I307660 a7 __B7五、發明説明（3 ) 經濟部中央標準局員工消費合作社印製 含 水中真4,真 因氧性 K 合 適發面 性本假 本此會 於之劑殺 ^2’殺 ，為水難 混對而表水為t(成，不 , 劑溶之 -有 性因疏而 之。 ，型疏稱 Ξ 完質者 中性櫬理 DC2具 活，及因。滋劑果酸於中安此性或 其活有處 一-Ν-w 菌而水，方拉菌结磺解文 因利物 ,面性子.3Ε-Ϊ 真然於態配洛真的素溶後 ，有留 物表水種 -,ίϋ 殺。溶固之克殺究質化方之殘 成型疏為 代-PU 有劑難半態剖的研木乳物豸配性出 組酸於作 氧ftIHM· 1 具菌且為型和理入之且成如態散倒 菌磺解合8-)«I(g»滋真質時體酸處深 5 -組 ¥ 型分地 I •含 _ 真素溶適 £ 酸胺 拉殺物溫液克子方 2 酸菌 Ϊ 體再易 0 包 殺質化物--I克醢 洛之態常之寧種配於克真 液好輕 之木乳成 一，寧1-克理固於定里之態高寧殺®,之良能 穎之且組,8里1 剖處之滋安代譜型不里之性 } 有後 新 5 ，菌-5代 U 和子點拉得氧菌體度代滋M澱具泡 種 2 酸真 基氧 ί 酸種熔洛獲用真液化氧拉 W 沈亦浸 一 於克殺 乙»(基 克為高克物使殺之磺散洛胄未物子 關高寧此5-β 乙 寧作有剖合想廣霧均分克 — 物成種 有不里。 知 里於具而化構寬嗔平 ，剖 合姐在 係度代滋 已-7基 代用為 -二 人有或有中之),化明得 明化氧拉 ，啉氧 氧可酸中此明具泡含水中物分發使 發磺散洛 今of苯。於為克劑合發為浸於之劑成成本質 本均分克。迄g]氯性由，認寧溶混本作子種劑溶組性。性 平，剖劑5-三活 被里櫬由 方種一性機明活明利 有中之菌4,6-菌 而代有藉 配合現活有發定發有 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X 297公釐） 3 經濟部中央標準局員工消費合作社印製 A7 ____B7 _ 五、發明説明（4 ) 阻塞噴霧器之噴嘴。 本發明中使用之「平均磺化度不高於2.5之木質素磺 酸型表面活性劑」意指木質素磺酸型表面活性劑，其中每 1,000單元分子量之木質素，磺酸基之平均數目不超過2.5 ,通常為0.2-2.5 。一般而言，木霣素磺酸型表面活性劑 為鹼金鼷塩如木質素磺酸之鉀塩及納塩，鹸土金臛塩如木 質素磺酸之鈣塩等。這些木質素磺酸型表面活性劑可單獨 或K兩種或兩種Μ上合併使用。表面活性劑之用量係足Μ 分散氧代里寧克酸及乳化溶解於疏水性有機溶劑中之剖克 洛拉滋者，更詳而言之，此用量係本發明組成物之 ν l-15wt% ,較佳為 2-10wt% 。 本發明中，用以溶解剖克洛拉滋之疏水性有機溶劑為 於10C之水溶解度通常不超過300ppm且在常溫時能夠溶解 不超過20wt%之剖克洛拉滋之有櫬溶劑。此溶劑之實例包 含芳族烴如烷基苯例如二甲苯，苯基二甲苯基乙烷；K及 酯類如酞酸烷酯。這些疏水性有櫬溶劑可單獨或Μ兩種或 兩棰Μ上合併使用。 本發明組成物中之氧代里寧克酸及剖克洛拉滋的用最 大約分別為5〜40wt%及1〜15wt% 。上述之疏水性有櫬溶 劑之用量為足以溶解其中之剖克洛拉滋者，例如，大約為 本發明組成物總量之l-30wt% 。 本發明組成物可又包括配方肋劑如增稠劑，潤濕劑， 防凍劑及防腐劑。增稠劑之實例包含咕噸樹膠，剌槐木磺 材樹膠，瓜爾膠，角叉菜膠，海藻酸及其塩，西黃蕃膠， 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ---------f -裝 -----訂------{抹 (請先閱讀背面之注意事項再填寫本頁) 1 4 307660 A7 __B7 五、發明説明（5 ) 矽酸鋁鎂，膨潤土，膠體狀二氧化矽等。含量通常大約為 本發明組成物總量之0.02-5wt% ,較佳為0.05-2vit% 。 (請先閱讀背面之注意事項再填寫本1) 潤濕劑包含，例如，聚氧乙烯烷基笨基醚如聚氧乙烯 辛基苯基醚；聚氧乙烯烷基魅如聚氧乙婦月桂基醚；聚氧 乙烯烷基酯如聚氧乙烯油醢基酯等。含量通常大約為本發 明組成物缠置之0.01-0.，較佳為0,05-0.2wt% 。 防凍劑包含乙二酵，丙二醇，甘油等。含量通常大約 為本發明組成物總量之3-15wt%，較佳為5-lOwt% 。防腐 劑包含福、林，1,2 -苯并異I*唑-3-酮等，含量通常為本 發明組成物總量之0.005-2¥1:%,較佳為0.01-0.5%。 為了在種子處理之應用上能夠容易地確定本發明組成 物沈積在種子上，本發明組成物可含有染料或顔料。染料 或顔料之實例包含，偁氮，酞菁，憩醌及甲晚染枓。 本發明組成物係依據，例如，下述之程序製備之。 經濟部中央標準局員工消費合作社印製 將氧代里寧克酸分散於含有平均磺化度不高於2.5之 木質素磺酸型表面活性劑之水中，接著Μ球磨機等予Μ濕 式研磨Κ獲得漿液。或者，可Μ空氣研磨機等乾式研磨氧 代里寧克酸，接著再將其分散於含有平均磺化度不高於2.5 之木質素磺酸型表面活性劑之水中，Μ獲得漿液。另一方 面，將剖克洛拉滋溶解於疏水性有櫬溶劑中，然後藉由使 用混合器使其與含有平均磺化度不高於2.5之木質素磺酸 型表面活性劑之水混合，且乳化於其中，接著與上述之氧 代里寧克酸漿液合併。需要的話，進一步混合配方肋劑， 因而獲得本發明組成物。_ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） 經濟部中央標準局員工消費合作社印製 A7 ____ B7 _ 五、發明説明（6 ) 另一可行方式為，本發明組成物可藉由以上述相同之 方式製備氧代里寧克酸^液，在以混合器將其混合的同時 將溶解於疏水性有機溶劑中之剖克洛拉滋添加至該漿液， 需要的話，進一步混合該些助劑而製得之。 又一可行方式為，本發明組成物可藉由將氧代里寧克 酸分散於含有平均磺化度不高於2. 5之木質素磺酸型表面 活性劑之水中，再將溶解於疏水性有機溶劑中之剖克洛拉 滋添加至分散液，接著K球磨機等予Μ濕式研磨，需要的 話，進一步混合該些肋劑而製得之。 1 上述製備程序中，較佳係使用具有大剪切力之混合器 \ ,如分散器及球磨機。 本發明組成物適合作為種子處理之殺真菌劑，例如， 將種子浸泡在以水稀釋至大約1:10-1000之組成物中，將 本發明組成物原樣施用在種子上，或將與水之1:2-100稀 釋液嗔佈在種子上。 本發明藉由配方例及試驗例詳述之，但其應不用於限 制本發明。 配方例1 使80g之Reax 85Α(平均磺化度為1.0之木質素磺酸納 ,Westv言co製造）溶解於800g蒸餾水中，再添加400g之氧 代里寧克酸，接著以球磨櫬精细地研磨，獲得漿液。在以 Μ型自動均混機（Tokushu Kika Kogyo K.K.)授拌600g所得 漿液的同時，加入溶解於50g Solvesso 150( —種芳族烴 ,Exxon公司製造）之&〇s剖克洛拉滋之溶液，接著混合及 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ---------{威-------訂------ (請先閱讀背面之注意事項再填寫本頁) 6 經濟部中央標準局員工消費合作社印製 307660 at __B7 五、發明説明（7 ) 微粉化，K獲得分散-乳化液體。另一方面，將20g之Kelzan S(咕噸樹膠，Sansho Κ,Κ供應）添加至9 8 0 g蒸餾水中，且 藉加熱至60"C而溶解之，K獲得增稠溶液。將50克丙二醇 及125g增稠溶液添加至上述之分散-乳化液體中，接著再 --------(-裝------訂-----f 龈 (請先閱讀背面之注意事項再填寫本頁) 添 加 蒸 覦 水 >λ 製 得 1 000克之 本 發 明組 成 物 〇 經 由 顯 微 /Wg m 對 所 得 之 本 發 明 組 成 物的 觀察 顯 示 沒有 發 現 聚 集 之 粒 子 0 配 方 例 2 重 複 配 方 例 1 , 但以溶解东 M20g蒸餱水中之1 60 g Re a X 83 A (平 均 磺 化 度 為 2.1之木質素磺酸納， V e s tv 八 a c 〇製造） 取 代 溶 解 於 800g 蒸 緬 水之 80g Re ax 85 A t 因 而 獲 得 本 發 明 組 成 物 0 經 由 顯 微 鏡 對所 得之 本 發 明組 成. 物 的 觀 察 顯 示 發 現 極 少 之 聚 集 粒 子 〇 配 方 例 3 重 禊 配 方 例 1 , 但使用80s R e a X 82 (平均磺化度為2 .0 之 木 質 素 磺 酸 納 t West v*a c 〇 製 造 )取代8 0 g 之 Re ax 85 A 9 因 而 獲 得 本 發 明 組 成 物。 經由 顯 微 鏡對 所 得 之 本 發 明 組 成 物 的 觀 察 顯 示 發 現 極 少之 聚集 粒 子 〇 配 方 例 4 重 複 配 方 例 1 . 但使用80g R e a X 8 1 A ( 平 均 磺 化 度 為 1.9 之 木 質 素 磺 酸 納 > West v a c 〇 製 造 )取代8 〇g 之 Re ax 85 A f 因 而 獲 得 本 發 明 組 成 物0 經由 顯 微 鏡對 所 得 之 本 發 明 組 成 物 的 觀 察 顯 示 發 現 搔 少之 聚集 粒 子 〇 配 方 例 5 重 複 配 方 例 1 , 但使用80g P ο 1 y f on 0 (平 均 磺 化 度 為 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 7 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（8 ) 1.2之木質素磺酸納，Westvtco製造）取代80g之Reax 85A, 因 而 獲 得 本 發 明 組 成 物 〇 m 由 顯 微 鏡 對 所 得 之 本 發 明 組 成 物 的 觀 察 顯 示 發 現 極 少 之 聚 集 粒 子 0 配 方 例 重 複 配 方 例 1 , 但使用8 0 g R e a X 91 0 ( 平 均 磺 化 度 為 1.7 之 木 質 素 磺 酸 納 » We s t v^a CO 製 造 )取代8 0 g 之 Re ax 85 A 1 因 而 獲 得 本 發 明 組 成 物 0 經 由 顯 微 鏡 對 所 得 之 本 發 明 組 成 物 的 觀 察 顯 示 發 現 極 少 之 聚 集 粒 子 〇 配 方 例 7 重 複 配 方 例 1 , ii i使用8 0 g P ο 1 yf on Η (平 均 磺 化 % 為 0 . 