gasified poly-B are mixed to obtain the third precursor. Fourth precursor. Contains 75kg deionized water and 48kg Nitrate Nine Hydrate Ο Mix 1505.5 kg of the third precursor with 123 kg of the fourth precursor to form a gel, and then dry at 130 ° C. for 20 minutes. Pulverize the dried material and then forge at 850 ° C. Burn 15 minutes. Then sinter in a tubular rotary furnace at a temperature of 145CT C 12 8 One by one paper according to the reverse m 丨, net home standard standard (CNS) Λ4 specifications (2 丨 0X297mm) (please Read the precautions on the back and then fill out this page). Packing. Ordered by the Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperative. Printed A7 B7. 5. Description of invention () Minutes and then decorated with categories. The abrasive particles obtained in this way contain tin children (In the state of vaporized tin) is 0.36% by weight, its flat The hardness was 19.1 GPa. The second case repeated the steps of Example 1, but the amount of tin oxide in the third precursor was changed to 5.5 kg. As a result, the average hardness of the particles produced was 18.1 GPa, and the density was higher than that of Example 1. Example 3 repeats the steps of Example 1 but uses an additional 25.4 kg of lithium nitrate. As a result, the lithium content of the particles (in the state of vaporized lithium) is 2%, and the average Knoop hardness is 22.22 GPa. Official Example 4-h Use the same method and material composition as in Example 3, but change the lithium nitrate (Please read the precautions on the back before filling in this page) Pack. The proportion makes the content of lithium vapor in the final product: 0.1% by weight (Example 4) 0.2% by weight (Example 5) 0.3% by weight (Example 6) 0.4 car max 9 ^ (Example 7) 0.5% by weight (Example 8) 1.0% by weight (Example 9) 3.0% child (Example 10) -In, τ The hardness described in this article (Knoop method) is based on Shimadzu Measured by a test device with a manufacturing model of HMV-2000. Average Knoop Hardness [GPa] Example 4 18.9 ～ 9 ～ This paper ruler national standard (C’NS) Λ4 specification (210X 297 public sounds) A7 B7 V. Description of invention () Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs
實例五 20.3 實例六 20.5 實例七 20.5 實例八 20.6 實例九 20.7 實例十 19.7 宵例+—— 以實例三的步驟産製工業規模量的本發明磨料，每隔 60分鐘即從進行中的生産過程取出兩份磨料顆粒試樣。 將10次取得的試樣分成兩批測其硬度，得結果如下（ Knoop GPa)： 試樣1 試樣2 22.22 22.22 21.21 23.70 20.57 20.88 21.88 22.58 21.88 22.22 20.72 21.54 21.88 20.41 21.04 20.72 21.88 21.04 22.22 21.04 Ma= Ma= Zl^&A (請先閱讀背面之注意事項再填寫本頁) -9 本紙張尺度適十阐阀家《卒（（'NS ) Λ4規格（2丨0乂297公釐） A7 五、發明説明（） 窗例+二 、 為評估本發明磨料的性能，以實例一與實例三所製成 顆粒大小為P36的磨料顆粒製造硫化纖維研磨輪。 以相同方式製造硫化纖維研磨輪並令其含有熔化金鋼 砂作為比較試樣（fcfc較試樣A)。 車箱子的直徑為180mm (cross recess design，轉速為 6000 min1)。被用來研磨的物品是一條直徑195nun的鋼 管ST 37,像以16.3 min1的速度與研磨輪相反的方向旋 轉。下表所列數值是毎隔60秒鐘鋼管被磨掉的董[g]。 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 磨掉的量[g] 使用的磨料 0-60 秒 60-120秒 120-180秒 120-240秒 相當於賁例三 的磨料頼粒 65 47 39 35 相當於實例一 的磨料顆粒 52 35 27 23 比較試樣A 32 17 12 9 以溶化金鋼砂（fcb較試樣B)、相當於賁例一之磨料 以及相當於實例三的磨料製造尺寸為50mm X 2000mm的磨 〜 11 〜 本紙张又度通川'I’W阀家標隼（CNS ) Λ4規格（210κ297公釐）Example 5 20.3 Example 6 20.5 Example 7 20.5 Example 8 20.6 Example 9 20.7 Example 10 19.7 Night Example + —— In the process of Example 3, an industrial-scale amount of the abrasive of the present invention is produced, which is taken out of the ongoing production process every 60 