5之木質素磺酸納， W e s t V "a c 〇製造）取 代 80 g之R e a X 85A * 因 而 獲 得 本 發 明 組 成 物 〇 經 由 顯 微 鏡 對 所 得 之 本 發 明 組 成 物 的 觀 察 顯 示 沒 有 發 現 聚 集 粒 子 0 配 方 例 8 重 複 配 方 例 1 , 但使用50g 乙 二 醇 取 代 50 g 丙 二 醇 〇 經 由 顯 微 鏡 對 所 得 之 本 發 明 組 成 物 的 觀 察 顯 示 沒 有 發 現 聚 集 粒 子 〇 配 方 例 9 - 重 m 配 方 例 1 , 但使用1 Os K el z a η及1 0 g V e e g υ m R ( 矽 酸 鋁 鎂 9 Sa Π S h 〇 K .K .供應） 取 代 20 g之K e 1 z a η s 〇 經 由 顯 微 鏡 對 所 得 之 組 成 物 的 觀 察 顯 示 沒 有 發 現 聚 集 粒 子 0 配 方 例 1 〇 使 80 丨克 之 R e a X 85A溶 解 於 80 1 0 g 蒸 餾 水 中 » 再 加 入 4 0 0 g 氧代里寧克酸並分散之，接著KKDL型Dyno -研磨機（ ---------f -裝------訂-----八線 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 8 經濟部中央標準局員工消費合作社印製 A7 __B7 五、發明説明（9 )I307660 a7 __B7 Fifth, the description of invention (3) The Ministry of Economic Affairs Central Standards Bureau employee consumer cooperative printed the water content of the true 4, true due to oxygen K suitable for facial properties, this fake will be used to kill the agent ^ 2 'kill, water difficulties Mixed and the surface water is t (come, no, the agent dissolves-the nature is due to sparseness., The type is called Ξ The intact person is neutral and the DC2 is active, and the cause. The nourishment acid is neutral Or there is a place where -N-w bacteria and water, Fangella bacteria sulfonate lysate Wen Yinli, noodles. 3Ε-Ϊ It is really in the state of the state, after dissolving the element, it has a surface water- , ίϋ kill. The solution of the solid solution of the killing of the qualitative side is sparsely replaced-PU has a hard-to-half-analyze wood-based milk product and is compatible with oxygen. ftIHM · 1 has bacteria and is a type and Incorporate and disintegrate bacterium and sulfolysis 8-) when «I (g» is a true substance, the body acid is at a depth of 5-group ¥ type sub-division I • Contains _ true element soluble £ amide pull kill Warm Liquid Kezifang 2 Acid Bacteria Ϊ body re-easy 0 packs of mass killing chemicals-I gram of the state of the Luo Ning is often mixed with Ke Zhen Ye good light wood milk into one, Ning 1- gram solid fixed in Ding Li Fang Gao Ning Shai®, the best of the best and the best, 8 miles and 1 cut Generation spectrum type is not in the nature} There is Houxin5, bacteria-5th generation U and sub-point pull oxobacteria degree generation zizi M with bubble seed 2 acid true base oxygen acid species melt Luo obtained true liquefied oxygen pull W Shen Yibing is in the gram to kill B »(Kick is a high gram of material to kill the sulfonolone and the child is not a child Guan Gaoning. This 5-β yining has a combination of thoughts. The fog is evenly divided into grams. The knowledge is wide and flat with the specific chemical structure, and the sister is used in the system of Dudaizi already-7 base substitution is-two people have or have). The distribution of the water-containing medium in the Ming Dynasty makes the sulfonamides of benzene. The combined cost of the Yuwei gram and the immersion agent is equal to the cost. So far, the chlorine property can be recognized as a sub-seed agent. Dissolve the group. The sex is flat, the dissection agent 5-three live is covered by the side, the one kind of machine is lively, and the beneficial bacteria are 4,6-bacteria. Note on the back and then fill out this page) This paper scale is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 3 Printed by the Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperative A7 ____B7 _ V. Description of invention (4) Blocking spray Nozzle of the device. "Ligninsulfonic acid type surfactant with an average sulfonation degree not higher than 2.5" used in the present invention means ligninsulfonic acid type surfactant, in which lignin per 1,000 unit molecular weight, sulfonic acid The average number of bases does not exceed 2.5, usually 0.2-2.5. Generally speaking, lignin sulfonic acid type surfactants are alkali gold halide such as potassium and sodium sulfonate of lignin sulfonate, such as earthen gold halide. Calcium salt of lignin sulfonic acid, etc. These lignin sulfonic acid surfactants can be used alone or in combination of two or two types of M. The amount of the surfactant is sufficient to disperse the oxolinenic acid and emulsified and dissolved in the hydrophobic organic solvent, and more specifically, the amount is ν l-15wt of the composition of the present invention. %, Preferably 2-10wt%. In the present invention, the hydrophobic organic solvent used to dissolve crocoraz is a natural solvent whose water solubility at 10C is usually not more than 300 ppm and can dissolve not more than 20 wt% of crocoraz at normal temperature. Examples of this solvent include aromatic hydrocarbons such as alkylbenzene such as xylene, phenylxylylethane; K and esters such as alkyl phthalate. These hydrophobic solvents can be used alone or in combination of two or two. The use of oxolinic acid and secorolazide in the composition of the present invention is approximately 5 to 40 wt% and 1 to 15 wt%, respectively. The amount of the above-mentioned hydrophobic organic solvent is sufficient to dissolve the progesterone in it, for example, about 1-30 wt% of the total composition of the present invention. The composition of the present invention may further include formulated rib agents such as thickeners, wetting agents, antifreeze agents and preservatives. Examples of thickeners include xanthan gum, locust wood sulfonate gum, guar gum, carrageenan, alginic acid and its salt, xanthan gum, and the paper size is applicable to China National Standard (CNS) A4 specifications ( 210X297mm) --------- f -installed ----- ordered ------ {wipe (please read the precautions on the back before filling this page) 1 4 307660 A7 __B7 5. Description of the invention (5) Aluminum magnesium silicate, bentonite, colloidal silica, etc. The content is usually about 0.02-5wt% of the total composition of the present invention, preferably 0.05-2vit%. (Please read the precautions on the back before filling in this 1) Wetting agent contains, for example, polyoxyethylene alkyl stupid ether such as polyoxyethylene octyl phenyl ether; polyoxyethylene alkyl charm such as polyoxyethylene laurel Base ether; polyoxyethylene alkyl esters such as polyoxyethylene oleyl ester, etc. The content is usually about 0.01-0., Preferably 0,05-0.2wt% of the composition of the present invention. Antifreeze contains glyphosate, propylene glycol, glycerin, etc. The content is usually about 3 to 15% by weight of the total composition of the present invention, preferably 5 to 10% by weight. The preservatives include Fu, Lin, 1,2-benziso I * azol-3-one, etc., and the content is usually 0.005-2 ¥ 1:% of the total composition of the present invention, preferably 0.01-0.5%. In order to be able to easily determine that the composition of the present invention is deposited on seeds in the application of seed treatment, the composition of the present invention may contain dyes or pigments. Examples of dyes or pigments include, nitrogen, phthalocyanine, polyquinone, and formazan. The composition of the present invention is prepared according to, for example, the following procedure. Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs to disperse oxolinic acid in water containing ligninsulfonic acid surfactants with an average sulfonation degree of not higher than 2.5, and then wet milled by Μ ball mill Obtain the slurry. Alternatively, oxylinnamic acid may be dry-milled by an air mill or the like, and then dispersed in water containing a lignosulfonic acid-type surfactant having an average sulfonation degree of not higher than 2.5 to obtain a slurry. On the other hand, dissolve crocoraz in a hydrophobic solvent, and then mix it with water containing lignosulfonic acid surfactant with an average sulfonation degree not higher than 2.5 by using a mixer. And emulsified in it, and then combined with the above-mentioned oxolinic acid slurry. If necessary, the formula rib agent is further mixed to obtain the composition of the present invention. _ This paper scale is applicable to China National Standard (CNS) Α4 specification (210X 297 mm) A7 ____ B7 _ printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. V. Description of invention (6) Another possible way is the composition of the invention The oxolinenic acid solution can be prepared in the same manner as described above, and cecrolazi dissolved in a hydrophobic organic solvent can be added to the slurry while mixing it with a mixer, if necessary, further It is prepared by mixing these additives. Yet another feasible way is that the composition of the present invention can be dissolved in hydrophobic by dispersing oxolinic acid in water containing ligninsulfonic acid surfactant with an average sulfonation degree not higher than 2.5 In the organic solvent is added to the dispersion liquid, then K ball mill and other wet grinding, if necessary, further mixing these ribs to prepare. 