minutes Two samples of abrasive particles. Divide the samples obtained 10 times into two batches and measure the hardness. The results are as follows (Knoop GPa): Sample 1 Sample 2 22.22 22.22 21.21 23.70 20.57 20.88 21.88 22.58 21.88 22.22 20.72 21.54 21.88 20.41 21.04 20.72 21.88 21.04 22.22 21.04 Ma = Ma = Zl ^ & A (please read the precautions on the back before filling in this page) -9 This paper is suitable for the tenth chapter of the book "Shi (('NS) Λ4 Specification (2 丨 0 侂 297mm) A7 Five 2. Description of the invention () Window example + 2. In order to evaluate the performance of the abrasive of the present invention, the vulcanized fiber grinding wheel is manufactured with the abrasive particles with the particle size of P36 prepared in Example 1 and Example 3. The vulcanized fiber grinding wheel is manufactured in the same way It contains molten gold steel sand as a comparative sample (fcfc compared with sample A). The diameter of the car box is 180mm (cross recess design, speed is 6000 min1). The object used for grinding is a steel pipe ST 37 with a diameter of 195nun, It is like rotating in the opposite direction of the grinding wheel at a speed of 16.3 min1. The values listed in the table below are Dong [g] that the steel pipe is worn away every 60 seconds. (Please read the precautions on the back before filling this page) Ministry of Economic Affairs central Amount printed by quasi-bureau employee consumer cooperatives [g] Abrasives used 0-60 seconds 60-120 seconds 120-180 seconds 120-240 seconds equivalent to the abrasive grains of Example 3 65 47 39 35 equivalent to Example 1 Abrasive particles 52 35 27 23 Comparative sample A 32 17 12 9 A 50 mm X 2000 mm mill was manufactured with molten gold sand (fcb compared to sample B), the abrasive equivalent to Example 1 and the abrasive equivalent to Example 3 ～ 11 〜 This paper is again Tongchuan 'I'W valve house standard falcon (CNS) Λ4 specification (210κ297mm)
•IT A7 B7 312703 五、發明説明（） 帶以作進一步的比較試驗。被用來研磨的物品是一條直徑 219.1mm且管壁厚度為6.3mm的鋼管ST 35-8/1，係以33.4 min-1的速度旋轉。磨帶的直線速度為38 m/s。 下表所列數值是到達指定時間後鋼管被磨掉的總量[g ]〇 驗斗 mm 5 10 15 20 25 30 35 童 40 45 fcb車爲式0.91 1.46 1.93 2.35 2.75 2.98. 3.16 3.29 3.44«® 實例一 0.95 1.67 2.29 2.85 3.28 3-73 4.12 4.45 4.71 實例三 1.29 2.27 3.18 4.01 4.80 5.57 6.26 6.87 7.42 富例+四 同於實例三，但不加錫，結果得到的顆粒硬度為19.1 GPa〇 (請先閱讀背面之注意事項再填寫本頁) 訂· % 經濟部中央標準局負工消費合作社印製 本紙中阀阀本椋苹（「NS ) Λ4現格（210X 297公釐）• IT A7 B7 312703 V. Description of the invention () Taken for further comparative tests. The object used for grinding was a steel pipe ST 35-8 / 1 with a diameter of 219.1 mm and a wall thickness of 6.3 mm, which was rotated at a speed of 33.4 min-1. The linear velocity of the abrasive belt is 38 m / s. The values listed in the table below are the total amount of steel pipes worn away after reaching the specified time [g]. Test mm 5 10 15 20 25 30 35 Tong 40 45 fcb car is 0.91 1.46 1.93 2.35 2.75 2.98. 3.16 3.29 3.44 «® Example one 0.95 1.67 2.29 2.85 3.28 3-73 4.12 4.45 4.71 Example three 1.29 2.27 3.18 4.01 4.80 5.57 6.26 6.87 7.42 Rich example + four is the same as example three, but without tin, the resulting particle hardness is 19.1 GPa (please first Read the precautions on the back and then fill out this page) Order ·% Valves and valves in the printed paper printed by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (“NS”) Λ4 cash (210X 297 mm)