1 In the above preparation procedure, it is preferable to use a mixer with large shear force, such as a disperser and a ball mill. The composition of the present invention is suitable as a fungicide for seed treatment, for example, the seeds are soaked in a composition diluted with water to about 1: 10-1000, and the composition of the present invention is applied to the seeds as they are, or it is mixed with water 1: 2-100 dilution liquid spread on the seeds. The present invention is described in detail by formula examples and test examples, but it should not be used to limit the present invention. Formulation Example 1 80 g of Reax 85A (sodium lignosulfonate with an average sulfonation degree of 1.0, manufactured by Westvyan Co) was dissolved in 800 g of distilled water, and then 400 g of oxolinic acid was added, followed by ball milling. Grind to obtain a slurry. While mixing 600g of the obtained slurry with an M-type automatic homomixer (Tokushu Kika Kogyo KK), a solution of & 〇s 克克拉拉兹 dissolved in 50g Solvesso 150 (an aromatic hydrocarbon, manufactured by Exxon Corporation) was added. ， Then mixed and the paper standard is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) --------- {威 ------- 定 ------ (please first Read the precautions on the back and fill in this page) 6 Printed 307660 at __B7 by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (7) Micronized, K obtains dispersion-emulsified liquid. On the other hand, 20 g of Kelzan S (xanthan gum, supplied by Sansho Κ, Κ) was added to 980 g of distilled water, and dissolved by heating to 60 ° C. K obtained a thickened solution. Add 50g of propylene glycol and 125g of thickening solution to the above dispersion-emulsified liquid, and then -------- (-packing ------ order ----- f gingival (please read first (Notes on the back and then fill in this page) Add distilled water> λ to prepare 1 000 g of the composition of the invention. Observation of the obtained composition of the invention by microscopy / Wg m shows that no aggregated particles are found. 0 Formulation Example 2 Repeat Formulation Example 1, but dissolve 1 60 g Re a X 83 A (manufactured sodium lignin sulfonate with an average sulfonation degree of 2.1, manufactured by V es tv 8ac 〇) instead of dissolving in 800 g steam 80g Re ax 85 A t of Burmese water thus obtained the composition of the present invention. Obtained the composition of the present invention through a microscope. Observation of the object revealed that very few aggregated particles were found. Formulation Example 3 Heavy Formulation Formulation Example 1, but using 80s R ea X 82 (manufactured by sodium lignosulfonate t West v * ac 〇 with an average sulfonation degree of 2.0) instead of 80 g of Re ax 85 A 9 Obtained the composition of the present invention. Observation of the obtained composition of the present invention through a microscope revealed that very few aggregated particles were found. Formulation Example 4 Repeated Formulation Example 1. However, 80 g of Rea X 8 1 A (average sulfonation degree of 1.9 wood was used Sodium sulfonate (manufactured by West vac 〇) replaces 8 〇g of Re ax 85 A f and thus obtains the composition of the present invention. Observation of the obtained composition of the present invention through a microscope shows that few aggregated particles are found. Formulation Example 5 Repeat the formula example 1, but use 80g P ο 1 yf on 0 (the average sulfonation degree is based on the paper standard. It is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 7 Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 5. Description of the invention (8) 1.2 sodium lignosulfonate (manufactured by Westvtco) replaces 80g of Reax 85A, thus obtaining the composition of the present invention. Observation of the obtained composition of the present invention by microscope Very few aggregated particles were found. 0 Formulation Example Repeat Formulation Example 1, but use 80 g R ea X 91 0 (manufactured by sodium lignosulfonate with average sulfonation degree 1.7 »We stv ^ a CO) instead of 80 g Re Ax 85 A 1 thus obtained the composition of the present invention. Observation of the obtained composition of the present invention through a microscope revealed that very few aggregated particles were found. Formulation Example 7 Repeated Formulation Example 1, ii i used 80 g P ο 1 yf on Η ( Sodium lignosulfonate with an average sulfonation% of 0.5, manufactured by West V " ac 〇) replaces 80 g of Rea X 85A * thus obtaining the composition of the present invention. The composition of the present invention obtained by microscope Observation showed that no aggregated particles were found. Formulation Example 8 Formulation Example 1 was repeated, but 50 g of ethylene glycol was used instead of 50 g of propylene glycol. Observation of the obtained composition of the present invention through a microscope revealed No agglomerated particles were found. Formulation Example 9-Weight m Formulation Example 1, but replaced with 1 Os K el za η and 10 g V eeg υ m R (aluminum magnesium silicate 9 Sa Π S h 〇K .K. Supplied) 20 g of K e 1 za η s ○ Observation of the resulting composition through a microscope revealed that no aggregated particles were found. 0 Formulation Example 1 80 gram of Rea X 85A was dissolved in 80 1 0 g of distilled water »and then added 4 0 0 g oxolinic acid and disperse it, then KKDL type Dyno-grinding machine (--------- f -installation ------ order ----- eight lines (please read first Note on the back and then fill out this page) This paper standard is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) 8 Printed by the Ministry of Economic Affairs Central Standards Bureau employee consumer cooperatives A7 __B7 5. Invention description (9)
Sh丨nmal Enterprises公司製造）予Μ精细地研磨，而獲得 漿液。在以Μ型自動均混櫬攬拌200g之所得漿液的同時， 加入溶解於50g Solvesso 150之50g剖克洛拉滋溶液，接 著混合及微粉化，K獲得分散-乳化液體。另一方面，將 20g之Kelzan S添加至980g之蒸餾水中，再藉加熱至60T： 而溶解之，Μ獲得增稠溶液。將50g之丙二酵及400g之增 稠溶液添加至上述之分散-乳化液體中，接著又添加蒸餾 水，以製得l〇〇〇g之本發明組成物。經由顯微鏡對所得之 本發明組成物的観察顯示沒有發現聚集粒子。 配方例11 使150s之Reax 85A溶解於650g之蒸餾水中，再加人 i2〇〇g之氧代里寧克酸並分散之，接著以KDL型Dyno_研磨 機予K精细地研磨，以獲得漿液。在型自動均混機攪 拌650g之所得漿液的同時，加人溶解於508 solvesso 150之50g剖克洛拉滋溶液，接著混合反微粉化，以獲得分 散-乳化液體。另一方面，將20g之Kelzan S添加至980g 之蒸餾水中，並藉加熱至60C而溶解之，Μ獲得增稠溶液 。將50g丙二酵及50g增稠溶液添加至上述之分散-乳化液 體中，接著又添加蒸餱水，Μ较得1000S之本發明組成物 。經由顯微鏡觀察所得之本發明組成物顯示沒有發規聚集 粒子。 配方例1 2 使80g之Reax 85A溶解於800g之蒸餾水中，再加入 400g之氧代里寧克酸並分散之，接著以KDL型Dyno_研磨機 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ^ I裝------訂-------{線 (請先閱讀背面之注意事項再填寫本頁) 9 A7 B7 經濟部中央標準局員工消費合作社印製 五、 發明説明（10 ) 1 1 予 >λ 精 细 的 研 磨 » K 獲 得 漿 液 0 在 Μ Μ型 白 動 均 混 機 攬 拌 1 1 I 600s 之 所 得 漿 液 的 同 時 1 加 入 溶 解 於 90s So 1 ν e s SO 150之 1 1 I 1 0 g剖克洛拉滋溶液， 接著混合及微粉化， Μ獲得分散- 乳 /-—ν 請 1 1 I 化 液 體 0 另 一 方 面 i 將 20g Ke 1 z an S 加入9 80 g 蒸 餾 水 中 先 閲 讀 背 之 1 1 1 並 藉 加 熱 至 Q0V 而 溶 解 之 1 Μ 獲 得 增稠 溶 液 〇 將50g 丙 1 1 1 二 醇 及 1 25g 增 稠 溶 液 添 加 至 上 述 之 分 散- 乳 化 液 體 中 > 接 >王 意 事 1 1 ,1— 1 著 又 添 加 m 踊 水 ， Μ 製 得 lOOOg 之 本 發明 組 成 物 〇 經 由 顯 項 再 填 微 鏡 觀 察 所 得 之 本 發 明 組 成 物 顯 示 沒 有發 現 聚 集 粒 子 〇 罵 本 頁 裝 1 SL 方 例 13 1 使80s之R e a X 85Α溶解於80〇g_餾水中， 再加入40 0 g 1 之 氧 代 里 寧 克 酸 並 分 散 之 S 接 著 Μ KDL 型 D y η 〇 - 研 磨 機 予 Μ 1 1 訂 1 精 细 地 研 磨 9 以 獲 得 漿 液 〇 在 Μ Μ 型 自動 均 混 機 m 拌 5 0 0 s 之 所 得 漿 液 的 同 時 9 加 入 溶 解 於 1 5 0 g So 1 ν e S S 0 1 5 0 g 剖 洛 1 1 克 拉 滋 溶 液 接 著 混 合 及 微 粉 化 ， 獲得 分 散 - 乳 化 液 體 1 〇 另 一 方 面 > 將 20g 之 Ke 1 z a η S 加 入 9 8 0 g 蒸 餾 水 中 t 並 藉 線 加 熱 至 60勺 而 溶 解 之 t 以 獲 得 增 稠 溶 液。 將 50 g 丙 二 酵 及 1 I 5 0 s增稠溶液添加至上述之分散- 乳 化 液體 中 * 接 著 又 添 加 1 1 蒸 餾 水 » 以 製 得 lOOOg. 之 本 發 明 組 成 物。 經 由 顯 微 鏡 觀 察 • 1 1 所 得 之 本 發 明 組 成 物 9 顯 示 沒 有 發 現 聚集 粒 子 0 - 1 1 £ 方 例 1 4 1 將 80s 之 R e a X 8 5/\及 2 g之S Ο Γ P 〇 1 8 0 4 3 ( 聚 氧 乙 烯 烷 基 1 1 | 笨 基 醚 9 To h 〇 化 學 公 司 製 造 )溶解於7 1 8g 蒸 踊 水 中 ， 再 加 1 I 人 400 s 之 氧 代 里 寧 克 酸 並 分 敗 之 接 著以 KDL 型 D y η 0 - 研 磨 1 1 I 機 予 Μ 精 细 地 研 磨 Μ 獲 得 漿 液 0 在 Μ Μ 型 白 動 均 混 機 撟 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 B7 307660 五、發明説明（11 ) 拌6 00g之所得漿液的同時，加入溶解於150g Hisol SAS-296(苯基二甲苯基乙烷，日本石化股份有限公司製造）中 之50g剖克洛拉滋溶液，接著混合及微粉化，K獲得分散 -乳化液體。另一方面，將l〇g Kelzan S及20g Veegum R 添加至970蒸皤水中，並_加熱至而溶解Kelzan S , K獲得增稠溶液。將50g丙二酵及100g增稠溶液添加至上 述之分散-乳化液體中，接著又添加蒸餾水，Μ製得1000s 之本發明組成物。經由顯微鏡觀察所得之本發明組成物顯 示沒有發現聚集粒子。 參者方例1 , 重複配方例1 ,但使用8 0 g之R e a X 8 8 β (平均磺化度為 3.8之木質素磺酸納，West d co製造）取代80g之Reax 85Α, 因而獲得比較組成物。當剖克洛拉滋溶液於漿液中乳化時 ,所得混合物圼現十分之黏稠狀。比較組成物含有巨大之 聚集粒子。 參老ffi方例2 重複配方例1 ,但使用8 0 S之R e a X 1 0 0 Μ (平均磺化度為 4.7之木質素碌酸納，'^51；¥完(：〇製造）取代8〇8之1^3)(85/\， 因而獲得比較組成物。當剖克洛拉滋溶液於漿液中乳化時 ，所得混合物呈現十分之黏稠狀。此比較組成物含有巨大 之聚集粒子。 由上述可清楚得知，使用具有較大磺化度之木質素磺 酸型表面活性劑時，無法獲得良好品質之水性懸浮-乳液 Ο 本纸張尺度適用中國國家標準（CNS ) Α4規格（2丨ΟΧ29?公釐） ，， -------「—ΐ (請先閱讀背面之注意事項再填寫本頁) 、ve 經濟部中央標準局員工消費合作社印製 30766α Α7 __Β7 五、發明説明（1 2 ) 經濟部中央標準局員工消費合作社印製 參者配方例3 重 複 配 方 例 1 , 但使用80g之 D e m 〇 1 SNB ( 一 種 表 面 活 性 劑 t 係 芳 基 磺 酸 納 與 福 馬林 之 縮 合 物 9 花 王 公 司 製 造 ) 取 代 80g 之 R e a X 85 Α。 當剖克洛β [滋溶液於 t漿液中分散時， 所 得 混 合 物 圼 現 十 分 之 黏稠 狀 〇 此 外 > 產 生 巨 大 之 聚 集 粒 子 9 因 此 1 無 法 獲 得 均 勻之 殺 真 菌 組 成 物 0 參 考 配 方 例 4 重 複 配 方 例 1 , 但使用80s之 So p r 0 P ho Γ F L ( 一 棰 表 面 活 性 劑 I 係 二 苯 乙 烯 基 酚磷 酸 酯 之 聚 環 氧 乙 烯 加 成 物 ) R h*o η e - Po u 1 e η c製造）取 代80 s之R e a X 8 5 A 0 結 果 * 當 剖 克 洛 拉 滋 溶 液 於 漿 液 中 乳 化時 所 得 混 合 物 呈 現 十 分 之 黏 稠 狀 0 此 外 > 產 生 巨 大 之 聚集 粒 子 » 因 此 > 無 法 獲 得 均 勻 之 殺 真 菌 組 成 物 0 參 考 配 方 例 5 重 複 配 方 例 1 , 但使用80s 之 十 二 基 苯 磺 酸 納 取 代 80 之 Re a X 85 A 0 當 剖 克 洛 拉滋 溶 液 於 漿 液 中 乳 化 時 9 所 得 混 合 物 圼 現 十 分 之 黏 稠 狀 。此 外 t 產 生 巨 大 之 聚 集 粒 子 « 因 此 > 無 法 獲 得 均 勻 之 殺 真菌 組 成 物 〇 # 考 配 方 例 () Γ. 重 複 配 方 例 1 , 但使用80g 之 N e ! W Po '1 e ：P E - 1 08 ( 種 非 離 子 性 之 表 面 活 性 劑 » 三洋 化 學 工 業 股 份 有 限 公 司 製 造 > 聚 氧 乙 烯 -聚氧丙烯嵌段共聚物） 取 代 80 丨g之R ：e a IX 8£ ί A 0 當 剖 克 洛 拉 滋 溶 液 於 漿 液 中乳 化 時 ， 所 得 混 合 物 呈 現 十 分 之 黏 稠 狀 〇 此 外 > 產 生 巨 大之 聚 集 粒 子 因 此 t 無 法 獲 得 均 -----「-裝|_ (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α·4規格（210X 297公釐） 訂 上線 12 3〇766〇 Λ7 B7 五、發明説明（13 ) 勻之殺真菌組成物。 參者配方例7 重複配方例1,但使用80g之Gohsenol GL-05(聚乙烯 酵，日本合成化學工業股份有限公司）取代80g之Reax 85A 。當剖克洛拉滋溶液於漿液中乳化時，所得混合物圼現十 分之黏稠狀。此外，產生巨大之聚集粒子，因此，無法獲 得均匀之殺真菌組成物。 參者配方例8 重複配方例1,但使用80gZGerop〇? T-36(聚羧酸納 型表面活性劑，R ne-Poulenc製造）.取代80g；2· Reax 85Α 。當剖克1洛拉滋溶液於漿液中乳化時，所得混合物圼現十 分之黏稠狀。此外，產生巨大之聚集粒子，因此，無法獲 表 種 各 之 外 Μ 。 劑液 性乳 活浮 面懸 表性 塩水 酸之 磺好 。 素良 物質得 成木獲 組用法 菌使無 真/當 ， 殺-時 之此劑 句因性 均 活 得面 將筒 且 圓 ，分 :5積 至121 釋om 稀10 水為 Μ 積 樓 » uenw 物之 成子 組蓋 之有 配具 調至 中充 2 填 或液 J1釋 例 稀 方 -之 配丨 --------4 —裝------訂-----^線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作杜印製 使轉 率之 速需 之所 轉散 3 分 鐘再 分全 1 完 每得 Μ 使 ，算 後計 時 ， 小下 24朝 〇 至 茼轉 圓 側 分上 憒之 置筒 靜圓 且分 中積 1 轉 例 4 方需 配物 -成 果組 结之 。 配 性調 散所 分 2 再例 之方 物配 成 ， 組轉 驗 2 試需 测物 檢成 Κ 組 , 之 數配 次調 動所 本生 之產 滋會 拉不 洛為 克且 剖 · 及方 酸配 克菌。 寧真物 里殺成 代態組 氧型異 之體優 分液之 成之殺 性合沈 活適體 為為晶 作物及 括成集 包姐聚 明子 發粒 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐）Shnmal Enterprises) was finely ground to obtain a slurry. While automatically mixing and mixing 200g of the resulting slurry in the M-type, 50g of Secroprozil solution dissolved in 50g of Solvesso 150 was added, followed by mixing and micronization, and K obtained a dispersion-emulsified liquid. On the other hand, 20g of Kelzan S was added to 980g of distilled water, and then heated to 60T: and dissolved, Μ obtained a thickened solution. 50 g of malonyl fermentation and 400 g of thickened solution were added to the above-mentioned dispersion-emulsified liquid, followed by addition of distilled water to prepare 1000 g of the composition of the present invention. Examination of the resulting composition of the present invention through a microscope revealed that no aggregated particles were found. Formulation Example 11 Dissolve Reax 85A in 150 s in 650 g of distilled water, add and disperse it with i200 g of oxolinic acid, and then finely grind it with KDL type Dyno_grinding machine to obtain a slurry . While the 650g of the resulting slurry was stirred by an automatic homomixer, 50g of cecrolazi solution dissolved in 508 solvesso 150 was added, followed by mixing and demicronization to obtain a dispersion-emulsified liquid. On the other hand, add 20g of Kelzan S to 980g of distilled water and dissolve it by heating to 60C to obtain a thickened solution. Add 50 g of malonate and 50 g of thickening solution to the above dispersion-emulsion liquid, and then add distilled water, M is 1000S of the composition of the present invention. Observation of the composition of the present invention through a microscope revealed that there were no hair-shaped aggregate particles. Formulation example 1 2 Dissolve 80g of Reax 85A in 800g of distilled water, then add 400g of oxolinic acid and disperse it, then use KDL type Dyno_grinding machine. The paper size is applicable to China National Standard (CNS) A4 specifications (210X297mm) ^ I installed ------ ordered ------- {line (please read the precautions on the back before filling out this page) 9 A7 B7 Printed by Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs V. Description of the invention (10) 1 1 I> λ Fine grinding »K Obtain the slurry 0 While mixing the resulting slurry of 1 1 I 600s with Μ Μ type white dynamic homomixer 1 Add and dissolve in 90s So 1 ν es SO 150-1 1 I 1 0 g sucralose solution, followed by mixing and micronization, Μ to obtain dispersion-milk /--ν please 1 1 I liquid 0 on the other hand i add 20g Ke 1 z an S 9 Read the 1 1 1 on the back of 80 g of distilled water and dissolve 1 Μ by heating to Q0V to obtain a thickened solution. Add 50 g of propylene 1 1 1 diol and 1 25 g of the thickened solution to the above dispersion-emulsified liquid > Connect > King Intention 1 1, 1— 1 and then added m water, M produced 1000 g of the composition of the invention. The composition of the invention obtained through observation and refilling the micromirror showed no aggregate particles were found. SL Example 13 1 Dissolve 80 s of Rea X 85A in 80 〇g_ distilled water, then add 40 g 1 of oxolinic acid and disperse S followed by Μ KDL type D y η 〇- mill Μ 1 1 Order 1 Finely grind 9 to obtain a slurry. While adding the resulting slurry of Μ Μ type automatic homomixer m to 5 0 0 s, 9 was added and dissolved in 1 5 0 g So 1 ν e SS 0 1 5 0 g The 1K caratzol solution of Chaluo is then mixed and micronized to obtain a dispersion-emulsified liquid. On the other hand, 20 g of Ke 1 za η S is added to 9 80 g of distilled water and heated to 60 scoops by wire to dissolve T to obtain a thickened solution. Add 50 g of malonate and 1 I 50 s thickening solution to the above dispersion-emulsified liquid * followed by adding 1 1 distilled water »to obtain the invention composition of 100 g. Observation through a microscope • The composition 9 of the present invention obtained by 1 1 shows that no aggregated particles are found 0-1 1 £ Example 1 4 1 The 80 s Rea X 8 5 / \ and 2 g of S Ο Γ P 〇1 8 0 4 3 (Polyoxyethylene alkyl 1 1 | Benzyl ether 9 To h 〇 Chemical Co., Ltd.) dissolved in 7 1 8g of distilled water, plus 1 I 400 s of oxolinic acid and then divided KDL type D y η 0-grind 1 1 I machine to Μ finely grind Μ to obtain slurry 0 in Μ Μ type white motion homomixer 挢 1 1 The paper size is applicable to China National Standards (CNS) A4 specifications (210X297 mm ) A7 B7 307660 V. Description of the invention (11) While mixing 600g of the resulting slurry, add 50g of Secrosol dissolved in 150g of Hisol SAS-296 (phenylxylylethane, manufactured by Nippon Petrochemical Co., Ltd.) Lazi solution, followed by mixing and micronization, K to obtain dispersion-emulsified liquid. On the other hand, 10g Kelzan S and 20g Veegum R were added to 970 distilled water and heated to dissolve Kelzan S, K to obtain a thickened solution. 50 g of malonyl fermentation and 100 g of thickened solution were added to the above-mentioned dispersion-emulsified liquid, followed by the addition of distilled water to prepare 1000 s of the composition of the present invention. Observation of the composition of the present invention through a microscope revealed that no aggregated particles were found. Participant's Example 1 and Repeated Formulation Example 1, but using 80 g of Rea X 8 8 β (sodium lignosulfonate with an average sulfonation degree of 3.8, manufactured by West d co) instead of 80 g of Reax 85Α, thus obtained Compare the composition. When Eccleolax solution was emulsified in the slurry, the resulting mixture appeared very viscous. The comparative composition contains huge aggregated particles. Refer to Example 2 of the old ffi Repeat Example 1 of the recipe, but use Rea X 1 0 0 Μ of 80 S (an average sulfonation degree of 4.7 lignin sodium acid, '^ 51; ¥ end (: 〇 manufacturing) instead 1〇3 of 8〇8) (85 / \, thus obtaining a comparative composition. When the emulsifying solution of crocolax is emulsified in the slurry, the resulting mixture appears very viscous. This comparative composition contains huge aggregated particles. It is clear from the above that when using ligninsulfonic acid surfactants with a relatively large degree of sulfonation, a good quality aqueous suspension-emulsion cannot be obtained. This paper size is applicable to China National Standard (CNS) Α4 specifications (2丨 ΟΧ29? Mm) ,, ------- "— (Please read the precautions on the back before filling out this page), ve printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, 30766α Α7 __Β7 V. Description of the invention (1 2) The Ministry of Economic Affairs, Central Bureau of Standards, Employee Consumer Cooperative printed the participant ’s recipe example 3 Repeated recipe example 1, but using 80g of Dem 〇1 SNB (a surfactant t-based arylsulfonate and formalin condensation Object 9 made by Kao Corporation) replaced 80 g of Rea X 85 Α. When Secrole β [the nourishing solution is dispersed in the t slurry, the resulting mixture appears to be very viscous. In addition> huge aggregated particles 9 are produced. Therefore 1 a uniform fungicidal composition cannot be obtained Material 0 Refer to Formulation Example 4 Repeat Formulation Example 1, but use 80 s So pr 0 P ho Γ FL (one-surfactant I is a polyoxyethylene adduct of stilbene phenol phosphate) R h * o η e-manufactured by Po u 1 e η c) replaces 80 s of Rea X 8 5 A 0 Result * The mixture obtained when emulsified crocolaz solution in the slurry appears to be very viscous 0 In addition > Aggregated particles »Therefore> Unable to obtain a uniform fungicidal composition 0 Refer to Formulation Example 5 Repeat Formulation Example 1, but replace 80 of Re a X 85 A 0 with 80s of sodium dodecylbenzenesulfonate The solution is emulsified in the slurry 9 to obtain mixed composition Nie now sticky viscous tenths. In addition, t produces huge aggregated particles «Therefore> Unable to obtain a uniform fungicidal composition. 〇 Consider the formulation example () Γ. Repeat the formulation example 1, but use 80g of N e! W Po '1 e: PE-1 08 (A kind of nonionic surfactant »Made by Sanyo Chemical Industry Co., Ltd.> Polyoxyethylene-polyoxypropylene block copolymer) Substitute R of 80 丨 g: ea IX 8 £ ί A 0 Dangsa Cola When the nourishing solution is emulsified in the slurry, the resulting mixture appears to be very viscous. In addition > huge aggregated particles are produced so that t cannot be obtained ----- "-install | _ (please read the precautions on the back before filling in this Page) This paper scale applies the Chinese National Standard (CNS) A · 4 specifications (210X 297 mm). Ordered online 12 3〇766〇Λ7 B7 5. Description of the invention (13) A uniform fungicidal composition. Participant formulation example 7 Repeat Formulation Example 1, but use 80g of Gohsenol GL-05 (polyethylene leaven, Japan Synthetic Chemical Industry Co., Ltd. ) Replace 80g of Reax 85A. When the emulsified crocolaz solution is emulsified in the slurry, the resulting mixture appears very viscous. In addition, huge aggregated particles are generated, so a uniform fungicidal composition cannot be obtained. Formulation Example 8 Formulation Example 1 was repeated, but using 80 g of ZGerop〇? T-36 (polycarboxylate sodium surfactant, manufactured by R ne-Poulenc). Instead of 80 g; 2. Reax 85Α. When emulsified in the slurry, the resulting mixture appears very viscous. In addition, it produces huge aggregated particles, so it is not possible to obtain M other than the surface species. The sulfonate of the surface acid is good when the liquid emulsion surface is suspended. The material can be made into wood with the use of bacteria to make it true / dang, killing-time, this agent sentence will live and be round and round due to its nature, points: 5 to 121 release om dilute 10 water for Μ building »uenw The sub-group cover is equipped with a tool that is adjusted to the middle charge 2 filling or liquid J1 release example thin side-the matching 丨 -------- 4-loading ------ order ----- ^ line (Please read the precautions on the back before filling out this page) Du Printed by the Consumer Cooperation of the Central Standards Bureau of the Ministry of Economic Affairs The speed of the rotation rate needs to be dispersed for 3 minutes and then divided into 1 to complete the calculation. After counting, count down 24 to 0 to the side of the turn circle. 4 The party needs the ingredients-the results are assembled. The distribution of dispersal is divided into 2 other prescriptions, and the group transfer test 2 test needs to be tested into the K group, the number of times of the transfer of the birth of the birth will be Labrolo for grams and cut. Acid bacteria. Ning Zhenwu's killing generation group oxygen type heterogeneous body excellent liquid separation and killing combined aptamers are for crystalline crops and Baochengji Baojie Jumingzi hair granules. The paper size applies to the Chinese National Standard ) Α4 specification (210Χ297mm)